BACKGROUND OF THE INVENTION
1. Field of the Invention
[0001] The present invention is related to a coal treatment process for a coal fired power
plant, and particularly for a process, which is implemented with a coal-beneficiation
process module to extract water, non-combustible ash, mercury and oil that are associated
with coal before firing the coal.
2. Description of the Prior Art
[0002] Technologies for the treatment of coal to improve its quality as a fuel for power
plants have been known including pyrolysis of coal with microwave energies. The following
nine patents and published patent applications are the closest prior art references
which are related to the present invention.
- 1. United States Patent No. 3,449,213 issued to Edward M. Knapp et. al on June 10, 1969 for "Pyrolysis of Coal With Microwave" (hereafter the "Knapp
'213 Patent");
- 2. United States Patent No. 3,560,347 issued to Edward M. Knapp et. al on February
2, 1971 for "Apparatus For Carbonizing Carbonaceous Materials Using Microwave Energy"
(hereafter the "Knapp '347 Patent");
- 3. United States Patent No. 4,118,282 issued to Floyd D. Wallace and assigned to Wallace Energy Conversion, Inc. on October 3, 1978 for "Process And
Apparatus For The Destructive Distillation Of High Molecular Weight Organic Materials"
(hereafter the "Wallace Patent");
- 4. United States Patent No. 4,123,230 issued to Chalmer G. Kirkbride on October 31, 1978 for "Sulfur Removal From Coal" (hereafter the "Kirkbride '230 Patent");
- 5. United States Patent No. 4,148,614 issued to Chalmer G. Kirkbride on April 10, 1979 for "Process For Removing Sulfur From Coal" (hereafter the "Kirkbride '614 Patent");
- 6. United States Patent No. 4,234,402 issued to Chalmer G. Kirkbride on November 18, 1980 for "Sulfur Removal From Crude Petroleum" (hereafter the "Kirkbride '402 Patent");
- 7. United States Patent Published Application No. US2007/0131591 to Frank G. Pringle and published on June 14, 2007 for "Microwave-Based Recovery of Hydrocarbons and Fossil Fuels" (hereafter the "Pringle
Patent Application");
- 8. United States Patent No. 4,259,560 issued to George W. Rhodes on March 31, 1981 for "Process for Drying Coal and Other Conductive Materials Using Microwaves" (hereafter
the "Rhodes Patent"); and
- 9. Australia Patent Published Application No WO/2007/028208 to Edek Choros and published on March 15, 2007 for "Hybrid Energy System" (hereinafter
the Choros patent application)
[0003] The Knapp '213 Patent discloses a method for recovering sophisticated volatile materials
of commerce extracted by heat from coal. The method consists of the following four
steps: (1) The heating of coal to a temperature of approximately 600 F; (2) The pyrolysis
of the coal by the use of an industrial heating microwave unit to a temperature of
approximately 800 F in a partial vacuum; (3) The total absorption of the effluent
from the pyrolysis in an oil bath, followed by partial desorption of the chemicals
of commerce at a temperature which separates the chemicals of commerce and (4) The
vapor phase fractionation of the resulting gas stream prior to any commingling of
the chemicals of commerce and before returning to ambient temperature.
[0004] The Knapp '347 Patent, which is a division of the Knapp '213 Patent, discloses an
apparatus for carbonizing coal. The coal is first preheated in a first chamber by
direct contact with hot gases, and is then carbonized in a second chamber using microwave
energy as the heat source. The volatile materials from the second chamber are fractionally
condensed.
[0005] The Wallace Patent discloses a process and apparatus for destructive distillation
of high molecular weight organic materials such as organic wastes using ultrasonic
and microwave generators together to irradiate and molecularly disperse the organic
molecules in the organic materials. Application of the patented technology produces
products of clean gaseous volatile chemicals having a high fuel value and by-products
of charcoal, tars, resins and pure carbon.
[0006] The Kirkbride '230 Patent discloses a process for decreasing the sulfur content of
coal, including drying coal and subjecting the dried coal in a hydrogen atmosphere
to the influence of microwave energy.
[0007] The Kirkbride '614 Patent discloses a process for decreasing the sulfur content of
coal, including forming a slurry of coal particles in an inert solvent, and subjecting
the slurry in admixture with hydrogen with microwave energy.
[0008] The Kirkbride '402 Patent discloses a process for decreasing the sulfur content of
coal or crude petroleum, including drying coal and subjecting the dried coal in a
hydrogen atmosphere to microwave energy.
[0009] The Pringle Patent Application discloses methods for decomposing and extracting compositions
for the recovery of petroleum based materials from composites comprising those petroleum-based
materials. The methods include subjecting the compositions and/or composites to microwave
radiation in the range of from about 4GHz to about 18GHz.
[0010] The Rhodes Patent discloses a process for drying a conductive material, particularly
coal, by subjecting the material to microwave energy, wherein a conductive aggregate
is directed, through a region where microwave energy excites absorbed water molecules
and the conductive material causes the water evaporate, resulting in a drier material.
[0011] The Choros Patent describes a hybrid method for producing energy from a carbonaceous
material including the steps of: heating the carbonaceous material under a reduced
oxygen atmosphere in a distillation plant to generate distillate vapors; processing
the resulting distillate vapors; transferring the char residue from the distillation
plant to a power station boiler; and combusting the char residue in the power station
boiler for the generation of electrical power.
[0012] In general, coal is a primary energy resource to generate electricity at coal-fired
power plants in numerous locations throughout the world. Coal is also associated with
various other chemical substances, including water, non-combustible ash, mercury and
oil. The presence of such chemicals causes significant problems in the coal firing
process that is required for producing electricity. The coal's water content lowers
the BTU energy value of the coal and reduces the power plant boiler's efficiency.
The coal's non-combustible ash content results in boiler furnace erosion and ash-deposition
problems. The coal's mercury content causes an air pollution emission, and the coal's
oil values are lost during combustion, wasting a valuable natural resource of oil
for transportation fuels.
[0013] The problems disclosed above have a significant impact on the environment, since
a typical 500 mega watts (MW) coal-fired power plant consumes some 7,000 tons of coal
a day. In the United States, Wyoming Powder River Basin coal (PRB) is frequently used
because it has a low sulfur constituent. Typically, the PRB coal contains 15% to 25%
of water, 6% to 15% of non-combustible ash, up to 40 % of volatile matter (oil), and
mercury constituents (approximately 100-150 parts per Billion). Therefore, if the
500 MW power plant uses the PRB coal every day, the equivalent of 260,000 gallons
of water, 700 tons of non-combustible ash and 5,000 barrels of oil are estimated to
be consumed, with about 1.4 pounds of mercury released to the atmosphere each day.
In a situation where some 281 U.S. power plants fire PRB type coals, the collection
and or control of such natural chemical substance in the coal is significant, both
in economic impact and environmental protection to the United States. It also will
be appreciated that the issue of such substance collection and or control is also
critical to rest of the world, where coal fired power plants are frequently used.
[0014] A typical coal-fired power plant pulverizes the coal to a fine powder (approximately
50 micron in size) in a coal mill using hot "primary" air extracted from the power
plant combustion air heater. As the coal is pulverized, the hot air evaporates the
water in the coal and cools. The primary air then conveys the powdered coal along
with the water vapor from the coal mill to the power plant coal burners, wherein the
coal is burned to create heat and steam for electricity production. The water vapor
from the coal that is carried along with the powdered coal into the furnace causes
loss of heat energy and results in a boiler efficiency loss. A "rule of thumb" estimates
that for each 10% of coal moisture carried into the furnace results in a 1% efficiency
loss. Therefore, a method to remove the coal moisture from the furnace will improve
the boiler efficiency.
