Technical Field
[0001] The present invention relates to a wrapping paper for a smoking article that has
a low ignition propensity and a smoking article comprising a wrapping paper that has
a low ignition propensity.
Background Art
[0002] When a burning smoking article is left on furnishings and equipment, such as a couch
or a bed, it could cause a fire. In order to prevent this, several approaches are
known from the state of the art to cause a smoking article to self-extinguish. These
types of smoking articles are generally known as "low ignition propensity" smoking
articles. However it is undesirable to have a smoking article self-extinguish while
a smoker is using it.
[0003] US 2013/104,915 teaches a cigarette paper that provides a cigarette manufactured therefrom with self-extinguishing
properties, wherein the base paper has a CO
2 diffusivity of less than 0.35 cm/s and the cigarette paper comprises at least one
discrete area, wherein this area is perforated and has an air permeability greater
than the air permeability beyond the perforated area.
[0004] US 2016/198,761 relates to a cigarette paper with self-extinguishing properties that has treated
areas, onto which a composition is applied that contains filler particles or a mixture
of filler particles, wherein the diffusion capacity in the treated areas is less than
in an untreated area of the cigarette paper. In this regard, at least 20% by weight
of the filler particles in the treated areas are formed by a filler with a flaked
shape, a filler with a scalenohedral crystal structure, a filler with a rhombohedral
crystal structure, or a filler with a cubic shape.
[0005] To prevent a fire and to suppress sidestream smoke,
Japanese Utility Model No. 3049857 discloses a cigarette wherein the length of the tobacco rod is half that of the ordinary
cigarette. Also
Japanese Patent Application KOKAI No. 7-327654 discloses a cigarette wherein the length of the tobacco rod is decreased to 1 to
1.5 cm in order to prevent a fire and to suppress the sidestream smoke. These cigarettes
having a shorter than usual tobacco rod provide a number of puffs considerably smaller
than that provided by the cigarette available on the market.
[0006] The problem of the present invention is to provide a wrapping paper for a smoking
article that has a low ignition propensity and a reduced impact on taste.
[0007] US 2012/0227754 discloses a smoking article which includes a smokable rod manufactured using a paper
wrapping material having an additive material applied thereto as a pattern. The wrapping
paper includes at least one region coated with an additive material coating formulation
having a porosity of less than about 20 CORESTA and a diffusion capacity no greater
than 0.2 cm/sec. The coated region is on a base sheet having a porosity of greater
than about 120 CORESTA and a diffusion capacity of at least 1.7 cm/sec.
Brief description of the invention
[0008] The inventors have found that by providing a wrapping paper for a smoking article
with a plurality of burn-suppressing regions and a certain ratio of diffusion capacity
between the burn-suppressing regions and the base paper, i.e. the non-burn-suppressing
regions, it is possible to obtain a low ignition propensity smoking article with a
reduced impact on taste.
[0009] A first aspect of the present invention relates to a wrapping paper comprising a
base paper, where the base paper comprises a plurality of burn-suppressing regions
that are provided apart from each other, wherein the ratio of diffusion capacity between
the burn-suppressing regions and the base paper, i.e. the non-burn suppressing regions,
is in the range of 5% to 35%.
[0010] In another aspect of the present invention, a smoking article is disclosed comprising
a charge of smokable material surrounded by a wrapping paper according to the first
aspect of the invention. The smoking article is in particular a low ignition propensity
smoking article.
[0011] Further aspects and embodiments of the invention are disclosed in the dependent claims
and can be taken from the following description and examples, without being limited
thereto.
Figures
[0012] The enclosed drawings should illustrate embodiments of the present invention and
convey a further understanding thereof. In connection with the description it serves
as explanation of concepts and principles of the invention. Other embodiments and
many of the stated advantages can be derived in relation to the drawings.
[0013] FIG. 1 is a schematic perspective view, partly broken away, showing an example of
a cigarette that is wrapped with a cigarette paper having stripe-shaped burn-suppressing
regions according to one embodiment of the present invention.
[0014] The cigarette 10 has a tobacco rod 11 consisting of a tobacco filler 13 that is wrapped
with a wrapping paper 12 of the present invention in the form of a column. An ordinary
filter 15 may be attached to the proximal end (namely, the downstream end in the inhaling
direction) 11b of the tobacco rod 11 by using a tipping paper 14 according to a conventional
method.
[0015] A plurality of stripe-shaped burn-suppressing regions 122, which are coated as will
be explained in the forthcoming description, are formed on one of the surfaces of
the base paper 121 that constitutes the wrapping paper 12 of the present invention.
These stripe-shaped burn-suppressing regions 122 are formed apart from each other
in the circumferential direction of the tobacco rod 11.
[0016] Non-burn-suppressing regions 123 are formed between the adjacent stripe-shaped burn-suppressing
regions 122. Since the regions 123 are constituted by a part of the base paper 121,
they can burn in an ordinary smoking state. Therefore, the regions 123 each act as
a non-burn-suppressing region. For example, the stripe-shaped burn-suppressing regions
122 each may have a width of 1 to 6 mm in the circumferential direction. The distance
between the adjacent burn-suppressing regions 122 may be 2 to 20 mm.
[0017] In the cigarette shown in FIG. 1, a non-burn-suppressing region 124 may be provided
to the region covering a distance d from the tip 11a of the base paper 121.
