Field of the invention
[0001] The present invention relates to a method and system for re-liquefying boil-off gas
by processing a stream of hydrocarbon gas, a stream of cryogenic fluid, and a stream
of boil-off gas. More particularly, the present invention relates to controlling the
flow rate of the stream of cryogenic fluid based in part on the flow rates of the
streams of hydrocarbon gas and boil-off gas.
Background of the invention
[0002] Natural gas is a key source of energy for the world economy; it is estimated that
natural gas supplies approximately one-fifth of global energy needs. This compares
to one-third and one-quarter for oil and coal respectively. As is generally the case
with bulk energy commodities, natural gas reserves do not lie near the major areas
of demand, and so natural gas must be transported and traded internationally. Approximately
30% of natural gas produced globally is traded on the world market.
[0003] The two principal methods for transporting natural gas are: a) transporting in gaseous
form in pipelines; and b) transporting in liquid form as liquefied natural gas (LNG)
in transport vessels.
[0004] To transport natural gas in liquid form as LNG, the gas must be liquefied (i.e. changed
from a gaseous state to a liquid state). The liquefaction of LNG is an energy intensive
process and so is more economical for long distance transport; in particular across
oceans. As a result, LNG accounts for nearly three-quarters of long-distance natural
gas trade. Due to the energy required for its liquefaction, LNG contains a large quantity
of embodied cold energy which is released when it is re-gasified (i.e. changed from
its liquid state following liquefaction back into its gaseous state).
[0005] The use of LNG in recent years has risen significantly as a share of both gas production
and trade. Global LNG trade has more than doubled since 2000, while pipeline trade
has risen by only around one-third.
[0006] In the Atlantic natural gas market, pipeline trade and local gas production have
a dominant market share, which tends to favour inter-basin trading; particularly in
the UK where LNG import terminals have seen a downturn in utilisation over the past
few years, with cargoes being diverted to the Asia-Pacific in search of higher prices.
In such a competitive market, the flexibility and efficiency of LNG import terminals
is particularly important. The owners of LNG infrastructure such as LNG import terminals
therefore seek further improvements in handling, storage and re-gasification of LNG.
[0007] LNG import terminals typically receive LNG from a transport vessel, such as a specially
designed cargo ship, and pump it into large capacity low-pressure storage tanks, where
it is stored at cryogenic temperatures (around -163 °C). When market conditions are
favourable, LNG is pumped to high pressure, warmed and vaporised before being exported
on the gas network. The export rate, or nomination, is highly dependent on gas price.
[0008] In recent years, the UK LNG market has experienced volatile gas prices, leading to
fluctuating export and significant periods of zero export nomination from LNG terminals.
Figure 6 shows an example profile of a year's send-out from an LNG terminal. These
conditions require a liquefaction plant to be as flexible and efficient as possible
to enable operators to have maximum control over when and how much LNG is exported,
whilst maximising storage capacity and longevity.
[0009] In any thermal process, efficiency losses occur when heat is allowed to flow in to
or out of the process. Due to the low temperatures involved in cryogenic systems,
a significant source of uncontrolled heat is the ambient environment. This heat may
enter the system through pipe and vessel walls. In an LNG infrastructure the ingress
of heat results in the loss of LNG through evaporation. This is commonly known in
the industry as boil-off and the resulting vapour phase as boil-off gas (BOG).
[0010] It is widely understood that over long periods, a significant proportion of LNG may
be lost through boil-off. In a well-insulated LNG tank, a typical boil-off rate may
be 0.05% of the volume per day. However, this rate may increase up to 3 times or more
depending on the design and operational requirements of the plant. The boil-off rate
may be even higher during transients such as unloading of an LNG cargo.
[0011] Furthermore, LNG is a multi-component fluid (typically composed of methane, ethane,
nitrogen, propane and butane) and it is widely understood that during the storage
and handling of such multi-component cryogenic fluids, boil-off may result in a change
in their component concentration. This is the result of the different volatilities
of the component fluids. Heat ingress will cause the components to evaporate at different
rates. The more volatile components (with lower saturation temperatures for a fixed
pressure) will tend to evaporate first and the liquid phase will therefore become
more concentrated in the less volatile components. This represents an additional problem
as strict regional standards for natural gas composition must be respected. Over time,
evaporation leads to a costly degradation of the LNG stock. The ratio of the calorific
value and the density of the gas (the Wobbe index) must subsequently be controlled
by the reinjection of LNG components, typically propane and nitrogen.
[0012] It is therefore of critical importance to carefully manage LNG stocks to minimise
losses through boil-off.
[0013] The higher the rate of heat flow into the process the faster the rate of boil-off.
In an LNG infrastructure, the rate of heat flow is minimised primarily by insulating
the infrastructure from the surrounding ambient environment. For example, a typical
LNG tank is well insulated in order to minimise the ingress of heat. Although particular
to the infrastructure design and operation, further limitation of boil-off may typically
be achieved through management of tank levels, optimised timing of deliveries, and
cooling of key systems.
[0014] For example, during unloading of LNG to an import terminal, the transfer of heat
from warm pipework to the incoming LNG causes the boil-off rate to increase. This
may result in a peak in the rate of boil-off. Often it is preferable to maintain the
pipework at cryogenic temperatures by active cooling. This allows the plant to remain
in a state of readiness, improving reactivity. This may be achieved most effectively
by continuously running LNG through the pipelines. This represents a trade-off, inducing
a higher continuous boil-off rate in order to maintain the pipework at operational
temperature.
[0015] It is widely appreciated that boil-off cannot be completely eliminated. However,
the loss of LNG stock through boil-off may be eliminated by re-liquefying the boil-off
gas and returning it to storage in its liquid form. The full volume of LNG is thus
retained and the degradation of the LNG composition is avoided, thus increasing the
longevity of the stock. Re-liquefaction is achieved by compressing, cooling and in
some cases expanding the boil-off gas. Typically, cooling is achieved using closed-loop
refrigeration cycles with a refrigerant fluid. Sometimes the boil-off gas may be employed
as a refrigerant fluid by returning a portion of cooled or re-liquefied boil-off gas
to the system to perform cooling. The process of re-liquefaction is energy intensive
and represents a high operating cost.
[0016] Where re-liquefaction is too costly, all or a portion of the boil-off gas may be
utilised to offset the operating costs of the plant. Examples include extracting useful
heat or work from combustion. The benefits of this solution vary according to market
conditions as the boil-off gas used in this way is diverted from the gas market. In
some cases there may not be sufficient energy requirement in the plant and it is often
more cost effective to import energy from external sources.
[0017] Boil-off gas may alternatively be sent out on the local or regional gas network,
but compressing the gaseous boil-off gas to the required pressure for the network
is costly. To reduce energy requirements the boil-off gas is often condensed into
a stream of supercooled LNG. The resulting liquid may be pumped to higher pressure
and gasified to achieve the required network pressure. Alternatively, the boil-off
gas may be re-liquefied in heat exchange with a stream of LNG before being mixed in
its liquid phase. In any case, since boil-off gas is richer in the more volatile components
of LNG, mixing with LNG allows the criteria for gas composition to be respected. However,
during this process, up to two units or more of re-gasified LNG must be added to one
unit of boil-off gas. This often results in a minimum rate of continuous export that
is considerably greater than the actual boil-off rate. This minimum send-out rate
limits the flexibility of the plant to respond to market conditions. Moreover, since
the export of LNG is required for this process, continuous operation of the re-gasification
plant is necessary.
[0018] The advantages of boil-off gas re-liquefaction are evident. Re-liquefaction represents
a means of addressing both the loss of LNG over time through boil-off and the degradation
of the LNG stock. The operator is afforded maximum control over when and how much
gas is exported; crucially, the operator is not required to export gas during unfavourable
market conditions.
[0019] However, the operating costs of re-liquefaction processes are usually prohibitive,
especially in large infrastructures with large amounts of pipework, where high levels
of boil-off occur, and where active cooling is employed. These operating costs arise
from the work required by the process, which is generally provided by electric motors.
[0020] A re-liquefaction process requires the input of work to compress the working fluid.
The fluid is then cooled by a cold source. Those skilled in the art will recognise
that the quantity of work required to achieve the required cooling is dependent on
the temperature of the cold source. Where the cold source is at ambient temperature,
a greater quantity of work is required. Where the cold source is below ambient temperature,
for example at cryogenic temperature, the quantity of work required is greatly reduced.
[0021] One source of cold in an LNG import terminal is the re-gasification of LNG, which
is heated from approximately -163°C to near-ambient temperature. The cold recovered
from this process is often dissipated as waste. However, if this cold is recovered
and recycled in a liquefaction process, the electrical consumption of the process
may be reduced by as much as two thirds. This approach has been adopted in the design
of nitrogen liquefiers and air separation plants integrated into LNG infrastructure,
a number of which are in operation in Japan and Korea.
[0022] US 4329842 describes a system for utilising cold energy from regasification of LNG at an LNG
vaporising plant. LNG is taken from an LNG source ship and passed through to a pipeline
via a liquid air generating plant where it is used generate liquid air for subsequent
use in a power generation system.
[0023] However, it has been established that the re-liquefaction of boil-off gas is of primary
importance during unfavourable market conditions, at a time when the cold from re-gasification
of LNG is not available. This "anti-phase" between the requirement for and the availability
of cold has hitherto prevented the cold from LNG re-gasification being used to re-liquefy
boil-off gas during such periods.
[0024] US 3400547 discloses a process for utilising a cryogenic fluid to facilitate generation and
transport of LNG. Cold energy from evaporation of LNG at a market site Is used to
liquefy nitrogen, which is transported to the field. Here, cold energy from the liquefied
nitrogen is used to liquefy natural gas to form LNG, which is transported back to
the market site.
[0025] US2007/0186563 discloses a method of cold recovery in a cold compressed natural gas cycle. Cold
energy from cold compressed natural gas in a cavern is used to liquefy air for storage,
with the resulting natural gas being distributed via pipeline. Natural gas may be
drawn from the pipeline, cooled using cold energy form the liquefied air, and stored
in the cavern.
[0026] Neither of these documents offers a solution to the problems described above of how
to deal efficiently with the problem of boil-off. Accordingly, an improved method
and system is required for liquefying boil-off gas which overcomes the above-mentioned
problems.
[0027] US 3768271 B discloses a method and plant for storing and transporting a liquefied combustible
gas.
[0028] JP 2002 295799 A discloses an LNG storage tank and a liquid nitrogen tank connected to an air separator.
Liquid nitrogen of an appropriate quantity is pumped to a heat exchanger for generating
gaseous nitrogen from the liquid nitrogen tank while reliquefying BOG from the LNG
storage tank. At the same time, gaseous nitrogen boil-off gas is liquefied by gasifying
LNG from the storage tank.
Summary of the invention
[0029] The invention is defined by the appended claims.
[0030] A method for liquefying boil-off gas according to the invention is disclosed in claim
1.
[0031] By performing the steps of the method according to the invention, an improved method
of re-liquefying boil-off gas is achieved through effective recovery, storage and
recycling at a later time of the cold energy released during re-gasification of a
hydrocarbon gas. In some circumstances, the energy required to re-liquefy boil-off
gas using the method of the invention may be more than halved compared with conventional
methods. The energy requirements for the method of the invention are low enough to
be implemented in existing hydrocarbon gas infrastructure. Thus, the method provides
a cost-effective technique which improves flexibility of managing the export of hydrocarbon
gas according to market conditions; increases the longevity of storage; and effectively
increases the storage volume of the hydrocarbon gas tanks by ensuring hydrocarbon
gas used in continuous cooling is not lost. It is particularly advantageous in that
it reduces the work required for the re-liquefaction of boil-off gas by the recycling
of cold available on site that would otherwise be unavailable when required.
[0032] A particular advantage of the present invention is that cold from the re-gasification
of hydrocarbon gas may be recovered, stored and utilised in a process for the re-liquefaction
of boil-off gas independently of the rate and time of cold recovery.
[0033] In particular, by storing a liquefied cryogenic fluid in a fluid store, and by controlling
the flow rate of the cryogenic fluid into and out of the store, it is possible to
make use of cold recovered from regasification of the liquefied hydrocarbon gas whilst
that process is taking place; store the recovered cold in the fluid store; and utilise
it when required to re-liquefy boil-off gas. The steps of storing and controlling
the cryogenic fluid enable energy to be transferred between two processes even if
those processes are not taking place at the same time.
[0034] The present invention is particularly useful at LNG import terminals and any other
LNG storage infrastructure with a regasification plant, where the cold from re-gasification
of LNG may be recovered and utilised for the re-liquefaction of boil-off gas. However,
it would also be applicable to boil-off from other high volume cryogenic storage systems
where the cold from regasification is periodically available.
[0035] It should be noted that, for convenience, the description and claims refer to the
cryogenic fluid, boil-off gas and hydrocarbon gas in their gaseous and liquefied forms.
It should be understood that in each case, the same fluid is being referred to albeit
in a different phase. For instance, the invention mentions a liquefied cryogenic fluid.
It will be understood that this is the liquefied state of the stream of gaseous cryogenic
fluid which is also mentioned.
[0036] It should also be noted that, for consistency of nomenclature, the cryogenic fluid
is described as such in both its gaseous and liquefied forms irrespective of the temperature
of the fluid. Hence, in certain circumstances the gaseous cryogenic fluid may be at
near-ambient or above ambient temperatures. Regardless, it is referred to in this
application as a cryogenic fluid because it is utilised to transfer heat to and from
fluids at cryogenic temperatures.
