Field of the Invention
[0001] The invention relates to polymer chemistry, technology of thin-film polymeric materials,
and composite multi-layered polymeric products. Polymeric films have currently found
wide application in the manufacture of various multi-layered products e.g. documents
that must be secure from counterfeit and are intended to identify their owner. Composite
materials for production of secure documents are being improved constantly, and they
should ensure high physical and mechanical characteristics of the product in terms
of its durability and resistance to the effects aimed at delamination and changes
to graphics and other data. For mass production of identification documents, it is
necessary that the used materials were produced without changing the existing technologies.
[0002] The use of polymeric multi-layered materials in identity documents such as passports,
identity cards, driver's licenses, is important to ensure counterfeit protection.
To protect such documents against forgery at their manufacture and issuance, personal
information about the document's owner is inscribed in them. Typically, this is a
portrait and biometric data of the owner, date and place of birth, time and place
of issue of the document, etc. In current technology of applying multi-layered polymeric
materials for identification documents, personal information is inscribed in the form
of portrait and text images that are placed on/or in individual layers of the multi-layered
plastic structures. To protect the document from counterfeit, in addition to the basic
personal information in many cases additional or duplicate images and information
related to the basic information are inscribed, which are semi-transparent, visualized
in transmitted and/or reflected light, and do not interfere with the perception of
the basic information. In some cases, hidden or encrypted information is added to
the additional or duplicate images, which allows authentication of the document with
the use of dedicated instruments.
[0003] The biggest security effect is achieved, if the duplicate images are colored and
easily recognizable, and the image formation technology is available only to the manufacturer
of the documents.
[0004] Additional colored graphic or text images are effective for counterfeit protection
of not only documents, but also individual multi-layered polymeric elements, for example,
non-removable protective stickers applied to the articles to confirm their authenticity.
These articles may include any product, in particular printing products. In this case,
elements are individualized, that is images applied to them are individual for each
element or a limited group of such elements, and these images can be related to individual
characteristics of the protected products e.g. their serial numbers.
Background Art
[0005] Conventional colored digital and analog images, widely used in multi-layered polymeric
products, are formed by standard technologies based on direct printing methods, in
which paint or colored ink is applied onto a carrier by various methods. The main
disadvantage of these colored images, in terms of their use in identification documents,
is the widespread availability of technologies for their production, allowing replacement
and forgery of photos and graphic personal data in the documents individualized by
such methods.
[0006] A variety of unique methods of recording colored images in multi-layered polymeric
materials are also known at present, which require the use of special substances and
materials available to only a limited number of companies.
[0007] The methods include e.g. a method of recording in multi-layered structures containing
inks that change color when exposed to laser radiation (
RU 2286888 C2, 10.11.2006), or a method of laser engraving of sub-layers of a multi-layer structure including
a sequence of layers of pigments of various colors (
US 7763179 B2 27.07.2009). The disadvantage of the methods is the need for unique multi-layered materials
with special composition and pigment coatings, which complicates implementation of
the methods and their use in industry.
[0008] Various methods are also known for inscribing colored holographic 3D images in photopolymeric
layers, e.g. using a lenticular array (
US 20130301090 A1, 14.11.2013). The main disadvantage of these methods is the need to produce the holograms on
a film carrier in a separate process followed by application of a film with the hologram
to the document.
[0009] A method is known, in which an additional image is formed in a multi-layered polymeric
document in a semi-transparent layer by laser engraving of partially demetalized diffraction
grating, which is a component of the main fixed holographic image (
US 2013/0082458 A1 04.04.2013). This is done at laser marking of the underlying layer, which is carbonized under
laser radiation. Partial demetallization of the diffraction grating protects the document
against delamination since it provides fusion of the material of adjacent layers in
the areas free of metallization. The main disadvantage of this method is that it is
impossible to form an arbitrary colored image.
[0010] One of the most promising methods for personalization and individualization of documents
is a method of forming full-color holographic images in a multi-layered polymeric
structure (
RU 2079167 C1, 10.05.1997). Images are inscribed on internal diffraction gratings, one above the other in multi-layered
polymeric carriers. The full-color images are restored in white light. Information
placed on the carrier is in the form of text and graphic images.
