Technical Field
[0001] The present invention relates to a continuous steel casting method that includes
continuously casting molten steel while applying an AC magnetic field to molten steel
present in a mold and controlling, via the AC magnetic field, the flow of the molten
steel present in the mold.
Background Art
[0002] In recent years, quality requirements of high-quality steel sheet products, such
as automotive steel sheets, steel sheets for cans, and high-functionality steel plates
have become stricter. It is desired that a slab strand as produced by continuous casting
be of high quality. One of the properties a slab strand (hereinafter also simply referred
to as a "strand") is required to have is the property that the number of oxide-based
non-metallic inclusions (hereinafter simply referred to as "inclusions") in the surface
portion and the inner portion of the strand is small.
[0003] Examples of inclusions entrapped in the surface portion and the inner portion of
a strand include the following: (1) deoxidation products produced in the step of deoxidizing
molten steel with aluminum or the like and suspended in the molten steel; (2) bubbles
of argon gas injected into the molten steel present in the tundish or the submerged
entry nozzle; and (3) molding powder sprayed onto the surface of the in-mold molten
steel and subsequently entrained and suspended in the molten steel. All of these inclusions
form surface defects or internal defects in final products, and it is therefore important
to reduce inclusions that are entrapped in the surface portion and the inner portion
of a strand.
[0004] In the related art, one technique used to prevent product defects due to inclusions
is to control the flow of molten steel by applying a magnetic field to the molten
steel in a mold and utilizing an electromagnetic force due to the magnetic field to
prevent deoxidation products, molding powder, and argon bubbles in the molten steel
from being entrapped in the solidified shell. Numerous proposals have been made with
regard to this technology.
[0005] For example, Patent Literature 1 discloses the following technology. An AC magnetic
field is applied to a discharge flow discharged from a submerged entry nozzle submerged
in the in-mold molten steel, thereby imparting a braking force or horizontal rotating
force to the discharge flow in a manner such that the molten steel flow velocity at
the surface of the in-mold molten steel is within a range of an inclusion-adherence
critical flow velocity or more to a molding-powder entrainment critical flow velocity
or less.
[0006] Patent Literature 2 discloses a method for continuously casting molten steel. In
the method, the upper ends of AC magnetic field generation devices are positioned
20 to 60 mm below the surface of the in-mold molten steel, and a submerged entry nozzle
having an angle of 1 to 30° in a downward direction is used, whereby the discharge
flow from the submerged entry nozzle is controlled so that the discharge flow can
impinge on the solidified shell at portions within a range from a center of each of
the AC magnetic field generation devices to a position 450 mm downward therefrom.
[0007] Furthermore, Patent Literature 3 discloses a method for continuously casting molten
steel. In the method, to impart a swirling and stirring flow to the in-mold molten
steel in the mold width direction via AC magnetic field generation devices, discharge
ports of a submerged entry nozzle are positioned at locations where the magnetic flux
density at the discharge ports is less than or equal to 50% of the maximum magnetic
flux density of the AC magnetic field generation devices.
Citation List
Patent Literature
[0008]
PTL 1: Japanese Unexamined Patent Application Publication No. 2003-320440
PTL 2: Japanese Unexamined Patent Application Publication No. 2000-202603
PTL 3: Japanese Unexamined Patent Application Publication No. 2001-047201
Summary of Invention
Technical Problem
[0009] Unfortunately, the related-art technologies described above pose the following problems.
[0010] Specifically, in the method of Patent Literature 1, the flow is controlled by imparting
a braking force or horizontal stirring force to the discharge flow discharged from
a submerged entry nozzle, in accordance with the value of the molten steel flow velocity,
which is a velocity at the surface of the in-mold molten steel, and therefore the
method requires an instrument for measuring or monitoring the molten steel flow velocity,
which is a velocity at the surface of the in-mold molten steel. Furthermore, there
is a concern that in a case where the placement locations of the AC magnetic field
generation devices, which are each placed on a back surface of the mold, are changed,
the accuracy of the critical flow velocity prediction formula may deteriorate. It
is therefore difficult to say that the technology is a technology that is applicable
regardless of at which portion of a back surface of a mold an AC magnetic field generation
device is placed.
[0011] The technology of Patent Literature 2 is a technology that focuses on the location
of impingement of the discharge flow discharged from the submerged entry nozzle, but
the technology is limited to cases in which AC magnetic field generation devices are
placed near the surface of the in-mold molten steel and is therefore not applicable
to cases in which AC magnetic field generation devices are placed at a relatively
low location with respect to the surface of the in-mold molten steel.
[0012] Similarly to Patent Literature 2, Patent Literature 3 is also limited to cases in
which AC magnetic field generation devices are placed near the surface of the in-mold
molten steel. Furthermore, the discharge ports of the submerged entry nozzle are provided
at locations where the magnetic flux density is less than or equal to 50% of the maximum
magnetic flux density, but, in this case, the following concern may arise. Since the
discharge flow discharged from the submerged entry nozzle flows downward relative
to the AC magnetic field generation devices, inclusions and the like may sink into
regions below the AC magnetic field generation devices and cause internal defects
in the strand.
[0013] The present invention has been made in view of the above circumstances, and an object
of the present invention is to provide a continuous steel casting method that enables
production of a high-quality strand, which is achieved as follows. In a continuous
steel casting method in which a swirling and stirring flow is created in in-mold molten
steel by applying an AC magnetic field to the in-mold molten steel from AC magnetic
field generation devices that are placed with mold long sides positioned therebetween,
an appropriate AC magnetic flux density is provided in accordance with the distance
from the surface of the in-mold molten steel to the location of the peak of the AC
magnetic field and with the submergence depth of the submerged entry nozzle.
Solution to Problem
[0014] A summary of the present invention, which is provided to solve the problems described
above, is as follows.
