BACKGROUND OF THE INVENTION
Technical Field
The present invention
[0001] The invention belongs to the field of amorphous alloy thermoplastic forming, and
more particularly relates to a plastic forming and gradient toughening method and
a device based on ultrasonic vibration.
Description of the Related Art
[0002] Amorphous alloy is a novel material with excellent properties such as high strength,
corrosion resistance and wear resistance. Amorphous alloy exhibits good superplasticity
in the hot state and can achieve near net shape formation of parts. However, due to
the significant room temperature brittleness of the amorphous alloy, the amorphous
alloy parts may directly undergo brittle fracture and completely fail once they are
overloaded during service, making it difficult to directly apply the amorphous alloy
parts in occasions where impact loads are present. Therefore, it is necessary to further
improve the toughness of the amorphous alloy without impairing its excellent properties
so as to improve the impact resistance of the amorphous alloy parts.
[0003] The amorphous alloy is in a thermodynamically metastable state, and spontaneously
transformed to its thermodynamically stable state after obtaining sufficient energy,
that is, crystallization occurs. After the amorphous alloy is crystallized, its properties
are also changed. By forming nanocrystallines inside the amorphous alloy, the strength
and toughness of the amorphous alloy can be remarkably improved. Therefore, according
to the requirements of actual service conditions for the performance of amorphous
alloy parts, nanocrystallines can be induced locally in the amorphous matrix by some
means to form a nanocrystalline toughened amorphous matrix composite with a mechanical
property gradient.
[0004] Chinese Patent Publication No.
101736213 proposed a method for strengthening and toughening an amorphous alloy by ultrasonic
treatment, in which the amorphous alloy is strengthened and toughened by placing the
amorphous alloy in a cooling water tank with a temperature lower than the crystallization
temperature of the amorphous alloy and then applying an oscillation frequency with
a power less than 3×10
4 W/mm
2 per unit area at the bottom of the water tank. The amorphous alloy treated by the
method has a great improvement in plastic deformation capability at room temperature
and an increase in thermal discharge in relaxation, with the precondition that the
fracture strength is not changed. However, this method can only perform strengthening
and toughening treatment on the entire amorphous alloy sample, and cannot retain some
amorphous regions according to actual use requirements to form an amorphous matrix
composite with a mechanical property gradient; Chinese Patent Publication No.
102002659 proposed a method for continuously performing nanocrystallization on an amorphous
alloy strip, in which at a temperature below the glass transition temperature of the
amorphous alloy, the amorphous alloy strip is pressed on the top end of an amplitude
transformer of a power ultrasonic device, and the amplitude transformer of the ultrasonic
device exerts an ultrasonic effect on the amorphous alloy strip as the amorphous alloy
strip moves, thereby achieving continuous nanocrystallization of the amorphous alloy
strip. However, this method can only process the entire amorphous alloy strip, and
can neither process actual parts with complex shapes nor achieve nanocrystal gradient
toughening; Chinese Patent Publication No.
105420522 proposed a method for preparing an amorphous matrix composite, in which the flaky
amorphous alloy and the second phase toughening material are alternately laminated
and placed in a jig, and under a condition of constant pressure or increasing load,
the laminated amorphous alloy and porous plate are heated while ultrasonic vibration
is applied thereto, so that the amorphous alloy is rapidly softened and pressed into
the pores of the second phase toughening plate to obtain an amorphous matrix composite.
However, this method needs to introduce a second phase to perform overall toughening
treatment on the amorphous alloy, is only suitable for the processing of sheet products,
and cannot enable the processing of actual parts with complex shapes as well as local
nanocrystalline gradient toughening of the parts according to actual use requirements.
The above three strengthening and toughening methods are all not combined with the
thermoplastic forming process of the amorphous alloy, and thus the parts need to be
specially processed after being formed, resulting in complicated process and long
production cycle.
SUMMARY OF THE INVENTION
[0005] In view of the above-described defects or improvement requirements in the art, the
present invention provides a plastic forming and gradient toughening method and a
device based on ultrasonic vibration, which aims to achieve nanocrystallization of
a local region to be toughened on the amorphous alloy part by applying ultrasonic
vibration to the local region to be toughened with an insert connected to an ultrasonic
vibration amplitude transformer, thereby solving the technical problem of local toughening
during thermoplastic forming.
