FIELD OF THE INVENTION
[0001] Consumer product comprising a container and at least one water-soluble unit dose
article.
BACKGROUND OF THE INVENTION
[0002] Water-soluble unit dose articles are liked by consumers due to their convenience
and ease of use. Without wishing to be bound by theory, water-soluble unit dose articles
comprise a water-soluble film shaped to form at least one internal compartment which
houses a single use dose of a detergent. Upon addition of the water-soluble unit dose
article to water, the water-soluble film dissolves and/or disintegrates releasing
the detergent into the surrounding water to produce a wash liquor.
[0003] Such water-soluble unit dose articles are stored and transported in rigid or flexible
plastic containers. Without wishing to be bound by theory, consumers purchase containers
comprising a plurality of water-soluble unit dose articles. The containers are shipped
from the place of manufacture to supermarkets and once purchased are stored in consumers'
homes.
[0004] The detergent composition enclosed in the water-soluble unit dose article typically
comprises a perfume. An issue is during transport and storage perfume will partially
migrate from the detergent composition through the water-soluble film and start building
up in the headspace of the container. Some consumers, however, do not like strong
perfumes applied to their clothes, e.g. they desire minimum perfume application, purely
as a sign that their clothes are clean and refreshed but do not want to experience
an "overwhelming" perfume. To them, a strong perfume headspace build up in the tub
is undesired as it is perceived as a signal that during washing also a strong perfume
will be applied to their clothes. Even when formulating a "light" perfume targeting
this consumer segment the perfume build-up in the headspace experience is still to
be improved.
[0005] A possible solution could be for the consumer to store the containers in an open
position such that a perfume headspace cannot build up. This is undesired however,
as it will increase the sensitivity of the water-soluble unit dose article to external
humidity conditions as well as the risk of accidently contaminating the water-soluble
unit dose articles. More importantly, while keeping the container open would reduce
the risk of strong perfume build up in the storing container, this approach will not
provide the consumer a reassuring signal that the detergent composition is not comprising
a strong perfume. He/she will not know as there would not be a perfumed headspace
based on which the consumer can judge whether the formulated perfume would match his/her
need. Therefore, the consumer prefers such containers comprise latches to ensure they
remain closed until intentionally opened, such that a perfume headspace can build-up
and the consumer is able to judge the strength of the perfume based on the perfume
build-up in the headspace.
[0006] Therefore, there is a need for a consumer product comprising a water-soluble unit
dose article comprising a perfumed detergent composition in which strong perfume build-up
in the headspace while stored in a closed position is avoided.
[0007] It was surprisingly found that a consumer product according to the present invention
overcomes the above problem.
SUMMARY OF THE INVENTION
[0008] A consumer product comprising at least one water-soluble unit dose article and a
container; wherein the at least one water-soluble unit dose article comprises at least
one water-soluble film orientated to create at least one unit dose internal compartment,
wherein the at least one unit dose internal compartment comprises a detergent composition;
and wherein the container comprises a first part, wherein the first part comprises
a first compartment in which the at least one water-soluble unit dose article is contained,
and wherein the first compartment is accessible through a first opening; and wherein
the container comprises a second part, wherein the second part is positioned so that
it prevents access through the first opening when the container is not in use, but
is moveable to allow access to the first opening when the container is in use; and
wherein the container comprises a locking means wherein the locking means comprises
a first locking component on the first part and a second locking component on the
second part, wherein the first locking component engages the second locking component
to prevent movement of the second part to allow access to the first opening until
the first locking component and second locking component are disengaged from one another
by a user; and wherein the first part comprises an interior surface and an exterior
surface, wherein the interior surface faces the internal compartment; and wherein
at least part of the interior surface of the first part is constructed from paper-based
material so that the water-soluble film of the at least one unit dose article directly
contacts the paper-based material of the internal surface; and wherein the detergent
composition comprises a free perfume composition.
BRIEF DESCRIPTION OF THE DRAWINGS
[0009]
FIG. 1 depicts a consumer product (1) comprising at least one water-soluble unit dose
article (not shown) and a container (2) according to the present invention.
FIGS. 2A, 2B and 2C depict a cross sectional view of the container (2) of FIG. 1
FIG.3 depicts a consumer product (1) as according to FIG.1 but wherein the second
part (4) is connected to the first part (3) via a hinge (21).
FIG. 4 depicts an alternative example according to the present invention.
FIG.5 depicts the container according to FIG.4 in an open position.
FIG. 6 depicts the first part (3) of FIGs 4 and 5 completely removed from the second
part (4).
FIG.7 depicts a first part (3) according to FIG. 5 but having a larger first opening
(6).
FIG. 8 depicts a top cross-sectional view of the second part (4) according to FIG.4.
FIG. 9 depicts a 3D representation of the second part (4) according to FIG. 4
FIGS. 10A and B depict a cross-sectional view of the consumer product (1) according
to FIG. 4.
FIG. 11 depicts a consumer product (1) as according to FIGS. 4-9, 10A and 10B but
wherein the second locking component (8) is in a different location.
FIG. 12 discloses a water-soluble unit dose article according to the present invention.
DETAILED DESCRIPTION OF THE INVENTION
Consumer Product
[0010] The present invention is to a consumer product comprising at least one water-soluble
unit dose article and a container. The water-soluble unit dose article and the container
are described in more detail below.
[0011] The consumer product can be sold 'as is', in other words the consumer product is
the item that the consumer picks up from the shelf. Alternatively, the consumer product
could be housed as one unit of a multi-component product. For example, more than one
consumer product could be housed within an outer package and the multiple packaged
consumer products sold together in a single purchase.
[0012] The consumer product may comprise aesthetic elements, for example shrink sleeves
or labels attached to the container. Alternatively, the container may be coloured
or printed with aesthetic elements or informative print such as usage instructions.
Water-soluble unit dose article
[0013] The at least one water-soluble unit dose article comprises at least one water-soluble
film orientated to create at least one unit dose internal compartment, wherein the
at least one unit dose internal compartment comprises a detergent composition. The
water-soluble film and the detergent composition are described in more detail below.