- [1] A continuous steel casting method, the method including producing a strand, the
producing of the strand including pouring molten steel into a mold for continuous
casting and withdrawing a solidified shell from the mold, the solidified shell being
a solidified portion of the molten steel, the mold having a pair of mold long sides
and a pair of mold short sides with a rectangular interior space being defined within
the mold,
the method including applying an AC magnetic field to in-mold molten steel via AC
magnetic field generation devices, thereby creating, via the AC magnetic field, a
horizontal swirling and stirring flow in the in-mold molten steel, each of the AC
magnetic field generation devices being placed on a back surface of a corresponding
one of the pair of mold long sides, the AC magnetic field generation devices facing
each other with the mold long sides being positioned therebetween, wherein
a spacing between the mold long sides that face each other is 200 to 300 mm,
a submerged entry nozzle has two discharge ports for pouring molten steel into the
interior space, each of the discharge ports having a discharge angle within a range
of 5° in a downward direction to 50° in a downward direction,
the AC magnetic field has a frequency of 0.5 Hz or greater and 3.0 Hz or less,
a distance from a surface of the in-mold molten steel to a location of a peak of the
AC magnetic field is 200 mm or greater and less than 300 mm,
a submergence depth of the submerged entry nozzle (a distance from the surface of
the in-mold molten steel to an upper end of the discharge ports of the submerged entry
nozzle) is 100 mm or greater and less than 200 mm, and
a magnetic flux density at the location of the peak of the AC magnetic field is 0.040
T or greater and less than 0.060 T.
- [2] A continuous steel casting method, the method including producing a strand, the
producing of the strand including pouring molten steel into a mold for continuous
casting and withdrawing a solidified shell from the mold, the solidified shell being
a solidified portion of the molten steel, the mold having a pair of mold long sides
and a pair of mold short sides with a rectangular interior space being defined within
the mold,
the method including applying an AC magnetic field to in-mold molten steel via AC
magnetic field generation devices, thereby creating, via the AC magnetic field, a
horizontal swirling and stirring flow in the in-mold molten steel, each of the AC
magnetic field generation devices being placed on a back surface of a corresponding
one of the pair of mold long sides, the AC magnetic field generation devices facing
each other with the mold long sides being positioned therebetween, wherein
a spacing between the mold long sides that face each other is 200 to 300 mm,
a submerged entry nozzle has two discharge ports for pouring molten steel into the
interior space, each of the discharge ports having a discharge angle within a range
of 5° in a downward direction to 50° in a downward direction,
the AC magnetic field has a frequency of 0.5 Hz or greater and 3.0 Hz or less,
a distance from a surface of the in-mold molten steel to a location of a peak of the
AC magnetic field is 300 mm or greater and less than 400 mm,
a submergence depth of the submerged entry nozzle (a distance from the surface of
the in-mold molten steel to an upper end of the discharge ports of the submerged entry
nozzle) is 100 mm or greater and less than 300 mm, and
a magnetic flux density at the location of the peak of the AC magnetic field is 0.060
T or greater and less than 0.080 T.
- [3] A continuous steel casting method, the method including producing a strand, the
producing of the strand including pouring molten steel into a mold for continuous
casting and withdrawing a solidified shell from the mold, the solidified shell being
a solidified portion of the molten steel, the mold having a pair of mold long sides
and a pair of mold short sides with a rectangular interior space being defined within
the mold,
the method including applying an AC magnetic field to in-mold molten steel via AC
magnetic field generation devices, thereby creating, via the AC magnetic field, a
horizontal swirling and stirring flow in the in-mold molten steel, each of the AC
magnetic field generation devices being placed on a back surface of a corresponding
one of the pair of mold long sides, the AC magnetic field generation devices facing
each other with the mold long sides being positioned therebetween, wherein
a spacing between the mold long sides that face each other is 200 to 300 mm,
a submerged entry nozzle has two discharge ports for pouring molten steel into the
interior space, each of the discharge ports having a discharge angle within a range
of 5° in a downward direction to 50° in a downward direction,
the AC magnetic field has a frequency of 0.5 Hz or greater and 3.0 Hz or less,
a distance from a surface of the in-mold molten steel to a location of a peak of the
AC magnetic field is 400 mm or greater and less than 500 mm,
a submergence depth of the submerged entry nozzle (a distance from the surface of
the in-mold molten steel to an upper end of the discharge ports of the submerged entry
nozzle) is 100 mm or greater and less than 300 mm, and
a magnetic flux density at the location of the peak of the AC magnetic field is 0.080
T or greater and less than 0.100 T.
- [4] A continuous steel casting method, the method including producing a strand, the
producing of the strand including pouring molten steel into a mold for continuous
casting and withdrawing a solidified shell from the mold, the solidified shell being
a solidified portion of the molten steel, the mold having a pair of mold long sides
and a pair of mold short sides with a rectangular interior space being defined within
the mold,
the method including applying an AC magnetic field to in-mold molten steel via AC
magnetic field generation devices, thereby creating, via the AC magnetic field, a
horizontal swirling and stirring flow in the in-mold molten steel, each of the AC
magnetic field generation devices being placed on a back surface of a corresponding
one of the pair of mold long sides, the AC magnetic field generation devices facing
each other with the mold long sides being positioned therebetween, wherein
a spacing between the mold long sides that face each other is 200 to 300 mm,
a submerged entry nozzle has two discharge ports for pouring molten steel into the
interior space, each of the discharge ports having a discharge angle within a range
of 5° in a downward direction to 50° in a downward direction,
the AC magnetic field has a frequency of 0.5 Hz or greater and 3.0 Hz or less, and
in accordance with a location of a peak of the AC magnetic field, a submergence depth
of the submerged entry nozzle (a distance from the surface of the in-mold molten steel
to an upper end of the discharge ports of the submerged entry nozzle) and a magnetic
flux density at the location of the peak of the AC magnetic field generated by the
AC magnetic field generation devices are determined to satisfy one of three types
of conditions described below, namely conditions (A), conditions (B), and conditions
(C), conditions (A): when the distance from the surface of the in-mold molten steel
to the location of the peak of the AC magnetic field is 200 mm or greater and less
than 300 mm, the submergence depth of the submerged entry nozzle is 100 mm or greater
and less than 200 mm, and the magnetic flux density at the location of the peak of
the AC magnetic field is 0.040 T or greater and less than 0.060 T,
conditions (B): when the distance from the surface of the in-mold molten steel to
the location of the peak of the AC magnetic field is 300 mm or greater and less than
400 mm, the submergence depth of the submerged entry nozzle is 100 mm or greater and
less than 300 mm, and the magnetic flux density at the location of the peak of the
AC magnetic field is 0.060 T or greater and less than 0.080 T, and conditions (C):
when the distance from the surface of the in-mold molten steel to the location of
the peak of the AC magnetic field is 400 mm or greater and less than 500 mm, the submergence
depth of the submerged entry nozzle is 100 mm or greater and less than 300 mm, and
the magnetic flux density at the location of the peak of the AC magnetic field is
0.080 T or greater and less than 0.100 T.
Advantageous Effects of Invention
[0015] With the present invention, a high-quality strand can be produced easily because
a swirling and stirring flow is imparted to in-mold molten steel by applying an AC
magnetic field with an appropriate magnetic flux density in accordance with the distance
from the surface of the in-mold molten steel to the location of the peak of the AC
magnetic field and with the submergence depth of the submerged entry nozzle, so that
deoxidation products, argon gas bubbles, and molding powder are inhibited from being
entrapped in the solidified shell.
