[0001] The present invention relates to a method for providing an air fraction to, and for
processing the air fraction in, a processing unit and to a corresponding system according
to the preambles of the independent claims.
Prior art
[0003] In the following, the term "air fraction" shall refer to any product which is produced
from air by depleting or enriching the air in one or more components, especially in
oxygen or nitrogen. Especially, the term "air fraction" shall refer to oxygen or nitrogen
or a gas mixture enriched, in comparison to atmospheric air, in oxygen or nitrogen.
If, in the following, reference is made to "oxygen" or "nitrogen", this shall also
include air fractions enriched in, but not entirely consisting of, oxygen or nitrogen.
For example, in such fractions, the oxygen or nitrogen content may be above 30%, 60%,
80%, 90%, 95% or 99%. Obviously, a corresponding air fraction can also consist, except
from inevitable impurities, entirely of oxygen or nitrogen. The same applies for other
air components like the noble gases krypton, xenon and/or argon.
[0004] Cryogenic air separation units comprise rectification columns which may be part of
double column systems, e.g. of classical Linde double column systems, but also of
triple or multiple column systems. Besides the rectification columns for producing
nitrogen and/or oxygen or corresponding air fractions, i.e. the rectification columns
for nitrogen/oxygen separation, rectification columns for producing other air fractions,
especially of the noble gases krypton, xenon and/or argon, may be present.
[0005] In cryogenic air separation units, purified air is compressed, cooled, and subsequently
at least in part supplied to one or more of the rectification columns. To compress
the air, large multistage compressors are generally provided which are, in air separation
units of the prior art, normally driven by electric motors.
[0006] Generally, in air separation units, at least a so-called main air compressor (MAC)
is present which is adapted to compress all the air which is supplied to the rectification
column(s). However, the main air compressor is not necessarily the only compressor
present in an air separation unit, as explained below.
[0007] While the present invention will, in the following, mainly be described with reference
to cryogenic air separation methods and units, the present invention may equally be
useful in methods and devices wherein compressed air is separated by means other than
cryogenic rectification, for example via pressure swing adsorption. Also such units
are, in the language used herein, referred to as "air separation units". Also such
units are provided with one or more compressors which are operated as explained above.
[0008] Generally, the compressors are the major consumers of energy in air separation methods
and units. It is therefore desirable to enhance the efficiency of the air compression
in such methods and units.
Disclosure of the invention
[0009] According to the present invention, a method for providing an air fraction to, and
processing the air fraction in, a processing unit and a corresponding system with
the features of the independent claims are provided. Preferred embodiments of the
present invention are the subject of the dependent claims and the description that
follows.
[0010] As to the terminology regarding technical apparatus used herein, reference is made
to expert literature, e.g. Haring (op. cit.), section 2.2.5.6, "Apparatus".
[0011] Compressors used in air separation units are typically embodied as turbo or positive
displacement machines, multiple stage turbo compressors being most widely used. The
term "compressor" as used herein therefore especially relates to multiple stage turbo
compressors, especially radial compressors. The stages of such compressors are arranged
on one or more shafts which are driven, typically via a gear, by an electric motor
or a steam turbine. A compressor for use in the present invention may also comprise
one or more shafts which are driven by different means, such a machine also being
referred to as a "hybrid" compressor. For example, one shaft of a turbo compressor
may be driven by an electric motor and another shaft may be driven by steam turbine.
An electric motor and a steam turbine may also be coupled with the same shaft and
operate in parallel or alternatingly. One compressor may also be used for different
compression purposes, for example a group of stages of a compressor in cryogenic air
separation unit may be used as the main air compressor mentioned above and one or
more further compression stages in such a compressor may be used as a so-called booster
air compressor (BAC).
[0012] Steam turbines are also generally known from the prior art. Also steam turbines may
comprise multiple stages for steam expansion, providing for a close approach to an
ideal reversible expansion process. Typically, steam turbines are used to drive electrical
generators for electricity production. This is also possible in the context of the
present invention wherein, however, a steam turbine is primarily used to drive a compressor
directly, "directly" meaning that output shaft power of the steam turbine is, without
conversion into another form of energy, particularly electrical energy, used as input
shaft power of the compressor. It will be understood that if, in the following, reference
is made to "a" steam turbine or "a" compressor in singular, the corresponding explanations
may also refer to more than one device.
