Improved polyester-ether resin blends

Abstract

 The application relates to compositions for preparing an article, preform or container comprising a base polyester, a copolyester-ether, a transition metal-based oxidation catalyst, and a monomeric, oligomeric or polymeric hindered amine light stabilizer of formula (I),

wherein each R1 independently represents C1-C4 alkyl, R2 represents H, C1-C4 alkyl, OH, O-C1-C4 alkyl, or a further part of an oligomeric or polymeric HALS, and R3 represents a further part of a monomeric, oligomeric or polymeric HALS.

Description

FIELD OF THE INVENTION

[0001] The present invention relates to novel stabilized polyester-ether compositions and their use in polyester resins. Articles, preforms and containers comprising these stabilized polyester-ethers show reduced side-products and excellent oxygen barrier properties.

BACKGROUND OF THE INVENTION

[0002] Polyesters have been replacing glass and metal packaging materials due to their lighter weight, decreased breakage compared to glass, and potentially lower cost. One major deficiency with standard polyesters, however, is its relatively high gas permeability. This curtails the shelf life of carbonated soft drinks and oxygen sensitive beverages or foodstuffs such as beer, wine, tea, fruit juice, ketchup, cheese and the like. Organic oxygen scavenging materials have been developed partly in response to the food industry's goal of having longer shelf-life for packaged food. These oxygen scavenging materials are incorporated into at least a portion of the package and remove oxygen from the enclosed package volume which surrounds the product or which may leak into the package, thereby inhibiting spoilage and prolonging freshness.

[0003] Suitable oxygen scavenging materials include oxidizable organic polymers which may react with ingressing oxygen. One example of an oxidizable organic polymer is a polyether. The polyether is typically used as a polyester-ether copolymer and in low amounts of less than 10 weight percent of the packaging material. The polyester-ether is dispersed in the matrix polyester phase and interacts with a suitable oxygen scavenging catalyst that catalyzes the reaction of the ingressing oxygen with the polyether. Oxygen scavenging catalysts are typically transition metal compounds, for example an organic or inorganic salt of cobalt. Polyester containers comprising polyester-ethers and an oxygen scavenging catalyst show excellent oxygen barrier properties. However, polyethers are also lacking in stability. During preparation and processing the polyether-containing material into articles and containers, undesirable degradation products such as acetaldehyde, tetrahydrofuran, and other C₂- to C₄-molecules may be produced in various amounts. These side products can inter alia cause undesirable off-tastes in the product. The problem is aggravated by the presence of the transition metal oxygen scavenging catalyst. The oxygen scavenging catalyst may also catalyze polyether degradation reactions.

[0004] The amount of degradation products may in turn be reduced by adding stabilizers to the resin blend. It is commonly believed that these stabilizers reduce the amount of degradation products by scavenging radicals generated during production of the resins and their processing to the final articles. However, the use of such stabilizers is considered to be problematic in its own way: Stabilizers are considered to attenuate all radical reactions. Since the oxygen scavenging reaction also involves a transition metal-catalyzed radical mechanism, the presence of such stabilizers is considered to also negatively affect the oxygen barrier properties. In other words, the use of stabilizers reduces side-products in the packaging material but also deteriorates the oxygen barrier properties. Therefore, the use of stabilizers is limited in practical application.

[0005] There is a need in the art to provide polyether-containing resins which have reduced amounts of degradation products such as acetaldehyde, tetrahydrofuran, and other C₂- to C₄-molecules but still provided excellent oxygen-scavenging properties.

SUMMARY OF THE INVENTION

[0006] It was now surprisingly found that certain hindered amine light stabilizers (HALS) are, on the one hand, particularly efficient in reducing the above-mentioned degradation products in polyester-ether-compositions and, on the other hand, do not excessively reduce oxygen barrier properties.

[0007] Accordingly, in one aspect, there is provided a composition for preparing an article, preform or container s comprising:

a) 80-98.5 parts by weight of a base polyester;

b) 0.5-20 parts by weight of a copolyester-ether,

b1) wherein the copolyester-ether comprises one or more polyester segments and one or more polyether segments,

b2) wherein the one or more polyether segments are present in an amount of about 5 to about 95 wt.-% of the copolyester-ether,

b3) wherein the weight ratio of the one or more polyether segments to the total amount of base polyester and polyester segments in the composition is 0.2-10 wt.-%;

c) a transition metal-based oxidation catalyst; and

d) a monomeric, oligomeric or polymeric hindered amine light stabilizer (HALS) in an amount of 15 - 10,000 ppm, on basis of the weight of the stabilizer in the total composition, wherein the HALS is represented by the formula (I) or a mixture of compounds of formula (I),

wherein each R₁ independently represents C₁-C₄ alkyl, R₂ represents H, C₁-C₄ alkyl, OH, O-C₁-C₄ alkyl, or a further part of an oligomeric or polymeric HALS, and R₃ represents a further part of a monomeric, oligomeric or polymeric HALS.

[0008] There are also provided articles, preforms and containers comprising or prepared from such a composition.

[0009] In another aspect, there is provided a masterbatch for use in preparing an article, preform or container comprising:

a) copolyester-ether, wherein the copolyester-ether comprises one or more polyester segments and one or more polyether segments, wherein the one or more polyether segments are present in an amount of about 5 to about 95 wt.-% of the copolyester-ether; and

b) a monomeric, oligomeric or polymeric hindered amine light stabilizer (HALS) in an amount of 100 - 30,000 ppm, on basis of the weight of the stabilizer in the total composition, wherein the HALS is represented by the formula (I) or a mixture of compounds of formula (I),

wherein each R₁ independently from each represents C₁-C₄ alkyl, R₂ represents H, C₁-C₄ alkyl, OH, O-C₁-C₄ alkyl, or a further part of an oligomeric or polymeric HALS, and R₃ represents a further part of a monomeric, oligomeric or polymeric HALS.

[0010] In another aspect, there is provided a method of preparing a masterbatch for use in preparing an article, preform or container comprising mixing a copolyester-ether, wherein the copolyester-ether comprises one or more polyester segments and one or more polyether segments, wherein the one or more polyether segments are present in an amount of about 5 to about 95 wt.-% of the copolyester-ether; with a monomeric, oligomeric or polymeric hindered amine light stabilizer (HALS) in an amount of 100 - 30,000 ppm, on basis of the weight of the stabilizer in the total composition, wherein the HALS is represented by the formula (I) or a mixture of compounds of formula (I),

wherein each R₁ independently represents C₁-C₄ alkyl, R₂ represents H, C₁-C₄ alkyl, OH, O-C₁-C₄ alkyl, or a further part of an oligomeric or polymeric HALS, and R₃ represents a further part of a monomeric, oligomeric or polymeric HALS.

[0011] In another aspect, there is provided a method of preparing a composition for use in preparing an article, preform or container comprising mixing 80-98.5 parts by weight of a base polyester with:

a) 0.5-20 parts by weight of a copolyester-ether, wherein the copolyester-ether comprises one or more polyester segments and one or more polyether segments, wherein the one or more polyether segments are present in an amount of about 5 to about 95 wt.-% of a copolyester-ether,

b) a transition metal-based oxidation catalyst; and

c) a monomeric, oligomeric or polymeric hindered amine light stabilizer (HALS) in an amount of 15 - 10,000 ppm, on basis of the weight of the stabilizer in the total composition, wherein the HALS is represented by the formula (I) or a mixture of compounds of formula (I),

wherein each R₁ independently represents C₁-C₄ alkyl, R₂ represents H, C₁-C₄ alkyl, OH, O-C₁-C₄ alkyl, or a further part of an oligomeric or polymeric HALS, and R₃ represents a further part of a monomeric, oligomeric or polymeric HALS.

[0012] In another aspect, there is provided the use of a monomeric, oligomeric or polymeric hindered amine light stabilizer (HALS), wherein the HALS is represented by the formula (I) or a mixture of compounds of formula (I),

wherein each R₁ independently represents C₁-C₄ alkyl, R₂ represents H, C₁-C₄ alkyl, OH, O-C₁-C₄ alkyl, or a further part of an oligomeric or polymeric HALS, and R₃ represents a further part of a monomeric, oligomeric or polymeric HALS; for reducing the amount of decomposition products in an article, preform or container comprising: 80-98.5 parts by weight of a base polyester; 0.5-20 parts by weight of a copolyester-ether, wherein the copolyester-ether comprises one or more polyester segments and one or more polyether segments, and wherein the one or more polyether segments are present in an amount of about 5 to about 95 wt.-% of the copolyester-ether, and a transition metal-based oxidation catalyst.