[0015] Along with the coal, the non-combustible ash is also pulverized to a fine powder.
This ash includes many natural elements and mineral compounds that may form air pollutants
and or accumulate as mineral deposits on the boiler furnace surfaces. These deposits
reduce the heat transfer from the hot combustion gases to the boiler surfaces, resulting
in a reduced boiler efficiency. Additionally, some minerals may cause erosion and
or corrosion of the boiler heat transfer surfaces. A reduction of the quantity of
the ash passing through the furnace is needed to improve boiler operating reliability
and efficiency.
[0016] Coal also contains traces of the element mercury. Recent air pollution regulations
require stringent control of mercury emissions from power plants. The conventional
mercury control methods capture the mercury from the exhaust gases downstream of the
power plant where the mercury specie are very dilute (in parts per trillion) and difficult
to capture. A method to efficiently remove the mercury from the coal before the coal
is fired in the power plant is needed.
[0017] Many coals include a volatile hydrocarbon component that may be extracted as a crude
oil product. Demonstrated thermal processes to extract oil from coal date from the
1850's, in England and Eastern U.S. driven by the need to avoid the extinction of
Whales, a primary source of lamp oil for that period. More recent programs funded
by the United States Department of Energy and others have further developed oil from
coal extraction processes. The conventional oil extraction methods convey raw lumps
of coal (two inch by two inch) to a sealed air-tight vessel. The coal lumps are carefully
heated in the absence of air (pyrolyzed) to release some fraction of the volatile
matter contained in the coal as an oil vapor. The oil vapor product is then transferred
to an oil condenser and collected as a crude oil liquid. The crude oil must be further
treated with hydrogen to make it suitable for conventional oil refinery processing
into diesel, gasoline and jet fuels. Generally, the process to heat coal lumps is
very slow with care to avoid over heating the coal, taking approximately 20 to 60
minutes to vaporize the oil. These time consuming methodologies of coal treatment
result in significantly large and costly equipment installations in order process
the many tons a day of coal required by a typical coal fired power plant and are not
commercially viable.
[0018] Therefore, there is an important need to provide a method by which large quantities
of coal can be processed very rapidly, right at the power plant site; to collect the
water, non-combustible ash, mercury and oil values that are associated with the coal,
thereby significantly improving the power plant electric generation efficiency with
reduced pollutant emissions, and providing a reduced cost of operation through sale
of the oil and water products.
SUMMARY OF THE INVENTION
[0019] An embodiment of the present invention is a coal treatment process containing a coal-beneficiation
process module. The module may be implemented into the conventional coal-fired power
plant after the coal treatment process step of grinding the coal with a coal mill
to a fine powder. A typical coal-fired power plant may use a multiple of coal mills
in order to grind a sufficient quantity of coal to supply the total energy required
for the power plant. It is expected that a coal-beneficiation process module will
be added to each coal mill, and process the powdered coal from that mill. A process
module embodying the present invention sequentially extracts chemical substances of
water, non-combustible ash, mercury and oil that are naturally present in coal before
the coal is burned in the power plant, so that the embodiment can achieve goals of
increasing the combustion efficiency to produce electricity, reducing pollution in
the environment, and saving the precious natural substances at the coal-fired power
plants. In addition, the process module embodying the present invention treats the
fine coal particles conveyed with an inert sweep gas in a fluidity state to thereby
achieve the very rapid processing that results in less equipment to treat the coal,
and thereby reduce the cost of the process. Another key innovation is that the process
embodying the present invention is located adjacent to and integrated with the power
plant and its coal handling equipment, thereby providing the necessary equipment and
inert gases for safe and rapid processing of the large quantities of coal used by
the power plant.
[0020] The present invention process module includes two preferred embodiments for extracting
chemical substances from the powdered coal before the coal is used in a power plant.
Both embodiments have the same first steps in the process module to extract the surface
water and non-combustible ash from the powdered coal to thereby form a dried powdered
coal containing mercury and oil. For the first preferred embodiment, the process comprises
extraction of mercury and oil associated with the coal. During the extraction process,
the powdered coal is irradiated with microwave energy to quickly heat and vaporize
the mercury in the coal, which is released at a lower temperature than the oil. The
produced mercury vapor that is separated from the coal is then collected to thereby
form a liquid mercury product. In the next step of extracting the oil in the coal,
the oil is vaporized by irradiating the powdered coal with additional microwave energies
to achieve the necessary higher temperatures to release the oil values. The resulting
oil vapor is collected and further condensed to form an oil product.
[0021] Alternatively, in the second preferred embodiment, the process uses sufficient microwave
energy to simultaneous vaporize both the mercury and oil in the coal. Then the vaporized
oil is condensed into a liquid for the oil separation. Then the remaining vaporized
mercury is additionally condensed to thereby collect a liquid mercury product.
[0022] It will be appreciated that a process module embodying the present invention includes
an option, which comprises at least one, and up to four processes for extracting the
respective naturally occurring chemical substances in coal if a particular substance
or substances are found in the specific coal being used.
[0023] It has also been discovered, according to an embodiment of the present invention,
that if the process to treat coal to extract substances before the coal is used in
a power plant is performed at a facility adjacent to the power plant, then the treated
coal is immediately ready for use in the power plant and the costs of transporting
the treated coal to be used in the power plant will be significantly reduced. The
power plant also can provide the necessary inert gases to safely convey the dry powdered
coal through the process steps, and can dispose of any waste gases that may be released
by the mercury and oil extraction processes by combustion in the furnace. The integration
of the coal-beneficiation process module with the power plant equipment is thereby
expected to substantially reduce to the overall cost of the process.
[0024] It is therefore desirable to provide a coal treatment process containing a coal-beneficiation
process module. A module embodying the present invention may be implemented into the
conventional coal-fired power plant after the coal treatment process step of grinding
the coal to a fine powder. The process module sequentially extracts chemical substances
of water, non-combustible ash, mercury and oil that are naturally found in coal before
the coal is fired, so that the embodiment can achieve objects of increasing efficiency
to produce electricity, reducing pollution of environment, and saving the precious
natural substances in coal at the coal-fired power plants.
[0025] It is also desirable to provide a coal treatment process containing a coal-beneficiation
process module, wherein the process module treats the fine coal particles conveyed
by an inert sweep gas in a fluidity state to thereby achieve a rapid coal treatment
process, provide safe transport of the coal through the process, require less equipment
in the coal treatment process, and therefore improves the economic cost of the coal
production and treatment.
[0026] It is also desirable to provide two preferred embodiments for extracting the chemical
substances, wherein both embodiments have the same first steps of the process module
to extract the non-combustible ash and water, which forms a dried powdered coal containing
mercury and oil. The first preferred embodiment is comprised of rest of the process
to extract chemical substances from within the coal. During the extraction process,
microwave energies are irradiated into the coal, which first vaporizes the mercury.
The produced mercury vapor that is separated from the coal is then collected to form
a liquid mercury product. In the next step of extracting the oil in the coal, the
oil is vaporized by irradiation of additional microwave energies, wherein the oil
vapor is collected and further condensed to form an oil product.
[0027] It is also desirable to provide a second preferred embodiment of the present invention
process module, wherein water and a non-combustible ash are first separated from the
powdered coal. The second embodiment also includes a step to simultaneously vaporize
the mercury and oil in the coal, and then to selectively first condense oil vapor
for the oil separation and then condense mercury vapor to thereby collect a liquid
mercury product.
[0028] It is also desirable to provide an option to comprise at least one, or up to four,
processes, so that the embodiment can extract the respective naturally found chemical
substances if a particular substance or substances are within the coal being used.