[0037] Finally, whilst it is appreciated that 'cold' is merely the absence of energy, rather
than a form of energy itself, it is convenient to use the expression 'cold energy'
in a discussion of energy transfer in a cryogenic energy system because it is typically
cold temperatures which are sought to be preserved and ingress of heat energy which
is sought to be excluded. The skilled reader will appreciate that in this sense, 'cold
energy' is a convenient fiction for describing this technology and is analogous to
the transfer and preservation of heat energy in non-cryogenic systems.
[0038] The method may further comprise the step of processing the stream of gaseous boil-off
gas and the stream of liquefied hydrocarbon gas from the liquefied hydrocarbon gas
store such that:
- a) the stream of liquefied hydrocarbon gas undergoes a phase change from a liquefied
hydrocarbon gas to a gaseous hydrocarbon gas; and
- b) the stream of gaseous boil-off gas undergoes a phase change from a gaseous boil-off
gas to a liquefied boil-off gas;
wherein the step of processing comprises transferring heat from the stream of gaseous
boil-off gas to the stream of liquefied hydrocarbon gas from the liquefied hydrocarbon
gas store.
[0039] This method is advantageous because it permits the boil-off gas to be re-liquefied
whilst regasification of the liquefied hydrocarbon gas is taking place, as well as
at a later time using the cold stored in the cryogenic fluid. This further improves
the efficiency of the process because cold energy from regasification can be used
to cool boil-off gas directly, whereas cooling using the cryogenic fluid may be reserved
for when regasification is not taking place.
[0040] In the case mentioned above, the steps of: a) transferring heat from the stream of
gaseous cryogenic fluid to the stream of liquefied hydrocarbon gas from the liquefied
hydrocarbon gas store; and b) transferring heat from the stream of gaseous boil-off
gas to the stream of liquefied hydrocarbon gas from the liquefied hydrocarbon gas
store; may be concurrent.
[0041] When the steps are concurrent, the cold energy from regasification is used to re-liquefy
boil-off gas and cool and liquefy the cryogenic fluid for later use. This may be particularly
preferable if there is a plentiful supply of cryogenic fluid; stocks of liquefied
cryogenic fluid in the store are low; and/or a long delay is expected until the next
regasification of hydrocarbon gas.
[0042] The step of processing the stream of gaseous cryogenic fluid and the stream of liquefied
hydrocarbon gas may further comprise one or both of the steps of: expanding the stream
of gaseous cryogenic fluid after heat transfer; and compressing the stream of gaseous
cryogenic fluid prior to heat transfer. The stream of gaseous cryogenic fluid may
be compressed to a supercritical pressure.
[0043] In certain circumstances, the transfer of heat itself is sufficient to effect the
change of phase from liquid to gas and vice versa. In these circumstances one fluid
will enter a heat exchange (for example) in the liquid phase and exit in the gaseous
phase whilst the other will enter the heat exchange in the gaseous phase and exit
in the liquid phase. However, in practice this is not always possible or convenient,
and the process is made more efficient by one or both of compressing and expanding
one or more of the fluids before and after heat transfer. In the present case it has
been found advantageous to expand the gaseous cryogenic fluid after heat transfer
to achieve liquefaction and compress the gaseous cryogenic fluid before heat transfer.
[0044] The method may further comprise the steps of passing the stream of liquefied hydrocarbon
gas through first and second branches. In that case, the step of transferring heat
from the stream of gaseous cryogenic fluid to the stream of liquefied hydrocarbon
gas from the liquefied hydrocarbon gas store may further comprise:
transferring heat to a stream of liquefied hydrocarbon gas in the first branch from
the stream of gaseous cryogenic fluid prior to compression; and
transferring heat to a stream of liquefied hydrocarbon gas in the second branch from
the stream of gaseous cryogenic fluid after compression.
[0045] Preferably, the method further comprises combining the streams of gaseous hydrocarbon
gas in the first and second branches.
[0046] Passing the stream through first and second branches enables the cold energy transferred
from the liquefied hydrocarbon gas to be used in more than one place. In particular,
it is advantageous for the gaseous cryogenic gas to undergo initial cooling, prior
to compression for example, and then to undergo subsequent cooling to liquefy the
cryogenic gas. By providing first and second streams of liquefied hydrocarbon gas,
both stages of cooling can be achieved by the cold energy from the regasification
process.
[0047] It will be understood that hydrocarbon gas finds many uses in commercial and residential
properties, as well as in industry and the plants themselves. Preferably, the method
further comprises the step of delivering the stream of gaseous hydrocarbon gas to
a recipient such as one or more of: a hydrocarbon pipe network; a power station; and
a consumer of gaseous hydrocarbon gas.
[0048] Preferably, the method further comprises the step of collecting the stream of gaseous
boil-off gas, such as by collecting the boil-off gas from the liquefied hydrocarbon
gas store and/or collecting the boil-off gas from a store, conduit, or collection
point coupled to the liquefied hydrocarbon gas store. Boil-off can occur wherever
liquefied hydrocarbon gas is present and at risk of being warmed through insufficient
insulation. The skilled person is familiar with methods for collecting this boil-off
from all over an infrastructure, wherever it occurs - even very far from the tank
- and thus efficiencies can be increased.
[0049] The step of transferring heat from the stream of gaseous cryogenic fluid to the stream
of liquefied hydrocarbon gas from the hydrocarbon gas store may be direct, or it may
comprise transferring heat from the stream of gaseous cryogenic fluid to a heat transfer
fluid in a closed-loop refrigeration circuit and cooling the gaseous cryogenic fluid
to a temperature below the saturation temperature of the liquefied hydrocarbon gas;
and transferring heat from the heat transfer fluid in the closed-loop refrigeration
circuit to the stream of liquefied hydrocarbon gas.
[0050] Heat transfer takes place indirectly via one or more refrigeration circuits (or equivalent),
wherein cold from a source stream is passed to one or more intermediate streams of
heat transfer fluid before reaching Its destination stream. In the method according
to the invention, cold from the stream of liquefied hydrocarbon gas (i.e. the source
stream) is passed to a closed-loop refrigeration circuit before reaching the stream
of gaseous cryogenic fluid (i.e. the destination stream). The closed-loop refrigeration
circuit may also involve expanding and compressing the heat transfer fluid to obtain
the required temperatures.
[0051] In cases where heat from the stream of gaseous boil-off gas is transferred to the
stream of liquefied hydrocarbon gas from the liquefied hydrocarbon gas store, the
step of transferring heat from the stream of gaseous boil-off gas to the stream of
liquefied hydrocarbon gas from the liquefied hydrocarbon gas store may further comprise:
transferring heat from the stream of gaseous boil-off gas to the heat transfer fluid
in the closed-loop refrigeration circuit; and
transferring heat from the heat transfer fluid in the closed-loop refrigeration circuit
to the stream of liquefied hydrocarbon gas.
[0052] It will be appreciated that the destination stream for the cold energy which passes
from the source stream through the one or more intermediate streams may be more than
one stream. In the preferred example, cold energy is transferred not only to the stream
of gaseous cryogenic gas, but also to the stream of gaseous boil-off gas.
[0053] Preferably, the method further comprises processing a stream of ambient air to form
the stream of gaseous cryogenic fluid. This may involve, for example, filtering the
stream of ambient air to remove moisture, carbon dioxide and/or hydrocarbons; and/or
compressing the stream of ambient air. Air is particularly advantageous due to its
abundance. This permits a readily available supply of gaseous cryogenic fluid for
use on demand.
[0054] Preferably, the method further comprises passing the stream of liquefied cryogenic
fluid through a separator prior to it entering the liquefied cryogenic fluid tank
to separate any residual vapour phase from the stream of liquefied cryogenic fluid,
and returning the residual vapour phase to the stream of gaseous cryogenic fluid.
[0055] It will be appreciated that cryogenic fluid may suffer boil-off within the infrastructure
itself, in particular before the liquefied cryogenic fluid enters the store. Moreover,
the liquefaction of cryogenic fluid may not be 100% efficient, and there may be cryogenic
fluid in the vapour or gas phase even after the stream has been processed. In these
circumstances, separating the vapour or gas phase and returning it to the gaseous
stream of cryogenic fluid is particularly advantageous because the efficiency of the
liquefaction process is improved.
[0056] Preferably, the method further comprises pumping the stream of liquefied cryogenic
fluid from the liquefied cryogenic fluid store to increase its pressure prior to the
step of transferring heat from the stream of gaseous boil-off gas to the stream of
liquefied cryogenic fluid from the liquefied cryogenic fluid store.
[0057] Preferably, the step of transferring heat from the stream of gaseous boil-off gas
to the stream of liquefied cryogenic fluid from the liquefied cryogenic fluid store
results in a second stream of gaseous cryogenic fluid. In that case, the method may
further comprise the step of expanding the second stream of gaseous cryogenic fluid
to extract work from the stream.
[0058] The step of expanding the second stream of gaseous cryogenic fluid to extract work
from the second stream may be performed in a single-stage expansion device, a two-stage
expansion device, or a multi-stage expansion device.
[0059] Preferably the method further comprises super-heating the second stream of gaseous
cryogenic fluid prior to one or more stages of expansion. The heat source for super-heating
the cryogenic fluid may be ambient air. It may otherwise be any heat source from a
co-located process with a temperature of up to 500°C, for instance.
[0060] Preferably the method further comprises the step of converting the work extracted
from the second stream into electricity.
[0061] By extracting work from the gaseous cryogenic fluid used to re-liquefy the boil-off
gas, the work required by the process (such as the work done in compressing the gaseous
cryogenic fluid and/or pumping the liquefied cryogenic fluid) may be offset. Steps
of increasing the pressure of the liquefied cryogenic fluid, and expanding and superheating
the cryogenic fluid increase the efficiency by which work may be extracted from the
stream. This work may be converted to electricity using an electric generator.
[0062] A system for liquefying boil-off gas according to the Invention is disclosed in claim
2.
[0063] Most of the advantages associated with a system according to the present invention
have already been described above in connection with the method according to the invention.
Hence, for conciseness, they are not repeated here.
[0064] The first and second arrangements of conduits may be arranged such that heat is transferred
from the stream of gaseous boil-off gas passing through the second arrangement of
conduits to the stream of liquefied hydrocarbon gas passing through the first arrangement
of conduits.
[0065] The third arrangement of conduits may comprise a compressor for compressing the stream
of gaseous cryogenic fluid. In that case, the first arrangement of conduits may comprise
a first branch and a second branch. The first branch is preferably arranged such that
heat is transferred to a stream of liquefied hydrocarbon gas passing through the first
branch from the stream of gaseous cryogenic fluid passing through the third arrangement
of conduits at a first heat exchange region upstream of the compressor. The second
branch is preferably arranged such that heat is transferred to a stream of liquefied
hydrocarbon gas passing through the second branch from a stream of gaseous cryogenic
fluid passing through the third arrangement of conduits at a second heat exchange
region downstream of the compressor.
[0066] The first and second branches may bifurcate from a single conduit upstream of the
first and second heat exchange regions, and recombine to a single conduit downstream
of the first and second heat exchange regions.
[0067] The source of boil-off gas may be the first store, and/or a store, conduit, or collection
point coupled to the first store.
[0068] The first and third arrangements of conduits are arranged such that heat is transferred
between the first and third arrangements of conduits via a closed-loop refrigeration
circuit comprising a heat transfer fluid passing through a fifth arrangement of conduits.
According to the invention, the fifth and third arrangements of conduits are arranged
such that heat is transferred from the stream of gaseous cryogenic fluid passing through
the third arrangement of conduits to the heat transfer fluid passing through the fifth
arrangement of conduits. The fifth and first arrangements of conduits are arranged
such that heat is transferred from the heat transfer fluid passing through the fifth
arrangement of conduits to the stream of liquefied hydrocarbon gas passing through
the first arrangement of conduits.
[0069] If the first and second arrangements of conduits are arranged such that heat is transferred
from the stream of gaseous boil-off gas passing through the second arrangement of
conduits to the stream of liquefied hydrocarbon gas passing through the first arrangement
of conduits, then the first and second arrangements of conduits may also be arranged
such that heat is transferred between the first and second arrangements of conduits
via the closed-loop refrigeration circuit. In that case, the fifth and second arrangements
of conduits may be arranged such that heat is transferred from the stream of gaseous
boil-off gas passing through the second arrangement of conduits to the heat transfer
fluid passing through the fifth arrangement of conduits.
[0070] If the first arrangement of conduits comprises first and second branches, then the
second branch may be arranged such that heat is transferred from the heat transfer
fluid passing through the fifth arrangement of conduits to the stream of liquefied
hydrocarbon gas passing through the second branch.
[0071] Preferably, the stream of gaseous cryogenic fluid air, and the third arrangement
of conduits further comprises one or both of: a filtration system for removing moisture,
carbon dioxide and/or hydrocarbons from a stream of ambient air; and a compressor
for compressing a stream of ambient air.
[0072] The third arrangement of conduits may further comprise a separator upstream of the
second store for extracting any residual vapour phase from the stream of liquefied
cryogenic fluid passing through the third arrangement of conduits prior to entering
the second store, and a return conduit arranged to direct the residual vapour phase
extracted from the stream of liquefied cryogenic fluid to the stream of gaseous cryogenic
fluid passing through the third arrangement of conduits.