[0014] The consumer product comprises at least one water-soluble unit dose article, preferably
at least two water-soluble unit dose articles.
[0015] A water-soluble unit dose article is generally in the form of a pouch. It comprises
a unitary dose of a composition as a volume sufficient to provide a benefit in an
end application.
[0016] The water-soluble unit dose article comprises at least one water-soluble film shaped
such that the unit-dose article comprises at least one internal compartment surrounded
by the water-soluble film. The at least one compartment comprises a cleaning composition.
The water-soluble film is sealed such that the cleaning composition does not leak
out of the compartment during storage. However, upon addition of the water-soluble
unit dose article to water, the water-soluble film dissolves and releases the contents
of the internal compartment into the wash liquor.
[0017] The unit dose article may comprise more than one compartment, even at least two compartments,
or even at least three compartments, or even at least four compartments, or even at
least five compartments. The compartments may be arranged in superposed orientation,
i.e. one positioned on top of the other. Alternatively, the compartments may be positioned
in a side-by-side orientation, i.e. one orientated next to the other. The compartments
may even be orientated in a 'tyre and rim' arrangement, i.e. a first compartment is
positioned next to a second compartment, but the first compartment at least partially
surrounds the second compartment, but does not completely enclose the second compartment.
Alternatively, one compartment may be completely enclosed within another compartment.
[0018] Wherein the unit dose article comprises at least two compartments, one of the compartments
may be smaller than the other compartment. Wherein the unit dose article comprises
at least three compartments, two of the compartments may be smaller than the third
compartment, and preferably the smaller compartments are superposed on the larger
compartment. The superposed compartments preferably are orientated side-by-side.
[0019] Each individual unit dose article may have a weight of between 10g and 40g, or even
between 15g and 35g.
[0020] The film of the present invention is soluble or dispersible in water. Prior to be
being formed into a unit dose article, the water-soluble film preferably has a thickness
of from 20 to 150 micron, preferably 35 to 125 micron, even more preferably 50 to
110 micron, most preferably about 76 micron.
[0021] Preferred film materials are preferably polymeric materials. The film material can,
for example, be obtained by casting, blow-moulding, extrusion or blown extrusion of
the polymeric material, as known in the art.
[0022] Preferably, the water-soluble film comprises polyvinyl alcohol polymer or copolymer,
preferably a blend of polyvinylalcohol polymers and/or polyvinylalcohol copolymers,
preferably selected from sulphonated and carboxylated anionic polyvinylalcohol copolymers
especially carboxylated anionic polyvinylalcohol copolymers, most preferably a blend
of a polyvinylalcohol homopolymer and a carboxylated anionic polyvinylalcohol copolymer.
[0023] Preferably, the water-soluble film comprises a polymer wherein the polymer comprises
a homopolymer, copolymer, or mixture thereof selected from polyvinyl alcohols, polyvinyl
pyrrolidone, polyalkylene oxides, acrylamide, acrylic acid, cellulose, cellulose ethers,
cellulose esters, cellulose amides, polyvinyl acetates, polycarboxylic acids and salts,
polyaminoacids or peptides, polyamides, polyacrylamide, copolymers of maleic/acrylic
acids, polysaccharides including starch and gelatine, xanthum, carragum or a mixture
thereof, preferably, polyvinylalcohol homopolymers and/or anionic polyvinylalcohol
copolymers preferably selected from sulphonated and carboxylated anionic polyvinylalcohol
copolymers especially carboxylated anionic polyvinylalcohol copolymers.
[0024] Preferred films are those supplied by Monosol under the trade references M8630, M8900,
M8779, M8310.
[0025] The film may be opaque, transparent or translucent. The film may comprise a printed
area.
[0026] The area of print may be achieved using standard techniques, such as flexographic
printing or inkjet printing.
[0027] The film may comprise an aversive agent, for example a bittering agent. Suitable
bittering agents include, but are not limited to, naringin, sucrose octaacetate, quinine
hydrochloride, denatonium benzoate, or mixtures thereof. Any suitable level of aversive
agent may be used in the film. Suitable levels include, but are not limited to, 1
to 5000ppm, or even 100 to 2500ppm, or even 250 to 2000ppm.
[0028] The water-soluble film or water-soluble unit dose article or both may be coated with
a lubricating agent. Preferably, the lubricating agent is selected from talc, zinc
oxide, silicas, siloxanes, zeolites, silicic acid, alumina, sodium sulphate, potassium
sulphate, calcium carbonate, magnesium carbonate, sodium citrate, sodium tripolyphosphate,
potassium citrate, potassium tripolyphosphate, calcium stearate, zinc stearate, magnesium
stearate, starch, modified starches, clay, kaolin, gypsum, cyclodextrins or mixtures
thereof.
Container
[0029] The consumer product comprises a container. The container comprises a first part,
wherein the first part comprises a first compartment in which the at least one water-soluble
unit dose article is contained. Preferably the first compartment comprises at least
two water-soluble unit dose articles. The first compartment may comprise between 1
and 80 water-soluble unit dose articles, or even between 1 and 60 water-soluble unit
dose articles, or even between 1 and 40 water-soluble unit dose articles, or even
between 1 and 20 water-soluble unit dose articles. The volume of the first compartment
may be between 500ml and 5000ml, preferably between 800ml and 4000ml.
[0030] The first compartment is accessible through a first opening. Those skilled in the
art will be aware of a suitable size for the first opening. Without wishing to be
bound by theory, the first opening should be of sufficient size to retrieve at least
a single water-soluble unit dose article at a time. Alternatively, the first opening
may be shaped to allow the unit dose articles to be poured out from the container.
Therefore, it should be dimensioned to be big enough for at least a single unit dose
article to fit through the first opening. Preferably, the first opening should be
big enough for a user to fit their hand through to retrieve at least one water-soluble
unit dose article.
[0031] The container comprises a second part, wherein the second part is positioned so that
it prevents access through the first opening when the container is not in use, but
is moveable to allow access to the first opening when the container is in use. Without
wishing to be bound by theory, the first part and the second part are able to move
relative to one another. This relative movement allows the second part to block entry
to the first opening when not in use, but then allow access to the first opening when
in use. Without wishing to be bound by theory, the user controls the movement of the
first and second parts relative to one another to achieve this.
