TECHNICAL FIELD
[0001] The present invention relates to the field of aluminum alloy material technologies,
and in particular, to a die casting aluminum alloy, a production method of the die
casting aluminum alloy, and a communications product.
BACKGROUND
[0002] With the development of a 4G/5G communications technology, a communications product
constantly strives for large power, miniaturization, and lightness. Consequently an
increasingly high requirement is imposed on a heat dissipation capability of a die
casting material of the communications product. Currently, a commonly used die casting
material of the communications product is mainly a die casting aluminum alloy. However,
common thermal conductivity of a die casting aluminum alloy in the communications
product industry is 90 W/(m·K) to 150 W/(m·K), and a requirement of a future product
with high heat flux density and large power cannot be met. In addition, a communications
die-casting fitting is usually in a complex structure with a large quantity of complex
thin-wall heat sink fins, higher and lower bosses, and deep-cavity structures, and
has relatively large dimensions. A heat sink fin layout of a future heat sink is to
be denser and thinner, and a fin shape is to be more complex. Therefore, a requirement
on casting fluidity of the die casting material of the communications product is to
be higher. Fluidity of an aluminum-silicon (Al-Si) series die casting aluminum alloy
commonly used in a current industry increases as content of silicon increases, and
the fluidity is the best in a eutectic composition, but thermal conductivity of the
alloy decreases at the same time. Therefore, it is difficult to have both a high heat-conducting
property and good formability.
[0003] Therefore, currently, to develop a die casting aluminum alloy with both a high heat-conducting
property and good formability has become an urgent need in the communications industry.
SUMMARY
[0004] In view of this, a first aspect of embodiments of the present invention provides
a die casting aluminum alloy that has both a high heat-conducting property and good
formability, to resolve a prior-art problem that forming and heat dissipation requirements
of a communications product with a complex structure, high heat flux density, and
large power cannot be met at the same time because it is difficult for a die casting
aluminum alloy to have both a high heat-conducting property and good formability.
[0005] Specifically, the first aspect of the embodiments of the present invention provides
the die casting aluminum alloy, including constituents with the following mass percentages:
silicon: 4.0% to 10.0%;
magnesium: 0.2% to 1.0%;
copper: ≤0.1 %;
manganese: ≤0.1 %;
zinc: ≤0.1 %;
ferrum: ≤1.3 %;
titanium: ≤0.2%.
in the embodiments of the present invention, content of the silicon in the die casting
aluminum alloy is controlled within 4.0% to 10.0% to improve thermal conductivity
of the aluminum alloy and ensure formability of the aluminum alloy, content of elements
such as the magnesium is also properly controlled so that the aluminum alloy has a
mechanical property and corrosion resistance, and total content of other elements
in the aluminum alloy other than aluminum is relatively low, to ensure that the aluminum
alloy has a relatively high heat-conducting property; and
inevitable impurities: ≤0.15%; and the rest: the aluminum.
[0006] In the first aspect of the present invention, a mass percentage of the silicon is
5.5% to 6.5%.
[0007] In the first aspect of the present invention, the mass percentage of the silicon
is 5.8% to 6.3%.
[0008] In the first aspect of the present invention, the mass percentage of the silicon
is 5.7%.
[0009] In the first aspect of the present invention, a mass percentage of the silicon is
4.3% to 5.0%.
[0010] In the first aspect of the present invention, the mass percentage of the silicon
is 4.4% to 4.8%.
[0011] In the first aspect of the present invention, a mass percentage of the silicon is
6.5% to 7.5%.
[0012] In the first aspect of the present invention, a mass percentage of the magnesium
is 0.3% to 0.8%.
[0013] In the first aspect of the present invention, the mass percentage of the magnesium
is 0.4% to 0.7%.
[0014] In the first aspect of the present invention, the mass percentage of the magnesium
is 0.5% to 0.6%.
[0015] In the first aspect of the present invention, a mass percentage of the copper is
0.001% to 0.05%.
[0016] In the first aspect of the present invention, the mass percentage of the copper is
0.01% to 0.03%.
[0017] In the first aspect of the present invention, a mass percentage of the manganese
is 0.001% to 0.006%.
[0018] In the first aspect of the present invention, the mass percentage of the manganese
is 0.002% to 0.004%.
[0019] In the first aspect of the present invention, a mass percentage of the zinc is 0.001%
to 0.02%.
[0020] In the first aspect of the present invention, the mass percentage of the zinc is
0.001% to 0.008%.
[0021] In the first aspect of the present invention, a mass percentage of the ferrum is
0.3% to 1.0%.
[0022] In the first aspect of the present invention, the mass percentage of the ferrum is
0.5% to 0.7%.
[0023] In the first aspect of the present invention, a mass percentage of the titanium is
0.001% to 0.06%.
[0024] In the first aspect of the present invention, the mass percentage of the titanium
is 0.01% to 0.03%.
[0025] A total mass percentage of elements other than the aluminum in the die casting aluminum
alloy in the present invention is less than 10%.
[0026] The total mass percentage of the elements other than the aluminum in the die casting
aluminum alloy in the present invention is 5.0% to 8.0%.