[0006] In order to achieve the above objective, according to an aspect of the present invention,
there is provided a plastic forming and gradient toughening method based on ultrasonic
vibration, characterized in that the toughening method comprising:
- (a) according to actual use requirements of an amorphous alloy part to be formed,
dividing one or more portions to be toughened on the amorphous alloy part to be formed,
the portion being used for generating a nanocrystalline toughening phase and an amorphous
state of other portions being retained;
- (b) designing a toughening device for forming the amorphous alloy part to be formed,
wherein the toughening device is connected to an external drive mechanism and comprises
one or more inserts connected to an ultrasonic vibration amplitude transformer and
one or more heating rods, the insert is disposed corresponding to the portion to be
toughened and used for applying ultrasonic vibration to the portion to be toughened,
the heating rod is used for heating raw material blank to be processed to a forming
temperature, and parameters of the ultrasonic vibration generated by the ultrasonic
vibration amplitude transformer are obtained by analyzing an energy propagation process
of the ultrasonic vibration by finite element numerical simulation, in which energy
of the ultrasonic vibration is adjusted by adjusting an amplitude, a frequency and
a power of the ultrasonic vibration, and when the energy of the ultrasonic vibration
exceeds an energy threshold value required for nanocrystallization, the corresponding
amplitude, frequency and power of the ultrasonic vibration are required parameters
of the ultrasonic vibration; and
- (c) placing raw material blank in the toughening device, heating the raw material
blank by the heating rod to a forming temperature, and performing mold closing of
the toughening device to form a required amorphous alloy part, ultrasonic vibration
being started in the mold closing process and stopped when mold opening is performed.
[0007] Preferably, the forming temperature is between a glass transition temperature and
a crystallization temperature of the raw material blank.
[0008] Further preferably, in the step (b), the heating rod is preferably a resistance heating
rod.
[0009] Further preferably, in the step (b), the toughening device is preferably a mold for
thermoplastic forming.
[0010] Further preferably, the amorphous alloy is a Pd, Pt, Au, Zr, Ti, Fe, Cu, Ni, Al,
Mg or Ce based amorphous alloy with a thermoplastic forming ability.
[0011] According to another aspect of the present invention, there is provided a device
for use in the above toughening method, characterized in that the device comprises
an upper mold, a lower mold and a female mold,
[0012] the upper mold and the lower mold are oppositely disposed and form a mold cavity
with the female mold, the upper mold and the lower mold are respectively provided
with a punch and one or more inserts, the punches are connected to a driving servo
press and used to form raw material blank into a desired three-dimensional structure,
the inserts are connected to an ultrasonic vibration amplitude transformer and used
to apply ultrasonic vibration to one or more portions to be toughened, the female
mold is provided with one or more heating rod for heating the raw material blank.
[0013] In general, by comparing the above technical solution of the present inventive concept
with the prior art, the present invention has the following beneficial effects:
- 1. in the present invention, an insert which is partially connected with an ultrasonic
vibration amplitude transformer is disposed corresponding to a portion to be toughened
to apply ultrasonic vibration to the portion, thereby achieving nanocrystallization
process. The nanocrystallization process and the thermoplastic forming process are
simultaneously carried out without additional processing after the parts are formed,
which simplifies production processes and shortens the forming time;
- 2. in the present invention, ultrasonic vibration is adopted to improve the toughness
of the material, since the ultrasonic vibration can significantly improve the forming
ability of the material, and the propagation of the ultrasonic vibration wave has
strong directionality so that the vibration energy distribution of the ultrasonic
vibration wave can be precisely controlled. Therefore, nanocrystallization can be
facilitated by using the ultrasonic vibration to achieve amorphous alloy toughening;
- 3. in the present invention, one or more resistance heating rods are used, so that
the forming temperature in the thermoplastic forming process is ensured on the one
hand, and the uniformity of the temperature field inside the mold can be ensured by
adjusting the distribution of the resistance heating rods on the other hand; and
- 4. in the method based ultrasonic vibration according to the present invention, nanocrystallization
toughening and thermoplastic forming of an amorphous alloy part are combined to achieve
integration of forming and toughening, which simplifies production processes, shortens
the processing time and improves the dimensional accuracy. Meanwhile, according to
the actual service conditions of the amorphous alloy part, the microstructure of an
amorphous alloy-based composite with a mechanical property gradient is formed inside
the part, which can significantly improve the overall performance of the part.
BRIEF DESCRIPTION OF THE DRAWINGS
[0014]
FIG. 1 is a flow chart of a toughening method according to a preferred embodiment
of the present invention; and
FIG. 2 is a schematic structural diagram of an amorphous alloy gear member forming
device according to the preferred embodiment of the present invention.