[0032] The movement of the first part and the second part relative to one another can be
achieved via any suitable means. Those skilled in the art will be aware of suitable
means. The first part may slide within the second part. Alternatively, the second
part may act as a lid to the first part. The lid may be hinged to the first part or
may be completely separated from the first part. Preferably, the second part comprises
a top wall and at least one side wall, and the first part comprises a base wall and
the first opening, wherein the first opening is opposite to the base wall and the
base wall and the first opening are connected by at least one side wall. In the closed
position the at least one side wall of the second part overlaps at least partially
within the one side wall of the first part. In other words, the second part acts as
a hood positioning over the first part and so blocking access to the first opening.
Alternatively, in the closed position the at least one side wall of the first part
overlaps at least partially within the one side wall of the second part, in other
words, the second part slots inside the first opening blocking access to the first
opening.
[0033] The container further comprises a locking means. The locking means comprises a first
locking component on the first part and a second locking component on the second part.
The first locking component engages the second locking component to prevent sufficient
movement of the second part relative to the first part to allow access to the first
opening, until the first locking component and second locking component are disengaged
from one another by a user. Those skilled in the art will be aware of suitable locking
means to achieve this. A preferred locking means is where the first locking component
comprises a tab and the second locking component comprises an abutment against which
the tab abuts when in the closed position. The abutment may simply comprise a surface
against which the tab abuts. Alternatively, the abutment comprises a slot or pocket
capable of receiving the tab when in the locked position. Preferably, the first locking
component is a tab that protrudes from the exterior surface of the first part and
the second part comprises an abutment against which the first locking tab is able
to releasably engage.
[0034] The container may comprise more than one locking means. The container may comprise
two locking means. The locking means may be orientated to be opposite one another
on the container, such that the consumer can hold the container and using a thumb
and a finger to open both locking means simultaneously. Preferably, wherein the locking
means are opposite to one another the container is of an appropriate dimension to
allow the user, especially an adult user, to grip the container with one hand and
simultaneously open both locking means using the thumb and finger of the other hand.
When the container comprises at least two locking means, preferably the two locking
means are spaced apart by a distance of between 70mm and 150mm, more preferably between
80mm and 120mm. Without wishing to be bound by theory such distance allows for the
adult human handspan to ergonomically fit around the container to allow simultaneous
disengagement of the two locking means.
[0035] Preferably both locking means comprise a first locking component on the first part
and a second locking component on the second part. Preferably the first locking means
and second locking means both comprise tabs on the first part and abutments on the
second part.
[0036] The first part comprises an interior surface and an exterior surface, wherein the
interior surface faces the internal compartment. At least part of the interior surface
of the first part is constructed from paper-based material so that the water-soluble
film of the at least one unit dose article directly contacts the paper-based material
of the internal surface. In other words, at least one water-soluble unit dose article
housed within the container will be in direct contact with the paper-based material.
During storage and transport, the water-soluble unit dose article may move within
the container, however, there is no impendent between the water-soluble unit dose
article and the paper-based material, except for other water-soluble unit dose articles.
[0037] By paper-based material, we herein mean a material comprising paper. Without wishing
to be bound by theory, by 'paper' we herein mean a material made from a cellulose-based
pulp. Preferably, the paper-based material comprises paper, cardboard, or a mixture
thereof, wherein preferably, cardboard comprises paper-board, corrugated fibre-board,
or a mixture thereof. The paper-based material may comprise a printed image thereon.
[0038] Preferably, the entire interior surface of the first part is constructed from a paper-based
material, more preferably, the whole of the first part is constructed from a paper-based
material.
[0039] Preferably, the second part comprises an interior surface and an exterior surface.
Preferably, at least part of the interior surface of the second part is constructed
from a paper-based material, preferably the entire interior surface of the second
part is constructed from a paper-based material, even more preferably, the entire
second part is constructed from a paper-based material.
[0040] Preferably, the first locking component is constructed from a paper-based material
or the second locking component is constructed a paper-based material or a combination
thereof.
[0041] The paper-based material may be a laminate comprising paper, cardboard, or a mixture
thereof, wherein preferably, cardboard comprises paper-board, corrugated fibre-board,
or a mixture thereof, and at least a second material. Wherein the paper-based material
is a laminate, then the internal surface of the first part and preferably the internal
surface of the second part comprises paper, cardboard, or a mixture thereof, wherein
preferably, cardboard comprises paper-board, corrugated fibre-board, or a mixture
thereof, and preferably the external surface of the first part, external surface of
the second part or a mixture thereof comprises the second material. Alternatively,
the second material might also be laminated in-between two paper-based material layers.
Without wishing to be bound by theory this second material might act as a barrier
for any leaked liquid absorbed by the paper-based material facing the interior side
of the container, to flow through the container wall and contaminating the outer wall
of the container. Contamination of the outer wall of the container might be unsightly
to consumers or worse case further contaminate the storage area. It was surprisingly
found that despite lamination with the second material acting as a barrier for leaked
liquid absorbed by the paper-based material, there was still a perfume headspace build-up
avoidance relative to pure plastic-based containers.
[0042] The first locking component may be a tab made from corrugated fibre-board. Without
wishing to be bound by theory, corrugated fibre-board comprises a series of flutes.
Each flute can be understood to be a channel. The flutes run parallel to one another,
with the flute direction being the direction travelled along each channel. Preferably,
the tab comprises a fold which runs perpendicular to the flute direction. Such folding
of the tab results in the tab being capable of returning to its original position,
in other words having a memory property to allow it to spring back. This is preferably
so that it can re-engage efficiently with the second locking component on subsequent
use.
[0043] Alternatively, the first locking component may be a tab made from paper-board. Without
wishing to be bound by theory, paper-board comprises fibres running in the fibre direction,
wherein the fibre direction should be understood to be the direction along the longest
dimension of the fibres. Preferably, the tab comprises a fold which runs perpendicular
to the fibre direction. Such folding of the tab results in the tab being capable of
returning to its original position, in other words having a memory property to allow
it to spring back. This is preferably so that it can re-engage efficiently with the
second locking component on subsequent use.
