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EP 2 851 640 B1 |
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EUROPEAN PATENT SPECIFICATION |
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Mention of the grant of the patent: |
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27.04.2016 Bulletin 2016/17 |
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Date of filing: 20.09.2013 |
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International Patent Classification (IPC):
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Refractory ceramic lining brick and corresponding refractory ceramic lining
Feuerfester keramischer Verkleidungsziegel und entsprechende feuerfeste keramische
Verkleidung
Brique de garniture en céramique réfractaire et revêtement céramique réfractaire correspondant
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Designated Contracting States: |
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AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL
NO PL PT RO RS SE SI SK SM TR |
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Date of publication of application: |
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25.03.2015 Bulletin 2015/13 |
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Proprietor: Refractory Intellectual Property GmbH & Co. KG |
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1100 Wien (AT) |
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Inventor: |
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- Zivanovic, Bojan
1100 Wien (AT)
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Representative: Becker, Thomas |
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Patentanwälte
Becker & Müller
Turmstrasse 22 40878 Ratingen 40878 Ratingen (DE) |
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References cited: :
AT-B- 286 336 GB-A- 927 813
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FR-A- 1 265 500
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| Note: Within nine months from the publication of the mention of the grant of the European
patent, any person may give notice to the European Patent Office of opposition to
the European patent
granted. Notice of opposition shall be filed in a written reasoned statement. It shall
not be deemed to
have been filed until the opposition fee has been paid. (Art. 99(1) European Patent
Convention).
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[0001] The invention relates to a refractory ceramic lining brick and a corresponding ceramic
refractory lining.
[0002] Many industrial installations, especially industrial furnaces, high temperature treating
vessels, combustion chambers etc. must be lined internally with a corresponding high
temperature resistant material, being in most cases a ceramic refractory material,
either based on basic ceramics like MgO or non-basic materials like Al
2O
3, ZrO
2, TiO
2 etc..
[0003] The most common lining technologies are:
- applying a monolithic ceramic material onto the inner surface of a corresponding outer
envelope (casing) of the apparatus to be protected,
- providing a brickwork instead of or together with said monolithic lining.
[0004] The invention deals with a refractory lining made of a multiplicity of refractory
ceramic lining bricks and at the same time deals with said bricks.
[0005] Although lining technologies as mentioned above have proven successful in most cases
there is a continuous demand for improvements.
[0006] One improvement to be solved is compensation of thermal expansion within the brick
and/or brickwork during high temperature applications.
[0007] It is well known that there is a more or less significant temperature gradient within
a single brick from its inner part (the "hot side", adjacent to the process chamber
of the corresponding apparatus) to the outer part (the "cold side") of the brick,
adjoining the outer casing of the apparatus. These temperature gradients cause uncontrolled
and varying thermal expansions over the brickwork, including the risk of crack formation
and excessive wear of the ceramic lining.
[0008] This is in particular true with linings and bricks used in an apparatus (vessel),
the outer casing of which being cooled (for example water-cooled).
[0009] For example in electric arc furnaces (EAF) the upper part of the furnace is typically
made of water-cooled panels comprising a refractory lining on its inner surface.
[0010] Similar cooling panels or cooling walls are used in combustion chambers, boilers,
etc..
[0011] It is an object of the invention to provide a brick and a corresponding lining respectively
reducing the risk of excessive wear by thermal expansions during high temperature
applications.
[0012] The invention is based on the idea of a "floating" arrangement of the bricks within
the corresponding brickwork. "Floating" means that each brick has a number of degrees
of freedom to move without initiating mechanical stresses within the respective brick
and/or within the brickwork.
[0013] To provide said variances to each brick within the brickwork a lining brick according
to the invention is characterized by at least one hole, able to accommodate a fixation
means (like a rod) which is inserted into said hole.
[0014] Insofar the invention relates - in its most general embodiment as defined by claim
1 - to a refractory ceramic lining brick with, inter alia
- an upper main surface,
- a lower main surface,
- an inner surface ,
- an outer surface,
- two side surfaces,
- all being distinct from each other,
- at least one hole, extending from the upper main surface to the lower main surface
and able to accommodate a fixation rod inserted into said hole.