[0029] It is also desirable to provide a process to treat coal to extract substances before
the coal is used in a power plant that is performed at a facility adjacent to the
power plant, so that the treated coal is immediately ready for use in the power plant
and the costs of transporting the treated coal to be used in the power plant will
be significantly reduced. The power plant also can provide the necessary inert gases
to safely convey the dry powdered coal through the process steps, and can safely dispose
of any waste gases that may be released by the mercury and oil extraction processes
by combustion in the furnace.
[0030] Further novel features and other advantages of the present invention will become
apparent from the following detailed description, discussion and the appended claims,
taken in conjunction with the drawings.
BRIEF DESCRIPTION OF THE DRAWINGS
[0031] Referring particularly to the drawings for the purpose of illustration only and not
limitation, there is illustrated:
FIG. 1 is a schematic diagram of a traditional process at a typical pulverized coal-fired
power plant, which illustrates the primary steps related to coal firing;
FIG. 2 is a schematic diagram to illustrate that a coal-beneficiation process module
is implemented into the traditional process, which embodies the present invention;
FIG. 3A is a schematic diagram, which illustrate a first part of a first preferred
embodiment of the present invention coal-beneficiation process module;
FIG. 3B is a schematic diagram, which illustrates a second part of the first preferred
embodiment of the present invention coal-beneficiation process module; and
FIG. 4 is a schematic diagram, which illustrates a second part of the second preferred
embodiment of the present invention process module, wherein a first part of the preferred
embodiment is the same as the first part of the first preferred embodiment of the
present invention process module.
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS
[0032] Although specific embodiments of the present invention will now be described with
reference to the drawings, it should be understood that such embodiments are by way
of example only and merely illustrative of but a small number of the many possible
specific embodiments which can represent applications of the principles of the present
invention. Various changes and modifications obvious to one skilled in the art to
which the present invention pertains are deemed to be within the spirit, scope and
contemplation of the present invention as further defined in the appended claims.
[0033] An embodiment of the present invention is a coal treatment process containing a coal-beneficiation
process module. The module is implemented into the conventional coal-fired power plant
after the coal treatment process step of grinding the coal in a coal mill to a fine
powder. The process module sequentially extracts chemical substances of water, non-combustible
ash, mercury and oil that are naturally found in the coal before the coal is fired,
so that the embodiment can achieve objects of increasing efficiency to produce electricity
by burning cleaner coal with low water content, reducing pollution of environment
by burning cleaner coal, and obtaining maximum energy from the coal so that less coal
is wasted. In addition, by using a hot inert gas derived from the power plant as a
sweep gas to convey the material, the process module treats the fine coal particles
in a fluidity state to thereby enable the process to be performed safely, rapidly
and more efficiently, enabling the process to be performed with less equipment in
the coal treatment process and thereby results in a more economical treatment process.
[0034] Referring to Figure 1, there is illustrated the conventional process
10 in a typical coal-fired power plant. As illustrated, raw coal
42 is transferred from a coal bunker
40 to a coal feeder
44, which is connected to a coal mill
46. Therefore, the raw coal
42 containing chemical substances of water, non-combustible ash, mercury and oil that
are naturally found in the coal, which is fed into the coal mill, is ground into a
powdered coal. Preferably, the grinding is achieved so that the ground coal particles
have a typical size less than 50 micro meters. During the grinding process, a hot
primary air
50 is blown into the mill by a mill fan
48 that is connected to the mill
46. The hot primary air
50 serves to evaporate some moisture from the coal
42 during the grinding process and is cooled. The powdered coal is then mixed with the
hot primary air
50 inside of the mill
46 to thereby form a mixture
60 of powdered coal, water vapor and cooled primary air. The mixture
60 of the powdered coal is then swept into burners
66 with the primary air
50. The powdered coal is burned in the presence of the primary air
50 with additional hot secondary air
52 for completion of the coal combustion in the furnace
64.
[0035] It will be appreciated that the hot primary air
50 is produced from the ambient combustion air
56 in the above illustrated conventional process. The ambient air
56, which is blown by a fan
58, is heated by a combustion air heater
78, where the exchange of the heat takes place from a hot inert flue gas
76 produced by burning coal in the furnace
64. Therefore, the ambient combustion air
56 is turned into hot combustion air
54, which also serves as the hot primary air
50 and hot secondary air
52 to perform a chemical function in combustion of the powdered coal.
[0036] As further illustrated, a boiler feed water
70 is transferred into a boiler
68 that is a built-in apparatus inside of the furnace
64, where heat from the coal firing is exchanged with the water. Therefore, the boiler
feed water
70 is converted to boiler steam
72 having a high temperature and pressure. The boiler steam
72, which is out of the boiler
68, is then used as a source of power to drive turbines that are mechanically connected
to respective electric generators, so that electricity is produced.
[0037] It will be appreciated that the coal combustion produces the hot inert flue gas
76 having less than 10% oxygen and more typically approximately 3% oxygen at an economizer
74 of the furnace
64. The hot inert flue gas
76 passes through the air heater
78, to partially exchange its heat to the ambient combustion air
56, and become a cooler inert flue gas
80. The cooler inert flue gas
80 is then transferred to an emission control unit
82, where waste products
84 are separated and collected. The produced flue gas
86 which is pressurized by a fan
88 is further transferred to a stack for disposal to the atmosphere.
[0038] Referring to the above illustrated conventional process at the typical coal fired
power plants, it will be appreciated that, the process possesses two major disadvantages.
First, it bums and therefore wastes various chemical substances that are naturally
found in the coal, including water, non-combustible ash, mercury and oil. Without
prior extraction, the water, non-combustible ash, mercury and oil that are in the
coal are burned in the coal firing process. By burning these materials in the coal,
these materials are wasted. If they are separated from the coal before burning, the
materials can be used for other purposes. Further, burning the coal containing these
materials reduces the efficiency of the combustion process and results in greater
pollution of the air. Another problem encountered in the conventional process is that
the hot combustion air that serves as the carrier to transfer the powdered coal in
the power plant may provide the condition to cause the coal to bum outside of the
furnace in a self-burn process. This can happen because the hot combustion air
54 which has a high temperature and may contain sufficient oxygen (such as 22%) that
will support and facilitate the self burning of the coal or cause a dangerous explosion
or "puff" event in the equipment. It may be appreciated that the use of an hot inert
sweep gas containing less than 10% oxygen and more typically 3% oxygen to transport
the powdered coal prevents fires and "puffs" in the equipment.
[0039] Referring to Figure 2, there is illustrated a portion of the improved coal firing
process
20 for a coal fired power plant, which implements a coal-beneficiation process module
30 embodying the present invention having first and second preferred embodiments
31 and
32. The process module comprises the steps of extracting water, non-combustible ash,
mercury and oil before the coal is fired, so that the embodiment eliminates these
elements from the coal before it is burned in the power plant. As specifically illustrated
in Figure 2, the process module
30 is implemented into the conventional coal-fired power plant after the coal treatment
process step of grinding the coal in a coal mill to a fine powder
[0040] In addition to the implemented process module
30, a sweep gas generator
106 may also be added in an embodiment of the present invention. The sweep gas generator
106 generates a sweep gas
108, which includes a low oxygen content at a controllable and adjustable temperature.
The addition of the low oxygen sweep gas significantly reduces the risk of the coal
self burning which is a problem with the conventional process. As illustrated, a part
of the hot inert flue gas
76 is combined with a part of the cool inert flue gas
80 at the sweep gas generator
106 to form the sweep gas
108 having a controlled temperature. It will be appreciated that controlling the temperature
of the sweep gas
108 is achieved by controlling the ratio of the hot inert flue gas
76 and cool inert flue gas
80, when they are combined inside of the generator
106. Therefore, the sweep gas
108 having a low oxygen content less than 10% and more typically approximately 3% and
controlled temperature prevents the powdered coal from self burning when the coal
is transferred by the sweep gas
108 in the process module embodying the present invention.