[0073] Preferably, the second and fourth arrangements of conduits are arranged such that
heat is transferred between the second and fourth arrangements of conduits at a third
heat exchange region and the fourth arrangement of conduits further comprises a pump
upstream of the third heat exchange region for pumping the stream of liquefied cryogenic
fluid passing through the fourth arrangement of conduits prior to it passing through
the third heat exchange region.
[0074] Preferably, the third heat exchange region is configured such that heat is transferred
from the stream of gaseous boil-off gas passing through the second arrangement of
conduits to the stream of liquefied cryogenic fluid passing through the fourth arrangement
of conduits to produce a second stream of gaseous cryogenic fluid. In that case, the
fourth arrangement of conduits further comprises an expansion device for expanding
the second stream of gaseous cryogenic fluid and extracting work from the second stream
of cryogenic fluid.
[0075] The expansion device may be a single-stage expansion device, a two-stage expansion
device, or a multi-stage expansion device.
[0076] Preferably, the fourth arrangement of conduits is coupled to one or more super-heaters,
wherein each super-heater is either upstream of the first stage of the expansion device
or between stages of the expansion device. In one example, if the expansion device
has three expansion stages, and the fluid passing through is superheated before passing
through each stage, then the system will comprise a first superheater upstream of
the first stage, a second superheater between the first and second stages, and a third
superheater between the second and third stages. In this context, the terms 'upstream'
and 'between' do not preclude the possibility of there being other components (valves,
an suchlike) between a superheater and a respective stage. It will be appreciated
that not every stage need have a corresponding superheater. For a given arrangement
in an expansion device, any number of superheaters may be provided in any arrangement
appropriate for the circumstances.
[0077] In a preferred embodiment, the first, second, third and fourth arrangements of conduits
are arranged such that heat is transferred between the first and third arrangements
of conduits, between the second and fourth arrangements of conduits, at a single heat
exchange region.
[0078] It will be appreciated that further efficiencies, both in terms of heat transfer
as well as space, may be achieved by providing a single heat exchange region to for
effecting more than one transfer of heat between two different streams. The heat exchange
region may be provided by a single heat exchange (i.e. such that heat transfer is
effected directly), or by a plurality of heat exchangers .i.e. such that heat transfer
is effected via the aforementioned closed-loop refrigeration circuit.
[0079] More preferably, the first, second, third and fourth arrangements of conduits are
arranged such that heat is transferred between the first and second arrangements of
conduits at the single heat exchange region.
[0080] The closed-loop refrigeration circuit mentioned above may operate using one of a
single-phase Brayton cycle and a dual-phase Rankine cycle.
[0081] The heat transfer fluid may be any fluid with the appropriate thermo-dynamic properties
with respect to the saturation temperatures of the hydrocarbon gas and the cryogenic
fluid. For example, nitrogen or propane may be used, both of which are typically available
at a hydrocarbon gas terminal.
[0082] The cryogenic fluid mentioned above may be one of nitrogen or air, preferably ambient
air. Nitrogen is typically available at a hydrocarbon gas terminal and requires minimal
processing before it can be used, whereas air is abundant.
[0083] Finally, it should be noted that the liquefied hydrocarbon gas mentioned herein is
preferably Liquefied Natural Gas (LNG). LNG is the predominant kind of hydrocarbon
gas in current supply, and therefore the present invention finds particular utility
with LNG. However, the present invention may be implemented with any hydrocarbon gas
wherein the re-liquefaction of boil-off in any application where a hydrocarbon which
is normally in its gaseous phase under ambient conditions is stored as a cryogenic
liquid in large quantities and then re-gasified for use.
Brief description of the drawings
[0084] Preferred embodiments of the invention will now be described with reference to the
accompanying drawings, in which:
figure 1 is a diagram of a system according to a first embodiment of the invention;
figure 2 is a diagram of a system according to a second embodiment of the invention;
figure 3 is a diagram of a system according to a third embodiment of the invention;
figure 4 is a diagram of a system according to a fourth embodiment of the invention;
figure 5 is a diagram of a system according to a fifth embodiment of the invention;
and
figure 6 is a graph depicting an example of the gas send-out of an LNG terminal over
a year.
Detailed description of the invention
[0085] The present inventors have previously disclosed, in patent application number
WO200709665, a cryogenic energy storage system which stores energy using a cryogenic fluid. The
present inventors have also described, in UK patent application number
1305640.3, an efficient method of cooling within an air liquefaction processes using cold recovery
from adjacent LNG re-gasification process. Both of these disclosures are helpful,
but not necessary, for putting the present invention into practice.
[0086] A first embodiment of the present invention uses a cryogenic fluid, such as liquid
air or liquid nitrogen, to store the cold from the re-gasification of LNG. A system
diagram of the first embodiment is presented in figure 1.
[0087] During re-gasification, the LNG is pumped to high pressure and split into two streams,
whereby the first stream is warmed and vaporised in heat exchange with the cryogenic
fluid in its gaseous phase; and the second stream is warmed and vaporised in heat
exchange with a refrigerant, typically nitrogen, in a closed-loop refrigeration cycle.
[0088] The two, now gaseous, streams are then merged into a single stream of gaseous natural
gas for export. The re-gasified natural gas is sent, as known in the art, to a recipient,
which may form part of the LNG infrastructure or be an external infrastructure or
customer. Examples include, but are not limited to: a gas sendout station, a pipe
network, a power station, and a bottling plant. The stream may be split and sent to
multiple recipients.
[0089] For this process, the cryogenic fluid is supplied in its gaseous form at near ambient
temperature and is pre-cooled in heat exchange with the first stream of LNG; compressed
using a compressor to supercritical pressure; sub-cooled in heat exchange with the
refrigerant in the closed-loop refrigeration cycle; and expanded, whereby it condenses
to form a cryogenic liquid.
[0090] The closed-loop refrigeration cycle is used to cool the cryogenic fluid to a temperature
below the saturation temperature of LNG. The closed-loop system may be a single-phase
Brayton cycle wherein the heat transfer fluid is compressed with a compressor; cooled
in counter-flow heat exchange with the second stream of LNG; expanded in an expander;
and warmed in heat exchange with the pre-cooled, compressed gaseous phase cryogenic
fluid.
[0091] During export of LNG, the present invention uses some of the cold produced by re-gasification
of the LNG to re-liquefy boil-off gas. The boil-off gas is compressed with a compressor;
and cooled in counter-flow heat exchange with the refrigerant in the closed-loop refrigeration
cycle, whereby its condenses into liquid phase.
[0092] During times of zero export of LNG (i.e. when no LNG is exported on the network),
the present invention uses the cold stored in the cryogenic fluid to re-liquefy boil-off
gas. Thus, the boil-off gas is compressed using a compressor; and cooled in heat exchange
with the cryogenic fluid such that it becomes liquid.
[0093] The warmed cryogenic fluid is thus vaporised, super-heated; and expanded isentropically
through one or multiple turbo-expansion stages, thus producing work.
[0094] During times of low export of LNG, the present invention may use both the cold from
the re-gasification of LNG and the cold stored in the cryogenic fluid to re-liquefy
boil-off gas.
[0095] The system is able to operate flexibly, at different operating points, by altering
the flow of boil-off gas (e.g. by changing the flow rate and/or by redirecting the
boil-off gas as described below) and by adjusting the duty of the nitrogen and boil-off
gas compressors accordingly.
[0096] A cryogenic store (e.g. storage tank) is provided for storing the cryogenic fluid,
allowing the flow of cryogenic fluid in and the flow of cryogenic fluid out to be
controlled independently. Thus, the heat transfer rate between the cryogenic fluid
and the LNG, and the heat transfer rate between the boil-off gas and the cryogenic
fluid from the cryogenic storage tank, may be independently and dynamically controlled
by varying the flow rate of the cryogenic fluid into and the flow rate of the cryogenic
fluid out of the cryogenic storage tank respectively. The re-gasification of LNG and
the re-liquefaction of boil-off gas may therefore occur independently at different
times and at different rates.
[0097] As a skilled person will recognise, the larger the volume of the cryogenic storage
tank, the longer the period that boil-off gas may be re-liquefied during times of
low, or zero, LNG send-out.
[0098] The flow rates may be controlled in response to both current, real time operational
parameters and future predicted operational parameters in order to optimise the management
of the LNG stock in the LNG tank. Operational parameters include, for example, one
or more of demand for LNG, availability of LNG or cryogenic fluid, and rate of boil-off
[0099] In one example, the flow rate of liquid cryogenic fluid out of the cryogenic storage
tank may be controlled as a function of the measured flow of boil-off gas. Alternatively,
if the period of low, or zero, LNG sendout is predicted to be short, it may be preferential
to economise the stock of liquid cryogenic fluid in the cryogenic storage tank and
allow boil-off gas to accumulate within the pressure limits of the LNG tank.
[0100] In another example, the flow-rate of gaseous cryogenic fluid may be controlled as
a function of the LNG sendout rate. Alternatively, it may be reduced as the cryogenic
storage tank approaches full capacity.
[0101] In one embodiment, during LNG send-out, boil-off gas may be mixed in its gaseous
phase with the gasified liquid natural gas rather than being re-liquefied.
[0102] Turning to the system diagram shown in Fig.1, the cold boil-off gas, which comes
from an LNG tank or a chamber, vessel, header or anywhere where boil-off gas is collected,
is withdrawn via conduit 1 by compressor 3. Boil-off gas is compressed into conduit
2 from the tank storage pressure, which normally is just above ambient pressure, to
between 1 and 10 bar, but more typically 3 to 6 bar. At times of high LNG send-out
rate no fraction of boil-off gas is diverted into conduit 42 but it is all conveyed
through conduit 4 and liquefied and sub-cooled In heat exchanger 5. Boil-off gas,
which is now in its liquid form, thus can be used as LNG, is then expanded through
an expansion device 7, and conveyed by pump 9 to an LNG tank 11 via conduit 10. Purely
for completeness, it will be appreciated that the method of independent claim 1 is
not performed if no heat is transferred from the stream of boil-off gas to the stream
of cryogenic fluid from the fluid store.
[0103] Nitrogen, in gaseous form, available at a pressure between 1 and 16 bar, but more
typically 6 to 9 bar, is withdrawn via conduit 12 and passed through heat exchanger
13 where it is cooled to near LNG storage temperature. Nitrogen is then compressed
by a single or multistage compressor 15 to a pressure between 50 and 70 bar, but more
typically 54 to 60 bar. Nitrogen, which is now above its supercritical pressure, is
cooled in heat exchanger 5 to between -155°C and -185°C, but more typically -165°C
and -175°C. Leaving the heat exchanger the nitrogen passes through conduit 21 and
then expands through the expansion device 22. The liquid fraction obtained from the
isenthalpic expansion, which in this embodiment is 100%, passes through conduit 23
to reach the liquid nitrogen storage tank 24.
[0104] Cooling to heat exchanger 5 is supplied by the refrigeration cycle shown between
heat exchangers 5 and 29, where a refrigerant gas, typically nitrogen, is compressed
by compressor 37 to between 4 bar and 16 bar, but more typically 7 bar to 10 bar,
fed to heat exchanger 29, wherein it is cooled by heat exchange with LNG to between
-161°C and - 140°C, but more typically -156°C. The cold refrigerant passes through
conduit 39 to reach the inlet of the expansion device 40, where the refrigerant is
expanded to between 1 bar and 7 bar, but more typically 2 to 4 bar. The refrigerant
passes through conduit 41 and is fed to heat exchanger 5 at a temperature between
-190°C and -170°C, more typically - 185°C.
[0105] Cooling to heat exchangers 29 and 13 is supplied by the LNG which is withdrawn from
the LNG tank 11 by the LNG pump 26, pumped to a pressure between 60bar and 150 bar,
more typically 80 bar and 120 bar. The high pressure LNG in conduit 27 is then split
in two streams. A proportion of the LNG flow is directed to heat exchanger 29 via
conduit 28 and the rest is sent to heat exchanger 13 via conduit 32. Conduit 30 and
33 are merged together to form conduit 34 and convey the LNG, which is now in gaseous
form, to the natural gas distribution network.
[0106] Similarly to any other commodity, LNG is subject to a volatile demand which means
that the send-out rate can vary between 0% and 100% of the maximum capacity of the
LNG re-gasification terminal. When the send-out rate is above a certain threshold
there is enough cold to liquefy the boil-off gas stream and the nitrogen stream. However
when the send-out rate drops below this threshold it is enough to turn down the nitrogen
compressor 15 to adjust the system to the new operating conditions. However the preferred
system can easily adjust to any level of send-out rate by completely stopping compressor
15 and, should the LNG send-out rate drop even further, diverting some of the compressed
boil-off gas to conduit 42. The boil-off gas is then conveyed to heat exchanger 43,
wherein it is cooled, liquefied and subcooled by heat exchange with liquid nitrogen.
Boil-off gas, which is now in its liquid form, is then expanded through an expansion
device 45, and conveyed by pump 47 to an LNG tank 11 via conduit 48.
[0107] The liquid nitrogen flow rate which passes through heat exchanger 43 is throttled
by control valve 50. The nitrogen emerges from heat exchanger 43 in conduit 52 in
its gaseous form. The nitrogen is then superheated in heat exchanger 53 to any temperature
up to 500°C and expanded through a turbine 55 to recover the energy. Depending by
the pressure and type of machine employed the expansion of the nitrogen stream can
be done in a single stage, two stages, as shown in Fig.1, or several stages with intermediate
heat exchangers for superheating the nitrogen.
