Technical Field
[0001] The present invention relates to high-strength steel sheets, having excellent formability,
applicable to automotive parts and particularly relates to a high-strength steel sheet
having a tensile strength TS of 600 MPa to 700 MPa, an elongation El of 25% or more
(in the case of a JIS #5 test specimen with a thickness of 1.6 mm), and a hole expansion
ratio λ of 80% or more, the hole expansion ratio λ being an indicator for stretch
flangeability, and a method for producing the same.
Background Art
[0002] In recent years, the improvement of automotive fuel efficiency by automotive weight
reduction has become an important issue from the viewpoint of environmental conservation.
Therefore, gauge reduction and weight reduction have been investigated by increasing
the strength of steel sheets which are materials of automotive parts. However, the
increase in strength of steel sheets generally causes the reduction in ductility thereof;
hence, high-strength steel sheets having both high strength and good formability are
strongly needed.
[0003] Hitherto, several proposals have been made for high-strength steel sheets having
excellent formability.
[0004] Patent Literature 1 discloses a high-strength steel sheet, having an excellent strength-hole
expansion ratio balance and excellent shape fixability, for forming. The steel sheet
contains 0.02% to 0.16% C, 0.010% or less P, 0.003% or more S, 0.2% to 4% one or both
of Si and Al in total, and 0.5% to 4% one or more of Mn, Ni, Cr, Mo, and Cu in total
as chemical components on a mass basis, the remainder being Fe and inevitable impurities,
C / (Si + Al + P) being 0.1 or less. The cross-sectional microstructure of the steel
sheet contains one or both of martensite and retained austenite, the sum of the area
fraction of martensite and the area fraction of retained austenite being less than
3%, and one or both of ferrite and bainite, the sum of the area fraction of ferrite
and the area fraction of bainite being 80% or more, the remainder being pearlite.
The maximum length of pearlite, martensite, and retained austenite is 10 microns or
less. The number of inclusions, having a size of 20 microns or more, present in a
cross section of the steel sheet is 0.3 or less per square millimeter.
[0005] Patent Literature 2 discloses a hot-rolled steel containing 0.05% to less than 0.15%
C, 0.8% to 1.2% Mn, 0.02% to 2.0% Si, 0.002% to less than 0.05% sol. Al, and 0.001%%
to less than 0.005% N on a mass basis, the remainder being Fe and impurities. Each
of Ti, Nb, and V in the impurities is less than 0.005%. The hot-rolled steel has a
microstructure containing ferrite with an average grain size of 1.1 µm to 5.0 µm as
a primary phase and one or both of pearlite and cementite as a secondary phase and
satisfies the inequality Mnθ / Monα ≤ 1, where Mnθ is the content of Mn in cementite
in pearlite containing cementite and Mnα is the content of Mn in ferrite.
[0006] Patent Literature 3 discloses a method for producing a hot-rolled steel sheet in
which the structural fraction of cementite with an equivalent circle radius of 0.1
µm or more is 0.1% or less and/or the structural fraction of martensite is 5% or less
and which has a tensile strength of 50 kgf/mm
2 or more, stretch flangeability corresponding to a hole expansion ratio of 1.8 or
more, and excellent ductility. The hot-rolled steel sheet is obtained in such a way
that steel containing 0.07% to 0.18% C, 0.5% to 1.0% Si, 0.7% to 1.5% Mn, 0.02% or
less P, 0.005% or less S, 0.0005% to 0.0050% Ca, and 0.01% to 0.10% Al on a weight
basis, the remainder being Fe and inevitable impurities, is formed into a slab; the
slab is heated to 1,000°C to 1,200°C and is hot-rolled; finish rolling is completed
at a temperature of (Ar
3 transformation temperature + 60)°C to 950°C; cooling is performed at a rate of 50
°C/s or more within 3 seconds from the completion of finish rolling; quenching is
completed within the range of not lower than (T - 70)°C to not higher than a temperature
(T°C) calculated by the equation T = 660 - 450 x [%C] + 40 x [%Si] - 60 × [%Mn] +
470 x [%P]; air-cooling is performed; and coiling is then performed at higher than
350°C to 500°C.