[0044] Those skilled in the art will be aware of suitable second materials. Preferably,
the second material comprises a plastic material. Preferably, the plastic material
comprises polyethylene, polyethylene terephthalate, polypropylene, polyvinylalcohol
or a mixture thereof. The barrier material may be a biaxially orientated polypropylene,
a metallised polyethylene terephthalate or a mixture thereof. Alternatively, the second
material may be a wax, a cellulose material, polyvinylalcohol, or a mixture thereof.
[0045] Preferably, the paper-based laminate comprises greater than 50%, preferably greater
than 85%, and more preferably greater than 95% by weight of the laminate of fibre-based
materials. Preferably, the plastic material has a thickness of between 10 micron and
40 micron, more preferably between 10 micron and 35 micron.
[0046] Preferably, the second part is a sleeve that receives the first part therein and
the first part is able to slide within the second part between an open position in
which the first opening is accessible and wherein the first locking component and
second locking component are disengaged from one another in a closed position in which
the second part blocks access to the first opening when the first locking component
and the second locking component are engaged.
[0047] Alternatively, preferably, the first part comprises a base wall and the first opening,
wherein the first opening is opposite to the base wall and the base wall and the first
opening are connected by at least one side wall, and the second part comprises a second
opening and at least one connecting wall, wherein the first part slides within the
second part via the second opening and the connecting wall blocks the first opening
when in the closed position. In this preferred option, the at least one side wall
of the first part comprises the first locking component and the at least one connecting
wall of the second part comprises the second locking component. Preferably, the second
part comprises an end wall opposite to the second opening and the second opening and
the end wall are connected via the at least one connecting wall.
[0048] The connecting wall has an inside surface and an exterior surface. The inside surface
faces the first part and the exterior surface faces the exterior environment to the
container.
[0049] The second locking component may be an abutment formed by cutting a portion of the
connecting wall and folding said portion back upon itself and then adhering said folded
back portion to the inside surface of the connecting wall to create the abutment.
The cut portion of the connecting wall forms the opening of the second locking component.
Alternatively, wherein the second locking component is an abutment, it may be formed
by adhering a separate piece of material, preferably wherein the separate piece of
material is selected from paper, cardboard, or a mixture thereof, to the inside surface
of the connecting wall.
[0050] The container may comprise stopper means to prevent the first part from being completely
removed from the second part. Such stopper means may comprise a stopper abutment on
the second part which interacts with the first locking component, preferably wherein
the first locking component is a tab, preventing further movement of the first part
when being slid out of the second part during use. Without wishing to be bound by
theory, when the first locking component is disengaged from the second locking component,
the first part and second part can be moved relative to one another. During movement,
the first locking component then abuts against the stopper abutment preventing any
further movement. Alternatively, the stopper means may comprise a stopper tab, separate
to the first locking component, that abuts against the second locking means. In this
instance, without wishing to be bound by theory, after disengagement of the first
locking component and the second locking component, the first part and second part
can be moved relative to one another, and the stopper tab abuts against the second
locking means preventing any further movement.
[0051] The stopper means may be formed by folding back the end of the connecting wall and
adhering the folded back part to the inside surface of the connecting wall. The end
of the connecting wall should be understood to mean the edge of the connecting wall
forming the second opening. Alternatively, the stopper means may be formed by adhering
a separate piece of material, preferably wherein the separate piece of material is
selected from paper, cardboard, or a mixture thereof, to the inside surface of the
connecting wall.
[0052] Alternatively, the second part is a removable lid, wherein the second part in a closed
position blocks access to the first opening and when in a closed position the first
locking component is engaged with the second locking component, and when in an open
position the first locking component and second locking component are disengaged and
the second part is removable to allow access to the first opening. Preferably, the
second part is attached to the first part via a hinge or the second part can be completely
removed from the first part. Preferably, the second part can be completely removed
from the first part.
[0053] Preferably, the second part comprises a top wall and at least one side wall, and
the first part comprises a base wall and the first opening, wherein the first opening
is opposite to the base wall and the base wall and the first opening are connected
by at least one side wall. In the closed position the at least one side wall of the
second part overlaps at least partially within the one side wall of the first part.
In this preferred example, the first locking component is positioned on the at least
one side wall of the first part and second locking component is positioned on the
at least one side wall of the second part.
[0054] The at least one side wall of the second part has an inside surface and an exterior
surface. The inside surface faces the first part and the exterior surface faces the
exterior environment to the container. Alternatively, in a less preferred option,
in the closed position the at least one side wall of the first part overlaps at least
partially within the one side wall of the second part.
[0055] The second locking component may be an abutment formed by cutting a portion of the
at least one side wall of the second part and folding said portion back upon itself
and then adhering said folded back portion to the inside surface of the at least one
side wall of the second part to create the abutment. The cut portion of the at least
one side wall of the second part forms the opening of the second locking component.
Alternatively, wherein the second locking component is an abutment, it may be formed
by adhering a separate piece of material, preferably wherein the separate piece of
material is selected from paper, cardboard, or a mixture thereof, to the inside surface
of the at least one side wall of the second part. Alternatively, wherein the second
locking component is an abutment, the second locking component may be formed by folding
the end of the at least one wall of the second part back upon itself and then adhering
the folded portion to the inside surface of the at least one wall of the second part.
Detergent Composition
[0056] The detergent composition may be a laundry detergent composition, an automatic dishwashing
composition, a hard surface cleaning composition, or a combination thereof. The detergent
composition is a perfumed detergent composition. By 'perfumed detergent composition'
we mean that free perfume has been added to the detergent composition. By 'free perfume'
we herein mean perfume compounds are added directly to the detergent composition and
are not present on encapsulates or on carrier materials. The composition might also
comprise secondary perfume sources such as perfume capsule and/or pro-perfume e.g.
perfume bound to a carrier material technology. The detergent composition may comprise
a solid, a liquid or a mixture thereof. The term liquid includes a gel, a solution,
a dispersion, a paste, or a mixture thereof.