[0018] FIG. 2 is a schematic perspective view, partly broken away, showing an example of
a cigarette that is wrapped with a cigarette paper having annular band-shaped burn-suppressing
regions according to another embodiment of the present invention.
[0019] The cigarette 20 has a similar structure to that of the cigarette 10 shown in FIG.
1, except for the structure of the burn-suppressing regions in the wrapping paper.
Therefore, in FIG. 2, an identical reference number is assigned to the same element
as the constitutional element in FIG. 1, and the explanation thereof is omitted.
[0020] In the cigarette 20 shown in FIG. 2, a plurality of annular band-shaped burn-suppressing
regions 211 are formed on the base paper 121 of the wrapping paper 21 wrapping the
tobacco filler 13, defining burn-suppressing regions. These annular band-shaped burn-suppressing
regions 211 are formed apart from each other in the longitudinal direction of the
tobacco rod 11.
[0021] Non-burn-suppressing regions 212 are formed between the adjacent annular band-shaped
burn-suppressing regions 211. Since the non-burn-suppressing regions 212 are constituted
by a part of the base paper 121, they can burn in an ordinary smoking state. Therefore,
the regions 212 each act as a non-burn-suppressing region, as the regions 123 in FIG.
1 do. For example, the annular band-shaped burn-suppressing regions 211 each may have
a width of 4 to 7 mm in the longitudinal direction. The distance between the adjacent
burn-suppressing regions 211 may be 18 to 25 mm.
Detailed description of the invention
[0022] Unless defined otherwise, technical and scientific terms used herein have the same
meaning as commonly understood by one of ordinary skill in the art to which this invention
belongs.
[0023] All values given in the present disclosure are to be understood to be complemented
by the word "about", unless it is clear to the contrary from the context.
[0024] Smoking articles as referred to herein are not particularly limited and can for example
be cigarettes, cigarillos or the like. They typically have a generally cylindrical
rod shaped configuration and include a charge, roll, or column of smokable material,
such as shredded tobacco (e.g. in cut filler form), which is surrounded by a paper
wrapper forming a so-called "tobacco rod". A cigarette or cigarillo usually also has
a cylindrical filter element aligned in end-to-end relationship with the tobacco rod.
The filter element may, for example, comprise a plug of cellulose acetate tow, and
the tow is circumscribed by a wrapper material known as "plug wrap". Typically, the
filter element is attached to one end of the tobacco rod using a circumscribing wrapping
material known as "tipping wrapper". The filter element wrapped by the tipping wrapper
is known as "mouthpiece element".
[0025] As used herein, wt.-% is to be understood as weight percent, based on the dry weight
of the base paper, unless explicitly otherwise specified. In the present disclosure,
all amounts given in wt.-% in a particular embodiment add up to 100 wt.-%. The weight
percent are thereby calculated by dividing the mass of each component by the dry mass
of the base paper.
[0026] As used herein, a "low ignition propensity" smoking article is one that has been
designed to be less likely than a conventional cigarette to ignite furnishings and
equipment, e.g. soft furnishings such as a couch or mattress. Ideally, a low ignition
propensity smoking article will continue to burn when freely suspended such as in
the holder of an ashtray or when being held in the hand without puffing ("free burn").
The tendency for a cigarette to go out during free burn is referred to as "self-extinguishment".
[0027] The capability of a smoking article to extinguish or to generate sufficient heat
to continue burning, and thus potentially cause ignition of bedding or upholstered
furniture (referred to as LIP) may be measured by any suitable method. In the present
invention this is done according to ISO 12863:2010.
[0028] The likelihood of a smoking article to extinguish while burning in free air (referred
to as FASE) may be measured by any suitable method. In the present invention this
is done according to ISO 12863:2010.
[0029] TNCO levels as referred to herein stand for tar, nicotine and carbon monoxide levels
and can be measured by any suitable method. In the present invention this is done
according to ISO 3308:2012.
[0030] The symbol "CU" herein designates the CORESTA air permeability unit that is commonly
used in paper specifications by smoking article designers. The CORESTA air permeability
unit is defined as: "the volumetric flow rate of air in cubic centimeters per minute
(cm3/min) passing through a 1 square centimeter (cm2) sample of substrate at an applied
pressure difference of 1 kilo-Pascal (kPa)." and are measured according to ISO 6565:2011.
[0031] The number of puffs of a smoking article may be measured by any suitable method.
In the present invention this is done according to ISO 3308:2012.
[0033] The present invention relates to a wrapping paper for a smoking article comprising
a base paper, wherein the base paper comprises a plurality of burn-suppressing regions
that are provided apart from each other, wherein the ratio of diffusion capacity between
the burn-suppressing regions and the base paper is in the range of 5% to 35%. By providing
this ratio of diffusion capacity between the burn-suppressing regions and the base
paper outside of the burn-suppressing regions (non-burn-suppressing regions) it is
possible to provide a low ignition propensity smoking article with a reduced impact
on taste. The wrapping paper is formed of a base paper with burn-suppressing regions
provided therein. As the regions of the wrapping paper which are outside the burn-suppressing
regions are to be considered as non-burn suppressing regions the latter being the
same as the base paper, the present application uses the terms "non-burn suppressing
regions" and "base paper" interchangeably.
