COMPOSITION, ITS USE AND METHOD FOR REMOVING AND PREVENTING WET STRENGTH RESINS FROM CONTAMINATING PAPERMAKING EQUIPMENT

Description

Field of the Invention

[0001] This invention relates to methods for cleaning wet strength resin contamination from papermaking equipment and/or for preventing wet strength resins from contaminating papermaking equipment.

Background of the Invention

[0002] Wet strength resins are major additives used in the papermaking process. Use of wet strength resins, for example, polyamide-epichlorohydrin (PAE), results in buildup of crosslinked chemicals and fouling of wet press felts, causing the felts to lose permeability and decrease water absorption speed after a period of time. Paper mills spend time and money to clean the fouled felts and even have to change the felts frequently.

[0003] Chemical products that are currently used for wet press felt cleaning or cleaning wet strength resin contamination are either highly caustic or highly acidic. These chemical products are corrosive, not renewable or biodegradable, and are inappropriate for safe handling. Additionally, the products not only remove the wet strength resin contamination but may also damage the felt itself.

[0004] Thus, there is a need for products that are highly efficient in cleaning wet strength resin contamination from papermaking equipment and/or preventing wet strength resins from contaminating papermaking equipment, without appreciably damaging the equipment. Additionally, the products must be safe to handle and environmentally friendly, such as renewable and/or biodegradable.

[0005] JP2014130029A relates to a cleaning agent used for cleaning radioactive contaminants from soil, and cleaning method using said cleaning agent. JP2014130029A relates to reagents and cleaning methods that can efficiently separate and remove radioactive materials from soil containing radioactive materials.

[0006] US3772078 relates to compositions and methods for metallization of bodies. The document discloses process to produce images on substrate, as well as base materials and processes for metallization.

[0007] WO97/32968 relates to an acidic liquid crystal detergent composition comprising an ethoxylated nonionic surfactant, an aliphatic carboxylic acid, an ethoxylated alkyl ether sulfate surfactant or sodium lauryl sulfate, a weak base, a water-insoluble organic compound, a cosurfactant, a magnesium salt and water.

Summary of the Invention

[0008] One objective of the present invention is to provide solutions to or alleviate the problems encountered in the prior art.

[0009] In particular, one objective of is to provide a substantially biodegradable, safe and efficient composition for cleaning wet strength resin contamination from papermaking equipment and/or preventing wet strength resins from contaminating papermaking equipment.

[0010] A typical composition for cleaning wet strength resin contamination from papermaking equipment and/or for preventing wet strength resins from contaminating papermaking equipment, comprises an aqueous solution of a weak organic acid; a surfactant, preferably nonionic surfactant; a divalent metal ion containing catalyst; and optionally a glycol ether containing solvent.

[0011] A typical method according to present invention of cleaning wet strength resin contamination from papermaking equipment, the method comprises the steps of contacting the equipment with a composition comprising an aqueous solution of a weak organic acid; a surfactant, preferably a nonionic surfactant; a divalent metal ion containing catalyst and optionally a glycol ether containing solvent.

[0012] A typical method according to the present invention of preventing wet strength resins from contaminating papermaking equipment of a papermaking process, the method comprises the steps of contacting the equipment with a composition comprising an aqueous solution of a weak organic acid; a surfactant, preferably a nonionic surfactant; a divalent metal ion containing catalyst and optionally a glycol ether containing solvent, before and/or during and/or after addition of the wet strength resin in the papermaking process.

[0013] A typical use according to the present invention of a composition comprising an aqueous solution of a weak organic acid; a surfactant, preferably a nonionic surfactant; a divalent metal ion containing catalyst and optionally a glycol ether containing solvent, is for cleaning an equipment by contacting the equipment with the composition, as defined in claim 1.

[0014] Compositions have multiple advantages. The compositions are renewable, environmentally friendly and substantially biodegradable. The cleaning compositions are FDA compliant and thus are suitable for cleaning equipment used in making paper, board or the like to be used with food contact. The compositions are stable and highly efficient in cleaning wet strength resin contamination from papermaking equipment and in preventing wet strength resins from contaminating papermaking equipment, without damaging the equipment. The components of the composition may also show synergistic effect, wherein the composition may have higher cleaning efficiency or capacity than the individual components.

[0015] Other objects, features, and advantages of the present invention will become apparent from the following detailed description. It should be understood, however, that the detailed description and the specific examples, while indicating specific embodiments of the invention, are given by way of illustration only, since various changes and modifications within the spirit and scope of the invention will become apparent to those skilled in the art from this detailed description.

Brief Description of the Drawings

[0016] The following schematical drawings form part of the present specification and are included to further demonstrate certain aspects of the present invention. The invention may be better understood by reference to one or more of these drawings in combination with the detailed description of the specification embodiments presented herein.

[0017] Figure 1: Felt conditioning process, as described in Example 2.

Detailed Description of the Invention

[0018] The present invention provides use of a stable, renewable, environmentally friendly, FDA compliant and safe to handle composition for cleaning wet strength resin contamination from papermaking equipment and/or preventing wet strength resins from contaminating papermaking equipment.