[0016] In other words: contrary to prior art the said bricks are not mortared to each other
and thus chemically fixed to each other but arranged within a corresponding brickwork
by corresponding rods which penetrate corresponding holes within said bricks.
[0017] If such hole is positioned in a part of the brick adjacent to the casing to be protected
("the cold end") then there might be no or just little thermal expansions around said
hole in the brick. The cross-section of the hole then might be more or less the same
as the cross-section of the corresponding rod or slightly larger.
[0018] Generally spoken it is advantageous to provide the brick with a hole that has a cross-section
being larger than the cross-section of the corresponding rod to provide a (ring shaped)
clearance between said hole and said rod in the mounting state (low temperature application),
wherein said clearance being large enough to compensate any thermal expansion around
said hole/rod to avoid mechanical stresses within the bricks and brickwork.
[0019] To easily assemble brick (hole) and rod one embodiment of the invention provides
a brick with a hole which extends perpendicular to at least one of said upper main
surface or lower main surface respectively.
[0020] This is in particular suitable with bricks wherein the upper main surface and/or
the lower main surface being planar. Other brick designs are characterized by side
surfaces being planar.
[0021] The said hole may be arranged offset between the inner surface (the hot end) and
the outer surface (the cold end); in other words: in close vicinity to the casing
(envelope) of the apparatus concerned.
[0022] In a brickwork with bricks, arranged offset to each other (row by row) the hole should
be arranged offset between the two side surfaces to allow the corresponding rod to
penetrate a multiplicity of holes of bricks arranged one of the top of the other.
[0023] As explained above, the inner brick surface, often being in contact with a hot gas
or a hot melt expands much more under said thermal load than the other (outer) "cold
end". During corresponding research work it was found that the vertical expansion
at the inner end tilts the respective brick. As a consequence the outer surface of
the brick changes its orientation. This leads to the following problem:
In case of a cubic brick with six planar surfaces, wherein the outer surface being
flush with the inner surface of the casing to be protected tilting of the brick will
cause at least the vertically lower end of the outer surface to remove from the said
contact position to a remote position. Consequently, the cooling effect by said cooling
panels mentioned above is characteristicly reduced.
[0024] These disadvantageous are compensated by a brick design wherein the outer surface
and the lower surface of the brick provide an interjacent angle smaller than 90°,
typically ≤ 85°, ≤ 80°, ≤ 75° and often larger than 45°, ≥ 50° or ≥ 55 °.
[0025] This sloped outer surface enables the brick to pivot (under thermal load at its inner
surface) into a position wherein the outer surface now being flush with the inner
wall provided by said casing.
[0026] In other words: During assembly the outer surface of such brick is at least partially
arranged at a certain distance to the corresponding wall section but is tilted under
thermal load in a way to compensate any gap between outer brick surface and casing.
[0027] As further explained hereinafter a gap may be provided in the "cold state" between
the outer surface of the brick(s) and the panel/wall of the apparatus to be lined.
This gap, for example with a V-shape in a vertical cross sectional view, may be filled
with a material able to compensate any variations of the shape of the gap. It may
be a powdery or granular filler material, a viscous material or the like, all of them
able to follow changes of the gap shape and characterized by a certain deformability
under cold and hot environment.
[0028] All brick features mentioned above may be realised independently of the general shape
of the lining brick. Typically the upper main surface of a brick according to the
invention has an overall shape of the group comprising: Square, rectangle, trapezoid,
segment of a circle, T, double T, L.
[0029] The refractory ceramic lining, made of a multiplicity of refractory ceramic lining
bricks of the type mentioned is characterized in its most general embodiment by the
feature of an arrangement of said bricks to a brickwork such that each rod may be
inserted into and through the holes of vertically adjacent lining bricks.
[0030] The said rods may be fixedly secured at their free ends.
