FIELD OF THE INVENTION
[0001] The invention relates to the field of stain removal.
[0002] The invention may for example be used in the field of fabric care, such as garment
care.
BACKGROUND OF THE INVENTION
[0003] Oxidizing agents are widely used in area of cleaning, disinfecting and bleaching.
Oxidizing agents like hydrogen peroxide having formula H
2O
2, carbamide, sodium percarbonate, sodium perborate are also very widely added in laundry
powders and detergents to remove stains on garment.
[0004] The chemical reacting mechanism of stain removing by oxidization mechanism is illustrated
by Fig.12.
[0005] The stain comprises colored molecule (chromophore) defining a first product P1.
[0006] The colored molecule is then oxidized by an oxidization agent or bleach, resulting
in an intermediate product P2.
[0007] Water is then applied to the intermediate product, resulting in a colorless molecule
defining a final product P3.
[0008] As the H
2O
2 concentration in commercial stain removing products is low, the bleaching reaction
is not very effective and requires comparatively longer time to diminish the stain
color, normally 5 min to 30 min treatment time is needed depending on the stain age
and stain type.
[0009] Reaction can be accelerated by using high temperature (e.g. 70 degreeC) to reduce
the treatment time significantly. But there is a risk of user's skin being injured
if apply the high temperature stain removal system without taking off the stained
cloth.
SUMMARY OF THE INVENTION
[0010] It is an object of the invention to propose a stain removal system that avoids or
mitigates above-mentioned problems.
[0011] The invention is defined by the independent claims. The dependent claims define advantageous
embodiments.
[0012] To this end, the stain removal system for treating a stained area on a cloth comprises:
a container for containing a bleach chemical,
a system for carrying the bleach chemical to the stained area under a liquid form,
a light source for generating light radiation over the stained area.
[0013] Light acceleration is a good substitution of heat. A stain removal system with light
source integration allows fast stain removing and user can use it to treat a stain
on clothes while they are wearing it.
[0014] Small and light weight of the light source also enables designing a compact, portable
stain removal system that is convenient for user to handle and bring along.
[0015] The invention also relates to a cartridge forming a container for containing a bleach
chemical. The cartridge is adapted to cooperate with a stain removal system as described
above.
[0016] The invention also relates to a method of treating a stained area on a cloth by a
stain removal system as described above.
[0017] Detailed explanations and other aspects of the invention will be given below.
BRIEF DESCRIPTION OF THE DRAWINGS
[0018] Particular aspects of the invention will now be explained with reference to the embodiments
described hereinafter and considered in connection with the accompanying drawings,
in which identical parts or sub-steps are designated in the same manner:
Fig.1 depicts a first stain removal system according to the invention,
Fig.2 depicts a second stain removal system according to the invention,
Fig.3 depicts a third stain removal system according to the invention,
Fig.4 depicts a stain removal system according to the invention comprising a detachable
container for containing a liquid bleach chemical,
Fig.5 depicts a stain removal system according to the invention comprising a container
for containing a first type of solid bleach chemical,
Fig.6A is a zoomed view of the container as depicted in Fig.5 for containing a first
type of solid bleach chemical,
Fig.6B is a zoomed view of a container for containing a second type of solid bleach
chemical,
Fig.7 depicts a three-dimensional view of a stain removal system as depicted in Fig.5,
Fig.8A depicts an internal view of a stain removal system as depicted in Fig.5,
Fig.8B depicts a three-dimensional cross-section of a front end of the system as depicted
in Fig.8A,
Fig.8C depicts a two-dimensional cross-section of a front end of the system as depicted
in Fig.8A,
Fig.8D depicts a quantitative example of a two-dimensional cross-section of a front
end of the system as depicted in Fig.8A,
Fig.9 depicts a stain removal system according to the invention comprising a heater
fan,
Fig. 10 depicts a stain removal system according to the invention comprising an infra-red
lamp,
Fig.11 depicts a flow chart of a method according to the invention of treating a stained
area by a stain removal system,
Fig. 12 illustrates the chemical reacting mechanism of stain removing by oxidization
mechanism.
DETAILED DESCRIPTION OF EMBODIMENTS
[0019] In the following, a bleach chemical refers to a group of chemicals that work through
oxidation mechanisms to remove a stain. Including liquid type of bleach chemical like
hydrogen peroxide and peroxy acids and solid type of bleach chemical like sodium percarbonate,
sodium perborate, carbamide peroxide, etc.