[0108] Control of the system is achieved using any conventional controller which operates
to vary the duty of gaseous cryogenic fluid compressor 15 to control the flow rate
of the stream of gaseous cryogenic fluid; open and close valve 50 to control the flow
rate of the stream of liquefied cryogenic fluid from tank 24; and optionally vary
the duty of gaseous boil-off gas compressor 3 to control the flow rate of the stream
of gaseous boil-off gas. However, other means for controlling the flow rates of these
streams are possible and within the capabilities of a skilled person to implement
depending on particular circumstances.
[0109] A system diagram of a second embodiment of the invention is shown in Fig.2. The second
embodiment is identical to the first in every way, except that the cryogenic fluid
is air rather than nitrogen. Thus, conduit 12 no longer coveys gaseous nitrogen but
ambient air which has undergone a cleaning, scrubbing and drying process. Ambient
air is withdrawn through conduit 61, it undergoes a first stage of cleaning as it
passes through the air filter 62, compressed by compressor 64, sent to the air filtration
unit 66, where moisture, carbon dioxide and hydrocarbons are removed, before emerging
as clean and dry air in conduit 12.
[0110] A system diagram of a third embodiment of the invention is shown in Fig.3. The third
embodiment is identical to the first in every way, except that the liquid fraction
obtained from the isenthalpic expansion of the nitrogen is not 100%, resulting in
a vapour or gas phase of nitrogen existing immediately upstream of the nitrogen tank
24. Thus, in this embodiment, a separator 17 is added between the tank 24 and the
expansion device 22. The liquid and the vapour fraction obtained from the isenthalpic
expansion passes through conduit 23 to reach the separator 17, wherein the liquid
fraction is conveyed via conduit 18 to the nitrogen storage tank 24 and the vapour
fraction is conveyed via conduit 19 to heat exchanger 5. The nitrogen is warmed by
heat exchange with incoming warm nitrogen and boil-off gas in heat exchanger 5 and
then conveyed via conduit 20 back to the suction side of compressor 15 where it joins
the incoming nitrogen in conduit 12.
[0111] A system diagram of a fourth embodiment of the invention is shown in Fig.4. The fourth
embodiment is identical to the first in every way, except that a pump 35 is installed
downstream of the control valve to raise the pressure of the liquefied nitrogen from
the nitrogen tank to between 100 bar and 200 bar, but more typically 120 bar and 150
bar. The nitrogen emerges from heat exchanger 43 at high pressure and enters conduit
52 in its gaseous form. The nitrogen is then superheated in heat exchanger 53 to any
temperature up to 500°C and expanded through a turbine 55 to recover the energy. Depending
on the pressure and type of machine employed the expansion of the nitrogen stream
can be done in a single stage, two stages, as shown in Fig.4, or several stages with
intermediate heat exchangers for superheating the nitrogen. In this embodiment the
expansion turbines would be able to generate more power per unit mass of nitrogen
compared to the first embodiment of this invention but a higher flow rate of nitrogen
would be required to liquefy the same boil-off gas flow rate.
[0112] A system diagram of a fifth embodiment of the invention is shown in Fig.5. The fifth
embodiment is identical to the first in every way, except that heat exchanger 5 and
heat exchanger 43 from previous embodiments are replaced with a single heat exchanger
70. In this embodiment the system no longer needs a separate heat exchanger to liquefy
the boil-off gas when using liquid nitrogen.
1. A method for liquefying boil-off gas, comprising:
storing a liquefied hydrocarbon gas in a liquefied hydrocarbon gas store (11);
processing a stream of gaseous cryogenic fluid and a stream of liquefied hydrocarbon
gas from the liquefied hydrocarbon gas store (11), such that:
a) the stream of liquefied hydrocarbon gas undergoes a phase change from a liquefied
hydrocarbon gas to a gaseous hydrocarbon gas; and
b) the stream of gaseous cryogenic fluid undergoes a phase change from a gaseous cryogenic
fluid to a liquefied cryogenic fluid;
wherein the step of processing comprises transferring heat from the stream of gaseous
cryogenic fluid to the stream of liquefied hydrocarbon gas from the liquefied hydrocarbon
gas store (11);
storing the liquefied cryogenic fluid in a liquefied cryogenic fluid store (24);
processing a stream of gaseous boil-off gas and a stream of liquefied cryogenic fluid
from the liquefied cryogenic fluid store (24) such that:
a) the stream of liquefied cryogenic fluid undergoes a phase change from a liquefied
cryogenic fluid to a gaseous cryogenic fluid; and
b) the stream of gaseous boil-off gas undergoes a phase change from a gaseous boil-off
gas to a liquefied boil-off gas;
wherein the step of processing comprises transferring heat from the stream of gaseous
boil-off gas to the stream of liquefied cryogenic fluid from the liquefied cryogenic
fluid store (24);
storing the liquefied boil-off gas in the liquefied hydrocarbon gas store (11);
controlling the flow rate of the stream of gaseous cryogenic fluid based at least
in part on the flow rate of the stream of liquefied hydrocarbon gas from the liquefied
hydrocarbon gas store (11); and
independently controlling the flow rate of the stream of liquefied cryogenic fluid
from the liquefied cryogenic fluid store (24) based at least in part on the flow rate
of the stream of gaseous boil-off gas; the method characterised in that
the step of transferring heat from the stream of gaseous cryogenic fluid to the stream
of liquefied hydrocarbon gas from the hydrocarbon gas store (11) further comprises:
transferring heat from the stream of gaseous cryogenic fluid to a heat transfer fluid
in a closed-loop refrigeration circuit (37, 39, 40, 41) and cooling the gaseous cryogenic
fluid to a temperature below the saturation temperature of the liquefied hydrocarbon
gas; and
transferring heat from the heat transfer fluid in the closed-loop refrigeration circuit
to the stream of liquefied hydrocarbon gas.
2. A system for liquefying boil-off gas, comprising:
a first store (11) for storing liquefied hydrocarbon gas;
a first arrangement of conduits (30, 33, 34) coupled to the first store (11) and to
a hydrocarbon gas network for delivering hydrocarbon gas to a recipient;
a second arrangement of conduits (1, 2) coupled to a source of boil-off gas and to
the first store (11) for delivering liquefied boil-off gas to the first store (11);
a second store (24) for storing a liquefied cryogenic fluid:
a third arrangement of conduits (12, 21) coupled to a source of gaseous cryogenic
fluid and the second store (24) for delivering liquefied cryogenic fluid to the second
store (24);
a fourth arrangement of conduits (52) coupled to the second store (24) for delivering
cryogenic fluid from the second store (24); wherein:
the first (30, 33, 34) and third (12, 21) arrangements of conduits are arranged such
that heat is transferred from a stream of gaseous cryogenic fluid passing through
the third arrangement of conduits (12, 21) to a stream of liquefied hydrocarbon gas
passing through the first arrangement of conduits (30, 33, 34);
the second (1, 2) and fourth (52) arrangements of conduits are arranged such that
heat is transferred from a stream of gaseous boil-off gas passing through the second
arrangement of conduits (1, 2) to a stream of liquefied cryogenic fluid passing through
the fourth arrangement of conduits (52); and
a controller configured to:
a) control the flow rate of the stream of gaseous cryogenic fluid passing through
the third arrangement of conduits (12, 21) based at least in part on the flow rate
of the stream of liquefied hydrocarbon gas passing through the first arrangement of
conduits (30, 33, 34); and
b) independently control the flow rate of the stream of liquefied cryogenic fluid
passing through the fourth arrangement of conduits (52) based at least in part on
the flow rate of the stream of gaseous boil-off gas passing through the second arrangement
of conduits (1, 2);
and characterised in that the system further comprises a fifth arrangement of conduits (39, 41) being arranged
as a closed-loop refrigeration circuit (37, 39, 40. 41) comprising a heat transfer
fluid passing through the fifth arrangement of conduits, wherein:
the first (30, 33, 34) and third (12, 21) arrangements of conduits are arranged such
that heat is transferred between the first (30, 33, 34) and third (12, 21) arrangements
of conduits via the closed-loop refrigeration circuit (37, 39, 40, 41). wherein:
the fifth (39, 41) and third (12, 21) arrangements of conduits are arranged such that
heat is transferred from the stream of gaseous cryogenic fluid passing through the
third arrangement of conduits (12, 21) to the heat transfer fluid passing through
the fifth arrangement of conduits (39, 41); and
the fifth (39, 41) and first (30, 33, 34) arrangements of conduits are arranged such
that heat is transferred from the heat transfer fluid passing through the fifth arrangement
of conduits (39, 41) to the stream of liquefied hydrocarbon gas passing through the
first (30, 33, 34) arrangement of conduits.
3. The method of claim 1, further comprising the step of processing the stream of gaseous
boil-off gas and the stream of liquefied hydrocarbon gas from the liquefied hydrocarbon
gas store (11) such that:
a) the stream of liquefied hydrocarbon gas undergoes a phase change from a liquefied
hydrocarbon gas to a gaseous hydrocarbon gas; and
b) the stream of gaseous boil-off gas undergoes a phase change from a gaseous boil-off
gas to a liquefied boil-off gas;
wherein the step of processing comprises transferring heat from the stream of gaseous
boil-off gas to the stream of liquefied hydrocarbon gas from the liquefied hydrocarbon
gas store (11); or the system of claim 2, wherein the first (30, 33, 34) and second
(1, 2) arrangements of conduits are arranged such that heat is transferred from the
stream of gaseous boil-off gas passing through the second arrangement of conduits
(1, 2) to the stream of liquefied hydrocarbon gas passing through the first arrangement
of conduits (30, 33, 34).
4. The method of claim 3, wherein the steps of:
a) transferring heat from the stream of gaseous cryogenic fluid to the stream of liquefied
hydrocarbon gas from the liquefied hydrocarbon gas store (11); and
b) transferring heat from the stream of gaseous boil-off gas to the stream of liquefied
hydrocarbon gas from the liquefied hydrocarbon gas store (11);
are concurrent.
5. The method of any one of claims 1, 3 or 4, wherein the step of processing the stream
of gaseous cryogenic fluid and the stream of liquefied hydrocarbon gas further comprises
the steps of:
expanding the stream of gaseous cryogenic fluid after heat transfer, and
compressing the stream of gaseous cryogenic fluid prior to heat transfer;
wherein the step of compressing the stream of gaseous cryogenic fluid prior to heat
transfer comprises compressing the stream to a supercritical pressure.
6. The method of claim 5, further comprising the steps of passing the stream of liquefied
hydrocarbon gas through first (32) and second (28) branches;
wherein the step of transferring heat from the stream of gaseous cryogenic fluid to
the stream of liquefied hydrocarbon gas from the liquefied hydrocarbon gas store (11)
further comprises:
transferring heat to a stream of liquefied hydrocarbon gas in the first branch (32)
from the stream of gaseous cryogenic fluid prior to compression; and
transferring heat to a stream of liquefied hydrocarbon gas in the second branch (28)
from the stream of gaseous cryogenic fluid after compression via the closed-loop refrigeration
circuit (37, 39, 40, 41).
7. The method of any one of claims 1 or 3 to 6, further comprising the step of delivering
the stream of gaseous hydrocarbon gas to a recipient,
wherein the recipient is one or more of: a hydrocarbon pipe network; a power station;
and a consumer of gaseous hydrocarbon gas.
8. The method of any one of claims 1 or 3 to 7, further comprising the step of collecting
the stream of gaseous boil-off gas from the liquefied hydrocarbon gas store (11);
wherein the step of collecting the stream of gaseous boil-off gas comprises collecting
the boil-off gas from a store, or collection point coupled to the liquefied hydrocarbon
gas store (11).
9. The system of claim 2 or claim 3, wherein the third arrangement of conduits (12, 21)
comprises a compressor (15) for compressing the stream of gaseous cryogenic fluid
to a supercritical pressure, and an expander (22) for expanding the stream of cryogenic
fluid at supercritical pressure to condense and form a cryogenic liquid after heat
exchange with the heat transfer fluid passing through the fifth arrangement of conduits
(39, 41); and wherein the first arrangement of conduits (30, 33, 34) comprises a first
branch (32) and a second branch (28);
the first branch (32) being arranged such that heat is transferred to a stream of
liquefied hydrocarbon gas passing through the first branch (32) from the stream of
gaseous cryogenic fluid passing through the third arrangement of conduits (12, 21)
at a first heat exchange region (13) upstream of the compressor (15); and
the second branch (30) being arranged such that heat is transferred to a stream of
liquefied hydrocarbon gas passing through the second branch from the stream of gaseous
cryogenic fluid passing through the third arrangement of conduits (12, 21) at a second
heat exchange region (5, 29) downstream of the compressor (15) via the closed-loop
refrigeration circuit (37, 39, 40, 41).
10. The system of claim 9, wherein the first (32) and second (28) branches bifurcate from
a single conduit (27) upstream of the first and second heat exchange regions, and
recombine to a single conduit (34) downstream of the first (13) and second (5, 29)
heat exchange regions.
11. The system of any one of claims 2, 3, 9, or 10, wherein the source of boil-off gas
is the first store (11), or a store, conduit, or collection point coupled to the first
store (11).