[0027] Phases inside an organization structure of the die casting aluminum alloy include
a hypoeutectic α-Al phase, a eutectic α-Al phase, a eutectic Si phase, and an intermetallic
compound, the intermetallic compound is distributed at a grain boundary location or
is precipitated in the hypoeutectic α-Al phase and the eutectic α-Al phase, and the
intermetallic compound includes an Mg
2Si phase. When the constituents of the die casting aluminum alloy further include
an element Fe and an element Cu, the intermetallic compound further includes an Al
3Fe phase, an Al
2Cu phase, and a ternary compound Al-Si-Fe phase.
[0028] In the present invention, a coefficient of thermal conductivity of the die casting
aluminum alloy is 170 W/(m·K) to 195 W/(m·K).
[0029] In the present invention, Brinell hardness of the die casting aluminum alloy is 60
HBW to 80 HBW, tensile strength is 170 MPa to 220 MPa, yield strength is greater than
or equal to 100 MPa, and an elongation rate is greater than or equal to 2%.
[0030] The die casting aluminum alloy provided in the first aspect of the embodiments of
the present invention has both a high heat-conducting property and good formability,
also has high corrosion resistance, a good mechanical property, and low costs, and
can meet forming and heat dissipation requirements of a communications product with
a complex structure.
[0031] A second aspect of the embodiments of the present invention provides a production
method of a die casting aluminum alloy, including the following steps:
providing raw materials based on constituents of a die casting aluminum alloy, and
performing heat treatment at any temperature within 180°C to 375°C after casting,
to obtain a die casting aluminum alloy, where the die casting aluminum alloy includes
constituents with the following mass percentages: silicon: 4.0% to 10.0%; magnesium:
0.2% to 1.0%; copper: ≤0.1%; manganese: ≤0.1%; zinc: ≤0.1%; ferrum: ≤1.3 %; titanium:
≤0.2%; inevitable impurities: ≤0.15%; and the rest: aluminum.
[0032] The foregoing heat treatment process may be at a constant temperature, or may be
at a non-constant temperature. In some implementations, a temperature may be selected
from 180°C to 375°C to perform heat treatment. In other implementations, a plurality
of temperatures may be separately selected from 180°C to 375°C as heat treatment temperatures
at a plurality of heat treatment stages.
[0033] In the production method in the present invention, the casting is performed through
liquid die casting, semi-solid die casting, vacuum die casting, investment casting,
gravity casting, or squeeze casting.
[0034] In the production method in the present invention, time for the heat treatment is
0.2h to 8h.
[0035] A process of the production method provided in the second aspect of the present invention
is simple, and the produced die casting aluminum alloy has both a high heat-conducting
property and good formability, and also has high corrosion resistance and a good mechanical
property.
[0036] A third aspect of the embodiments of the present invention provides a communications
product, including a housing and a power supply circuit and a functional circuit that
are located in the housing, where the power supply circuit supplies power to the functional
circuit, and the housing is obtained through casting by using the die casting aluminum
alloy according to the first aspect of the embodiments of the present invention.
[0037] The communications product provided in the third aspect of the embodiments of the
present invention has a high heat-conducting property, good formability, high corrosion
resistance, and a mechanical property, and can meet a design requirement for high
density and large power.
DESCRIPTION OF EMBODIMENTS
[0038] Embodiments of the present invention are described below with reference to some specific
implementations of the present invention.
[0039] As a communications product constantly strives for large power, miniaturization,
and lightness, the industry imposes an increasingly high requirement on a heat dissipation
capability of a die casting material of the communications product. Currently, a commonly
used die casting material of the communications product is mainly a die casting aluminum
alloy. However, common thermal conductivity of a die casting aluminum alloy in the
communications product industry is 90 W/(m·K) to 150 W/(m·K), and a requirement of
a future product with high heat flux density and large power cannot be met. In addition,
a communications die-casting fitting is usually in a complex structure with a large
quantity of complex thin-wall heat sink fins, higher and lower bosses, and deep-cavity
structures, and has relatively large dimensions. A heat sink fin layout of a future
heat sink is to be denser and thinner, and a fin shape is to be more complex. Therefore,
a requirement on casting fluidity of the die casting material of the communications
product is to be higher. Fluidity of an Al-Si series die casting aluminum alloy commonly
used in a current industry increases as content of silicon increases, and the fluidity
is the best in a eutectic composition, but thermal conductivity of the alloy decreases
at the same time. Therefore, it is difficult to have both a high heat-conducting property
and good formability. In view of this, currently, to develop a die casting aluminum
alloy with both a high heat-conducting property and good formability has become an
urgent need in the communications industry. In addition, because communications products
are used in a diversity of environments and are often in relatively poor environments,
such as seawater, acid rain, and an environment with alternate high and low temperatures,
and it needs to be ensured that the communications products are maintenance-free,
the die casting aluminum alloy needs to have both relatively high corrosion resistance
and a mechanical property.
[0040] Specifically, an embodiment of the present invention provides a die casting aluminum
alloy that has both a high heat-conducting property and good formability. The die
casting aluminum alloy includes constituents with the following mass percentages:
silicon: 4.0% to 8.0%;
magnesium: 0.2% to 1.0%;
copper: ≤0.1 %;
manganese: ≤0.1 %;
zinc: ≤0.1 %;
ferrum: ≤1.3 %;
titanium: ≤0.2%; and
inevitable impurities: ≤0.15%; and the rest: aluminum.
[0041] According to the high heat-conductive casting aluminum alloy provided in this embodiment
of the present invention, the constituents of the alloy are determined by comprehensively
considering contribution of each chemical element to an integrated performance index
(including thermal conductivity, fluidity, corrosion resistance, hardness, strength,
and the like) of the alloy, and with a joint effect of various elements of the foregoing
specific content, different types of performance are balanced, and a stable crystal
structure is formed, so that a die casting aluminum alloy with good integrated performance
is obtained.