[0019] Certain embodiments are related to compositions for cleaning wet strength resin contamination from papermaking equipment and/or preventing wet strength resins from contaminating papermaking equipment, the composition comprising an aqueous solution of a weak organic acid; a surfactant, preferably a nonionic surfactant; a divalent metal ion containing catalyst, and optionally a glycol ether containing solvent. In certain embodiments the weak organic acid is selected from a group consisting of citric acid, adipic acid, glycolic acid and combinations thereof, preferably citric acid. In certain embodiments the glycol ether containing solvent is selected from a group consisting of diethylene glycol monobutyl ether, diethylene glycol monoethyl ether and a combination thereof. In certain embodiments the surfactant is selected from a group consisting of isotridecyl alcohol ethoxylate, dodecanol ethoxylate, ethoxylated 2,4,7,9-tetramethyl-5-decyne-4,7-diol, polyethylene glycol trimethylnonyl ether, polysorbates, ethoxylated secondary alcohols containing surfactants and combinations thereof. In certain embodiments the divalent metal ion is selected from a group consisting of Ca⁺², Mg⁺², Ba⁺², Fe⁺², Cu⁺², Ni⁺², Mn⁺² and Co⁺², preferably Fe⁺², Ca⁺², Cu⁺² or Ni⁺². In certain embodiments the weak organic acid concentration is within 15%-45%, preferably 20%-30%. In certain embodiments the glycol ether containing solvent concentration is within 0%-15%, preferably 3%-8%. In certain embodiments the surfactant concentration is within 2%-25%, preferably 5%-13%. In certain embodiments the divalent metal ion containing catalyst concentration is within 0.01%-5%, preferably 0.25% - 3%. In certain embodiments such cleaning compositions are further diluted with one or more diluting agents wherein diluting agent:composition, weight:weight, ratio is in range 500:1 - 0:1, preferably 200:1-9:1.

[0020] Certain embodiments of the invention are related to methods of cleaning wet strength resins contamination from a papermaking equipment, the method comprising the steps of contacting the equipment with a composition comprising an aqueous solution of a weak organic acid; a surfactant, preferably a nonionic surfactant; a divalent metal ion containing catalyst, and optionally a glycol ether containing solvent. In certain embodiments the weak organic acid is selected from a group consisting of citric acid, adipic acid, glycolic acid and combinations thereof, preferably citric acid. In certain embodiments the glycol ether containing solvent is selected from a group consisting of diethylene glycol monobutyl ether, diethylene glycol monoethyl ether and a combination thereof. In certain embodiments the surfactant is selected from a group consisting of isotridecyl alcohol ethoxylate, dodecanol ethoxylate, ethoxylated 2,4,7,9-tetramethyl-5-decyne-4,7-diol, polyethylene glycol trimethylnonyl ether, polysorbates, ethoxylated secondary alcohols containing surfactants and combinations thereof. In certain embodiments the divalent metal ion is selected from a group consisting of Ca⁺², Mg⁺², Ba⁺², Fe⁺², Cu⁺², Ni⁺², Mn⁺² and Co⁺², preferably Fe⁺², Ca⁺², Cu⁺² or Ni⁺². In certain embodiments the weak organic acid concentration is within 15%-45%, preferably 20%-30%. In certain embodiments the glycol ether containing solvent concentration is within 0%-15%, preferably 3%-8%. In certain embodiments the surfactant concentration is within 2%-25%, preferably 5%-13%. In certain embodiments the divalent metal ion containing catalyst concentration is within 0.01%-5%, preferably 0.25%-3%. In certain embodiments such cleaning compositions are further diluted with one or more diluting agents wherein diluting agent:composition, weight:weight, ratio is in range 500:1-0:1, preferably 200:1-9:1. In certain embodiments cleaning is performed at elevated temperatures. In certain other embodiments contact time is between 0.1 second to 5 hours, preferably between 30 seconds to 1 hour, more preferably 1 minute to 30 minutes. In certain other embodiments the papermaking equipment is wet press felts, dryer fabric, papermaking equipment used in a papermaking process that uses wet strength resins or other papermaking machine surface. The wet strength resin is polyamide-epichlorohydrin (PAE) resin.