[0011] The method described in
RU 2079167 is the most relevant prior art for the present identification document. The disadvantage
of the method is that it cannot form transparent and semi-transparent images. Furthermore,
such multi-layered holographic structures are not homogeneous. In production of plastic
documents, solid metallized diffraction gratings are disposed within multi-layered
polymeric structures, and this often facilitates separation between layers and counterfeit
of the documents.
SUMMARY OF THE INVENTION
[0012] The object of the invention is to provide a multi-layered polymeric article such
as a secure identification document, which comprises, in addition to basic personal
data, additional colored images related to the personal data and individualizing the
document, the document being protected from delamination and counterfeit of the inscribed
personal information. To attain the object, the additional colored images are formed
as a semi-transparent matrix of pixels comprising metallized diffraction gratings
and spaced apart so that the polymeric layers of the article can be fused together
in the areas free of diffraction gratings in the manufacture of the article.
[0013] In an embodiment, the layer with a semi-transparent pixel matrix is disposed above
the layer with personalized graphics and text data.
[0014] In an embodiment, the pixels are diffraction gratings reflecting electromagnetic
radiation of a predetermined wavelength in a predetermined direction.
[0015] It should be noted that the article manufactured according to any embodiment can
be a banknote, protective sticker, blank sheet for a valuable document, excise stamp,
passport, identity card, travel document, driver's license, diploma, plastic card
or similar document.
[0016] In an embodiment, the pixels are formed by masking and then etching the matrix structures
on the surface of transparent polymer films prior to fusing together the layers of
the identification document.
[0017] Images are inscribed in the present identification document by a focused laser radiation
on laser engraving machines. Images are formed by partially destroying the metallized
diffraction gratings, which changes the color saturation and brightness of the sub-pixel
areas owing to modulation of intensity, duration and number of laser pulses, with
precise positioning of the laser beam on elements of the pixel matrix and/or special
markers disposed on the surface of the pixel matrix.
[0018] The ability to remove the diffraction grating is determined by the presence of its
metallization, since engraving is generally performed by infrared lasers with the
electromagnetic radiation wavelength of 1.064 µm, which is well absorbed in metals
and leads to demetallization of the diffraction gratings and loss of their reflective
properties.
[0019] Laser beam is moved over pixels of the matrix structure and focused on subpixels
with diffraction gratings that reflect light of a specific wavelength. Depending on
the duration and power of laser pulses, the diffraction grating in the selected pixel
is removed completely or partially.
[0020] By moving on pixels and subpixels of the matrix structure, colored images are formed
which can be observed in predetermined directions of observation.
[0021] Pixel elements of the matrix structure may have various forms, for example, rectangular,
diamond-shaped or round. The pixels can have a size of 30 to 200 µm. Furthermore,
at least two polymeric layers are joined together by fusion, and pixel matrixes are
formed on the surfaces between the fused layers, one of which is transparent, and
consist of pixels spaced apart by a distance of 30 to 500 µm. Predetermined transparency
of the formed images is from 50 to 99%. Size, location and distance between the pixels
determine the transparency of inscribed images and the complexity of delamination
of the multi-layered polymeric card without destroying the diffraction gratings in
subpixels of the matrix structure, therefore, without destroying the inscribed images.
[0022] Minimum size of the pixels is determined by the diameter of the laser beam used in
practice, which is in the range of from 5 µm to 100 µm, and the ability of pointing
the beam to pixels with precision that allows engraving the diffraction gratings.
[0023] Maximum size of the pixels is limited by the fact that non-transparent pixels overlap
underlying images and make them inaccessible for observation. For a typical thickness
of the transparent layer between the additional and main image of 50 to 100 µm the
maximum pixel size should not exceed 200 µm.
[0024] At the same time, to provide protection from delamination, two adjacent polymeric
layers must be uniformly fused together over the area not less than 50% of the total
area of the layer because the metallized diffraction structure relates to easily peelable
components.
[0025] Sub-pixel diffraction gratings can be disposed inside the pixels both adjacent to
each other and at some distance from each other; this is determined by the resolution
of the laser engraving machine employed. As a result of laser individualization in
identification of documents, the density of diffraction pixels performs the function
of control of the transparency of the diffraction structure. Any attempt to separate
the layer with the applied additional image from the layer with personal data will
result in distortion of spatial relationship between the elements, which will be easily
discernible at instrumental authentication of the document in a case of poor legibility
of the image with the naked eye.