[0034] In certain embodiments of the present wrapping paper, the ratio of diffusion capacity
between the burn-suppressing regions and the non-burn-suppressing regions, i.e. the
base paper, is in the range of 10% to 35%, or 15% to 35%, or 5% to 30%, or 10% to
30%, or 15% to 30%, or 10% to 25%, or 15% to 25%.
[0035] In a particularly preferred embodiment, the ratio of diffusion capacity between the
burn-suppressing regions and the non-burn-suppressing regions is in the range of 9%
to 17%. It has been found that the impact on taste is particularly reduced in this
range while the wrapping paper still exhibits a good LIP and FASE performance.
[0036] The burn-suppressing regions may be provided on a surface of the base paper or embedded
within a matrix of the base paper. The plurality of burn-suppressing regions may be
provided on a same surface of the base paper. Alternatively, one or more of the plurality
of burn-suppressing regions may be provided on a first surface of the base paper and
the remaining of the plurality of burn-suppressing regions may be provided on a second,
opposite surface of the base paper.
[0037] The shape and amount of these burn-suppressing regions is not further limited and
may vary according to the specific requirements of the smoking article. In certain
embodiments the burn-suppressing regions are in a form of stripes. In one embodiment
all stripes are parallel to each other. In another embodiment at least two stripes
are non-parallel to each other.
[0038] In certain embodiments of the present smoking article comprising a wrapping paper,
when a tobacco rod is wrapped by the wrapping paper, the burn-suppressing regions
are in a form of stripes extending in a longitudinal direction of the tobacco rod
and being spaced apart from each other in a circumferential direction of the tobacco
rod.
[0039] In certain embodiments of the present smoking article comprising a wrapping paper,
when a tobacco rod is wrapped by the wrapping paper, the burn-suppressing regions
are in a form of round annular bands extending in a circumferential direction of the
tobacco rod and being spaced from each other in a longitudinal direction of the tobacco
rod.
[0040] In certain embodiments of the present wrapping paper, the diffusion capacity of the
base paper, i.e. the non-burn suppressing regions, is 1.0 to 2.0 cm/s, e.g. 1.0 to
1.8 cm/s, or e.g. 1.2 to 1.6 cm/s, or e.g. 1.2 to 2.0 cm/s, or e.g. 1.2 to 1.8 cm/s,
or e.g. 1.2 to 1.6 cm/s, or e.g. 1.4 to 2.0 cm/s, or e.g. 1.4 to 1.8 cm/s, or e.g.
1.4 to 1.6 cm/s.
[0041] In certain embodiments of the present wrapping paper, the diffusion capacity of the
burn-suppressing regions is 0.10 to 0.35 cm/s, or e.g. 0.15 to 0.35 cm/s, or e.g.
0.20 to 0.35 cm/s or e.g. 0.10 to 0.30 cm/s, or e.g. 0.15 to 0.30 cm/s, or e.g. 0.20
to 0.30 cm/s, or e.g. 0.10 to 0.25 cm/s, or e.g. 0.15 to 0.25 cm/s, or e.g. 0.20 to
0.25 cm/s.
[0042] These burn-suppressing regions may contain additives that reduce the diffusion capacity
of the base paper. The additives that may be applied to the wrapper may be any of
those used in the art to reduce the ignition propensity of smoking articles.
[0043] In certain embodiments of the present wrapping paper, the burn-suppressing regions
in the wrapping paper contain at least one additive that reduces the diffusion capacity
of the base paper. The additives are optionally selected from the group consisting
of alginates, polyvinyl alcohol, polyvinyl acetates, including partially hydrolyzed
derivatives and copolymers, modified and unmodified starches, cellulose derivatives,
such as carboxy-methyl cellulose, ethyl-cellulose, hydroxymethyl-cellulose and combinations
thereof. The additives may further comprise inorganic ions such as phosphates, mono-
or divalent metal salts, silicas or mixtures thereof. The additives may yet further
comprise natural gums, such as guar gum.
[0044] The additives may be applied to the wrapping paper with a liquid carrier, which may
be in the form of a solution, suspension, emulsion or a combination thereof. The liquid
carrier may be aqueous, non-aqueous or a combination thereof and may contain an emulsifying
agent depending on the nature of the additives.
[0045] In one embodiment, a suspension of additive may be applied within an aqueous carrier.
The aqueous carrier penetrates the base paper transporting the additive into its matrix.
Once the carrier evaporates, the additive is left within the base paper matrix where
it can reduce the diffusion capacity either before or during the burning of the smoking
article. Once applied to the base paper, the liquid carrier is allowed to evaporate
allowing the wrapping paper to dry and for the additive to set within the matrix of
the base paper.
[0046] In certain embodiments of the present wrapping paper, the base paper comprises a
fibrous material, a filler material, and one or more burning additives.
[0047] In certain examples of the present wrapping paper, the paper porosity of the base
paper is 10 to 60 CU and a total amount of burning additive is 0.1 to 0.7 wt.-% based
on the dry weight of the base paper. By providing a base paper with such porosity
and amount of burning additive it is possible to increase the puff count of the smoking
article without impacting on the TNCO levels nor changing the tobacco rod length or
diameter.
[0048] In certain embodiments of the present wrapping paper, the paper porosity of the base
paper is 10 to 50 CU, e.g. 15 to 45 CU. This further increases the puff count of the
smoking article.