[0041] As illustrated in Figure 2, the sweep gas
108 at the controlled temperature is fed into the coal mill
46, along with the raw coal
42, that includes naturally occurring elements including water, non-combustible ash,
mercury and oil where it is ground into a powdered coal. During the grinding process,
the sweep gas
108 serves to evaporate some moisture from the coal
42 during the grinding process and is cooled. The cool sweep gas, water vapor and powdered
coal (containing residual water, mercury, and oil) and non-combustible ash forms a
mixture
110. The mixture
110 is conveyed from the mill to the coal-beneficiation process module
30. The mixture
110 is then treated by the process module
30 to thereby obtain a water product
166, oil product
162, mercury product
146 and non-combustible ash
118, in addition to a byproduct of waste sweep gases
144, 160, 168 and
216. The coal-beneficiation process module
30 thereby delivers an improved quality cleaned powdered coal-char product
154 conveyed with additional sweep gas
108 to the coal burners
66. As previously described, the ambient combustion air
56 is turned into hot combustion air
54, which also serves as the hot secondary air
54 to perform a chemical function in combustion of the powdered coal-char product
154 in the furnace
64 thereby generating heat and steam
72.
[0042] Referring to Figures 3A and 3B, there is illustrated first preferred embodiment
31 of the present invention coal-beneficiation process module
30. The mixture
110 of the sweep gas and powdered coal containing water vapor, water, mercury and oil
that is mixed with the non-combustible ash is transferred into a conventional bag
house separator (or solid-gas separator)
112 for extracting the powdered coal containing, water, mercury and oil that is mixed
with the non-combustible ash from the water vapor and sweep gas. It will be appreciated
that the separator
112 forms a mixture
114 of a water vapor and the sweep gas at the upper stream of the separator. The mixture
114 is further transferred into a water condenser
164, where clean water
166 is produced and collected at a location downstream of the condenser
164.
[0043] As illustrated in Figure 3A, at a location down stream of the separator
112, a mixture
113 of the powdered non-combustible ash and a less wet powdered coal containing residual
water, mercury and oil is produced. The mixture
113 is transferred into a triboelectric separator
116 that is connected to the separator
112.
[0044] It will be appreciated that the fine coal powders of the mixture
113 carry no electrical charge from the bag house separation process. The triboelectric
separator
116 applies electrical charges to the powder mixture
113. In the present embodiment, the non-combustible ash
118 is not charged, while the coal powders are electrically charged. In the triboelectric
separator
116, an electrostatic field is applied to the powder mixture
113 to produce the separated non-combustible powdered ash
118 that is further collected for disposal, and a mixture
120 of the reduced wetted powdered coal containing residual water, mercury and oil, which
is also further collected.
[0045] The mixture
120 is transferred into a final coal dryer
122, where any residual water that is associated with the less wetted powdered coal is
vaporized in the presence of the sweep gas
108 to form a mixture
124 of the water vapor and sweep gas. It will be appreciated that removing the residual
water in the coal in final coal dryer
122 will reduce the time and energy needed to heat the fine dry coal particles with microwave
energies in the next process step. As there are a multiple of coal-beneficiation process
modules, one for each coal mill, a large quantity of powdered coal can be processed
rapidly. The mixture
124 is further transferred to the water condenser
164, where it is combined with the water vapor mixture
114. Therefore, the combined water vapor is converted to water in a liquid form that is
further collected to create a total produced water
166 from the process module.
[0046] Referring to Figures 2 and 3A, the waste sweep gas byproduct
168 with moisture removed is then fed to the furnace
64 for combustion of any contaminated materials derived in the extraction process. In
addition, it will be appreciated that removal of the water from the coal, as water
vapor in the sweep gas mixture
114 and
124 as provided in the process module, results in an improved combustion efficiency of
the furnace
64.
[0047] As further illustrated in Figure 3A, after the final coal drying step, the embodiment
produces a dried powdered coal
125 containing mercury and oil at a location down stream of the dryer
122. The powdered coal is further mixed by the sweep gas
108 to form a mixture
126. Referring to Figure 3B, there is illustrated the remaining steps in the first embodiment
31. The mixture
126 is then conveyed by the sweep gas into a first microwave oven
128, where the mixture
126 is heated by the microwave energies to reach a temperature of approximately 400 F.
It will be appreciated that the microwave energies will quickly heat the fine dry
coal particles sufficiently to vaporize the mercury that is naturally found in the
powdered coal. This forms a mixture
130 of a mercury vapor, the sweep gas, and cleaned powdered coal containing oil.
[0048] The mixture
130 is transferred into a solid-gas separator
132 for separation. In the separator
132, there is produced a mixture
134 of the mercury vapor and the sweep gas in the upper stream of the separator
132. The mixture
134 is further transferred into a mercury condenser
142 to thereby form a mercury product
146 for safe disposal or further use. In addition, the condensation process further produces
a waste sweep gas
144 at the upper stream of the condenser
142.
[0049] As illustrated in Figure 3B, the separation of the mercury vapor mixture
134 further produces a dried cleaned powdered coal
136 containing oil at a location down stream of the separator
132. The coal
136 is then mixed by the sweep gas
108 to form a mixture
138, which is further transferred into a second microwave oven
140 having a preferred temperature approximately at 1000 F, so that the mixture
136 is heated. It will be appreciated that the microwave energies will quickly heat the
fine dry coal particles sufficiently to vaporize the oil values associated with the
powdered coal
136 to form a mixture
148 of an oil vapor, the sweep gas and a high quality cleaned dried powdered coal-char.
[0050] The mixture
148 is transferred into a solid-gas separator
150 where the dried powdered coal-char
152 is produced and collected at a location down stream of the separator
150. Alternatively, in a continuous configuration, the high quality cleaned powdered coal-char
152 is mixed by the sweep gas
108 to form a mixture
154, which can be conveniently transferred.
[0051] In addition, a mixture
156 of the oil vapor and sweep gas produced after the separation is transferred into
an oil condenser
158. This produces a liquid oil product
162 at a location down stream of the oil condenser, and an additional product waste sweep
gas
160 at the upper stream. It will be appreciated that, as illustrated in Figure 3B, the
produced oil product
162 is collected for shipment for use, or for further hydrogenation treatment
170 to form various oil products suitable for conventional refining to transportation
fuels, including gasoline, diesel fuel and JP-8 jet fuel.
[0052] Referring to Figures 2 and 3B, the produced mixture
154 of the high quality cleaned powdered coal-char
152 and sweep gas is transferred to the burners
66 of the furnace
64, where the high quality cleaned powdered coal-char
152 with the sweep gas is burned in the presence of the hot combustion secondary air
54 that is produced according to the step of the conventional process that is illustrated
above. Therefore, electricity can be produced following the illustrated procedure
as discussed above. It will be appreciated that the combustion of the high quality
cleaned powdered coal-char
152 from the embodiment wherein the chemicals of water, mercury, and oil have been eliminated
to create a more eco-friendly power plant where less pollution is generated than through
the conventional process. The embodiment burning high quality cleaned powdered coal-char
with water removed also results in a much more efficient generation of electricity
as compared with the conventional process at the coal-fired power plant. In addition,
all the waste sweep gases
144, 160 and
168 that are combined in the process embodying the present invention are sent into the
furnace
64 to burn, wherein the burning of the waste sweep gases efficiently disposes of these
gases and results in less environmental pollution.