Brief Description of Drawings
[0016]
[Fig. 1] Fig. 1 is a diagram illustrating an example of an embodiment of the present
invention, schematically illustrating a mold portion of a continuous slab casting
machine.
[Fig. 2] Fig. 2 is an enlarged view of a submerged entry nozzle illustrated in Fig.
1.
Description of Embodiments
[0017] An embodiment of the present invention will now be described.
[0018] With regard to a continuous steel casting method including applying an AC magnetic
field to molten steel present in a mold and creating, via the AC magnetic field, a
horizontal swirling and stirring flow in the molten steel present in the mold, the
present inventors conducted a test and an investigation regarding the flow status
of molten steel present in the mold by using a low-melting-point alloy apparatus.
In the test, a mold having a pair of mold long sides and a pair of mold short sides,
which define a rectangular interior space, was used; a submerged entry nozzle having
two discharge ports (hereinafter also referred to as a "2-port submerged entry nozzle")
was placed in a middle portion of the interior space; a situation in which a discharge
flow of the molten steel is discharged from each of the discharge ports toward a corresponding
one of the mold short sides was simulated; and, the flow status of the molten steel
present in the mold, particularly in cases where the location of the peak of the AC
magnetic field and the submergence depth of the submerged entry nozzle were varied,
was tested.
[0019] Here, the location of the peak of an AC magnetic field is as follows. When the maximum
value among root mean square values of the orthogonal component of the magnetic flux
density of the AC magnetic field is determined for locations positioned along the
mold inner wall surfaces surrounding the interior space of a mold, the location where
the maximum value is greatest is the location of the peak of the AC magnetic field,
the root mean square values being periodically obtained, the orthogonal component
being orthogonal to a corresponding one of the inner wall surfaces. Furthermore, the
submergence depth of a submerged entry nozzle is defined as the distance from the
surface (also referred to as the "meniscus") of the in-mold molten steel to the upper
end of a discharge port of the submerged entry nozzle.
[0020] In the test, the placement locations of AC magnetic field generation devices, which
were placed facing each other on the back surfaces of the mold long sides, were varied,
and the placement location of the submerged entry nozzle, that is, the submergence
depth, was varied, and, in those cases, the flow status of a low-melting-point alloy
in the mold, the flow velocity distribution thereof in the mold, and the like were
investigated by utilizing numerical simulation and a low-melting-point alloy apparatus,
which is one-fourth the size of an actual machine. The low-melting-point alloy used
was a Bi-Pb-Sn-Cd alloy (melting point: 70°C) .
[0021] The investigations revealed that appropriate application ranges for the magnetic
flux density of an AC magnetic field exist in association with the location of the
peak of the AC magnetic field and the submergence depth of a submerged entry nozzle.
That is, it was found that the conditions for AC magnetic field application can generally
be classified into three types, namely conditions (A) to (C), depending on the location
of the peak of the AC magnetic field and the submergence depth of the submerged entry
nozzle. The results of the investigations are shown in Table 1. Note that the location
of the peak of the AC magnetic field is expressed as the distance from the surface
of the in-mold molten steel to the location of the peak of the AC magnetic field.
[Table 1]
|
Distance from meniscus to AC magnetic field peak location |
Frequency of AC magnetic field |
Discharge angle of submerged entry nozzle |
Submergence depth of submerged entry nozzle |
Magnetic flux density at AC magnetic field peak location |
Conditions (A) |
200 mm or greater and less than 300 mm |
0.5 Hz or greater and 3.0 Hz or less |
Range of 5° in downward direction to 50° in downward direction |
100 mm or greater and less than 200 mm |
0.040 T or greater and less than 0.060 T |
Conditions (B) |
300 mm or greater and less than 400 mm |
0.5 Hz or greater and 3.0 Hz or less |
Range of 5° in downward direction to 50° in downward direction |
100 mm or greater and less than 300 mm |
0.060 T or greater and less than 0.080 T |
Conditions (C) |
400 mm or greater and less than 500 mm |
0.5 Hz or greater and 3.0 Hz or less |
Range of 5° in downward direction to 50° in downward direction |
100 mm or greater and less than 300 mm |
0.080 T or greater and less than 0.100 T |
1. Conditions (A)
[0022] In cases where the location of the peak of the AC magnetic field is 200 mm or greater
and less than 300 mm from the surface of the in-mold molten steel, the submergence
depth of a 2-port submerged entry nozzle is 100 mm or greater and less than 200 mm,
and the magnetic flux density at the location of the peak of the AC magnetic field
is 0.040 T or greater and less than 0.060 T.
[0023] Note that the magnetic flux density is determined as follows. Magnetic flux densities
at locations 15 mm away from a flat surface of a copper plate of the mold in a direction
normal to the flat surface and toward the interior space are considered. The copper
plate of the mold is one of the copper plates of the mold and is a plate behind which
an AC magnetic field generation device is provided. The flat surface is a surface
that forms the interior space. Among the magnetic flux densities in the normal direction,
the magnetic flux density at the location of the peak of the magnetic flux density
in the strand withdrawal direction is determined. The magnetic flux density is determined
as the effective value (root mean square value) of the arithmetic mean of values measured
at a desired pitch in the mold width direction. It can be assumed that the measurement
pitch in the mold width direction suffices if the measurement pitch is one that sufficiently
represents the spatial profile of the magnetic flux density.
[0024] If the magnetic flux density is less than 0.040 T, the swirling and stirring force
is low, and as a result, it is difficult to produce the effect of clearing argon gas
bubbles and deoxidation products from the solidified shell. On the other hand, if
the magnetic flux density is greater than or equal to 0.060 T, the swirling and stirring
force is too high, which contributes to entrainment of molding powder.