[0057] The solid may be a powder. By powder we herein mean the detergent composition may
comprise solid particulates or may be a single homogenous solid. Preferably, the powder
detergent composition comprises particles. This means the powder detergent composition
comprises individual solid particles as opposed to the solid being a single homogenous
solid. The particles may be free-flowing or may be compacted, preferably free-flowing.
[0058] Preferably, the detergent composition is a laundry detergent composition, most preferably
a liquid laundry detergent composition.
[0059] The laundry detergent composition can be used in a fabric hand wash operation or
may be used in an automatic machine fabric wash operation, preferably an automatic
machine fabric wash operation.
[0060] The laundry detergent composition comprises a non-soap surfactant, wherein the non-soap
surfactant comprises an anionic non-soap surfactant and a non-ionic surfactant. Preferably,
the laundry detergent composition comprises between 10% and 60%, more preferably between
20% and 55% by weight of the laundry detergent composition of the non-soap surfactant.
[0061] The weight ratio of non-soap anionic surfactant to nonionic surfactant is from 1:1
to 20:1, preferably from 3:1 to 17.5:1, more preferably from 5:1 to 15:1, most preferably
from 7.5:1 to 12.5:1.
[0062] The non-soap anionic surfactant comprises linear alkylbenzene sulphonate, alkyl sulphate
or a mixture thereof. The weight ratio of linear alkylbenzene sulphonate to alkyl
sulphate is from 1:2 to 9:1, preferably from 1:1 to 7:1, more preferably from 1.25:1
to 5:1, most preferably from 1.4:1 to 3:1.
[0063] Exemplary linear alkylbenzene sulphonates are C
10-C
16 alkyl benzene sulfonic acids, or C
11-C
14 alkyl benzene sulfonic acids. By 'linear', we herein mean the alkyl group is linear.
Alkyl benzene sulfonates are well known in the art.
[0064] The alkyl sulphate anionic surfactant may comprise alkoxylated alkyl sulphate or
non-alkoxylated alkyl sulphate or a mixture thereof. The alkoxylated alkyl sulphate
anionic surfactant preferably is an ethoxylated alkyl sulphate anionic surfactant.
[0065] The alkyl sulphate anionic surfactant may comprise an ethoxylated alkyl sulphate
anionic surfactant, preferably with a mol average degree of ethoxylation from 1 to
5, more preferably from 1 to 3, most preferably from 2 to 3.
[0066] The alkyl sulphate anionic surfactant may comprise a non-ethoxylated alkyl sulphate
and an ethoxylated alkyl sulphate wherein the mol average degree of ethoxylation of
the alkyl sulphate anionic surfactant is from 1 to 5, more preferably from 1 to 3,
most preferably from 2 to 3.
[0067] The alkyl fraction of the alkyl sulphate anionic surfactant can preferably be derived
from fatty alcohols, oxo-synthesized alcohols, guerbet alcohols, or mixtures thereof.
[0068] Preferably, the laundry detergent composition comprises between 10% and 50%, more
preferably between 15% and 45%, even more preferably between 20% and 40%, most preferably
between 30% and 40% by weight of the laundry detergent composition of the non-soap
anionic surfactant.
[0069] Preferably, the non-ionic surfactant is selected from alcohol alkoxylate, an oxo-synthesised
alcohol alkoxylate, Guerbet alcohol alkoxylates, alkyl phenol alcohol alkoxylates,
or a mixture thereof.
[0070] The laundry detergent composition comprises between 0.01% and 10%, preferably between
0.01% and 8%, more preferably between 0.1% and 6%, most preferably between 0.15% and
5% by weight of the liquid laundry detergent composition of a non-ionic surfactant.
[0071] Preferably, the laundry detergent composition comprises between 1.5% and 20%, more
preferably between 2% and 15%, even more preferably between 3% and 10%, most preferably
between 4% and 8% by weight of the laundry detergent composition of soap, preferably
a fatty acid salt, more preferably an amine neutralized fatty acid salt, wherein preferably
the amine is an alkanolamine more preferably selected from monoethanolamine, diethanolamine,
triethanolamine or a mixture thereof, more preferably monoethanolamine.
[0072] Preferably, the laundry detergent composition is a liquid laundry detergent composition,
more preferably the liquid laundry detergent composition comprises less than 15%,
more preferably less than 12% by weight of the liquid laundry detergent composition
of water.
[0073] Preferably, the laundry detergent composition is a liquid laundry detergent composition
comprising a non-aqueous solvent selected from 1,2-propanediol, dipropylene glycol,
tripropyleneglycol, glycerol, sorbitol, polyethylene glycol or a mixture thereof.
Preferably, the liquid laundry detergent composition comprises between 10% and 40%,
preferably between 15% and 30% by weight of the liquid laundry detergent composition
of the non-aqueous solvent.
[0074] The laundry detergent composition comprises a perfume, more specifically a free perfume.
Those skilled in the art will know of possible free perfumes to be formulated inside
a liquid laundry detergent composition to be formulated inside a water soluble unit
dose article. These free perfume compositions are composed of a broad range of individual
perfume raw materials which are carefully balanced to create a desired perfumed character,
perfume deposition and perfume longevity profile, and this across the different stages
of the wash and wear process, e.g. upon dosing of the detergent composition, upon
removal of the wet fabrics from the laundry washing machine or upon hand-washing,
upon line-drying or at the end of tumble drying process, upon storage of the fabrics
in consumers' wardrobe and upon wearing the fabrics. This balanced selection of individual
perfume materials typically considers, in addition to the perfume character of an
individual raw material, also its polarity, volatility and perceived intensity. The
detergent composition preferably comprises between 0.01 and 10%, preferably between
0.1% and 5%, more preferably between 0.5% and 3% of free perfume. In addition to free
perfume also a secondary source of perfume can be present, more particularly the detergent
composition might also comprise encapsulated perfumes or pro-perfume technologies,
or a mixture thereof. Preferably, the laundry detergent composition comprises an adjunct
ingredient selected from the group comprising builders including enzymes, citrate,
bleach, bleach catalyst, dye, hueing dye, brightener, cleaning polymers including
alkoxylated polyamines and polyethyleneimines, soil release polymer, surfactant, solvent,
dye transfer inhibitors, chelant, encapsulated perfume, polycarboxylates, structurant,
pH trimming agents, and mixtures thereof.
