Field of the Invention
[0001] The present invention relates to a smoking substitute apparatus and, in particular,
a smoking substitute apparatus that is able to deliver nicotine to a user in an effective
manner.
Background
[0002] The smoking of tobacco is generally considered to expose a smoker to potentially
harmful substances. It is thought that a significant amount of the potentially harmful
substances are generated through the burning and/or combustion of the tobacco and
the constituents of the burnt tobacco in the tobacco smoke itself.
[0003] Low temperature combustion of organic material such as tobacco is known to produce
tar and other potentially harmful by-products. There have been proposed various smoking
substitute systems in which the conventional smoking of tobacco is avoided.
[0004] Such smoking substitute systems can form part of nicotine replacement therapies aimed
at people who wish to stop smoking and overcome a dependence on nicotine.
[0005] Known smoking substitute systems include electronic systems that permit a user to
simulate the act of smoking by producing an aerosol (also referred to as a "vapour")
that is drawn into the lungs through the mouth (inhaled) and then exhaled. The inhaled
aerosol typically bears nicotine and/or a flavourant without, or with fewer of, the
health risks associated with conventional smoking.
[0006] In general, smoking substitute systems are intended to provide a substitute for the
rituals of smoking, whilst providing the user with a similar, or improved, experience
and satisfaction to those experienced with conventional smoking and with combustible
tobacco products.
[0007] The popularity and use of smoking substitute systems has grown rapidly in the past
few years. Although originally marketed as an aid to assist habitual smokers wishing
to quit tobacco smoking, consumers are increasingly viewing smoking substitute systems
as desirable lifestyle accessories. There are a number of different categories of
smoking substitute systems, each utilising a different smoking substitute approach.
Some smoking substitute systems are designed to resemble a conventional cigarette
and are cylindrical in form with a mouthpiece at one end. Other smoking substitute
devices do not generally resemble a cigarette (for example, the smoking substitute
device may have a generally box-like form, in whole or in part).
[0008] One approach is the so-called "vaping" approach, in which a vaporisable liquid, or
an aerosol former or aerosol precursor, sometimes typically referred to herein as
"e-liquid", is heated by a heating device (sometimes referred to herein as an electronic
cigarette or "e-cigarette" device) to produce an aerosol vapour which is inhaled by
a user. The e-liquid typically includes a base liquid, nicotine and may include a
flavourant. The resulting vapour therefore also typically contains nicotine and/or
a flavourant. The base liquid may include propylene glycol and/or vegetable glycerine.
[0009] A typical e-cigarette device includes a mouthpiece, a power source (typically a battery),
a tank for containing e-liquid and a heating device. In use, electrical energy is
supplied from the power source to the heating device, which heats the e-liquid to
produce an aerosol (or "vapour") which is inhaled by a user through the mouthpiece.
[0010] E-cigarettes can be configured in a variety of ways. For example, there are "closed
system" vaping smoking substitute systems, which typically have a sealed tank and
heating element. The tank is prefilled with e-liquid and is not intended to be refilled
by an end user. One subset of closed system vaping smoking substitute systems include
a main body which includes the power source, wherein the main body is configured to
be physically and electrically couplable to a consumable including the tank and the
heating element. In this way, when the tank of a consumable has been emptied of e-liquid,
that consumable is removed from the main body and disposed of. The main body can then
be reused by connecting it to a new, replacement, consumable. Another subset of closed
system vaping smoking substitute systems are completely disposable, and intended for
one-use only.
[0011] There are also "open system" vaping smoking substitute systems which typically have
a tank that is configured to be refilled by a user. In this way the entire device
can be used multiple times.
[0012] An example vaping smoking substitute system is the myblu™ e-cigarette. The myblu™
e-cigarette is a closed system which includes a main body and a consumable. The main
body and consumable are physically and electrically coupled together by pushing the
consumable into the main body. The main body includes a rechargeable battery. The
consumable includes a mouthpiece and a sealed tank which contains e-liquid. The consumable
has an air inlet which is fluidly connected to an outlet at the mouthpiece by an air
flow channel. The consumable further includes a heater, which for this device is a
heating filament coiled around a portion of a wick positioned across the width of
the air flow passage. The wick is partially immersed in the e-liquid, and conveys
e-liquid from the tank to the heating filament. The system is controlled by a microprocessor
on board the main body. The system includes a sensor for detecting when a user is
inhaling through the mouthpiece, the microprocessor then activating the device in
response. When the system is activated, electrical energy is supplied from the power
source to the heating device, which heats e-liquid from the tank to produce a vapour,
which promptly condenses to form an aerosol as it is cooled by an air flow passing
through the air flow passage. A user may therefore inhale the generated aerosol through
the mouthpiece.
Summary of the Invention
[0013] For a smoking substitute system it is desirable to deliver nicotine into the user's
lungs, where it can be absorbed into the bloodstream. However, the present disclosure
is based in part on a realisation that in some prior art smoking substitute systems,
such delivery of nicotine is not efficient. In some prior art systems, the aerosol
droplets have a size distribution that is not suitable for delivering nicotine to
the lungs. Aerosol droplets of a large particle size tend to be deposited in the mouth
and/or upper respiratory tract. Aerosol particles of a small (e.g. sub-micron) particle
size can be inhaled into the lungs but may be exhaled without delivering nicotine
to the lungs. As a result the user would require drawing a longer puff, more puffs,
or vaporising e-liquid with a higher nicotine concentration in order to achieve the
desired experience.
[0014] Furthermore, in such prior art smoking substitute systems the air inlet is often
positioned at the base of the vaporising chamber. In use, coalesced aerosol droplets
that are too large to be suspended in the air flow, as well as excess aerosol precursor
that is wicked from the sealed tank, may undesirably leak through the air inlet by
gravity.
[0015] Accordingly, there is a need for improvement in the delivery of nicotine to a user,
as well as reduction in liquid leakage, in the context of a smoking substitute system.
[0016] The present disclosure has been devised in the light of the above considerations.
[0017] In a general aspect, the present invention utilises flow-induced localised pressure
reduction in order to draw out an aerosol from an aerosol generation chamber.
[0018] According to a first preferred aspect there is provided a smoking substitute apparatus
for generating an aerosol, comprising:
an air inlet and an outlet;
a passage extending between the air inlet and the outlet, air flowing in use along
the passage for inhalation by a user drawing air through the apparatus; and
an aerosol generating chamber containing an aerosol generator being operable to generate
an aerosol from an aerosol precursor;
wherein the aerosol generation chamber comprises at least one chamber outlet in fluid
communication with the passage at a junction, the at least one chamber outlet permitting,
in use, aerosol generated by the aerosol generator to be entrained into an air flow
along the passage; and
wherein the passage has a constriction configured to induce, in use, a localised reduced
pressure in the air flow at the junction for drawing out the aerosol from the aerosol
generation chamber.
[0019] The smoking substitute apparatus, or consumable, may comprise a housing containing
the aerosol generation chamber. The air inlet may open at a first end of the housing,
which may be a base of the smoking substitute apparatus. The first end of the housing
may be engageable with a main body of a smoking substitute system. The outlet may
open at a second end of the housing having a mouthpiece which the user may puff onto
in order to draw an air flow through the passage. Alternatively or in addition, the
air inlet may open at a sidewall of the housing, wherein the passage may extend directly
towards the outlet at the second end of the housing, or it may extend towards the
first end of the housing before routing back towards the outlet at the second end
of the housing.
[0020] In contrast to prior art smoking substitute systems, which generate an aerosol by
directly passing an air flow over the heater, the passage according to the present
disclosure may be arranged to allow all, or substantially all, of the air flow entering
the apparatus through the air inlet to bypass the aerosol generation chamber. In other
words, the passage may extend externally to the aerosol generation chamber. More specifically,
the air flow may not directly pass over the aerosol generator, but may only come into
contact with the aerosol once the aerosol has been discharged from the aerosol generation
chamber.
[0021] The aerosol precursor may comprise a liquid aerosol precursor, and wherein the aerosol
generator may comprise a heater configured to generate the aerosol by vaporising the
liquid aerosol precursor. The liquid aerosol precursor may be an e-liquid and may
comprise nicotine and a base liquid such as propylene glycol and/or vegetable glycerine
and may include a flavourant. The aerosol generator may be a heater such as a heater
coil wounded around a wick.
[0022] In use, the aerosol generator may vaporise an aerosol precursor to form a vapour.
A portion of the vapour may cool and condense to from an aerosol in the aerosol generation
chamber and subsequently be discharged to the passage through the chamber outlet.
The remaining portion of vapour may emerge through the chamber outlet into the passage,
and may form further aerosol upon contacting the air flow in the passage. The aerosol
generation chamber is arranged to reduce ingress of air flow from the passage, and
thereby reduces the turbulence around the aerosol generator in the aerosol generation
chamber.
[0023] For example, the aerosol generation chamber may be substantially sealed against air
flow except for the at least one chamber outlet. More specifically, the at least one
chamber outlet may form the only aperture, or apertures in the case where there is
a plurality of chamber outlets, of the aerosol generation chamber that provides a
substantial gas flow passage for a gas, e.g. a gas containing an aerosol, through
the sealed aerosol generation chamber. In other words, the aerosol generator is located
in a stagnant cavity of the aerosol generation chamber, wherein said stagnant cavity
is substantially free of the air flow entering the housing through the air inlet.
Because the air flow does not pass through the internal volume of the aerosol generation
chamber, said internal volume may form the stagnant cavity during a user puff. "Stagnant"
may not necessary mean a complete lack of convection, e.g. a degree of convention
may result from vapour and/or aerosol generated during aerosol formation. Advantageously,
because the air flow substantially does not pass over the aerosol generator, such
arrangement may reduce the amount of turbulence in the vicinity of the aerosol generator.
Accordingly, an aerosol with enlarged droplet sizes may be formed.
[0024] It is contemplated that the aerosol generation chamber may have a vent to permit
minor ingress of air into the chamber, in particular to aid pressure equalisation
in the aerosol generation chamber. However, it is considered that such a vent (or
vents) would not contribute significantly to air flow through the chamber in a manner
to affect the air flow delivered to the user. In alternative embodiments, there may
be no such vent.