[0031] The rods may be fixedly secured to a track or beam at least at one of their free
ends. Again the connection between rods and track (rail) may be such that a relative
movement of the two components is possible to allow compensation of any mechanical
stresses. As an example: rods with a circular cross section may be fitted within oval
openings in the track. A corresponding embodiment is shown in the attached drawing.
[0032] The brickwork may be adjacent to the cooling panel (as described above) with the
proviso that the outer surfaces of the bricks being arranged neighbouring said cooling
panel.
[0033] It follows from the above description of the invention that an advantageous arrangement
of the bricks being to provide the said holes close to the "cold end" in the mounted
state.
[0034] Further features of the invention will become apparent from the sub claims and the
other application documents.
[0035] The invention will now be described with respect to the attached drawing, which schematically
represents one embodiment of the invention, namely in
- Figure 1:
- A three-dimensional view onto a refractory ceramic lining,
- Figure 2:
- A vertical cross-sectional view through part of said lining.
- Figure 3:
- A cross-sectional view of the lower part of the refractory lining
- Figures 4a-c:
- A corresponding lining brick in three different views.
[0036] Figure 1 shows a part of a planar outer metal casing, hereinafter called a cooling
panel as said casing has a (not disclosed) double wall structure with a cooling fluid
like water flowing between the two metal walls.
[0037] Said cooling panel P defines an inner wall surface PI which is directed towards a
treating chamber TC of a corresponding industrial furnace. In view of the high temperatures
(far above 1.000°C) within said treating chamber TC the metallic cooling panel P is
thermally protected by a refractory ceramic lining L, made of a multiplicity of refractory
ceramic lining bricks B, wherein said lining bricks B are arranged to a brickwork
BW, namely one next to the other in horizontal rows, wherein vertically adjacent rows
are offset to each other (Figure 1).
[0038] According to Figure 4, each brick B comprises an upper main surface U, a lower main
surface L, an inner surface I, an outer surface O as well as two side surfaces S1,
S2. All of said brick surfaces extend perpendicular to adjacent surface sections except
outer surface O as said outer surface O and said lower surface L provide an interjacent
angle α of smaller than 90°, namely 87°.
[0039] It derives from this: When assembling brickwork BW the lower end of OL of the each
outer surface O either touches the inner wall surface PI of cooling panel P or being
arranged at least closer to said inner wall surface PI than the upper end OU when
the said brick B is horizontally aligned with respect to the vertically aligned panel
P.
[0040] Each brick B comprises one hole H, extending from the upper main surface U to lower
main surface L. Said hole H is arranged offset between the inner surface I and the
outer surface O (x2 >> x1) and offset between the two side surfaces S1, S2 (x4 > x3).
[0041] This arrangement of hole H allows an overall arrangement of said brickwork BW according
to Figure 1 wherein holes H of bricks B arranged vertically on top of each other are
flush to each other so that a common rod R may be inserted into corresponding holes
H (Figure 1).
[0042] A larger diameter D of hole H compared with diameter d of rod R allows a clearance
C between rod R and hole H and thus a certain maneuverability of each individual brick
B in all three directions of the coordinate system.
[0043] Rods R are running through all bricks B of said brickwork BW from the upper most
row UR to the lower most row LR. While rods R are fixed at the lower end in one of
said bricks B they are fixed at their upper end in a corresponding fin (track T) protruding
from the inner wall PI of the cooling panel P and equipped with long slots LS to give
the rods R the certain maneuverability parallel to cooling panel P.
[0044] Figure 2 shows the arrangement of bricks B after a corresponding assembly.
[0045] Because of the inclination of each outer surface O of each brick B a gap G is provided
between said outer surface O and inner wall PI of cooling panel P which gap G has
a triangular profile in a cross-sectional view according to Figure 2.