[0021] Certain embodiments of the invention are related to methods of preventing wet strength resins from contaminating papermaking equipment of a papermaking process, the method comprising the steps of contacting the equipment with a composition comprising an aqueous solution of a weak organic acid; a surfactant, preferably a nonionic surfactant, a divalent metal ion containing catalyst, and optionally a glycol ether containing solvent, before and/or during and/or after addition of the wet strength resin in the papermaking process. In certain embodiments the weak organic acid is selected from a group consisting of citric acid, adipic acid, glycolic acid and combinations thereof, preferably citric acid. In certain embodiments the glycol ether containing solvent is selected from a group consisting of diethylene glycol monobutyl ether, diethylene glycol monoethyl ether and a combination thereof. In certain embodiments the surfactant is selected from a group consisting of isotridecyl alcohol ethoxylate, dodecanol ethoxylate, ethoxylated 2,4,7,9-tetramethyl-5-decyne-4,7-diol, polyethylene glycol trimethylnonyl ether, polysorbates, ethoxylated secondary alcohols containing surfactants and combinations thereof. In certain embodiments the divalent metal ion is selected from a group consisting of Ca⁺², Mg⁺², Ba⁺², Fe⁺², Cu⁺², Ni⁺², Mn⁺² and Co⁺², preferably Fe⁺², Ca⁺², Cu⁺² or Ni⁺². In certain embodiments the weak organic acid concentration is within 15%-45%, preferably 20%-30%. In certain embodiments the glycol ether containing solvent concentration is within 0%-15%, preferably 3%-8%. In certain embodiments the surfactant concentration is within 2%-25%, preferably 5%-13%. In certain embodiments the divalent metal ion containing catalyst concentration is within 0.01%-5%, preferably 0.25%-3%. In certain embodiments such cleaning compositions are further diluted with one or more diluting agents wherein diluting agent: composition, weight:weight, ratio is in range 500:1-0:1, preferably 200:1-9:1. In certain other embodiments contact time is between 0.1 second to 5 hours, preferably between 30 seconds to 1 hour, more preferably 1 minute to 30 minutes. In certain other embodiments the papermaking equipment is wet press felts, dryer fabric, papermaking equipment used in a papermaking process that uses wet strength resins or other papermaking machine surface. The wet strength resin is polyamide-epichlorohydrin (PAE) resin.

[0022] Certain embodiments of the invention are related to use of a composition, comprising an aqueous solution of a weak organic acid; a surfactant, preferably a nonionic surfactant; a divalent metal ion containing catalyst, and optionally a glycol ether containing solvent, for cleaning an equipment by contacting the equipment with the composition. In certain embodiments the weak organic acid is selected from a group consisting of citric acid, adipic acid, glycolic acid and combinations thereof, preferably citric acid. In certain embodiments the glycol ether containing solvent is selected from a group consisting of diethylene glycol monobutyl ether, diethylene glycol monoethyl ether and a combination thereof. In certain embodiments the surfactant is selected from a group consisting of isotridecyl alcohol ethoxylate, dodecanol ethoxylate, ethoxylated 2,4,7,9-tetramethyl-5-decyne-4,7-diol, polyethylene glycol trimethylnonyl ether, polysorbates, ethoxylated secondary alcohols containing surfactants and combinations thereof. In certain embodiments the divalent metal ion is selected from a group consisting of Ca⁺², Mg⁺², Ba⁺², Fe⁺², Cu⁺², Ni⁺², Mn⁺² and Co⁺², preferably Fe⁺², Ca⁺², Cu⁺² or Ni⁺². In certain embodiments the weak organic acid concentration is within 15%-45%, preferably 20%-30%. In certain embodiments the glycol ether containing solvent concentration is within 0%-15%, preferably 3%-8%. In certain embodiments the surfactant concentration is within 2%-25%, preferably 5%-13%. In certain embodiments the divalent metal ion containing catalyst concentration is within 0.01%-5%, preferably 0.25%-3%. In certain embodiments such cleaning compositions are further diluted with one or more diluting agents wherein diluting agent: composition, weight: weight, ratio is in range 500:1-0:1, preferably 200:1-9:1. In certain embodiments cleaning is performed at elevated temperatures. In certain other embodiments contact time is between 0.1 second to 5 hours, preferably between 30 seconds to 1 hour, more preferably 1 minute to 30 minutes. In certain embodiments the equipment is a paper making equipment. In certain other embodiments the papermaking equipment is wet press felts, dryer fabric, papermaking equipment used in a papermaking process that uses wet strength resins or other papermaking machine surface. In certain embodiments the papermaking equipment contains contamination formed from use of wet strength resins in a papermaking process. The wet strength resin is polyamide-epichlorohydrin (PAE) resin.

[0023] Other embodiments of the invention are discussed throughout this application. Any embodiment discussed with respect to one aspect of the invention applies to other aspects of the invention as well and vice versa. Each embodiment described herein is understood to be embodiments of the invention that are applicable to all aspects of the invention. It is contemplated that any embodiment discussed herein can be implemented with respect to any method or composition, and vice versa. Furthermore, compositions and kits can be used to achieve methods of the invention.

[0024] In certain embodiments the equipment is a paper making equipment. In certain embodiments the papermaking equipment contains contamination formed from use of wet strength resins in a papermaking process.

[0025] The composition comprises an aqueous solution of a weak organic acid. The use of weak organic acid makes the composition more benign and safe, both for process operators and workers as well as for equipment which is to be cleaned. At the same time, however, it promotes the unexpectedly sufficient cleaning effect which is obtained with the composition.

[0026] According to one preferable embodiment the organic acid concentration in the composition is within 10%-45%, preferably 20%-30%.

[0027] Weak organic acid may have pKa greater than 1.5, preferably greater than 2, more preferably greater than 3. The weak organic acid may be dibasic or tribasic acid and it may have at least one pKa value in the range from 3 to 6. According to one embodiment of the invention the weak organic acid may be selected from a group consisting of citric acid, adipic acid, glycolic acid and any combinations thereof. Preferably the weak organic acid is citric acid.