[0013] According to the present invention, a method for providing an air fraction to, and
for processing the air fraction in, a processing unit is provided. The processing
unit may particularly be adapted to process a hydrocarbon stream, for example a sour
natural gas stream, as explained below, but may equally be adapted to process other
process streams, provided that, in a corresponding processing unit, an air fraction
providable by an air separation unit is used. As a particular example, such a processing
unit may be adapted to perform a process involving oxygen enriched combustion. As
mentioned before, the present invention is equally useful for different air separation
methods, e.g. cryogenic air separation methods and methods based on pressure swing
adsorption. For reasons of conciseness, however, the present invention is explained
mainly with reference to cryogenic air separation.
[0014] According to the present invention, the air fraction is provided in the cryogenic
or non-cryogenic air separation unit by a process involving the steps of submitting
an amount of air to a compression step comprising the use of the compressor in a compression
section of the air separation unit, wherein the compressor is at least in part driven
by a steam turbine in which an amount of steam generated in a steam generation unit
is expanded from a first pressure level to a second pressure level. The second pressure
level may especially be in a range of 5 to 20 bar. The steam is preferably expanded
at a superheated temperature level commonly known in the field of steam management.
[0015] As to the terms "compressor" and "steam turbine", reference is made to the definitions
above. As known to the skilled person and as already mentioned before, in air separation
units different compressors may be present which all may be driven by one or more
steam turbines or steam turbine stages, individually or in unison, in the context
of the present invention. For example, typical cryogenic air separation units comprise
a so-called main air compressor which typically comprises several compressor stages.
One or more compressor stages of such a main air compressor may be driven by one or
more steam turbines or steam turbine stages. The same applies for a booster air compressor
which may also be embodied together with the main air compressor in the form of one
or more compression stages on the same shaft. In a corresponding compressor, different
pressure levels can be obtained. Particularly, in the example of a cryogenic air separation
unit, at least the pressure level at which a high-pressure column of a rectification
column system is operated is provided. However, also a compression to a significantly
higher pressure level may be performed.
[0016] Generally, compressors of air separation units can be driven by steam turbines, which
are however, as regards capital expenses (CAPEX) and operating and maintenance expenses
(OPEX), considered disadvantageous when compared to other sources of shaft power like
electric motors. However, according to the present invention, it was found that driving
compressors with steam turbines may be particularly advantageous if the expanded steam
of such steam turbines can be used in other facilities and/or other method steps that
also use air fractions from the air separation unit and, correspondingly, an integrated
system is created. However, the expanded steam can also advantageously be used to
heat streams and/or to drive rotary equipment in the air separation unit. It is particularly
of advantage if steam for driving the steam turbines is generated by using thermal
solar energy, particularly from solar thermal units, in particular concentrated solar
power/energy, as explained in more detail below.
[0017] According to the present invention, the amount of steam expanded in the steam turbine
is at least in part supplied to the steam consumer of the processing unit which is
separated from the steam generation unit, the term "separated" meaning that the processing
unit represents a functional and optionally constructional entity different from the
steam generation unit and that the processing unit is adapted to perform at least
one further function except from steam production, this at least one further function
comprising also the processing of the air fraction provided by the air separation
unit. Particularly, steam which is expanded in the steam turbine is not (or only partially),
or at least not at first place, reintroduced into the steam generation system. In
other words, the steam expanded in the steam turbine is used, in the context of the
present invention, also for other purposes than for generating steam. This does, however,
not exclude that the steam expanded in the steam turbine and subsequently used in
the processing unit cannot be ultimately used, for example after condensation or cooling,
to generate steam.
[0018] Additionally or alternatively, the amount of steam expanded in the steam turbine
is at least in part used, at a temperature level not exceeding a temperature level
at which the steam is withdrawn from the steam turbine, to heat a regeneration gas
used in a purification section of the air separation unit. In other words, if the
steam expanded in the steam turbine is at least in part used in the purification section
of the air separation unit, it is not further heated before its use. A steam turbine
can be operated with parameters such that it provides an expanded steam stream whose
energy content is sufficiently high to be able to dispense of further heating and/or
expansion in a steam turbine driver of auxiliary pumps such as oil pump or cooling
water pumps in the air separation unit. Particular, the temperature of such a steam
stream is, for the use according to this alternative of the invention, 200 °C to 300
°C. Avoiding further heating steps enables for significantly reducing installation
costs. The utilized steam, once utilized to benefit from the thermal/mechanical energy
as described above, can further be used in other, "separated" (in the sense explained
above) units, e.g. it can be injected into a furnace to moderate furnace temperature.