[0015] In all figures, the same elements or structures are denoted by the same reference
numerals, in which:
- 1-upper ultrasonic vibration ring, 2-upper punch, 3-heating rod, 4-female mold, 5-raw
material blank, 6-lower ultrasonic vibration ring, and 7-lower punch.
DETAILED DESCRIPTION OF THE EMBODIMENTS
[0016] For clear understanding of the objectives, features and advantages of the present
invention, detailed description of the present invention will be given below in conjunction
with accompanying drawings and specific embodiments. It should be noted that the embodiments
described herein are only meant to explain the present invention, and not to limit
the scope of the present invention. Furthermore, the technical features related to
the embodiments of the invention described below can be mutually combined if they
are not found to be mutually exclusive.
[0017] FIG. 1 is a flow chart of a toughening method according to a preferred embodiment
of the present invention, and as shown in FIG. 1, a plastic forming and gradient toughening
method based on ultrasonic vibration is illustrated, the method comprising:
- (1) According to actual use requirements of the amorphous alloy part, the amorphous
state is retained in a portion requiring high strength, strong corrosion resistance
and wear resistance, and the nanocrystalline toughening phase is formed in a portion
requiring high toughness. Therefore, in the design of the thermoplastic forming process,
ultrasonic vibration is applied to the portion where the nanocrystalline toughening
phase needs to be formed, and the ultrasonic vibration is not applied to the portion
where the amorphous state needs to be retained.
- (2) In the mold design, one or more inserts connected to the ultrasonic vibration
amplitude transformer are disposed in one or more portions where ultrasonic vibration
is required; the amplitude, frequency and power of the ultrasonic vibration are determined
by analyzing the energy propagation process of the ultrasonic vibration by finite
element numerical simulation and adjusting the amplitude, frequency and power of the
ultrasonic vibration such that the vibration energy in the toughening target region
exceeds the energy threshold value for nanocrystallization; and one or more resistance
heating rods are embedded in the mold to heat the blank to a set forming temperature,
and the mold is integrally mounted on a servo press.
- (3) Integration of forming and toughening
[0018] The amorphous alloy blank is placed in the mold cavity and heated by the one or more
resistance heating rods to a temperature between a glass transition temperature and
a crystallization temperature. The lower mold and the female mold are kept stationary,
and ultrasonic vibration is started after the upper mold is moved down and comes into
contact with the blank. The upper mold continues to be moved down until the upper
mold, the lower mold and the female mold are completely closed to obtain a desired
amorphous alloy part. The ultrasonic vibration is stopped, and the upper mold is moved
up to be separated from the part. The lower mold is moved up until the part is pushed
out of the female mold.
[0019] The present invention will be further described in detail below with reference to
the embodiment and the accompanying drawings.
[0020] FIG. 2 is a schematic structural diagram of an amorphous alloy gear member forming
device according to the preferred embodiment of the present invention, and as shown
in FIG. 2, ultrasonic vibration assisted hot closed-die forging forming of the amorphous
alloy gear member is illustrated.
[0021] Since gear failure mainly occurs in the tooth portion, it is necessary to perform
nanocrystallization toughening of the tooth portion while retaining the amorphous
state of the spoke portion, so as to improve the impact resistance of the amorphous
alloy gear member. According to this demand, a forming device as shown in FIG. 2 was
designed.
[0022] The forming device is composed of three parts of an upper mold, a lower mold and
a female mold 4. In the forming device, the upper mold is composed of an upper ultrasonic
vibration ring 1 and an upper punch 2, the upper punch 2 is embedded in the upper
ultrasonic vibration ring 2, and the upper punch 2 is provided with a shoulder for
limiting the movement of the upper ultrasonic vibration ring 1. The lower mold is
composed of a lower ultrasonic vibration ring 6 and a lower punch 7, the lower punch
7 is embedded in the lower ultrasonic vibration ring 6, and the lower punch 7 is provided
with a shoulder for limiting the movement of the lower ultrasonic vibration ring 6.
The upper punch 2 is connected to an upper slider of a servo press. The lower punch
7 is connected to a lower slider of the servo press. The upper ultrasonic vibration
ring 1 and the lower ultrasonic vibration ring 6 are respectively connected to an
ultrasonic generator. An inner wall of the female mold 4 is machined in a tooth shape,
and one or more resistance heating rods 3 are embedded in the female mold 4.