[0025] The aerosol generation chamber may be configured to discharge aerosol to the passage
based on the pressure difference between the aerosol generation chamber and the passage.
For example, the aerosol may be drawn into the passage due to a reduced pressure downstream,
or it may be expelled from the aerosol generation chamber due to an elevated pressure
resulting from aerosol generation.
[0026] The chamber outlet may be defined as an opening at the aerosol generation chamber
which directly opens to the passage at the junction, e.g. the passage is adjacent
to the aerosol generation chamber.
[0027] Alternatively, the chamber outlet may be spaced from the passage and is in fluid
communication with the junction of the passage through an aerosol channel. The aerosol
channel may be configured such that pressure drop in the aerosol across the aerosol
channel is negligible.
[0028] The constriction may be positioned at, or adjacent to, the junction. That is, the
cross sectional area or hydraulic diameter of the passage at or adjacent to said junction
may be smaller than the portion of passage immediately upstream of the junction in
the direction of air flow. Such arrangement may cause the air flow to accelerate through
the constriction. According to Bernoulli's principle, as the air flow increases in
speed through the constriction, the pressure of the air flow therein may reduce accordingly.
This may result in a localised reduced pressure, or pressure drop, at the junction
and therefore as it passes through the junction, the air flow may draw the vapour
and/or aerosol out of the aerosol generation chamber. Advantageously, this may allow
the aerosol to be discharged from the aerosol generation chamber more effectively.
Furthermore, as the aerosol is formed in the aerosol generation chamber, the vaporised
aerosol precursor, or the vapour, may expand in the aerosol generation chamber and
thereby it may increase the internal pressure at the aerosol generation chamber. Such
elevated internal pressure may advantageously help forcing the aerosol through the
chamber opening into the passage, even when the user is not puffing on the mouthpiece.
[0029] For example, the aerosol generation chamber may have a specified volume of air at
atmospheric pressure prior to the vaporization of aerosol precursor. As the user puffs
on the mouthpiece, the pressure inside the passage decreases which may cause an activation
of the aerosol generator and thus the vaporisation process. At the same time, the
localised reduced pressure downstream of the aerosol generation chamber may draw out
the higher-pressure aerosol or air out of the aerosol generation chamber to equalise
the pressure therein. This may result in an equalized pressure across the aerosol
generation chamber and the outlet.
[0030] During aerosol generation, aerosol precursor may be vaporised at the heater and expand
into the surrounding stagnant air. The vaporised aerosol precursor may immediately
begin to cool and some of the condensed vapour may form aerosol droplets suspended
in the air. Due to vaporisation two mechanisms of pressure increase may occur in the
aerosol generation chamber:
- 1. The vapour has a defined volume at a particular temperature. Adding this volume
of gaseous vapour to the defined volume of air inside the aerosol generation chamber
may increase the pressure therein.
- 2. The aerosol droplets has a specified volume. These liquid droplets may displace
the same volume of air.
Both effects may increase the pressure in the aerosol generation chamber with respect
to the reduced pressure downstream caused by the venturi effect. This may aid the
expulsion of vapour and/or aerosol from the aerosol generation chamber during vaporisation.
[0031] By reducing or limiting the volume of the aerosol generation chamber, the expulsion
of the aerosol from the chamber may be made more efficient. That is, a smaller aerosol
generation chamber volume may result in greater pressure rise in the aerosol generation
chamber for a given vapor generation rate. More specifically, increasing the internal
volume of the aerosol generation chamber may reduce the amount of vapour and/or aerosol
that is able to be ejected from the aerosol generation chamber during a puff, with
the aerosol generated with an increase average droplet size. On the other hand, reducing
the internal volume of the aerosol generation chamber increases the amount of vapour
and/or aerosol during a puff with a reduction in the average aerosol droplet size.
Optionally, the aerosol generation chamber is configured to have an internal volume
ranging between 68mm
3 to 680mm
3. Optionally, the length of the aerosol generation chamber ranges between 2mm to 20mm.
Such arrangements may advantageously allow the aerosol to be expulsed from the aerosol
generation chamber at a rate greater than 0.1 mg/second during a puff.
[0032] The aerosol generation chamber may resemble an open ended container or a cup. The
chamber outlet may open towards the second end of the housing, or the mouthpiece.
More specifically, when the apparatus is oriented upright in use, the chamber outlet
may be directed towards an upward direction during use. Advantageously, this may help
to contain any excess aerosol precursor and/or coalesced aerosol droplets in the aerosol
generation chamber, any thereby preventing liquid leakage out of the chamber outlet.
Alternatively or in addition, the chamber outlet opens on a sidewall of the aerosol
generation chamber, e.g. the aerosol generated in the aerosol generation chamber may
be entrained into the passage from a direction orthogonal to the air flow.
[0033] The aerosol generation chamber may comprise a base, wherein the base may be sealed
to prevent fluid leakage through the first end of the housing. More specifically,
the base of the aerosol generation chamber may be completely closed or it may comprise
sealed apertures for allowing electrical contact to extending therethrough. Advantageously,
such arrangement may prevent excess aerosol precursor and coalesced aerosol droplets
in the aerosol generation chamber to leak through the base of the apparatus.
[0034] Optionally, the constriction comprises one or more of a venturi tube, an orifice
plate and a narrowed section along the passage. For example, in the case of a venturi
tube, the constriction may comprise, in the direction of air flow, a flow converging
portion followed by a narrowed passage, wherein the hydraulic diameter of the narrowed
passage is smaller than the flow converging portion. More specifically, the chamber
outlet is configured to be in fluid communication with the narrowed passage where
a localised pressure drop is created by the air flow. Advantageously, such arrangement
allows the aerosol in the aerosol generation chamber to be drawn into the narrowed
passage more effectively by the lowered pressure.
[0035] Optionally, the passage comprises an expanded portion immediately upstream of the
constriction in the passage. More specifically, the expanded portion may have a larger
hydraulic diameter than the constriction. Furthermore, the expanded portion may have
a larger hydraulic diameter than the passage immediate upstream thereto. Advantageously,
such expanded portion may allow an air flow to slow down before it accelerates through
the constriction. As a result, it may allow a larger pressure drop across the constriction,
and therefore it may lead to a more effective extraction of aerosol from the aerosol
generation chamber.
[0036] Optionally, a portion of the flow passage extends alongside the aerosol generation
chamber. Optionally, a portion of the flow passage coaxially extends alongside the
aerosol generation chamber.. For example, the passage may take the form of an annulus
surrounding the aerosol generation chamber. Advantageously, the passage may form an
effective insulation for reducing heat transfer to the external surface of the housing.
[0037] Optionally, the junction is configured to be in fluid communication with the chamber
outlet through a junction inlet, and wherein said junction inlet opens towards a direction
orthogonal to the air flow at the junction. That is, the aerosol may be drawn into
the junction from the side of the passage. Advantageously, this may allow the aerosol
to mix with the air flow in a more effective manner, and thereby allowing aerosol
to form more uniformly.
[0038] Alternatively, the chamber outlet is positioned adjacent to the passage and opens
in the direction of air flow. For example, the chamber outlet may open directly to
the passage. Such arrangement may allow the aerosol and air flow to flow concurrently,
and therefore advantageously, such arrangement may reduce the turbulence when the
two are mixed at the junction.
[0039] Optionally, the chamber outlet is closed by a one way valve, such as a check valve
or a duck bill value, which may advantageously prevent the air flow from entering
the aerosol generation chamber through the chamber outlet.
[0040] Optionally, the volumetric flowrate of aerosol in the aerosol generation chamber
is arranged to be less than 0.1 litre per minute. More specifically, the arrangement
according to the present disclosure may reduce or eliminate the amount of air flow
entering the aerosol generation chamber. Advantageously, this may reduce the turbulence
in the vicinity of the heater, and thereby increasing the median aerosol droplet size,
d
50, in the aerosol at the outlet. Here, the flowrate of aerosol is considered to be
the flowrate of air with the entrained aerosol droplets.
[0041] Optionally, the smoking substitute apparatus further comprises a tank for storing
a reservoir of liquid aerosol precursor. The tank may be spaced from the aerosol generation
chamber. The tank may be arranged to be in fluid communication with a wick of the
heater through a liquid conduit. The tank may be provided at a location between the
aerosol generation chamber and the outlet, and therefore the wick may not extend directly
from the aerosol generation chamber into the tank. Advantageously, this may allow
the tank to be positioned flexibly at various positions within the housing, and thereby
such arrangement may free up the space required for the constriction.
[0042] The liquid conduit may be sized to control the feed rate of the aerosol precursor
from the tank to the wick. Optionally, the liquid conduit has a hydraulic diameter
ranging from 0.01mm to 10 mm for controlling the flow rate of the aerosol precursor
from the tank towards the wick. Optionally, the liquid conduit has a hydraulic diameter
ranging from 0.01mm to 5 mm. Optionally, the liquid conduit has a hydraulic diameter
ranging from 0.1mm to 1 mm. Advantageously, such arrangements may limit the flow of
aerosol precursor towards the wick under gravity, and thereby may reduce the leakage
of excess aerosol precursor into the aerosol generation chamber.
[0043] Furthermore, the inclusion of a liquid conduit may solve the problem of insufficient
supply of aerosol precursor at the wick. For example, by adapting a stagnant aerosol
generation chamber there is a substantial lack of air flow in the aerosol generation
chamber, therefore the associated driving force, e.g. the pressure drop in the aerosol
generation chamber, for drawing out aerosol precursor from the tank may reduce accordingly.
By relocating the tank to a position between the aerosol generation chamber and the
outlet, e.g. by locating the tank above the aerosol generation chamber when the apparatus
is in an upright orientation during use, the aerosol precursor may flow from the tank
towards the wick under additional hydraulic head and thereby mitigate such problem.
Advantageously, by providing a liquid conduit that is configured to allow sufficient
flow of aerosol precursor, the wick may be prevented from drying out during vaporisation.