[0075] Preferably, the laundry detergent composition has a pH between 6 and 10, more preferably
between 6.5 and 8.9, most preferably between 7 and 8, wherein the pH of the laundry
detergent composition is measured as a 10% product concentration in demineralized
water at 20°C.
[0076] When liquid, the laundry detergent composition may be Newtonian or non-Newtonian.
Preferably, the liquid laundry detergent composition is non-Newtonian. Without wishing
to be bound by theory, a non-Newtonian liquid has properties that differ from those
of a Newtonian liquid, more specifically, the viscosity of non-Newtonian liquids is
dependent on shear rate, while a Newtonian liquid has a constant viscosity independent
of the applied shear rate. The decreased viscosity upon shear application for non-Newtonian
liquids is thought to further facilitate liquid detergent dissolution. The liquid
laundry detergent composition described herein can have any suitable viscosity depending
on factors such as formulated ingredients and purpose of the composition.
[0077] Those skilled in the art will know how to formulate and make a suitable detergent
composition using known knowledge and techniques.
Manufacture
[0078] Those skilled in the art will be aware of standard techniques and methods to make
the consumer product according to the present invention. Those skilled in the art
will be aware of methods to make the at least one water-soluble unit dose article.
Those skilled in the art will be aware of standard methods to make the container.
Preferably, the first part is constructed from a first blank and the second part is
constructed from a second blank.
[0079] The dimensions and values disclosed herein are not to be understood as being strictly
limited to the exact numerical values recited. Instead, unless otherwise specified,
each such dimension is intended to mean both the recited value and a functionally
equivalent range surrounding that value. For example, a dimension disclosed as "40
mm" is intended to mean "about 40 mm."
EXAMPLES
[0080] The following are non-limiting examples according to the present invention.
FIG. 1 depicts a consumer product (1) comprising at least one water-soluble unit dose
article (not shown) and a container (2). The container (2) comprises a first part
(3) and a second part (4). The second part (4) in this example is a removable lid.
In FIG.1 the container (2) is shown in the open position. The first part (3) comprises
a first compartment (5) in which the at least one water-soluble unit dose article
is contained (not shown), and wherein the first compartment (5) is accessible through
a first opening (6). The first part (3) comprises a first locking component (7) and
the second part (4) comprises a second locking component (8). In FIG. 1 the first
locking component (7) is a tab made from paper-board, corrugated fibre-board or a
mixture thereof. The second locking component (8) comprises an abutment (10) depicted
by dotted lines and arranged on the inside surface of the at least one wall (9) of
the second part (4). The abutment (10) is created by folding back the end of the at
least one side wall (9) and adhering the folded back portion to the inside surface
of the at least one wall (9). The second locking component (8) also comprises an opening
(11) to allow the user access to disengage the first locking component (7) from the
second locking component (8). The first part (3) comprises an interior surface (12)
and an exterior surface (13). At least a part of the interior surface (12) is constructed
from paper-based material. The container (2) in this example comprises two first locking
components (7), on opposite sides of the first part (3) and two corresponding second
locking components (8) on opposite sides of the second part (4).
FIGS. 2A, 2B and 2C depict a cross sectional view of the container (2) of FIG. 1 In
FIG. 2A the first locking component (7) is engaged with the abutment (10) of the second
locking component (8). The abutment (10) is formed by folding the bottom edge of the
first wall (9) back over itself and adhering the folded back portion to the inside
surface of the at least first wall of the second part (9). In FIG. 2A the user disengages
the first locking component (7) from the abutment (10) via application of force (14)
through the opening (11). As shown in FIG. 2B, the application of force (14) displaces
the first locking component (7), allowing the user to move the second part (4) away
(15) from the first part (3) as shown in FIG. 2C.
FIG.3 depicts a consumer product (1) as according to FIG.1 but wherein the second
part (4) is connected to the first part (3) via a hinge (21).
FIG. 4 depicts an alternative example according to the present invention. Depicted
is a consumer product (1) comprising a container (2) and at least one water-soluble
unit dose article (not shown). The container comprises a first part (3) and a second
part (4). Also shown is an opening (11) for the user to disengage the first locking
component (not shown) from the second locking component (not shown). The container
further comprises a cut-out (16) to allow easy gripping of the first part (3) when
sliding out of the second part (4).
FIG.5 depicts the container according to FIG.4 in an open position. Here the first
part (3) has been slid out of the second part (4). The first part (3) comprises a
first compartment (5) in which the at least one water-soluble unit dose article is
contained (not shown), and wherein the first compartment (5) is accessible through
a first opening (6). The first part (3) comprises an interior surface (12) and an
exterior surface (13). At least a part of the interior surface (12) is constructed
from paper-based material.
FIG. 6 depicts the first part (3) of FIGs 4 and 5 completely removed from the second
part (4). As can be seen in FIG. 6 the first part comprises two first locking components
(7), one either side. In FIG. 5 the first locking component (7) is a tab made from
paper-board, corrugated fibre-board or a mixture thereof. The first part (3) further
comprises a stopper means (17) at the top and the bottom to prevent the first part
(3) sliding completely out of the second part (4).
FIG.7 depicts a first part (3) according to FIG. 5 but having a larger first opening
(6).
FIG.8 depicts a top cross-sectional view of the second part (4) according to FIG.4.
The second part (4) comprises an opening (20) through which the first part (3) can
slide. Further depicted are abutments (10) into which the first locking component
(7) engages when in a locked position. The abutments (10) are formed by cutting a
portion of the connecting wall (18) and folding said portion back upon itself and
then adhering said folded back portion to the inside surface of the connecting wall
(18) to create the abutment (10). Also shown is are stopper means abutment (19) formed
by folding the end of the connecting wall (18) over onto itself and adhering the folded
over portion to the inside surface of the connecting wall (19).