[0053] In a preferred embodiment, the process module
30 and
31 discussed above in Figures 2, 3A and 3B is located within or at least adjacent to
the power plant illustrated in Figure 1 so that the high quality cleaned powdered
coal-char
152 which is clean coal with the contaminants of water, mercury and oil removed is ready
for immediate use in the power plant and it is not necessary to transport the high
quality cleaned powdered coal-char from a separate location to the location of the
power plant. This significantly reduces costs of transportation and significantly
improves the efficiency and safety of the entire electricity generating process.
[0054] It will be appreciated that the present invention also includes a second embodiment
32 of the process module
30, which is illustrated in Figures 2 and 4. Referring to Figure 4 there is illustrated
the remaining steps of the second preferred embodiment
32 of the present invention process module
30, which follows first part of the embodiment
30 that extracts water and non-combustible ash. The first part is the same as illustrated
in Figure 3A of the first embodiment
31. Therefore, the first part of the second embodiment
32 will not be repeated and is incorporated herein by reference.
[0055] Referring to Figure 3A, there is illustrated the process to extract the non-combustible
ash and water from the coal. As illustrated in Figure 4, after extracting the water
and non-combustible ash, the mixture
126 of the sweep gas and dried powdered coal
125 containing mercury and oil is heated in a microwave oven
200 at a preferred temperature of approximately 1000 F to thereby produce a mixture
202 of the sweep gas, a mercury vapor, an oil vapor and high quality cleaned powdered
coal-char. It will be appreciated that the microwave energies will quickly heat the
fine dry coal particles sufficiently to vaporize the mercury and oil values associated
with the powdered coal
125. The mixture
202 is separated in a bag house separator
204 to produce high quality cleaned powdered coal-char
206 at a location down stream of the separator
204. In the upper stream of the separator
204, there is produced an additional mixture
208 of oil vapor, mercury vapor and sweep gas. The mixture
208 is first transferred to an oil condenser
210, working at a preferred temperature of approximately 500 F where a liquid oil product
162 is produced and then collected. It will be appreciated that, as illustrated in Figure
4, the produced oil product
162 is collected for shipment for use, or further treated by hydrogenation
170 to form various oil products suitable for refining to transportation fuels, including
gasoline, diesel fuel and JP-8 jet fuel.
[0056] Referring to Figure 4, it illustrates that the oil condensation step further produces
a mixture
212 of the sweep gas and mercury vapor at the upper stream of the oil condenser
210. The mixture
212 is transferred to a mercury condenser
214 working at a preferred temperature of approximately 300 F. Therefore, it produces
a mercury product
146 at a location down stream of the condenser, and a waste sweep gas
216 at the upper stream that is further transferred into the furnace
64 to be safely disposed of by combustion, which is shown in Figure 2.
[0057] In a preferred embodiment, the process module
30 and
32 discussed above in Figures 2, 3A and 4 is located within or at least adjacent to
the power plant illustrated in Figure 1 so that the high quality cleaned powdered
coal-char
206 which is a cleaned coal with the contaminants of water, mercury and oil removed,
is ready for immediate use in the power plant and it is not necessary to transport
the high quality cleaned powdered coal-char from a separate location to the location
of the power plant. Additionally, locating the process module
30 and
32 adjacent to the power plant allows it to make cost-effective use of the coal mill
equipment to powder the coal and to use the furnace exhaust gases associated with
the power plant as a source of hot inert sweep gas. This fit to the power plant significantly
reduces costs of coal beneficiation and significantly improves the efficiency, safety
and economics of the entire electricity generating process.
[0058] It will be appreciated that the above disclosed process module
30 is targeted for extraction of all four valuables: non-combustible ash, water, mercury
and oil that are found in coal. However, if the coal that is being used only contains
some of these elements, then the process modules embodying the present invention are
modified to provide only the steps illustrated to remove the specific one or more
elements found in the particular type of coal being used. For example, if only the
non-combustible ash and water are contained in a particular coal, the process module
only needs to keep steps shown in Figure 3A. In that setting, the produced cleaned
powdered coal
125 can be transferred into the furnace
64 for combustion.
[0059] It will be further appreciated that, a process module embodying the present invention
treats the fine coal particles in a fluidity state when they are mixed by the sweep
gas to thereby achieve a rapid coal treatment process, as compared with the conventional
methods of treating lumps of coal, which requires significantly larger equipment and
extended time to process. Therefore, an embodiment of the present invention provides
significant commercial value by requiring less equipment with short coal treatment
processing times, which is a significant improvement over these problems found in
conventional coal-beneficiation processes.
[0060] Of course the present invention is not intended to be restricted to any particular
form or arrangement, or any specific embodiment, or any specific use, disclosed herein,
since the same may be modified in various particulars or relations without departing
from the spirit or scope of the claimed invention hereinabove shown and described
of which the apparatus or method shown is intended only for illustration and disclosure
of an operative embodiment and not to show all of the various forms or modifications
in which this invention might be embodied or operated.
1. A coal-liquid-extraction process module to recover a non-combustible ash and water
that are found in coal in a powdered form, comprising the steps of:
a. at a location of a power plant having a furnace separating said powdered coal associated
with said non-combustible ash and water further mixed with an inert sweep gas in a
solid-gas separator to obtain at a location down stream of the solid-gas separator
a powdered coal containing a residual water mixed with said non-combustible ash, and
a said inert sweep gas containing a water vapor at an upper stream of the solid-gas
separator, which is transferred to a water condenser;
b. separating said powdered coal containing said residual water that is mixed with
said non-combustible ash in a triboelectric separator to obtain said non-combustible
ash and said powdered coal containing said residual water;
c. drying said powdered coal containing said residual water in a coal dryer to obtain
said residual water at an upper stream of the coal dryer and a dried powdered coal-char
at a location down stream of said coal dryer, which is transferred into burners of
said furnace wherein said coal-char burning generates heat, controllable pollutant
emissions, and a hot inert flue gas in said furnace; and
d. said hot inert flue gas is divided into first and second streams, said first stream
of said hot inert flue gas is transferred to an external sweep gas generator, said
second stream of said hot inert flue gas is transferred to a heat exchanger of said
furnace thereby creating a cold inert flue gas that is further transferred to said
external sweep gas generator, said hot inert flue gas and said cold inert flue gas
are mixed inside of said external sweep gas generator wherein a ratio of mixing said
hot and cold inert flue gases is controlled to generate said inert sweep gases having
a controllable temperature that is applied in said coal-liquid-extraction process
module.
2. The process module in accordance with Claim 1 to recover a non-combustible ash, water
and oil that are found in coal in a powdered form, further comprising the steps of:
a. at a location of a power plant having a furnace, separating said powdered coal
associated with said non-combustible ash, water, and oil further mixed with an inert
sweep gas in a solid-gas separator to obtain at a location down stream of the solid-gas
separator a powdered coal containing a residual water and oil mixed with said non-combustible
ash, and said inert sweep gas containing a water vapor at an upper stream of the solid-gas
separator, wherein said inert sweep gas containing said water vapor is transferred
to a water condenser;
b. separating said powdered coal containing said residual water and oil that is mixed
with said non-combustible ash in a triboelectric separator to obtain said non-combustible
ash and said powdered coal containing said residual water and oil;
c. drying said powdered coal containing said residual water and oil in a coal dryer
to obtain said residual water at an upper stream of the coal dryer and a dried powdered
coal containing said oil at a location down stream of said coal dryer
d. applying microwave energies to heat said dried powdered coal containing said oil
to obtain an oil vapor, and a cleaned dried powdered coal-char which is transferred
into burners of said furnace wherein said coal-char burning generates heat, controllable
pollutant emissions, and a hot inert flue gas in said furnace, and said oil vapor
is further transferred into an oil condenser;
e. condensing said oil vapor to form a liquid oil product at a location down stream
of the oil condenser; and
f. said hot inert flue gas is divided into first and second streams, said first stream
of said hot inert flue gas is transferred to an external sweep gas generator, said
second stream of said hot inert flue gas is transferred to a heat exchanger of said
furnace thereby creating a cold inert flue gas that is further transferred to said
external sweep gas generator, said hot inert flue gas and said cold inert flue gas
are mixed inside of said external sweep gas generator wherein a ratio of mixing said
hot and cold inert flue gases is controlled to generate said inert sweep gases having
a controllable temperature that is applied in said coal-liquid-extraction process
module.