[0028] The composition comprises further a surfactant, preferably a nonionic surfactant. The surfactant concentration in the composition may preferably be within 2%-25%, preferably 5%-13%. A surfactant, as referred in this disclosure, contains a hydrophilic head group and a hydrophobic tail group. Nonionic surfactants are surfactants with an uncharged hydrophilic head group and do not dissociate into ions in aqueous solutions. Preferable nonionic surfactants include ethoxylates, especially fatty alcohol ethoxylates, alkoxylates and cocamides. A surfactant useful for the current invention makes the components of the claimed composition miscible with each other, keeps them well dispersed and forms a micro-emulsion. The surfactants may also enhance the cleaning efficiency of the individual components of the composition.

[0029] According to one embodiment surfactant may be selected from a group consisting of isotridecyl alcohol ethoxylate, dodecanol ethoxylate, ethoxylated 2,4,7,9-tetramethyl-5-decyne-4,7-diol, polyethylene glycol trimethylnonyl ether, polysorbates, ethoxylated secondary alcohols-containing surfactants and any combinations thereof.

[0030] Suitable dodecanol ethoxylates are nonionic surfactants containing one or more moles of ethylene oxide per mole of dodecanol. In certain embodiments mole ratio of ethylene oxide and dodecanol is 7:1.

[0031] In certain embodiments, suitable isotridecyl alcohol ethoxylates are nonionic surfactants containing one or more moles of ethylene oxide per mole of isotridecyl alcohol. In certain embodiments mole ratio of ethylene oxide and isotridecyl alcohol is 9:1.

[0032] In certain embodiments, suitable polysorbates are nonionic surfactants composed of fatty acid esters of polyoxyethylene sorbitan. Examples of polysorbates are polyoxyethylene sorbitan monolaurate, polysorbate sorbitan monopalmitate, polyoxyethylene sorbitan monostearate, polyoxyethylene sorbitan monooleate.

[0033] In certain embodiments, suitable polyethylene glycol trimethylnonyl ether may be polyoxyethylene 2,6,8-trimethyl-4-nonyl ether.

[0034] In certain embodiments, the composition comprises further a divalent metal ion containing catalyst. According to one embodiment the divalent metal ion containing catalyst concentration in the composition may be within 0.01%-5%, preferably 0.25%-3%. The divalent metal ion may be selected from a group consisting of Ca⁺², Mg⁺², Ba⁺², Fe⁺², Cu⁺², Ni⁺², Mn⁺², and Co⁺², preferably from a group of Fe⁺², Ca⁺², Cu⁺² and Ni⁺². The origin of the effect, which is obtained when the composition comprises a divalent metal ion containing catalyst, is not yet fully understood. However, it is speculated, without wishing to be bound by a theory, that either oxidation-reduction reactions or some chelating reactions might be involved.

[0035] In certain embodiments, the divalent metal ion containing catalyst may be in form of salt, where the counterion is any suitable organic or inorganic, divalent or monovalent anion, preferably citrate, acetate, maleate, sulphate or chloride, even more preferably sulphate or chlorate.

[0036] According to one embodiment the composition comprises a glycol ether containing solvent. The glycol ether containing solvents may be selected from the group consisting of diethylene glycol monobutyl ether, diethylene glycol monoethyl ether, ethylene glycol monophenyl ether, diethylene glycol monophenyl ether, polyethylene glycol monophenyl ether, triethylene glycol monophenyl ether containing solvents and any combination thereof. Preferably, the glycol ether containing solvent is selected from the group consisting of diethylene glycol monobutyl ether, diethylene glycol monoethyl ether and any combinations thereof. The glycol ether containing solvent concentration in the composition may be within 0%-15%, preferably 0.01%-15%, more preferably 3%-8%.

[0037] The compositions remove wet strength resin contamination and/or prevent wet strength resins from contaminating papermaking equipment through removal, prevention or reduction of formation of crosslinked chemicals from wet strength resins on the papermaking equipment.

[0038] The cleaning composition may be diluted before it is used for cleaning the papermaking equipment and brought into contact with the said equipment. Diluting agent may be selected from the group consisting of water, compatible chemicals, compatible chemical mixtures or premixtures, compatible liquids, compatible solids or combinations thereof, preferably water. "Compatible" are those that do not result in separation between the components of compositions and/or precipitation, and maintain the micro-emulsion state of the composition while and/or after adding and/or mixing those to the composition. According to one embodiment of the invention diluting agent:composition ratio, given weight:weight, is in range 500:1 - 0:1, preferably 200:1-9:1.

[0039] The composition is contacted with an equipment, preferably with a papermaking equipment. The contacting may be carried out by spraying the composition onto the equipment surface, by soaking or immersing the equipment into the composition or by applying the composition to a circulating process flow, which comes into contact with the equipment.

[0040] According to one embodiment of the invention the cleaning is performed at an elevated temperature. This means that the composition and/or the equipment are at an elevated temperature at the time of cleaning. Cleaning at elevated temperatures is performed through heating the cleaning composition or equipment being cleaned, or both, at elevated temperature before and/or while in contact with each other. The cleaning compositions or equipment being cleaned, or both, are heated to temperatures between above room temperature to below 130°C, preferably between 45°C to 70°C, more preferably between 50°C to 60°C. At the preferred temperature range, energy optimized cleaning performance is observed.