FIG. 9 depicts a 3D representation of the second part (4) according to FIG. 4. Shown
are four connecting walls (21, 22, 23, 24). The stopper means abutments (19) are formed
by folding over the ends of each of the four connecting walls back on themselves and
adhering the folded portions to the inside surface of the respective connecting wall
(21, 22, 23, 24).
FIG 10A and FIGB depict a cross-sectional view of the consumer product (1) according
to FIG. 4. In FIG. 10A the first locking component (7) is engaged with the abutment
(10). The abutment (10) is formed by cutting a portion of the connecting wall (18)
and folding said portion back upon itself and then adhering said folded back portion
to the inside surface of the connecting wall (18) to create the abutment. The resulting
hole creates the opening (11). In FIG. 2A the user disengages the first locking component
(7) from the abutment (10) via application of force (14) through the opening (11).
As shown in FIG. 2B, the application of force (14) displaces the first locking component
(7), allowing the user to move the second part (4) away (15) from the first part (3)
until the first locking component (7) abuts against the stopper abutment (19) preventing
further movement. FIG 10B depicts the consumer product (1) in the open position.
FIG. 11 depicts a consumer product (1) as according to FIGS. 4-9, 10A and 10B but
wherein the second locking component (8) is in a different location, namely on the
same side as the first opening (6). The first locking component (7) and second locking
component (8) interact in the same way as depicted in FIG. 10. Shown are two opening
(11) corresponding to two separate second locking components (8).
FIG. 12 discloses a water-soluble unit dose article according to the present invention.
The water-soluble unit dose article (3) comprises a first water-soluble film (301)
and a second water-soluble film (302) which are sealed together at a seal region (303).
A detergent composition, preferably a laundry detergent composition (304) is comprised
within the water-soluble soluble unit dose article (3).
Example 1 : Perfume headspace dependency on container material
[0081] Too strong perfume deposition on clothes washed with a perfumed laundry detergent
composition are an ongoing complaint for Laundry soluble unit dose articles within
the segment of consumers that seek avoiding an overwhelming perfume experience on
their clothes. Perfume build-up in the headspace of a container upon storage is used
as a signal to assess the risk of clothes getting "over"-perfumed during a wash cycle.
In this study we cross-compared the impact of the storage container material in view
of the perfume build-up in the headspace of the container, more particularly paper-based
containers were single variably compared versus traditional in market plastic type
containers.
[0082] Closed packages of similar dimensions comprising 38 water soluble unit dose articles
were exposed to a 20 and a 35 days storage in a 20°C and a 32°C climate room after
which the built-up perfume headspace has been analytically quantified. Two replicates
of each container type were tested and the average total headspace number is reported.
Materials :
[0083]
- Water soluble unit dose article : Ariel 3 in 1 Pods, as commercially available in
the UK in April 2019
- Comparative example : Plastic tubs - Ariel 3 in 1 Pods Polypropylene tubs, as commercially
available in the UK in April 2019 (dimensions : Length=245mm; Height=135mm; width=96mm,
count size : 38)
- Example 1 : Corrugated paper tub (dimensions : Length=245mm; Height=135mm; width=96mm,
material: E-flute corrugated board 382 gsm KW2 135 / RF1 90 / Board KW2 135, count
size : 38)
- Example 2 : corrugated paper tub with PE lamination (dimensions : Length=245mm; Height=135mm;
width=96mm, material code GD2 210 / HPF 140 (E-Flute) / BKR 170 + PE15
Test Setup :
Storage :
[0084] Two replicates of every container type were filled with 38 pouches and stored in
closed position in a constant temperature climate room (20°C and a 32°C) for 20 days
after which the perfume headspace was analytically quantified as described herein.
After analytical quantification the containers were closed again and restored in the
climate room for another 15 days.
Analytical quantification :
[0085] Stored containers were placed in open position in a sealed off plastic box and left
for one hour to allow the perfume headspace to re-distribute from the container into
the plastic box. Air was consequently sucked out of the box (10 min @ constant flow)
through an aerosol filter capturing perfume particles from the air space. The aerosol
filter was then analytically assessed using GC/MS for presence and quantification
(mmol/L) of specific perfume particles. Table 1 summarizes the list of perfume materials
analyzed for. The individual perfume material quantities retrieved were summed up
and the resulting total headspace number has been reported.
Table 1 : Analyzed perfume materials
Perfume materials |
Cis-3-hexenol |
dihydromyrcenol |
allyl caproate |
tetrahydrolinalool |
linalool |
rose oxide |
phenyl ethyl alcohol |
benzyl acetate |
methyl phenyl carbinyl acetate |
alpha-terpineol |
citronellyl nitrile |
citronellol |
mayol |
verdox |
vertenex |
methyl nonyl acetaldehyde |
dihydro-eugenol |
delta-damascone |
confiran |
alpha-pinyl iso-butyrate |
gamma-methyl ionone |
lacto-j asmon |
frutene |
hedione |
iso e super + hexyl salicylate |
peonile |
ambrox |
habanolide |
Results :
[0086] The total headspace results in table 2 clearly show that unlike plastic tubs, paper
based containers (with or without lamination) according to the invention show a significantly
lower headspace build-up upon storage.
Table 2 : Average # perfume materials in headspace (mmol/L)
Storage temperature |
20°C |
32°C |
Container type |
Example 1 |
Example 2 |
Comparative example |
Example 1 |
Example 2 |
Comparative example |
20 days |
2.8 |
9.4 |
26.6 |
7.0 |
14.9 |
29.4 |
35 days |
2.6 |
8.5 |
23.0 |
8.4 |
14.7 |
29.9 |
[0087] The dimensions and values disclosed herein are not to be understood as being strictly
limited to the exact numerical values recited. Instead, unless otherwise specified,
each such dimension is intended to mean both the recited value and a functionally
equivalent range surrounding that value. For example, a dimension disclosed as "40
mm" is intended to mean "about 40 mm".