[0049] In certain embodiments of the present wrapping paper, the burning additive is included
in the base paper in an amount of 0.2 to 0.6 wt.-%, e.g. 0.3 to 0.5 wt.-% based on
the dry weight of the base paper. This further increases the puff count of the smoking
article.
[0050] In certain embodiments of the present wrapping paper, the burning additive is selected
from the group consisting of citrate salts, e.g. sodium and potassium citrate, acetate
salts, e.g. sodium and potassium acetate, phosphate salts, e.g. sodium and potassium
phosphate, tartrate salts, e.g. sodium and potassium tartrate, nitrate salts, e.g.
sodium and potassium nitrate, or mixtures thereof.
[0051] The burning additive is not particularly limited, as long as it is suitable for use
in a smoking article. In certain embodiments citrate salts are used.
[0052] In certain embodiments of the present wrapping paper, the amount of filler in the
base paper is 17 to 28 wt.-%, e.g. 20 to 25 wt.-%, based on the dry weight of the
base paper. This amount of filler provides an adequate resistance to manufacturing
forces to which the wrapping paper is subject to during high speed manufacturing and
also allows obtaining a desired opacity of the wrapping paper.
[0053] In certain embodiments of the present smoking article comprising a wrapping paper,
the filler in the base paper is selected from the group consisting of calcium carbonate,
such as precipitated calcium carbonate (PCC) or ground calcium carbonate (GCC), kaolin
clay, talc, titanium dioxide, alumina trihydrate, and precipitated silica and silicates
(PSS), or mixtures thereof.
[0054] Just like the burning additive, the filler is not particularly limited, as long as
it is suitable for use in a smoking article. In certain embodiments calcium carbonate
is used.
[0055] In one embodiment according to the present invention, the paper porosity of the base
paper is 40 to 50 CU, e.g. 43 to 47 CU, e.g. 45 CU, the total amount of burning additive
is in an amount of 0.4 to 0.6 wt.-%, e.g. 0.5 wt.-%, based on the dry weight of the
base paper, and the amount of filler in the base paper is 17 to 23 wt.-%, e.g. 19
to 21 wt.-%, e.g. 20 wt.-%, based on the dry weight of the base paper.
[0056] According to certain embodiments, the balance to 100 wt.-% of the dry weight of the
base paper is essentially filler and fibrous material.
[0057] In certain embodiments of the present wrapping paper, the basis weight of the base
paper is 20 to 26 g/m
2, e.g. 21 to 24 g/m
2, or e.g. 23 to 25 g/m
2, e.g. 24 g/m
2. By providing a base paper with a basis weight comprised in these ranges it is possible
to obtain a desired opacity of the wrapping paper while controlling the level of CO.
[0058] In certain embodiments of the present wrapping paper, the fibrous material is a cellulosic
fibrous material.
[0059] The present invention further relates to a smoking article comprising a wrapping
paper as in the embodiments described above and in which the wrapping paper surrounds
a charge, roll or column of smokable material to form a tobacco rod.
[0060] In certain embodiments of the present smoking article, when a tobacco rod is wrapped
by the wrapping paper, the burn-suppressing regions are in a form of stripes extending
in a longitudinal direction of the tobacco rod and being spaced apart from each other
in a circumferential direction of the tobacco rod.
[0061] In certain embodiments of the present smoking article, when a tobacco rod is wrapped
by the wrapping paper, the burn-suppressing regions are in a form of round annular
bands extending in a circumferential direction of the tobacco rod and being spaced
from each other in a longitudinal direction of the tobacco rod.
[0062] The present invention relates to a wrapping paper comprising a plurality of burn-suppressing
regions that are provided apart from each other on one surface of the wrapping paper,
wherein the ratio of diffusion capacity between the burn-suppressing regions and the
non-burn suppressing regions is in the range of 5% to 35%.
[0063] Without being bound to a certain theory, the positive effect of the present invention,
i.e. the combination of a low ignition propensity without a deterioration of taste
properties is due to the specific ratio of diffusion capacity between the burn-suppressing
regions and the non-burn suppressing regions that are provided apart from each other
at the base paper as laid out above.
[0064] The above embodiments can be combined arbitrarily, if appropriate. Further possible
embodiments and implementations of the invention comprise also combinations of features
not explicitly mentioned in the foregoing or in the following with regard to the examples
of the invention. Particularly, a person skilled in the art will also add individual
aspects as improvements or additions to the respective basic form of the invention.
Examples
[0065] The present invention will now be described in detail with reference to examples
thereof. However, these examples are illustrative and do not limit the scope of the
invention.
Example 1
[0066] Two 84 mm cigarettes with increased puff count were prepared with the same tobacco
blend. These cigarettes had both a 63 mm tobacco rod attached to a 21 mm filter by
a tipping paper. The filters were cut from the same filter rod and the tipping papers
were cut from the same reel. The tobacco rod of cigarette A was wrapped in a prior
art wrapping paper (paper A), while cigarette B was wrapped in a wrapping paper according
to the invention (paper B). In both wrapping papers the burn-suppressing regions were
6 mm wide annular bands separated between them by 18 mm in a construction similar
to the one depicted in FIG. 2. The specifications of the respective wrapping papers
are indicated in Table 1 below.