[0020] The invention is based on the principle that light activation of hydrogen peroxide
H
2O
2 helps peroxide decompose faster to form free radicals that react with organic molecules
(stain colors).
[0021] Below is the light activated free radical generation:
H
2O
2 + hv → 2 OH• (1)
OH• + H
2O
2 → HO
2• + H
2O (2)
HO
2• + H
2O
2 → OH• + H
2O + O
2 (3)
2 HO
2•→ H
2O
2 + O
2 (4)
[0022] In above chemical reactions, "hv" corresponds to the chemical equation for photon.
[0023] Selection of the light source, wavelength, intensity and exposure time affect the
bleaching efficiency.
[0024] Light source can for example correspond to UV light which has a high photon energy.
Blue light can also be considered. Although light source of longer wavelengths has
lower photon energy which may result in less efficient photo catalysis, more heat
generated by the longer wavelength light can still increase the oxidizing reaction.
[0025] Typical spectrum for blue light is between 492nm to 455nm.
[0026] Preferably, to ensure an efficient stain removal, the power of the light source is
at least 500mW.
[0027] In this invention, blue light is applied as an example but other light sources like
IR, white light, green light etc. should not be excluded from the same principle.
[0028] Fig.1 depicts a first stain removal system 101 according to the invention for treating
a stained area 102 on a cloth 103.
[0029] The stain removal system comprises:
a container 104 for containing a bleach chemical,
a system 105 for carrying the bleach chemical to the stained area 102, and
a light source 106 for generating light radiation 107 over the stained area 102.
[0030] The container 104 may for example correspond to a bottle or recipient, as illustrated.
For example, the bottle can be detachable from the device 101.
[0031] The system 105 for carrying the bleach chemical may correspond to the spout of the
bottle, for example forming an elongated outlet.
[0032] The liquid bleach chemical is externally provided and dosed by user onto the stained
area. The bleach chemical is in liquid form for this type of execution.
[0033] The light source 106 is preferably arranged at a front end FE of the system. In particular,
the front end FE corresponds to the part of the stain removal system cooperating with
the stained area. The light source 106 is preferably but not limited to be light emitting
diode (LED) lamps. Higher light intensity increases the radical generation rate and
result in better stain removal results.
[0034] Fig.2 depicts a second stain removal system 201 according to the invention.
[0035] Compared to the embodiment of Fig.1 in which the container 104 containing a bleach
chemical is a separate element, the container 204 for containing the bleach chemical
in the embodiment of Fig.2 is integrated with all other elements. The container 204
is preferably arranged in a top part of the stain removal system 201.
[0036] The system for carrying the bleach chemical to the stained area 102 comprises a tube
202 along which a valve 203 is arranged. The valve 203 can be opened or closed (not
shown) by a user, mechanically or electrically, in order to open or close the liquid
circuit. When the valve 203 is open, bleach chemical liquid is flowing down by gravity
force until reaching the stained area 102.
[0037] Fig.3 depicts a third stain removal system 301 according to the invention.
[0038] Compared to the embodiment of Fig.2, the system for carrying the bleach chemical
to the stained area 102 comprises a tube 202 along which a pump 302 is arranged. The
pump 302 is preferably an electrical pump that can be actuated by a switch (not shown)
by a user. Alternatively, the pump 302 is a mechanical pump actuated by user via a
manual actuator such as a lever. Compared to only using gravity for carrying the bleach
chemical, using a pump allows having a faster and increased flow rate of bleach chemical
carried to the stained area 102.
[0039] It is noted that in the various embodiments according to the invention, the container
for containing a bleach chemical can take any form taken among:
a fixed reservoir that can be filled-in by user with a liquid bleach chemical, a removable
/ detachable reservoir (or cartridge) that can be filled-in by user with a liquid
bleach chemical, or
a removable / detachable cartridge being pre-filled with a liquid bleach chemical.
[0040] Fig.4 depicts a stain removal system 401 according to the invention.