3. The process module in accordance with Claim 1 to recover a non-combustible ash, water
and mercury that are found in coal in a powdered form, further comprising the steps
of:
a. at a location of a power plant having a furnace, separating said powdered coal
associated with said non-combustible ash, water and mercury further mixed with an
inert sweep gas in a first solid-gas separator to obtain at a location down stream
of the first solid-gas separator a powdered coal containing a residual water and mercury
mixed with said non-combustible ash, and said inert sweep gas containing a water vapor
at an upper stream of the first solid-gas separator, wherein said inert sweep gas
containing said water vapor is transferred to a water condenser;
b. separating said powdered coal containing said residual water and mercury that is
mixed with said non-combustible ash in a triboelectric separator to obtain said non-combustible
ash and said powdered coal containing said residual water and mercury;
c. drying said powdered coal containing said residual water and mercury in a coal
dryer to obtain said residual water at an upper stream of the coal dryer and a dried
powdered coal containing said mercury at a location down stream of said coal dryer;
d. applying microwave energies to heat said dried powdered coal containing said mercury
in a microwave oven to form a mixture of a mercury vapor and a cleaned dried powdered
coal-char, wherein said mixture is transferred into a second solid- gas separator;
e. separating said mixture to obtain said mercury vapor at an upper stream of the
second solid-gas separator and said cleaned dried powdered coal-char at a location
down stream of the second solid-gas separator which is transferred into burners of
said furnace wherein said coal-char burning generates heat, controllable pollutant
emissions, and a hot inert flue gas in said furnace, said mercury vapor is transferred
into a mercury condenser where a liquid mercury product is formed and collected; and
f. said hot inert flue gas is divided into first and second streams, said first stream
of said hot inert flue gas is transferred to an external sweep gas generator, said
second stream of said hot inert flue gas is transferred to a heat exchanger of said
furnace thereby creating a cold inert flue gas that is further transferred to said
external sweep gas generator, said hot inert flue gas and said cold inert flue gas
are mixed inside of said external sweep gas generator wherein a ratio of mixing said
hot and cold inert flue gases is controlled to generate said first and second inert
sweep gases being identical and having a controllable temperature that are applied
in said coal-liquid-extraction process module.
4. The process module in accordance with Claim 1 to recover a non-combustible ash, water,
mercury and oil that are found in coal in a powdered form, further comprising the
steps of:
a. at a location of a power plant having a furnace, separating a mixture of an inert
sweep gas containing a water vapor and a powdered coal containing a residual water,
mercury and oil that is mixed with said non-combustible ash in a first solid-gas separator
to obtain at a location down stream of the first solid-gas separator said powdered
coal containing said residual water, oil and mercury that is mixed with said non-combustible
ash, and said inert sweep gas containing said water vapor at an upper stream of the
first solid-gas separator, wherein said inert sweep gas containing said water vapor
is transferred to a water condenser;
b. separating said powdered coal containing said residual water, mercury and oil that
is mixed with said non-combustible ash in a triboelectric separator to obtain said
non-combustible ash and said powdered coal containing said residual water, mercury
and oil;
c. drying said powdered coal containing said residual water, mercury and oil in a
coal dryer to obtain said residual water at an upper stream of the dryer and a dried
powdered coal containing said mercury and oil at a down stream of said dryer;
d. applying microwave energies to heat said dried powdered coal containing said mercury
and oil in a microwave oven to form a mixture of a mercury vapor, an oil vapor, and
a cleaned powdered coal-char, wherein said mixture is transferred into a second solid-gas
separator;
e. separating said mixture to obtain said mercury vapor and said oil vapor at an upper
stream of the second solid-gas separator, and said cleaned powdered coal-char at a
down stream of the second solid-gas separator that is further transferred into burners
of said furnace wherein said coal-char burning generates heat, controllable pollutant
emissions, and a hot inert flue gas in said furnace, said mercury vapor and oil vapor
are transferred into an oil condenser, where a liquid oil product is formed and collected
at a location down stream of the oil condenser, and said mercury vapor is obtained
at an upper stream of the oil condenser which is further transferred to a mercury
condenser;
f. condensing said mercury vapor in said mercury condenser to obtain a liquid mercury
product at a down stream of the mercury condenser; and
g. said hot inert flue gas is divided into first and second streams, said first stream
of said hot inert flue gas is transferred to an external sweep gas generator, said
second stream of said hot inert flue gas is transferred to a heat exchanger of said
furnace thereby creating a cold inert flue gas that is further transferred to said
external sweep gas generator, said hot inert flue gas and said cold inert flue gas
are mixed inside of said external sweep gas generator wherein a ratio of mixing said
hot and cold inert flue gases is controlled to generate said inert sweep gases having
a controllable temperature that is applied in said coal-liquid-extraction process
module.
5. The process module in accordance with Claim 1 to recover a non-combustible ash, water,
mercury and oil found in coal in a powdered form, further comprising the steps of:
a. at a location of a power plant having a furnace, separating said powdered coal
associated with said non-combustible ash, water, mercury and oil further mixed with
an inert sweep gas in a first solid-gas separator to obtain at a location down stream
of the first solid-gas separator a powdered coal containing a residual water, mercury
and oil mixed with said non-combustible ash, and said inert sweep gas containing a
water vapor at an upper stream of the first solid-gas separator which is transferred
to a water condenser;
b. separating said powdered coal containing said residual water, mercury and oil that
is mixed with said non-combustible ash in a triboelectric separator to obtain said
non-combustible ash and said powdered coal containing said residual water, mercury
and oil;
c. drying said powdered coal containing said residual water, mercury and oil in a
coal dryer to obtain said residual water at an upper stream of the coal dryer and
a dried powdered coal containing said oil and mercury at a location down stream of
said coal dryer;
d. applying microwave energies to heat said dried powdered coal containing said oil
and mercury in a first microwave oven to form a first mixture of a mercury vapor,
and a dried powdered coal containing said oil, wherein said first mixture is transferred
into a second solid-gas separator;
e. separating said first mixture to obtain said mercury vapor at an upper stream of
the second solid-gas separator and said dried powdered coal containing said oil at
a location down stream of the second solid-gas separator, said mercury vapor is transferred
into a mercury condenser where a liquid mercury product is formed and collected, and
said dried powdered coal containing said oil is transferred into a second microwave
oven;
f. applying microwave energies to heat said dried powdered coal containing said oil
to obtain a second mixture of an oil vapor and a cleaned powdered coal-char wherein
said second mixture is transferred into a third solid-gas separator, said cleaned
powdered coal-char is obtained at a location down stream of the third solid-gas separator
and which is transferred into burners of said furnace wherein said coal-char burning
generates heat, controllable pollutant emissions, and a hot inert flue gas in said
furnace, and said oil vapor is obtained at an upper stream of the third solid-gas
separator and which is further transferred into an oil condenser;
g. condensing said oil vapor to form a liquid oil product at a location down stream
of the oil condenser; and
h. said hot inert flue gas is divided into first and second streams, said first stream
of said hot inert flue gas is transferred to an external sweep gas generator, said
second stream of said hot inert flue gas is transferred to a heat exchanger of said
furnace thereby creating a cold inert flue gas that is further transferred to said
external sweep gas generator, said hot inert flue gas and said cold inert flue gas
are mixed inside of said external sweep gas generator wherein a ratio of mixing said
hot and cold inert flue gases is controlled to generate said inert sweep gases having
a controllable temperature that is applied in said coal-liquid-extraction process
module.