[0042] Phases inside an organization structure of the die casting aluminum alloy in this
embodiment of the present invention include a hypoeutectic α-Al phase, a eutectic
α-Al phase, a eutectic Si phase, and an intermetallic compound, and the intermetallic
compound is distributed at a grain boundary location or is precipitated in the α-Al
phases. The phase means uniform and continuous components having a same chemical composition,
a same atom aggregation state, and a same atom property, and different phases are
separated by an interface. The intermetallic compound is a compound including a metal
and a metal, or a metal and a metalloid. Specifically, in a crystal structure of the
die casting aluminum alloy in the present invention, the intermetallic compound mainly
includes an Mg
2Si phase. When the constituents of the die casting aluminum alloy further include
an element Fe and an element Cu, the intermetallic compound further includes an Al
3Fe phase, an Al
2Cu phase, a ternary compound Al-Si-Fe phase, and the like. The ferrum, the copper,
the magnesium, the manganese, the zinc, and the titanium are partially solidly dissolved
in the hypoeutectic α-Al phase and the eutectic α-Al phase in a form of atoms. The
Al
2Cu phase and the Mg
2Si phase are uniformly dispersed and distributed.
[0043] Adding of the element silicon (Si) can improve casting fluidity of an Al-Si series
alloy, and in the alloy, Si and Al form an (α-Al+Si) eutectic phase. This is a main
reason why casting fluidity of the aluminum-silicon alloy is improved. However, thermal
conductivity of the alloy decreases as content of Si increases. For example, thermal
conductivity of an aluminum alloy with a Japanese designation ADC12 (in which content
of silicon is 9.6% to 12%) is only 95 W/(m·K). This is because a large amount of Si
in the Al-Si alloy exists mainly in a form of primary Si or eutectic Si or is solidly
dissolved in an Al matrix, and consequently the thermal conductivity of the alloy
greatly decreases. Therefore, to obtain relatively high thermal conductivity, Si needs
to be controlled at lower content. In consideration of both fluidity and thermal conductivity,
in this embodiment of the present invention, a mass percentage of the silicon is controlled
within 4.0% to 8.0%. Further, in an implementation of the present invention, the mass
percentage of the silicon is specifically controlled within 5.5% to 6.5%, and is further
5.8% to 6.3%, or 5.7%, or 6.0%. In another implementation of the present invention,
the mass percentage of the silicon is specifically controlled within 4.3% to 5.0%,
and is further 4.4% to 4.8%, or 4.5%, or 4.7%. In other implementations of the present
invention, the mass percentage of the silicon may alternatively be 6.5% to 7.5%, and
is further 7.0%.
[0044] The element magnesium (Mg) is a main strengthening element in the aluminum-silicon
alloy. Mg and Si form the Mg
2Si phase that is uniformly dispersed and distributed in the organization structure
of the alloy and performs a dispersion strengthening function. The dispersion strengthening
means a material strengthening effect achieved by organizing and mixing a plurality
of phases. The dispersion strengthening is essentially using dispersed ultra-fine
particles to hinder dislocation motion, thereby improving a mechanical property of
a material at a high temperature. When it is ensured that a weight ratio of Mg to
Si meets Mg/Si<1.73, higher content of the element Mg leads to a better mechanical
property of the alloy. However, excessive elements Mg lead to an increase in a grain
quantity and an increase in a grain boundary quantity of the grains. The grain boundary
is an interface between grains with a same structure and different orientations, in
other words, a contact interface between grains. At the crystal boundary, atom arrangement
is in transition from one orientation to another. The atom arrangement is in a transition
state at the crystal boundary. Consequently, a heat conduction path loses continuity
at the crystal boundary, and finally thermal conductivity of a material decreases.
Therefore, in consideration of both the mechanical property and the thermal conductivity,
in an implementation of the present invention, a mass percentage of the element Mg
is controlled within 0.2% to 1.0%. Further, in an implementation of the present invention,
the mass percentage of the magnesium is 0.3% to 0.8%, and is further 0.4% to 0.7%
or 0.5% to 0.6%.
[0045] The element copper (Cu) is also a main strengthening element in the aluminum-silicon
alloy. Cu and Al form the Al
2Cu phase that is uniformly dispersed and distributed in the organization structure
of the alloy and performs a dispersion strengthening function. Because solidly dissolved
copper has a high cathode effect on the alloy, a copper ion that enters a liquid corrosion
dielectric solution is re-plated on a surface of the aluminum alloy in a state of
a fine metallic copper grain, to form activity and even large galvanic corrosion,
thereby reducing corrosion resistance of the alloy. Specifically, the solidly dissolved
copper and a metal that is in the alloy and that has different potential from that
of the copper form a micro battery when there is the corrosion dielectric solution.
The copper acts as a cathode, and another metal with relatively negative potential
acts as an anode. In a battery reaction, the copper ion in the corrosion dielectric
solution is reduced to metallic copper and the metallic copper is deposited on a surface
of the aluminum alloy, thereby accelerating electrochemical corrosion. Therefore,
for obtaining superior corrosion resistance, content of the copper needs to be controlled
to control content of solidly dissolved copper, so as to reduce galvanic corrosion.
