TECHNICAL FIELD
[0001] The present invention relates to a bainitic steel according to the preamble of claim
1. The present invention further relates to a drill rod component according to the
preamble of claim 7. The present invention further relates to method for manufacture
a drill rod component according to the preamble of claim 10. The present invention
also relates to the use of the inventive bainitic steel according to the preamble
of claim 15.
BACKGROUND ART
[0002] Drilling rods for mining and construction work typically comprises a central rod
portion, a threaded male end and a threaded female end. In operation, a drilling head
or drilling bit is screwed onto the male end of the rod and the drilling head is driven
into the rock or ground by a drill rig. One type of drilling is the so called "top
hammer drilling" in which the drilling rig is arranged to provide high rotational
movement and percussion to the drill rod. As the length of the drill hole proceeds,
the drill rod may be extended by screwing further drill rods onto the end of the precedent
one.
[0003] Drill rods may be manufactured by forging and threading the ends of a steel rod into
mating male and female connectors. However, the most common practice today is to manufacture
the male and female connectors separately and then attach the connectors with friction
welding to a respective end of a steel rod.
[0004] One problem related to drill rods is their relative short service life, since the
rate by which the drill rods wear out and have to be replaced, has a direct impact
on the total cost for the drilling operation. A further problem is the strength of
the rod. If a rod breaks, it may take considerable time to retrieve it from the drill
hole.
[0005] In the past some work has been done to improve drill rods. For example,
WO97/27022 is directed to the problem of soft material zones occurring in the interface between
the connector and the central rod after friction welding. When a connector and a central
rod are friction welded together, heat evolves in the interface between connector
and central rod. The heated zone is referred to as "the Heat Affected Zone", (HAZ).
In the HAZ the steel material is annealed and a zone of soft material occurs in the
interface between rod and connector. The soft zone becomes the weakest part of the
drill rod and is typically the position where the drill rod breaks. To solve this
problem,
WO97/27022 proposes a steel in which the chemical composition has been balanced such that the
hardness of the most tempered portion in the HAZ has a hardness equal to the core
hardness of the drilling rod.
[0006] The steel described in
WO97/27002 has lead to improvements in the service life of drill rods, in particular in view
of failure in the interface between connector and central rod. However, the overall
service life of drill rods is still not sufficient.
[0007] Field observation has shown that today failure in drill rods rarely occurs in the
interface between connector and central rod. Instead, the life length of the drill
rods seems to be limited by failure in the threaded portion of the connectors.
[0008] Consequently, it is an object of the present invention to solve at least one of the
above problems. In particular it is an object of the present invention to achieve
an improved steel composition which allows for the manufacturing of drill rods with
long service life. A further object of the present invention is to achieve a cost
effect drill component which can be used over a long period of time. It is also an
object of the present invention to achieve a method for producing wear resistant drill
components. Yet a further object of the present invention relates to the use of the
improved steel composition in rock drilling components.
SUMMARY OF THE INVENTION
[0009] According to the invention at least one of these objects is met by a bainitic steel
comprising (in weight%):
| C: |
0.16 - 0.23 |
| Si: |
0.8 - 1.0 |
| Mo: |
0.67 - 0.9 |
| Cr: |
1.10 - 1.30 |
| V: |
0.18 - 0.4 |
| Ni: |
1.60 - 2.0 |
| Mn: |
0.65 - 0.9 |
| P: |
≤ 0.020 |
| S: |
≤ 0.02 |
| Cu: |
< 0.20 |
| N: |
<0.012 |
balance Fe and unavoidable impurities.
[0010] The inventive steel is primarily intended for producing case hardened components
that are subjected to repeated wear at high temperatures (i.e. 300 - 500°C), for example
case hardened threaded connectors in drill rods. These components have a martensitic
surface zone and a bainitic-martensitic core.
[0011] Results from field test performed during top hammer drilling have shown that case
hardened drill rods manufactured from the inventive steel last surprisingly longer
than drill rods manufactured from conventional steel.