[0023] At the time of forming, a cylindrical blank 5 is first placed inside the female mold
4. The resistance heating rods 3 are started to heat the blank 5 to a set temperature.
The lower molds (6 and 7) and the female mold 4 are kept stationary. The upper punch
2 drives the upper ultrasonic vibration ring 1 to move down until they come into contact
with the upper surface of the blank 5. The upper ultrasonic vibration ring 1 and the
lower ultrasonic vibration ring 6 are started to vibrate at a set frequency and amplitude.
The upper punch 2 continues to drive the upper ultrasonic vibration ring 1 to move
down at a set loading rate until the female mold 4 is completely filled by the blank
5. In this process, the ultrasonic vibration concentrates on the edge portion of the
blank 5, that is, the tooth portion of the gear member. On the one hand, filling of
the material into the mold cavity can be significantly facilitated, and the dimensional
accuracy of the part can be improved; on the other hand, nanocrystallization is induced
in the tooth portion to achieve toughening, while the amorphous state of the spoke
portion is retained. The ultrasonic vibration of the upper ultrasonic vibration ring
1 and the lower ultrasonic vibration ring 6 and the resistance heating rod 3 are closed.
The upper ultrasonic vibration ring 1, the upper punch 2, the lower ultrasonic vibration
ring 6 and the lower punch 7 are moved up together at the same speed until the formed
part 5 is pushed out of the inner cavity of the female mold 5. At this time, the forming
process is finished.
[0024] It should be readily understood to those skilled in the art that the above description
is only preferred embodiments of the present invention, and does not limit the scope
of the present invention. Any change, equivalent substitution and modification made
without departing from the spirit and scope of the present invention should be included
within the scope of the protection of the present invention.
1. A plastic forming and gradient toughening method based on ultrasonic vibration,
characterized in that the toughening method comprising:
(a) according to actual use requirements of an amorphous alloy part to be formed,
dividing one or more portions to be toughened on the amorphous alloy part to be formed,
the portion being used for generating a nanocrystalline toughening phase and an amorphous
state of other portions being retained;
(b) designing a toughening device for forming the amorphous alloy part to be formed,
wherein the toughening device is connected to an external drive mechanism and comprises
one or more inserts connected to an ultrasonic vibration amplitude transformer and
one or more heating rods, the insert is disposed corresponding to the portion to be
toughened and used for applying ultrasonic vibration to the portion to be toughened,
the heating rod is used for heating raw material blank to be processed to a forming
temperature, and parameters of the ultrasonic vibration generated by the ultrasonic
vibration amplitude transformer are obtained by analyzing an energy propagation process
of the ultrasonic vibration by finite element numerical simulation, in which energy
of the ultrasonic vibration is adjusted by adjusting an amplitude, a frequency and
a power of the ultrasonic vibration, and when the energy of the ultrasonic vibration
exceeds an energy threshold value required for nanocrystallization, the corresponding
amplitude, frequency and power of the ultrasonic vibration are required parameters
of the ultrasonic vibration; and
(c) placing raw material blank in the toughening device, heating the raw material
blank by the heating rod to a forming temperature, and performing mold closing of
the toughening device to form a required amorphous alloy part, ultrasonic vibration
being started in the mold closing process and stopped when mold opening is performed.
2. The plastic forming and gradient toughening method based on ultrasonic vibration according
to claim 1, characterized in that the forming temperature is between a glass transition temperature and a crystallization
temperature of the raw material blank.
3. The plastic forming and gradient toughening method based on ultrasonic vibration according
to claim 1 or 2, characterized in that in the step (b), the heating rod is preferably a resistance heating rod.
4. The plastic forming and gradient toughening method based on ultrasonic vibration according
to any one of claims 1-3, characterized in that in the step (b), the toughening device is preferably a mold for thermoplastic forming.
5. The plastic forming and gradient toughening method based on ultrasonic vibration according
to any one of claims 1-4, characterized in that the amorphous alloy is a Pd, Pt, Au, Zr, Ti, Fe, Cu, Ni, Al, Mg or Ce based amorphous
alloy with a thermoplastic forming ability.
6. A device for use in the toughening method according to any one of claims 1-5, characterized in that the device comprises an upper mold, a lower mold and a female mold,
the upper mold and the lower mold are oppositely disposed and form a mold cavity with
the female mold, the upper mold and the lower mold are respectively provided with
a punch and one or more inserts, the punches are connected to a driving servo press
and used to form raw material blank into a desired three-dimensional structure, the
inserts are connected to an ultrasonic vibration amplitude transformer and used to
apply ultrasonic vibration to one or more portions to be toughened, the female mold
is provided with one or more heating rod for heating the raw material blank.