As such the steam is further integrated to benefit from steam/water molecules physically,
e.g. heat capacity, or chemically.
[0019] Particularly, the purification section of the separation unit may comprise one or
more molsieve adsorbers as also known to the skilled person and described in the cited
expert literature. Molsieve adsorbers are operated in cycles, one cycle including
an adsorption phase which may last for up to several hours and which is performed
at the pressure of the process air to be purified, and a regeneration period in which
a dry gas stream, the "regeneration gas" mentioned before, is passed in a counter
current direction through the adsorbers. This regeneration period comprises a heating
phase in which hot regeneration gas is used to desorb adsorbed components from the
adsorbers. For heating the regeneration gas, the steam expanded in the steam turbine
may be used according to the alternative of the present invention mentioned above.
[0020] With the present invention, the overall efficiency of a combined process as mentioned
before can be enhanced because the energy of low pressure steam which is withdrawn
from the steam turbine driving the compressor can be extracted and advantageously
used. This allows for a more efficient use of steam turbines which makes them more
competitive with the use of electric motors. This is particularly advantageous when
no or insufficient connectivity to the electrical grid is present, especially in remote
areas where, however, a demand for industrial gases exists. Local production of electrical
power may be an option in such scenarios but would require sufficient availability
of fuel (natural gas, coal, diesel, etc.). New investments to establish or increase
electrical power production come with a high capital investment, feedstock may become
unavailable or prices may significantly increase. As such, long-term availability
and cost of electrical power is critical and not predictable. Furthermore, as power
production from fossil fuels has a significant carbon dioxide footprint, additional
costs for carbon dioxide certificates have to be considered and thus the economics
of projects may be negatively influenced. These problems are overcome in the context
of the present invention.
[0021] In this context, it is, as mentioned, particularly advantageous if the amount of
steam expanded in the steam turbine is at least in part generated using solar thermal
energy in the steam generation unit. Typically, solar thermal energy is present in
sufficient amounts in the scenarios mentioned, e.g. at natural gas treatment plants
in the Middle East. In consequence, the present invention provides for a very low
carbon dioxide footprint and overcomes the problem of in availability or high costs
of electricity generated from fossil fuels.
[0022] As a particularly advantageous form or source of thermal energy, thermal energy gathered
in concentrated solar power systems is used. Concentrated solar power systems (CSP)
are classically used to produce steam that is converted into electrical energy by
a steam turbine. In a particularly advantageous embodiment of the present invention,
a CSP system using a thermal oil is used, such a system being able to provide superheated
steam with temperatures above 400 °C. Corresponding units are particularly cost competitive
in areas with high electricity prices, like those mentioned before, and high solar
capacity, e.g. in desert areas. Concentrated solar power units can provide electrical
power and steam uninterruptedly. In such systems, thermal energy may be stored in
molten salt or concrete (ceramics) during the day. During the night, heat is extracted
and used for electricity production. Standard boilers using natural gas to produce
steam can be used for backup during lack of solar irradiation/heat (e.g. during sand
storms, clouds, etc.). Electrical power produced by solar energy is considered as
"green" and does not have any carbon dioxide footprint. As concentrated solar power
systems can generally provide electrical energy as well as steam, also hybrid systems
for driving compressors, including electrical motors and steam turbines, are contemplated
in the context of the present invention. Also contemplated are operating scenarios
wherein at certain periods of time the compressors are driven by electric motors and
during other periods time steam turbines are alternatively or additionally used.
[0023] It is particularly advantageous if the processing unit is embodied as a gas processing
unit, especially a natural gas processing unit, including a sour gas removal unit,
especially as a sour natural gas purification unit, because in such a unit numerous
possibilities of integration with an air separation unit and a corresponding steam
system are present. Correspondingly, the synergy of such units or method steps is
significantly increased in the context of the present invention.