[0044] In addition, different consumables having liquid conduits with different hydraulic
diameters may be used to accommodate different types of users. For example, consumables
having liquid conduits with broader hydraulic diameter may cater for heavy users taking
longer puffs, where an increased flow of aerosol precursor may reduce the likelihood
of drying out at the wick. Consumables having liquid conduits with narrower hydraulic
diameter may cater for light users who take shorter puffs, where a reduced flow of
aerosol precursor may reduce the amount of excess aerosol precursor at the wick.
[0045] Optionally, the aerosol generator is located at a position immediately upstream of
the chamber outlet. More specifically, the aerosol generator may be positioned in
the aerosol generation chamber by the chamber outlet. Advantageously, this may shorten
the path of travel for the aerosol and thereby allows the aerosol to be drawn into
the passage more effectively.
[0046] Alternatively, the aerosol generator may be spaced from the chamber outlet. Advantageously,
such arrangement may reduce the likelihood of air flow entering into the aerosol generation
chamber, and thereby limiting the turbulence in the vicinity of the aerosol generator.
Further, this may increase the residence time of the vapour in the aerosol generation
chamber and thus it may allow some aerosol droplets to form and even coalesce before
being entrained in the air flow. Optionally, the aerosol generator is separated from
the chamber outlet by a distance of at least 10 mm. Optionally, the aerosol generator
is separated from the chamber outlet by a distance ranged from 10mm to 50mm.
[0047] Optionally, the passage comprises a flow converging portion downstream to the aerosol
generation chamber, the flow converging portion is configured to converge the aerosol
with the air flow in the passage. Optionally, the flow converging portion comprises
a funnel or a tapered section for gradually merging the aerosol with the air flow.
Advantageously, this may reduce the turbulence that may prohibit the formation of
larger aerosol droplets. Alternatively or in addition, the flow converging portion
comprises a length of passage having a constant cross sectional profile along its
length. Advantageously, this reduces the change in flow direction of the aerosol and
the air flow as they flow towards the outlet.
[0048] Optionally, the flow converging portion having a length of at least 10 mm. Optionally,
the flow converging portion having a length between 10 mm and 50mm.
[0049] Optionally, the aerosol generation chamber is configured to have a uniform cross
sectional profile along its length. Optionally, the chamber outlet is configured to
have the same cross sectional profile as the aerosol generation chamber. For example,
the aerosol flow path along the length of the aerosol generation chamber may have
the same cross-sectional area. Advantageously, this may reduce turbulence, as well
as fluctuation in pressure in the aerosol flow path and thereby such arrangement may
lead to an increase in the size of aerosol droplets.
[0050] Optionally, the smoking substitute apparatus is configure to generate an aerosol
having a median droplet size, d
50, of at least 1 µm. Optionally, the smoking substitute apparatus is configure to generate
an aerosol having a median droplet size, d
50, ranged between 1 µm to 4 µm. Optionally, the smoking substitute apparatus is configure
to generate an aerosol having a median droplet size, d
50, ranged between 2 µm to 3 µm. Advantageously, aerosol having droplets in such size
ranges may improve delivery of nicotine into the user's lung, by reducing the likelihood
of nicotine deposition in the mouth and/or upper respiratory tract, e.g. in the case
of oversized aerosol droplets, or not being absorbed at all, e.g. in the case of undersized
aerosol droplets.
[0051] The smoking substitute apparatus may be in the form of a consumable. The consumable
may be configured for engagement with a main body. When the consumable is engaged
with the main body, the combination of the consumable and the main body may form a
smoking substitute system such as a closed smoking substitute system. For example,
the consumable may comprise components of the system that are disposable, and the
main body may comprise non-disposable or non-consumable components (e.g. power supply,
controller, sensor, etc.) that facilitate the generation and/or delivery of aerosol
by the consumable. In such an embodiment, the aerosol precursor (e.g. e-liquid) may
be replenished by replacing a used consumable with an unused consumable.
[0052] Alternatively, the smoking substitute apparatus may be a non-consumable apparatus
(e.g. that is in the form of an open smoking substitute system). In such embodiments
an aerosol precursor (e.g. e-liquid) of the system may be replenished by re-filling,
e.g. a reservoir of the smoking substitute apparatus, with the aerosol precursor (rather
than replacing a consumable component of the apparatus).
[0053] In light of this, it should be appreciated that some of the features described herein
as being part of the smoking substitute apparatus may alternatively form part of a
main body for engagement with the smoking substitute apparatus. This may be the case
in particular when the smoking substitute apparatus is in the form of a consumable.
[0054] Where the smoking substitute apparatus is in the form of a consumable, the main body
and the consumable may be configured to be physically coupled together. For example,
the consumable may be at least partially received in a recess of the main body, such
that there is an interference fit between the main body and the consumable. Alternatively,
the main body and the consumable may be physically coupled together by screwing one
onto the other, or through a bayonet fitting, or the like.
[0055] Thus, the smoking substitute apparatus may comprise one or more engagement portions
for engaging with a main body. In this way, one end of the smoking substitute apparatus
may be coupled with the main body, whilst an opposing end of the smoking substitute
apparatus may define a mouthpiece of the smoking substitute system.
[0056] The smoking substitute apparatus may comprise a reservoir configured to store an
aerosol precursor, such as an e-liquid. The e-liquid may, for example, comprise a
base liquid. The e-liquid may further comprise nicotine. The base liquid may include
propylene glycol and/or vegetable glycerine. The e-liquid may be substantially flavourless.
That is, the e-liquid may not contain any deliberately added additional flavourant
and may consist solely of a base liquid of propylene glycol and/or vegetable glycerine
and nicotine.
[0057] The reservoir may be in the form of a tank. At least a portion of the tank may be
light-transmissive. For example, the tank may comprise a window to allow a user to
visually assess the quantity of e-liquid in the tank. A housing of the smoking substitute
apparatus may comprise a corresponding aperture (or slot) or window that may be aligned
with a light-transmissive portion (e.g. window) of the tank. The reservoir may be
referred to as a "clearomizer" if it includes a window, or a "cartomizer" if it does
not.
[0058] The outlet may be at a mouthpiece of the smoking substitute apparatus. In this respect,
a user may draw fluid (e.g. air) into and through the passage by inhaling at the outlet
(i.e. using the mouthpiece). The passage may be at least partially defined by the
tank.
[0059] The smoking substitute apparatus may comprise an aerosol generator. The aerosol generator
may comprise a wick. The aerosol generator may further comprise a heater. The wick
may comprise a porous material, capable of wicking the aerosol precursor. A portion
of the wick may be exposed in the aerosol generation chamber. The wick may also comprise
one or more portions in contact with liquid stored in the reservoir, e.g. via the
liquid conduit. For example, opposing ends of the wick may protrude into the reservoir,
or liquid conduit in fluid communication with the reservoir, and an intermediate portion
(between the ends) may extend across the aerosol generation chamber. Thus, liquid
may be drawn (e.g. by capillary action) along the wick, from the reservoir to the
portion of the wick extending across the aerosol generation chamber.
[0060] The heater may comprise a heating element, which may be in the form of a filament
wound about the wick (e.g. the filament may extend helically about the wick in a coil
configuration). The heating element may be wound about the intermediate portion of
the wick that extends across the aerosol generation chamber. The heating element may
be electrically connected (or connectable) to a power source. Thus, in operation,
the power source may apply a voltage across the heating element so as to heat the
heating element by resistive heating. This may cause liquid stored in the wick (i.e.
drawn from the tank) to be heated so as to form a vapour in the aerosol generation
chamber. This vapour may subsequently cool to form an aerosol in the aerosol generation
chamber, typically downstream from the heating element.
[0061] In use, the user may puff on a mouthpiece of the smoking substitute apparatus, i.e.
draw on the smoking substitute apparatus by inhaling, to draw in an air stream therethrough.
The air stream (also referred to as a "dilution air flow" or "bypass air flow)) may
bypass the aerosol generation chamber and be directed to mix with the generated aerosol
downstream from the aerosol generation chamber. That is, the dilution air flow may
be an air stream at an ambient temperature and may not be directly heated at all by
the aerosol generator. Alternatively, the dilution air flow may be directly inhaled
by the user without passing though the passage of the smoking substitute apparatus.
[0062] As a user puffs on the mouthpiece, vaporised e-liquid or aerosol may entrained in
the air flow along the passage may be drawn towards the outlet of passage. For example,
the vapour may cool, and thereby nucleate and/or condense to form a plurality of aerosol
droplets, e.g. nicotine-containing aerosol droplets. A portion of these aerosol droplets
may be delivered to and be absorbed at a target delivery site, e.g. a user's lung,
whilst a portion of the aerosol droplets may instead adhere onto other parts of the
user's respiratory tract, e.g. the user's oral cavity and/or throat. Typically, in
some known smoking substitute apparatuses, the aerosol droplets as measured at the
outlet of the passage, e.g. at the mouthpiece, may have a median droplet size, d
50, of less than 1µm.
[0063] The median particle droplet size, d
50, of an aerosol may be measured by a laser diffraction technique. For example, the
stream of aerosol output from the outlet of the passage may be drawn through a Malvern
Spraytec laser diffraction system, where the intensity and pattern of scattered laser
light are analysed to calculate the size and size distribution of aerosol droplets.
As will be readily understood, the particle size distribution may be expressed in
terms of d
10, d
50 and d
90, for example. Considering a cumulative plot of the volume of the particles measured
by the laser diffraction technique, the d
10 particle size is the particle size below which 10% by volume of the sample lies.
The d
50 particle size is the particle size below which 50% by volume of the sample lies.
The d
90 particle size is the particle size below which 90% by volume of the sample lies.
Unless otherwise indicated herein, the particle size measurements are volume-based
particle size measurements, rather than number-based or mass-based particle size measurements.
[0064] The smoking substitute apparatus (or main body engaged with the smoking substitute
apparatus) may comprise a power source. The power source may be electrically connected
(or connectable) to a heater of the smoking substitute apparatus (e.g. when the smoking
substitute apparatus is engaged with the main body). The power source may be a battery
(e.g. a rechargeable battery). A connector in the form of e.g. a USB port may be provided
for recharging this battery.