Brief Description of the Drawing
[0026] Fig. 1 shows a schematic diagram of an identification document according to the invention,
where 1 is an upper transparent polymeric layer comprising thin-film aluminum reflecting
elements; 2 - pixels in nodes of a matrix with sub-pixel structures; 3, 4 - sub-pixels
filled with diffraction gratings, which reflect white light 5 falling on them in a
predetermined direction 6, radiation of red and blue color, respectively.
[0027] When a personalization image is inscribed in each of subpixels 7, part of the diffraction
grating is burned out; 8 is a pixel consisting of a single sub-pixel comprising a
diffraction grating that reflects light of a predetermined wavelength in a predetermined
direction. It can be used for personalization of a document by inscribing a monochromatic
image of a predetermined color.
Description of Preferred Embodiment
[0028] An exemplary embodiment of the present invention is a multi-layered identification
document, in which an upper transparent polymeric layer 1, disposed above underlying
layers with main graphic images and personal data, comprises thin-film aluminum reflective
elements. Images are formed in a matrix with nodes, in which pixels 2 are disposed;
the pixels 2 have sub-pixel structures consisting of two areas with different diffraction
gratings reflecting electromagnetic light radiation of red and blue color, respectively,
in a predetermined direction. The pixels may have rectangular or any other shape with
typical sizes of 30 to 200 µm. The pixel elements of the matrix are spaced apart at
distances of 30 to 500 µm, which determine the transparency level of the image - the
transparency of the formed images can be adjusted by the density of pixels. Transparency
of the images formed according to the invention is from 50 to 99%. Each pixel is divided
into two areas: subpixels 3, 4, filled with diffraction gratings, which reflect radiation
of red and blue color, respectively, when white light 5 falls on them, in a predetermined
direction 6, for example, perpendicular to the surface of the information carrier.
The number of subpixels is not limited to two, there may be 3, 4, etc. Areas occupied
by the diffraction gratings are identical in each of the subpixels. When a personalization
image, for example, colored text, is inscribed, part of the diffraction grating is
burned out in each of the subpixels 7. By changing the reflectivity of the diffraction
gratings of the subpixels in different pixels of the pixel matrix, a colored image
is formed, which can be restored under exposure to white light 5 and observed in a
predetermined direction 6 to the surface of the pixel array. The size and diffraction
efficiency of the sub-pixel areas can be varied by changing the intensity, duration
and number of laser pulses. For precise positioning of the laser beam at engraving
in sub-pixel areas, high-precision methods are used to point the beam to pixel elements
of the matrix and special marking labels. Given the quite large number of pixels (thousands
or more) coding by positions of each pixel is very secure.
[0029] It should be noted that the predetermined transparency of the formed images is dictated
by the following: the upper limit of the range is selected owing to the fact that
if the layer contains a distributed array of metallized diffraction pixels occupying
1% of the area of the layer, light reflected by the matrix will be still sufficient
for perception of the image. The lower limit of the range is selected owing to the
fact that 50% of transparency is directly related to the requirement of protection
from delamination, since the document will be able to be delaminated if the area of
non-transparent pixels is more than 50% of the total area of the layer.
[0030] A further exemplary embodiment comprises two sub-pixel structures (reflecting blue
and red color), rather than three, as in the RGB color image system (red, green, blue),
to illustrate a simplified procedure of image formation with a laser, because in this
case the laser beam pointing system is simpler. The embodiment with two basic colors
can form a colored image having a limited range of colors, but easily distinguishable
and identifiable. Use of two basic colors reduces requirements to the complexity of
scanning and laser beam guidance control algorithms, but retains the counterfeit security
of the document owing to the unique method of laser control.
[0031] According to one feature of the invention, the security feature comprises a reflective
layer containing aluminum reflective elements. The observer perceives the area as
non-transparent or totally reflective when 85% of incident light is reflected and
as transparent when less than 20% of the incident light is reflected and more than
60% is transmitted. It has been determined that the transparency and/or reflectivity
level of the metal layer depends on the wavelength. Therefore, color effects can be
observed under exposure to polychromatic, for example, day light.
[0032] Pixel areas can be of various shapes, for example, hexagon, rectangle, rhombus, square,
irregularly shaped spot, etc. To ensure maximum use of the area of pixels in the observed
images, the shape of sub-pixel areas may be chosen, for example, as rectangles with
coincident boundaries; in this case pixels have the shape of squares.