[0024] Particularly, the air fraction provided by the air separation unit to the processing
unit is an oxygen enriched air fraction or pure oxygen and the sour gas removal unit
comprises means for oxygen enriched desulfurisation which are adapted to operate using
at least a part of the oxygen enriched fraction. Oxygen enriched desulfurisation is
generally known from the prior art and comprises the injection of oxygen or an oxygen
enriched air flow into the combustion/reaction chamber of a Claus unit to enable the
reaction of hydrogen sulfide to elemental sulfur.
[0025] Furthermore, the gas processing unit may advantageously comprise means for separating
hydrogen sulfide and/or carbon dioxide from a produced natural gas stream or separating
a blend of carbon dioxide and hydrogen sulfide via an amine wash and/or another physical
or chemical washing process, to which heat is provided via at least the part of the
steam expanded in the steam turbine. Generally, amine washing processes are known
from the prior art and comprise washing out sour gases like carbon dioxide and/or
hydrogen sulfide with a washing solution comprising one or more washing agents in
the form of amines in a washing column or "absorber". The washing solution is regenerated
in a separate column, wherein it is heated and the sour gas is driven out of the loaded
washing solution. This is precisely the point where heat can be provided according
to the presently explained embodiment of the invention.
[0026] Furthermore, the gas processing unit may advantageously comprise tail gas treatment
means to which heat can also be provided via at least a part of the steam expanded
in the steam turbine. Such tail gas treatment means are particularly established to
enhance the recovery rate of sulfur in a desulfurization process to reduce emissions
of sulfur into the atmosphere. They involve the use of adsorbers which may, like the
adsorbers in the purification section of the air separation unit, be regenerated with
a corresponding regeneration gas stream.
[0027] It is also advantageously possible, according to a further embodiment of the present
invention, to use a catalyst bed in the gas processing unit, especially its sour gas
removal unit, which is regenerated from time to time. For a corresponding regeneration,
also at least some of the steam expanded in the steam turbine may be used.
[0028] Furthermore, it is possible to use at least a part of the steam expanded in the steam
turbine for heating at least one fluid, particularly vaporising at least one liquid,
in the air separation unit. For example, liquid air products may be evaporated and
provided in gaseous form thereby. Generally, also further process streams, be it in
the air separation unit or in the processing unit, can be treated, heated or formed
using at least a part of the steam expanded in the steam turbine.
[0029] However, at least part of the steam expanded in the steam turbine may also be used
for driving at least one further rotary unit of the air separation unit, like e.g.
auxiliary pumps for oils, condensates or cooling water.
[0030] Furthermore, it is possible to use at least a part of the steam expanded in the steam
turbine for heating at least one fluid, particularly vaporising water or producing
steam with another composition in the processing unit which is used in the processing
unit, e.g. injected into a combustion chamber as mentioned below.
[0031] Generally, in contrast to previously known systems, the steam fed into the steam
turbine, i.e. the steam expanded in the steam turbine, does not comprise steam previously
expanded in the steam turbine. In other words, the steam is not, or at least not at
first, reintroduced into the steam generating unit. However, in the context of the
present invention, steam may be also be used in a series of different units or aggregates
(each at lower thermal energy content) before at least partially being reintroduced
into the steam generating unit. In this context, at least some of the steam may also
be "lost", particularly when used in a combustion process as mentioned above. Therefore,
corresponding makeup steam or water is preferably provided.
[0032] According to the present invention, the processing unit may comprise means for oxygen
enriched combustion, in which an oxygen enriched air fraction from the air separation
unit is used to enhance combustion of a fuel, wherein the steam expanded in the steam
turbine optionally is at least in part used to moderate, i.e. adjust, a flame temperature
in the means for oxygen enriched combustion. For example, corresponding steam may
be injected into a combustion chamber.
[0033] A system comprising an air separation unit, a processing unit and steam generation
unit is also part of the present invention. The air separation unit is adapted to
provide an air fraction to the processing unit using a process involving the steps
of submitting an amount of air to a compression step comprising the use of a compressor
in a compression section of the air separation unit, and of separating at least a
part of the compressed air in a separation section of the air separation unit, wherein
the compressor is adapted to be at least in part driven by a steam turbine adapted
to expand an amount of steam provided by the steam generation unit from a first pressure
level to a second pressure level.