[0041] Contact time depends on the area of the equipment being cleaned, the type of equipment surface being cleaned and/or contamination level of the equipment. Contact method depends on the equipment being cleaned. The contact method may be soaking, spraying or any other suitable contact method, as described above. Contact time is optimized such that optimum cleaning is obtained with minimum loss in production time. According to one embodiment the contact time may be between 0.1 second to 5 hours, preferably between 30 seconds to 1 hour, more preferably 1 minute to 30 minutes.

[0042] The composition is preferably used for cleaning papermaking equipment, especially papermaking equipment that contains contamination formed from use of wet strength resins in a papermaking process. The equipment to be cleaned may be wet press felt, dryer fabric or any papermaking equipment used in a papermaking process that uses wet strength resins, or other papermaking machine surface. Preferably the composition is used for cleaning wet press felts or dryer fabrics.

[0043] The composition is preferably used for cleaning contamination caused by wet strength resin, especially when the wet strength resin is polyamide-epichlorohydrin (PAE) resin.

Definitions

[0044] The use of the word "a" or "an" when used in conjunction with the term "comprising" in the claims and/or the specification may mean "one," but it is also consistent with the meaning of "one or more," "at least one," and "one or more than one."

[0045] Throughout this document, the term "about" is used to indicate that a value includes the standard deviation of error for the device or method being employed to determine the value.

[0046] The use of the term "or" in the claims is used to mean "and/or" unless explicitly indicated to refer to alternatives only or the alternatives are mutually exclusive, although the disclosure supports a definition that refers to only alternatives and "and/or."

[0047] As used in this disclosure, the words "comprising" (and any form of comprising, such as "comprise" and "comprises"), "having" (and any form of having, such as "have" and "has"), "including" (and any form of including, such as "includes" and "include") or "containing" (and any form of containing, such as "contains" and "contain") are inclusive or open-ended and do not exclude additional, unrecited elements or method steps.

[0048] Percentages of components in compositions described throughout this application are weight percentages of the components in the compositions. Weight percentages are calculated with the assumption that the components contain no impurities.

Examples

[0049] The following examples as well as the figures are included to demonstrate preferred embodiments of the invention. It should be appreciated by those of skill in the art that the techniques disclosed in the examples or figures represent techniques discovered by the inventors to function well in the practice of the invention, and thus can be considered to constitute preferred modes for its practice. However, those of skill in the art should, in light of the present disclosure, appreciate that many changes can be made in the specific embodiments which are disclosed and still obtain a like or similar result without departing from the spirit and scope of the invention.

Example 1: Cleaning of wet press felts

[0050] Four sets of felt samples, with each set containing 2 samples, were used for this study. Circular felt samples with around 2" diameter were randomly die-cut from the bulk felt samples. Three sets were from tissue and towel producing paper mills (Mill 1-3). The remaining set was virgin felts contaminated with PAE in the laboratory (VF). The circularly cut virgin felt samples were soaked in PAE solution, followed by heating in a 105°C oven for 2.5 hours to promote cross-linking.

[0051] Each felt sample was washed and tested separately. A tergotometer was used to wash the felt samples. Loose fibers were collected between the wash and rinse cycles. This fiber collection was rolled into a small ball, dried, weighed, and recorded as "fiber loss" in the results. The results reported for contaminant removal are corrected for the fiber loss.

[0052] One felt sample from each set was washed with 5% (w/w) of composition A (Table 1). The composition was diluted with tap water. The other felt sample from each set was washed with tap water and was used as control for comparison. The felts were placed in separate washing containers and were placed in the tergotometer. The tergotometer was run at 60°C for 30 minutes for the first washing step; pH was checked and recorded for each container. The container contents were then poured over a vacuum sieve to collect the felt samples and the loose fibers. The samples and container were rinsed with tap water and the samples were placed back in the container for the rinse cycle at the same temperature for 15 minutes; pH was checked and recorded for each container. Again, the contents of these containers were poured over a vacuum sieve to collect the felt samples and the loose fibers.

[0053] The mass of each felt sample was recorded pre- and post-wash. The felt fiber loss was collected at the end of each wash and rinse cycle and weighed as a fiber loss percentage. This fiber loss percentage indicates how harsh the chemical treatment was for the felt. Fiber loss was partially due to the harshness of the chemical treatment and partially due to the fact the felts were used felts from mills used in wash studies and were not brand new. After accounting for fiber loss, the remaining difference in felt mass between pre- and post-wash measurements is attributed to contaminant removal and reported as such. Ideally, the chemical treatment removes the greatest amount of contaminant without causing too much fiber loss and damage to the felt. Percentage contaminant removed and fiber loss percentages are reported in Table 2 and 3, respectively and were calculated as

[0054] Porosity (or air permeability) test was conducted on pre- and post- wash felts using a Gurley Precision Porosity tester with a digital timer. The test was conducted with air passing through the individual felt sample. A digital timer records the length of time for a controlled volume of air to pass through the sample. The pre-wash porosity accounts for any contamination of felts, which would block the felt pores. The post-wash test indicates the porosity after targeted contaminant removal. Thus, comparing pre- and post- wash porosity is indicative of overall contaminant removal. The porosity time was recorded in Gurley seconds and was compared for pre- and post-wash. The lower the Gurley porosity seconds, the more porous the felts are. Cleaner felts should have higher porosity, thus lower Gurley porosity seconds indicate better cleaning ability. Gurley porosity seconds are reported in Table 4.