[0041] Compared to the embodiment of Fig.3 in which the container 204 is not detachable,
the container 404 in the embodiment of Fig.4 is detachable. The detachable container
404 takes the form of a cartridge containing liquid bleach chemical. The cartridge
is coupled to the stain removal system 401 via a coupling valve arrangement 403 that
allows a firm holding of the cartridge and also prevents any leakage of liquid chemical.
[0042] Fig.5 depicts a stain removal system 501 according to the invention comprising a
container 504 for containing a first type of solid bleach chemical 502.
[0043] This embodiment comprises a water reservoir 503 and a water path 505a-505b for carrying
water from the water reservoir 503 to the container 504 in order to dissolve the solid
bleach chemical 502. The resulting dissolved solid bleach chemical releases a bleach
solution, like H
2O
2, or mixture of H
2O
2 and peracetic acid, etc.
[0044] The water reservoir 503 comprises an opening 506 so that the user can fill-in water
when the water reservoir 503 gets empty.
[0045] Preferably, a pump 302 is arranged along the water path 505a-505b to facilitate the
carrying of water into the container, so that the solid bleach chemical 502 can be
dissolved faster and more efficiently.
[0046] The solid bleach chemical 502 is arranged inside the container 504 which is closed
by a detachable cover 507.
[0047] The solid bleach chemical 502 preferably defines a solid-chemical pill that can be
dissolved by water. To this end, chemical powder is pressed into a certain shape (for
example cylindrical) to form a pill.
[0048] Fig.6A is a zoomed view of the container 504 as depicted in Fig.5.
[0049] The container 504 comprises an inlet 601 to allow water W to enter in order to dissolve
the solid bleach chemical 502. The detachable cover 507 comprises an outlet 602 to
let the dissolved chemical solution DCS exit the container 504.
[0050] The detachable cover 507 is first detached by user from the body of the container
504. Then user inserts a solid bleach chemical 502 inside the container 504. Then
user closes the container 504 by attaching the detachable cover 507 back to the body
of the container 504. For example, the detachable cover 507 is detached / attached
from the body of the container 504 via a screw arrangement (as illustrated), or a
clipping mechanism (not shown).
[0051] Fig.6B is a zoomed view of a container 504b for containing a second type of solid
bleach chemical 502b.
[0052] The container 504b is intended to be used similarly as the container 504 in the embodiment
of Fig.5. The container 504b differs from the container 504 in that its size is smaller
in order to accommodate a second type of solid bleach chemical 502b having a smaller
thickness.
[0053] The solid bleach chemical 502b preferably defines a powder-chemical porous pouch.
The porous material containing the powder-chemical preferably has a pore size smaller
than the grain size of the chemical powder, and is made of non-water dissolvable material
forming a soft pod for containing said solid bleach chemical. This powder-chemical
porous pouch may look like a "tea-bag".
[0054] Fig.7 depicts a three-dimensional view of a stain removal system 501 as depicted
in Fig.5.
[0055] It shows that the light source 106 is arranged at a front end FE of the stain removal
system in order to conveniently face a stained area. The container 504 containing
the solid bleach chemical and its cover 507 are arranged in the central part of the
front end FE.
[0056] Preferably, as illustrated for example in Fig.5, the stain removal system 501 according
to the invention further comprises a heating system for heating water of the water
reservoir 503.
[0057] For example, the heating system is an electrical heater 508 arranged in thermal contact
with a bottom part of the water reservoir 503.
[0058] The goal of using this heating system is to carry heated water into the container
504 containing the solid bleach chemical.
[0059] The heated water provides the benefit of:
dissolving more efficiently and faster the bleach chemical reagent contained in the
solid bleach chemical 502 (or 502b), resulting in a higher concentration of reagent
obtained quicker.
increasing the chemical reaction rate and efficiency of stain removal.
[0060] Alternatively, as illustrated for example in Figs.8A-8B-8C-8D, the heating system
for heating water of the water reservoir 503 is formed by a water channel 801 arranged
in a heat sink 802 of the light source 106 (not shown in this view).
[0061] In order to dissipate heat of the light source, the heat sink 802 is thermally coupled
to the light source 106. The heat sink 802 comprises a water channel formed there
into. The water channels have a water inlet 804 to which the tubing 505b is connected.
When the light source 106 is switched-on, heat is dissipated and absorbed by the heat
sink 802. As a result, water circulating into the water channel 801 gets heated before
reaching the inlet 601 of the container 504 containing the solid bleach chemical.