[0025] If the submergence depth of the submerged entry nozzle is less than 100 mm, the distance
between the surface of the in-mold molten steel and the discharge flow is too small,
which likely contributes to molten steel level fluctuation in the mold. If the submergence
depth is greater than or equal to 200 mm, the long length of the main body portion
of the submerged entry nozzle increases the cost of the refractory material, and also,
from the standpoint of heat resistance and resistance to loading, increases the probability
of damage to the submerged entry nozzle, and therefore, contrarily, there is a concern
that the operating costs may increase.
2. Conditions (B)
[0026] In cases where the location of the peak of the AC magnetic field is 300 mm or greater
and less than 400 mm from the surface of the in-mold molten steel, the submergence
depth of a 2-port submerged entry nozzle is 100 mm or greater and less than 300 mm,
and the magnetic flux density at the location of the peak of the AC magnetic field
is 0.060 T or greater and less than 0.080 T.
[0027] The location of the peak of the AC magnetic field is a location deeper than that
of conditions (A) with respect to the surface of the in-mold molten steel, and therefore
a magnetic flux density greater than that of conditions (A) is necessary. That is,
if the magnetic flux density is less than 0.060 T, the swirling and stirring force
is low, and as a result, it is difficult to produce the effect of clearing argon gas
bubbles and deoxidation products from the solidified shell. On the other hand, if
the magnetic flux density is greater than or equal to 0.080 T, the swirling and stirring
force is too high, which contributes to entrainment of molding powder.
[0028] If the submergence depth of the submerged entry nozzle is less than 100 mm, the distance
between the surface of the in-mold molten steel and the discharge flow is too small,
which likely contributes to molten steel level fluctuation in the mold. If the submergence
depth is greater than or equal to 300 mm, the long length of the main body portion
of the submerged entry nozzle increases the cost of the refractory material, and also,
from the standpoint of heat resistance and resistance to loading, increases the probability
of damage to the submerged entry nozzle, and therefore, contrarily, there is a concern
that the operating costs may increase.
3. Conditions (C)
[0029] In cases where the location of the peak of the AC magnetic field is 400 mm or greater
and less than 500 mm from the surface of the in-mold molten steel, the submergence
depth of a 2-port submerged entry nozzle is 100 mm or greater and less than 300 mm,
and the magnetic flux density at the location of the peak of the AC magnetic field
is 0.080 T or greater and less than 0.100 T.
[0030] The location of the peak of the AC magnetic field is a location even deeper than
those of conditions (A) and conditions (B) with respect to the surface of the in-mold
molten steel, and therefore an even greater magnetic flux density is necessary. That
is, if the magnetic flux density is less than 0.080 T, the swirling and stirring force
is low, and as a result, it is difficult to produce the effect of clearing argon gas
bubbles and deoxidation products from the solidified shell. On the other hand, if
the magnetic flux density is greater than or equal to 0.100 T, the swirling and stirring
force is too high, which contributes to entrainment of molding powder.
[0031] If the submergence depth of the submerged entry nozzle is less than 100 mm, the distance
between the surface of the in-mold molten steel and the discharge flow is too small,
which likely contributes to molten steel level fluctuation in the mold. If the submergence
depth is greater than or equal to 300 mm, the long length of the main body portion
of the submerged entry nozzle increases the cost of the refractory material, and also,
from the standpoint of heat resistance and resistance to loading, increases the probability
of damage to the submerged entry nozzle, and therefore, contrarily, there is a concern
that the operating costs may increase.
[0032] In the conditions (A) to (C), the discharge angle of the submerged entry nozzle to
be used is within the range of 5° in a downward direction to 50° in a downward direction.
If the discharge angle is less than 5° in a downward direction, the AC magnetic field
cannot sufficiently act on the discharge flow. On the other hand, if the discharge
angle is greater than 50° in a downward direction, the downward flow of the discharge
flow is too strong, and as a result, there is a concern that deoxidation products
and gas bubbles may sink into deep locations with respect to the casting direction
and form internal defects, which may act as crack initiation sites when the steel
sheet is subjected to forming.
[0033] In the present invention, the location of the peak of the AC magnetic field is 200
mm or greater and less than 500 mm from the surface of the in-mold molten steel. If
the location of the peak of the AC magnetic field is less than 200 mm from the surface
of the in-mold molten steel, the submergence depth of the submerged entry nozzle needs
to correspond to a location shallower than the location of the peak of the AC magnetic
field in order for the AC magnetic field to act on the discharge flow discharged from
the submerged entry nozzle, and therefore operational limitations arise and efficient
application of the AC magnetic field cannot be accomplished. Furthermore, if the location
of the peak of the AC magnetic field is a location greater than or equal to 500 mm
away from the surface of the in-mold molten steel, the swirling and stirring flow
is imparted in a region where the solidified shell is increased in size, and therefore
the effect of clearing deoxidation products and argon gas bubbles from the solidified
shell is not sufficiently obtained.
[0034] The frequency of the AC magnetic field is 0.5 to 3.0 Hz and preferably 1.0 to 2.0
Hz. If the frequency is less than 0.5 Hz, the imparting of an electromagnetic force
via the AC magnetic field is too intermittent, and therefore the effect of clearing
deoxidation products and argon gas bubbles from the solidified shell is unstable.
On the other hand, if the frequency is greater than 3.0 Hz, the reduction in magnetic
flux density due to the mold and the solidified shell increases, and it is therefore
impossible to efficiently apply an AC magnetic field to the in-mold molten steel.
[0035] A specific method for implementing the present invention will now be described with
reference to the drawings. Fig. 1 is a diagram illustrating an example of an embodiment
of the present invention, schematically illustrating a mold portion of a continuous
slab casting machine. Fig. 2 is an enlarged view of a submerged entry nozzle illustrated
in Fig. 1.
[0036] In Fig. 1 and Fig. 2, reference character 1 denotes molten steel; 2, a solidified
shell; 3, a surface of in-mold molten steel; 4, a discharge flow; 5, a strand; 6,
a mold; 7, a water-cooled mold long side; 8, a water-cooled mold short side; 9, a
submerged entry nozzle; 10, a discharge port; 11, an AC magnetic field generation
device; 12, molding powder; and θ, a discharge angle of the submerged entry nozzle.