[0055] Water absorption speed was performed on pre- and post-wash felts as well. 100 ml fresh deionized water was added to an 8 oz straight-sided, wide-mouth jar. Felt samples were manually flattened and were placed on top of the water surface using tweezers. The time between initial touching of felts on water surface and the start of sinking of felt samples was recorded. As is often the case, the felts may be too contaminated (even after a wash) and too hydrophobic to allow water to permeate the fabric. If the test runs over 180 seconds, a ">180 s" or "failed water absorption speed test" was reported. This test helps to indicate how easily the felt sample would absorb water by how "open/free" the felt was and how hydrophilic or hydrophobic the felt was after comparing pre- and post-wash measurements. Cleaner felts have higher water absorption speed (more open sites for water to absorb because less contaminants are holding those sites), and thus water absorption seconds would be lower. Water absorption seconds are reported in Table 5.

[0056] Results in Table 2 show that wash with 5% of Composition A removes significantly higher percentage of contaminants compared to the control. Results in Table 3 show fiber loss percentage for wash with 5% of Composition A, for all types of tested felts, were very low, and were similar to that of the control. Results in Table 4 show porosity of the felts increased (Gurley porosity seconds decreased) more compared to the control, by washing with 5% of Composition A. Results in Table 5 show water absorption speed of the felts increased (water absorption seconds decreased) significantly compared to the control, by washing with 5% of Composition A. Thus, Composition A cleans contaminants from the felts (Tables 2, 4 and 5) without appreciably damaging the felts (Table 3).

Example 2: Preventing wet strength resins from contaminating wet press felts.

[0057] Virgin felt samples with around 2" diameter were cut by a standard die cutter. One set of samples were then placed into a 10% (w/w) aqueous solution of Composition A and another set in water, used as control. The samples were soaked for five minutes at room temperature and dried overnight (16 hours) in a 45°C oven. Wet strength chemical, PAE, was diluted using deionized water. The dried soaked felts were placed into the diluted PAE solution (2.5% w/w) and soaked for five minutes at room temperature, then dried for 6.5 hours in a 45°C oven and then crosslinked in 90°C oven for 4.5 hours. Felts were washed at 60°C in 600 ml tap water for 30 minutes at 150 rpm in tergotometer (Figure 1). Fiber loss, porosity and water absorption speed were measured with processes as described in Example 1. Percentage weight increased was calculated as

[0058] Percentage weight increased, fiber loss, Gurley porosity seconds and water absorption seconds are reported in Table 6. Percentage weight increased, for felts that were placed in 10% aqueous solution of Composition A were lower compared to control felts (felts that were placed in water instead of 10% aqueous solution of Composition A). Porosity and water absorption speed of felts that were placed in 10% aqueous solution of Composition A were higher (Gurley porosity seconds and water absorption seconds lower) compare to the control. These results show Composition A prevents PAE from contaminating the felts. Fiber loss percentages for felts that were placed in 10% aqueous solution of Composition A were lower compared to the control. This shows that the Composition A does not damage the felts.

Table 1: Composition A

	Weight %
Water	61.5
Citric acid	25
Isotridecyl alcohol ethoxylate (9 EO)	5
Diethylene glycol monobutyl ether	5
Carbowet GA-211 (Air Products)	3
FeSO4	0.5

Table 2: Contaminant (%) removed

	Mill 1	Mill 2	Mill 3	VF
Comp. A (5%)	1.03	2.16	1.81	1.032
Control	0.87	1.42	1.41	0.485

Table 3: Felt Fiber loss (%)

	Mill 1	Mill 2	Mill 3	VF
Comp. A (5%)	0.83	0.76	0.68	0.97
Control	0.84	0.51	0.62	0.65

Table 4: Gurley Porosity (s)

	Mill 1		Mill 2		Mill 3		VF
	Before wash	After wash	Before wash	After wash	Before wash	After wash	Before wash	After wash
Comp. A (5%)	9.86	8.67	12.30	9.42	12.98	10.88	7.62	9.43
Control	9.98	9.52	14.73	13.17	13.43	11.81	7.62	10.00

Table 5: Water Absorption Speed (s)

	Mill 1		Mill 2		Mill 3		VF
	Before wash	After wash	Before wash	After wash	Before wash	After wash	After wash
Comp. A (5%)	11.82	3.54	3.30	2.64	>180	7.76	5.06
Control	10.91	45.73	3.15	3.40	>180	>180	102.68

Table 6: Preventing PAE crosslinking on Virgin Felts

Formulation	Weight increased (%)	Fiber Loss (%)	Gurley Porosity (s)		Water Absorption (s)
			Average	STDEV	Average	STDEV
Control	2.73	0.74	8.15	0.42	319.310∗	14.22
Comp. A (10%)	2.21	1.25	8.00	0.32	4.21	0.33

∗ For the control, the water absorption spend test were run longer than 180 seconds.