[0034] According to the present invention, in such a system, the processing unit is separated
from the steam generation unit and means are provided which are adapted to supply
the amount of steam expanded in the steam turbine at least in part to a steam consumer
of the processing unit and/or means are provided which are adapted to use the amount
of steam expanded in the steam turbine to heat a regeneration gas used in the purification
section of the separation unit at a temperature level not exceeding a temperature
level at which the steam is withdrawn from the steam turbine.
[0035] As to features and advantages of such a system, reference is made to the explanations
regarding the inventive method and its embodiments above. The same applies for a particularly
advantageous system which comprises means which are adapted to perform a method according
to the invention and of any of the embodiments as explained above.
[0036] Further details of the present invention are explained with reference to the appended
drawings illustrating preferred embodiments of the present invention.
Short description of the figures
[0037]
Figure 1 illustrates a system according to an embodiment of the present invention.
Figure 2 partially illustrates a processing unit of a system according to an embodiment
of the present invention.
[0038] In the drawings, like reference numerals indicate the same or technically equivalent
elements which are not repeatedly explained for reasons of conciseness.
Embodiments of the invention
[0039] In figure 1, a system according to a particularly preferred embodiment of the present
invention is schematically illustrated and designated 100. As its main components,
the system 100 comprises an air separation unit 1 and a processing unit 2. Furthermore,
a steam generation unit 3 is provided. The illustration of the system 100 is radically
simplified and a number of technical elements are omitted for reasons of clarity.
The system 100 is especially not drawn to scale.
[0040] In the air separation unit 100, an air stream 101 is aspirated, e.g. via a filter
(not shown) by a compressor 111. As repeatedly explained before, in typical air separation
units, different compressors comprising one or more compression stages may be provided.
The compressor 111 schematically illustrated in figure 1 may stand for one or more
of such compressors or compressor stages. Any one of such compressors or one or more
individual compressor stages of one or more of such compressors can be operated as
explained in the following. Particularly, in cryogenic air separation unit 100, a
main air compressor and a booster air compressor may be provided, each of which or
both of which optionally being operable as follows.
[0041] One or more compression stages of the compressor 111 are coupled, e.g. via one or
more shafts 113, to one or more steam turbines 112. As explained for the compressor
111, figure 1 is strictly simplified and thus one or more steam turbines 112 or turbine
stages of one more steam turbines 112 may be present and may be mechanically coupled,
individually or in groups, with the compressor 111, one or more compressors, or one
or more compression stages of one or more compressors. If, in the following, reference
is made to "one" compressor 111 or "one" steam turbine 112, all these alternatives
shall be encompassed thereby.
[0042] To the steam turbine 112, an amount of steam is provided in form of a steam stream
102. The amount of steam is expanded in the steam turbine 112 from a first (higher)
pressure level to a second (lower) pressure level. This steam is withdrawn from the
steam turbine 112 at a temperature level which is the result of the initial temperature
of the steam stream 102 and the expansion cooling in the steam turbine 112. A central
aspect of the present invention is the use of the expanded steam stream 102, designated
103 for referencing purposes. Exemplary uses of the expanded steam stream 103 are
explained below in detail.
[0043] In the compressor 111, an amount of air supplied to the compressor 111 in form of
the air stream 101 mentioned before is compressed to a suitable pressure level. This
pressure level particularly depends on the air separation technique subsequently used.
[0044] For a cryogenic air separation method, for example, this pressure level may be at
least the pressure level of a high pressure column of a known double column system.
For further details, reference is made to the expert literature cited in the outset.
[0045] The compressed air is, in the example shown, provided in form of a compressed air
stream 104, to a purification section 13 of the air separation unit 1. In the purification
section 13, the compressed air stream is e.g. purified by guiding it through one of
a pair of mole sieve adsorbers 131, 132, of which, in the example shown in figure
1, the adsorber 132 is in operation mode and the adsorber 131 is in regeneration mode.
For regenerating the adsorbers 131, 132, a regeneration and gas stream 105, which
is heated in a heater 133, is guided through the adsorbers 131, 132. For further details,
as before, reference is made to the expert literature cited in the outset.