12. The method of claim 3, or any method claim dependent thereon, wherein the step of
transferring heat from the stream of gaseous boil-off gas to the stream of liquefied
hydrocarbon gas from the liquefied hydrocarbon gas store (11) further comprises:
transferring heat from the stream of gaseous boil-off gas to the heat transfer fluid
in the closed-loop refrigeration circuit; and
transferring heat from the heat transfer fluid in the closed-loop refrigeration circuit
to the stream of liquefied hydrocarbon gas; or the system of claim 3, or any system
claim dependent thereon, wherein the first (30, 33, 34) and second (1, 2) arrangements
of conduits are arranged such that heat is transferred between the first (30, 33,
34) and second (1, 2) arrangements of conduits via the closed-loop refrigeration circuit,
wherein:
the fifth (39, 41) and second (1, 2) arrangements of conduits are arranged such that
heat is transferred from the stream of gaseous boil-off gas passing through the second
arrangement of conduits (1, 2) to the heat transfer fluid passing through the fifth
arrangement of conduits (39, 41).
13. The system of claim 9, wherein the second branch is arranged such that heat is transferred
from the heat transfer fluid passing through the fifth arrangement of conduits (39,
41) to the stream of liquefied hydrocarbon gas passing through the second branch.
14. The method of any one of claims 1, 3 to 8, or 12, further comprising processing a
stream of ambient air to form the stream of gaseous cryogenic fluid, wherein the step
of processing the stream of ambient air comprises one or both of the steps of:
filtering the stream of ambient air to remove moisture, carbon dioxide and/or hydrocarbons;
and
compressing the stream of ambient air; or the system of any one of claims 2, 3, 9
to 11, 12, or 13, wherein the stream of gaseous cryogenic fluid is air, and wherein
the third arrangement of conduits (12, 21) further comprises one or both of:
a filtration system for removing moisture, carbon dioxide and/or hydrocarbons from
a stream of ambient air; and
a compressor for compressing a stream of ambient air.
15. The method of any one of claims 1, 3 to 6, 12 or 14, further comprising passing the
stream of liquefied cryogenic fluid through a separator prior to it entering the liquefied
cryogenic fluid tank to separate any residual vapour phase from the stream of liquefied
cryogenic fluid, and returning the residual vapour phase to the stream of gaseous
cryogenic fluid; or the system of any one of claims 2, 3, 9 to 11, or 12 to 14, wherein
the third arrangement of conduits (12. 21) further comprises a separator upstream
of the second store (24) for extracting any residual vapour phase from the stream
of liquefied cryogenic fluid passing through the third arrangement of conduits (12,
21) prior to entering the second store (24), and a return conduit arranged to direct
the residual vapour phase extracted from the stream of liquefied cryogenic fluid to
the stream of gaseous cryogenic fluid passing through the third arrangement of conduits
(12, 21).
16. The method of any one of claims 1, 3 to 8, 12, 14 or 15, further comprising pumping
the stream of liquefied cryogenic fluid from the liquefied cryogenic fluid store (24)
to increase its pressure prior to the step of transferring heat from the stream of
gaseous boil-off gas to the stream of liquefied cryogenic fluid from the liquefied
cryogenic fluid store (24); or the system of any one of claims 2, 3, 9 to 11, or 12
to 15, wherein the second (1, 2) and fourth (52) arrangements of conduits are arranged
such that heat is transferred between the second (1, 2) and fourth (52) arrangements
of conduits at a third heat exchange region (43), and wherein the fourth arrangement
of conduits (52) further comprises a pump upstream of the third heat exchange region
(43) for pumping the stream of liquefied cryogenic fluid passing through the fourth
arrangement of conduits (52) prior to it passing through the third heat exchange region
(43).
17. The method of any one of claims 1, 3 to 8. 12 or 14 to 16, wherein the step of transferring
heat from the stream of gaseous boil-off gas to the stream of liquefied cryogenic
fluid from the liquefied cryogenic fluid store (24) such that the stream of liquefied
cryogenic fluid undergoes a phase change from a liquefied cryogenic fluid to a gaseous
cryogenic fluid results in a second stream of gaseous cryogenic fluid, the method
further comprising the steps of expanding the second stream of gaseous cryogenic fluid
to extract work from the stream; super-heating the second stream of gaseous cryogenic
fluid prior to one or more stages of expansion; and converting the work extracted
from the second stream into electricity; wherein the step of expanding the second
stream of gaseous cryogenic fluid to extract work from the second stream is performed
in a single-stage expansion device, a two-stage expansion device, or a multi-stage
expansion device; or the system of claim 16, wherein the third heat exchange region
(43) is configured such that heat is transferred from the stream of gaseous boil-off
gas passing through the second arrangement of conduits (1, 2) to the stream of liquefied
cryogenic fluid passing through the fourth arrangement of conduits (52) to produce
a second stream of gaseous cryogenic fluid, and wherein the fourth arrangement of
conduits (52) further comprises an expansion device for expanding the second stream
of gaseous cryogenic fluid and extracting work from the second stream of cryogenic
fluid;
wherein the expansion device is a single-stage expansion device, a two-stage expansion
device, or a multi-stage expansion device;
wherein the fourth arrangement of conduits (52) is coupled to one or more super-heaters,
and wherein each super-heater is either upstream of the first stage of the expansion
device or between stages of the expansion device.
18. The system of any one of claims 2, 3, 9, 10, or 11, further comprising one or more
heat exchangers (5, 13, 29, 43) wherein the first (30, 33, 34), second (1, 2), third
(12, 21) and fourth (52) arrangements of conduits are arranged such that heat is transferred
between the first (30, 33, 34) and third (12, 21) arrangements of conduits, between
the second (1, 2) and fourth (52) arrangements of conduits by the one or more heat
exchangers (5, 13, 29, 43).
19. The system of claim 18, when dependent on claim 3 or any claim dependent thereon,
wherein the first (30, 33, 34), second (1, 2), third (12, 21) and fourth (52) arrangements
of conduits are arranged such that heat is transferred between the first (30, 33,
34) and second (1, 2) arrangements of conduits by the one or more heat exchangers
(5, 13, 29, 43).
20. The system of claim 2 or the method of claim 1, or any claim dependent thereon, wherein
the closed-loop refrigeration circuit operates using one of a single-phase Brayton
cycle and a dual-phase Rankine cycle.
21. The system of claim 2 or the method of claim 1, or any claim dependent thereon, wherein
the heat transfer fluid is one of nitrogen or propane.
22. The system of any one of claims 2, 3, or 9 to 21 or method of any one of claims 1,
3 to 8, 12, 14 to 17, 20, or 21 wherein the cryogenic fluid is one of nitrogen or
air, preferably ambient air.
23. The system of any one of claims 2 to 3 or 9 to 22 or method of any one of claims 1,
3 to 8, 12, 14 to 17, 20, 21 or 22 wherein the liquefied hydrocarbon gas is Liquefied
Natural Gas (LNG).
1. Verfahren zum Verflüssigen von Boil-off-Gas, umfassend:
Speichern eines verflüssigten Kohlenwasserstoffgases in einem Speicher (11) für verflüssigtes
Kohlenwasserstoffgas;
Aufbereiten eines Stroms aus gasförmigem tiefkaltem Fluid und eines Stroms aus verflüssigtem
Kohlenwasserstoffgas aus dem Speicher (11) für verflüssigtes Kohlenwasserstoffgas
derart, dass:
a) der Strom aus verflüssigtem Kohlenwasserstoffgas seinen Aggregatzustand von einem
verflüssigten Kohlenwasserstoffgas in ein gasförmiges Kohlenwasserstoffgas ändert;
und
b) der Strom aus gasförmigem tiefkaltem Fluid seinen Aggregatzustand von einem gasförmigen
tiefkalten Fluid in ein verflüssigtes tiefkaltes Fluid ändert;
wobei der Schritt des Aufbereitens ein Übertragen von Wärme von dem Strom aus gasförmigem
tiefkaltem Fluid auf den Strom aus verflüssigtem Kohlenwasserstoffgas aus dem Speicher
(11) für verflüssigtes Kohlenwasserstoffgas umfasst;
Speichern des verflüssigten tiefkalten Fluids in einem Speicher (24) für verflüssigtes
tiefkaltes Fluid;
Aufbereiten eines Stroms aus gasförmigem Boil-off-Gas und eines Stroms aus verflüssigtem
tiefkaltem Fluid aus dem Speicher (24) für verflüssigtes tiefkaltes Fluid derart,
dass:
a) der Strom aus verflüssigtem tiefkaltem Fluid seinen Aggregatzustand von einem verflüssigten
tiefkalten Fluid in ein gasförmiges tiefkaltes Fluid ändert; und
b) der Strom aus gasförmigem Boil-off-Gas seinen Aggregatzustand von einem gasförmigen
Boil-off-Gas in ein verflüssigtes Boil-off-Gas ändert;
wobei der Schritt des Aufbereitens ein Übertragen von Wärme von dem Strom aus gasförmigem
Boil-off-Gas auf den Strom aus verflüssigtem tiefkaltem Fluid aus dem Speicher (24)
für verflüssigtes tiefkaltes Fluid umfasst;
Speichern des verflüssigten Boil-off-Gases in dem Speicher (11) für verflüssigtes
Kohlenwasserstoffgas;
Regeln des Durchflusses des Stroms aus gasförmigem tiefkaltem Fluid zumindest teilweise
auf Grundlage des Durchflusses des Stroms aus verflüssigtem Kohlenwasserstoffgas aus
dem Speicher (11) für verflüssigtes Kohlenwasserstoffgas; und
unabhängig davon Regeln des Durchflusses des Stroms aus verflüssigtem tiefkaltem Fluid
aus dem Speicher (24) für verflüssigtes tiefkaltes Fluid zumindest teilweise auf Grundlage
des Durchflusses des Stroms aus gasförmigem Boil-off-Gas; wobei das Verfahren dadurch gekennzeichnet ist, dass
der Schritt des Übertragens von Wärme von dem Strom aus gasförmigem tiefkaltem Fluid
auf den Strom aus verflüssigtem Kohlenwasserstoffgas aus dem Speicher (11) für Kohlenwasserstoffgas
ferner umfasst:
Übertragen von Wärme von dem Strom aus gasförmigem tiefkaltem Fluid auf ein Wärmeträgerfluid
in einem geschlossenen Kühlkreislauf (37, 39, 40, 41) und Abkühlen des gasförmigen
tiefkalten Fluids auf eine Temperatur unter der Sättigungstemperatur des verflüssigten
Kohlenwasserstoffgases; und
Übertragen von Wärme von dem Wärmeträgerfluid in dem geschlossenen Kühlkreislauf auf
den Strom aus verflüssigtem Kohlenwasserstoffgas.
2. System zum Verflüssigen von Boil-off-Gas, umfassend:
einen ersten Speicher (11) zum Speichern von verflüssigtem Kohlenwasserstoffgas;
eine erste Anordnung aus Leitungen (30, 33, 34), die zum Befördern von Kohlenwasserstoffgas
zu einer Abnahmestelle mit dem ersten Speicher (11) und mit einem Kohlenwasserstoffgasnetz
verbunden ist;
eine zweite Anordnung aus Leitungen (1, 2), die zum Befördern von verflüssigtem Boil-off-Gas
zum ersten Speicher (11) mit einer Quelle für Boil-off-Gas und mit dem ersten Speicher
(11) verbunden ist;
einen zweiten Speicher (24) zum Speichern eines verflüssigten tiefkalten Fluids;
eine dritte Anordnung aus Leitungen (12, 21), die zum Befördern von verflüssigtem
tiefkaltem Fluid zum zweiten Speicher (24) mit einer Quelle für gasförmiges tiefkaltes
Fluid und mit dem zweiten Speicher (24) verbunden ist;
eine vierte Anordnung aus Leitungen (52), die zum Befördern von tiefkaltem Fluid aus
dem zweiten Speicher (24) heraus mit dem zweiten Speicher (24) verbunden ist; wobei:
die erste (30, 33, 34) und dritte (12, 21) Anordnung aus Leitungen derart angeordnet
sind, dass Wärme von einem Strom aus gasförmigem tiefkaltem Fluid, der durch die dritte
Anordnung aus Leitungen (12, 21) strömt, auf einen Strom aus verflüssigtem Kohlenwasserstoffgas
übertragen wird, der durch die erste Anordnung aus Leitungen (30, 33, 34) strömt;
die zweite (1, 2) und vierte (52) Anordnung aus Leitungen derart angeordnet sind,
dass Wärme von einem Strom aus gasförmigem Boil-off-Gas, der durch die zweite Anordnung
aus Leitungen (1, 2) strömt, auf einen Strom aus verflüssigtem tiefkaltem Fluid übertragen
wird, der durch die vierte Anordnung aus Leitungen (52) strömt; und
einen Regler, der derart eingerichtet ist, dass er:
a) den Durchfluss des Stroms aus gasförmigem tiefkaltem Fluid, der durch die dritte
Anordnung aus Leitungen (12, 21) strömt, zumindest teilweise auf Grundlage des Durchflusses
des Stroms aus verflüssigtem Kohlenwasserstoffgas, der durch die erste Anordnung aus
Leitungen (30, 33, 34) strömt, regelt; und
b) unabhängig davon den Durchfluss des Stroms aus verflüssigtem tiefkaltem Fluid,
der durch die vierte Anordnung aus Leitungen (52) strömt, zumindest teilweise auf
Grundlage des Durchflusses des Stroms aus gasförmigem Boil-off-Gas, der durch die
zweite Anordnung aus Leitungen (1, 2) strömt, regelt;
und dadurch gekennzeichnet, dass das System ferner eine fünfte Anordnung aus Leitungen (39, 41) umfasst, die als geschlossener
Kühlkreislauf (37, 39, 40, 41) angeordnet sind, der ein Wärmeträgerfluid umfasst,
das durch die fünfte Anordnung aus Leitungen strömt, wobei:
die erste (30, 33, 34) und dritte (12, 21) Anordnung aus Leitungen derart angeordnet
sind, dass Wärme zwischen der ersten (30, 33, 34) und dritten (12, 21) Anordnung aus
Leitungen über den geschlossenen Kühlkreislauf (37, 39, 40, 41) übertragen wird, wobei:
die fünfte (39, 41) und dritte (12, 21) Anordnung aus Leitungen derart angeordnet
sind, dass Wärme von dem Strom aus gasförmigem tiefkalten Fluid, der durch die dritte
Anordnung aus Leitungen (12, 21) strömt, auf das Wärmeträgerfluid übertragen wird,
das durch die fünfte Anordnung aus Leitungen (39, 41) strömt; und
die fünfte (39, 41) und erste (30, 33, 34) Anordnung aus Leitungen derart angeordnet
sind, dass Wärme von dem Wärmeträgerfluid, das durch die fünfte Anordnung aus Leitungen
(39, 41) strömt, auf den Strom aus verflüssigtem Kohlenwasserstoffgas übertragen wird,
der durch die erste (30, 33, 34) Anordnung aus Leitungen strömt.