In an implementation of the present invention, a mass percentage of the element Cu
is controlled to be less than or equal to 0.1%. Further, in an implementation of the
present invention, the mass percentage of the copper is 0.001% to 0.05%, and further,
the mass percentage of the copper is 0.003% to 0.005%, or 0.008% to 0.01%, or 0.01%
to 0.03%, or 0.02% to 0.05%, or 0.03% to 0.04%. In another implementation of the present
invention, the mass percentage of the copper is 0.07% to 0.1%, and is further 0.08%
to 0.09%.
[0046] The element ferrum (Fe) forms a needle-like brittle phase in the die casting aluminum
alloy. Existence of the Fe splits a matrix, it is likely to cause stress concentration
around the brittle phase, and a fatigue crack or static load fracture occurs on the
alloy, thereby reducing a mechanical property of the alloy. Therefore, content of
Fe is limited to some extent. However, excessively low content of Fe leads to an increase
in a mold sticking risk during casting, and the element Fe has relatively small impact
on thermal conductivity. Therefore, after comprehensive consideration, a mass percentage
of the element Fe is controlled to be less than or equal to 1.3% in this embodiment
of the present invention. In an implementation of the present invention, the mass
percentage of the ferrum is 0.3% to 1.0%, and is further 0.5% to 0.7%, or 0.7% to
0.9%, or 0.8% to 1.0%. In an implementation of the present invention, the mass percentage
of the ferrum may alternatively be 0.2% to 0.4%, or 0.25% to 0.45%, or 1.1% to 1.2%.
[0047] Adding of the element manganese (Mn) may improve a mechanical property and corrosion
resistance of the aluminum-silicon alloy. However, Mn has relatively large impact
on thermal conductivity at the same time, and reduces a heat-conducting property of
the alloy. Therefore, a content range of the element Mn may be specifically determined
based on the content of the element Fe, and is specifically controlled to be less
than or equal to 0.1% in this embodiment of the present invention. In an implementation
of the present invention, a mass percentage of the manganese is 0.001% to 0.006%,
and is further 0.002% to 0.003%. In other implementations of the present invention,
a mass percentage of the manganese may alternatively be 0.004% to 0.005%, or 0.008%
to 0.01%, or 0.012% to 0.05%, or 0.04% to 0.06%, or 0.07% to 0.08%.
[0048] In an aluminum alloy casting process, the element titanium (Ti) preferentially reacts
with Al to form an Al
3Ti grain refiner that can convert α-Al grains from a thick branch shape into fine
and uniform equiaxed grains, so that strength and plasticity of the aluminum alloy
are improved, but a heat-conducting property of a material is reduced at the same
time. The Al
3Ti grain refiner has an excellent refinement effect, improves surface quality of castings
so that the castings obtain fine equiaxed grains, especially reduces casting cold
shuts and eliminates a trichite and a columnar crystal, and can effectively overcome
casting cracks and improve a casting appearance. The equiaxed grains are grains with
a relatively small grain dimension difference in all orientations. Therefore, in comprehensive
consideration of thermal conductivity and a mechanical property during actual production,
in this embodiment of the present invention, a mass percentage of the titanium is
controlled to be less than or equal to 0.2%. Further, in an implementation of the
present invention, the mass percentage of the titanium is 0.001% to 0.06%, and is
further 0.001% to 0.003%, or 0.01% to 0.03%, or 0.004% to 0.005%, or 0.008% to 0.01%,
or 0.012% to 0.05%, or 0.04% to 0.06%. In another implementation of the present invention,
the mass percentage of the titanium is greater than 0 and less than 0.001%. In other
implementations of the present invention, the mass percentage of the titanium may
alternatively be 0.07% to 0.08% or 0.1% to 0.15%.
[0049] In an implementation of the present invention, a mass percentage of the zinc is specifically
0.001% to 0.02%, and is further 0.001% to 0.008%. In another implementation of the
present invention, a mass percentage of the zinc is greater than 0 and less than or
equal to 0.001%. In other implementations of the present invention, a mass percentage
of the zinc may alternatively be 0.03% to 0.06%, or 0.07% to 0.08%, or 0.09% to 0.1%.
[0050] In an implementation of the present invention, because an increase in an impurity
element leads to reduction in thermal conductivity of a material, in this embodiment
of the present invention, content of the inevitable impurity elements is controlled
to be less than or equal to 0.15%.
[0051] In a specific implementation of the present invention, the die casting aluminum alloy
includes constituents with the following mass percentages: silicon: 5.8% to 6.3%;
magnesium: 0.3% to 0.4%; copper: <0.1%; manganese: <0.08%; zinc: <0.02%; ferrum: 0.2%
to 0.68%; titanium: <0.02%; inevitable impurities: ≤0.15%; and the rest: aluminum.
[0052] In another specific implementation of the present invention, the die casting aluminum
alloy includes constituents with the following mass percentages: silicon: 5.7%; magnesium:
0.33%; copper: 0.1%; manganese: 0.001%; zinc: <0.001%; ferrum: 0.58%; titanium: <0.001%;
inevitable impurities: ≤0.15%; and the rest: aluminum.
[0053] Adding of each element to pure metal aluminum leads to reduction in orderly arrangement
of a crystal lattice of a material, and leads to lattice distortion and limited periodic
motion of electrons, and a heat-conducting property and electrical conductivity of
the material are reduced. Therefore, in an implementation of the present invention,
for obtaining a relatively high heat-conducting property, a total mass percentage
of elements other than the aluminum in the die casting aluminum alloy is controlled
to be less than 10%, and is further controlled within 5.0% to 8.0%, or within 5.5%
to 7.5%, or within 6.0% to 6.5%.