[0037] The mold 6 includes a pair of mold long sides 7, which face each other, and a pair
of mold short sides 8, which face each other and are held between the mold long sides
7. The pair of mold long sides 7 and the pair of mold short sides 8 define a rectangular
interior space. A pair of AC magnetic field generation devices 11 are placed on the
back surfaces of the respective mold long sides 7. The AC magnetic field generation
devices 11 face each other with the mold long sides 7 positioned therebetween. Here,
the spacing between the mold long sides that face each other is 200 to 300 mm, the
submerged entry nozzle 9 has two discharge ports 10, and the discharge angle (θ) of
each of the discharge ports 10 is within the range of 5° in a downward direction to
50° in a downward direction.
[0038] The submerged entry nozzle 9 is placed in a middle portion of the rectangular interior
space of the mold 6. The discharge flows 4 of the molten steel 1 are discharged from
the two discharge ports 10 so that each of the discharge flows 4 flows toward one
of the mold short sides 8 that a corresponding one of the discharge ports 10 faces.
Thus, the molten steel 1 is poured into the interior space of the mold 6. After being
poured into the interior space of the mold 6, the molten steel 1 is cooled by the
mold long sides 7 and the mold short sides 8 to form the solidified shell 2. Subsequently,
after a predetermined amount of molten steel 1 is poured into the interior space of
the mold 6, pinch rolls (not illustrated) are driven in a state in which the discharge
ports 10 are immersed in the molten steel 1 in the mold, to start withdrawing the
strand 5, which includes an unsolidified portion of the molten steel 1 in the interior,
with the solidified shell 2 being the outer shell. After the withdrawal is started,
the strand withdrawal speed is increased to a predetermined strand withdrawal speed
while controlling the location of the surface 3 of the in-mold molten steel to be
a substantially fixed location. In Fig. 1, the submergence depth of the submerged
entry nozzle 9 is denoted by L
1, and the distance from the surface 3 of the in-mold molten steel to the location
of the peak of the AC magnetic field is denoted by L
2.
[0039] The molding powder 12 is added onto the surface 3 of the in-mold molten steel. The
molding powder 12 melts and prevents the molten steel 1 from being oxidized and also
flows into a space between the solidified shell 2 and the mold 6 to provide a lubricant
effect. Furthermore, argon gas, nitrogen gas or a mixed gas of argon gas and nitrogen
gas is injected into the molten steel 1 flowing down through the submerged entry nozzle
9, to prevent deoxidation products suspended in the molten steel from adhering to
the inner walls of the submerged entry nozzle.
[0040] When the molten steel 1 is continuously cast as described above, an AC magnetic field
is applied from the AC magnetic field generation devices 11 to the molten steel 1
present in the mold, thereby creating a horizontal swirling and stirring flow in the
molten steel 1 present in the mold. The frequency of the AC magnetic field is 0.5
Hz or greater and 3.0 Hz or less.
[0041] When an AC magnetic field is applied, in the case where the distance (L
2) from the surface 3 of the in-mold molten steel to the location of the peak of the
AC magnetic field is 200 mm or greater and less than 300 mm (conditions (A)), the
submergence depth (L
1) of the submerged entry nozzle 9 is 100 mm or greater and less than 200 mm, and the
magnetic flux density at the location of the peak of the AC magnetic field is 0.040
T or greater and less than 0.060 T.
[0042] Furthermore, in the case where the distance (L
2) from the surface 3 of the in-mold molten steel to the location of the peak of the
AC magnetic field is 300 mm or greater and less than 400 mm (conditions (B)), the
submergence depth (L
1) of the submerged entry nozzle 9 is 100 mm or greater and less than 300 mm, and the
magnetic flux density at the location of the peak of the AC magnetic field is 0.060
T or greater and less than 0.080 T.
[0043] Still furthermore, in the case where the distance (L
2) from the surface 3 of the in-mold molten steel to the location of the peak of the
AC magnetic field is 400 mm or greater and less than 500 mm (conditions (C)), the
submergence depth (L
1) of the submerged entry nozzle 9 is 100 mm or greater and less than 300 mm, and the
magnetic flux density at the location of the peak of the AC magnetic field is 0.080
T or greater and less than 0.100 T.
[0044] The adjustment of the magnetic flux density at the location of the peak of the AC
magnetic field is carried out in the following manner. Specifically, the relationship
between the electrical power supplied to the AC magnetic field generation devices
11 and the magnetic flux density at a location in the interior space of the mold 6,
which is a location 15 mm away from the surface of a copper plate of the mold, at
the location of the peak of the AC magnetic field is measured in advance, and the
electrical power to be supplied to the AC magnetic field generation devices 11 is
adjusted in a manner such that the magnetic flux density at the location of the peak
of the AC magnetic field becomes a desired magnetic flux density.
[0045] As described above, with the present invention, a high-quality slab strand can be
produced easily because a swirling and stirring flow is imparted to in-mold molten
steel by applying an AC magnetic field with an appropriate magnetic flux density in
accordance with the distance (L
2) from the surface 3 of the in-mold molten steel to the location of the peak of the
AC magnetic field and with the submergence depth (L
1) of the submerged entry nozzle, so that deoxidation products, argon gas bubbles,
and molding powder 12 are inhibited from being entrapped in the solidified shell 2.
EXAMPLES
[0046] A test in which approximately 300 tons of molten aluminum killed steel was continuously
cast was conducted by using a continuous slab casting machine having a mold such as
that illustrated in Fig. 1. In the test, the submergence depth (L
1) of the submerged entry nozzle and the distance (L
2) from the surface of the in-mold molten steel to the location of the peak of the
AC magnetic field were varied. The thickness of the slab strand was 250 mm, and the
width thereof was 1000 to 2200 mm. The molten steel pouring flow rate in a steady
casting period was 2.0 to 6.5 tons/min (strand withdrawal speed of 1.0 to 3.0 m/min).
Furthermore, the frequency of the AC magnetic field was 1.0 Hz.
[0047] The submerged entry nozzle used was a 2-port submerged entry nozzle having a discharge
angle (θ) of 25° in a downward direction. Argon gas was injected via an upper nozzle
into the molten steel flowing downward through the submerged entry nozzle. The cast
slab strand was subjected to hot rolling, cold rolling, and galvannealing successively.