Citation List
Patent Literature
[0007]
PTL 1: Japanese Unexamined Patent Application Publication No. 2004-68095
PTL 2: Japanese Unexamined Patent Application Publication No. 2004-137564
PTL 3: Japanese Unexamined Patent Application Publication No. 4-88125
Summary of Invention
Technical Problem
[0008] However, in the high-strength steel sheet disclosed in Patent Literature 1 and the
hot-rolled steel disclosed in Patent Literature 2, a TS of 600 MPa to 700 MPa is not
achieved. In the high-strength hot-rolled steel sheet, an El of 25% or more is not
achieved when the thickness thereof is 1.6 mm.
[0009] It is an object of the present invention to provide a high-strength steel sheet,
excellent in formability, having a TS of 600 MPa to 700 MPa, an El of 25% or more
(in the case of a JIS #5 test specimen with a thickness of 1.6 mm), and a λ of 80%
or more and a method for producing the same. Solution to Problem
[0010] The inventors have investigated a high-strength steel sheet targeted as described
above and have found that it is effective to form a microstructure which contains
ferrite and pearlite and in which the volume fraction of ferrite is 70% to 97%, the
volume fraction of pearlite is 3% or more, the volume fraction of cementite present
at ferrite grain boundaries is 2% or less, the sum of the volume fractions of the
other phases is less than 3% or less, and the average grain size of ferrite is 7 µm
or less.
[0011] The present invention has been made on the basis of this finding and provides a high-strength
steel sheet having a composition containing 0.10% to 0.18% C, more than 0.5% to 1.5%
Si, 0.5% to 1.5% Mn, 0.05% or less P, 0.005% or less S, and 0.05% or less Al on a
mass basis, the remainder being Fe and inevitable impurities, and also having a microstructure
containing ferrite and pearlite. The volume fraction of the ferrite is 70% to 97%.
The volume fraction of the pearlite is 3% or more. The volume fraction of cementite
present at grain boundaries of the ferrite is 2% or less. The sum of the volume fractions
of phases other than the ferrite, the pearlite, and the cementite is less than 3%.
The average grain size of the ferrite is 7 µm or less.
[0012] The high-strength steel sheet according to the present invention preferably further
contains at least one selected from the group consisting of 0.01% to 1.0% Cr, 0.01%
to 0.1% Ti, and 0.01% to 0.1% V on a mass basis.
[0013] The high-strength steel sheet according to the present invention preferably has a
tensile strength TS of 600 MPa to 700 MPa. The high-strength steel sheet according
to the present invention preferably has a hole expansion ratio λ of 80% or more. In
the high-strength steel sheet according to the present invention, the volume fraction
of the ferrite is preferably 80% to 95%.
[0014] In the high-strength steel sheet according to the present invention, the volume fraction
of the pearlite is preferably 3% to 30%. In the high-strength steel sheet according
to the present invention, the volume fraction of the pearlite is preferably 5% to
28%.
[0015] A method for producing a high-strength steel sheet according to the present invention
includes a step of preparing a steel slab having a chemical composition containing
0.10% to 0.18% C, more than 0.5% to 1.5% Si, 0.5% to 1.5% Mn, 0.05% or less P, 0.005%
or less S, and 0.05% or less Al on a mass basis, the remainder being Fe and inevitable
impurities; a step of hot-rolling the steel slab into a hot-rolled sheet; and a step
of annealing the hot-rolled sheet in such a way that the hot-rolled sheet is heated
to a two-phase temperature range between the Ac
1 transformation temperature and the Ac
3 transformation temperature, is cooled to a temperature range of 450°C to 600°C at
an average cooling rate of 5 °C/s to 30 °C/s, and is then held at this temperature
range for 100 s or more.
[0016] The steel slab preferably further contains at least one selected from the group consisting
of 0.01% to 1.0% Cr, 0.01% to 0.1% Ti, and 0.01% to 0.1% V on a mass basis.
[0017] The annealing step preferably includes heating to the two-phase temperature range
between the Ac
1 transformation temperature and the Ac
3 transformation temperature, cooling to a temperature range of 450°C to 600°C at an
average cooling rate of 10 °C/s to 20 °C/s, and then holding at this temperature range
for 100 s to 300 s.
Advantageous Effects of Invention
[0018] According to the present invention, a high-strength steel sheet, excellent in formability,
having a TS of 600 MPa to 700 MPa, an El of 25% or more, and a λ of 80% or more can
be produced.