[0012] During top hammer rock- or soil drilling above ground, the drill rod is subjected
to intensive percussion from the drilling rig. The percussion causes a shock wave
which progresses through the interconnected drill rods down to the drill bit in the
bottom of the hole. As the shock wave progresses through the interconnected rods,
approximately 5 % of its energy is lost in the form of heat that mainly evolves in
the threads of the male and female connectors of the interconnected drill rods. Consequently,
the working temperature in the connectors during top hammer drilling is high, typically
up to 300°C but it may reach 500°C. In above-ground top hammer drilling, air is typically
used for cooling the drill rods and also for removing the drill cuttings. However,
air is not an effective cooling fluid and does not cool the rods sufficiently to avoid
that the evolved heat causes the martensitic case in the threads of the connectors
of the drill rods to transform into the softer phase cementite. In conventional drill
rods, the transformation of the martensite may cause the surface of the threads to
soften and eventually cause the connectors to wear out.
[0013] The reason for the surprisingly long service life of the drill rods manufactured
from the inventive steel is not entirely understood. However, without being bound
by theory, it is believed that the balanced amounts of the alloy elements silicon,
molybdenum, chromium and vanadium in the steel causes the martensitic surface of the
drill rod connectors to retain the hardness at the high working temperatures during
top hammer drilling.
[0014] Silicon stabilizes epsilon carbide and retards therefore the transformation of the
hard martensitic surface zone of the connectors into softer cementite up to temperatures
of approximately 300°C. However, as the temperature rises in the connectors during
drilling, the martensitic phase in the surface of the case hardened connectors will
eventually start to transform into cementite. The amount of martensite in the surface
zone of the connectors therefore drops and consequently also the hardness of the surface
zone drops. During the transformation of the martensite into cementite, carbon is
released into the steel.
[0015] In the inventive steel the alloy elements molybdenum, chromium and vanadium forms
hard and stable carbides with the excess carbon resulting from the transformed martensitic
phase. The hard carbides precipitate in the remaining martensitic phase of the connectors
and compensate thereby for the hardness, that is lost by transformation of martensite
into cementite.
[0016] The core of the connectors consists of martensite and bainite. Bainite is a fine
mixture of the phases cementite and ferrite. Bainite is stable at high temperatures
and remains therefore sufficiently strong to support the hardened surface zone of
the connectors at high working temperatures.
[0017] According to an alternative, the amount of Si is 0.85 - 0.95 wt% in the inventive
steel.
[0018] According to an alternative, the amount of Mo is 0.70 - 0.80 wt% in the inventive
steel.
[0019] According to an alternative, the amount of Cr is 1.20 - 1. 25 wt% in the inventive
steel.
[0020] According to an alternative, the amount of V is 0.20 - 0. 30 wt%, preferably 0.2
- 0.25 wt% in the inventive steel.
[0021] According to an alternative, the amount of N is 0.005 - 0.012 wt%, preferably 0.005
- 0.012 wt% in the inventive steel.
[0022] The invention also relates to component for rock drilling comprising the inventive
steel.
[0023] The component may be a threaded male or female connector for a drill rod.
[0024] For example, the component is a drill rod comprising a threaded male and a threaded
female connector.
[0025] The invention also relates to a method for manufacturing a component for rock drilling
comprising the steps of:
- a. forming a component for rock drilling as described above from the inventive steel.
- b. heating said component to austenitizing temperature;
- c. holding said component at austenitizing temperature in a carbon containing atmosphere
for a predetermined time;
- d. cooling said component.
[0026] Preferably, said component is heated to a temperature of 900 -1000°C.
[0027] Preferably, said component is heated in an atmosphere of CO and H
2.
[0028] Preferably, the component is heated for 3-6 hours.
[0029] Preferably, the component is cooled in air.
[0030] The invention also relates to the use of the inventive bainitic steel in case hardened
connectors for drill rods during air cold top hammer drilling above ground.
DETAILED DESCRIPTION OF THE INVENTION
[0031] The inventive steel comprises the following elements in weight% (wt%):
[0032] Carbon (C). Carbon is included in the inventive steel for strength and to govern
the final structure of the steel, which should be bainitic. Carbon is also added to
the inventive steel for ensuring the formation of carbides. The carbides provide a
precipitation hardening effect in the bainitic structure of the steel. The carbides
further prevent the grains in the steel from growing by coalescence, and thereby ensures
fine grains in the steel and consequently high strength. The carbon content should
therefore be at least 0.16 wt% in the steel. Too high carbon content reduces the impact
strength of the steel. Carbon should therefore be limited to 0.23 wt%. Preferably,
carbon is 0.18 - 0.20 wt%.