Table 1
| |
Paper A |
Paper B |
| Basis weight |
27 g/m2 |
24 g/m2 |
| Porosity |
80 CU |
45 CU |
| Diffusion capacity in the burn-suppressing regions |
0.045 cm/s |
0.230 cm/s |
| Diffusion capacity in the non-burn-suppressing regions (base paper diffusion capacity) |
2.3 cm/s |
1.8 cm/s |
| Burning additive type |
Citrate salt |
Citrate salt |
| Burning additive amount |
1.4 wt.-% |
0.5 wt.-% |
| Filler (calcium carbonate) |
27.7 wt.-% |
20.0 wt.-% |
[0067] These cigarettes were measured under ISO 3308:2012 conditions to determine their
TNCO levels as well as their respective puff counts. Self-extinguishment was also
measured for these cigarettes, both when positioned on a surface (ISO 12863:2010 -
referred to as LIP) and when burning in free air (ISO 12863:2010 - referred to as
FASE). The results are shown in Table 2 below. It was found that wrapping paper B
increased the puff count of cigarette B by 1.3 while maintaining very similar TNCO
levels. Paper B also shows a high self-extinguishing rate when positioned on a surface
and a significantly improved performance when burning in free air.
[0068] A blind smoking test conducted with a panel of smoking experts was used to evaluate
the impact on taste. The test consisted of providing one cigarette of each type to
each panelist, who smoked them consecutively and then indicated which one tasted better.
The panel of experts concluded that cigarette B has a better taste than cigarette
A.
Table 2
| |
Cigarette A |
Cigarette B |
| Tar |
9.8 mg |
10.0 mg |
| Nicotine |
0.80 mg |
0.85 mg |
| CO |
9.0 mg |
9.3 mg |
| Puff count |
6.8 |
8.1 |
| LIP |
100% |
94% |
| FASE |
30% |
8% |
Example 2
[0069] Two 84 mm low ignition propensity cigarettes were prepared with the same tobacco
blend. These cigarettes had both a 57 mm tobacco rod attached to a 27 mm filter by
a tipping paper. The filters were cut from the same filter rod and the tipping papers
were cut from the same reel. The tobacco rod of cigarette C was wrapped in the prior
art wrapping paper from example 1 (paper A), while cigarette D was wrapped in the
wrapping paper according to the invention from example 1 (paper B).
[0070] These cigarettes were measured under ISO 3308:2012 conditions to determine their
TNCO levels as well as their respective puff counts. Self-extinguishment was also
measured for these cigarettes, both when positioned on a surface (ISO 12863:2010 -
referred to as LIP) and when burning in free air (ISO 12863:2010 - referred to as
FASE). The results are shown in Table 3 below. It was found that wrapping paper B
increased the puff count of cigarette D by 0.9 while maintaining very similar TNCO
levels. Paper B continues to show a high self-extinguishing rate when positioned on
a surface and a significantly improved performance when burning in free air.
[0071] A blind smoking test conducted with a panel of smoking experts as in example 1 showed
that cigarette D has a better taste than cigarette C.
Table 3
| |
Cigarette C |
Cigarette D |
| Tar |
8.0 |
8.1 |
| Nicotine |
0.62 |
0.68 |
| CO |
9.1 |
9.2 |
| Puff count |
5.6 |
6.5 |
| LIP |
98% |
95% |
| FASE |
38% |
23% |
Example 3
[0072] Four 84 mm cigarettes were prepared with the same tobacco blend. These cigarettes
had both a 63 mm tobacco rod attached to a 21 mm filter by a tipping paper. The filters
were cut from the same filter rod and the tipping papers were cut from the same reel.
The tobacco rod of cigarette E was wrapped in a wrapping paper (paper C) with no burn-suppressing
regions, which was used as a taste benchmark for the wrapping papers of the tobacco
rods of cigarettes F, G and H (papers D, E and F, respectively) that do contain burn-suppressing
regions. Wrapping papers D, E and F only differ from wrapping paper C in the presence
of burn-suppressing regions and differ amongst each other in the diffusion capacity
of the burn-suppressing regions. In wrapping papers D, E and F the burn-suppressing
regions were 6 mm wide annular bands separated between them by 18 mm in a construction
like the one depicted in FIG. 2. The specifications of the respective wrapping papers
are indicated in Table 4 below.
[0073] These cigarettes were measured under ISO 3308:2012 conditions to determine their
TNCO levels as well as their respective puff counts. Self-extinguishment was also
measured for these cigarettes, both when positioned on a surface (ISO 12863:2010 -
referred to as LIP) and when burning in free air (ISO 12863:2010 - referred to as
FASE). The results are shown in Table 5 below. It was found that wrapping paper F
continues to show a high self-extinguishing rate when positioned on a surface and
a significantly improved performance when burning in free air when compared to wrapping
papers D and E, while maintaining very similar TNCO levels to wrapping paper C.