[0033] For personalization of the identification document, in addition to the visible image,
hidden information can be inscribed on the pixel matrix by changing the shape and/or
size of pixels. For example, a pixel consists of two rectangular subpixels of different
color. In the process of personalization, the upper or lower half of one sub-pixel
can be removed. At visual observation, the difference is undetectable because the
pixel is seen at distance as having the average color and area. Hidden encoded information
can be formed by changing the place of removal of the sub-pixel grating, that is,
by changing the overall shape of the pixel, which consists of shapes of subpixels,
and maintaining the total area of removal,. This information can be decoded with the
aid of a dedicated instrument.
[0034] In addition to visible graphical information, the inventive identification document
may contain personal information in electronic form, inscribed on an electronic carrier
integrated in the document.
[0035] A special case of the invention is a document, which is personalized by inscribing
a monochromatic image of a predetermined color. In this case, each pixel consists
of only one sub-pixel 8 containing a diffraction grating that reflects light of a
predetermined wavelength in a predetermined direction.
[0036] It should be noted that protection of a multi-layered polymer product from delamination
is definitely determined by the location and size of the pixels, that is, the complexity
of delamination is determined by the pixel structure. As known, delamination of a
product occurs at the areas where the adhesion between the layers is the least. If
two layers with identical molecular structure are fused together, maximum bond between
the layers is provided owing to formation of a monolithic layer. However, absolute
fusion is difficult to implement technologically. Diffraction grating is formed on
the surface of one polymeric layer. To enhance its reflectivity, a thin metal layer
is applied to the grating surface. However, it is known that the strength of adhesion
between metal layer and polymeric layer is low because molecules of polymer and atoms
of metal poorly adhere because of different properties. When the product is delaminated,
disruption between the layers passes through the contact area of metal, that is, diffraction
gratings, and polymer. It has been found that when a pixel matrix with metallic diffraction
gratings, uniformly distributed on the surface of the layer, is present, the force
of delamination is below the established standards (not less than 0.35 N/mm) at the
metallization area of more than 50% of the area of the layer.
Industrial Applicability
[0037] The invention relates to polymer chemistry, technology of thin-film polymeric materials
and can be used in the production of various multi-layered products, such as documents
that require protection from counterfeit and are intended to identify their owner.
1. A multi-layered polymeric article, such as an individualizing identification document
or a security element, including a plurality of polymeric layers joined without adhesive,
wherein at least one of said layers comprising colored identifying individualizing
images inscribed therein, said article characterized in that the images are inscribed in the form of semi-transparent pixel matrixes consisting
of thin-film pixel elements with sub-pixel structures consisting of areas with metallized
diffraction gratings, the reflectivity of which on predetermined light wavelengths
is changed when the article is individualized by laser engraving of diffraction gratings
with precise pointing of the laser beam to the areas of their location; at least two
polymeric layers are joined together by fusion; wherein the pixel matrixes are formed
on surfaces between the fused layers, one of which being transparent, and consist
of pixels of a size of 30 to 200 µm spaced apart by a distance of 30 to 500 µm, so
that the formed images have a predetermined transparency of 50 to 99%, and the area
of the metallized diffraction gratings does not exceed 50% of the area of the layer
in which they are disposed.
2. The article according to claim 1, characterized in that the pixels are diffraction gratings reflecting electromagnetic radiation of a predetermined
wavelength in a predetermined direction.
3. The article of claim 1, characterized in that the pixels are formed by masking and then etching the matrix structures on the surface
of transparent polymeric films prior to fusing them together to produce a multi-layered
identification document or a security element.
4. The article according to claim 1, characterized in that each pixel comprises a plurality of subpixels with different reflective properties
for different wavelength ranges of electromagnetic waves.
5. The article according to claim 1, characterized in that the layer with a semi-transparent pixel matrix is above a layer with personalized
graphics and text data.
6. The article according to claim 1, characterized in that the layer with a semi-transparent pixel matrix comprises at least part of the personal
information inscribed in an electronic carrier integrated in the article.
7. The article according to claim 4, characterized in that it comprises a hidden mark provided by differences in the size and/or shape of the
pixels.
8. The article according to any one of claims 1 to 7, characterized in that it is a banknote, protective sticker, blank sheet for a valuable document, excise
stamp, passport, identity card, travel document, driver's license, diploma, plastic
card or similar document.