[0046] After the corresponding furnace has been set into its operating state each brick
B will be heated up correspondingly with a temperature profile between its inner end
(starting from inner surface I) to its outer end (at outer surface O). This is followed
by a considerable larger thermal expansion at the inner end ("the hot end") facing
treating chamber TC compared with the outer end ("the cold end") facing cooling panel
P and, as a consequence, each brick B tends to tilt according to arrows A shown in
Figure 2. Because of clearance C between rod R and hole H such tilting may be achieved
without any mechanical stresses in the corresponding brick B. The inclined outer surface
O now provides the advantage that, corresponding to the tilting of each brick B, its
surface gets closer to the inner wall PI of cooling panel P and thus the cooling effect
is increased correspondingly. In Figure 2 the lower most brick Bis shown in a position
with its outer surface O being in full contact (flush) with inner panel wall PI. Correspondingly
its upper surface U
x being arranged in a slidely inclined fashion with its right end (around inner surface
I) being higher than its left end (close to outer surface O).
[0047] In Figure 3 a foundation F beneath brickwork BW is schematically represented.
1. Refractory ceramic lining brick (B) with
1.1 an upper main surface (U)
1.2 a lower main surface (L)
1.3 an inner surface (I)
1.4 an outer surface (O)
1.5 two side surfaces (S1,S2)
all being distinct from each other,
1.6 at least one hole (H) extending from the upper main surface (U) to the lower main
surface (L) and able to accommodate a fixation rod (R) inserted into said hole (H),
characterized by
1.7 an interjacent angle (α) between the outer surface (O) and the lower surface (L)
being smaller than 90°
2. Refractory ceramic lining brick (B) according to claim 1, wherein the hole (H) extends
perpendicular to at least one of said upper main surface (U) or lower main surface
(L) respectively.
3. Refractory ceramic lining brick (B) according to claim 1, wherein the hole (H) has
a cross-section being larger than the cross section of the corresponding rod (R) to
provide a clearance (C) between hole (H) and rod (R) in the mounting state, wherein
said clearance (C) being large enough to compensate any maximum thermal expansion
of said lining brick (B) and rod (R) respectively.
4. Refractory ceramic lining brick (B) according to claim 1, wherein at least one of
the upper main surface (U), lower main surface (L) or side surfaces (S1, S2) being
planar.
5. Refractory ceramic lining brick (B) according to claim 1, wherein the hole (H) is
arranged offset between the inner surface (I) and the outer surface (O).
6. Refractory ceramic lining brick (B) according to claim 1, wherein the hole (H) is
arranged offset between the two side surfaces (S1, S2).
7. Refractory ceramic lining brick (B) according to claim 1, wherein the outer surface
(O) and the lower surface (L) provide an interjacent angle (α) smaller than 85°.
8. Refractory ceramic lining brick (B) according to claim 1, wherein the outer surface
(O) and the lower surface (L) provide an interjacent angle (α) larger than 75°.
9. Refractory ceramic lining brick (B) according to claim 1, wherein the upper main surface
(U) has an overall shape of the group comprising: square, rectangle, trapezoid, segment
of a circle, T, double T, L.
10. A refractory ceramic lining (L), made of a multiplicity of refractory ceramic lining
bricks (B) according to any of claims 1 9, wherein said lining bricks (B) are arranged
to a brickwork (BW) such that each rod (R) may be inserted into and through the holes
(H) of vertically adjacent lining bricks (B).
11. The refractory ceramic lining (L) according to claim 10, wherein the rods (R) are
fixedly secured at their free ends.
12. The refractory ceramic lining (L) according to claim 10, wherein the rods (R) are
fixedly secured to a track (T) at least at one of their free ends.
13. The refractory ceramic lining (L) according to claim 12, wherein the rods (R) are
fixed to the track (T) with relative movement to each other.
14. The refractory ceramic lining (L) according to claim 10, wherein the brickwork is
arranged adjacent to a cooling panel (P) with the proviso that the outer surfaces
(O) of said bricks (B) being arranged neighboring said cooling panel (P).