Table 4
| |
Paper C |
Paper D |
Paper E |
Paper F |
| Basis weight |
24 g/m2 |
24 g/m2 |
24 g/m2 |
24 g/m2 |
| Porosity |
45 CU |
45 CU |
45 CU |
45 CU |
| Diffusion capacity in the burn-suppressing regions |
N/A |
0.04 cm/s |
0.09 cm/s |
0.28 cm/s |
| Diffusion capacity in the non-burn-suppressing regions (base paper diffusion capacity) |
1.67 cm/s |
1.67 cm/s |
1.67 cm/s |
1.67 cm/s |
| Burning additive type |
Citrate salt |
Citrate salt |
Citrate salt |
Citrate salt |
| Burning additive amount |
0.5 wt.-% |
0.5 wt.-% |
0.5 wt.-% |
0.5 wt.-% |
| Filler (calcium carbonate) |
20 wt.-% |
20 wt.-% |
20 wt.-% |
20 wt.-% |
Table 5
| |
Cigarette E |
Cigarette F |
Cigarette G |
Cigarette H |
| Tar |
8.4 |
9.1 |
9.2 |
8.9 |
| Nicotine |
0.7 |
0.7 |
0.8 |
0.7 |
| CO |
8.3 |
10.3 |
10.1 |
9.5 |
| LIP |
20% |
100% |
100% |
85% |
| FASE |
0% |
90% |
65% |
10% |
[0074] A blind smoking test conducted with a panel of experts was used to evaluate the impact
on taste. Each panelist received three reference cigarettes (cigarette E), and three
test cigarettes, one of each type (F, G, H), grouped in pairs so that each pair would
contain a reference cigarette and a test cigarette. The panelists smoked the pairs
of cigarettes consecutively, and then indicated which of the test cigarettes was closer
in taste to the reference cigarette. The smoking test concluded that cigarette H was
closer in taste to reference cigarette E.
Example 4
[0075] Four 84 mm cigarettes were prepared with the same tobacco blend. These cigarettes
had both a 63 mm tobacco rod attached to a 21 mm filter by a tipping paper. The filters
were cut from the same filter rod and the tipping papers were cut from the same reel.
The tobacco rod of cigarette I was wrapped in a wrapping paper (paper G) with no burn-suppressing
regions, which was used as a taste benchmark for the wrapping papers of the tobacco
rods of cigarettes J, K and L (papers H, I and J, respectively) that do contain burn-suppressing
regions. Wrapping papers H, I and J only differ from wrapping paper G in the presence
of burn-suppressing regions and differ amongst each other in the diffusion capacity
of the burn-suppressing regions. In wrapping papers H, I and J the burn-suppressing
regions were 6 mm wide annular bands separated between them by 18 mm in a construction
similar to the one depicted in FIG. 2. The specifications of the respective wrapping
papers are indicated in Table 6 below.
Table 6
| |
Paper G |
Paper H |
Paper I |
Paper J |
| Basis weight |
24 g/m2 |
24 g/m2 |
24 g/m2 |
24 g/m2 |
| Porosity |
45 CU |
45 CU |
45 CU |
45 CU |
| Diffusion capacity in the burn-suppressing regions |
N/A |
0.04 cm/s |
0.11 cm/s |
0.18 cm/s |
| Diffusion capacity in the non-burn-suppressing regions (base paper diffusion capacity) |
1.95 cm/s |
1.95 cm/s |
1.95 cm/s |
1.95 cm/s |
| Burning additive type |
Citrate salt |
Citrate salt |
Citrate salt |
Citrate salt |
| Burning additive amount |
0.5 wt.-% |
0.5 wt.-% |
0.5 wt.-% |
0.5 wt.-% |
| Filler (calcium carbonate) |
20 wt.-% |
20 wt.-% |
20 wt.-% |
20 wt.-% |
[0076] These cigarettes were measured under ISO 3308:2012 conditions to determine their
TNCO levels as well as their respective puff counts. Self-extinguishment was also
measured for these cigarettes, both when positioned on a surface (ISO 12863:2010 -
referred to as LIP) and when burning in free air (ISO 12863:2010 - referred to as
FASE). The results are shown in Table 7 below. It was found that wrapping paper J
continues to show a high self-extinguishing rate when positioned on a surface and
a significantly improved performance when burning in free air when compared to wrapping
papers H and I, while maintaining very similar TNCO levels to wrapping paper G.
Table 7
| |
Cigarette I |
Cigarette J |
Cigarette K |
Cigarette L |
| Tar |
8.0 |
9.3 |
9.6 |
8.9 |
| Nicotine |
0.7 |
0.8 |
0.7 |
0.7 |
| CO |
8.4 |
11.2 |
10.5 |
10.3 |
| LIP |
20% |
100% |
100% |
95% |
| FASE |
5% |
95% |
75% |
40% |
[0077] A blind smoking test conducted with a panel of experts as in example 3 showed that
cigarette L was closer in taste to reference cigarette I.
1. A wrapping paper (12, 21) for a smoking article, comprising a base paper (121), wherein
the base paper (121) comprises a fibrous material, a filler material, and one or more
burning additives, and a plurality of burn-suppressing regions (122, 211) that are
provided apart from each other,
the ratio of diffusion capacity between the burn-suppressing regions (122, 211) and
the base paper (121) is in the range of 5% to 35%,
characterized in that
a paper porosity of the base paper (121) is 40 to 50 CU, the total amount of burning
additive is in an amount of 0.4 to 0.6 wt.-% based on the dry weight of the base paper
(121), and the amount of filler in the base paper (121) is 17 to 23 wt.-% based on
the dry weight of the base paper (121).
2. The wrapping paper (12, 21) according to claim 1, wherein the diffusion capacity of
the burn-suppressing regions (122, 211) is 0.10 to 0.35 cm/s.