Description of Embodiments
[0019] Reasons for limiting a high-strength steel sheet according to the present invention
and a method for producing the same are described below in detail.
(1) Composition
[0020] The unit "%" for the content of an element component hereinafter refers to mass percent.
C: 0.10% to 0.18%
[0021] C forms a secondary phase such as pearlite, microstructure, or cementite to contribute
to increasing the strength of the steel sheet. In order to achieve a TS of 600 MPa
or more, the content of C needs to be 0.10% or more. However, when the C content is
more than 0.18%, the amount of the secondary phase is too large; hence, TS exceeds
700 MPa or El or λ is reduced. Therefore, the C content is 0.10% to 0.18%. The C content
is preferably 0.12% to 0.16%.
Si: more than 0.5% to 1.5%
[0022] Si is an element contributing to solid solution hardening. In order to achieve a
TS of 600 MPa or more, the content of Si needs to be more than 0.5%. However, when
the Si content is more than 1.5%, surface properties of the steel sheet are impaired
by scaling. Therefore, the Si content is more than 0.5% to 1.5%. The Si content is
preferably 0.7% to 1.2%.
Mn: 0.5% to 1.5%
[0023] Mn is an element contributing to solid solution hardening. In order to achieve a
TS of 600 MPa or more, the content of Mn needs to be 0.5% or more. However, when the
Mn content is more than 1.5%, TS exceeds 700 MPa or a reduction in λ is caused by
segregation. Therefore, the Mn content is 0.5% to 1.5%. The Mn content is preferably
1.1% to 1.5%.
P: 0.05% or less
[0024] P is an element contributing to solid solution hardening. However, when the content
of P is more than 0.05%, a reduction in El is caused by segregation. Therefore, the
P content is 0.05% or less. The P content is preferably 0.03% or less.
S: 0.005% or less
[0025] When the content of S is more than 0.005%, S segregates at prior-austenite grain
boundaries or Mn precipitates in the steel sheet to cause a reduction in λ. Therefore,
the S content is 0.005% or less and is preferably low.
Al: 0.05% or less
[0026] Al is added to steel as a deoxidizer and is an element effective in enhancing the
cleanliness of steel. However, when the content of Al is more than 0.05%, a large
number of inclusions are caused, thereby causing surface defects of the steel sheet.
Therefore, the Al content is 0.05% or less. The Al content is preferably 0.03% or
less.
[0027] The remainder is Fe and inevitable impurities. At least one selected from the group
consisting of 0.01% to 1.0% Cr, 0.01% to 0.1% Ti, and 0.01% to 0.1% V may be contained.
This is because Cr, Ti, and V have a function of suppressing the recrystallization
and recovery of austenite in a hot-rolling temperature range, promoting the grain
refining of ferrite, forming a carbide, or strengthening ferrite in a solid solution
state. Incidentally, Nb is an element for achieving a similar effect. The addition
of these elements does not significantly reduce the elongation (El) as compared to
the addition of the same amount of Nb. It is preferred that C is 0.02% to 0.5%, Ti
is 0.02% to 0.05%, and V is 0.02% to 0.05%.
[0028] Incidentally, the inevitable impurities are, for example, O, which is 0.003% or less,
Cu, Ni, Sn, and Sb, which are 0.05% or less.
(2) Microstructure
[0029] In order to increase the strength and formability of the steel sheet, a microstructure
containing ferrite and pearlite is formed.
Volume fraction of ferrite: 70% to 97%
[0030] When the volume fraction of ferrite in the microstructure is less than 70%, TS exceeds
700 MPa or a λ of 80% or more is not achieved. In contrast, when the volume fraction
thereof is more than 97%, a TS of 600 MPa is not achieved because the amount of pearlite
is reduced. Therefore, the volume fraction of ferrite is 70% to 97%.
[0031] The volume fraction of ferrite is preferably 95% or less and more preferably 80%
to 90%.
Volume fraction of pearlite: 3% or more
[0032] When the volume fraction of pearlite is 3% or more, λ is increased. The volume fraction
of pearlite is preferably 5% or more. This is probably because pearlite is soft as
compared to cementite, martensite, and retained austenite and therefore the number
of voids caused at the interface between ferrite and pearlite is small as compared
to the number of voids caused at the interface between ferrite and martensite and
the interface between ferrite and retained austenite after forming.