DETAILED DESCRIPTION OF THE INVENTION

[0013] The following detailed description of components is applicable to all of the above-mentioned aspects of the present invention. In addition, individual elements of the detailed description are intended to be freely combinable with the above various aspects of the invention.

[0014] Generally, polyesters suitable for the present invention can be prepared by one of two processes, namely: (1) the ester process and (2) the acid process. The ester process is where a dicarboxylic ester (such as dimethyl terephthalate) is reacted with ethylene glycol or other diol in an ester interchange reaction. Catalysts for use in the ester interchange reaction are well known and may be selected from manganese, zinc, cobalt, titanium, calcium, magnesium or lithium compounds. Because the reaction is reversible, it is generally necessary to remove the alcohol (e.g. methanol when dimethyl terephthalate is employed) to completely convert the raw materials into monomers. The catalytic activity of the interchange reaction catalyst may optionally be sequestered by introducing a phosphorus compound, for example polyphosphoric acid, at the end of the ester interchange reaction. Then the monomer undergoes polycondensation. The catalyst employed in this reaction is typically an antimony, germanium, aluminum, zinc, tin or titanium compound, or a mixture of these. In some embodiments, it may be advantageous to use a titanium compound. In the second method for making polyester, an acid (such as terephthalic acid) is reacted with a diol (such as ethylene glycol) by a direct esterification reaction producing monomer and water. This reaction is also reversible like the ester process and thus to drive the reaction to completion one must remove the water. The direct esterification step does not require a catalyst. The monomer then undergoes polycondensation to form polyester just as in the ester process, and the catalyst and conditions employed are generally the same as those for the ester process. In summary, in the ester process there are two steps, namely: (1) an ester interchange, and (2) polycondensation. In the acid process there are also two steps, namely: (1) direct esterification, and (2) polycondensation.

[0015] Suitable polyesters can be aromatic or aliphatic polyesters, and are preferably selected from aromatic polyesters. An aromatic polyester is preferably derived from one or more diol(s) and one or more aromatic dicarboxylic acid(s). The aromatic dicarboxylic acid includes, for example, terephthalic acid, isophthalic acid, 1,4-, 2,5-, 2,6- or 2,7-naphthalenedicarboxylic acid and 4,4'-diphenyldicarboxylic acid (and of these terephthalic acid is preferred). The diol is preferably selected from aliphatic and cycloaliphatic diol(s), including, for example, ethylene glycol, 1,4-butanediol, 1,4-cyclohexane dimethanol, and 1,6-hexanediol (and of these, aliphatic diols, and preferably ethylene glycol, is preferred). Preferred polyesters are polyethylene terephthalate (PET) and polyethylene-2,6-naphthalene dicarboxylate (also referred to herein as polyethylene-2,6-naphthalate), and particularly preferred is PET.

[0016] Thus, suitable polyesters include those produced from the reaction of a diacid or diester component comprising at least 65 mol.-% aromatic diacid (preferably terephthalic acid) or the C₁-C₄ dialkyl ester of the aromatic acid (preferably C₁-C₄ dialkylterephthalate), for example at least 70 mol.-% or at least 75 mol.-% or at least 95 mol.-%, with a diol component comprising at least 65 mol.-% diol (preferably ethylene glycol), for example at least 70 mol.-% or at least 75 mol.-% or at least 95 mol.%. Exemplary polyesters include those wherein the diacid component is terephthalic acid and the diol component is ethylene glycol, thereby forming polyethylene terephthalate (PET). The mole percent for all the diacid components totals 100 mol.-%, and the mole percentage for all the diol components totals 100 mol.-%.

[0017] The polyester may be modified by one or more diol components other than ethylene glycol. In this case, the polyester is a copolyester. Suitable diol components of the described polyester may be selected from 1,4-cyclohexane-dimethanol, 1,2-propanediol, 1,4-butanediol, 2,2-dimethyl-1, 3-propanediol, 2-methyl-1,3-propanediol (2MPDO) 1,6-hexanediol, 1,2-cyclo-hexanediol, 1,4-cyclohexanediol, 1,2-cyclohexanedimethanol, 1,3-cyclohexanedimethanol, and diols containing one or more oxygen atoms in the chain, e.g., diethylene glycol, triethylene glycol, dipropylene glycol, tripropylene glycol or mixtures of these, and the like. In general, these diols contain 2 to 18, preferably 2 to 8 carbon atoms. Cycloaliphatic diols can be employed in their cis- or trans-configuration or as mixture of both forms. Suitable modifying diol components can be 1,4-cyclohexanedimethanol or diethylene glycol, or a mixture of these.

[0018] The polyester may be modified by one or more acid components other than terephthalic acid. In this case, the polyester is a copolyester. Suitable acid components (aliphatic, alicyclic, or aromatic dicarboxylic acids) of the linear polyester may be selected, for example, from isophthalic acid, 1,4- cyclohexanedicarboxylic acid, 1,3-cyclohexanedicarboxylic acid, succinic acid, glutaric acid, adipic acid, sebacic acid, 1,12-dodecanedioic acid, 2,6-naphthalene-dicarboxylic acid, bibenzoic acid, or mixtures of these and the like. In the polymer preparation, it is possible to use a functional acid derivative of the above acid components. Typical functional acid derivatives include the dimethyl, diethyl, or dipropyl ester of the dicarboxylic acid or its anhydride.

[0019] Advantageously, the polyester is a copolyester of ethylene glycol with a combination of terephthalic acid and isophthalic acid and/or 5-sulfoisophthalic acid. Generally, the isophthalic acid can be present from about 0.05 mol.-% to about 10 mol.% and the 5-sulfoisophthalic acid from can be present from about 0.1 mol.% to about 3 mol.-% of the copolymer.

[0020] Advantageously, the polyester is selected from polyethylene terephthalate, polyethylene naphthalate, polyethylene isophthalate, copolymers of polyethylene terephthalate, copolymers of polyethylene naphthalate, copolymers of polyethylene isophthalate, or mixtures thereof; for example the polyester can be a copolymer of polyethylene terephthalate, such as poly(ethylene terephthalate-co-ethylene isophthalate) or poly(ethylene terephthalate-co-ethylene 5-sulfoisophthalate).

[0021] The composition for preparing an article, preform or container comprises 80 - 98.5 parts by weight of a base polyester, including 85 - 98.5, 90 - 98.5, or 95 - 98.5 parts by weight of the base polyester. Preferably, the composition comprises 90 - 98.5 parts by weight of the base polyester.

[0022] Copolyester-ethers suitable for the present invention comprise one or more polyester segments and one or more polyether segments having a number-average molecular weight of from about 200 to about 5000 g/mol. Advantageously, the copolyester-ether has a number-average molecular weight of from about 600 to about 2500 g/mol, more specifically about 800 to about 1800 g/mol or about 1000 to about 1600 g/mol. The Copolyester-ethers are present in the composition in an amount from 0.5 - 20 parts by weight, including 0.5 - 15 parts by weight, 0.5 - 10 parts by weight, and 0.5 - 5 parts by weight. Preferably, the composition comprises 0.5 - 10 parts by weight of the copolyester-ethers.

[0023] The one or more polyether segments may advantageously be present in an amount of about 5 to about 60 wt.% of the copolyester-ether. Advantageously, he polyether segments are present in an amount of about 10 to about 45 wt.-%, more specifically about 20 to about 40 wt.-%, or in particular about 25 to about 35 wt.-% or about 25 to about 30 wt.-%, in all cases based on the copolyester-ether.

[0024] Generally, copolyester-ethers suitable for the present invention comprise one or more polyether segments in amounts so that the weight ratio of the one or more polyether segments to the total amount of base polyester and polyester segments in the composition is about 0.2 to about 15 wt.%, more specifically about 0.5 to about 10 wt.-%, or in particular about 0.7 to about 5 wt.-%, or about 0.5 to about 1.5 wt.%, or about 1 to about 2.5 wt.-%.