3. Verfahren nach Anspruch 1, ferner umfassend den Schritt des derartigen Aufbereitens
des Stroms aus gasförmigem Boil-off-Gas und des Stroms aus verflüssigtem Kohlenwasserstoffgas
aus dem Speicher (11) für verflüssigtes Kohlenwasserstoffgas, dass:
a) der Strom aus verflüssigtem Kohlenwasserstoffgas seinen Aggregatzustand von einem
verflüssigten Kohlenwasserstoffgas in ein gasförmiges Kohlenwasserstoffgas ändert;
und
b) der Strom aus gasförmigem Boil-off-Gas seinen Aggregatzustand von einem gasförmigen
Boil-off-Gas in ein verflüssigtes Boil-off-Gas ändert;
wobei der Schritt des Aufbereitens ein Übertragen von Wärme von dem Strom aus gasförmigem
Boil-off-Gas auf den Strom aus verflüssigtem Kohlenwasserstoffgas aus dem Speicher
(11) für verflüssigtes Kohlenwasserstoffgas umfasst; oder System nach Anspruch 2,
wobei die erste (30, 33, 34) und zweite (1, 2) Anordnung aus Leitungen derart angeordnet
sind, dass Wärme von den Strom aus gasförmigem Boil-off-Gas, der durch die zweite
Anordnung aus Leitungen (1, 2) strömt, auf den Strom aus verflüssigtem Kohlenwasserstoffgas,
der durch die erste Anordnung aus Leitungen (30, 33, 34) strömt, übertragen wird.
4. Verfahren nach Anspruch 3, wobei die Schritte:
a) des Übertragens von Wärme von dem Strom aus gasförmigem tiefkaltem Fluid auf den
Strom aus verflüssigtem Kohlenwasserstoffgas aus dem Speicher (11) für verflüssigtes
Kohlenwasserstoffgas; und
b) des Übertragens von Wärme von dem Strom aus gasförmigem Boil-off-Gas auf den Strom
aus verflüssigtem Kohlenwasserstoffgas aus dem Speicher (11) für verflüssigtes Kohlenwasserstoffgas
gleichzeitig ablaufen.
5. Verfahren nach einem der Ansprüche 1, 3 oder 4, wobei der Schritt des Aufbereitens
des Stroms aus gasförmigem tiefkaltem Fluid und des Stroms aus verflüssigtem Kohlenwasserstoffgas
ferner folgende Schritte umfasst:
Entspannen des Stroms aus gasförmigem tiefkaltem Fluid nach der Wärmeübertragung und
Verdichten des Stroms aus gasförmigem tiefkaltem Fluid vor der Wärmeübertragung,
wobei der Schritt des Verdichtens des Stroms aus gasförmigem tiefkaltem Fluid vor
der Wärmeübertragung ein Verdichten des Stroms auf einen überkritischen Druck umfasst.
6. Verfahren nach Anspruch 5, ferner umfassend die Schritte des Leitens des Stroms aus
verflüssigtem Kohlenwasserstoffgas durch eine erste (32) und zweite (28) Abzweigung;
wobei der Schritt des Übertragens von Wärme von dem Strom aus gasförmigem tiefkaltem
Fluid auf den Strom aus verflüssigtem Kohlenwasserstoffgas aus dem Speicher (11) für
verflüssigtes Kohlenwasserstoffgas ferner umfasst:
Übertragen von Wärme auf einen Strom aus verflüssigtem Kohlenwasserstoffgas in der
ersten Abzweigung (32) von dem Strom aus gasförmigem tiefkaltem Fluid vor dem Verdichten;
und
Übertragen von Wärme auf einen Strom aus verflüssigtem Kohlenwasserstoffgas in der
zweiten Abzweigung (28) von dem Strom aus gasförmigem tiefkaltem Fluid nach dem Verdichten
über den geschlossenen Kühlkreislauf (37, 39, 40, 41).
7. Verfahren nach einem der Ansprüche 1 oder 3 bis 6, ferner umfassend den Schritt des
Beförderns des Stroms aus gasförmigem Kohlenwasserstoffgas zu einer Abnahmestelle;
wobei die Abnahmestelle ein Kohlenwasserstoffrohrleitungsnetz und/oder ein Kraftwerk
und/oder ein Verbraucher von gasförmigem Kohlenwasserstoffgas ist.
8. Verfahren nach einem der Ansprüche 1 oder 3 bis 7, ferner umfassend den Schritt des
Sammelns des Stroms aus gasförmigem Boil-off-Gas aus dem Speicher (11) für verflüssigtes
Kohlenwasserstoffgas;
wobei der Schritt des Sammelns des Stroms aus gasförmigem Boil-off-Gas ein Sammeln
des Boil-off-Gases aus einem Speicher oder von einem Sammelpunkt umfasst, der mit
dem Speicher (11) für verflüssigtes Kohlenwasserstoffgas verbunden ist.
9. System nach Anspruch 2 oder Anspruch 3, wobei die dritte Anordnung aus Leitungen (12,
21) einen Verdichter (15) zum Verdichten des Stroms aus gasförmigem tiefkaltem Fluid
auf einen überkritischen Druck umfasst, sowie eine Entspannungsmaschine (22) zum Entspannen
des Stroms aus tiefkaltem Fluid bei dem überkritischen Druck, damit er nach einem
Wärmeaustausch mit dem Wärmeträgerfluid, das durch die fünfte Anordnung aus Leitungen
(39, 41) strömt, kondensiert und eine tiefkalte Flüssigkeit bildet; und wobei die
erste Anordnung aus Leitungen (30, 33, 34) eine erste Abzweigung (32) und eine zweite
Abzweigung (28) umfasst;
wobei die erste Abzweigung (32) derart angeordnet ist, dass auf einen Strom aus verflüssigtem
Kohlenwasserstoffgas, der durch die erste Abzweigung (32) strömt, von dem Strom aus
gasförmigem tiefkaltem Fluid, der durch die dritte Anordnung aus Leitungen (12, 21)
strömt, in einem ersten Wärmeaustauschbereich (13) in Strömungsrichtung vor dem Verdichter
(15) Wärme übertragen wird; und
wobei die zweite Abzweigung (30) derart angeordnet ist, dass auf einen Strom aus verflüssigtem
Kohlenwasserstoffgas, der durch die zweite Abzweigung strömt, von dem Strom aus gasförmigem
tiefkaltem Fluid, der durch die dritte Anordnung aus Leitungen (12, 21) strömt, in
einem zweiten Wärmeaustauschbereich (5, 29) in Strömungsrichtung hinter dem Verdichter
(15) über den geschlossenen Kühlkreislauf (37, 39, 40, 41) Wärme übertragen wird.
10. System nach Anspruch 9, wobei sich die erste (32) und zweite (28) Abzweigung von einer
einzigen Leitung (27) in Strömungsrichtung vor dem ersten und zweiten Wärmeaustauschbereich
aufzweigen und sich in Strömungsrichtung hinter dem ersten (13) und zweiten (5, 29)
Wärmeaustauschbereich wieder zu einer einzigen Leitung (34) vereinen.
11. System nach einem der Ansprüche 2, 3, 9 oder 10, wobei die Quelle für Boil-off-Gas
der erste Speicher (11) oder ein Speicher, eine Leitung oder ein Sammelpunkt ist,
der bzw. die mit dem ersten Speicher (11) verbunden ist.
12. Verfahren nach Anspruch 3 oder einem davon abhängigen Verfahrensanspruch, wobei der
Schritt des Übertragens von Wärme von dem Strom aus gasförmigem Boil-off-Gas auf den
Strom aus verflüssigtem Kohlenwasserstoffgas aus dem Speicher (11) für verflüssigtes
Kohlenwasserstoffgas ferner Folgendes umfasst:
Übertragen von Wärme von dem Strom aus gasförmigem Boil-off-Gas auf das Wärmeträgerfluid
in dem geschlossen Kühlkreislauf; und
Übertragen von Wärme von dem Wärmeträgerfluid in dem geschlossenen Kühlkreislauf auf
den Strom aus verflüssigtem Kohlenwasserstoffgas; oder System nach Anspruch 3 oder
einem davon abhängigen Systemanspruch, wobei die erste (30, 33, 34) und zweite (1,
2) Anordnung aus Leitungen derart angeordnet sind, dass Wärme zwischen der ersten
(30, 33, 34) und zweiten (1, 2) Anordnung aus Leitungen über den geschlossenen Kühlkreislauf
übertragen wird, wobei:
die fünfte (39, 41) und zweite (1, 2) Anordnung aus Leitungen derart angeordnet sind,
dass Wärme von dem Strom aus gasförmigem Boil-off-Gas, der durch die zweite Anordnung
aus Leitungen (1, 2) strömt, auf das Wärmeträgerfluid übertragen wird, das durch die
fünfte Anordnung aus Leitungen (39, 41) strömt.
13. System nach Anspruch 9, wobei die zweite Abzweigung derart angeordnet ist, dass Wärme
von dem Wärmeträgerfluid, das durch die fünfte Anordnung aus Leitungen (39, 41) strömt,
auf den Strom aus verflüssigtem Kohlenwasserstoffgas übertragen wird, der durch die
zweite Abzweigung strömt.
14. Verfahren nach einem der Ansprüche 1, 3 bis 8 oder 12, ferner umfassend ein Aufbereiten
eines Stroms aus Umgebungsluft zur Bildung des Stroms aus gasförmigem tiefkaltem Fluid,
wobei der Schritt des Aufbereitens des Stroms aus Umgebungsluft einen oder beide der
folgenden Schritten umfasst:
Filtern des Stroms aus Umgebungsluft zum Entfeuchten, zum Entfernen von Kohlendioxid
und/oder Kohlenwasserstoffen; und
Verdichten des Stroms aus Umgebungsluft; oder System nach einem der Ansprüche 2, 3,
9 bis 11, 12 oder 13, wobei der Strom aus gasförmigem tiefkaltem Fluid Luft ist und
wobei die dritte Anordnung aus Leitungen (12, 21) ferner umfasst:
ein Filtersystem zum Entfeuchten eines Stroms aus Umgebungsluft, zum Entfernen von
Kohlendioxid und/oder Kohlenwasserstoffen aus einem Strom aus Umgebungsluft; und
einen Verdichter zum Verdichten eines Stroms aus Umgebungsluft.
15. Verfahren nach einem der Ansprüche 1, 3 bis 8, 12 oder 14, ferner umfassend Leiten
des Stroms aus verflüssigtem tiefkaltem Fluid durch einen Abscheider, bevor er in
den Tank für das verflüssigte tiefkalte Fluid strömt, damit restliche Dampfphase aus
dem Strom aus verflüssigtem tiefkaltem Fluid abgetrennt wird, und Zurückleiten der
restlichen Dampfphase zu dem Strom aus gasförmigem tiefkaltem Fluid; oder System nach
einem der Ansprüche 2, 3, 9 bis 11, oder 12 bis 14, wobei die dritte Anordnung aus
Leitungen (12, 21) ferner einen Abscheider in Strömungsrichtung vor dem zweiten Speicher
(24) zum Extrahieren von restlicher Dampfphase aus dem Strom aus verflüssigtem tiefkaltem
Fluid, der durch die dritte Anordnung aus Leitungen (12, 21) strömt, bevor er in den
zweiten Speicher (24) strömt, und eine Rückführleitung umfasst, die so angeordnet
ist, dass sie die restliche Dampfphase, die aus dem Strom aus verflüssigtem tiefkaltem
Fluid extrahiert ist, zu dem Strom aus gasförmigem tiefkaltem Fluid leitet, der durch
die dritte Anordnung aus Leitungen (12, 21) strömt.
16. Verfahren nach einem der Ansprüche 1, 3 bis 8, 12, 14 oder 15, ferner umfassend Pumpen
des Stroms aus verflüssigtem tiefkaltem Fluid aus dem Speicher (24) für verflüssigtes
tiefkaltes Fluid zwecks Erhöhung seinen Drucks vor dem Schritt des Übertragens von
Wärme von dem Strom aus gasförmigem Boil-off-Gas auf den Strom aus verflüssigtem tiefkaltem
Fluid aus dem Speicher (24) für verflüssigtes tiefkaltes Fluid; oder System nach einem
der Ansprüche 2, 3, 9 bis 11, oder 12 bis 15, wobei die zweite (1, 2) und vierte (52)
Anordnung aus Leitungen derart angeordnet sind, dass Wärme zwischen der zweiten (1,
2) und vierten (52) Anordnung aus Leitungen in einem dritten Wärmeaustauschbereich
(43) übertragen wird, und wobei die vierte Anordnung aus Leitungen (52) ferner eine
Pumpe in Strömungsrichtung vor dem dritten Wärmeaustauschbereich (43) umfasst, zum
Pumpen des Stroms aus verflüssigtem tiefkaltem Fluid, der durch die vierte Anordnung
aus Leitungen (52) strömt, bevor er durch den dritten Wärmeaustauschbereich (43) strömt.