[0033] Silicon (Si) is used as deoxidizer in the manufacturing of the steel and some amounts
of silicon is therefore always present in the steel. Silicon has a positive effect
on the inventive steel since it increases the hardenablity, i.e. the rate by which
the austenitic phase is transformed into martensite during quenching. In the inventive
steel, silicon is an important alloy element since it retards the transformation of
martensite into cementite.
[0034] Martensite is an unstable phase and when heated it transforms, via various carbides,
into cementite which leads to decreased hardness of the steel. Silicon stabilizes
epsilon carbide, which is one of the carbides that precedes the cementite phase during
the transformation of martensite and thereby retards the transformation of martensite.
Furthermore, during the dissolving of the martensitic phase, carbon must diffuse through
the steel to the carbides in order for the carbides to grow. The presence of silicon
in the steel increases the carbon activity in the steel which in turn retards the
growth of the already formed carbides and also the nucleation of new carbides. Also
this mechanism substantially retards the transformation of the martensite. Silicon
has therefore a positive effect on retaining the strength of the surface zone in case
hardened components of the inventive steel at high temperatures.
[0035] However, silicon stabilizes ferrite and therefore will too high amounts of silicon
lead to an increase of the A1-temperature. This has a negative effect as the steel
during hardening must be heated to higher temperature which causes grain growth in
the austenitic phase and thereby reduces the strength. Consequently, the amount of
silicon is limited to 0.80 - 1.0 wt% in the inventive steel. Preferably, the amount
of silicon is 0.85 - 0.95 wt%.
[0036] Molybdenum, chromium and vanadium are key elements in the inventive steel since they
form hard carbides which compensate for the hardness drop when the martensitic phase
transforms into cementite. The different carbide formers molybdenum, chromium and
vanadium form stable carbides at various temperatures. Hence, at low temperatures
and therefore moderate transformation of the martensite, mainly molybdenum rich carbides
are precipitated. With increasing temperatures the transformation of martensite increases.
However at higher temperatures, chromium rich carbides are first precipitated and
subsequently, at even higher temperatures, also vanadium rich carbides. This provides
the effect that the hardness of the martensite in the surface of the connector is
kept substantially constant over a wide range of working temperatures.
[0037] Molybdenum (Mo), forms stable molybdenum rich carbides at a temperature from 300°C
up to approximately 500°C and compensates for the hardness drop when the martensitic
phase is transformed into cementite. To ensure that a sufficient amount of carbides
is precipitated, the amount of molybdenum shall be at least 0.67 wt%. However, molybdenum
stabilizes austenite and has therefore a very strong influence on hardenability. Too
high amounts of molybdenum could therefore lead to the formation of martensite in
the core of the connector, which make the connector brittle. High amounts of molybdenum
could also cause the formation of secondary hardness maximum. The upper limit for
molybdenum is therefore 0.9 wt% in the inventive steel. Preferably, molybdenum is
0.67 to 0.83 wt% in the steel.
[0038] Chromium (Cr) forms stable chromium rich carbides with carbon. Some chromium rich
carbides are precipitated even at low temperatures, i.e. 300°C. However, the majority
of the chromium rich carbides are precipitated at temperature between 400 - 500°C.
To ensure that a sufficient amount of chromium rich carbides are formed, the inventive
steel should contain at least 1.10 wt% chromium. Very high amounts of chromium could
lead to the formation of a so called secondary hardness maximum in the steel at high
temperatures, typically above 600°C. This phenomenon is generally caused by the formation
of a large amount of chromium carbides, and also of vanadium- and molybdenum carbides.
However, if the temperature of the steel is increased further, the hardness rapidly
drops due to growth of the precipitated carbides which in turn steal carbon from other
precipitations in the steel. Chromium should therefore be limited to 1.30 wt%. Preferably,
the content of chromium is 1.20 - 1.25 in the inventive steel to ensure that sufficient
amount of carbides are formed and that the formation of a secondary hardness maximum
is avoided.