[0025] Advantageously, the polyether segment is a poly (C₂-C₆-alkylene glycol) segment. The C₂-C₆-alkylene glycol may be a linear or branched aliphatic C₂-C₆-moiety. Specific examples of such copolyester-ethers include poly(ethylene glycol), linear or branched poly(propylene glycol), linear or branched poly(butylene glycol), linear or branched poly(pentylene glycol), linear or branched poly(hexylene glycol) as well as mixed poly (C₂-C₆-alkylene glycols) obtained from two or more of the glycolic monomers used in preparing the before-mentioned examples. Advantageously, the polyether segment is a linear or branched poly(propylene glycol) or a linear or branched poly(butylene glycol).

[0026] The copolyester-ethers suitable for the present invention also comprise one or more polyester segments. The type of polyester in these segments is not particularly limited and can be any of the above-referenced polyesters. Advantageously, the copolyester-ether comprises a polyethylene terephthalate (co)polymer segment. Advantageously, the copolyester-ether comprises a polyethylene terephthalate (co)polymer segment and a linear or branched poly(butylene glycol) segment.

[0027] The composition for preparing an article, preform or container comprises 0.5 - 20 parts by weight of a copolyester-ether, including 0.5 - 15, 0.5 - 10, and 0.5 - 5 parts by weight of the copolyester-ether. Preferably, the composition comprises 0.5 - 10 parts by weight of the copolyester-ether.

[0028] Methods of preparing polyethers and copolyester-ethers are well known in the art. For example, the copolyester-ether can be produced by ester interchange with the dialkyl ester of a dicarboxylic acid. In the ester interchange process dialkyl esters of dicarboxylic acids undergo transesterification with one or more glycols in the presence of a catalyst such as zinc acetate as described in WO 2010/096459 A2, incorporated herein by reference. A suitable amount of elemental zinc in the copolyester-ether can be about 35 to about 100 ppm, for example about 40 to about 80 ppm, by weight of the copolyester-ether. The poly(alkylene oxide) glycols replace part of these glycols in these transesterification processes. The poly(alkylene oxide) glycols can be added with the starting raw materials or added after transesterification. In either case, the monomer and oligomer mixture can be produced continuously in a series of one or more reactors operating at elevated temperature and pressures at one atmosphere or lesser. Alternatively, the monomer and oligomer mixture can be produced in one or more batch reactors. Suitable conditions for these reactions are temperatures of from about 180°C to 250°C and pressures of from about 1 bar to 4 bar.

[0029] Next, the mixture of copolyester-ether monomer and oligomers undergoes melt-phase polycondensation to produce a polymer. The polymer is produced in a series of one or more reactors operating at elevated temperatures. To facilitate removal of excess glycols, water, and other reaction products, the polycondensation reactors are run under a vacuum. Catalysts for the polycondensation reaction include compounds of antimony, germanium, tin, titanium and/or aluminum. In some embodiments, it may be advantageous to use a titanium compound. A suitable amount of elemental Ti can be about 5 to about 60 ppm, for example about 10 to about 35 ppm. Reaction conditions for polycondensation can include (i) a temperature less than about 290°C, or about 10°C higher than the melting point of the copolyester-ether; and (ii) a pressure of less than about 0.01 bar, decreasing as polymerization proceeds. This copolyester-ether can be produced continuously in a series of one or more reactors operating at elevated temperature and pressures less than one atmosphere. Alternatively this copolyester-ether can be produced in one or more batch reactors. The intrinsic viscosity after melt phase polymerization can be in the range of about 0.5 dl/g to about 1.5 dl/g. Antioxidants and other additives can be added before and/or during polymerization to control the degradation of the polyester-ether segments. Alternatively, the copolyester-ethers can be produced by reactive extrusion of the polyether with the polyester. In the above-described methods of preparing the copolyester-ethers, it may happen that the polyether does not fully react with the polyester but is partly present as an intimate blend of the polyester and polyether. Therefore, throughout the specification and claims, the reference to a copolyester-ether comprising one or more polyester segments and one or more polyether segments is to be understood as referring to the respective copolyester-ethers, blends of respective polyesters and polyethers, and mixtures comprising both the respective copolyester-ethers and blends of the respective polyesters and polyethers.

[0030] The copolyester-ether is preferably used in amounts of about 0.5 to about 20 wt.-% in relation to the final composition. Advantageously, the amount of the copolyester-ether is selected within the range of about 0.5 to about 10 wt.-%, in relation to the final container, preform and article composition, so that the amount of polyether segments to the total amount of base polyester and polyester segments in the composition is about 0.2 to about 10 wt.-%, more specifically about 0.5 to about 10 wt.-%, or in particular about 0.7 to about 5 wt.-%, or about 0.5 to about 1.5 wt.-% or about 1 to about 2.5 wt.-%.

[0031] Advantageously, the copolyester-ether contains one or more polyether segments in an amount of about 5 to about 45 wt.%, in particular about 15 to about 35 wt.-%, more specifically about 20 to about 30 wt.%, and that the amount of the copolyester-ether is selected so that the amount of polyether segments to the total amount of base polyester and polyester segments in the composition is about 0.5 to about 10 wt.-%, in particular about 0.7 to about 5 wt.-%, or about 0.5 to about 1.5 wt.-%, or about 1 to about 2.5 wt.-%.

[0032] It is particularly advantageous that the polyether segments in the copolyester-ether have a number-average molecular weight of from about 600 to about 2000 g/mol, in particular about 800 to about 1600 g/mol, that the copolyester-ether contains one or more polyether segments in an amount of about 15 to about 35 wt.-%, in particular about 20 to about 30 wt.-%, and that the amount of the copolyester-ether is selected within the range of about 0.5 to about 40 wt.-%, in relation to the final composition, so that the amount of polyether segments to the total amount of base polyester and polyester segments in the composition is about 0.5 to about 10 wt.-%, in particular about 0.7 to about 5 wt.-%, or about 0.5 to about 1.5 wt.-%, or about 1 to about 2.5 wt.-%.

[0033] It is particularly advantageous that the polyether segments in the copolyester-ether are selected from a linear or branched poly(propylene glycol) or a linear or branched poly(butylene glycol) having a number-average molecular weight of from about about 600 to about 2000 g/mol, in particular about 800 to about 1600 g/mol, that the copolyester-ether contains one or more polyether segments in an amount of about 15 to about 35 wt.-%, in particular about 20 to about 30 wt.-%, and that the amount of the copolyester-ether is selected within the range of about 0.5 to about 20 wt.-%, in relation to the final composition, so that the amount of polyether segments to the total amount of base polyester and polyester segments in the composition is about 0.5 to about 10 wt.-% , in particular about 0.7 to about 5 wt.-%, or about 0.5 to about 1.5 wt.-%, or about 1 to about 2.5 wt.-%.

[0034] The HALS used in the embodiments of the present invention is represented by the formula (I) or a mixture of compounds of formula (I),

wherein each R₁ independently represents C₁-C₄ alkyl, R₂ represents H, C₁-C₄ alkyl, OH, O-C₁-C₄ alkyl, or a further part of an oligomeric or polymeric HALS, and R₃ represents a further part of a monomeric, oligomeric or polymeric HALS. For instance, when the HALS is a polymeric HALS, R₃ may represent the polymer backbone of the polymeric HALS. An example of such as HALS is Uvinul^® 5050. As a further example, when additionally R₂ represents a further part of an oligomeric or polymeric HALS, the piperidine ring in above formula (I) is part of the repeat unit of the oligomeric or polymeric HALS. An example of such a HALS is Uvinul^® 5062. The HALS may be a mixture of compounds of formula (I). An example of such a HALS is Uvinul^® 4092.

[0035] Specific HALS suitable for use in the invention are Uvinul^® 4050, Uvinul^® 4077, Uvinul^® 4092, Uvinul^® 5050 and Uvinul^® 5062. Uvinul^® 4050 is particularly preferred. Alternatively, suitable HALS for the invention are: Nylostab^®, Hostavin^®, and Nylostab^® SEED^® from Clariant.

[0036] Advantageously, in the above formula (I) each R₁ independently represents C₁-C₄ alkyl, R₂ represents H or C₁-C₄ alkyl, or a further part of an oligomeric or polymeric HALS.

[0037] It is particularly advantageous that in the above formula (I) each R₁ represents methyl and R₂ represents H or methyl.

[0038] It is particularly advantageous that the HALS is a monomeric HALS. Preferably, the HALS has a a molecular weight of about 400g/mol or above, or about 400 to about 1500 g/mol, or about 400 to about 1200 g/mol, or in particular about 400 to about 800 g/mol.