For example, as illustrated, the water channel 801 is spiral-shaped.
[0062] The water that passes in the water channel 801 is heated to a temperature dependent
on:
- 1) the thermal energy generated by the heat sink 802 ,
- 2) the material type and material mass of the metal plate forming the heat sink 802.
Material with very good thermal conductivity like aluminum, copper, or stainless steel
is preferred,
- 3) the time water passing through the water channel 801, and
- 4) the amount or flow rate of water in the water channel 801.
[0063] The estimated temperature range of the heated water is between 40 and 80degreeC.
The heated water then passes via the chemical to dissolve the solid bleach chemical
and finally on to the garment. Chemical powder can be more effectively dissolved as
the water temperature is elevated. And the stain removal effect can be also further
increased as the temperature of chemical solution dosed is higher.
[0064] Fig.8A depicts an internal view of a stain removal system as depicted in Fig.5.
[0065] Fig.8B depicts a three-dimensional cross-section of a front end of the system as
depicted in Fig.8A.
[0066] Fig.8C depicts a two-dimensional cross-section of a front end of the system as depicted
in Fig.8A.
[0067] Fig.8D depicts a quantitative example of a two-dimensional cross-section of a front
end of the system as depicted in Fig.8A.
[0068] Water flows via a tubing 505a-505b from the water reservoir in direction of the container
504 containing the solid bleach chemical. In a cost-effective embodiment, water is
only carried under gravity. In another embodiment (as shown), a water pump 302 actuated
by a button 803 is inserted along the tubing.
[0069] At the front end FE, the light source 106 is arranged, for example a plurality of
LEDs. For example, two LED elements of 10W blue light each are arranged at a distance
d1 = 1 cm between the center CC of the LED elements and the center of the front end
FE. Under such conditions, a red wine stain can be effectively removed within 5 min.
This example is illustrated in Fig.8D. With the same light position, the stain removal
efficiency/speed is also dependent on chemical formulation selected, as well as the
type, concentration, and size of the stain.
[0070] Preferably, the distance d1 between a central part of the light source (e.g. LED)
and center central part of the front end FE of the system (logically corresponding
to the center of the stained area 102 when the system is in contact with the cloth)
has a value less 10 centimeters, considering the light intensity at the stain surface
should be sufficient and the stain removal system must be as small as possible, in
particular if it is a handheld device. Preferably the distance d1 has a value less
than 5 cm.
[0071] Preferably, the stain removal system according to the invention further comprises
a heating system for heating the stained area 102. The heat provided to the stained
area 102 allows increasing speed of the chemical reaction during stain removal. Some
examples will now be explained in more details along with Figs.9-10.
[0072] Fig.9 depicts a stain removal system 901 according to the invention comprising a
heater fan 902. The stain removal system 901 is based on the stain removal system
301 depicted along with Fig.3, with an additional heater fan 902.
[0073] The heater fan 902 is preferably arranged at a mid-height position of the body of
the stain removal system 901. The heater fan 902 combines an air fan 902a and a heating
element 902b placed upstream in the air flow. The heater fan 902 primarily generates
heat by convection to the stained area 102. The heater fan 902 is activated during
the stain removal process.
[0074] A top hollow portion 903 is arranged to let (room-temperature) air to circulate towards
the air fan 902a. Air flow is illustrated by arrows in dotted line style. A bottom
hollow portion 904 is arranged to let the heated air to circulate towards the front
end FE. In other words, air 905 that reaches the front end FE corresponds to heated
air.
[0075] For example, the heater fan 902 is adapted to generate heated air up to 60 degrees
Celsius at the front end. This range of temperature allows treating stain without
taking off the clothes. At a temperature less than 60degreeC, combined with the use
of the fan 902a, water evaporation of the treated stained area is accelerated significantly,
leaving the treated clothes with less moisture.
[0076] Note that in Fig.9, a container 204 containing a liquid bleach chemical is illustrated.
However, similar solution can be implemented with a container for containing a solid
bleach chemical, as described above.
[0077] Fig.10 depicts a stain removal system 1001 according to the invention comprising
an infra-red lamp 1002. The stain removal system 1001 is based on the stain removal
system 301 depicted along with Fig.3, with an additional infra-red lamp 1002.