Claims

1. Use of a composition comprising

- an aqueous solution of a weak organic acid,

- a surfactant, preferably a nonionic surfactant,

- a divalent metal ion containing catalyst, and

- optionally a glycol ether containing solvent,

for cleaning wet strength resin contamination from papermaking equipment, wherein the contamination is formed from use of wet strength resins in a papermaking process, wherein the wet strength resin is polyamide epichlorohydrin (PAE) resin,

by contacting the papermaking equipment with the composition.

2. The use of claim 1, wherein the organic acid is selected from a group consisting of citric acid, adipic acid, glycolic acid and combinations thereof.

3. The use of claims 1 or 2, wherein the surfactant is selected from a group consisting of isotridecyl alcohol ethoxylate, dodecanol ethoxylate, ethoxylated 2,4,7,9-tetramethyl 5 decyne-4,7-diol, polyethylene glycol trimethylnonyl ether, polysorbates, ethoxylated secondary alcohols containing surfactants and combinations thereof.

4. The use of any one of claims 1, 2 or 3, wherein the divalent metal ion is selected from a group consisting of Ca⁺², Mg⁺², Ba⁺², Fe⁺², Cu⁺², Ni⁺², Mn⁺², and Co⁺², preferably Fe⁺², Ca⁺², Cu⁺² or Ni⁺².

5. The use of any one of claims 1-4, wherein the glycol ether containing solvent is selected from the group consisting of diethylene glycol monobutyl ether, diethylene glycol monoethyl ether and a combination thereof.

6. The use of any one of claims 1-5, wherein organic acid concentration is within 10%-45%, preferably 20%-30%; and/or surfactant concentration is within 2%-25%, preferably 5%-13%; and/or glycol ether containing solvent concentration is within 0%-15%, preferably 3%-8%; and/or divalent metal ion containing catalyst concentration is within 0.01%-5%, preferably 0.25%-3% and rest being water.

7. The use of any of claims 1-6, wherein the composition and/or the equipment are at an elevated temperature.

8. The use of any one of claims 1-7, wherein contact time is between 0.1 second to 5 hours, preferably between 30 seconds to 1 hour, more preferably 1 minute to 30 minutes.

9. A method of preventing wet strength resins from contaminating a papermaking equipment in a papermaking process, wherein the method comprises a step of contacting the equipment with a composition comprising

- an aqueous solution of a weak organic acid,

- a surfactant, preferably a nonionic surfactant,

- a divalent metal ion containing catalyst, and

- optionally a glycol ether containing solvent,

before and/or during and/or after addition of wet strength resin in the papermaking process, wherein the wet strength resin is polyamide epichlorohydrin (PAE) resin.

Ansprüche

1. Verwendung einer Zusammensetzung umfassend

- eine wässrige Lösung einer schwachen organischen Säure,

- ein Tensid, vorzugsweise ein anionisches Tensid,

- einen Zweiwertiges-Metallion-enthaltenden Katalysator und

- gegebenenfalls ein Glycolether-enthaltendes Lösungsmittel,

zum Reinigen von Verunreinigung durch nassfestes Harz an Papierherstellungsausrüstung, wobei die Verunreinigung durch die Verwendung von nassfesten Harzen bei einem Papierherstellungsverfahren gebildet ist, wobei das nassfeste Harz Polyamidepichlorhydrin(PAE)-Harz ist,

durch Inkontaktbringen der Papierherstellungsausrüstung mit der Zusammensetzung.

2. Verwendung gemäß Anspruch 1, wobei die organische Säure ausgewählt ist aus einer Gruppe bestehend aus Citronensäure, Adipinisäure, Glycolsäure und Kombinationen davon.

3. Verwendung gemäß Anspruch 1 oder 2, wobei das Tensid ausgewählt ist aus einer Gruppe bestehend aus Isotridecylalkoholethoxylat, Dodecanolethoxylat, ethoxyliertem 2,4,7,9-Tetramethyl-5-decin-4,7-diol, Polyethylenglycoltrimethylnonylether, Polysorbaten, ethoxylierten sekundären Alkoholen, die Tenside enthalten, und Kombinationen davon.

4. Verwendung gemäß einem der Ansprüche 1, 2 oder 3, wobei das zweiwertige Metallion ausgewählt ist aus einer Gruppe bestehend aus Ca⁺², Mg⁺², Ba⁺², Fe⁺², Cu⁺², Ni⁺², Mn⁺² und Co⁺², vorzugsweise Fe⁺², Ca⁺², Cu⁺² oder Ni⁺².

5. Verwendung gemäß einem der Ansprüche 1-4, wobei das Glycolether-enthaltende Lösungsmittel ausgewählt ist aus der Gruppe bestehend aus Diethylenglycolmonobutylether, Diethylenglycolmonoethylether und einer Kombination davon.