[0065] When the smoking substitute apparatus is in the form of a consumable, the smoking
substitute apparatus may comprise an electrical interface for interfacing with a corresponding
electrical interface of the main body. One or both of the electrical interfaces may
include one or more electrical contacts. Thus, when the main body is engaged with
the consumable, the electrical interface of the main body may be configured to transfer
electrical power from the power source to a heater of the consumable via the electrical
interface of the consumable.
[0066] The electrical interface of the smoking substitute apparatus may also be used to
identify the smoking substitute apparatus (in the form of a consumable) from a list
of known types. For example, the consumable may have a certain concentration of nicotine
and the electrical interface may be used to identify this. The electrical interface
may additionally or alternatively be used to identify when a consumable is connected
to the main body.
[0067] Again, where the smoking substitute apparatus is in the form of a consumable, the
main body may comprise an identification means, which may, for example, be in the
form of an RFID reader, a barcode or QR code reader. This identification means may
be able to identify a characteristic (e.g. a type) of a consumable engaged with the
main body. In this respect, the consumable may include any one or more of an RFID
chip, a barcode or QR code, or memory within which is an identifier and which can
be interrogated via the identification means.
[0068] The smoking substitute apparatus or main body may comprise a controller, which may
include a microprocessor. The controller may be configured to control the supply of
power from the power source to the heater of the smoking substitute apparatus (e.g.
via the electrical contacts). A memory may be provided and may be operatively connected
to the controller. The memory may include non-volatile memory. The memory may include
instructions which, when implemented, cause the controller to perform certain tasks
or steps of a method.
[0069] The main body or smoking substitute apparatus may comprise a wireless interface,
which may be configured to communicate wirelessly with another device, for example
a mobile device, e.g. via Bluetooth®. To this end, the wireless interface could include
a Bluetooth® antenna. Other wireless communication interfaces, e.g. WiFi®, are also
possible. The wireless interface may also be configured to communicate wirelessly
with a remote server.
[0070] A puff sensor may be provided that is configured to detect a puff (i.e. inhalation
from a user). The puff sensor may be operatively connected to the controller so as
to be able to provide a signal to the controller that is indicative of a puff state
(i.e. puffing or not puffing). The puff sensor may, for example, be in the form of
a pressure sensor or an acoustic sensor. That is, the controller may control power
supply to the heater of the consumable in response to a puff detection by the sensor.
The control may be in the form of activation of the heater in response to a detected
puff. That is, the smoking substitute apparatus may be configured to be activated
when a puff is detected by the puff sensor. When the smoking substitute apparatus
is in the form of a consumable, the puff sensor may be provided in the consumable
or alternatively may be provided in the main body.
[0071] The term "flavourant" is used to describe a compound or combination of compounds
that provide flavour and/or aroma. For example, the flavourant may be configured to
interact with a sensory receptor of a user (such as an olfactory or taste receptor).
The flavourant may include one or more volatile substances.
[0072] The flavourant may be provided in solid or liquid form. The flavourant may be natural
or synthetic. For example, the flavourant may include menthol, liquorice, chocolate,
fruit flavour (including e.g. citrus, cherry etc.), vanilla, spice (e.g. ginger, cinnamon)
and tobacco flavour. The flavourant may be evenly dispersed or may be provided in
isolated locations and/or varying concentrations.
[0073] According to a second aspect there is provided a smoking substitute system for generating
an aerosol, comprising:
- i) the smoking substitute apparatus of the first aspect; and
- ii) a main body configured to engage with the smoking substitute apparatus; wherein
the main body comprises a controller and a power source configured to energise the
aerosol generator.
[0074] According to a third aspect there is provided a method of using the smoking substitute
apparatus of the first aspect, comprising:
- i) generating the aerosol with the aerosol generator;
- ii) drawing on the apparatus to induce a localised pressure drop in the air flow at
the junction, so as to draw out the generated aerosol from the aerosol generation
chamber.
[0075] The present inventors consider that a flow rate of 1.3 L min
-1 is towards the lower end of a typical user expectation of flow rate through a conventional
cigarette and therefore through a user-acceptable smoking substitute apparatus. The
present inventors further consider that a flow rate of 2.0 L min
-1 is towards the higher end of a typical user expectation of flow rate through a conventional
cigarette and therefore through a user-acceptable smoking substitute apparatus. Embodiments
of the present invention therefore provide an aerosol with advantageous particle size
characteristics across a range of flow rates of air through the apparatus.
[0076] The aerosol may have a Dv50 of at least 1.1 µm, at least 1.2 µm, at least 1.3 µm,
at least 1.4 µm, at least 1.5 µm, at least 1.6 µm, at least 1.7 µm, at least 1.8 µm,
at least 1.9 µm or at least 2.0 µm.
[0077] The aerosol may have a Dv50 of not more than 4.9 µm, not more than 4.8 µm, not more
than 4.7 µm, not more than 4.6 µm, not more than 4.5 µm, not more than 4.4 µm, not
more than 4.3 µm, not more than 4.2 µm, not more than 4.1 µm, not more than 4.0 µm,
not more than 3.9 µm, not more than 3.8 µm, not more than 3.7 µm, not more than 3.6
µm, not more than 3.5 µm, not more than 3.4 µm, not more than 3.3 µm, not more than
3.2 µm, not more than 3.1 µm or not more than 3.0 µm.
[0078] A particularly preferred range for Dv50 of the aerosol is in the range 2-3 µm.
[0079] When the air flow rate inhaled by the user through the apparatus is 1.3 L min
-1, the average magnitude of velocity of air in the vaporisation chamber may be not
more than 0.001 ms
-1, or not more than 0.005 ms
-1, or not more than 0.01 ms
-1, or not more than 0.05 ms
-1.
[0080] The aerosol generator may comprise a vaporiser element loaded with aerosol precursor,
the vaporiser element being heatable by a heater and presenting a vaporiser element
surface to air in the vaporisation chamber. A vaporiser element region may be defined
as a volume extending outwardly from the vaporiser element surface to a distance of
1 mm from the vaporiser element surface.
[0081] The air inlet, flow passage, outlet and the vaporisation chamber may be configured
so that, when the air flow rate inhaled by the user through the apparatus is 1.3 L
min
-1, the average magnitude of velocity of air in the vaporiser element region is in the
range 0-1.2 ms
-1. The average magnitude of velocity of air in the vaporiser element region may be
calculated using computational fluid dynamics.
[0082] When the air flow rate inhaled by the user through the apparatus is 1.3 L min
-1, the average magnitude of velocity of air in the vaporiser element region may be
not more than 0.001 ms
-1, or not more than 0.005 ms
-1, or not more than 0.01 ms
-1, or not more than 0.05 ms
-1.
[0083] When the average magnitude of velocity of air in the vaporiser element region is
in the ranges specified, it is considered that the resultant aerosol particle size
is advantageously controlled to be in a desirable range. It is further considered
that the velocity of air in the vaporiser element region is more relevant to the resultant
particle size characteristics than consideration of the velocity in the vaporisation
chamber as a whole. This is in view of the significant effect of the velocity of air
in the vaporiser element region on the cooling of the vapour emitted from the vaporiser
element surface.
[0084] Additionally or alternatively is it relevant to consider the maximum magnitude of
velocity of air in the vaporiser element region.
[0085] Therefore, the air inlet, flow passage, outlet and the vaporisation chamber may be
configured so that, when the air flow rate inhaled by the user through the apparatus
is 1.3 L min
-1, the maximum magnitude of velocity of air in the vaporiser element region is in the
range 0-2.0 ms
-1.
[0086] When the air flow rate inhaled by the user through the apparatus is 1.3 L min
-1, the maximum magnitude of velocity of air in the vaporiser element region may be
not more than 0.001 ms
-1, or not more than 0.005 ms
-1, or not more than 0.01 ms
-1, or not more than 0.05 ms
-1.
[0087] It is considered that configuring the apparatus in a manner to permit such control
of velocity of the airflow at the vaporiser permits the generation of aerosols with
particularly advantageous particle size characteristics, including Dv50 values.
[0088] Additionally or alternatively is it relevant to consider the turbulence intensity
in the vaporiser chamber in view of the effect of turbulence on the particle size
of the generated aerosol. For example, the air inlet, flow passage, outlet and the
vaporisation chamber may be configured so that, when the air flow rate inhaled by
the user through the apparatus is 1.3 L min
-1, the turbulence intensity in the vaporiser element region is not more than 1%.
[0089] When the air flow rate inhaled by the user through the apparatus is 1.3 L min
-1, the turbulence intensity in the vaporiser element region may be not more than 0.95%,
not more than 0.9%, not more than 0.85%, not more than 0.8%, not more than 0.75%,
not more than 0.7%, not more than 0.65% or not more than 0.6%.
[0090] It is considered that configuring the apparatus in a manner to permit such control
of the turbulence intensity in the vaporiser element region permits the generation
of aerosols with particularly advantageous particle size characteristics, including
Dv50 values.
[0091] Following detailed investigations, the inventors consider, without wishing to be
bound by theory, that the particle size characteristics of the generated aerosol may
be determined by the cooling rate experienced by the vapour after emission from the
vaporiser element (e.g. wick). In particular, it appears that imposing a relatively
slow cooling rate on the vapour has the effect of generating aerosols with a relatively
large particle size. The parameters discussed above (velocity and turbulence intensity)
are considered to be mechanisms for implementing a particular cooling dynamic to the
vapour.
[0092] More generally, it is considered that the air inlet, flow passage, outlet and the
vaporisation chamber may be configured so that a desired cooling rate is imposed on
the vapour. The particular cooling rate to be used depends of course on the nature
of the aerosol precursor and other conditions. However, for a particular aerosol precursor
it is possible to define a set of testing conditions in order to define the cooling
rate, and by extension this imposes limitations on the configuration of the apparatus
to permit such cooling rates as are shown to result in advantageous aerosols. Accordingly,
the air inlet, flow passage, outlet and the vaporisation chamber may be configured
so that the cooling rate of the vapour is such that the time taken to cool to 50 °C
is not less than 16 ms, when tested according to the following protocol. The aerosol
precursor is an e-liquid consisting of 1.6% freebase nicotine and the remainder a
65:35 propylene glycol and vegetable glycerine mixture, the e-liquid having a boiling
point of 209 °C. Air is drawn into the air inlet at a temperature of 25 °C. The vaporiser
is operated to release a vapour of total particulate mass 5 mg over a 3 second duration
from the vaporiser element surface in an air flow rate between the air inlet and outlet
of 1.3 L min
-1.