[0078] The infra-red lamp 1002 is arranged at the front end FE of the stain removal system
1001, with the goal to primarily generates heat by radiation to the stained area 102.
For example, the infra-red lamp 1002 is adapted to generate heated radiation 1003
up to 60 degrees Celsius at the front end FE. This range of temperature allows treating
stain without taking off the clothes.
[0079] Note that in Fig. 10, a container 204 containing a liquid bleach chemical is illustrated.
However, similar solution can be implemented with a container for containing a solid
bleach chemical.
[0080] It is noted that the heater fan and the infra-red lamp can also be used after stain
treatment, in order to dry the area where the stained area was initially.
[0081] Fig.11 depicts a flow chart of a method according to the invention of treating a
stained area 102 by a stain removal system as described above.
[0082] The method of treating a stained area 102 on a cloth 103 by a stain removal system
comprises the steps of:
carrying 1101 a bleach chemical under a liquid form to the stained area,
generating 1102 a light radiation over the stained area.
[0083] The above embodiments as described are only illustrative, and not intended to limit
the technique approaches of the present invention. Although the present invention
is described in details referring to the preferable embodiments, those skilled in
the art will understand that the technique approaches of the present invention can
be modified or equally displaced without departing from the protective scope of the
claims of the present invention. In the claims, the word "comprising" does not exclude
other elements or steps, and the indefinite article "a" or "an" does not exclude a
plurality. Any reference signs in the claims should not be construed as limiting the
scope.
1. A stain removal system (101, 201, 301, 401, 501, 901, 1001) for treating a stained
area (102) on a cloth (103), the stain removal system comprising:
a container (104, 204, 404, 504, 504b) for containing a bleach chemical,
a system (105, 202, 302, 505a, 505b) for carrying the bleach chemical to the stained
area under a liquid form,
a light source (106) for generating light radiation (107) over the stained area (102).
2. Stain removal system as claimed in claim 1, wherein said light source (106) is a light
emitting diode (LED).
3. Stain removal system as claimed in any one of the preceding claims, wherein said light
source (106) is adapted to generate said light radiation (107) in a blue spectrum.
4. Stain removal system as claimed in any one of the preceding claims, wherein said light
source (106) has a power larger than 50mW, preferably larger than 500mW.
5. Stain removal system as claimed in any one of the preceding claims, wherein the light
source (106) is arranged at a front end (FE) of the stain removal system.
6. Stain removal system as claimed in any one of the preceding claims, wherein the distance
(d1) between center central part (CP) of the light source (106) and center central
part of the front end (FE) of the system has a value less than 10 cm, preferably less
than 5 cm.
7. Stain removal system as claimed in any one of the preceding claims, wherein said system
for carrying the bleach chemical comprises:
a tube (202) and a valve (203) arranged along said tube (202), and
a tube (202) and a pump (302) arranged along said tube (202).
8. Stain removal system as claimed in any one of the preceding claims, wherein said container
is a removable cartridge (404).
9. Stain removal system as claimed in any one of the preceding claims, wherein said container
is adapted to contain a liquid bleach chemical or a solid bleach chemical.
10. Stain removal system as claimed in claim 9, wherein said container is adapted to contain
a solid bleach chemical, and wherein said system further comprises a water reservoir
(503) and a water path (505a, 505b) for carrying water into the container to dissolve
the solid bleach chemical.
11. Stain removal system as claimed in claim 10, further comprising a heating system for
heating water of said water reservoir (503), said heating system being taken among:
- a heater (508) in thermal contact with the water reservoir (503), and
- a water channel (801) formed in a heat sink (802) of said light source (106).
12. Stain removal system as claimed in any one of the preceding claims, further comprising
a heating system (902) for heating the stained area (102), said heating system being
taken among a heater fan (902) and an infra-red lamp (1002).
13. Stain removal system as claimed in any one of the preceding claims, corresponding
to a portable cordless device.
14. Cartridge forming a container for containing a bleach chemical, the cartridge being
adapted to cooperate with a stain removal system as claimed in any one of the claims
1 to 13.
15. Method of treating a stained area (102) on a cloth (103) by a stain removal system,
the method comprising the steps of:
carrying (1101) a bleach chemical under a liquid form to the stained area,
generating (1102) a light radiation over the stained area.