[0054] In an implementation of the present invention, with a comprehensive effect of specific
content of specific elements, a coefficient of thermal conductivity of the die casting
aluminum alloy reaches 170 W/(m·K) to 195 W/(m·K), Brinell hardness is 60 HBW to 80
HBW, tensile strength is 170 MPa to 220 MPa, yield strength is greater than or equal
to 100 MPa, and an elongation rate is greater than or equal to 2%.
[0055] The tensile strength is a critical value at which a metal is in transition from uniform
plastic deformation to local-concentrated plastic deformation, and is also a maximum
bearing capability of the metal in a case of static stretching. The tensile strength
indicates resistance to maximum uniform plastic deformation of a material, and deformation
of a tensile sample is uniform and consistent before the tensile sample bears maximum
tensile stress. However, after the maximum tensile stress is exceeded, a necking phenomenon
starts to occur on the metal, to be specific, concentrated deformation occurs. The
yield strength is a yield limit when a yield phenomenon occurs on a metal material,
in other words, stress that resists microplastic deformation. For a metal material
on which no apparent yield phenomenon occurs, it is specified that a stress value
corresponding to residual deformation of 0.2% is used as a yield limit of the metal
material, and is referred to as a conditional yield limit or conditional yield strength.
The elongation rate is an index for describing plastic performance of a material,
and is a percentage of a ratio of total deformation ΔL of a gauge section after tensile
fracture of a sample to an original gauge length L.
[0056] The die casting aluminum alloy provided in this embodiment of the present invention
has a high heat-conducting property, good formability, high corrosion resistance,
and a mechanical property, can be applied to a harsh outdoor environment, can be used
for forming complex thin-wall castings (such as a heat sink) to meet a design requirement
for high density and large power, and can be specifically used in fields such as a
mobile phone, a notebook computer, a communications device industry, an automobile,
and civil hardware. More specifically, an embodiment of the present invention provides
a communications product, including a housing and a power supply circuit and a functional
circuit that are located in the housing, where the power supply circuit supplies power
to the functional circuit, and the housing is obtained through casting by using the
die casting aluminum alloy provided in the embodiments of the present invention. The
communications product may be a heat sink. Certainly, in the communications product,
another component that can use an aluminum alloy part may also be obtained through
casting by using the die casting aluminum alloy in the embodiments of the present
invention, such as a handle, a maintenance cavity cover, a guide rail, a rotating
shaft, and a supporting kit.
[0057] Correspondingly, an embodiment of the present invention further provides a production
method of a die casting aluminum alloy, including the following steps:
S10. Provide raw materials based on constituents of a die casting aluminum alloy,
and perform casting through liquid die casting, semi-solid die casting, vacuum die
casting, investment casting, gravity casting, or squeeze casting.
S20. Perform heat treatment within 180°C to 375°C after casting and cooling, to obtain
a die casting aluminum alloy, where the die casting aluminum alloy includes constituents
with the following mass percentages: silicon: 4.0% to 8.0%; magnesium: 0.2% to 1.0%;
copper: ≤0.1%; manganese: ≤0.1%; zinc: ≤0.1%; ferrum: ≤1.3 %; titanium: ≤0.2%; inevitable
impurities: ≤0.15%; and the rest: aluminum.
[0058] In the present invention, in step S10, all the liquid die casting, the semi-solid
die casting, the vacuum die casting, the investment casting, the gravity casting,
and the squeeze casting are existing conventional processes. Raw materials and process
parameters required for each process are not specially limited in the present invention,
and only need to be selected and set according to an industry requirement and an actual
requirement.
[0059] In the present invention, in step S20, further, a temperature for the heat treatment
is 200°C to 300°C or 240°C to 280°C. A heat treatment process may be at a constant
temperature, or may be at a non-constant temperature. Optionally, time for the heat
treatment is 0.2h to 8h, and further, the time for the heat treatment is 1h to 5h
or 2h to 6h. The heat treatment in the present invention can strengthen the alloy,
and can not only improve a mechanical property (such as strength, hardness, and an
elongation rate) of the alloy, but also improve physical performance (including density,
conductivity, and thermal conductivity) and electrochemical performance (including
solid solution potential) of castings. An alloy element more easily leads to reduction
in the conductivity and the thermal conductivity of the alloy when existing in a form
of a solid solution in comparison with being combined with another element to form
an intermetallic compound. Therefore, heat treatment is even needed during production
of a high heat-conductive and electricity-conductive component. After low-temperature
heat treatment of 180°C-375°C in the present invention, a point defect of the alloy
such as a vacancy or a solidly dissolved atom can be reduced. Specifically, at a relatively
low heat treatment temperature in the present invention, the vacancy may be transferred
from an interior of a material to a surface of the alloy and escapes, thereby reducing
lattice distortion of the alloy, and greatly improving thermal conductivity of the
alloy without reducing a mechanical property of the alloy. In addition, a dispersion
strengthening phase (such as Mg
2Si or Al
2Cu) is precipitated from a solid solution, thereby reducing content of a solidly dissolved
atom, so that strength and electrical conductivity of the alloy are optimized. In
the die casting aluminum alloy of the present invention, most elements Mg and Cu are
precipitated in a form of dispersion strengthening phases: Mg
2Si and Al
2Cu, and only a very small quantity of the elements exist inside an α-Al phase in a
form of a solidly dissolved atom.