1. Feuerfester keramischer Auskleidungsstein (B) mit
1.1 einer oberen Haupt-Oberfläche (U)
1.2 einer unteren Haupt-Oberfläche (L)
1.3 einer inneren Oberfläche (I)
1.4 einer äußeren Oberfläche (O)
1.5 zwei Seitenflächen (S1, S2) die alle unabhängig voneinander sind,
1.6 mindestens einem Loch (H), das sich von der oberen Haupt-Oberfläche (U) zur unteren
Haupt-Oberfläche (L) erstreckt und geeignet ist, einen Befestigungsstab (R) aufzunehmen,
der in das Loch (H) eingeführt ist,
gekennzeichnet durch
1.7 einen zwischen der äußeren Oberfläche (O) und der unteren Oberfläche (L) gebildeten
Winkel (α) kleiner 90°.
2. Feuerfester keramischer Auskleidungsstein (B) nach Anspruch 1, wobei das Loch (H)
sich senkrecht zu mindestens einer der oberen Haupt-Oberfläche (U) oder der unteren
Hauptoberfläche (L) erstreckt.
3. Feuerfester keramischer Auskleidungsstein (B) nach Anspruch 1, wobei das Loch (H)
einen Querschnitt hat, der größer ist als der Querschnitt des korrespondierenden Stabs
(R) um ein Spiel (C) zwischen dem Loch (H) und dem Stab im Montagezustand zu bilden,
wobei das Spiel (C) groß genug ist, um eine maximale thermische Ausdehnung des Auskleidungssteins
(B) beziehungsweise des Stabs (R) zu kompensieren.
4. Feuerfester keramischer Auskleidungsstein (B) nach Anspruch 1, wobei mindestens eine
der oberen Haupt-Oberfläche (U), unteren Haupt-Oberfläche (L) oder Seitenflächen (S1,
S2) planar ist.
5. Feuerfester keramischer Auskleidungsstein (B) nach Anspruch 1, wobei das Loch (H)
zwischen innerer Oberfläche (I) und der äußeren Oberfläche (O) versetzt angeordnet
ist.
6. Feuerfester keramischer Auskleidungsstein (B) nach Anspruch 1, wobei das Loch (H)
zwischen den beiden Seitenflächen (S1, S2) versetzt angeordnet ist.
7. Feuerfester keramischer Auskleidungsstein (B) nach Anspruch 1, wobei die äußere Oberfläche
(O) und die untere Oberfläche (L) zwischen sich einen Winkel (α) kleiner 85° bilden.
8. Feuerfester keramischer Auskleidungsstein (B) nach Anspruch 1, wobei die äußere Oberfläche
(O) und die untere Oberfläche (L) zwischen sich einen Winkel (α) größer 75° bilden,
9. Feuerfester keramischer Auskleidungsstein (B) nach Anspruch 1, wobei die obere Oberfläche
(U) eine Grundform aufweist aus der Gruppe: Quadrat, Rechteck, Trapez, Kreissegment,
T, doppel T, L.
10. Feuerfeste keramische Auskleidung (L), hergestellt aus einer Vielzahl feuerfester
keramischer Auskleidungssteine (B) nach einem der Ansprüche 1 bis 9, wobei die Auskleidungssteine
(B) zu einem Steinverbund (BW) so angeordnet sind, dass jeder Stab (R) in und durch
die Löcher (H) von vertikal benachbarten Auskleidungssteinen (B) gesteckt werden kann.
11. Feuerfeste keramische Auskleidung (L) nach Anspruch 10, wobei die Stäbe (R) an ihren
freien Enden gesichert sind.
12. Feuerfeste keramische Auskleidung (L) nach Anspruch 10, wobei die Stäbe (R) an einer
Stange (T) an mindestens einem ihrer freien Enden befestigt sind.
13. Feuerfeste keramische Auskleidung (L) nach Anspruch 12, wobei die Stäbe (R) an der
Schiene (T) mit relativer Beweglichkeit zueinander befestigt sind.
14. Feuerfeste keramische Auskleidung nach Anspruch 10, wobei der Steinverbund benachbart
zu einer Kühlwand (P) angeordnet ist, mit der Maßgabe, dass die äußeren Oberflächen
(O) der Steine (B) benachbart der Kühlwand (P) verlaufen.