[0039] It may also be particularly advantageous that the HALS is an oligomeric or polymeric HALS. In those cases it may also be particularly advantageous that the HALS comprises one or more moieties of the formula (I),

wherein each R₁ independently represents C₁-C₄ alkyl, R₂ represents H or C₁-C₄ alkyl, and R₃ represents a further part of the oligomeric or polymeric HALS. It may further be particularly advantageous in some embodiments that in the above formula (I), each R₁ represents methyl, R₂ represents H or methyl, and R₃ represents a further part of the oligomeric or polymeric HALS.

[0040] When referring throughout the specification to oligomeric or polymeric HALS, this is to be understood as referring to 2 to 8 repeating units in case of an oligomeric HALS and more than 8 repeating units in case of a polymeric HALS.

[0041] In some embodiments of the present invention, it may be particularly advantageous that the HALS is used in an amount of about 20 to about 2500 ppm, or about 30 to about 2000 ppm, or about 40 to about 1000 ppm, and in particular about 50 to about 800 ppm, respective to the weight of the total composition. In the masterbatch embodiments, the amount of HALS may be substantially higher, for instance about 250 to about 10,000 ppm, or about 750 to about 10,000 ppm, or in particular about 1000 to about 5000 ppm, respective to the weight of the total masterbatch.

[0042] In some embodiments of the present invention, it may be particularly advantageous that the polyether segments in the copolyester-ether have a number-average molecular weight of from about 600 to about 2000 g/mol, in particular about 800 to about 1600 g/mol, that the copolyester-ether contains one or more polyether segments in an amount of about 15 to about 35 wt.-%, in particular about 20 to about 30 wt.%, and that the amount of the copolyester-ether is selected within the range of about 0.5 to about 20 wt.-%, in relation to the final composition, so that the amount of polyether segments to the total amount of base polyester and polyester segments in the composition is about 0.5 to about 10 wt.-% , in particular about 0.7 to about 5 wt.-%, or about 0.5 to about 1.5 wt.-%, or about 1 to about 2.5 wt.-% ; and that HALS is represented by the formula (I) or a mixture of compounds of formula (I),

wherein each R₁ independently represents C₁-C₄ alkyl, in particular methyl, R₂ represents H or C₁-C₄ alkyl, in particular H, and R₃ represents a further part of a monomeric, oligomeric or polymeric HALS.

[0043] In some embodiments of the present invention, it may be particularly advantageous that the polyether segments in the copolyester-ether are selected from a linear or branched poly(propylene glycol) or a linear or branched poly(butylene glycol) having a number-average molecular weight of from about 600 to about 2000 g/mol, in particular about 800 to about 1600 g/mol, that the copolyester-ether contains one or more polyether segments in an amount of about 15 to about 35 wt.%, in particular about 20 to about 30 wt.-%, and that the amount of the copolyester-ether is selected within the range of about 0.5 to about 20 wt.-%, in relation to the final composition, so that the amount of polyether segments to the total amount of base polyester and polyester segments in the composition is about 0.5 to about 10 wt.-% , in particular about 0.7 to about 5 wt.-%, or about 0.5 to about 1.5 wt.-%, or about 1 to about 2.5 wt.% ; and that the HALS is represented by the formula (I) or a mixture of compounds of formula (I),

wherein each R₁ independently represents C₁-C₄ alkyl, in particular methyl, R₂ represents H or C₁-C₄ alkyl, in particular H, and R₃ represents a further part of a monomeric, oligomeric or polymeric HALS.

[0044] It may be particularly advantageous that the copolyester-ether and/or the polyester is produced using a titanium-based polycondensation catalyst. In particular, it may be advantageous that the polyester is produced using a titanium-based polycondensation catalyst.

[0045] It may be particularly advantageous that the weight ratio of titanium metal to HALS compound is about 1:2 to about 1:500, or about 1:10 to about 1:250, in particular about 1:50 to about 1:200 in the final composition.

[0046] Where the invention may further comprise a transition metal-based oxidation catalyst, suitable oxidation catalysts include those transition metal catalysts that activate or promote the oxidation of the copolyester-ether by ambient oxygen. Examples of suitable transition metals may include compounds comprising cobalt, manganese, copper, chromium, zinc, iron, or nickel. The transition metal-based oxidation catalyst may be introduced into the composition in the form of a metal salt. In this case, suitable counter ions for the transition metal include, but are not limited to, carboxylates, such as neodecanoates, octanoates, stearates, acetates, naphthalates, lactates, maleates, acetylacetonates, linoleates, oleates, palminates or 2-ethyl hexanoates, oxides, carbonates, chlorides, dioxides, hydroxides, nitrates, phosphates, sulfates, silicates or mixtures thereof. It is also possible that the transition metal-based oxidation catalyst is incorporated in the polymer matrix during e.g. extrusion. The transition metal-based oxidation catalyst can be added during polymerization of the polyester or compounded into a suitable polyester thereby forming a polyester-based masterbatch that can be added during the preparation of the article. The cobalt compound may be physically separate from the copolyester-ether, for example a sheath core or side-by-side relationship, so as not to activate the copolyester-ether prior to melt blending into a preform or bottle.

[0047] Advantageously, the transition metal based oxidation catalyst is a cobalt compound. In the container- or preform- related embodiments of the present invention, it may be advantageous that the transition metal-based oxidation catalyst is a cobalt compound that is present in an amount of about 40 to about 200 ppm, more specifically about 60 to about 120 ppm, on basis of the weight of cobalt in the total composition. In the masterbatch- related embodiments of the present invention, it may be advantageous that the transition metal-based oxidation catalyst is a cobalt compound that is present in an amount of about 50 to about 5,000 ppm, more specifically about 100 to about 2,500 ppm, on basis of the weight of cobalt in the total composition. In the embodiments of the present invention, it may be advantageous that the transition metal-based oxidation catalyst is a cobalt salt, in particular a cobalt carboxylate, and especially a cobalt C₈-C₂₀ carboxylate.

[0048] Advantageously, the weight ratio of metal of the transition metal based oxidation catalyst to HALS compound is about 100:1 to about 1: 50 or about 75:1 to about 1:30 in particular about 50:1 to about 1:25, respective to the final composition.

[0049] In some embodiments of the present invention, it may be particularly advantageous that the polyether segments in the copolyester-ether are selected from a linear or branched poly(propylene glycol) or a linear or branched poly(butylene glycol) having a number-average molecular weight of from about 600 to about 2000 g/mol, in particular about 800 to about 1600 g/mol, that the copolyester-ether contains one or more polyether segments in an amount of about 15 to about 35 wt.%, in particular about 20 to about 30 wt.-%, and that the amount of the copolyester-ether is selected within the range of about 0.5 to about 20 wt.-%, in relation to the final composition, so that the amount of polyether segments to the total amount of base polyester and polyester segments in the composition is about 0.5 to about 10 wt.-%, in particular about 0.7 to about 5 wt.-%, or about 0.5 to 1.5 wt.-%, or about 1 to about 2.5 wt.-%. The HALS in this embodiment is represented by the formula (I) or a mixture of compounds of formula (I),

wherein each R₁ independently represents C₁-C₄ alkyl, in particular methyl, R₂ represents H or C₁-C₄ alkyl, in particular H, and R₃ represents a further part of a monomeric, oligomeric or polymeric HALS. The transition metal-based oxidation catalyst in this embodiment is a cobalt compound, in particular a cobalt carboxylate, and especially a cobalt C₈-C₂₀ carboxylate.

[0050] Embodiments in some aspects of the invention may further comprise a further antioxidant selected from the group consisting of hindered phenols, benzophenones, sulfur-based antioxidants, and phosphites. Examples of such antioxidants include, but are not limited to 1,3,5-trimethyl-2,4,6-tris(3,5-di-tert-butyl-4-hydroxybenzyl)-benzene (CAS: 1709-70-2), tetrakis(2,4-di-tert-butylphenyl)-1,1-biphenyl-4,4'-diylbisphosphonite (CAS: 38613-77-3) or pentaerythritol tetrakis(3-(3,5-di-tert-butyl-4-hydroxyphenyl)propionate (CAS: 6683-19-8). Advantageously, one or more antioxidants are used in amounts of about 100 ppm to about 10,000 ppm, more specifically about 200 ppm to about 5,000 ppm or about 300 ppm to about 3,000 ppm, and in particular about 400 ppm to aobut 2,000 ppm, on basis of the total weight of the antioxidant to the total weight of the polyether composition.