Volume fraction of cementite present at ferrite grain boundaries: 2% or less
[0033] The steel sheet according to the present invention may possibly contain cementite,
martensite, and the like in addition to ferrite and pearlite. When the volume fraction
of cementite, particularly cementite present at ferrite grain boundaries, in the microstructure
is more than 2%, the number of voids caused at the interface between ferrite and cementite
during hole expansion is increased and therefore a reduction in λ is caused. Thus,
the volume fraction of the cementite present at the ferrite grain boundaries is 2%
or less. Incidentally, the volume fraction thereof may be 0%.
Volume fractions of phases other than ferrite, pearlite, and the cementite present
at ferrite grain boundaries: less than 3% in total
[0034] Phases other than ferrite, pearlite, and the cementite present at the ferrite grain
boundaries are martensite, retained austenite, and the like. When the sum of the volume
fractions of these phases in the microstructure is less than 3%, required properties
of the steel sheet are not significantly affected. Therefore, the sum of the volume
fractions of the phases other than ferrite, pearlite, and the cementite present at
the ferrite grain boundaries is less than 3%. The sum thereof is preferably 2.5% or
less and may be 0%.
Average grain size of ferrite: 7 µm or less
[0035] When the average grain size of ferrite is more than 7 µm, a reduction in strength
is caused and therefore a TS of 600 MPa or more is not achieved. Therefore, the average
grain size of ferrite is 7 µm or less. The average grain size of ferrite is preferably
5 µm or less.
[0036] Herein, the volume fraction of each of ferrite, pearlite, cementite, martensite,
and retained austenite in the microstructure is determined in such a way that a thickness-wise
cross-section of the steel sheet that is parallel to the rolling direction of the
steel sheet is polished and is subsequently corroded with nital, three fields of view
are photographed at 1,000 times magnification using an optical microscope, and the
types of structures are identified by image processing. Furthermore, the average grain
size of ferrite is also calculated by an intercept method. Herein, in the determination
of the average grain size of ferrite, orthogonal line segments are drawn so as to
longitudinally divide an image (corresponding to 84 µm in the rolling direction and
65 µm in the thickness direction) photographed at 1,000 times magnification using
the optical microscope into 20 parts and so as to laterally divide the image into
20 parts, a value obtained by dividing the sum of the lengths of ferrite grains cut
by one of the line segments by the number of the ferrite grains is defined as the
cut length, and the average intercept length L is calculated for each line segment.
The average grain size d is determined by the following equation:

[0037] The volume fraction of the cementite present at the ferrite grain boundaries in the
microstructure is determined in such a way that three fields of view are photographed
at 3,000 times magnification using a scanning electron microscope and the cementite
present at the ferrite grain boundaries is extracted by image processing.
(3) Production method
[0038] Steel slab: A steel slab used is preferably produced by a continuous casting process
for the purpose of preventing the macro-segregation of components of molten steel,
produced by a known process using a converter or the like, having the above composition
and may be produced by a ingot-casting process.
[0039] Hot rolling: The steel slab produced as described above is reheated in a furnace
after being cooled to room temperature or without being cooled to room temperature
or is held at high temperature without being fed through a furnace and is then hot-rolled.
Hot-rolling conditions are not particularly limited. It is preferred that after the
steel slab is heated to a temperature of 1,100°C to 1,300°C, hot rolling (finish rolling)
is completed at 850°C to 950°C and the steel slab is coiled at 720°C or lower. This
is due to reasons below. That is, when the heating temperature is lower than 1,100°C,
the deformation resistance of steel is high and therefore hot rolling may possibly
be difficult. When the heating temperature is higher than 1,300°C, crystal grains
become coarse and therefore TS may possibly be reduced. When the finishing delivery
temperature is lower than 850°C, ferrite is produced during rolling; hence, extended
ferrite is formed and a reduction in λ may possibly be caused. When the finishing
delivery temperature is higher than 950°C, crystal grains become coarse and therefore
TS may possibly be reduced. Furthermore, the coiling temperature is higher than 720°C,
the formation of an internal oxidation layer is significant and therefore chemical
treatability and post-painting corrosion resistance may possibly be deteriorated.
[0040] After hot rolling, a hot-rolled sheet is pickled for the purpose of removing scale
formed on the surface of the steel sheet.