1. Brique de revêtement en céramique réfractaire (B) avec
1.1 une surface principale supérieure (U)
1.2 une surface principale inférieure (L)
1.3 une surface intérieure (I)
1.4 une surface extérieure (O)
1.5 deux surfaces latérales (S1, S2) toutes distinctes les unes des autres,
1.6 au moins un trou (H) s'étendant de la surface principale supérieure (U) jusqu'à
la surface principale inférieure (L), apte à accueillir une tige de fixation (R) insérée
dans ledit trou (H),
caractérisée en ce que
1.7 un angle intermédiaire (α) entre la surface extérieure (O) et la surface inférieure
(L) étant inférieur à 90°.
2. Brique de revêtement en céramique réfractaire (B) selon la revendication 1, dans laquelle
le trou (H) s'étend perpendiculairement à au moins l'une parmi ladite surface principale
supérieure (U) et ladite surface principale inférieure (L) respectivement.
3. Brique de revêtement en céramique réfractaire (B) selon la revendication 1, dans laquelle
le trou (H) présente une section transversale supérieure à la section transversale
de la tige correspondante (R) afin de prévoir un jeu (C) entre le trou (H) et la tige
(R) à l'état monté, ledit jeu (C) étant suffisamment grand pour compenser toute dilatation
thermique maximale de ladite brique de revêtement (B) et de la tige (R) respectivement.
4. Brique de revêtement en céramique réfractaire (B) selon la revendication 1, dans laquelle
au moins l'une parmi la surface principale supérieure (U), la surface principale inférieure
(L) et les surfaces latérales (S1, S2) est planaire.
5. Brique de revêtement en céramique réfractaire (B) selon la revendication 1, dans laquelle
le trou (H) est disposé de façon décalée entre la surface intérieure (I) et la surface
extérieure (0).
6. Brique de revêtement en céramique réfractaire (B) selon la revendication 1, dans laquelle
le trou (H) est disposé de façon décalée entre les deux surfaces latérales (S1, S2).
7. Brique de revêtement en céramique réfractaire (B) selon la revendication 1, dans laquelle
la surface extérieure (O) et la surface inférieure (L) forment un angle intermédiaire
(α) inférieur à 85°.
8. Brique de revêtement en céramique réfractaire (B) selon la revendication 1, dans laquelle
la surface extérieure (O) et la surface inférieure (L) forment un angle intermédiaire
(α) supérieur à 75°.
9. Brique de revêtement en céramique réfractaire (B) selon la revendication 1, dans laquelle
la surface principale supérieure (U) présente une forme globale du groupe comprenant
: carrée, rectangulaire, trapézoïdale, en segment de cercle, en T, en double T, en
L.
10. Revêtement en céramique réfractaire (L) constitué d'une multitude de briques de revêtement
en céramique réfractaire (B) selon l'une quelconque des revendications 1 à 9, dans
lequel lesdites briques de revêtement (B) sont assemblées en un briquetage (BW), de
telle façon que chaque tige (R) peut être insérée dans et à travers les trous (H)
de briques de revêtement (B) verticalement adjacentes.
11. Revêtement en céramique réfractaire (L) selon la revendication 10, dans lequel les
tiges (R) sont fixées par leurs extrémités libres.
12. Revêtement en céramique réfractaire (L) selon la revendication 10, dans lequel les
tiges (R) sont fixées à une piste (T) par au moins l'une de leurs extrémités libres.
13. Revêtement en céramique réfractaire (L) selon la revendication 12, dans lequel les
tiges (R) sont fixées à la piste (T) avec un mouvement relatif de l'une par rapport
à l'autre.
14. Revêtement en céramique réfractaire (L) selon la revendication 10, dans lequel le
briquetage est agencé à côté d'un panneau de refroidissement (P), à condition que
les surfaces extérieures (O) desdites briques (B) soient agencées à côté dudit panneau
de refroidissement (P).
REFERENCES CITED IN THE DESCRIPTION
This list of references cited by the applicant is for the reader's convenience only.
It does not form part of the European patent document. Even though great care has
been taken in compiling the references, errors or omissions cannot be excluded and
the EPO disclaims all liability in this regard.
Patent documents cited in the description