[0051] Embodiments in some aspects of the invention may further comprise additives selected from the group consisting of dyes, pigments, fillers, branching agents, reheat agents, anti-blocking agents, anti-static agents, biocides, blowing agents, coupling agents, flame retardants, heat stabilizers, impact modifiers, crystallization aids, lubricants, plasticizers, processing aids, buffers, and slip agents. Representative examples of such additives are well-known to the skilled person.

[0052] It may be advantageous that an ionic compatibilizer is present or used. Suitable ionic compatibilizers can for instance be copolyesters prepared by using ionic monomer units as disclosed in WO 2011/031929 A2, page 5, incorporated herein by reference.

[0053] In the masterbatch embodiments of the present invention, it may be advantageous that the masterbatch is mixed or packaged with another masterbatch comprising the transition metal based oxidation catalyst (a "salt and pepper" mixture). It may be advantageous that the other masterbatch comprising the transition metal based oxidation catalyst further comprises a polyester.

[0054] The disclosed compositions, masterbatches and methods may be used for preparing articles of manufacture. Suitable articles include, but are not limited to, film, sheet, tubing, pipes, fiber, container preforms, blow molded articles such as rigid containers, thermoformed articles, flexible bags and the like and combinations thereof. Typical rigid or semi-rigid articles can be formed from plastic, paper or cardboard cartons or bottles such as juice, milk, soft drink, beer and soup containers, thermoformed trays or cups. In addition, the walls of such articles may comprise multiple layers of materials.

[0055] The term "comprising" encompasses "including" as well as "consisting" e.g. a composition "comprising" X may consist exclusively of X or may include something additional e.g. X + Y.

[0056] The invention is further illustrated by the following examples, although it will be understood that these examples are included for the purposes of illustration only and are not intended to limit the scope of the invention.

TEST PROCEDURES

Number Average Molecular Weight

[0057] The number average molecular weight of the polyols is determined by the titration method for the hydroxyl number of the polyols. Similar ASTM methods are ASTM E222A and ASTM E222B, herein incorporated by reference.

[0058] For that 1 h of polyglycol, whereas the actual weight is dependent on the expected hydroxyl number - (expected to be 50/hydroxyl number), was added into a 100 mL beaker 15 mL of dry tedrahydrofuran and the sample dissolved using a magnetic stirrer. 10 mL of p-toluenesulfonyl isocyanate in 250 mL anhydrous acetonitrile was then added to the solution. The solution was then stirred for five minutes after 1 mL of water was added. Then the solution was diluted to 60 mL with tetrahydrofuran and titrated with 0.1 N tetrabutyl ammonium hydroxide (TBAOH) using an automatic titrator.
(TBAOH titrant: 100 mL 1M TBAOH/MeOH in 1000 mL Isopropanol. Standardize against potassium biphthalate or benzoic acid standards. Restandardize every time the electrode is recalibrated.)
The hydroxyl number of the polyol was calculated as followed:


whereas

V1

= Titrant volume at first equivalence point (low pH)

V2

= Titrant volume at second equivalence point (higher oH)

N

= Normality of TBAOH

[0059] The number molecular weight of the polyol is then calculated as followed:

Intrinsic Viscosity

[0060] The determination of the intrinsic viscosity was determined on a 0.01 g/mL polymer solution in dichloroacetic acid.

[0061] Before dissolution of solid state polymerized material, the chips were pressed in a hydraulic press (pressure: 400 kN at 115°C for about 1 minute; type: PW40^® Weber, Remshalden-Grunbach, Germany). 480 to 500 mg polymer, either amorphous chips or pressed chips, were weighed on an analytical balance (Mettler AT 400^®) and dichloroacetic acid is added (via Dosimat^® 665 or 776 from Metrohm) in such an amount, that a final polymer concentration of 0.0100 g/mL is reached.

[0062] The polymer is dissolved under agitation (magnetic stirring bar, thermostat with set point of 65°C; Variomag Thermomodul 40ST^®) at 55°C (internal temperature) for 2.0 hrs. After complete dissolution of the polymer, the solution is cooled down in an aluminum block for 10 to 15 minutes to 20°C (thermostat with set point of 15°C; Variomag Thermomodul 40ST^®).

[0063] The viscosity measurement was performed with the micro Ubbelohode viscometer from Schott (type 53820/II; Ø: 0.70 mm) in the Schott AVS 500^® apparatus. The bath temperature is held at 25.00 ± 0.05°C (Schott Thermostat CK 101^®). First the micro Ubbelohde viscometer is purged 4 times with pure dichloroacetic acid then the pure dichloroacetic acid is equilibrated for 2 minutes. The flow time of the pure solvent is measured 3 times. The solvent is drawn off and the viscometer is purged with the polymer solution 4 times. Before measurement, the polymer solution is equilibrated for 2 minutes and then the flow time of this solution is measured 3 times.\

[0064] The relative viscosity (RV) is determined by dividing the flow time of the solution by the flow time of the pure solvent. RV is converted to IV using the equation: IV (dl/g) = [(RV-1) x 0.691] + 0.063.

Determination of the thermal decomposition products detected in the preforms

[0065] The decomposition products detected in the chips and preforms were measured via Headspace-GCMS. For the measurements 1 g of a powdered sample (particle size < 1.0 mm) and 2 µL hexafluorisopropanol (HFIP) as the internal standard were added in 20 g vials and then incubated for 1 hour at 150°C. 1 µL of the headspace of the vials was injected in the column (RTX-5, crossbond 5% diphenyl/ 95% dimethyl polysiloxane, 60m, 0.25 mm internal diameter) for separation. The main thermal decomposition products were detected and analysed via mass spectrometer.

[0066] The following setup was used:

Gas chromatograph (GC), Finnigan Focus GC (Thermo Electron Corporation)

[0067] 

• SSL inlet

  o Mode: Split

  o Inlet T - 230°C

  o Split flow - 63 mL·min^-1

  o Spilt ratio - 70

• Carrier

  o Constant flow

• Ramp from 40°C (hold for 8min) to 300°C (hold for 3min)
• T increase 15°C·min^-1

Mass spectrometer (MS), Finnigan Focus DSQ (Thermo Electron Corporation)

[0068] 

• MS transfer line - T-250°C
• Ion source T - 200°C
• Detector gain: 1.5·10⁵ (multiplier voltage 1445V)
• Scan: 10 - 250 (mass range)

[0069] The following thermal decomposition products were detected in the headspace of the powdered samples:

• C₂-bodies - acetaldehyde
• C₃-bodies - formic acid propyl ester, propanol, propionaldehyde
• C₄-bodies - tetrahydrofurane

[0070] The individual values for the above C₂- to C₄-bodies were summed up to give the reported value. The standard deviation of the thermal decomposition products is about 4 % for all measurements.

Oxygen ingress measurements - Non-Invasive Oxygen Determination (NIOD)

[0071] There are several methods available to determine the oxygen permeation, or transmission, into sealed packages such as bottles. In this case, non-invasive oxygen measurement systems (e.g., supplied by OxySense^® and PreSens Precision Sensing) based on a fluorescence quenching method for sealed packages were employed. They consist of an optical system with an oxygen sensor spot (e.g. OxyDot^®, which is a metal organic fluorescent dye immobilized in a gas permeable hydrophobic polymer) and a fiber optic reader-pen assembly which contains both a blue LED and photo-detector to measure the fluorescence lifetime characteristics of the oxygen sensor spot (e.g. OxyDot^®).

[0072] The oxygen measurement technique is based upon the absorption of light in the blue region of the metal organic fluorescent dye of the oxygen sensor spot (e.g., OxyDot^®), and fluorescence within the red region of the spectrum. The presence of oxygen quenches the fluorescent light from the dye as well as reducing its lifetime. These changes in the fluorescence emission intensity and lifetime are related to the oxygen partial pressure, and thus they can be calibrated to determine the corresponding oxygen concentration.

[0073] The oxygen level within a package such as a bottle can be measured by attaching an oxygen sensor spot (e.g., OxyDot^®) inside the package. The oxygen sensor spot is then illuminated with a pulsed blue light from the LED of the fiber optic reader-pen assembly. The incident blue light is first absorbed by the dot and then a red fluorescence light is emitted. The red light is detected by a photo-detector and the characteristic of the fluorescence lifetime is measured. Different lifetime characteristics indicate different levels of oxygen within the package.