3. The wrapping paper (12, 21) according to claims 1 or 2, wherein the diffusion capacity
of the base paper (121) is 1.0 to 2.0 cm/s.
4. The wrapping paper (12, 21) according to any of the previous claims 1-3, wherein the
burn-suppressing regions (122, 211) are provided on a surface of the base paper (121).
5. The wrapping paper (12, 21) according to any of the previous claims 1-4, wherein the
burn-suppressing regions (122, 211) are provided embedded in a base paper matrix.
6. The wrapping paper (12, 21) according to any of the previous claims 1-5, wherein the
burn-suppressing regions (122, 211) contain at least one additive that reduces the
diffusion capacity of the base paper (121), and wherein said additives are selected
from the group consisting of alginates, polyvinyl alcohol, polyvinyl acetates, modified
and unmodified starches, cellulose derivatives, inorganic ions, natural gums, or mixtures
thereof.
7. The wrapping paper (12, 21) according to any of the previous claims 1-6, wherein the
burn-suppressing regions (122, 211) are in a form of stripes.
8. The wrapping paper (12, 21) according to any of the previous claims 1-7, wherein a
paper porosity of the base paper (121) is 45 CU and a total amount of burning additive
is of 0.5 wt.-% based on the dry weight of the base paper (121) and the amount of
filler in the base paper (121) is 20 wt.-% based on the dry weight of the base paper
(121).
9. The wrapping paper (12, 21) according to any of the previous claims 1-8, wherein the
burning additive is selected from the group consisting of citrate salts, acetate salts,
phosphate salts, tartrate salts, nitrate salts, or mixtures thereof.
10. The wrapping paper (12, 21) according to any of the previous claims 1-9, wherein the
basis weight of the base paper (121) is 20 to 26 g/m2.
11. The wrapping paper (12, 21) according to any of the previous claims 1-10, wherein
the filler material is selected from the group consisting of calcium carbonate, kaolin
clay, talc, titanium dioxide, alumina trihydrate, and precipitated silica and silicates
(PSS), or mixtures thereof.
12. The wrapping paper (12, 21) according to any of the previous claims 1 -11, wherein
the fibrous material is a cellulosic fibrous material.
13. A smoking article (10, 20), comprising a charge of smokable material surrounded by
a wrapping paper (12, 21) according to any of the previous claims 1-12.
1. Hüllpapier (12, 21) für einen Rauchartikel, umfassend ein Basispapier (121), wobei
das Basispapier (121) ein Fasermaterial, ein Füllmaterial und einen oder mehrere Brennzusätze
und eine Vielzahl von Brennunterdrückungsbereichen (122, 211), die getrennt voneinander
angeordnet sind, umfasst,
das Verhältnis der Diffusionskapazität zwischen den Brennunterdrückungsbereichen (122,
211) und dem Basispapier (121) im Bereich von 5% bis 35% liegt,
dadurch gekennzeichnet, dass
eine Papierporosität des Basispapiers (121) 40 bis 50 CU beträgt, die Gesamtmenge
des Brennzusatzes eine Menge von 0,4 bis 0,6 Gew.-%, bezogen auf das Trockengewicht
des Basispapiers (121), ist, und die Menge des Füllstoffs in dem Basispapier (121)
17 bis 23 Gew.-%, bezogen auf das Trockengewicht des Basispapiers (121), beträgt.
2. Hüllpapier (12, 21) gemäß Anspruch 1, wobei die Diffusionskapazität der Brennunterdrückungsbereiche
(122, 211) 0,10 bis 0,35 cm/s beträgt.
3. Hüllpapier (12, 21) gemäß Anspruch 1 oder 2, wobei die Diffusionskapazität des Basispapiers
(121) 1,0 bis 2,0 cm/s beträgt.
4. Hüllpapier (12, 21) gemäß einem der vorhergehenden Ansprüche 1-3, wobei die Brennunterdrückungsbereiche
(122, 211) auf einer Oberfläche des Basispapiers (121) angeordnet sind.
5. Hüllpapier (12, 21) gemäß einem der vorhergehenden Ansprüche 1-4, wobei die Brennunterdrückungsbereiche
(122, 211) eingebettet in einer Matrix des Basispapiers angeordnet sind.
6. Hüllpapier (12, 21) gemäß einem der vorhergehenden Ansprüche 1-5, wobei die Brennunterdrückungsbereiche
(122, 211) mindestens einen Zusatzstoff enthalten, der die Diffusionskapazität des
Basispapiers (121) verringert, und wobei die Zusatzstoffe aus der Gruppe, bestehend
aus Alginaten, Polyvinylalkohol, Polyvinylacetaten, modifizierten und unmodifizierten
Stärken, Cellulosederivaten, anorganischen Ionen, natürlichen Gummis und Mischungen
davon, ausgewählt sind.
7. Hüllpapier (12, 21) gemäß einem der vorhergehenden Ansprüche 1-6, wobei die Brennunterdrückungsbereiche
(122, 211) in Form von Streifen sind.
8. Hüllpapier (12, 21) gemäß einem der vorhergehenden Ansprüche 1-7, wobei die Papierporosität
des Basispapiers (121) 45 CU beträgt, und die Gesamtmenge des Brennzusatzes 0,5 Gew.-%,
bezogen auf das Trockengewicht des Basispapiers (121), beträgt und die Menge des Füllstoffs
in dem Basispapier (121) 20 Gew.-%, bezogen auf das Trockengewicht des Basispapiers
(121), beträgt.
