An igniting substance mainly for detonators made of a metallic salt of 4,6-diazido-N-nitro-1,3,5-triazine-2-amine selected from a group of salts containing silver salt, copper(I) salt and copper(II) salt, with the following skeletal formula where M is a metal selected from a group comprising silver and copper:
M = Ag, m = 1, n = 1, x = 1 for silver salt,
M = Cu, m = 1, n = 2, x = 2 for copper(I) salt,
M = Cu, m = 2, n = 2, x = 1 for copper(II) salt.

Production method of silver salt of 4,6-diazido-N-nitro-1,3,5,-triazine-2-amine, when the heated aqueous solution of 4,6-diazido-N-nitro-1,3,5-triazine-2-amine is mixed with the aqueous solution of silver nitrate AgNO₃ and, while stirring vigorously, the silver salt of 4,6-diazido-N-nitro-1,3,5-triazine-2-amine is precipitated and then filtered off and dried at laboratory temperature.

Production method of silver salt of 4,6-diazido-N-nitro-1,3,5,-triazine-2-amine, when the heated aqueous solution of 4,6-diazido-N-nitro-1,3,5-triazine-2-amine is mixed with the aqueous solution of silver nitrate AgNO₃ and, while stirring vigorously, the silver salt of 4,6-diazido-N-nitro-1,3,5-triazine-2-amine is precipitated and then filtered off and dried at laboratory temperature.

A non-electric industrial detonator which has a casing in the form of a cup (1) with an inserted detonation tube (19) and a space (11) for the secondary explosive at the bottom of the cup (1) closed with a lid (15), where the space is closed at the top with a time-delay device (12) with a cylindrical case containing delay-action composition (14) and with the primary explosive (13) below it, above the space (11) for the secondary explosive as the igniting substance which is metallic salt of 4,6-diazido-N-nitro-1,3,5-triazine-2-amine selected from a group of salts containing silver salt, copper(I) salt and copper(II) salt.

An electric industrial detonator which has a casing in the form of a cup (2) with an inserted electric fuse head (25) provided with supply cables (26) where in the casing there is space (21) at least for the secondary explosive and for the time-delay device (14) with a cylindrical case containing delay-action composition (14) and with the primary explosive (13) below it, above the space (11) for the secondary explosive where the primary explosive (13) as the igniting substance is metallic salt of 4,6-diazido-N-nitro-1,3,5-triazine-2-amine selected from a group of salts containing silver salt, copper(I) salt and copper(II) salt.