6. The process module in accordance with Claim 1 for a coal-fired power plant having
furnace, further comprising the steps of:
a. pulverizing raw coal containing at least water and non-combustible ash through
a coal mill with a first inert sweep gas to form a solid-gaseous mixture that includes
a powdered coal containing a residual water that is mixed with said non-combustible
ash and said first inert sweep gas containing a water vapor at a location of said
coal-fired power plant;
b. transferring said solid-gaseous mixture into said process module, where said process
module comprising the steps of:
i. separating said mixture in a solid-gas separator to obtain at a location down stream
of the solid-gas separator said powdered coal containing said residual water mixed
with said non-combustible ash, and said first inert sweep gas containing said water
vapor at an upper stream of the solid-gas separator so that said first inert sweep
gas containing said water vapor is transferred to a water condenser;
ii. separating said powdered coal containing said residual water mixed with said non-combustible
ash in a triboelectric separator to obtain said non-combustible ash and said powdered
coal containing said residual water; and
iii. applying a second inert sweep gas to transfer said powdered coal containing said
residual water into said furnace;
c. burning said powdered coal containing said residual water inside of said furnace
in the presence of a hot combustion air, wherein said powdered coal burning generates
heat, controllable pollutant emissions, and a hot inert flue gas in said furnace,
and said generated heat is used to heat water in a process to produce electricity;
and
d. said hot inert flue gas is divided into first and second streams, said first stream
of said hot inert flue gas is transferred to an external sweep gas generator, said
second stream of said hot inert flue gas is transferred to a heat exchanger of said
furnace thereby creating a cold inert flue gas that is further transferred to said
external sweep gas generator, said hot inert flue gas and said cold inert flue gas
are mixed inside of said external sweep gas generator wherein a ratio of mixing said
hot and cold inert flue gases is controlled to generate said first and second inert
sweep gas being identical and having a controllable temperature that is applied in
said coal-beneficiation process module.
7. The process module in accordance with Claim 6 for a coal-fired power plant having
a furnace, further comprising the steps of:
a. pulverizing raw coal containing water, non-combustible ash, and an oil through
a coal mill with a first inert sweep gas to form a solid-gaseous mixture that includes
a powdered coal containing a residual water and said oil that is mixed with said non-combustible
ash and said first inert sweep gas containing a water vapor at a location of said
coal-fired power plant;
b. transferring said solid-gaseous mixture into said process module, where said process
module comprising the steps of:
i. separating said solid-gaseous mixture in a first solid-gas separator to obtain
at a location down stream of the first solid-gas separator said powdered coal containing
said residual water and oil mixed with said non-combustible ash, and said first inert
sweep gas containing said water vapor at an upper stream of the first solid-gas separator
so that said first inert sweep gas containing said water vapor is transferred to a
water condenser;
ii. separating said powdered coal containing said residual water and oil mixed with
said non-combustible ash in a triboelectric separator to obtain said non-combustible
ash and a said powdered coal containing said residual water and oil;
iii. drying said powdered coal containing said residual water and oil in a coal dryer
to obtain said residual water at an upper stream of the coal dryer and a dried powdered
coal containing said oil at a location down stream of said coal dryer;
iv. applying a second inert sweep gas to transfer said dried powdered coal containing
said oil into a microwave oven which applies microwave energies to heat said dried
powdered coal containing said oil to obtain a mixture of an oil vapor mixed with said
second inert sweep gas and a cleaned dried powdered coal-char, said mixture is transferred
into a second solid-gas separator, wherein said cleaned dried powdered coal-char is
obtained at a location down stream of the oil second solid-gas separator, and said
oil vapor mixed with said second inert sweep gas is obtained at an upper stream of
the second solid-gas separator and is further transferred into an oil condenser;
v. condensing said oil vapor mixed with said second inert sweep gas oil to form a
liquid oil product at a location down stream of the oil condenser; and
vi. applying a third inert sweep gas to transfer said cleaned powdered coal-char into
burners of said furnace;
c. burning said cleaned dried powdered coal-char inside of said furnace in the presence
of a hot combustion air, wherein said coal-char burning generates heat, controllable
pollutant emissions, and a hot inert flue gas in said furnace, and said generated
heat is used to heat water in a process to produce electricity; and
d. said hot inert flue gas is divided into first and second streams, said first stream
of said hot inert flue gas is transferred to an external sweep gas generator, said
second stream of said hot inert flue gas is transferred to a heat exchanger of said
furnace thereby creating a cold inert flue gas that is further transferred to said
external sweep gas generator, said hot inert flue gas and said cold inert flue gas
are mixed inside of said external sweep gas generator wherein a ratio of mixing said
hot and cold inert flue gases is controlled to generate said first, second and third
inert sweep gases having a controllable temperature that are applied in said process
module.
8. The process module in accordance with Claim 7 where said first, second and third inert
sweep gases are identical.
9. The process module in accordance with Claim 6 for a coal-fired power plant having
a furnace, further comprising the steps of:
a. pulverizing raw coal containing water, non-combustible ash and mercury through
a coal mill with a first inert sweep gas to form a solid-gaseous mixture that includes
a powdered coal containing a residual water and mercury that is mixed with said non-combustible
ash and said first inert sweep gas containing water vapor at a location of said coal-fired
power plant;
b. transferring said solid-gaseous mixture into said process module, where said process
module comprising the steps of:
i. separating said solid-gaseous mixture in a first solid-gas separator to obtain
at a location down stream of the first solid-gas separator said powdered coal containing
said residual water and mercury mixed with said non-combustible ash, and said first
inert sweep gas containing said water vapor at an upper stream of the first solid-gas
separator so that said first inert sweep gas containing said water vapor is transferred
to a water condenser;
ii. separating said powdered coal containing said residual water and mercury mixed
with said non-combustible ash in a triboelectric separator to obtain said non-combustible
ash and said powdered coal containing said residual water and mercury;
iii. drying said powdered coal containing said residual water and mercury in a coal
dryer to obtain said residual water at an upper stream of the coal dryer and a dried
powdered coal containing said mercury at a location down stream of said coal dryer;
iv. applying a second inert sweep gas to transfer said dried powdered coal containing
said mercury into a microwave oven which applies microwave energies to heat said dried
powdered coal containing said mercury to form a mixture of a mercury vapor mixed with
said second inert sweep gas and a cleaned dried powdered coal-char so that said mixture
is transferred into a second solid-gas separator; and
v. separating said mixture to obtain said mercury vapor mixed with said second inert
sweep gas at an upper stream of the second solid-gas separator and said cleaned dried
powdered coal-char at a down stream of the second solid-gas separator and said mercury
vapor mixed with said second inert sweep gas is transferred into a mercury condenser
where a liquid mercury product is formed and collected; and
vi applying a third inert sweep gas to transfer said cleaned dried powdered coal-char
into burners of said furnace;
c. burning said cleaned dried powdered coal-char inside of said furnace in the presence
of a hot combustion air, wherein said coal-char burning generates heat, controllable
pollutant emissions, and a hot inert flue gas in said furnace, and said generated
heat is used to heat water in a process to produce and electricity; and
d. said hot inert flue gas is divided into first and second streams, said first stream
of said hot inert flue gas is transferred to an external sweep gas generator, said
second stream of said hot inert flue gas is transferred to a heat exchanger of said
furnace thereby creating a cold inert flue gas that is further transferred to said
external sweep gas generator, said hot inert flue gas and said cold inert flue gas
are mixed inside of said external sweep gas generator wherein a ratio of mixing said
hot and cold inert flue gases is controlled to generate said first, second and third
inert sweep gases having a controllable temperature that are applied in said process
module.