[0093] Additionally or alternatively, the air inlet, flow passage, outlet and the vaporisation
chamber may be configured so that the cooling rate of the vapour is such that the
time taken to cool to 50 °C is not less than 16 ms, when tested according to the following
protocol. The aerosol precursor is an e-liquid consisting of 1.6% freebase nicotine
and the remainder a 65:35 propylene glycol and vegetable glycerine mixture, the e-liquid
having a boiling point of 209 °C. Air is drawn into the air inlet at a temperature
of 25 °C. The vaporiser is operated to release a vapour of total particulate mass
5 mg over a 3 second duration from the vaporiser element surface in an air flow rate
between the air inlet and outlet of 2.0 L min
-1.
[0094] Cooling of the vapour such that the time taken to cool to 50 °C is not less than
16 ms corresponds to an equivalent linear cooling rate of not more than 10 °C/ms.
[0095] The equivalent linear cooling rate of the vapour to 50 °C may be not more than 9
°C/ms, not more than 8 °C/ms, not more than 7 °C/ms, not more than 6 °C/ms or not
more than 5 °C/ms.
[0096] Cooling of the vapour such that the time taken to cool to 50 °C is not less than
32 ms corresponds to an equivalent linear cooling rate of not more than 5 °C/ms.
[0097] The testing protocol set out above considers the cooling of the vapour (and subsequent
aerosol) to a temperature of 50 °C. This is a temperature which can be considered
to be suitable for an aerosol to exit the apparatus for inhalation by a user without
causing significant discomfort. It is also possible to consider cooling of the vapour
(and subsequent aerosol) to a temperature of 75 °C. Although this temperature is possibly
too high for comfortable inhalation, it is considered that the particle size characteristics
of the aerosol are substantially settled by the time the aerosol cools to this temperature
(and they may be settled at still higher temperature).
[0098] Accordingly, the air inlet, flow passage, outlet and the vaporisation chamber may
be configured so that the cooling rate of the vapour is such that the time taken to
cool to 75 °C is not less than 4.5 ms, when tested according to the following protocol.
The aerosol precursor is an e-liquid consisting of 1.6% freebase nicotine and the
remainder a 65:35 propylene glycol and vegetable glycerine mixture, the e-liquid having
a boiling point of 209 °C. Air is drawn into the air inlet at a temperature of 25
°C. The vaporiser is operated to release a vapour of total particulate mass 5 mg over
a 3 second duration from the vaporiser element surface in an air flow rate between
the air inlet and outlet of 1.3 L min
-1.
[0099] Additionally or alternatively, the air inlet, flow passage, outlet and the vaporisation
chamber may be configured so that the cooling rate of the vapour is such that the
time taken to cool to 75 °C is not less than 4.5 ms, when tested according to the
following protocol. The aerosol precursor is an e-liquid consisting of 1.6% freebase
nicotine and the remainder a 65:35 propylene glycol and vegetable glycerine mixture,
the e-liquid having a boiling point of 209 °C. Air is drawn into the air inlet at
a temperature of 25 °C. The vaporiser is operated to release a vapour of total particulate
mass 5 mg over a 3 second duration from the vaporiser element surface in an air flow
rate between the air inlet and outlet of 2.0 L min
-1.
[0100] Cooling of the vapour such that the time taken to cool to 75 °C is not less than
4.5 ms corresponds to an equivalent linear cooling rate of not more than 30 °C/ms.
[0101] The equivalent linear cooling rate of the vapour to 75 °C may be not more than 29
°C/ms, not more than 28 °C/ms, not more than 27 °C/ms, not more than 26 °C/ms, not
more than 25 °C/ms, not more than 24 °C/ms, not more than 23 °C/ms, not more than
22 °C/ms, not more than 21 °C/ms, not more than 20 °C/ms, not more than 19 °C/ms,
not more than 18 °C/ms, not more than 17 °C/ms, not more than 16 °C/ms, not more than
15 °C/ms, not more than 14 °C/ms, not more than 13 °C/ms, not more than 12 °C/ms,
not more than 11 °C/ms or not more than 10 °C/ms.
[0102] Cooling of the vapour such that the time taken to cool to 75 °C is not less than
13 ms corresponds to an equivalent linear cooling rate of not more than 10 °C/ms.
[0103] It is considered that configuring the apparatus in a manner to permit such control
of the cooling rate of the vapour permits the generation of aerosols with particularly
advantageous particle size characteristics, including Dv50 values.
[0104] The invention includes the combination of the aspects and preferred features described
except where such a combination is clearly impermissible or expressly avoided.
Summary of the Figures
[0105] So that the invention may be understood, and so that further aspects and features
thereof may be appreciated, embodiments illustrating the principles of the invention
will now be discussed in further detail with reference to the accompanying figures,
in which:
Figure 1 illustrates a set of rectangular tubes for use in experiments to assess the
effect of flow and cooling conditions at the wick on aerosol properties. Each tube
has the same depth and length but different width.
Figure 2 shows a schematic perspective longitudinal cross sectional view of an example
rectangular tube with a wick and heater coil installed.
Figure 3 shows a schematic transverse cross sectional view an example rectangular
tube with a wick and heater coil installed. In this example, the internal width of
the tube is 12 mm.
Figures 4A-4D show air flow streamlines in the four devices used in a turbulence study.
Figure 5 shows the experimental set up to investigate the influence of inflow air
temperature on aerosol particle size, in order to investigate the effect of vapour
cooling rate on aerosol generation.
Figure 6 shows a schematic longitudinal cross sectional view of a first smoking substitute
apparatus (pod 1) used to assess influence of inflow air temperature on aerosol particle
size.
Figure 7 shows a schematic longitudinal cross sectional view of a second smoking substitute
apparatus (pod 2) used to assess influence of inflow air temperature on aerosol particle
size.
Figure 8A shows a schematic longitudinal cross sectional view of a third smoking substitute
apparatus (pod 3) used to assess influence of inflow air temperature on aerosol particle
size. Figure 8B shows a schematic longitudinal cross sectional view of the same third
smoking substitute apparatus (pod 3) in a direction orthogonal to the view taken in
Figure 8A.
Figure 9 shows a plot of aerosol particle size (Dv50) experimental results against
calculated air velocity.
Figure 10 shows a plot of aerosol particle size (Dv50) experimental results against
the flow rate through the apparatus for a calculated air velocity of 1 m/s.
Figure 11 shows a plot of aerosol particle size (Dv50) experimental results against
the average magnitude of the velocity in the vaporiser surface region, as obtained
from CFD modelling.
Figure 12 shows a plot of aerosol particle size (Dv50) experimental results against
the maximum magnitude of the velocity in the vaporiser surface region, as obtained
from CFD modelling.
Figure 13 shows a plot of aerosol particle size (Dv50) experimental results against
the turbulence intensity.
Figure 14 shows a plot of aerosol particle size (Dv50) experimental results dependent
on the temperature of the air and the heating state of the apparatus.
Figure 15 shows a plot of aerosol particle size (Dv50) experimental results against
vapour cooling rate to 50°C.
Figure 16 shows a plot of aerosol particle size (Dv50) experimental results against
vapour cooling rate to 75°C.
Figure 17 is a schematic front view of a smoking substitute system, according to a
first reference arrangement, in an engaged position;
Figure 18 is a schematic front view of the smoking substitute system of the first
reference arrangement in a disengaged position;
Figure 19 is a schematic longitudinal cross sectional view of a smoking substitute
apparatus of the first reference arrangement; and
Figure 20 is an enlarged schematic cross sectional view of part of the air passage
and aerosol generation chamber of the first reference arrangement;
Figure 21A is a schematic longitudinal cross sectional view of a smoking substitute
apparatus of the first embodiment;
Figure 21B is an enlarged schematic cross sectional view of a junction of the first
embodiment as shown in Figure 21A; and
Figure 22 is a plan view of a base of a smoking substitute apparatus of a second embodiment.
Detailed Description of the Invention
[0106] Further background to the present invention and further aspects and embodiments of
the present invention will now be discussed with reference to the accompanying figures.
Further aspects and embodiments will be apparent to those skilled in the art. The
contents of all documents mentioned in this text are incorporated herein by reference
in their entirety.
[0107] Figures 17 and 18 illustrate a smoking substitute system in the form of an e-cigarette
system 110. The system 110 comprises a main body 120 of the system 110, and a smoking
substitute apparatus in the form of an e-cigarette consumable (or "pod") 150. In the
illustrated embodiment the consumable 150 (sometimes referred to herein as a smoking
substitute apparatus) is removable from the main body 120, so as to be a replaceable
component of the system 110. The e-cigarette system 110 is a closed system in the
sense that it is not intended that the consumable should be refillable with e-liquid
by a user.
[0108] As is apparent from Figures 17 and 18, the consumable 150 is configured to engage
the main body 120. Figure 17 shows the main body 120 and the consumable 150 in an
engaged state, whilst Figure 18 shows the main body 120 and the consumable 150 in
a disengaged state. When engaged, a portion of the consumable 150 is received in a
cavity of corresponding shape in the main body 120 and is retained in the engaged
position by way of a snap-engagement mechanism. In other embodiments, the main body
120 and consumable 150 may be engaged by screwing one into (or onto) the other, or
through a bayonet fitting, or by way of an interference fit.
[0109] The system 110 is configured to vaporise an aerosol precursor, which in the illustrated
embodiment is in the form of a nicotine-based e-liquid 160. The e-liquid 160 comprises
nicotine and a base liquid including propylene glycol and/or vegetable glycerine.