Surface defects in the galvannealed steel sheet were measured continuously using an
on-line surface defect meter. Overview examination, SEM analysis, and ICP analysis
of the measured defects were performed. Of the measured defects, steelmaking-caused
defects (deoxidation-product-caused defects, argon-gas-bubble-caused defects, and
molding-powder-caused defects) were identified, and evaluations were made based on
the number of steelmaking-caused defects per 100 mm in length of the galvannealed
steel sheet (product defect index).
[0048] The test results of invention examples are shown in Table 2, and the test results
of comparative examples are shown in Table 3.
[Table 2]
|
Slab thickness (mm) |
Slab width (mm) |
Submergence depth L1 of submerged entry nozzle (mm) |
Discharge angle (downward) (deg.) |
Frequency of AC magnetic field (Hz) |
Distance L2 from meniscus to AC magnetic field peak location (mm) |
Magnetic flux density at AC magnetic field peak location (T) |
Product defect index (number/100 m) |
Invention example 1 |
250 |
1000 |
120 |
25 |
1.0 |
200 |
0.054 |
0.24 |
Invention example 2 |
250 |
1000 |
150 |
25 |
1.0 |
250 |
0.040 |
0.21 |
Invention example 3 |
250 |
1000 |
100 |
25 |
1.0 |
290 |
0.042 |
0.28 |
Invention example 4 |
250 |
1400 |
180 |
25 |
1.0 |
200 |
0.052 |
0.26 |
Invention example 5 |
250 |
1400 |
190 |
25 |
1.0 |
250 |
0.040 |
0.29 |
Invention example 6 |
250 |
1400 |
110 |
25 |
1.0 |
290 |
0.058 |
0.34 |
Invention example 7 |
250 |
1800 |
130 |
25 |
1.0 |
200 |
0.040 |
0.31 |
Invention example 8 |
250 |
1800 |
140 |
25 |
1.0 |
250 |
0.046 |
0.26 |
Invention example 9 |
250 |
1800 |
160 |
25 |
1.0 |
290 |
0.052 |
0.20 |
Invention example 10 |
250 |
2200 |
110 |
25 |
1.0 |
200 |
0.058 |
0.25 |
Invention example 11 |
250 |
2200 |
150 |
25 |
1.0 |
290 |
0.040 |
0.30 |
Invention example 12 |
250 |
2200 |
190 |
25 |
1.0 |
250 |
0.048 |
0.33 |
Invention example 13 |
250 |
1000 |
200 |
25 |
1.0 |
300 |
0.060 |
0.28 |
Invention example 14 |
250 |
1000 |
100 |
25 |
1.0 |
350 |
0.068 |
0.26 |
Invention example 15 |
250 |
1000 |
220 |
25 |
1.0 |
390 |
0.072 |
0.29 |
Invention example 16 |
250 |
1400 |
120 |
25 |
1.0 |
300 |
0.076 |
0.22 |
Invention example 17 |
250 |
1400 |
140 |
25 |
1.0 |
350 |
0.064 |
0.33 |
Invention example 18 |
250 |
1400 |
250 |
25 |
1.0 |
390 |
0.078 |
0.20 |
Invention example 19 |
250 |
1800 |
290 |
25 |
1.0 |
300 |
0.070 |
0.28 |
Invention example 20 |
250 |
1800 |
160 |
25 |
1.0 |
350 |
0.062 |
0.34 |
Invention example 21 |
250 |
1800 |
210 |
25 |
1.0 |
390 |
0.066 |
0.31 |
Invention example 22 |
250 |
2200 |
290 |
25 |
1.0 |
300 |
0.074 |
0.30 |
Invention example 23 |
250 |
2200 |
100 |
25 |
1.0 |
350 |
0.060 |
0.30 |
Invention example 24 |
250 |
2200 |
230 |
25 |
1.0 |
390 |
0.078 |
0.27 |
Invention example 25 |
250 |
1000 |
220 |
25 |
1.0 |
400 |
0.084 |
0.21 |
Invention example 26 |
250 |
1000 |
140 |
25 |
1.0 |
450 |
0.080 |
0.30 |
Invention example 27 |
250 |
1000 |
290 |
25 |
1.0 |
490 |
0.090 |
0.27 |
Invention example 28 |
250 |
1400 |
230 |
25 |
1.0 |
400 |
0.098 |
0.33 |
Invention example 29 |
250 |
1400 |
100 |
25 |
1.0 |
450 |
0.082 |
0.28 |
Invention example 30 |
250 |
1400 |
120 |
25 |
1.0 |
490 |
0.086 |
0.25 |
Invention example 31 |
250 |
1800 |
270 |
25 |
1.0 |
400 |
0.094 |
0.21 |
Invention example 32 |
250 |
1800 |
150 |
25 |
1.0 |
450 |
0.090 |
0.23 |
Invention example 33 |
250 |
1800 |
160 |
25 |
1.0 |
490 |
0.084 |
0.29 |
Invention example 34 |
250 |
2200 |
180 |
25 |
1.0 |
400 |
0.080 |
0.32 |
Invention example 35 |
250 |
2200 |
220 |
25 |
1.0 |
450 |
0.088 |
0.34 |
Invention example 36 |
250 |
2200 |
260 |
25 |
1.0 |
490 |
0.096 |
0.26 |
[Table 3]
|
Slab thickness (mm) |
Slab width (mm) |
Submergence depth L1 of submerged entry nozzle (mm) |
Discharge angle (downward) (deg.) |
Frequency of AC magnetic field (Hz) |
Distance L2 from meniscus to AC magnetic field peak location (mm) |
Magnetic flux density at AC magnetic field peak location (T) |
Product defect index (number/100 m) |
Comparative example 1 |
250 |
1000 |
120 |
25 |
1.0 |
200 |
0.038 |
0.51 |
Comparative example 2 |
250 |
1400 |
190 |
25 |
1.0 |
250 |
0.034 |
0.48 |
Comparative example 3 |
250 |
1800 |
140 |
25 |
1.0 |
250 |
0.036 |
0.53 |
Comparative example 4 |
250 |
2200 |
150 |
25 |
1.0 |
290 |
0.038 |
0.46 |
Comparative example 5 |
250 |
1000 |
120 |
25 |
1.0 |
200 |
0.060 |
0.55 |
Comparative example 6 |
250 |
1400 |
190 |
25 |
1.0 |
250 |
0.062 |
0.51 |
Comparative example 7 |
250 |
1800 |
140 |
25 |
1.0 |
250 |
0.064 |
0.50 |
Comparative example 8 |
250 |
2200 |
150 |
25 |
1.0 |
290 |
0.062 |
0.47 |
Comparative example 9 |
250 |
1000 |
140 |
25 |
1.0 |
300 |
0.058 |
0.49 |
Comparative example 10 |
250 |
1400 |
270 |
25 |
1.0 |
390 |
0.056 |
0.53 |
Comparative example 11 |
250 |
1800 |
180 |
25 |
1.0 |
350 |
0.058 |
0.52 |
Comparative example 12 |
250 |
2200 |
220 |
25 |
1.0 |
390 |
0.052 |
0.50 |
Comparative example 13 |
250 |
1000 |
160 |
25 |
1.0 |
300 |
0.084 |
0.48 |
Comparative example 14 |
250 |
1400 |
230 |
25 |
1.0 |
350 |
0.080 |
0.46 |
Comparative example 15 |
250 |
1800 |
270 |
25 |
1.0 |
350 |
0.082 |
0.48 |
Comparative example 16 |
250 |
2200 |
140 |
25 |
1.0 |
390 |
0.086 |
0.53 |
Comparative example 17 |
250 |
1000 |
260 |
25 |
1.0 |
450 |
0.074 |
0.55 |