[0039] Vanadium (V) form very small vanadium rich carbides at temperatures of 550 - 600°C
and compensate therefore for the hardness drop when the martensitic phase transforms
into cementite at high temperatures. The inventive steel should contain at least 0.18
wt% vanadium to ensure that a sufficient amount of vanadium carbides is precipitated
in the steel at high working temperatures.
[0040] Vanadium also forms vanadium carbonitrides at high temperatures, i.e. 900°C and above.
The vanadium carbonitrides are important since they prevent grain growth of the austenitic
phase during carburization of the steel. Too high amounts of vanadium could lead to
problems during hot working of the steel since the carbonitrides becomes so stable
that they do not dissolve in the annealing step that precedes hot working. Therefore
vanadium must be limited to 0.40 wt% in the inventive steel. Preferably, vanadium
is 0.20 -0.30 wt%, more preferred 0.20 - 0.25 wt%.
[0041] Manganese (Mn) is included in the inventive steel for forming MnS with sulphur, which
may be present as an impurity in the steel. Manganese has a positive effect on hardenabilty
of the steel, since it lowers the Ms-temperature, i.e. the temperature at which martensite
start to form after austenitizing. The low Ms-temperature also causes a fine bainitic
structure in the core of a connector manufactured from the inventive steel. This is
positive for ensuring a high strength in the core of the connector. Manganese should
be included in an amount of at least 0.65 wt% in order to ensure MnS-types of sulfides.
High amounts of manganese could result in the formation of retained austenite in the
steel, due to that manganese lowers the Ms-temperature. Manganese should therefore
be limited to 0.85 wt%. Preferably the amount of manganese is 0.70 - 0.80 wt% in the
steel since this amount of manganese also ensures a fine bainitic structure in the
inventive steel.
[0042] Phosphorus (P) is present as an impurity in the raw material for the inventive steel.
Phosphorous segregate to the liquid phase during solidification of the steel and causes
phosphorous rich streaks in the solidified steel. A high phosphors content therefore
has a negative impact on the ductility and impact toughness of the steel. Therefore,
phosphor should be limited to a maximum of 0.020 wt%, i.e. 0 - 0.020 wt%, in the inventive
steel.
[0043] Sulphur (S) is also present as an impurity in the raw material for the inventive
steel. Sulphur forms sulphide inclusions in the steel which has a negative impact
on the ductility and impact strength of the steel. Sulphur should therefore be limited
to 0.02wt%, i.e. 0 - 0.020 wt%, in the inventive steel, more preferred to max 0.015
wt%.
[0044] Nickel (Ni) increases the impact strength of the steel and is consequently an important
element in the inventive steel which is intended for drilling rods. Nickel further
reduces the Ms-temperature of the steel and increases thereby the hardenablity. In
order to ensure sufficient impact strength in the steel, the nickel content should
be at least 1.60 wt%. Too high content of nickel could reduce the Ms-temperature too
much and lead to the formation of retained austenite in the steel. Retained austenite
could cause tensile stress in the martensitic phase, and thereby reduce the strength
of the martensite. The nickel content should therefore be limited to 2.0 wt% in the
inventive steel. Nickel is further an expensive alloying element and should for that
reason be present in as low amounts as possible. Preferably, the content of nickel
is 1.70 - 1.90 wt% in the inventive steel since this amount of nickel yields a cost
effective steel with sufficient impact strength.
[0045] Cupper (Cu) is typically included in the scrap metal that is used as raw material.
Cupper may be allowed in amounts up to 0.20 wt%, i.e. 0-0.20 wt%.
[0046] Nitrogen (N). The inventive steel preferably contains nitrogen to ensure that the
stable vanadium carbonitrides are formed during carburization. Preferably, the amount
of nitrogen is 0.005 wt%, more preferred 0.008 wt%. If the steel contains too much
nitrogen, the vanadium carbonitrides will become too stable and may not dissolve during
heat treatment prior to hot working of the steel. Therefore the maximum amount of
nitrogen is 0.012 wt%.