In the present embodiment, the e-liquid 160 is flavoured by a flavourant. In other
embodiments, the e-liquid 160 may be flavourless and thus may not include any added
flavourant.
[0110] Figure 19 shows a schematic longitudinal cross sectional view of a smoking substitute
apparatus according to a reference arrangement that is configured to form part of
the smoking substitute system shown in Figures 17 and 18. The smoking substitute apparatus,
or consumable 150 as shown in Figure 19 is provided as a reference arrangement to
illustrate the features of a consumable 150 and its interaction with the main body
120. In Figure 19, the e-liquid 160 is stored within a reservoir in the form of a
tank 152 that forms part of the consumable 150. In the illustrated embodiment, the
consumable 150 is a "single-use" consumable 150. That is, upon exhausting the e-liquid
160 in the tank 152, the intention is that the user disposes of the entire consumable
150. The term "single-use" does not necessarily mean the consumable is designed to
be disposed of after a single smoking session. Rather, it defines the consumable 150
is not arranged to be refilled after the e-liquid contained in the tank 152 is depleted.
The tank may include a vent (not shown) to allow ingress of air to replace e-liquid
that has been used from the tank. The consumable 150 preferably includes a window
158 (see Figures 1 and 2), so that the amount of e-liquid in the tank 152 can be visually
assessed. The main body 120 includes a slot 157 so that the window 158 of the consumable
150 can be seen whilst the rest of the tank 152 is obscured from view when the consumable
150 is received in the cavity of the main body 120. The consumable 150 may be referred
to as a "clearomizer" when it includes a window 158, or a "cartomizer" when it does
not.
[0111] In other embodiments, the e-liquid (i.e. aerosol precursor) may be the only part
of the system that is truly "single-use". That is, the tank may be refillable with
e-liquid or the e-liquid may be stored in a non-consumable component of the system.
For example, in such other embodiments, the e-liquid may be stored in a tank located
in the main body or stored in another component that is itself not single-use (e.g.
a refillable cartomizer).
[0112] The external wall of tank 152 is provided by a casing of the consumable 150. The
tank 152 annularly surrounds, and thus defines a portion of, a passage 170 that extends
between a vaporiser inlet 172 and an outlet 174 at opposing ends of the consumable
150. In this respect, the passage 170 comprises an upstream end at the end of the
consumable 150 that engages with the main body 120, and a downstream end at an opposing
end of the consumable 150 that comprises a mouthpiece 154 of the system 110.
[0113] When the consumable 150 is received in the cavity of the main body 120 as shown in
Figure 3, a plurality of device air inlets 176 are formed at the boundary between
the casing of the consumable and the casing of the main body. The device air inlets
176 are in fluid communication with the vaporiser inlet 172 through an inlet flow
channel 178 formed in the cavity of the main body which is of corresponding shape
to receive a part of the consumable 150. Air from outside of the system 110 can therefore
be drawn into the passage 170 through the device air inlets 176 and the inlet flow
channels 178.
[0114] When the consumable 150 is engaged with the main body 120, a user can inhale (i.e.
take a puff) via the mouthpiece 154 so as to draw air through the passage 170, and
so as to form an air flow (indicated by the dashed arrows in Figure 19) in a direction
from the vaporiser inlet 172 to the outlet 174. Although not illustrated, the passage
170 may be partially defined by a tube (e.g. a metal tube) extending through the consumable
150. In Figure 19, for simplicity, the passage 170 is shown with a substantially circular
cross-sectional profile with a constant diameter along its length. In other arrangements
and in some embodiments, the passage may have other cross-sectional profiles, such
as oval shaped or polygonal shaped profiles. Further, in other arrangements and some
embodiments, the cross sectional profile and the diameter (or hydraulic diameter)
of the passage may vary along its longitudinal axis.
[0115] The smoking substitute system 110 is configured to vaporise the e-liquid 160 for
inhalation by a user. To provide this operability, the consumable 150 comprises an
aerosol generator in the form of a heater having a porous wick 162 and a resistive
heating element in the form of a heating filament 164 that is helically wound (in
the form of a coil) around a portion of the porous wick 162. The porous wick 162 extends
across the passage 170 (i.e. transverse to a longitudinal axis of the passage 170
and thus also transverse to the air flow along the passage 170 during use) and opposing
ends of the wick 162 extend into the tank 152 (so as to be immersed in the e-liquid
160). In this way, e-liquid 160 contained in the tank 152 is conveyed from the opposing
ends of the porous wick 162 to a central portion of the porous wick 162 so as to be
exposed to the air flow in the passage 170.
[0116] The helical filament 164 is wound about the exposed central portion of the porous
wick 162 and is electrically connected to an electrical interface in the form of electrical
contacts 156 mounted at the end of the consumable that is proximate the main body
120 (when the consumable and the main body are engaged). When the consumable 150 is
engaged with the main body 120, electrical contacts 156 make contact with corresponding
electrical contacts (not shown) of the main body 120. The main body electrical contacts
are electrically connectable to a power source (not shown) of the main body 120, such
that (in the engaged position) the filament 164 is electrically connectable to the
power source. In this way, power can be supplied by the main body 120 to the filament
164 in order to heat the filament 164. This heats the porous wick 162 which causes
e-liquid 160 conveyed by the porous wick 162 to vaporise and thus to be released from
the porous wick 162. The vaporised e-liquid becomes entrained in the air flow and,
as it cools in the air flow (between the heated wick and the outlet 174 of the passage
170), condenses to form an aerosol. This aerosol is then inhaled, via the mouthpiece
154, by a user of the system 110. As e-liquid is lost from the heated portion of the
wick, further e-liquid is drawn along the wick from the tank to replace the e-liquid
lost from the heated portion of the wick.
[0117] The filament 164 and the exposed central portion of the porous wick 162 are positioned
across the passage 170. More specifically, the part of passage that contains the filament
164 and the exposed portion of the porous wick 162 forms an aerosol generation chamber.
In the illustrated example, the aerosol generation chamber has the same cross-sectional
diameter as the passage 170. However, in other embodiments the aerosol generation
chamber may have a different cross sectional profile as the passage 170. For example,
the aerosol generation chamber may have a larger cross sectional diameter than at
least some of the downstream part of the passage 170 so as to enable a longer residence
time for the air inside the aerosol generation chamber.
[0118] Figure 20 illustrates in more detail the aerosol generation chamber of the reference
arrangement as shown in Figure 19 and therefore the region of the consumable 150 around
the wick 162 and filament 164. The helical filament 164 is wound around a central
portion of the porous wick 162. The porous wick extends across passage 170. E-liquid
160 contained within the tank 152 is conveyed as illustrated schematically by arrows
401, i.e. from the tank and towards the central portion of the porous wick 162.
[0119] When the user inhales, air is drawn from through the inlets 176 shown in Figure 19,
along inlet flow channel 178 to aerosol generation chamber inlet 172 and into the
aerosol generation chamber containing porous wick 162. The porous wick 162 extends
substantially transverse to the air flow direction. The air flow passes around the
porous wick, at least a portion of the air flow substantially following the surface
of the porous wick 162. In examples where the porous wick has a cylindrical cross-sectional
profile, the air flow may follow a curved path around an outer periphery of the porous
wick 162.
[0120] At substantially the same time as the air flow passes around the porous wick 162,
the filament 164 is heated so as to vaporise the e-liquid which has been wicked into
the porous wick. The air flow passing around the porous wick 162 picks up this vaporised
e-liquid, and the vapour-containing air flow is drawn in direction 403 further down
passage 170.
[0121] The power source of the main body 120 may be in the form of a battery (e.g. a rechargeable
battery such as a lithium ion battery). The main body 120 may comprise a connector
in the form of e.g. a USB port for recharging this battery. The main body 120 may
also comprise a controller that controls the supply of power from the power source
to the main body electrical contacts (and thus to the filament 164). That is, the
controller may be configured to control a voltage applied across the main body electrical
contacts, and thus the voltage applied across the filament 164. In this way, the filament
164 may only be heated under certain conditions (e.g. during a puff and/or only when
the system is in an active state). In this respect, the main body 120 may include
a puff sensor (not shown) that is configured to detect a puff (i.e. inhalation). The
puff sensor may be operatively connected to the controller so as to be able to provide
a signal, to the controller, which is indicative of a puff state (i.e. puffing or
not puffing). The puff sensor may, for example, be in the form of a pressure sensor
or an acoustic sensor.
[0122] Although not shown, the main body 120 and consumable 150 may comprise a further interface
which may, for example, be in the form of an RFID reader, a barcode or QR code reader.
This interface may be able to identify a characteristic (e.g. a type) of a consumable
150 engaged with the main body 120. In this respect, the consumable 150 may include
any one or more of an RFID chip, a barcode or QR code, or memory within which is an
identifier and which can be interrogated via the interface.
[0123] Figures 21A and 21B respectively illustrates a longitudinal cross sectional view
of a consumable 250 and an enlarged cross sectional view of a junction of the consumable
250 according to the first embodiment of the present disclosure. In Figure 21A, the
consumable 250 is shown attached, at a first end of the consumable 250, to the main
body 120 of Figure 17 and Figure 18. More specifically, the consumable 250 is configured
to engage and disengage with the main body 120 and is interchangeable with the reference
arrangement 150 as shown in Figures 3 and 4. Furthermore, the consumable 250 is configured
to interact with the main body 120 in the same manner as the reference arrangement
150 and the user may operate the consumable 250 in the same manner as the reference
arrangement 150.
[0124] The consumable 250 comprises a housing. The housing comprises an aerosol generation
chamber 280 for generating an aerosol. The housing having a plurality of air inlets
272 defined at the sidewall of the housing. An outlet 274 is defined at a second end
of the consumable 250 that comprises a mouthpiece 254. A pair of passages 270 each
extends between the respective air inlet 272 and the outlet 274 to provide flow passage
for an air flow 412 as a user puffs on the mouthpiece 254. In the illustrated embodiment,
the passages extend from the air inlets 272 towards the first end of the consumable
250 before routing back towards the outlet 274 at the second end of the consumable
250. The path of the air flow 412 is illustrated in Figure 21A and 21B. In other embodiments,
the passage 270 may extend from the air inlets 272 directly to the outlet 274 without
routing towards the first end of consumable 250.