1. A consumer product comprising at least one water-soluble unit dose article and a container;
wherein the at least one water-soluble unit dose article comprises at least one water-soluble
film orientated to create at least one unit dose internal compartment, wherein the
at least one unit dose internal compartment comprises a detergent composition; and
wherein the container comprises a first part, wherein the first part comprises a first
compartment in which the at least one water-soluble unit dose article is contained,
and
wherein the first compartment is accessible through a first opening; and
wherein the container comprises a second part, wherein the second part is positioned
so that it prevents access through the first opening when the container is not in
use, but is moveable to allow access to the first opening when the container is in
use; and
wherein the container comprises a locking means wherein the locking means comprises
a first locking component on the first part and a second locking component on the
second part, wherein the first locking component engages the second locking component
to prevent movement of the second part to allow access to the first opening until
the first locking component and second locking component are disengaged from one another
by a user; and
wherein the first part comprises an interior surface and an exterior surface, wherein
the interior surface faces the internal compartment; and
wherein at least part of the interior surface of the first part is constructed from
paper-based material so that the water-soluble film of the at least one unit dose
article directly contacts the paper-based material of the internal surface;
and wherein the detergent composition comprises a free perfume composition.
2. The consumer product according to claim 1 wherein the entire interior surface of the
first part is constructed from a paper-based material, more preferably, wherein the
whole of the first part is constructed from a paper-based material.
3. The consumer product according to claim 1, wherein the second part comprises an interior
surface and an exterior surface and wherein at least part of the interior surface
of the second part is constructed from a paper-based material, preferably wherein
the entire interior surface of the second part is constructed from a paper-based material,
even more preferably, wherein the entire second part is constructed from a paper-based
material.
4. The consumer product according to any preceding claims, wherein;
a. the first locking component is constructed from a paper-based material; or
b. the second locking component is constructed from a paper-based material; or
c. a combination thereof.
5. The consumer product according to any preceding claims, wherein the paper-based material
comprises paper, cardboard, or a mixture thereof, wherein preferably, cardboard comprises
paper-board, corrugated fibre-board, or a mixture thereof.
6. The consumer product according to claim 5, wherein the paper-based material is a laminate
comprising paper, cardboard, or a mixture thereof, wherein preferably, cardboard comprises
paper-board, corrugated fibre-board, or a mixture thereof, and at least a second material,
and wherein the internal surface of the first part and preferably the internal surface
of the second part comprises paper, cardboard, or a mixture thereof, wherein preferably,
cardboard comprises paper-board, corrugated fibre-board, or a mixture thereof, and
preferably the external surface of the first part, external surface of the second
part, or a mixture thereof comprises the second material.
7. The consumer product according to claim 6, wherein the second material comprises a
plastic material, preferably the plastic material comprises polyethylene, polyethylene
terephthalate, polypropylene, polyvinylalcohol or a mixture thereof, and preferably
wherein the paper-based laminate comprises greater than 50% by weight of the laminate
of paper-based materials.
8. The consumer product according to any preceding claims wherein the volume of the first
compartment is between 500ml and 5000ml, preferably between 800ml and 4000ml.
9. The consumer product according to any preceding claims, wherein the first locking
component is a tab that protrudes from the exterior surface of the first part and
wherein the second part comprises an abutment with which the first locking tab is
able to releasably engage.
10. The consumer product according to any preceding claims, wherein the detergent composition
is a liquid, a solid, or a mixture thereof, preferably a liquid.
11. The consumer product according to any preceding claims, wherein the water-soluble
film comprises a polymer wherein the polymer comprises a homopolymer, copolymer, or
mixture thereof selected from polyvinyl alcohols, polyvinyl pyrrolidone, polyalkylene
oxides, acrylamide, acrylic acid, cellulose, cellulose ethers, cellulose esters, cellulose
amides, polyvinyl acetates, polycarboxylic acids and salts, polyaminoacids or peptides,
polyamides, polyacrylamide, copolymers of maleic/acrylic acids, polysaccharides including
starch and gelatine, xanthum, carragum or a mixture thereof, preferably, polyvinylalcohol
homopolymers and/or anionic polyvinylalcohol copolymers preferably selected from sulphonated
and carboxylated anionic polyvinylalcohol copolymers especially carboxylated anionic
polyvinylalcohol copolymers.
12. The consumer product according to any preceding claims, wherein the second part is
a sleeve that receives the first part therein and wherein the first part is able to
slide within the second part between an open position in which the first opening is
accessible and wherein the first locking component and second locking component are
disengaged from one another, and a closed position in which the second part blocks
access to the first opening, and wherein the first locking component and the second
locking component are engaged.
13. The consumer product according to claim 12, wherein the first part comprises a base
wall and the first opening, wherein the first opening is opposite to the base wall
and the base wall and the first opening are connected by at least one side wall; and
the second part comprises a second opening and at least one connecting wall, wherein
the first part slides within the second part via the second opening and the connecting
wall blocks the first opening when in the closed; and
wherein the at least one side wall of the first part comprises the first locking component
and the at least one connecting wall of the second part comprises the second locking
component,
preferably, wherein the second part comprises an end wall opposite to the second opening
and wherein the second opening and the end wall are connected via the at least one
connecting wall.
14. The consumer product according to any of claims 1-11, wherein the second part is a
removable lid, wherein the second part in a closed position blocks access to the first
opening and when in a closed position the first locking component is engaged with
the second locking component, and when in an open position the first locking component
and second locking component are disengaged and the second part is removable to allow
access to the first opening.
15. The consumer product according to claim 14 wherein the second part is attached to
the first part via a hinge or wherein the second part can be completely removed from
the first part, preferably wherein the second part can be completely removed from
the first part.
16. The consumer product according to claims 14-15 wherein the second part comprises a
top wall and at least one side wall, and
wherein the first part comprises a base wall and the first opening, wherein the first
opening is opposite to the base wall and the base wall and the first opening are connected
by at least one side wall; and
wherein in the closed position the at least one side wall of the second part overlaps
at least partially within the one side wall of the first part; and
wherein the first locking component is positioned on the at least one side wall of
the first part and second locking component is positioned on the at least one side
wall of the second part.
17. The consumer product according to any preceding claims wherein the first part is constructed
from a first blank and the second part is constructed from a second blank.