9. Hüllpapier (12, 21) gemäß einem der vorhergehenden Ansprüche 1-8, wobei der Brennzusatz
aus der Gruppe ausgewählt ist, die aus Citratsalzen, Acetatsalzen, Phosphatsalzen,
Tartratsalzen, Nitratsalzen und Mischungen davon besteht.
10. Hüllpapier (12, 21) gemäß einem der vorhergehenden Ansprüche 1-9, wobei das Flächengewicht
des Basispapiers (121) 20 bis 26 g/m2 beträgt.
11. Hüllpapier (12, 21) gemäß einem der vorhergehenden Ansprüche 1-10, wobei der Füllstoff
aus der Gruppe ausgewählt ist, die aus Calciumcarbonat, Kaolin-Ton, Talkum, Titandioxid,
Aluminiumoxidtrihydrat, und gefälltem Silica und Silikaten (PSS) und Mischungen davon
besteht.
12. Hüllpapier (12, 21) gemäß einem der vorhergehenden Ansprüche 1-11, wobei das Fasermaterial
ein Cellulosefasermaterial ist.
13. Rauchartikel (10, 20), umfassend eine Ladung von rauchbarem Material, umgeben von
einem Hüllpapier (12, 21) gemäß einem der vorhergehenden Ansprüche 1-12.
1. Cape (12, 21) destinée à un article à fumer, comprenant un papier de base (121), dans
laquelle
le papier de base (121) comprend un matériau fibreux, un matériau de remplissage et
un ou plusieurs additifs de combustion, et une pluralité de régions de suppression
de combustion (122, 211) qui sont fournies séparément les unes des autres,
le rapport de la capacité de diffusion entre les régions de suppression de combustion
(122, 211) et le papier de base (121) se situe dans la plage allant de 5 % à 35 %,
caractérisée en ce que
une porosité de papier du papier de base (121) va de 40 à 50 UC, la quantité totale
d'additif de combustion représente une quantité allant de 0,4 à 0,6 % en poids en
fonction du poids sec du papier de base (121), et la quantité de remplissage dans
le papier de base (121) va de 17 à 23 % en poids en fonction du poids sec du papier
de base (121).
2. Cape (12, 21) selon la revendication 1, dans laquelle la capacité de diffusion des
régions de suppression de combustion (122, 211) va de 0,10 à 0,35 cm/s.
3. Cape (12, 21) selon les revendications 1 ou 2, dans laquelle la capacité de diffusion
du papier de base (121) va de 1,0 à 2,0 cm/s.
4. Cape (12, 21) selon l'une quelconque des revendications précédentes 1-3, dans laquelle
les régions de suppression de combustion (122, 211) sont fournies sur une surface
du papier de base (121).
5. Cape (12, 21) selon l'une quelconque des revendications précédentes 1-4, dans laquelle
les régions de suppression de combustion (122, 211) sont fournies de manière à être
intégrées dans une matrice du papier de base.
6. Cape (12, 21) selon l'une quelconque des revendications précédentes 1-5, dans laquelle
les régions de suppression de combustion (122, 211) contiennent au moins un additif
permettant de diminuer la capacité de diffusion du papier de base (121), et dans laquelle
lesdits additifs sont choisis parmi le groupe consistant en alginates, polyalcool
de vinyle, acétates de polyvinyle, amidons modifiés et non modifiés, dérivés de cellulose,
ions inorganiques, gommes naturelles ou des mélanges de ceux-ci.
7. Cape (12, 21) selon l'une quelconque des revendications précédentes 1-6, dans laquelle
les régions de suppression de combustion (122, 211) se présentent sous la forme de
bandes.
8. Cape (12, 21) selon l'une quelconque des revendications précédentes 1-7, dans laquelle
une porosité de papier du papier de base (121) est de 45 UC et une quantité totale
d'additif de combustion est de 0,5 % en poids en fonction du poids sec du papier de
base (121) et la quantité de remplissage dans le papier de base (121) est de 20 %
en poids en fonction du poids sec du papier de base (121).
9. Cape (12, 21) selon l'une quelconque des revendications précédentes 1-8, dans laquelle
l'additif de combustion est choisi parmi le groupe consistant en sels de citrate,
sels d'acétate, sels de phosphate, sels de tartrate, sels de nitrate ou des mélanges
de ceux-ci.
10. Cape (12, 21) selon l'une quelconque des revendications précédentes 1-9, dans laquelle
le poids de base du papier de base (121) va de 20 à 26 g/m2.
11. Cape (12, 21) selon l'une quelconque des revendications précédentes 1-10, dans laquelle
le matériau de remplissage est choisi parmi le groupe consistant en carbonate de calcium,
argile kaolinique, talc, dioxyde de titane, trihydrate d'alumine et silices précipitées
et silicates (SSP), ou des mélanges de ceux-ci.
12. Cape (12, 21) selon l'une quelconque des revendications précédentes 1-11, dans laquelle
le matériau fibreux est un matériau fibreux cellulosique.
13. Article à fumer (10, 20), comprenant une charge de matériau pouvant être fumé entouré
d'une cape (12, 21) selon l'une quelconque des revendications précédentes 1-12.