[0125] In contrast with the consumable 150 as shown in Figures 19 and 20, the air flow passages
270 of the consumable 250 is configured to bypass the aerosol generation chamber 280.
Such arrangement allows aerosol precursor to be vaporised in absence of the air flow.
Therefore, the aerosol generation chamber may be considered to be a "stagnant" chamber.
For example, volumetric flowrate of vapour and/or aerosol in the aerosol generation
chamber is configured to be less than 0.1 litre per minute. The vaporised aerosol
precursor may cool and therefore condense to form an aerosol in the aerosol generation
chamber 280, which is subsequently drawn into or entrained with the air flow in passages
270. In addition, a portion of the vaporised aerosol precursor may remain as a vapour
before leaving the aerosol generation chamber 280, and subsequently forms an aerosol
as it is cooled by the cooler air flow in the passages 270. The flow path of the vapour
and/or aerosol 414 is illustrated in Figures 21A and 21B.
[0126] As shown in Figures 21A and 21B, the aerosol generation chamber 280 takes the form
of an open ended container, or a cup, with a chamber outlet 282 opened towards the
outlet 274 of the consumable 250. The chamber outlet 282 serves as the only opening
to the interior of the aerosol generation chamber 280. In the illustrated embodiment,
the chamber outlet 282 is configured to be in fluid communication with junctions 290
at the passages 270 through respective aerosol channels 292. In other words, the aerosol
generation chamber 280 is sealed against air flow except for having the chamber outlet
282 in communication with the passages 270, the chamber outlet 282 permitting, in
use, aerosol generated by the heater to be entrained into an air flow along the passage
270. The junctions 290 merges the aerosol channels 292 with the passages 270 such
that vapour and/or aerosol formed in the aerosol generation chamber 280 may expand
or be drawn into the passages 270 through a junction inlet of respective junctions
290. The aerosol channels form a buffering volume to minimise the amount of air flow
entering the aerosol generation chamber 280. In some other embodiments, the chamber
outlet 282 directly opens towards the junctions 290 at respective passages 270, and
therefore in such embodiments the aerosol channel 292 may be omitted.
[0127] In the illustrated embodiment, the aerosol generation chamber is configured to have
a length of 20mm and a volume of 680mm
3. The aerosol generation chamber is configured to allow aerosol to be expulsed through
the chamber outlet at a rate greater than 0.1 mg/second. In other embodiments the
aerosol generation chamber may be configured to have an internal volume ranging between
68mm
3 to 680mm
3, wherein the length of the aerosol generation chamber may range between 2mm to 20mm.
[0128] As shown in Figures 21A and 21B, a part of each of the passages 270 extends alongside
a portion of the external sidewalls of the aerosol generation chamber 280. The aerosol
generation chamber 280 comprises a heater extending across its width. The heater comprises
a porous wick 262 and a heating filament 264 helically wound around a portion of the
porous wick 162. A tank 252 is provided in the space between the aerosol generation
chamber 280 and the outlet 274 for storing a reservoir of aerosol precursor. Therefore
in contrast with the reference arrangement as shown in Figures 19 and 20, the tank
252 in this embodiment does not substantially surround the aerosol generation chamber
280 nor the passages 270. Instead, as shown in Figure 21A, the tank is substantially
positioned above the aerosol generation chamber 280 and the porous wick 262 when the
consumable 250 is placed in an upright orientation during use. The end portions of
the porous wick 262 extend through the sidewalls of the aerosol generation chamber
280 and into liquid conduits 266 which is in fluid communication with the tank 252.
Such arrangement may allow the aerosol precursor stored in the tank 252 to convey
towards the porous wick 262 through the liquid conduits 266 by gravity. The liquid
conduits 266 are configured to have a hydraulic diameter that allow a controlled amount
of aerosol precursor to flow from the tank 252 towards the porous wick 262. More specifically,
the size of liquid conduits 266 may be selected based on the rate of aerosol precursor
consumption during vaporisation. For example, each of the liquid conduits 266 is sized
such that it allows a sufficient amount of aerosol precursor to flow towards and replenish
the wick, yet not large enough to cause excessive aerosol precursor to leak into the
aerosol generation chamber. The liquid conduits 266 are configured to have a hydraulic
diameter ranging from 0.01mm to 10mm or 0.01mm to 5mm. Preferably, the liquid conduits
266 are configured to have a hydraulic diameter in the range of 0.1mm to 1mm.
[0129] The heating filament is electrically connected to electrical contacts 256 at the
base of the aerosol generation chamber 280, which is sealed to prevent air ingress
or fluid leakage. As shown in Figure 21A, when the first end of the consumable 250
is received into the main body 120, the electrical contacts 256 are put into electrical
communication with corresponding electrical contacts of the main body 120, and thereby
allowing the heater to be energised.
[0130] The vaporised aerosol precursor, or aerosol in the condensed form, may discharge
from the aerosol generation chamber 280 based on pressure difference between the aerosol
generation chamber 280 and the passages 270. Such pressure difference may arise from
i) an increased pressure in the aerosol generation chamber 280 during vaporisation
of aerosol, and/or ii) a reduced pressure in the passages 270 during a puff.
[0131] During a puff, the aerosol generated in the aerosol generation chamber 280 may be
drawn out from the chamber outlet 282 by a region of lowered pressure downstream created
by Venturi effect. As best illustrated in Figure 21B, junctions 290 each comprises
a constriction 294 which formed from a narrowed section of respective passage 270.
The constrictions 294 are configured to have a smaller cross sectional area than the
respective passages 270 upstream, or more specifically immediately upstream, to the
junctions 290. In the illustrated embodiment, the passages 270 further comprise widened
portion 296 immediately upstream of the constrictions 294. Said widened portions 296
are configured to have a larger cross sectional area in comparison to the passages
270 upstream.
[0132] During a user puff, where the user draws an air flow from air inlets 272 towards
the outlet 274, the velocity of the air flow may reduce in the widened portions 296
due to the enlarged cross sectional area thereat. As the air flow continues along
the passages 270 it converges through the constrictions 294 and thereby increases
in velocity. According to Bernoulli's principle, as the air flow increases in speed
through a constriction, it results in a region of localised pressure drop thereat.
As such, as the air flow passes through junctions 290, it may induce additional suction
at the junction inlets for drawing out vapour and/or aerosol from the aerosol generation
chamber towards the air flow. Such phenomena may be referred to as the Venturi effect.
Advantageously, such arrangement allows vapour and/or aerosol to be withdrawn from
the aerosol generation chamber in a more effective manner.
[0133] The junction inlets at junction 290, as shown in Figure 21B, open in a direction
orthogonal to the air flow. That is, the junction inlets open at a sidewall of the
passage. This allows the vapour and/or aerosol from the aerosol generation chamber
280 to entrain into the air flow at an angle, and thus improving localised mixing
of the different streams, as well as encouraging aerosol formation. The aerosol may
be fully formed in the air flow and be drawn out through the outlet at the mouthpiece.
[0134] The illustrated embodiment comprises a widened portions 296 immediately upstream
of the constrictions 294, this may enable the air flow to accelerate from a lowered
velocity and thereby creating a larger localised pressure drop across the constrictions
294. However in other embodiments such widened portions may be omitted, e.g. the passages
270 upstream of the constrictions 294 may each be configured to have a substantially
uniform cross sectional area.
[0135] In some other embodiments, different constrictions 294 may be used. For example,
an orifice plate having an aperture with a smaller cross sectional area than the passage
270 may be provided at or adjacent to the junctions for accelerating the air flow
thereacross. Such orifice plates may advantageously reduce the footprint of the constrictions
294.
[0136] In the illustrated embodiment, the heater is positioned within the aerosol generation
chamber 280, e.g. the heater is spaced from the chamber outlet 282. Such arrangement
may reduce or prevent the amount of air flow entering the aerosol generation chamber,
and therefore it may minimise the amount of turbulence in the vicinity of the heater.
Furthermore, such arrangement may increase the residence time of vapour in the stagnant
aerosol generation chamber 280, and thereby it may result in the formation of larger
aerosol droplets. In some other embodiments, the heater may be positioned adjacent
to the chamber outlet and therefore that the path of aerosol 414 from the heater to
the chamber outlet 282 is shortened. This may allow aerosol to be drawn into or entrained
with the air flow in a more efficient manner.
[0137] With the absence of, or much reduced, air flow in the aerosol generation chamber,
the aerosol as generated by the illustrated embodiment has a median droplet size d
50 of at least 1µm. More preferably, the aerosol as generated by the illustrated embodiment
has an averaged droplet size d
50 of ranged between 2µm to 3µm.
[0138] Figure 22 illustrates a cross sectional view of a flow converging portion 384 of
a consumable 350 according to a second embodiment of the present disclosure. In order
to illustrate the internal structure of the consumable 350 more clearly, the heater
and its electrical connections are not shown but nevertheless present. The consumable
350 comprises air inlets 372 that open at the base of consumable 350. The air inlets
372 lead to the passage 370 that extend alongside the external sidewalls of the aerosol
generation chamber 380 and towards an outlet 374.
[0139] As shown in Figure 22, the passage 370 comprises a flow converging portion 384 downstream
of a chamber outlet 382. The flow converging portion 384 comprises a funnel or a tapered
section for gradually merging the aerosol and the air flow. The flow path of the aerosol
414 and the flow path of the air flow 412 extend concurrently into the flow converging
portion 384 as illustrated in Figure 22. Such an arrangement may help minimising the
turbulence when the two streams are merged and thereby it may allow aerosol to be
formed with larger droplet sizes. The aerosol is discharged, longitudinally along
the flow converging portion 384 and through the outlet 374.