[0046] After the purification of the compressed air stream 103 in the purification section
13 of the air separation unit 1, the stream, now designated 106, is, in the example
of the cryogenic air separation unit 1 shown, cooled in a heat exchanger 141 of a
heat exchange section 14 of the air separation unit 1 to appropriate temperature level,
e.g. to about -160 °C. Before and/or after cooling to the same or to different temperatures,
partial streams of the air stream 106 may be boosted to a higher pressure level, expanded,
throttled, combined and/or separated, as generally known in the art. Therefore, a
cooled air stream designated 107 in figure 1 may stand for one air stream or several
air streams at different temperature and/or pressure levels.
[0047] The air stream 107 is provided to a separation section 12 of the air separation unit
1 which comprises, in the example shown in figure 1, a double rectification column
121 as generally known from the prior art. As known to the skilled person, air streams
can be provided to a corresponding double rectification column 121 at different heights,
and in different physical conditions.
[0048] From the air separation section 12, a number of different streams (product streams
and/or waste streams) may be withdrawn. For example, a stream of "impure nitrogen"
may be withdrawn from the top of the low pressure column of the rectification column
121 which can at least in part used as the regeneration gas stream 105. A product
stream designated 108 may, e.g. after compression in the liquid state, be heated in
the heat exchanger 141 of the heat exchange section 14. For example, such a product
stream 108 may be enriched in oxygen. For reasons of generality, a corresponding product
stream 109 being the same as or different from the product stream 108 is also shown
leaving the bottom right part of the air separation section 12 and the air separation
unit 1. The product stream 109 is, in the example shown, provided to the processing
section 2, details of which are, in an embodiment, shown in figure 2.
[0049] While the separation unit 1 shown in figure 1 represents a typical cryogenic air
separation unit, the present invention may, as mentioned, equally be useful in non-cryogenic
air separation units and methods. Also in such non-cryogenic air separation units
and methods, compressors 111 can be driven by steam turbines 112.
[0050] According to the embodiment exemplified in figure 1, at least a part of the expanded
steam stream 103, designated 103a, can used in the heater 133 to heat the regeneration
gas stream 105. After this use, the steam may e.g. be vented to the atmosphere, condensed
or refed into the steam generation unit 3. Additionally or alternatively, at least
a part of the expanded steam stream 103 may e.g. be used to evaporate liquid streams
in the air separation unit 1 and/or to drive rotary machines like auxiliary pumps
(not shown). Additionally or alternatively, at least a part of the expanded steam
stream 103, designated 103b, may also be provided to the processing unit 2 and used
as explained hereinbelow. Further possible uses of the expanded steam stream 103 or
parts thereof were mentioned before.
[0051] The steam stream 102 is provided by the steam generation unit 3, which may especially
be adapted to generate steam by using solar thermal energy. Particularly, the steam
unit 3 may comprise a, preferably concentrated, solar thermal unit as generally known
in the art and described hereinbefore. It may be equipped with suitable thermal energy
storage means as explained before.
[0052] Figure 2 partially illustrates a processing unit of a system according to an embodiment
of the present invention which is embodied as a sour natural gas purification unit
as an example for a gas processing unit and which is designated 200. The sour natural
gas purification unit 200 may be part of the system 100 which is shown in figure 1.
[0053] The sour natural gas purification unit 200 is only partially illustrated. It is adapted
to be supplied with a stream 210 of (optionally pretreated) sour natural gas and comprises
means 201 for depleting the sour natural gas from e.g. carbon dioxide and other sour
gases. Means 201 may particularly comprise an amine washing unit as generally known
in the prior art. Furthermore, the sour natural gas purification unit 200 comprises
desulfurisation means 202, particularly adapted to perform oxygen enriched desulfurisation.
Furthermore, tail gas treatment means 203 are provided.
[0054] In the particular embodiment shown in figure 2, the desulfurisation means 202 are
adapted to be operated with an oxygen enriched air fraction designated 107 which is
provided by the separation unit 1 (see figure 1).
[0055] Furthermore, in the example shown in figure 2, at least a part of the expanded steam
stream 103 which is here, like in figure 1, designated 103b, is used to transfer heat
to the means 201 and/or 203. For example, in an amine washing unit of the means 201,
heat may be used to drive out absorbed carbon dioxide, hydrogen sulfide and other
sour gases from a loaded washing liquid. Furthermore, the expanded steam stream 103b
can alternatively or additionally also be used in desulfurization means 202. For details,
reference is made to expert literature.