[0041] Annealing: The pickled hot-rolled sheet is annealed in such a way that the hot-rolled
sheet is heated to a two-phase temperature range between the Ac
1 transformation temperature and the Ac
3 transformation temperature, is cooled to a temperature range of 450°C to 600°C at
an average cooling rate of 5 °C/s to 30 °C/s, and is then held at this temperature
range for 100 s or more. The reason for heating the hot-rolled sheet to the two-phase
temperature range between the Ac
1 transformation temperature and the Ac
3 transformation temperature is to form the microstructure containing ferrite and pearlite
is formed. Furthermore, the reason for cooling the hot-rolled sheet to a temperature
range of 450°C to 600°C at an average cooling rate of 5 °C/s to 30 °C/s is as follows:
when the cooling temperature is higher than 600°C, the volume fraction of the cementite
present at the ferrite grain boundaries exceeds 2% and therefore target λ is not achieved;
when the cooling temperature is lower than 450°C, the amount of martensite is increased
and therefore TS exceeds 700 MPa or λ is reduced; when the average cooling rate is
less than 5 °C/s, the ferrite grains become coarse and therefore a TS of 600 MPa is
not achieved; and when the average cooling rate is more than 30 °C/s, the volume fraction
of the cementite present at the ferrite grain boundaries exceeds 2% and therefore
a λ of 80% or more is not achieved. Incidentally, the average cooling rate is preferably
10 °C/s to 20 °C/s. The reason for holding the hot-rolled sheet at a temperature of
450°C to 600°C for 100 s or more is that when the residence time is less than 100
s, the amount of pearlite is reduced and therefore λ is reduced. The residence time
is more preferably 150 s or more. Incidentally, the residence time is preferably 300
s or less from the viewpoint of production efficiency because an effect due to residence
for an excessively long time is saturated. Annealing can be performed using a continuous
annealing line.
EXAMPLES
[0042] Steels having a composition shown in Table 1 were produced and were then formed into
slabs. Each slab was heated to 1,200°C, was hot-rolled at a finishing delivery temperature
of 890°C, and was then coiled at 600°C, whereby a hot-rolled sheet with a thickness
of 1.6 mm was obtained. After being pickled, the hot-rolled sheet was annealed in
a continuous annealing line under annealing conditions shown in Table 2. Incidentally,
the Ac
1 transformation temperature and Ac
3 transformation temperature of each steel shown in Table 1 were calculated by the
following equations:

and

where (%M) represents the mass percent of an element M.
[0043] The steel sheet obtained as described above was investigated for microstructure by
the above-mentioned method and was subjected to a tensile test using a JIS #5 test
specimen in accordance with JIS Z 2241, whereby TS and El were determined. Furthermore,
a hole expansion test was performed using a 100 mm square test specimen in accordance
with The Japan Iron and Steel Federation standard JFST 1001-1996, whereby λ was determined.
[0044] Results are shown in Table 3.
[0045] It is clear that steel sheets of examples of the present invention all have a TS
of 600 MPa to 700 MPa, an El of 25% or more, a λ of 80% or more and are high-strength
steel sheets with excellent formability. However, steel sheets of comparative examples
do not have a target TS or λ.