Experimental method with PET bottle at ambient conditions (23°C)

[0074] A PreSens non-invasive and non-destructive oxygen ingress measurement equipment (Fibox 3-trace meter, fiber optic cable and trace oxygen sensor spots) was used to determine the oxygen permeability of the bottle at room temperature (23°C). For a typical shelf-life test, the trace oxygen sensor spot was first attached onto the inner side wall of a 500 ml transparent PET bottle. The bottle was then filled with deionized and deoxygenated water containing AgNO₃ up to a headspace of approx. 20 ml, inside a nitrogen circulation glove box where the oxygen level of the water inside the bottle was stabilized at a level well below 50 ppb. These bottles were then stored in a conditioning cabinet (Binder 23°C, 50% relative humidity) and the oxygen ingresses were monitored as a function of time using the PreSens oxygen ingress measurement equipment.

[0075] At a given time of measurements, an average value was first obtained from about 10 readings taken on the output of the trace oxygen spot for each bottle. This was then repeated for all the 5 bottles so as to achieve an overall averaged value for the oxygen ingress through the formulated cap and the wall of the bottle.

[0076] Oxygen measurements were made on day 0, 1, 2, 3, 8, 14, 21, 28, 42 and 56, and the average oxygen ingress was determined and reported as ppb.

Preform and bottle process

[0077] Unless otherwise stated, the barrier copolyester-ether of the present invention was dryed for about 24 hours at 110 - 120°C under nitrogen atmosphere, blended with the dry base resin (BP 1) which contains the transition metal catalyst, melted and extruded into preforms. Each preform for a 0.5 liter soft drink bottle, for example, employed about 28 grams of the resin. The preform was then heated to about 85 - 120°C and stretch-blown into a 0.5 liter contour bottle at a planar stretch ratio of approx. 8. The stretch ratio is the stretch in the radial direction times the stretch in the length (axial) direction. Thus, if a preform is blown into a bottle, it may be stretched about two times in the axial direction and stretched up to about four times in the hoop direction giving a planar stretch ratio of up to eight (2x4). Since the bottle size is fixed, different preform sizes can be used for obtaining different stretch ratios. The sidewall thickness of the bottles was > 0.25 mm.

EXAMPLES

Example 1 - Synthesis of copolyester-ether (COPE E1)

[0078] Copolyester-ether was prepared using continuous polymerization process: A slurry of terephthalic (PTA) acid and glycol (EG) in a small molar excess of glycol (PTA/EG molar ratio < 1:1.15) was continuously charged to the primary esterification reactor. The amount of slurry added to the primary esterification reactor was controlled by a flow measuring device. In the primary esterification reactor terephthalic acid and glycol reacted at 250-260°C and 2-4 bar excess pressure under water elimination. The resulting low molecular weight esterification product was then transferred (via pump) to another reactor (secondary esterifier). A titanium catalyst (Sachtleben Hombifast HS06^®, 12 ppm Ti based on the final polymer) and 20 weight-% ofpoly(tetramethylene oxide) glycol (Terathane^® Polyetherglycol, having a number average molecular weight of 1400 g/mole, stabilized with 200 ppm Ethanox^® 330) based on the final polymer weight were then added to the reaction mixture and the polycondensation, the elimination of glycol under reduced pressure, started at 250-260°C. The dwell time of the reaction mixture (pre-condensate) was again controlled by a flow measuring device. The pre-condensate was then discharged consecutively in two downstream reactors where the dwell time was controlled via the level of the reaction mixture in each reactor. In both reaction vessels glycol was distilled out of the reaction mixture under increased temperature and reduced pressure until the desired polymerization degree was achieved. The desired polymer melt flowed through the reactor discharge pump in a cooling bath with deionized water. After the polymer strand cooled, it was pelletized with Pell-tec pelletizer.
The intrinsic viscosity of the final copolyester-ether polymer compositions was 0.693 dl/g.

Example 2 - Synthesis of the base polyester (BP1)

[0079] The base resin was prepared using continuous process: A slurry of terephthalic acid, isophthalic acid (3.05 wt.-% based on the final polymer) and glycol in a small molar excess of glycol (PTA/EG molar ratio < 1:1.08) was continuously charged to the primary esterification reactor. The amount of slurry added to the primary esterification reactor was controlled by a flow measuring device. In the primary esterification reactor terephthalic acid and glycol react at 250-260°C and 2-4 bar excess pressure under water release. The resulting low molecular weight esterification product was then transferred (via pump) to another reactor (secondary esterifier). A titanium catalyst (Sachtleben Hombifast HS06^®, 7 ppm Ti based on the final polymer) was then added to the reaction mixture and the polycondensation, the elimination of glycol under reduced pressure, started at 260-280°C. The dwell time of the reaction mixture (pre-condensate) is again controlled by a flow measuring device. The pre-condensate was then discharged consecutively in two downstream reactors whereas the dwell time was controlled via level of the reaction mixture in each reactor. In both reaction vessels further glycol was distilled out of the reaction mixture under increased temperature and reduced pressure until the desired polymerization degree is achieved. The oxidation catalyst (75 ppm Cobalt as Cobalt-stearate, CAS: 1002-88-6) was added late as a melt to the reaction mixture shortly before the polymer melt flowed through the reactor discharge pump in a cooling bath with deionized water. After the polymer strand cooled, it was pelletized with Pell-tec pelletizer.

[0080] The resulting polymer chips were crystallized for approx. 4 hours at 160°C, solid stated under vacuum at a temperature of 230°C for approx. 7 hours to the desired intrinsic viscosity value (∼ IV-value: 0.860 dl/g) and then cooled to ambient temperature.

Example 3 - Compounding of Copolyester-ether (COPE E1) with different stabilizers

[0081] The copolyester-ether COPE E1 described in Example 1 with an intrinsic viscosity of 0.693 dl/g was used for the compounding trials. Prior to the extrusion the COPE Elwas dried at 160°C under vacuum for 5 hours to remove residual moisture. The COPE E1 was then mixed with different powdered additives via salt and pepper method and the resulting mixtures were subsequently extruded using an intermeshing, co-rotating, twin screw extruder manufactured by Leistritz AG. The process conditions used during the experiment are described below:

• Extruder type: (Leistritz Micro 27 36D), co-rotating, extruder screw diameter 27 mm, screw length to diameter ratio (L:D) ratio is 36:1
• Operation conditions: T0 cooling water temperature/T1 210°C/T2 215°C/T3 210/T4-T5 240°C/T6-T8 210°C/T9 209°C
• No vacuum level in degassing area
• Polymer flow rate 8 kg/h
• Type of granules: cylindrical, length 3 mm and diameter 2 mm

[0082] The molten materials were extruded into a water bath and then pelletized. The intrinsic viscosity of the compounded material is about 0.668 dl/g. The kind and amount of the additives and the thermal decomposition products are summarized in the Tables 1 and 2 below. Table 1 shows the Hindered Amine Light Stabilizers (HALS) of the invention and Table 2 shows comparative stabilizers (UV-absorbers and thermo-oxidative stabilizers):

Table 1

Sample	1	2	3	4	5	6	7	8	9	10	11	12	13
HALS1	-	Uvinul® 4050					Uvinul® 5050			Uvinul® 5062
Total amount [ppm]	-	156	313	625	1250	2500	1513	3025	6050	781	1563	2500	3125
Active N2 [ppm]	-	10	20	39	78	156	39	78	156	39	77	123	154

Thermal C2-C4 decomposition products (ppm, detected in the resin)
C2-C4 decomp.	2436	1719	86	98	131	111	57	91	84	1918	579	1249	76

1 Uvinul® 4050 (N,N'-bisformyl-N,N'-bis-(2,2,6,6-tetramethyl-4-piperidinyl)-hexamethylendiamine), CAS: 124172-53-8 Uvinul® 5050 (sterically hindered amine, oligomeric), CAS: 152261-33-1 Uvinul® 5062 (sterically hindered amine, oligomeric), CAS: 65447-77-0 2 Active N: Amount of nitrogen contained in functional groups which have the ability to generate a stable nitroxyl radical

Table 2

Sample	14	15	16	17	18	19	20	21	23
Additive	UV-absorber1				Thermo-oxidative stabilizer2
	Hostavin® Aro8	Tinuvin® 234	Tinuvin® 1577	Uvinul® 3030	Hostanox® PEP-Q		Ethanox® 330
[ppm]	2500	2500	2500	2500	200	625	625	1250	2500