1. A method for providing an air fraction to, and processing the air fraction in, a processing
unit (2), wherein the air fraction is provided by a process involving the steps of
submitting an amount of air to a compression step comprising the use of a compressor
(111) in a compression section (11) of an air separation unit (1), and of separating
at least a part of the compressed air in a separation section (12) of the air separation
unit (1), wherein the compressor (111) is at least in part driven by a steam turbine
(112) in which an amount of steam provided by a steam generation unit (3) is expanded
from a first pressure level to a second pressure level, characterised in that the steam expanded in the steam turbine (112) is at least in part supplied to a steam
consumer (21) of the processing unit (2) separated from the steam generation unit
(3) and/or is at least in part used at a temperature level not exceeding a temperature
level at which the steam is withdrawn from the steam turbine (112) for heating a regeneration
gas stream used in a purification section (13) of the air separation unit (1).
2. The method according to claim 1, wherein the amount of steam expanded in the steam
turbine (112) is at least in part generated in the steam generation unit (3) using
solar thermal energy.
3. The method according to claim 2, wherein the thermal energy is provided at least in
part by a concentrated solar power unit.
4. The method according to claim 3, wherein the concentrated solar power unit is adapted
to store thermal energy in a thermal energy storage section.
5. The method according to any one of the preceding claims, wherein the processing unit
(2) is a gas processing unit (200) including a sour gas removal unit.
6. The method according to claim 5, wherein the air fraction is an oxygen enriched air
fraction and wherein the gas processing unit (200) comprises means (202) for oxygen
enriched desulfurisation which are adapted to operate using at least a part of the
oxygen enriched air fraction.
7. The method according to claim 5 or 6, wherein the gas processing unit (200) comprises
means (201) for depleting a gas mixture from at least hydrogen sulfide and/or carbon
dioxide via a physical or chemical wash process to which heat is provided via at least
a part of the steam expanded in the steam turbine (112).
8. The method according to any one of claims 5 to 7, wherein the gas processing unit
(200) comprises tail gas treatment means (203) to which heat is provided via at least
a part of the steam expanded in the steam turbine (112).
9. The method according to anyone of claims 5 to 8, wherein in the gas processing unit
(200) at least one catalyst bed is used which is regenerated using at least a part
of the steam expanded in the steam turbine (112).
10. The method according to any one of claims 5 to 9, wherein at least one further process
stream in the gas processing unit (200) is heated and/or formed using at least a part
of the steam expanded in the steam turbine (112).
11. The method according to any one of the preceding claims, wherein at least a part of
the steam expanded in the steam turbine (112) is used for heating at least one fluid
in the air separation unit (1).
12. The method according to any one of the preceding claims, wherein at least a part of
the steam expanded in the steam turbine (112) is used for driving at least one further
rotary unit of the air separation unit (1).
13. The method according to any one of the preceding claims, wherein the processing unit
comprises means for oxygen enriched combustion and wherein the steam expanded in the
steam turbine (112) is at least in part used to moderate a flame temperature in the
means for oxygen enriched combustion.
14. The method according to any one of the preceding claims, wherein the steam expanded
in the steam turbine (112) does not comprise steam previously expanded the steam turbine
(112).
15. A system (100) comprising an air separation unit (1), a processing unit (2) and a
steam generation unit (3), the air separation unit (1) being adapted to provide an
air fraction to the processing unit (2) using a process involving the steps of submitting
an amount of air to a compression step comprising the use of a compressor (111) in
a compression section (11) of the air separation unit (1), and of separating at least
part of the compressed air in a separation section (12) of the air separation unit
(1), wherein the compressor (111) is adapted to be at least in part driven by a steam
turbine (112) adapted to expand an amount of steam provided by the steam generation
unit from a first pressure level to a second pressure level, characterised in that the processing unit (2) is separated from the steam generation unit (3) and in that means are provided adapted to supply the amount of steam expanded in the steam turbine
(112) at least in part to a steam consumer (21) of the processing unit (2) and/or
in that means are provided adapted to use the amount of steam expanded in the steam turbine
(112) at a temperature level not exceeding a temperature level at which the steam
is withdrawn from the steam turbine (112) for heating a regeneration gas used in a
purification section (13) of the air separation unit (1).