[Table 1]
(mass percent) |
Steel No. |
C |
Si |
Mn |
P |
S |
Al |
Others |
Ac3 transformation temperature (°C) |
Ac1 transformation temperature (°C) |
Remarks |
A |
0.140 |
1.00 |
1.30 |
0.030 |
0.0020 |
0.035 |
- |
875 |
738 |
Within the scope of the present invention |
B |
0.105 |
1.05 |
1.15 |
0.020 |
0.0015 |
0.040 |
- |
887 |
741 |
Within the scope of the present invention |
C |
0.175 |
0.95 |
0.85 |
0.020 |
0.0035 |
0.030 |
- |
868 |
742 |
Within the scope of the present invention |
D |
0.125 |
0.65 |
1.25 |
0.045 |
0.0010 |
0.025 |
- |
871 |
729 |
Within the scope of the present invention |
E |
0.155 |
1.45 |
0.95 |
0.020 |
0.0025 |
0.035 |
- |
894 |
755 |
Within the scope of the present invention |
F |
0.165 |
0.70 |
0.55 |
0.010 |
0.0008 |
0.040 |
- |
865 |
737 |
Within the scope of the present invention |
G |
0.115 |
1.35 |
1.45 |
0.020 |
0.0040 |
0.035 |
- |
886 |
747 |
Within the scope of the present invention |
H |
0.185 |
1.05 |
0.85 |
0.020 |
0.0035 |
0.030 |
- |
870 |
744 |
Outside the scope of the present invention |
I |
0.085 |
1.05 |
0.85 |
0.020 |
0.0035 |
0.030 |
- |
895 |
744 |
Outside the scope of the present invention |
J |
0.105 |
0.40 |
1.15 |
0.020 |
0.0015 |
0.040 |
- |
860 |
724 |
Outside the scope ot the present invention |
K |
0.105 |
1.05 |
0.40 |
0.020 |
0.0015 |
0.040 |
- |
908 |
749 |
Outside the scope of the present invention |
L |
0.120 |
1.40 |
0.85 |
0.020 |
0.0015 |
0.040 |
Cr:0.04 |
907 |
755 |
Within the scope of the present invention |
M |
0.105 |
0.80 |
1.20 |
0.021 |
0.0016 |
0.041 |
Ti:0.04 |
875 |
733 |
Within the scope of the present invention |
N |
0.110 |
0.90 |
1.30 |
0.021 |
0.0016 |
0.041 |
V:0.03 |
875 |
735 |
Within the scope of the present invention |
[Table 2]
Steel Sheet No. |
Steel No. |
Annealing conditions |
Remarks |
Heating |
Cooling |
Residence time at a temperature range of 450°C to 600°C (s) |
Temperature (°C) |
Average cooling rate (°C/s) |
Cooling attained temperature at average cooling rate (°C) |
1 |
A |
820 |
15 |
500 |
120 |
Inventive example |
2 |
A |
821 |
32 |
498 |
126 |
Comparative example |
3 |
A |
817 |
3 |
498 |
253 |
Comparative example |
4 |
B |
815 |
20 |
480 |
135 |
Inventive example |
5 |
C |
800 |
25 |
490 |
130 |
Inventive example |
6 |
D |
780 |
28 |
460 |
140 |
Inventive example |
7 |
E |
780 |
17 |
460 |
105 |
Inventive example |
8 |
F |
790 |
23 |
490 |
195 |
Inventive example |
9 |
G |
870 |
25 |
570 |
200 |
Inventive example |
10 |
G |
872 |
25 |
320 |
105 |
Comparative example |
11 |
G |
872 |
27 |
570 |
95 |
Comparative example |
12 |
H |
800 |
15 |
520 |
130 |
Comparative example |
13 |
I |
806 |
20 |
521 |
125 |
Comparative example |
14 |
J |
798 |
23 |
525 |
135 |
Comparative example |
15 |
K |
802 |
23 |
525 |
132 |
Comparative example |
16 |
L |
821 |
19 |
495 |
123 |
Inventive example |
17 |
M |
820 |
21 |
496 |
124 |
Inventive example |
18 |
N |
825 |
20 |
495 |
135 |
Inventive example |
[Table 3]
Steel sheet No. |
Steel No. |
Volume fraction of ferrite (%) |
Volume fraction of pearlite (%) |
Volume fraction of cementite at ferrite grain boundaries (%) |
Another phase* and volume fraction (%) |
Average grain size of ferrite (µm) |
TS (MPa) |
EI (%) |
λ (%) |
Remarks |
1 |
A |
86.0 |
11.5 |
0.5 |
M:2.0% |
3.0 |
631 |
27 |
85 |
Inventive example |
2 |
A |
81.6 |
12.2 |
3.2 |
M:3.0% |
3.0 |
635 |
28 |
74 |
Comparative example |
3 |
A |
94.0 |
5.3 |
0.7 |
- |
8.2 |
510 |
34 |
80 |
Comparative example |
4 |
B |
92.0 |
7.8 |
0.2 |
- |
5.0 |
610 |
33 |
98 |
Inventive example |
5 |
C |
72.0 |
27.6 |
0.4 |
- |
4.5 |
620 |
26 |
83 |
Inventive example |
6 |
D |
87.0 |
11.5 |
1.5 |
- |
6.0 |
609 |
32 |
102 |
Inventive example |
7 |
E |
75.0 |
24.8 |
0.2 |
- |
6.5 |
625 |
28 |
80 |