Comparative example 18 |
250 |
1400 |
290 |
25 |
1.0 |
400 |
0.078 |
0.54 |
Comparative example 19 |
250 |
1800 |
100 |
25 |
1.0 |
490 |
0.072 |
0.49 |
Comparative example 20 |
250 |
2200 |
180 |
25 |
1.0 |
400 |
0.076 |
0.50 |
Comparative example 21 |
250 |
1000 |
240 |
25 |
1.0 |
400 |
0.102 |
0.51 |
Comparative example 22 |
250 |
1400 |
160 |
25 |
1.0 |
450 |
0.100 |
0.48 |
Comparative example 23 |
250 |
1800 |
280 |
25 |
1.0 |
490 |
0.104 |
0.51 |
Comparative example 24 |
250 |
2200 |
120 |
25 |
1.0 |
450 |
0.102 |
0.52 |
Comparative example 25 |
250 |
1000 |
90 |
25 |
1.0 |
200 |
0.046 |
0.49 |
Comparative example 26 |
250 |
1400 |
80 |
25 |
1.0 |
250 |
0.040 |
0.47 |
Comparative example 27 |
250 |
1800 |
80 |
25 |
1.0 |
250 |
0.048 |
0.48 |
Comparative example 28 |
250 |
2200 |
90 |
25 |
1.0 |
290 |
0.052 |
0.49 |
Comparative example 29 |
250 |
1000 |
200 |
25 |
1.0 |
250 |
0.044 |
0.53 |
Comparative example 30 |
250 |
1400 |
220 |
25 |
1.0 |
200 |
0.056 |
0.48 |
Comparative example 31 |
250 |
1800 |
200 |
25 |
1.0 |
250 |
0.048 |
0.55 |
Comparative example 32 |
250 |
2200 |
220 |
25 |
1.0 |
290 |
0.050 |
0.51 |
[0049] Invention Examples 1 to 12 correspond to conditions (A) of Table 1, Invention Examples
13 to 24 correspond to conditions (B) of Table 1, and Invention Examples 25 to 36
correspond to conditions (C) of Table 1. All of Invention Examples 1 to 36 had a product
defect index within a range of 0.21 to 0.34 (number/100 m) and therefore had a good
result.
[0050] On the other hand, in each of Comparative Examples 1 to 24, the magnetic flux density
at the location of the peak of the AC magnetic filed in the test was outside the range
of the present invention, and the product defect index was 0.46 to 0.55 (number/100
m) and therefore inferior.
[0051] Furthermore, in each of Comparative Examples 25 to 32, the submergence depth (L
1) of the submerged entry nozzle in the test was outside the range of the present invention,
and the product defect index was 0.47 to 0.55 (number/100 m) and was therefore also
inferior. Comparative Examples 25 to 32 are cases in each of which the distance (L
2) from the surface of the in-mold molten steel to the location of the peak of the
AC magnetic field corresponds to that of conditions (A) of Table 1. However, it was
confirmed that, under conditions (B) or conditions (C), too, the product defect index
deteriorated in the case where the submergence depth (L
1) of the submerged entry nozzle was outside the range of the present invention.
[0052] Although no description is given in this example, it was confirmed that when the
thickness of a strand was within a range of 200 to 300 mm, effects comparable to those
described in this example were produced. Furthermore, the shape of the submerged entry
nozzle is also not limited to the conditions described in this example, and it was
confirmed that when the discharge angle (θ) was within the range of 5° in a downward
direction to 50° in a downward direction, comparable effects were produced.
[0053] As described above, it was confirmed that employing the continuous casting method
according to the present invention enables casting of a good-quality slab strand.
Reference Signs List
[0054]
- 1
- Molten steel
- 2
- Solidified shell
- 3
- Surface of in-mold molten steel
- 4
- Discharge flow
- 5
- Strand
- 6
- Mold
- 7
- Mold long side
- 8
- Mold short side
- 9
- Submerged entry nozzle
- 10
- Discharge port
- 11
- AC magnetic field generation device
- 12
- Molding powder
1. A continuous steel casting method, the method including producing a strand, the producing
of the strand including pouring molten steel into a mold for continuous casting and
withdrawing a solidified shell from the mold, the solidified shell being a solidified
portion of the molten steel, the mold having a pair of mold long sides and a pair
of mold short sides with a rectangular interior space being defined within the mold,
the method comprising applying an AC magnetic field to in-mold molten steel via AC
magnetic field generation devices, thereby creating, via the AC magnetic field, a
horizontal swirling and stirring flow in the in-mold molten steel, each of the AC
magnetic field generation devices being placed on a back surface of a corresponding
one of the pair of mold long sides, the AC magnetic field generation devices facing
each other with the mold long sides being positioned therebetween, wherein
a spacing between the mold long sides that face each other is 200 to 300 mm,
a submerged entry nozzle has two discharge ports for pouring molten steel into the
interior space, each of the discharge ports having a discharge angle within a range
of 5° in a downward direction to 50° in a downward direction,
the AC magnetic field has a frequency of 0.5 Hz or greater and 3.0 Hz or less,
a distance from a surface of the in-mold molten steel to a location of a peak of the
AC magnetic field is 200 mm or greater and less than 300 mm,
a submergence depth of the submerged entry nozzle (a distance from the surface of
the in-mold molten steel to an upper end of the discharge ports of the submerged entry
nozzle) is 100 mm or greater and less than 200 mm, and
a magnetic flux density at the location of the peak of the AC magnetic field is 0.040
T or greater and less than 0.060 T.