[0060] Phases inside an organization structure of the die casting aluminum alloy produced
in this embodiment of the present invention include a hypoeutectic α-Al phase, a eutectic
α-Al phase, a eutectic Si phase, and an intermetallic compound, and the intermetallic
compound is distributed at a grain boundary location or is precipitated in the α-Al
phase. The intermetallic compound mainly includes an Al
3Fe phase, an Al
2Cu phase, an Mg
2Si phase, a ternary compound Al-Si-Fe phase, and the like. The ferrum, the copper,
the magnesium, the manganese, the zinc, and the titanium are partially solidly dissolved
in the hypoeutectic α-Al phase and the eutectic α-Al phase in a form of atoms. The
Al
2Cu phase and the Mg
2Si phase are uniformly dispersed and distributed.
[0061] In an implementation of the present invention, a mass percentage of the silicon is
specifically controlled within 5.5% to 6.5%, and is further 4.3% to 4.8% or 4.4% to
5.0%. In other implementations of the present invention, a mass percentage of the
silicon may alternatively be 4.5% to 5.0%, or 6.0% to 7.0%, or 6.5% to 7.5%.
[0062] In an implementation of the present invention, a mass percentage of the magnesium
is 0.3% to 0.7%, and is further 0.4% to 0.5% or 0.6% to 0.8%.
[0063] In an implementation of the present invention, a mass percentage of the copper is
0.001% to 0.05%. In another implementation of the present invention, a mass percentage
of the copper is 0.08% to 0.1%. In other implementations, a mass percentage of the
copper may alternatively be 0.003% to 0.005%, or 0.008% to 0.01%, or 0.02% to 0.05%,
or 0.04% to 0.06%.
[0064] In an implementation of the present invention, a mass percentage of the ferrum is
0.3% to 1.0%, and is further 0.5% to 0.7%. In an implementation of the present invention,
a mass percentage of the ferrum may alternatively be 0.25% to 0.45%, or 0.7% to 0.9%,
or 1.1% to 1.2%, or 0.8% to 1.0%.
[0065] In an implementation of the present invention, a mass percentage of the manganese
is 0.001% to 0.006%, and is further 0.002% to 0.003%. In other implementations of
the present invention, a mass percentage of the manganese may alternatively be 0.004%
to 0.005%, or 0.008% to 0.01%, or 0.012% to 0.05%, or 0.04% to 0.06%, or 0.07% to
0.08%.
[0066] In an implementation of the present invention, a mass percentage of the titanium
is 0.001% to 0.003%. In another implementation of the present invention, a mass percentage
of the titanium is greater than 0 and less than 0.001%.
[0067] In an implementation of the present invention, a mass percentage of the zinc is specifically
0.001% to 0.008%.
[0068] In another implementation of the present invention, a mass percentage of the zinc
is greater than 0 and less than or equal to 0.001%.
[0069] In a specific implementation of the present invention, the die casting aluminum alloy
includes constituents with the following mass percentages: silicon: 5.8% to 6.3%;
magnesium: 0.3% to 0.4%; copper: <0.1%; manganese: <0.08%; zinc: <0.02%; ferrum: 0.2%
to 0.68%; titanium: <0.02%; inevitable impurities: ≤0.15%; and the rest: aluminum.
[0070] In another specific implementation of the present invention, the die casting aluminum
alloy includes constituents with the following mass percentages: silicon: 5.7%; magnesium:
0.33%; copper: 0.1%; manganese: 0.001%; zinc: <0.001%; ferrum: 0.58%; titanium: <0.001%;
inevitable impurities: ≤0.15%; and the rest: aluminum.
[0071] A process of the production method of the die casting aluminum alloy provided in
this embodiment of the present invention is simple, and the produced die casting aluminum
alloy has a high heat-conducting property, good formability, high corrosion resistance,
and a good mechanical property.
[0072] The embodiments of the present invention are further described below by using a plurality
of embodiments.
Embodiment 1
[0073] A die casting aluminum alloy includes constituents with the following mass percentages:
silicon: 5.8% to 6.3%; magnesium: 0.3% to 0.4%; copper: <0.1%; manganese: <0.08%;
zinc: <0.02%; ferrum: 0.2% to 0.68%; titanium: <0.02%; inevitable impurities: ≤0.15%;
and the rest: aluminum.
[0074] A production method of a complex thin-wall communications housing that is obtained
through die casting by using the die casting aluminum alloy with the constituents
in this embodiment includes the following steps:
Based on the constituents of the foregoing die casting aluminum alloy, a pure aluminum
A00 aluminum ingot (whose purity is 99.7%), a pure magnesium ingot, an AlSi26 intermediate
alloy, an AlFe20 intermediate alloy, and the like are used as raw materials, melting,
semi-solid slurrying, and semi-solid die casting are performed on the raw materials,
and after cooling, 180°C to 375°C heat treatment is performed for 0.2 to 8 hours,
to obtain the thin-wall communications housing.
Embodiment 2
[0075] A die casting aluminum alloy includes constituents with the following mass percentages:
silicon: 5.7%; magnesium: 0.33%; copper: 0.1%; manganese: 0.001%; zinc: <0.001%; ferrum:
0.58%; titanium: <0.001%; inevitable impurities: ≤0.15%; and the rest: aluminum.