Inventive example |
8 |
F |
87.0 |
11.7 |
1.3 |
- |
2.5 |
612 |
31 |
108 |
Inventive example |
9 |
G |
83.9 |
12.3 |
1.7 |
M:2.1% |
3.5 |
625 |
27 |
87 |
Inventive example |
10 |
G |
80.0 |
12.5 |
1.5 |
M:6.0% |
3.2 |
704 |
26 |
69 |
Comparative example |
11 |
G |
80.0 |
12.1 |
1.4 |
M:6.5% |
3.7 |
695 |
26 |
70 |
Comparative example |
12 |
H |
64.6 |
32.0 |
0.4 |
M:3.0% |
3.5 |
682 |
26 |
72 |
Comparative example |
13 |
I |
97.7 |
2.0 |
0.3 |
- |
4.5 |
575 |
34 |
110 |
Comparative example |
14 |
J |
93.5 |
6.0 |
0.5 |
- |
6.3 |
585 |
30 |
85 |
Comparative example |
15 |
K |
93.0 |
6.0 |
1.0 |
- |
5.1 |
582 |
31 |
95 |
Comparative example |
16 |
L |
85.5 |
14.0 |
0.5 |
- |
2.3 |
623 |
32 |
95 |
Inventive example |
17 |
M |
86.3 |
13.0 |
0.7 |
- |
2.5 |
625 |
31 |
94 |
Inventive example |
18 |
N |
84.5 |
15.0 |
0.5 |
- |
2.5 |
625 |
32 |
96 |
Inventive example |
1. A high-strength steel sheet having a composition containing 0.10% to 0.18% C, more
than 0.5% to 1.5% Si, 0.5% to 1.5% Mn, 0.05% or less P, 0.005% or less S, and 0.05%
or less Al on a mass basis, the remainder being Fe and inevitable impurities, the
high-strength steel sheet having a microstructure containing ferrite and pearlite,
wherein the volume fraction of the ferrite is 70% to 97%, the volume fraction of the
pearlite is 3% or more, the volume fraction of cementite present at grain boundaries
of the ferrite is 2% or less, the sum of the volume fractions of phases other than
the ferrite, the pearlite, and the cementite is less than 3%, and the average grain
size of the ferrite is 7 µm or less.
2. The high-strength steel sheet according to Claim 1, further containing at least one
selected from the group consisting of 0.01% to 1.0% Cr, 0.01% to 0.1% Ti, and 0.01%
to 0.1% V on a mass basis.
3. The high-strength steel sheet according to Claim 1, further having a tensile strength
TS of 600 MPa to 700 MPa.
4. The high-strength steel sheet according to Claim 1, further having a hole expansion
ratio λ of 80% or more.
5. The high-strength steel sheet according to Claim 1, wherein the volume fraction of
the ferrite is 80% to 95%.
6. The high-strength steel sheet according to Claim 1, wherein the volume fraction of
the pearlite is 3% to 30%.
7. The high-strength steel sheet according to Claim 1, wherein the volume fraction of
the pearlite is 5% to 28%.
8. A method for producing a high-strength steel sheet, comprising:
a step of preparing a steel slab having a chemical composition containing 0.10% to
0.18% C, more than 0.5% to 1.5% Si, 0.5% to 1.5% Mn, 0.05% or less P, 0.005% or less
S, and 0.05% or less Al on a mass basis, the remainder being Fe and inevitable impurities;
a step of hot-rolling the steel slab into a hot-rolled sheet; and
a step of annealing the hot-rolled sheet in such a way that the hot-rolled sheet is
heated to a two-phase temperature range between the Ac1 transformation temperature and the Ac3 transformation temperature, is cooled to a temperature range of 450°C to 600°C at
an average cooling rate of 5 °C/s to 30 °C/s, and is then held at this temperature
range for 100 s or more.
9. The method for producing the high-strength steel sheet according to Claim 8, wherein
the steel slab further contains at least one selected from the group consisting of
0.01% to 1.0% Cr, 0.01% to 0.1% Ti, and 0.01% to 0.1% V on a mass basis.
10. The method for producing the high-strength steel sheet according to Claim 8, wherein
the annealing step includes heating to the two-phase temperature range between the
Ac1 transformation temperature and the Ac3 transformation temperature, cooling to a temperature range of 450°C to 600°C at an
average cooling rate of 10 °C/s to 20 °C/s, and then holding at this temperature range
for 100 s to 300 s.