17. Verfahren nach einem der Ansprüche 1, 3 bis 8, 12 oder 14 bis 16, wobei der Schritt
des Übertragens von Wärme von dem Strom aus gasförmigem Boil-off-Gas auf den Strom
aus verflüssigtem tiefkaltem Fluid aus dem Speicher (24) für verflüssigtes tiefkaltes
Fluid, derart, dass der Strom aus verflüssigtem tiefkaltem Fluid seinen Aggregatzustand
von einem verflüssigten tiefkalten Fluid in ein gasförmiges tiefkaltes Fluid ändert,
einen zweiten Strom aus gasförmigem tiefkaltem Fluid bewirkt, wobei das Verfahren
ferner folgende Schritte umfasst: Entspannen des zweiten Stroms aus gasförmigem tiefkaltem
Fluid, damit aus dem Strom Arbeit gewonnen wird; Überhitzen des zweiten Stroms aus
gasförmigem tiefkaltem Fluid vor einer oder mehreren Entspannungsstufen; und Umwandeln
der aus dem zweiten Strom gewonnenen Arbeit in Strom; wobei der Schritt des Entspannens
des zweiten Stroms aus gasförmigem tiefkaltem Fluid zum Gewinnen von Arbeit aus dem
zweiten Strom in einer einstufigen Entspannungsvorrichtung, einer zweistufigen Entspannungsvorrichtung
oder einer mehrstufigen Entspannungsvorrichtung durchgeführt wird; oder System nach
Anspruch 16, wobei der dritte Wärmeaustauschbereich (43) derart eingerichtet ist,
dass von dem Strom aus gasförmigem Boil-off-Gas, der durch die zweite Anordnung aus
Leitungen (1, 2) strömt, Wärme auf den Strom aus verflüssigtem tiefkaltem Fluid übertragen
wird, der durch die vierte Anordnung aus Leitungen (52) strömt, und so ein zweiter
Strom aus gasförmigem tiefkaltem Fluid erzeugt wird, und wobei die vierte Anordnung
aus Leitungen (52) ferner eine Entspannungsvorrichtung zum Entspannen des zweiten
Stroms aus gasförmigem tiefkaltem Fluid und Gewinnen von Arbeit aus dem zweiten Strom
aus tiefkaltem Fluid umfasst;
wobei die Entspannungsvorrichtung eine einstufige Entspannungsvorrichtung, eine zweistufige
Entspannungsvorrichtung oder eine mehrstufige Entspannungsvorrichtung ist;
wobei die vierte Anordnung aus Leitungen (52) mit einem oder mehreren Überhitzern
verbunden ist und wobei jeder Überhitzer entweder der ersten Stufe der Entspannungsvorrichtung
vorgeschaltet ist oder sich zwischen Stufen der Entspannungsvorrichtung befindet.
18. System nach einem der Ansprüche 2, 3, 9, 10 oder 11, ferner umfassend einen oder mehrere
Wärmetauscher (5, 13, 29, 43), wobei die erste (30, 33, 34), zweite (1, 2), dritte
(12, 21) und vierte (52) Anordnung aus Leitungen derart angeordnet sind, dass Wärme
von dem einen oder den mehreren Wärmetauschern (5, 13, 29, 43) zwischen der ersten
(30, 33, 34) und dritten (12, 21) Anordnung aus Leitungen, zwischen der zweiten (1,
2) und vierten (52) Anordnung aus Leitungen übertragen wird.
19. System nach Anspruch 18, wenn es von Anspruch 3 oder einem davon abhängigen Anspruch
abhängt, wobei die erste (30, 33, 34), zweite (1, 2), dritte (12, 21) und vierte (52)
Anordnung aus Leitungen derart angeordnet sind, dass Wärme von dem einen oder den
mehreren Wärmetauschern (5, 13, 29, 43) zwischen der ersten (30, 33, 34) und zweiten
(1, 2) Anordnung aus Leitungen übertragen wird.
20. System nach Anspruch 2 oder Verfahren nach Anspruch 1 oder einem davon abhängigen
Anspruch, wobei der geschlossene Kühlkreislauf nach einem Einphasen-Brayton-Kreisprozess
oder einem Zweiphasen-Rankine-Kreisprozess arbeitet.
21. System nach Anspruch 2 oder Verfahren nach Anspruch 1 oder einem davon abhängigen
Anspruch, wobei das Wärmeträgerfluid Stickstoff oder Propan ist.
22. System nach einem der Ansprüche 2, 3 oder 9 bis 21 oder Verfahren nach einem der Ansprüche
1, 3 bis 8, 12, 14 bis 17, 20 oder 21, wobei das tiefkalte Fluid Stickstoff oder Luft,
vorzugsweise Umgebungsluft ist.
23. System nach einem der Ansprüche 2 bis 3 oder 9 bis 22 oder Verfahren nach einem der
Ansprüche 1, 3 bis 8, 12, 14 bis 17, 20, 21 oder 22, wobei das verflüssigte Kohlenwasserstoffgas
Flüssigerdgas (LNG) ist.
1. Procédé pour la liquéfaction de gaz d'évaporation, comprenant :
le stockage d'un gaz d'hydrocarbures liquéfié dans un stockage de gaz d'hydrocarbures
liquéfié (11) ;
le traitement d'un flux de fluide cryogénique gazeux et d'un flux de gaz d'hydrocarbures
liquéfié provenant du stockage de gaz d'hydrocarbures liquéfié (11), de façon telle
que :
a) le flux de gaz d'hydrocarbures liquéfié subit un changement de phase d'un gaz d'hydrocarbures
liquéfié en un gaz d'hydrocarbures gazeux ; et
b) le flux de fluide cryogénique gazeux subit un changement de phase d'un fluide cryogénique
gazeux en un fluide cryogénique liquéfié ;
dans lequel l'étape de traitement comprend le transfert de chaleur du flux de fluide
cryogénique gazeux vers le flux de gaz d'hydrocarbures liquéfié provenant du stockage
de gaz d'hydrocarbures liquéfié (11) ;
le stockage du fluide cryogénique liquéfié dans un stockage de fluide cryogénique
liquéfié (24) ;
le traitement d'un flux de gaz d'évaporation gazeux et d'un flux de fluide cryogénique
liquéfié provenant du stockage de fluide cryogénique liquéfié (24) de façon telle
que :
a) le flux de fluide cryogénique liquéfié subit un changement de phase d'un fluide
cryogénique liquéfié en un fluide cryogénique gazeux ; et
b) le flux de gaz d'évaporation gazeux subit un changement de phase d'un gaz d'évaporation
gazeux en un gaz d'évaporation liquéfié ;
dans lequel l'étape de traitement comprend le transfert de chaleur du flux de gaz
d'évaporation gazeux vers le flux de fluide cryogénique liquéfié provenant du stockage
de fluide cryogénique liquéfié (24) ;
le stockage du gaz d'évaporation liquéfié dans le stockage de gaz d'hydrocarbures
liquéfié (11) ;
le réglage du débit du flux de fluide cryogénique gazeux sur la base au moins en partie
du débit du flux de gaz d'hydrocarbures liquéfié provenant du stockage de gaz d'hydrocarbures
liquéfié (11) ; et
indépendamment le réglage du débit du flux de fluide cryogénique liquéfié provenant
du stockage de fluide cryogénique liquéfié (24) sur la base au moins en partie du
débit du flux de gaz d'évaporation gazeux ;
le procédé étant
caractérisé en ce que
l'étape de transfert de chaleur du flux de fluide cryogénique gazeux vers le flux
de gaz d'hydrocarbures liquéfié provenant du stockage de gaz d'hydrocarbures (11)
comprend en outre :
le transfert de chaleur du flux de fluide cryogénique gazeux vers un fluide caloporteur
présent dans un circuit de réfrigération en boucle fermée (37, 39, 40, 41) et le refroidissement
du fluide cryogénique gazeux à une température au-dessous de la température de saturation
du gaz d'hydrocarbures liquéfié ; et
le transfert de chaleur du fluide caloporteur présent dans le circuit de réfrigération
en boucle fermée vers le flux de gaz d'hydrocarbures liquéfié.
2. Système pour la liquéfaction de gaz d'évaporation, comprenant :
un premier stockage (11) pour le stockage de gaz d'hydrocarbures liquéfié ;
un premier agencement de conduites (30, 33, 34) raccordées au premier stockage (11)
et à un réseau de gaz d'hydrocarbures pour l'acheminement de gaz d'hydrocarbures vers
un destinataire ;
un deuxième agencement de conduites (1, 2) raccordées à une source de gaz d'évaporation
et au premier stockage (11) pour l'acheminement de gaz d'évaporation liquéfié vers
le premier stockage (11) ;
un second stockage (24) pour le stockage d'un fluide cryogénique liquéfié ;
un troisième agencement de conduites (12, 21) raccordées à une source de fluide cryogénique
gazeux et au second stockage (24) pour l'acheminement de fluide cryogénique liquéfié
vers le second stockage (24) ;
un quatrième agencement de conduites (52) raccordées au second stockage (24) pour
l'acheminement de fluide cryogénique provenant du second stockage (24) ;
dans lequel :
les premier (30, 33, 34) et troisième (12, 21) agencements de conduites sont agencés
de façon telle que de la chaleur est transférée d'un flux de fluide cryogénique gazeux
passant dans le troisième agencement de conduites (12, 21) vers un flux de gaz d'hydrocarbures
liquéfié passant dans le premier agencement de conduites (30, 33, 34) ;
les deuxième (1, 2) et quatrième (52) agencements de conduites sont agencés de façon
telle que de la chaleur est transférée d'un flux de gaz d'évaporation gazeux passant
dans le deuxième agencement de conduites (1, 2) vers un flux de fluide cryogénique
liquéfié passant dans le quatrième agencement de conduites (52) ; et
un dispositif de réglage configuré pour :
a) régler le débit du flux débit du flux de fluide cryogénique gazeux passant le troisième
agencement de conduites (12, 21) sur la base au moins en partie du débit du flux de
gaz d'hydrocarbures liquéfié passant dans le premier agencement de conduites (30,
33, 34) ; et
b) indépendamment régler le débit du flux de fluide cryogénique liquéfié passant dans
le quatrième agencement de conduites (52) sur la base au moins en partie du débit
du flux de gaz d'évaporation gazeux passant dans le deuxième agencement de conduites
(1, 2) ;
et
caractérisé en ce que le système comprend en outre
un cinquième agencement de conduites (39, 41) qui est agencé sous forme d'un circuit
de réfrigération en boucle fermée (37, 39, 40, 41) comprenant un fluide caloporteur
passant dans le cinquième agencement de conduites, dans lequel :
les premier (30, 33, 34) et troisième (12, 21) agencements de conduites sont agencés
de façon telle que de la chaleur est transférée entre les premier (30, 33, 34) et
troisième (12, 21) agencements de conduite par l'intermédiaire du circuit de réfrigération
en boucle fermée (37, 39, 40, 41), dans lequel :
les cinquième (39, 41) et troisième (12, 21) agencements de conduites sont agencés
de façon telle que de la chaleur est transférée du flux de fluide cryogénique gazeux
passant dans le troisième agencement de conduites (12, 21) vers le fluide caloporteur
passant dans le cinquième agencement de conduites (39, 41) ; et
les cinquième (39, 41) et premier (30, 33, 34) agencements de conduites sont agencés
de façon telle que de la chaleur est transférée du fluide caloporteur passant dans
le cinquième agencement de conduites (39, 41) vers le flux de gaz d'hydrocarbures
liquéfié passant dans le premier (30, 33, 34) agencement de conduites.
3. Procédé selon la revendication 1, comprenant en outre l'étape de traitement du flux
de gaz d'évaporation gazeux et du flux de gaz d'hydrocarbures liquéfié provenant du
stockage de gaz d'hydrocarbures liquéfié (11) de façon telle que :
a) le flux de gaz d'hydrocarbures liquéfié subit un changement de phase d'un gaz d'hydrocarbures
liquéfié en un gaz d'hydrocarbures gazeux ; et
b) le flux de gaz d'évaporation gazeux subit un changement de phase d'un gaz d'évaporation
gazeux en un gaz d'évaporation liquéfié ;
dans lequel l'étape de traitement comprend le transfert de chaleur du flux de gaz
d'évaporation gazeux vers le flux de gaz d'hydrocarbures liquéfié provenant du stockage
de gaz d'hydrocarbures liquéfié (11) ; ou système selon la revendication 2, dans lequel
les premier (30, 33, 34) et deuxième (1, 2) agencements de conduites sont agencés
de façon telle que de la chaleur est transférée du flux de gaz d'évaporation gazeux
passant dans le deuxième agencement de conduites (1, 2) vers le flux de gaz d'hydrocarbures
liquéfié passant dans le premier agencement de conduites (30, 33, 34).