[0076] A complex thin-wall communications housing is obtained in the manner in Embodiment
1 of the present invention through die casting by using the die casting aluminum alloy
with the constituents in this embodiment.
Embodiment 3
[0077] A die casting aluminum alloy includes constituents with the following mass percentages:
silicon: 4.7%; magnesium: 0.33%; copper: ≤0.1%; manganese: <0.05%; zinc: <0.01%; ferrum:
0.58%; titanium: <0.1%; inevitable impurities: ≤0.15%; and the rest: aluminum.
[0078] A complex thin-wall communications housing is obtained in the manner in Embodiment
1 of the present invention through die casting by using the die casting aluminum alloy
with the constituents in this embodiment.
Embodiment 4
[0079] A die casting aluminum alloy includes constituents with the following mass percentages:
silicon: 4.5%; magnesium: 0.46%; copper: <0.1%; manganese: <0.1%; zinc: <0.001%; ferrum:
0.4% to 0.58%; titanium: ≤0.1%; inevitable impurities: ≤0.15%; and the rest: aluminum.
[0080] A complex thin-wall communications housing is obtained in the manner in Embodiment
1 of the present invention through die casting by using the die casting aluminum alloy
with the constituents in this embodiment.
Effect Embodiment
[0081] To provide strong support for beneficial effects brought by the technical solutions
in the embodiments of the present invention, the following product performance tests
are provided:
A comparison test is performed on the die casting aluminum alloys in Embodiment 1
to Embodiment 4 of the present invention and an ADC12 alloy in terms of thermal conductivity,
formability, and a mechanical property (including hardness, tensile strength, yield
strength, and an elongation rate). A result is as follows:
1. Thermal conductivity
[0082] A thermal conductivity test is performed on the die casting aluminum alloys in Embodiment
1 to Embodiment 4 of the present invention and the ADC12 alloy, and the thermal conductivity
test is performed by using a laser flash method (ASTM E 1461-01). Sample dimensions
are Φ12.7 mm×(2 to 4) mm. For heat, refer to ISO 11357 and ASTM E1269. For density,
refer to ISO 1183-1:2004. A thermal conductivity result of each alloy is shown in
Table 1.
Table 1 Comparison between thermal conductivity of alloys
Alloy designation |
Thermal conductivity (w/m·k) |
ADC12 |
95 |
Embodiment 1 |
185 |
Embodiment 2 |
190 |
Embodiment 3 |
182 |
Embodiment 4 |
180 |
[0083] It may be learned from the result in Table 1 that the die casting aluminum alloy
in the embodiments of the present invention has a better heat-conducting property
than that of the ADC12 aluminum alloy, and can meet a heat dissipation requirement
of a communications product with a complex structure, high heat flux density, and
large power.
2. Formability
[0084] Die casting is separately performed on three types of alloys: the alloys in Embodiment
1 and Embodiment 2 of the present invention and the ADC12 alloy, to obtain a complex
thin-wall communications housing. When formability of the alloy is poor, a short shot
defect is likely to occur on a thin-wall heat sink fin. According to existing statistics,
30 die-casting fittings are continuously produced by using each alloy. Statistical
results of maximum physical dimensions of each short shot feature on 25 heat sink
fins of the die-casting fittings are shown in Table 2. The maximum physical dimensions
(R) are described in three categories: 0.5 mm≤R≤1.0 mm, or 1.0 mm<R≤3 mm, or R>3 mm.
Table 2 Statistics of short shot features of different alloy die-casting fittings
Alloy designation |
Total defect quantity |
Short shot quantity: 0.5 mm≤R≤1.0 mm |
Short shot quantity: 1.0 mm<R≤3 mm |
Short shot quantity: R>3 mm |
ADC12 |
201 |
90 |
90 |
21 |
Embodiment 1 |
205 |
124 |
65 |
16 |
Embodiment 2 |
220 |
102 |
103 |
15 |
3. Corrosion resistance
[0085] A corrosion resistance test is performed on the die casting aluminum alloys in Embodiment
1 to Embodiment 4 of the present invention. Corrosion resistance of the die casting
aluminum alloy is compared with that of an existing alloy, and a result is shown in
Table 3. The corrosion resistance of the alloy is indicated by using a corrosion rate.
A test method for the corrosion rate complies with the standard GB/T19292.4 and the
standard GB/T 16545, and sample dimensions are 120 mm×100 mm×5 mm. For eliminating
an edge effect, an edge of a corrosion rate test sample is wrapped with an adhesive
tape. After 1440 h of a neutral salt spray test, an average corrosion rate is calculated
by using a weight change before and after salt spray.
Table 3 Comparison between corrosion rates of alloys
Alloy designation |
Corrosion rate (mg/(dm2×d)) |
ADC12 |
34.0 |
Embodiment 1 |
4.5 |
Embodiment 2 |
4.3 |
Embodiment 3 |
5.0 |
Embodiment 4 |
4.6 |
4. Mechanical property
[0086] Die casting is separately performed on the alloys in Embodiment 1 and Embodiment
2 of the present invention and the ADC12 alloy, to obtain a complex thin-wall communications
housing. A standard tensile mechanical test piece is cut from a product according
to a GB/T 228 requirement, and the mechanical property is tested on a tensile testing
machine. A result is shown in Table 4.