[0047] In hot rolled condition, the inventive steel has a throughout bainitic structure,
i.e. a non-lamellar structure of cementite (Fe
3C) and ferrite (α-iron). By "hot rolled" is meant that the inventive steel has been
produced by casting, thereafter been heated to a temperature of 1200°C and subjected
to hot rolling followed by cooling in air.
[0048] In case hardened condition, the inventive steel has a martensitic surface zone and
a bainitic/martensitic core.
BRIEF DESCRIPTION OF THE DRAWINGS
[0049]
Figure 1: A schematic drawing of a rock drilling component manufactured comprising
the inventive steel.
Figure 2: A graph showing the results from experiments performed on the inventive
steel.
Figure 3: A table showing the results from tests performed on the inventive steel.
DESCRIPTION OF EMBODIMENTS
[0050] Figure 1 shows schematically a longitudinal cross-section of a drilling component
according to a first embodiment of the present invention. The drilling component shown
in figure 1 is a MF-drilling rod 1, which comprises a central rod portion 10. The
first end of the central rod 10 comprises a male connector 20 and the second end of
the central rod comprises a female connector 30. The male connector 20 is provided
with an external thread 21 and the female connector is provided with an internal thread
31. The dimensions of the male and the female connectors and the threads 21, 31 are
dimensioned such that the male connector 20 of a first MF rod can be received in the
female connector 30 of a second MF-rod. The MF-rod further comprises a central channel
60, i.e. a bore that extends through the entire MF-rod. The channel has one opening
61 in the center of the male connector and one opening 61 in the centre of the female
connector. In operation, cooling fluid, such as air is lead through the channel 60.
[0051] In figure 1, the male and the female connectors 20, 30 are attached to the central
rod portion 10 by friction welding which is indicated by the dashed lines 11. However,
the MF-rod in figure 1 could also be manufactured in one piece, i.e the male and the
female connectors 20 and 30 could be formed by forging and threading the ends of the
rod.
[0052] The connectors 20 and 30 are manufactured from the bainitic steel according to the
invention. The central rod 10 may be manufactured from another type of steel, for
example a conventional low-alloyed carbon steel. However, the central rod could also
be manufactures from the bainitic steel according to the invention.
[0053] The connectors 20 and 30 are case hardened and have a bainitic core 40 and a martensitic
surface zone 50. The martensitic surface zone is 1 - 3 mm thick and extends from the
surface of the connector towards its centre.
[0054] Although the inventive drilling component has been described with regards to a MF-rod
it is obvious that it also could be any other type of component that is subjected
to repeated wear under high working temperatures, for example a drifter rod.
[0055] Preferably, the inventive drilling component is manufactured by a method which comprises
the following steps.
[0056] In a first step, a drilling component is formed in a bainitic steel according to
the invention. This is typically achieved by forging and threading a precursor of
the inventive steel into male and female connectors 20, 30. The precursor is typically
a portion of a solid rod that has been manufactured from the inventive steel.
[0057] In a second step, the connectors are subjected to case hardening. This is achieved
in that the connectors are heated in a furnace to austenitizing temperature, which
for the inventive steel is above 900°C. The furnace could be of any type, e.g a pit
furnace. In order to ensure complete austenitizing of the connectors and to avoid
negative effects, such as grain enlargement, the connectors should be heated to temperature
between 900°C and 950°C, preferably 925°C.
[0058] The step of austenitizing of the connectors is performed in a carbon rich atmosphere
to ensure that the content of carbon is increase in the surface zone of the connectors,
so called carburization. Typically the atmosphere in the furnace is a mixture of the
gases H
2 and CO, for example cracked methane.
[0059] The connectors are keep in the furnace for a time period of 3 - 6 hours. The time
governs the case depth, i.e. the thickness of the martensitic surface zone. Preferably
the time period is 5 hours to ensure a sufficient case depth.
[0060] When the heating time has expired, the connectors, which now are austenitized, are
taken out of the furnace and are cooled in the ambient air. Forced air cooling may
be employed by blowing air onto the connectors.
[0061] During cooling the carburized surface of the austenitized connectors transforms into
martensite and the core of the connectors into a mixture of bainite and martensite.