6. Verwendung gemäß einem der Ansprüche 1-5, wobei die Konzentration von organischer Säure innerhalb von 10 % bis 45 %, vorzugsweise 20 % bis 30 %, liegt; und/oder die Tensidkonzentration innerhalb von 2 % bis 25 %, vorzugsweise 5 % bis 13 %, liegt; und/oder die Konzentration von Glycolether-enthaltendem Lösungsmittel innerhalb von 0 % bis 15 %, vorzugsweise 3 % bis 8 %, liegt; und/oder die Konzentration von Zweiwertiges-Metallion-enthaltendem Katalysator innerhalb von 0,01 % bis 5 %, vorzugsweise 0,25 % bis 3 %, liegt, und der Rest Wasser ist.

7. Verwendung gemäß einem der Ansprüche 1-6, wobei die Zusammensetzung und/oder die Ausrüstung bei einer erhöhten Temperatur vorliegen.

8. Verwendung gemäß einem der Ansprüche 1-7, wobei die Kontaktdauer zwischen 0,1 Sekunde und 5 Stunden, vorzugsweise zwischen 30 Sekunden und 1 Stunde, bevorzugter 1 Minute bis 30 Minuten, beträgt.

9. Verfahren zum Verhindern, dass nassfeste Harze eine Papierherstellungsausrüstung bei einem Papierherstellungsverfahren verunreinigen, wobei das Verfahren einen Schritt des Inkontaktbringens der Ausrüstung mit einer Zusammensetzung umfassend

- eine wässrige Lösung einer schwachen organischen Säure,

- ein Tensid, vorzugsweise ein nichtionisches Tensid,

- einen Zweiwertiges-Metallion-enthaltenden Katalysator und

- gegebenenfalls ein Glycolether-enthaltendes Lösungsmittel,

vor und/oder während und/oder nach Zugeben von nassfestem Harz bei dem Papierherstellungsverfahren umfasst, wobei das nassfeste Harz Polyamidepichlorhydrin(PAE)-Harz ist.

Revendications

1. Utilisation d'une composition comprenant

- une solution aqueuse d'un acide organique faible,

- un tensioactif, préférablement un tensioactif non ionique,

- un catalyseur contenant un ion métallique divalent, et

- éventuellement un solvant contenant un éther de glycol,

pour le nettoyage d'une contamination avec une résine résistante à l'humidité provenant d'un appareil de fabrication de papier, la contamination étant formée par utilisation de résines résistantes à l'humidité dans un procédé de fabrication de papier, la résine résistante à l'humidité étant une résine de polyamide épichlorhydrine (PAE),

par mise en contact de l'appareil de fabrication de papier avec la composition.

2. Utilisation selon la revendication 1, l'acide organique étant choisi dans un groupe constitué par l'acide citrique, l'acide adipique, l'acide glycolique et des combinaisons correspondantes.

3. Utilisation selon la revendication 1 ou 2, le tensioactif étant choisi dans un groupe constitué par l'éthoxylate d'alcool isotridécylique, l'éthoxylate de dodécanol, le 2,4,7,9-tétramethyl-5-décyne-4,7-diol éthoxylé, l'éther de triméthylnonyle de polyéthylène glycol, des polysorbates, des tensioactifs contenant des alcools secondaires éthoxylés et des combinaisons correspondantes.

4. Utilisation selon l'une quelconque des revendications 1, 2 et 3, l'ion métallique divalent étant choisi dans un groupe constitué par Ca⁺², Mg⁺², Ba⁺², Fe⁺², Cu⁺², Ni⁺², Mn⁺², et Co⁺², préférablement Fe⁺², Ca⁺², Cu⁺² ou Ni⁺².

5. Utilisation selon l'une quelconque des revendications 1 à 4, le solvant contenant un éther de glycol étant choisi dans le groupe constitué par l'éther de monobutyle de diéthylèneglycol, l'éther de monoéthyle de diéthylèneglycol et une combinaison correspondante.

6. Utilisation selon l'une quelconque des revendications 1 à 5, la concentration en acide organique étant entre 10 % et 45 %, préférablement entre 20 % et 30 % ; et/ou la concentration en tensioactif étant entre 2 % et 25 %, préférablement entre 5 % et 13 % ; et/ou la concentration en solvant contenant un éther de glycol étant entre 0 % et 15 %, préférablement entre 3 % et 8 % ; et/ou la concentration en catalyseur contenant un ion métallique divalent étant entre 0,01 % et 5 %, préférablement entre 0,25 % et 3 % et le reste étant de l'eau.

7. Utilisation selon l'une quelconque des revendications 1 à 6, la composition et/ou l'appareil étant à une température élevée.

8. Utilisation selon l'une quelconque des revendications 1 à 7, le temps de contact étant compris entre 0,1 seconde et 5 heures, préférablement entre 30 secondes et 1 heure, plus préférablement entre 1 minute et 30 minutes.

9. Procédé de prévention de la contamination, par des résines résistantes à l'humidité, d'un appareil de fabrication de papier, le procédé comprenant une étape de mise en contact de l'appareil avec une composition comprenant

- une solution aqueuse d'un acide organique faible,

- un tensioactif, préférablement un tensioactif non ionique,

- un catalyseur contenant un ion métallique divalent, et

- éventuellement un solvant contenant un éther de glycol,

avant et/ou pendant et/ou après l'ajout d'une résine résistante à l'humidité dans le procédé de fabrication de papier, la résine résistante à l'humidité étant une résine de polyamide épichlorhydrine (PAE).

Drawing