2. A continuous steel casting method, the method including producing a strand, the producing
of the strand including pouring molten steel into a mold for continuous casting and
withdrawing a solidified shell from the mold, the solidified shell being a solidified
portion of the molten steel, the mold having a pair of mold long sides and a pair
of mold short sides with a rectangular interior space being defined within the mold,
the method comprising applying an AC magnetic field to in-mold molten steel via AC
magnetic field generation devices, thereby creating, via the AC magnetic field, a
horizontal swirling and stirring flow in the in-mold molten steel, each of the AC
magnetic field generation devices being placed on a back surface of a corresponding
one of the pair of mold long sides, the AC magnetic field generation devices facing
each other with the mold long sides being positioned therebetween, wherein
a spacing between the mold long sides that face each other is 200 to 300 mm,
a submerged entry nozzle has two discharge ports for pouring molten steel into the
interior space, each of the discharge ports having a discharge angle within a range
of 5° in a downward direction to 50° in a downward direction,
the AC magnetic field has a frequency of 0.5 Hz or greater and 3.0 Hz or less,
a distance from a surface of the in-mold molten steel to a location of a peak of the
AC magnetic field is 300 mm or greater and less than 400 mm,
a submergence depth of the submerged entry nozzle (a distance from the surface of
the in-mold molten steel to an upper end of the discharge ports of the submerged entry
nozzle) is 100 mm or greater and less than 300 mm, and
a magnetic flux density at the location of the peak of the AC magnetic field is 0.060
T or greater and less than 0.080 T.
3. A continuous steel casting method, the method including producing a strand, the producing
of the strand including pouring molten steel into a mold for continuous casting and
withdrawing a solidified shell from the mold, the solidified shell being a solidified
portion of the molten steel, the mold having a pair of mold long sides and a pair
of mold short sides with a rectangular interior space being defined within the mold,
the method comprising applying an AC magnetic field to in-mold molten steel via AC
magnetic field generation devices, thereby creating, via the AC magnetic field, a
horizontal swirling and stirring flow in the in-mold molten steel, each of the AC
magnetic field generation devices being placed on a back surface of a corresponding
one of the pair of mold long sides, the AC magnetic field generation devices facing
each other with the mold long sides being positioned therebetween, wherein
a spacing between the mold long sides that face each other is 200 to 300 mm,
a submerged entry nozzle has two discharge ports for pouring molten steel into the
interior space, each of the discharge ports having a discharge angle within a range
of 5° in a downward direction to 50° in a downward direction,
the AC magnetic field has a frequency of 0.5 Hz or greater and 3.0 Hz or less,
a distance from a surface of the in-mold molten steel to a location of a peak of the
AC magnetic field is 400 mm or greater and less than 500 mm,
a submergence depth of the submerged entry nozzle (a distance from the surface of
the in-mold molten steel to an upper end of the discharge ports of the submerged entry
nozzle) is 100 mm or greater and less than 300 mm, and
a magnetic flux density at the location of the peak of the AC magnetic field is 0.080
T or greater and less than 0.100 T.
4. A continuous steel casting method, the method including producing a strand, the producing
of the strand including pouring molten steel into a mold for continuous casting and
withdrawing a solidified shell from the mold, the solidified shell being a solidified
portion of the molten steel, the mold having a pair of mold long sides and a pair
of mold short sides with a rectangular interior space being defined within the mold,
the method comprising applying an AC magnetic field to in-mold molten steel via AC
magnetic field generation devices, thereby creating, via the AC magnetic field, a
horizontal swirling and stirring flow in the in-mold molten steel, each of the AC
magnetic field generation devices being placed on a back surface of a corresponding
one of the pair of mold long sides, the AC magnetic field generation devices facing
each other with the mold long sides being positioned therebetween, wherein
a spacing between the mold long sides that face each other is 200 to 300 mm,
a submerged entry nozzle has two discharge ports for pouring molten steel into the
interior space, each of the discharge ports having a discharge angle within a range
of 5° in a downward direction to 50° in a downward direction,
the AC magnetic field has a frequency of 0.5 Hz or greater and 3.0 Hz or less, and
in accordance with a location of a peak of the AC magnetic field, a submergence depth
of the submerged entry nozzle (a distance from the surface of the in-mold molten steel
to an upper end of the discharge ports of the submerged entry nozzle) and a magnetic
flux density at the location of the peak of the AC magnetic field generated by the
AC magnetic field generation devices are determined to satisfy one of three types
of conditions described below, namely conditions (A), conditions (B), and conditions
(C),
conditions (A): when the distance from the surface of the in-mold molten steel to
the location of the peak of the AC magnetic field is 200 mm or greater and less than
300 mm, the submergence depth of the submerged entry nozzle is 100 mm or greater and
less than 200 mm, and the magnetic flux density at the location of the peak of the
AC magnetic field is 0.040 T or greater and less than 0.060 T,
conditions (B): when the distance from the surface of the in-mold molten steel to
the location of the peak of the AC magnetic field is 300 mm or greater and less than
400 mm, the submergence depth of the submerged entry nozzle is 100 mm or greater and
less than 300 mm, and the magnetic flux density at the location of the peak of the
AC magnetic field is 0.060 T or greater and less than 0.080 T, and
conditions (C): when the distance from the surface of the in-mold molten steel to
the location of the peak of the AC magnetic field is 400 mm or greater and less than
500 mm, the submergence depth of the submerged entry nozzle is 100 mm or greater and
less than 300 mm, and the magnetic flux density at the location of the peak of the
AC magnetic field is 0.080 T or greater and less than 0.100 T.