[0062] The connectors may thereafter be subjected to a tempering step to optimized the hardness
of the martenistic surface. Tempering is thereby performed at 200 - 300 °C for 1 hour.
[0063] Finally, the connectors are attached to a central rod portion by friction welding.
EXAMPLES
[0064] The inventive steel material is following described by two non-limitating examples.
Example 1
[0065] Example 1 describes the results from field tests performed with case hardened drill
rods manufactured from the inventive bainitic steel.
[0066] In a first step a heat of the inventive steel was produced. The heat was produced
by melting scrap metal in an electric arc furnace, refining of the molten steel in
a CLU converter and subsequently cast in 24" moulds to ingots.
[0067] The obtained inventive steel had the following composition:
| C |
Si |
Mn |
P |
S |
Cr |
Ni |
Mo |
V |
Cu |
N |
| 0.19 |
0.87 |
0.72 |
0.004 |
0.009 |
1.15 |
1.66 |
0.70 |
0.20 |
0.13 |
0.009 |
[0068] From the inventive steel rods were produced. Some of the rods were forged into threaded
female type connectors and some into threaded male type connectors.
[0069] The male and female type connectors were subjected to case hardening. In a first
step the connectors were carburized in a pit furnace at a temperature of 925 °C for
a time period of 5 hours, the furnace contained an atmosphere of CO and H
2.
[0070] After five hours the connectors were removed from the furnace and allowed to cool
in air. The case hardening resulted in a martensitic layer which extended from the
surface of the connector towards the core which had bainitic/martensitic structure.
[0071] The connectors were thereafter attached to the end of a steel rod which also was
manufactured from the inventive steel material. A male connector was attached to one
end of the rod and a female connector to the other end. The connectors were attached
by friction welding.
[0072] Field testing was thereafter performed with the drilling rods from the inventive
steel at two different locations, Site A and Site B. Drilling was performed with a
drill bit having a diameter of 115 mm and a drilling rig of the type Sandvik DP1500
was used. The drilling speed was approximately 1 meter/minute.
[0073] As comparison were also conventional drill rods used. These rods were made of the
steel grade Sanbar 64.
[0074] Nine rods of each type (inventive and conventional) were used at Site A and 4 rods
of each type at site B. The drill rods were used until failure and the total number
of meters drilled with each rod was recorded as "drilling meter (dm)". Table 1 shows
the result of the testing as the average number of drilling meters drilled per rod
at site A and at site B.
Table 1: Results from drilling
| Site |
Conventional rod |
Inventive rod |
| Site A |
2400 dm (average) |
3200 dm (average) |
| Site B |
2100 dm (average) |
3100 dm (average) |
[0075] As can be seen in table 1, the drilling rods of the inventive steel had a considerable
longer operational life length than the rods of the conventional material.
Example 2
[0076] In a second example, the hardness reduction of test samples from an inventive steel
was determined under laboratory conditions at various reheating temperatures.
[0077] In a first step, a heat of the inventive steel was produced. The heat was produced
by melting scrap metal in an electric arc furnace, refining of the molten steel in
a CLU converter and subsequently casting in 24" moulds to ingots.
[0078] The obtained inventive steel had the following composition:
| C |
Si |
Mn |
P |
S |
Cr |
Ni |
Mo |
V |
Cu |
N |
| 0.20 |
0.89 |
0.79 |
0.011 |
0.013 |
1.27 |
1.75 |
0.77 |
0.21 |
<0.01 |
0.008 |
[0079] The ingots were rolled into bars and the bars were cut into 5 cm long cylinders,
which were used as samples.
[0080] The samples were thereafter subjected to a simulated hardening treatment. This treatment
included heating to austenitizing temperature, holding at austenitizing temperature
for a pre-determined temperature and subsequently cooling in oil which was heated
to room temperature. Thereafter the hardened samples were subjected to reheating in
order to simulate heating during drilling operation. After reheating, the samples
were cooled in air. After cooling of the reheated samples, the hardness was measured
in the surface, on the middle of the radius and in the center of each sample. The
hardness was measured in Vickers (HV1)
[0081] As reference, one sample of each series was left as hardened but in non reheated
condition.