10. The process in accordance with Claim 9 further comprising said first, second and third
inert sweep gases are identical.
11. The process module in accordance with Claim 6 for a coal-fired power plant having
a furnace, further comprising the steps of:
a. pulverizing raw coal containing water, non-combustible ash, mercury and oil through
a coal mill with a first inert sweep gas to form a solid-gaseous mixture that includes
a powdered coal containing a residual water, mercury and oil that is mixed with non-combustible
ash and said first inert sweep gas containing a water vapor at a location of said
coal-fired power plant;
b. transferring said solid-gaseous mixture into said process module, where said process
module comprising the steps of:
i. separating said solid-gaseous mixture in a first solid-gas separator to obtain
at a location down stream of the first solid-gas separator said powdered coal containing
said residual water, mercury and oil mixed with said non-combustible ash, and said
first inert sweep gas containing said water vapor at an upper stream of the first
solid-gas separator so that said first inert sweep gas containing said water vapor
is transferred to a water condenser;
ii. separating said powdered coal containing said residual water, mercury and oil
mixed with said non-combustible ash in a triboelectric separator to obtain said non-combustible
ash and said powdered coal containing said residual water, mercury and oil;
iii. drying said powdered coal containing said residual water, mercury and oil in
a coal dryer to obtain said residual water at an upper stream of the coal dryer and
a dried powdered coal containing said oil and mercury at a location down stream of
said coal dryer;
iv. applying a second inert sweep gas to transfer said dried powdered coal containing
said mercury and oil into a microwave oven which applies microwave energies to heat
said dried powdered coal containing said mercury and oil to form a mixture of a mercury
vapor and oil vapor mixed with said second inert sweep gas, and a cleaned powdered
coal-char so that said mixture is transferred into a second solid-gas separator;
v. separating said mixture to obtain said mercury vapor and said oil vapor mixed with
said second inert sweep gas at an upper stream of the second solid-gas separator,
and said cleaned powdered coal-char at a down stream location of the second solid-gas
separator, said mercury vapor and oil vapor mixed with said second inert sweep are
transferred into an oil condenser, where a liquid oil product is formed and collected
at a location down stream of the oil condenser, and said mercury vapor mixed with
said second inert sweep gas is obtained at an upper stream of the oil condenser, which
is further transferred to a mercury separator;
iv. condensing said mercury vapor mixed with second inert sweep gas in a said mercury
condenser to obtain a liquid mercury product at a location down stream of the mercury
condenser; and
vii. applying a third inert sweep gas to transfer said cleaned powdered coal-char
into burners of said furnace;
c. burning said cleaned powdered coal-char inside of said furnace in the presence
of a hot combustion air, wherein said coal-char burning generates heat, controllable
pollutant emissions, and a hot inert flue gas in said furnace, and said generated
heat is used to heat water in a process to produce electricity; and
d. said hot inert flue gas is divided into first and second streams, said first stream
of said hot inert flue gas is transferred to an external sweep gas generator, said
second stream of said hot inert flue gas is transferred to a heat exchanger of said
furnace thereby creating a cold inert flue gas that is further transferred to said
external sweep gas generator, said hot inert flue gas and said cold inert flue gas
are mixed inside of said external sweep gas generator wherein a ratio of mixing said
hot and cold inert flue gases is controlled to generate said first, second and third
inert sweep gases having a controllable temperature that are applied in said process
module.
12. The process in accordance with Claim 11 further comprising, said first, second and
third sweep gases are identical.
13. The process module in accordance with Claim 6 for a coal-fired power plant having
a furnace, further comprising the steps of:
a. pulverizing raw coal containing water, non-combustible ash, mercury and oil through
a coal mill with a first inert sweep gas to form a solid-gaseous mixture that includes
a powdered coal containing a residual water, said mercury and oil that is mixed with
said non-combustible ash and said first inert sweep gas containing a water vapor at
a location of said coal-fired power plant;
b. transferring said solid-gaseous mixture into said process module, where said process
module comprising the steps of:
i. separating said solid-gaseous mixture in a first solid-gas separator to obtain
at a location down stream of the first solid-gas separator said powdered coal containing
said residual water, mercury and oil mixed with said non-combustible ash, and said
first inert sweep gas containing said water vapor at an upper stream of the first
solid-gas separator which is transferred to a water condenser;
ii. separating said powdered coal containing said residual water, mercury and oil
further mixed with said non-combustible ash in a triboelectric separator to obtain
said non-combustible ash and said powdered coal containing said residual water, mercury
and oil;
iii. drying said powdered coal containing said residual water, mercury and oil in
a coal dryer to obtain said residual water at an upper stream of the coal dryer and
a dried powdered coal containing said mercury and oil at a location down stream of
said coal dryer, where said residual water is transferred to a water condenser;
iv. applying a second inert sweep gas to transfer said dried powdered coal containing
said oil and mercury into a first microwave oven which applies microwave energies
to heat said dried powdered coal containing said mercury and oil to form a first mixture
of a mercury vapor, said second inert sweep gas, and a dried powdered coal containing
said oil so that said first mixture is transferred into a second solid-gas separator;
v. separating said first mixture to obtain said mercury vapor mixed with said second
sweep gas at an upper stream of the second solid-gas separator and said dried powdered
coal containing said oil at a down stream of the second solid-gas separator so that
said mercury vapor mixed with said second sweep gas is transferred into a mercury
condenser where a liquid mercury product is formed and collected, and said dried powdered
coal containing said oil mixed with a third inert sweep gas is transferred into a
second microwave oven;
vi. applying microwave energies to heat said dried powdered coal containing said oil
mixed with said third inert sweep gas to obtain a second mixture of an oil vapor,
said third inert sweep gas and a cleaned powdered coal-char where said second mixture
is transferred into a third solid-gas separator, said cleaned powdered coal-char is
obtained at a location down stream of the third solid-gas separator, and said oil
vapor mixed with said third inert sweep gas is obtained at an upper stream of the
third solid-gas separator and which is further transferred into an oil condenser;
vii. condensing said oil vapor mixed with said third sweep gas oil to form a liquid
oil product at a location down stream of the oil condenser; and
viii. applying a fourth inert sweep gas to transfer said cleaned powdered coal-char
into burners of said furnace;
c. burning said cleaned powdered coal-char inside of said furnace in the presence
of a hot combustion air, wherein said coal-char burning generates heat, controllable
pollutant emission, and a hot inert flue gas in said furnace, and said generated heat
is used to heat water in a process to produce electricity; and
d. said hot inert flue gas is divided into first and second streams, said first stream
of said hot inert flue gas is transferred to an external sweep gas generator, said
second stream of said hot inert flue gas is transferred to a heat exchanger of said
furnace thereby creating a cold inert flue gas that is further transferred to said
external sweep gas generator, said hot inert flue gas and said cold inert flue gas
are mixed inside of said external sweep gas generator wherein a ratio of mixing said
hot and cold inert flue gases is controlled to generate said first, second, third
and fourth inert sweep gases being identical and having a controllable temperature
that are applied in said process module.