Table 4 Mechanical properties of alloys
Alloy designation |
Tensile strength (MPa) |
Yield strength (MPa) |
Elongation rate (%) |
Hardness (HBW) |
ADC12 |
260 |
≥100 |
0.7 |
92 |
Embodiment 1 |
210 |
136 |
4.6 |
79 |
Embodiment 2 |
199 |
132 |
4.0 |
70 |
[0087] It can be learned from the foregoing descriptions that the die casting aluminum alloy
obtained in the embodiments of the present invention has both a high heat-conducting
property and good formability, and also has high corrosion resistance and a good mechanical
property, thereby resolving a prior-art problem that a heat dissipation requirement
of a communications product with high heat flux density and large power cannot be
met because a heat-conducting property of a die casting aluminum alloy is poor. Therefore,
the following problems can be effectively avoided: a low yield rate of die-casting
fittings, severe burn-in caused due to heat emission of a product, corrosion in a
harsh environment such as a coastal area, assembling difficulties caused by an insufficient
mechanical property, or severe deformation in wind load.
1. A die casting aluminum alloy, consisting of constituents with the following mass percentages:
silicon: 4.0% to 10.0%;
magnesium: 0.2% to 1.0%;
copper: ≤0.1 %;
manganese: ≤0.1 %;
zinc: ≤0.1 %;
ferrum: ≤1.3 %;
titanium: ≤0.2%; and
inevitable impurities: ≤0.15%; and the rest: aluminum.
2. The die casting aluminum alloy according to claim 1, wherein a mass percentage of
the silicon is 5.5% to 6.5%.
3. The die casting aluminum alloy according to claim 2, wherein the mass percentage of
the silicon is 5.8% to 6.3%.
4. The die casting aluminum alloy according to claim 2, wherein the mass percentage of
the silicon is 5.7%.
5. The die casting aluminum alloy according to claim 1, wherein a mass percentage of
the silicon is 4.3% to 5.0%.
6. The die casting aluminum alloy according to claim 5, wherein the mass percentage of
the silicon is 4.4% to 4.8%.
7. The die casting aluminum alloy according to claim 1, wherein a mass percentage of
the silicon is 6.5% to 7.5%.
8. The die casting aluminum alloy according to any one of claims 1 to 7, wherein a mass
percentage of the magnesium is 0.3% to 0.8%.
9. The die casting aluminum alloy according to claim 8, wherein the mass percentage of
the magnesium is 0.4% to 0.7%.
10. The die casting aluminum alloy according to claim 9, wherein the mass percentage of
the magnesium is 0.5% to 0.6%.
11. The die casting aluminum alloy according to any one of claims 1 to 10, wherein a mass
percentage of the copper is 0.001% to 0.05%.
12. The die casting aluminum alloy according to claim 11, wherein the mass percentage
of the copper is 0.01% to 0.03%.
13. The die casting aluminum alloy according to any one of claims 1 to 12, wherein a mass
percentage of the manganese is 0.001% to 0.006%.
14. The die casting aluminum alloy according to claim 13, wherein the mass percentage
of the manganese is 0.002% to 0.004%.
15. The die casting aluminum alloy according to any one of claims 1 to 14, wherein a mass
percentage of the zinc is 0.001% to 0.02%.
16. The die casting aluminum alloy according to claim 15, wherein the mass percentage
of the zinc is 0.001% to 0.008%.
17. The die casting aluminum alloy according to any one of claims 1 to 16, wherein a mass
percentage of the ferrum is 0.3% to 1.0%.
18. The die casting aluminum alloy according to claim 17, wherein the mass percentage
of the ferrum is 0.5% to 0.7%.
19. The die casting aluminum alloy according to any one of claims 1 to 18, wherein a mass
percentage of the titanium is 0.001% to 0.06%.
20. The die casting aluminum alloy according to claim 19, wherein the mass percentage
of the titanium is 0.01% to 0.03%.
21. The die casting aluminum alloy according to any one of claims 1 to 20, wherein a total
mass percentage of elements other than the aluminum in the die casting aluminum alloy
is less than 10%.
22. The die casting aluminum alloy according to claim 21, wherein the total mass percentage
of the elements other than the aluminum in the die casting aluminum alloy is 5.0%
to 8.0%.
23. The die casting aluminum alloy according to claim 1, wherein phases inside an organization
structure of the die casting aluminum alloy comprise a hypoeutectic α-Al phase, a
eutectic α-Al phase, a eutectic Si phase, and an intermetallic compound, the intermetallic
compound is distributed at a grain boundary location or is precipitated in the hypoeutectic
α-Al phase and the eutectic α-Al phase, and the intermetallic compound comprises an
Mg2Si phase.
24. The die casting aluminum alloy according to any one of claims 1 to 23, wherein a coefficient
of thermal conductivity of the die casting aluminum alloy is 170 W/(m·K) to 195 W/(m·K).
25. The die casting aluminum alloy according to any one of claims 1 to 24, wherein Brinell
hardness of the die casting aluminum alloy is 60 HBW to 80 HBW, tensile strength is
170 MPa to 220 MPa, yield strength is greater than or equal to 100 MPa, and an elongation
rate is greater than or equal to 2%.
26. A communications product, comprising a housing and a power supply circuit and a functional
circuit that are located in the housing, wherein the power supply circuit supplies
power to the functional circuit, and the housing is obtained through casting by using
the die casting aluminum alloy according to any one of claims 1 to 25.