[0082] Twelve samples were used for each austenitizing temperature. The austenitizing temperatures
was :860°C, 1h holding time; 880°C, 1h holding time; 925°C, 20 min holding time. After
quenching in oil, the samples were reheated at the following temperatures: Non Reheated,
200°C, 300°C, 400°C, 500°C, 550°C, 580°C, 600°C, 650°C, 675°C and 700°C.
[0083] The result of the measurement is shown in table 2 and graphically demonstrated in
figure 2. Figure 2 shows a graph in which the result for each austenitizing temperature
is shown as a mean value for the measured hardness at each reheating temperature.
[0084] It should be noted that the experiment is performed on non-carburized samples. However,
from graph in figure 2, it is clear that the hardness of the three different samples
series is almost constant from the non-reheated samples up to 650°C. It is believed
that the constant hardness is due to the stabilizing effect of silicon on the martensitic
phase at low temperatures and by the precipitation of hard and stable carbides of
chromium, molybdenum and vanadium at higher temperatures which compensates for the
transformation of martensite into cementite. At 700°C, a secondary hardness maximum
is formed and thereafter the hardness sharply drops due to that the Cr-, Mo- and V-carbides
coalescence into fewer and coarser precipitations. The growth of the Cr-, Mo- and
V-carbides further causes the remaining martensite to dissolve into cementite and
thereby the hardness decreases even further.
[0085] It is evident that a carburized sample of the inventive steel material, at all reheating
temperatures, would be harder than the non-carburized samples. However, it is believed
that the hardness of a carburized sample would also exhibit an essentially constant
hardness up to approximately 650°C.
1. Bainitic steel comprising, in weight% (wt%):
| C: |
0.16 - 0.23 |
| Si: |
0.8 - 1.0 |
| Mo: |
0.67 - 0.9 |
| Cr: |
1.10 - 1.30 |
| V: |
0.18 - 0.4 |
| Ni: |
1.60 - 2.0 |
| Mn: |
0.65 - 0.9 |
| P: |
≤ 0.020 |
| S: |
≤ 0.02 |
| Cu: |
< 0.20 |
| N: |
<0.012 |
balance Fe and unavoidable impurities.
2. The bainitic steel according to claim 1, wherein the amount of Si is 0.85 - 0.95 wt%.
3. The bainitic steel according to claim 1 or 2, wherein the amount of Mo is 0.70 - 0.80
wt%.
4. The bainitic steel according to any of claims 1 - 3, wherein the amount of Cr is 1.20
- 1.25 wt%.
5. The bainitic steel according to any of claims 1 - 4, wherein the amount of V is 0.20
- 0.30 wt%, preferably 0.2 - 0.25 wt%.
6. The bainitic steel according to any of claims 1 - 5, wherein the amount of N is 0.005
- 0.012 wt%, preferably 0.005 - 0.012 wt%.
7. A component for rock drilling (10, 20, 30) comprising a steel according to any of
claims 1 - 6.
8. The component according to claim 7, wherein the component is a threaded male or female
connector (20, 30) for a drill rod (10).
9. The component according to any of claims 7 or 8, wherein the component is a drill
rod (10) comprising a threaded male and a threaded female connector (20, 30).
10. Method for manufacturing a component for rock drilling (10, 20, 30) comprising the
steps of:
a. forming a component (10, 20, 30) for rock drilling according to any of claims 7
- 9 in a steel according to any of claims 1 - 6;
b. heating said component (10, 20, 30) to austenitizing temperature;
c. holding said component (10, 20, 30) at austenitizing temperature in a carbon containing
atmosphere for a predetermined time;
d. cooling said component.
11. The method according to claim 10, wherein the component is heated to a temperature
of 900 - 1000°C.
12. The method according to claim 10 or 11, wherein the component is heated in an atmosphere
of CO and H2.
13. The method according to any of claims 10 - 12 wherein the component is heated for
3-6 hours.
14. The method according to any of claims 10 - 13, wherein the component is cooled in
air.
15. Use of a bainitic steel according to any of claims 1 - 7 in case hardened connectors
for drill rods during air cold top hammer drilling above ground.