4. Procédé selon la revendication 3, dans lequel les étapes de :
a) transfert de chaleur du flux de fluide cryogénique gazeux vers le flux de gaz d'hydrocarbures
liquéfié provenant du stockage de gaz d'hydrocarbures liquéfié (11) ; et
b) transfert de chaleur du flux de gaz d'évaporation gazeux vers le flux de gaz d'hydrocarbures
liquéfié provenant du stockage de gaz d'hydrocarbures liquéfié (11) ;
sont simultanées.
5. Procédé selon l'une quelconque des revendications 1, 3 ou 4, dans lequel l'étape de
traitement du flux de fluide cryogénique gazeux et du flux de gaz d'hydrocarbures
liquéfié comprend en outre les étapes de :
détente du flux de fluide cryogénique gazeux après le transfert de chaleur et
compression du flux de fluide cryogénique gazeux avant le transfert de chaleur ;
dans lequel l'étape de compression du flux de fluide cryogénique gazeux avant le transfert
de chaleur comprend la compression du flux à une pression supercritique.
6. Procédé selon la revendication 5, comprenant en outre les étapes de passage du flux
de gaz d'hydrocarbures liquéfié dans des première (32) et seconde (28) dérivations
;
dans lequel l'étape de transfert de chaleur du flux de fluide cryogénique gazeux vers
le flux de gaz d'hydrocarbures liquéfié provenant du stockage de gaz d'hydrocarbures
liquéfié (11) comprend en outre :
le transfert de chaleur vers un flux de gaz d'hydrocarbures liquéfié dans la première
dérivation (32) à partir du flux de fluide cryogénique gazeux avant la compression
; et
le transfert de chaleur vers un flux de gaz d'hydrocarbures liquéfié dans la seconde
dérivation (28) à partir du flux de fluide cryogénique gazeux après la compression
par l'intermédiaire du circuit de réfrigération en boucle fermée (37, 39, 40, 41).
7. Procédé selon l'une quelconque des revendications 1 ou 3 à 6, comprenant en outre
l'étape d'acheminement du flux de gaz d'hydrocarbures gazeux vers un destinataire
;
dans lequel le destinataire en est un ou plusieurs parmi : un réseau de tuyaux d'hydrocarbures
; une centrale électrique ; et un consommateur de gaz d'hydrocarbures gazeux.
8. Procédé selon l'une quelconque des revendications 1 ou 3 à 7, comprenant en outre
l'étape de collecte du flux de gaz d'évaporation gazeux provenant du stockage de gaz
d'hydrocarbures liquéfié (11) ;
dans lequel l'étape de collecte du flux de gaz d'évaporation gazeux comprend la collecte
du gaz d'évaporation à partir d'un stockage ou d'un point de collecte raccordé au
stockage de gaz d'hydrocarbures liquéfié (11).
9. Système selon la revendication 2 ou la revendication 3, dans lequel le troisième agencement
de conduites (12, 21) comprend un compresseur (15) pour la compression du flux de
fluide cryogénique gazeux à une pression supercritique et un détendeur (22) pour la
détente du flux de fluide cryogénique à pression supercritique pour condenser et former
un liquide cryogénique après échange de chaleur avec le fluide caloporteur passant
dans le cinquième agencement de conduites (39, 41) ; et dans lequel le premier agencement
de conduites (30, 33, 34) comprend une première dérivation (32) et une seconde dérivation
(28) ;
la première dérivation (32) étant agencée de façon telle que de la chaleur est transférée
vers un flux de gaz d'hydrocarbures liquéfié passant dans la première dérivation (32)
à partir du flux de fluide cryogénique gazeux passant dans le troisième agencement
de conduites (12, 21) au niveau d'une première zone d'échange de chaleur (13) en amont
du compresseur (15) ; et
la seconde dérivation (30) étant agencée de façon telle que de la chaleur est transférée
vers un flux de gaz d'hydrocarbures liquéfié passant dans la seconde dérivation à
partir du flux de fluide cryogénique gazeux passant dans le troisième agencement de
conduites (12, 21) au niveau d'une deuxième zone d'échange de chaleur (5, 29) en aval
du compresseur (15) par l'intermédiaire du circuit de réfrigération en boucle fermée
(37, 39, 40, 41).
10. Système selon la revendication 9, dans lequel les première (32) et seconde (28) dérivations
partent d'une seule conduite (27) en amont des première et deuxième zones d'échange
de chaleur et se réunissent en une seule conduite (34) en aval des première (13) et
deuxième (5, 29) zones d'échange de chaleur.
11. Système selon l'une quelconque des revendications 2, 3, 9 ou 10, dans lequel la source
de gaz d'évaporation est le premier stockage (11) ou un stockage, une conduite ou
un point de collecte raccordés au premier stockage (11) .
12. Procédé selon la revendication 3, ou une quelconque revendication de procédé dépendante
de celle-ci, dans lequel l'étape de transfert de chaleur du flux de gaz d'évaporation
gazeux vers le flux de gaz d'hydrocarbures liquéfié provenant du stockage de gaz d'hydrocarbures
liquéfié (11) comprend en outre :
le transfert de chaleur du flux de gaz d'évaporation gazeux vers le fluide caloporteur
présent dans le circuit de réfrigération en boucle fermée ; et
le transfert de chaleur du fluide caloporteur présent dans le circuit de réfrigération
en boucle fermée vers le flux de gaz d'hydrocarbures liquéfié ; ou système selon la
revendication 3, ou une quelconque revendication de système dépendante de celle-ci,
dans lequel les premier (30, 33, 34) et deuxième (1, 2) agencements de conduites sont
agencés de façon telle que de la chaleur est transférée entre les premier (30, 33,
34) et deuxième (1, 2) agencements de conduites par l'intermédiaire du circuit de
réfrigération en boucle fermée, dans lequel :
les cinquième (39, 41) et deuxième (1, 2) agencements de conduites sont agencés de
façon telle que de la chaleur est transférée du flux de gaz d'évaporation gazeux passant
dans le deuxième agencement de conduites (1, 2) vers le fluide caloporteur passant
dans le cinquième agencement de conduites (39, 41).
13. Système selon la revendication 9, dans lequel la seconde dérivation est agencée de
façon telle que de la chaleur est transférée du fluide caloporteur passant dans le
cinquième agencement de conduites (39, 41) vers le flux de gaz d'hydrocarbures liquéfié
passant dans la seconde dérivation.
14. Procédé selon l'une quelconque des revendications 1, 3 à 8 ou 12, comprenant en outre
le traitement d'un flux d'air ambiant pour former le flux de fluide cryogénique gazeux,
dans lequel l'étape de traitement du flux d'air ambiant comprend l'une des étapes
de :
filtration du flux d'air ambiant pour éliminer de l'humidité, du dioxyde de carbone
et/ou des hydrocarbures ; et
compression du flux d'air ambiant,
ou les deux, ou système selon l'une quelconque des revendications 2, 3, 9 à 11, 12
ou 13, dans lequel le flux de fluide cryogénique gazeux est de l'air et dans lequel
le troisième agencement de conduites (12, 21) comprend en outre l'un de :
un système de filtration pour l'élimination d'humidité, de dioxyde de carbone et/ou
d'hydrocarbures d'un flux d'air ambiant ; et
un compresseur pour la compression d'un flux d'air ambiant.
15. Procédé selon l'une quelconque des revendications 1, 3 à 8, 12 ou 14, comprenant en
outre le passage du flux de fluide cryogénique liquéfié dans un séparateur avant qu'il
entre dans le réservoir de fluide cryogénique liquéfié pour séparer toute phase vapeur
résiduelle du flux de fluide cryogénique liquéfié et le renvoi de la phase vapeur
résiduelle vers le flux de fluide cryogénique gazeux ; ou système selon l'une quelconque
des revendications 2, 3, 9 à 11 ou 12 à 14, dans lequel le troisième agencement de
conduites (12, 21) comprend en outre un séparateur en amont du second stockage (24)
pour l'extraction de toute phase vapeur résiduelle du flux de fluide cryogénique liquéfié
passant dans le troisième agencement de conduites (12, 21) avant qu'il entre dans
le second stockage (24) et une conduite de retour agencée pour envoyer la phase vapeur
résiduelle extraite du flux de fluide cryogénique liquéfié vers le flux de fluide
cryogénique gazeux passant dans le troisième agencement de conduites (12, 21).
16. Procédé selon l'une quelconque des revendications 1, 3 à 8, 12, 14 ou 15, comprenant
en outre le pompage du flux de fluide cryogénique liquéfié provenant du stockage de
fluide cryogénique liquéfié (24) pour augmenter sa pression avant l'étape de transfert
de chaleur du flux de gaz d'évaporation gazeux vers le flux de fluide cryogénique
liquéfié provenant du stockage de fluide cryogénique liquéfié (24) ; ou système selon
l'une quelconque des revendications 2, 3, 9 à 11 ou 12 à 15, dans lequel les deuxième
(1, 2) et quatrième (52) agencements de conduites sont agencés de façon telle que
de la chaleur est transférée entre les deuxième (1, 2) et quatrième (52) agencements
de conduites au niveau d'une troisième zone d'échange de chaleur (43) et dans lequel
le quatrième agencement de conduites (52) comprend en outre une pompe en amont de
la troisième zone d'échange de chaleur (43) pour le pompage du flux de fluide cryogénique
liquéfié passant dans le quatrième agencement de conduites (52) avant qu'il passe
dans la troisième zone d'échange de chaleur (43).
17. Procédé selon l'une quelconque des revendications 1, 3 à 8, 12 ou 14 à 16, dans lequel
l'étape de transfert de chaleur du flux de gaz d'évaporation gazeux vers le flux de
fluide cryogénique liquéfié provenant du stockage de fluide cryogénique liquéfié (24)
de façon telle que le flux de fluide cryogénique liquéfié subit un changement de phase
d'un fluide cryogénique liquéfié en un fluide cryogénique gazeux résulte en un second
flux de fluide cryogénique gazeux, le procédé comprenant en outre les étapes de détente
du second flux de fluide cryogénique gazeux pour extraire du travail à partir du flux
; surchauffe du second flux de fluide cryogénique gazeux avant un ou plusieurs étages
de détente ; et conversion du travail extrait du second flux en électricité ; dans
lequel l'étape de détente du second flux de fluide cryogénique gazeux pour extraire
du travail à partir du second flux est effectuée dans dispositif de détente à un seul
étage, un dispositif de détente à deux étages ou un dispositif de détente à plusieurs
étages ; ou système selon la revendication 16, dans lequel la troisième zone d'échange
de chaleur (43) est configurée de façon telle que de la chaleur est transférée du
flux de gaz d'évaporation gazeux passant dans le deuxième agencement de conduites
(1, 2) vers le flux de fluide cryogénique liquéfié passant dans le quatrième agencement
de conduites (52) pour produire un second flux de fluide cryogénique gazeux et dans
lequel le quatrième agencement de conduites (52) comprend en outre un dispositif de
détente pour la détente du second flux de fluide cryogénique gazeux et l'extraction
de travail à partir du second flux de fluide cryogénique ; dans lequel le dispositif
de détente est un dispositif de détente à un seul étage, un dispositif de détente
à deux étages ou un dispositif de détente à plusieurs étages ;
dans lequel le quatrième agencement de conduites (52) est raccordé à un ou plusieurs
surchauffeurs et dans lequel chaque surchauffeur est soit en amont du premier étage
du dispositif de détente soit entre des étages du dispositif de détente.
18. Système selon l'une quelconque des revendications 2, 3, 9, 10 ou 11, comprenant en
outre un ou plusieurs échangeurs de chaleur (5, 13, 29, 43) dans lequel les premier
(30, 33, 34), deuxième (1, 2), troisième (12, 21) et quatrième (52) agencements de
conduites sont agencés de façon telle que de la chaleur est transférée entre les premier
(30, 33, 34) et troisième (12, 21) agencements de conduites, entre les deuxième (1,
2) et quatrième (52) agencements de conduites par le ou les échangeurs de chaleur
(5, 13, 29, 43).
19. Système selon la revendication 18, lorsqu'elle est dépendante de la revendication
3 ou d'une quelconque revendication dépendante de celle-ci, dans lequel les premier
(30, 33, 34), deuxième (1, 2), troisième (12, 21) et quatrième (52) agencements de
conduites sont agencés de façon telle que de la chaleur est transférée entre les premier
(30, 33, 34) et deuxième (1, 2) agencements de conduites par le ou les échangeurs
de chaleur (5, 13, 29, 43).
20. Système selon la revendication 2 ou procédé selon la revendication 1, ou une quelconque
revendication dépendante de celles-ci, dans lesquels le circuit de réfrigération en
boucle fermée fonctionne à l'aide de l'un d'un cycle de Brayton à une seule phase
et d'un cycle de Rankine à deux phases.
21. Système selon la revendication 2 ou procédé selon la revendication 1, ou une quelconque
revendication dépendante de celles-ci, dans lesquels le fluide caloporteur est l'un
de l'azote ou du propane.
22. Système selon l'une quelconque des revendications 2, 3 ou 9 à 21 ou procédé selon
l'une quelconque des revendications 1, 3 à 8, 12, 14 à 17, 20 ou 21, dans lesquels
le fluide cryogénique est l'un de l'azote ou de l'air, de préférence l'air ambiant.
23. Système selon l'une quelconque des revendications 2 à 3 ou 9 à 22 ou procédé selon
l'une quelconque des revendications 1, 3 à 8, 12, 14 à 17, 20, 21 ou 22, dans lesquels
le gaz d'hydrocarbures liquéfié est du gaz naturel liquéfié (GNL).