Thermal decomposition products (ppm, detected in the resin)
C2-C4 decomp.	1971	1884	2314	2098	2288	1996	54	52	46

1Hostavin® Aro8 (2-Hydroxy-4-n-octyloxybenzophenone), CAS:1843-05-6 Tinuvin® 234 (2-(2H-Benzotriazol-2-yl)-4,6-bis(1-methyl-1-phenylethyl)phenol, CAS: 70321-86-7 Tinuvin® 1577 (2-(4,6-diphenyl-1,3,5-triazin-2-yl)-5-[(hexyl)oxy]-phenol, CAS: 147315-50-2 Uvinul® 3030 (2-Propenoic acid, 2-cyano-3,3-diphenyl-,2,2-bis[[(2-cyano-1-oxo-3,3-diphenyl-2-propenyl)oxy] methyl]-1,3-propanediyl ester), CAS: 178671-58-4 2 Hostanox® PEP-Q (Diphosphonite antioxidant), CAS: 119345-01-6 Ethanox® 330 (1,3,5-trimethyl-2,4,6-tris(3,5-di-t-butyl-4-hydroxybenzyl)benzene, CAS: 1709-70-2

[0083] As is evident from the above Table 1, the HALS compounds of the invention are substantially reducing the amount of C₂-C₄ decomposition products. Different HALS stabilizers of the invention are of similar potency with the exception of Uvinul^® 5062 which is slightly less potent. Without being bound by theory, it may be speculated that this HALS stabilizer has first to be cleaved in-situ to yield a sterically hindered amine radical that is capable of scavenging radicals. Nevertheless, Uvinul^® 5062 is more efficient in reducing C₂-C₄ decomposition products than other types of stabilizers such as Hostavin^® Aro8, Tinuvin^® 234, Tinuvin^® 1577, Uvinul^® 3030 and Hostanox^® PEP-Q (Table 2).

Example 4 - Influence of different stabilizers on thermal decomposition products and oxygen barrier in preforms and bottles

[0084] Unless otherwise stated, various modified barrier copolyester-ether of the present invention (see above Table 1 and 2) were dryed for about 24 hours at 110 - 120°C under nitrogen atmosphere, blended with the dry base resin (BP1 from Example 2) which contains the transition metal catalyst, injection-molded into preforms and further stretch-blow molded into bottles (see below Table 3). The ratio of barrier resin to base resin was chosen as 5.0 / 95.0 (wt. by wt.). The preforms were stretch blow molded into 500 mL, 28 g bottles. The oxygen permeation, the color values as well as the haze of these bottles were measured. The bottles were then either cut and powdered (< 0.1mm) to determine the thermal by-product level or barrier measurement (as described in the Test Procedures). For reasons of better grindability, the thermal decomposition products were detected in the ground preforms and the barrier performance was measured in the bottles.

Table 3

Sample	I	II	III	IV	V
Stabilizer	-	Uvinul® 4050	Hostavin® Aro8	Hostanox® PEP-Q	Ethanox® 330
Amount stabilizer (added to the Copolyester-ester resin) [ppm]	-	2500	2500	2500	625
Thermal decomposition products (detected in the preforms) Total C2-C4 [ppm]	461	234	416	387	432
Barrier performance after 56 days (measured in the bottles) [ppb]	11	23	32	95	226

[0085] From the above Table 3, it is evident that HALS compounds of formula (I) are capable of substantially reducing the amount of C₂-C₄ decomposition products in final products such as preforms and bottles. At the same time, oxygen barrier properties of bottles are minimally affected. In comparison, other stabilizers do not provide the same performance: Hostavin^® Aro8 does not yield a comparable reduction in degradation products and is also more negatively impacting barrier performance. Hostanox^® PEP-Q is inferior in preventing degradation and provides substantially deteriorated barrier performance. Finally, Ethanox^® 330 leads to poor oxygen barrier properties already at 625 ppm addition level. At the same concentration, Ethanox^® 330 also provides poor protection against degradation.

Example 5 - Influence of the amount of HALS

[0086] In the next test series, the concentration of a HALS according to the invention was successively reduced. The following samples summarized in Table 4 were prepared as described in Example 4:

Table 4

Sample	I	II	VI	VII	VIII
Stabilizer	-	Uvinul® 4050
Amount stabilizer (added to the Copolyester-ester resin) [ppm]	-	2500	1250	625	313
Thermal decomposition products (detected in the preforms) Total C2-C4 [ppm]	461	234	224	300	308
Barrier performance after 56 days (measured in the bottles) [ppb]	11	23	26	27	12

[0087] As is evident from the above Table 4, the HALS compounds of the invention retain their performance at very low concentrations.

Embodiments

[0088] Although the present invention is defined in the attached claims, it should be understood that the present invention can also (alternatively) be defined in accordance with the following embodiments:

1. A composition for preparing an article, preform or container comprising:

a) 80-98.5 parts by weight of a base polyester;

b) 0.5-20 parts by weight of a copolyester-ether,
wherein the copolyester-ether comprises one or more polyester segments and one or more polyether segments, wherein the one or more polyether segments are present in an amount of about 5 to about 95 wt.-% of the copolyester-ether;

c) a transition metal-based oxidation catalyst; and

d) a monomeric, oligomeric or polymeric hindered amine light stabilizer (HALS) in an amount of 15 - 10,000 ppm, on basis of the weight of the stabilizer in the total composition, wherein the HALS is represented by the formula (I) or a mixture of compounds of formula (I),

wherein each R₁ independently represents C₁-C₄ alkyl, R₂ represents H, C₁-C₄ alkyl, OH, O-C₁-C₄ alkyl, or a further part of an oligomeric or polymeric HALS, and R₃ represents a further part of a monomeric, oligomeric or polymeric HALS.

2. The composition of embodiment 1, wherein the polyether segment is a linear or branched poly (C₂-C₆-alkylene glycol) segment.

3. The composition of embodiment 1 or 2, wherein the polyether segment has a number-average molecular weight of about 200 to about 5000g/mol, preferably about 600 to about 2500 g/mol.

4. The composition of any one of embodiments 1 to 3, wherein the polyether segments are present in the copolyester-ether in an amount of about 20 to about 40 wt.-%.

5. The composition of any one of embodiments 1 to 4, wherein the copolyester-ether comprises a polyethylene terephthalate (co)polyester segment.

6. The composition of any one of embodiments 1 to 5, wherein the HALS is a monomeric HALS, preferably having a molecular weight of 400 g/mol or above.

7. The composition of any one of embodiments 1 to 5, wherein the HALS is an oligomeric or polymeric HALS.

8. The composition of embodiment 7, wherein the HALS is an oligomeric or polymeric HALS comprising one or more moieties of the formula (I),

wherein each R₁ independently represents C₁-C₄ alkyl, R₂ represents H or C₁-C₄ alkyl, and R₃ represents a further part of the oligomeric or polymeric HALS.

9. The composition of any one of embodiments 1 to 8, wherein the HALS is present in an amount of about 20 to about 2500 ppm.

10. The composition of any one of embodiments 1 to 9, wherein transition metal-based oxidation catalyst is a cobalt compound.

11. The composition of any one of embodiments 1 to 10, wherein the copolyester-ether and/or the polyester is produced using a titanium-based polycondensation catalyst.

12. The composition of embodiment 11, wherein the weight ratio of titanium metal to HALS is 1:2 to 1:500.

13. The composition of any one of embodiments 1 to 12, wherein the transition metal-based oxidation catalyst is present in an amount of from about 15 to about 400 ppm based on the weight of the transition metal in the total composition

14. The composition of any one of embodiments 1 to 13, wherein the weight ratio of the one or more polyether segments to the total amount of base polyester and polyester segments in the composition is from about 0.2 to about 10 wt.%.

15. A masterbatch for use in preparing an article, preform or container comprising:

a) copolyester-ether,
wherein the copolyester-ether comprises one or more polyester segments and one or more polyether segments, wherein the one or more polyether segments are present in an amount of about 5 to about 95 wt.-% of the copolyester-ether; and

b) a monomeric, oligomeric or polymeric hindered amine light stabilizer (HALS) in an amount of 100 - 30,000 ppm, on basis of the weight of the stabilizer in the total composition, wherein the HALS is represented by the formula (I) or a mixture of compounds of formula (I),

wherein each R₁ independently represents C₁-C₄ alkyl, R₂ represents H, C₁-C₄ alkyl, OH, O-C₁-C₄ alkyl, or a further part of an oligomeric or polymeric HALS, and R₃ represents a further part of a monomeric, oligomeric or polymeric HALS.

16. The masterbatch of embodiment 15, wherein the polyether segment is a linear or branched poly (C₂-C₆-alkylene glycol) segment.

17. The masterbatch of embodiment 15 or 16, wherein the polyether segment has a number-average molecular weight from 200 to about 5000 g/mol, preferably about 600 to about 2500 g/mol.

18. The masterbatch of any one of embodiments 15 to 16, wherein the polyether segments are present in the copolyester-ether in an amount of about 20 to about 40 wt.-%.

19. The masterbatch of any one of embodiments 15 to 18, wherein the copolyester-ether comprises a polyethylene terephthalate (co)polyester segment.

20. The masterbatch of any one of embodiments 15 to 19, wherein the HALS is a monomeric HALS, preferably having a molecular weight of 400 g/mol or above.

21. The masterbatch of any one of embodiments 15 to 19, wherein the HALS is an oligomeric or polymeric HALS.

22. The masterbatch of embodiment 21, wherein the HALS is an oligomeric or polymeric HALS comprising one or more moieties of the formula (I),

wherein each R₁ independently represents C₁-C₄ alkyl, R₂ represents H or C₁-C₄ alkyl, and R₃ represents a further part of the oligomeric or polymeric HALS.

23. The masterbatch of any one of embodiments 15 to 22, wherein the HALS is present in an amount of about 250 to about 10,000 ppm.

24. The masterbatch of any one of embodiments 15 to 23, wherein the copolyester is prepared using a titanium-based polycondensation catalyst.

25. The masterbatch of any one of embodiments 15 to 23, further comprising a titanium compound.

26. The masterbatch of embodiment 24 or 25, wherein weight ratio of titanium metal to HALS is 1:2 to 1:500

27. The masterbatch or composition of any one of embodiments 1 to 26, wherein the weight ratio of the transition metal-based oxidation catalyst to the HALS is 100:1 1 to 1:50.

28. An article, preform or container prepared from a composition of any one of embodiments 1 to 27.

29. A method of preparing a masterbatch for use in preparing an article, preform or container comprising mixing a copolyester-ether, wherein the copolyester-ether comprises one or more polyester segments and one or more polyether segments, wherein the one or more polyether segments are present in an amount of about 5 to about 95 wt.-% in the copolyester-ether; with a monomeric, oligomeric or polymeric hindered amine light stabilizer (HALS) in an amount of 100 - 30,000 ppm, on basis of the weight of the stabilizer in the total composition, wherein the HALS is represented by the formula (I) or a mixture of compounds of formula (I),

wherein each R₁ independently represents C₁-C₄ alkyl, R₂ represents H, C₁-C₄ alkyl, OH, O-C₁-C₄ alkyl, or a further part of an oligomeric or polymeric HALS, and R₃ represents a further part of a monomeric, oligomeric or polymeric HALS.

30. A method of preparing a composition for use in preparing an article, preform or container comprising mixing 80-98.5 parts by weight of a base polyester with:

a) 0.5-20 parts by weight of a copolyester-ether,
wherein the copolyester-ether comprises one or more polyester segments and one or more polyether segments, wherein the one or more polyether segments are present in an amount of about 5 to about 95 wt.-% of the copolyester-ether;

b) a transition metal-based oxidation catalyst; and

c) a monomeric, oligomeric or polymeric hindered amine light stabilizer (HALS) in an amount of 15 - 10,000 ppm, on basis of the weight of the stabilizer in the total composition, wherein the HALS is represented by the formula (I) or a mixture of compounds of formula (I),

wherein each R₁ independently represents C₁-C₄ alkyl, R₂ represents H, C₁-C₄ alkyl, OH, O-C₁-C₄ alkyl, or a further part of an oligomeric or polymeric HALS, and R₃ represents a further part of a monomeric, oligomeric or polymeric HALS.

31. Use of a monomeric, oligomeric or polymeric hindered amine light stabilizer (HALS), wherein the HALS is represented by the formula (I) or a mixture of compounds of formula (I),

wherein each R₁ independently represents C₁-C₄ alkyl, R₂ represents H, C₁-C₄ alkyl, OH, O-C₁-C₄ alkyl, or a further part of an oligomeric or polymeric HALS, and R₃ represents a further part of a monomeric, oligomeric or polymeric HALS; for reducing the amount of decomposition products in an article, preform or container comprising: 80-98.5 parts by weight of a base polyester; 0.5-20 parts by weight of a copolyester-ether, wherein the copolyester-ether comprises one or more polyester segments and one or more polyether segments, wherein the one or more polyether segments are present in an amount of about 5 to about 95 wt.-% of the copolyester-ether; and a transition metal-based oxidation catalyst.

Claims

1. A composition for preparing an article, preform or container comprising:

a) 80-98.5 parts by weight of a base polyester;

b) 0.5-20 parts by weight of a copolyester-ether,
wherein the copolyester-ether comprises one or more polyester segments and one or more polyether segments, wherein the one or more polyether segments are present in an amount of about 5 to about 95 wt.-% of the copolyester-ether;

c) a transition metal-based oxidation catalyst; and

d) a monomeric, oligomeric or polymeric hindered amine light stabilizer (HALS) in an amount of 15 - 10,000 ppm, on basis of the weight of the stabilizer in the total composition, wherein the HALS is represented by the formula (I) or a mixture of compounds of formula (I),

wherein each R₁ independently represents C₁-C₄ alkyl, R₂ represents H, C₁-C₄ alkyl, OH, O-C₁-C₄ alkyl, or a further part of an oligomeric or polymeric HALS, and R₃ represents a further part of a monomeric, oligomeric or polymeric HALS.

2. The composition of claim 1, wherein the polyether segment is a linear or branched poly (C₂-C₆-alkylene glycol) segment.

3. The composition of claim 1 or 2, wherein the polyether segment has a number-average molecular weight of about 200 to about 5000g/mol, preferably about 600 to about 2500 g/mol.

4. The composition of any one of claims 1 to 3, wherein the polyether segments are present in the copolyester-ether in an amount of about 20 to about 40 wt.-%.

5. The composition of any one of claims 1 to 4, wherein the copolyester-ether comprises a polyethylene terephthalate (co)polyester segment.

6. The composition of any one of claims 1 to 5, wherein the HALS is a monomeric HALS, preferably having a molecular weight of 400 g/mol or above.

7. The composition of any one of claims 1 to 5, wherein the HALS is an oligomeric or polymeric HALS.

8. The composition of any one of claims 1 to 7, wherein transition metal-based oxidation catalyst is a cobalt compound.

9. A masterbatch for use in preparing an article, preform or container comprising:

a) copolyester-ether,
wherein the copolyester-ether comprises one or more polyester segments and one or more polyether segments, wherein the one or more polyether segments are present in an amount of about 5 to about 95 wt.-% of the copolyester-ether; and

b) a monomeric, oligomeric or polymeric hindered amine light stabilizer (HALS) in an amount of 100 - 30,000 ppm, on basis of the weight of the stabilizer in the total composition, wherein the HALS is represented by the formula (I) or a mixture of compounds of formula (I),

wherein each R₁ independently represents C₁-C₄ alkyl, R₂ represents H, C₁-C₄ alkyl, OH, O-C₁-C₄ alkyl, or a further part of an oligomeric or polymeric HALS, and R₃ represents a further part of a monomeric, oligomeric or polymeric HALS.

10. The masterbatch of claim 9, wherein the polyether segment is a linear or branched poly (C₂-C₆-alkylene glycol) segment.

11. The masterbatch of claim 9 or 10, wherein the polyether segment has a number-average molecular weight from 200 to about 5000 g/mol, preferably about 600 to about 2500 g/mol.

12. The masterbatch of any one of claims 9 to 10, wherein the polyether segments are present in the copolyester-ether in an amount of about 20 to about 40 wt.-%.

13. The masterbatch of any one of claims 9 to 12, wherein the copolyester-ether comprises a polyethylene terephthalate (co)polyester segment.

14. The masterbatch of any one of claims 9 to 13, wherein the HALS is a monomeric HALS, preferably having a molecular weight of 400 g/mol or above.

15. The masterbatch of any one of claims 9 to 13, wherein the HALS is an oligomeric or polymeric HALS.