[0140] In the illustrated embodiment, junctions 390 are formed in the passage 370 adjacent
to the chamber outlet 382, and wherein the chamber outlet 382 opens in a direction
parallel to the air flow at said junctions 390. During a user puff, air flow is drawn
into the consumable 350 through the air inlets 372. Since the air flow is drawn from
the atmosphere into the air inlets 372, said air inlets 372 may therefore serve as
a constriction that accelerates the air flow through the passage 370. According to
Bernoulli's principle, such increase in air flow velocity results in a localised pressure
drop in the vicinity of junctions 390. As such the air flow passing through the junction
390 it draws out the aerosol from the aerosol generation chamber 380, whereby the
two streams subsequently form an aerosol in the flow converging portion 384 further
downstream.
[0141] There now follows a disclosure of certain experimental work undertaken to determine
the effects of certain conditions in the smoking substitute apparatus on the particle
size of the generated aerosol.
[0142] The experiments reported here have relevance to the embodiments disclosed above in
particular in view of the "stagnant chamber" configuration used for the vaporisation
chamber, the experiments showing that control over the flow conditions at the wick
lead to control over the particle size of the aerosol.
1. Introduction
[0143] Aerosol droplet size is a considered to be an important characteristic for smoking
substitution devices. Droplets in the range of 2-5 µm are preferred in order to achieve
improved nicotine delivery efficiency and to minimise the hazard of second-hand smoking.
However, at the time of writing (September 2019), commercial EVP devices typically
deliver aerosols with droplet size averaged around 0.5 µm, and to the knowledge of
the inventors not a single commercially available device can deliver an aerosol with
an average particle size exceeding 1 µm.
[0144] The present inventors speculate, without themselves wishing to be bound by theory,
that there has to date been a lack of understanding in the mechanisms of e-liquid
evaporation, nucleation and droplet growth in the context of aerosol generation in
smoking substitute devices. The present inventors have therefore studied these issues
in order to provide insight into mechanisms for the generation of aerosols with larger
particles. The present inventors have carried out experimental and modelling work
alongside theoretical investigations, leading to significant achievements as now reported.
[0145] This disclosure considers the roles of air velocity, air turbulence and vapour cooling
rate in affecting aerosol particle size.
2. Experiments
[0146] In this work, a Malvern PANalytical Spraytec laser diffraction system was employed
for the particle size measurement. In order to limit the number of variables, the
same coil and wick (1.5 ohms Ni-Cr coil, 1.8 mm Y07 cotton wick), the same e-liquid
(1.6% freebase nicotine, 65:35 propylene glycol (PG)/vegetable glycerine (VG) ratio,
no added flavour) and the same input power (10W) were used in all experiments. Y07
represents the grade of cotton wick, meaning that the cotton has a linear density
of 0.7 grams per meter.
[0147] Particle sizes were measured in accordance with ISO 13320:2009(E), which is an international
standard on laser diffraction methods for particle size analysis. This is particularly
well suited to aerosols, because there is an assumption in this standard that the
particles are spherical (which is a good assumption for liquid-based aerosols). The
standard is stated to be suitable for particle sizes in the range 0.1 micron to 3
mm.
[0148] The results presented here concentrate on the volume-based median particle size Dv50.
This is to be taken to be the same as the parameter d
50 used above.
2.1. Rectangular tube testing
[0149] The work reported here based on the inventors' insight that aerosol particle size
might be related to: 1) air velocity; 2) flow rate; and 3) Reynolds number. In a given
EVP device, these three parameters are interlinked to each other, making it difficult
to draw conclusions on the roles of each individual factor. In order to decouple these
factors, experiments were carried out using a set of rectangular tubes having different
dimensions. These were manufactured by 3D printing. The rectangular tubes were 3D
printed in an MJP 2500 3D printer. Figure 1 illustrates the set of rectangular tubes.
Each tube has the same depth and length but different width. Each tube has an integral
end plate in order to provide a seal against air flow outside the tube. Each tube
also has holes formed in opposing side walls in order to accommodate a wick.
[0150] Figure 2 shows a schematic perspective longitudinal cross sectional view of an example
rectangular tube 1170 with a wick 1162 and heater coil 1164 installed. The location
of the wick is about half way along the length of the tube. This is intended to allow
the flow of air along the tube to settle before reaching the wick.
[0151] Figure 3 shows a schematic transverse cross sectional view an example rectangular
tube 1170 with a wick 1162 and heater coil 1164 installed. In this example, the internal
width of the tube is 12 mm
[0152] The rectangular tubes were manufactured to have same internal depth of 6 mm in order
to accommodate the standardized coil and wick, however the tube internal width varied
from 4.5 mm to 50 mm. In this disclosure, the "tube size" is referred to as the internal
width of rectangular tubes.
[0153] The rectangular tubes with different dimensions were used to generate aerosols that
were tested for particle size in a Malvern PANalytical Spraytec laser diffraction
system. An external digital power supply was dialled to 2.6A constant current to supply
10W power to the heater coil in all experiments. Between two runs, the wick was saturated
manually by applying one drop of e-liquid on each side of the wick.
[0154] Three groups of experiments were carried out in this study:
- 1. 1.3 Ipm (litres per minute, L min-1 or LPM) constant flow rate on different size tubes
- 2. 2.0 Ipm constant flow rate on different size tubes
- 3. 1 m/s constant air velocity on 3 tubes: i) 5mm tube at 1.4 Ipm flow rate; ii) 8mm
tube at 2.8 Ipm flow rate; and iii) 20mm tube at 8.6 Ipm flow rate.
[0155] Table 1 shows a list of experiments in this study. The values in "calculated air
velocity" column were obtained by simply dividing the flow rate by the intersection
area at the centre plane of wick. Reynolds numbers (Re) were calculated through the
following equation:

where:
ρ is the density of air (1.225 kg/m
3);
v is the calculated air velocity in table 1;
µ is the viscosity of air (1.48 × 10
-5 m
2/s); L is the characteristic length calculated by:

where:
P is the perimeter of the flow path's intersection, and
A is the area of the flow path's intersection.
Table 1. List of experiments in the rectangular tube study
|
Tube size |
Flow rate |
Reynolds number |
Calculated air velocity |
[mm] |
[lpm] |
[m/s] |
1.3 lpm constant flow rate |
4.5 |
1.3 |
153 |
1.17 |
6 |
1.3 |
142 |
0.71 |
7 |
1.3 |
136 |
0.56 |
8 |
1.3 |
130 |
0.47 |
10 |
1.3 |
120 |
0.35 |
12 |
1.3 |
111 |
0.28 |
20 |
1.3 |
86 |
0.15 |
50 |
1.3 |
47 |
0.06 |
2.0 Ipm constant flow rate |
4.5 |
2.0 |
236 |
1.81 |
5 |
2.0 |
230 |
1.48 |
6 |
2.0 |
219 |
1.09 |
8 |
2.0 |
200 |
0.72 |
12 |
2.0 |
171 |
0.42 |
20 |
2.0 |
132 |
0.23 |
50 |
2.0 |
72 |
0.09 |
1.0 m/s constant air velocity |
5.0 |
1.4 |
155 |
1.00 |
8 |
2.8 |
279 |
1.00 |
20 |
8.6 |
566 |
1.00 |
[0156] Five repetition runs were carried out for each tube size and flow rate combination.
Between adjacent runs there were at least 5 minutes wait time for the Spraytec system
to be purged. In each run, real time particle size distributions were measured in
the Spraytec laser diffraction system at a sampling rate of 2500 per second, the volume
distribution median (Dv50) was averaged over a puff duration of 4 seconds. Measurement
results were averaged and the standard deviations were calculated to indicate errors
as shown in section 4 below.
2.2. Turbulence tube testing
[0157] The Reynolds numbers in Table 1 are all well below 1000, therefore, it is considered
fair to assume all the experiments in section 2.1 would be under conditions of laminar
flow. Further experiments were carried out and reported in this section to investigate
the role of turbulence.
[0158] Turbulence intensity was introduced as a quantitative parameter to assess the level
of turbulence. The definition and simulation of turbulence intensity is discussed
below (see section 3.2).
[0159] Different device designs were considered in order to introduce turbulence. In the
experiments reported here, jetting panels were added in the existing 12mm rectangular
tubes upstream of the wick. This approach enables direct comparison between different
devices as they all have highly similar geometry, with turbulence intensity being
the only variable.
[0160] Figures 4A-4D show air flow streamlines in the four devices used in this turbulence
study. Figure 4A is a standard 12mm rectangular tube with wick and coil installed
as explained in the previous section, with no jetting panel. Figure 4B has a jetting
panel located 10mm below (upstream from) the wick. Figure 4C has the same jetting
panel 5mm below the wick. Figure 4D has the same jetting panel 2.5mm below the wick.
As can be seen from Figures 4B-4D, the jetting panel has an arrangement of apertures
shaped and directed in order to promote jetting from the downstream face of the panel
and therefore to promote turbulent flow. Accordingly, the jetting panel can introduce
turbulence downstream, and the panel causes higher level of turbulence near the wick
when it is positioned closer to the wick. As shown in Figures 4A-4D, the four geometries
gave turbulence intensities of 0.55%, 0.77%, 1.06% and 1.34%, respectively, with Figure
4A being the least turbulent, and Figure 4D being the most turbulent.
[0161] For each of Figures 4A-4D, there are shown three modelling images. The image on the
left shows the original image (colour in the original), the central image shows a
greyscale version of the image and the right hand image shows a black and white version
of the image. As will be appreciated, each version of the image highlights slightly
different features of the flow. Together, they give a reasonable picture of the flow
conditions at the wick.
[0162] These four devices were operated to generate aerosols following the procedure explained
above (section 2.1) using a flow rate of 1.3 Ipm and the generated aerosols were tested
for particle size in the Spraytec laser diffraction system.
2.3. High temperature testing
[0163] This experiment aimed to investigate the influence of inflow air temperature on aerosol
particle size, in order to investigate the effect of vapour cooling rate on aerosol
generation.
[0164] The experimental set up is shown in Figure 5. The testing used a Carbolite Gero EHA
12300B tube furnace 3210 with a quartz tube 3220 to heat up the air. Hot air in the
tube furnace was then led into a transparent housing 3158 that contains the EVP device
3150 to be tested. A thermocouple meter 3410 was used to assess the temperature of
the air pulled into the EVP device. Once the EVP device was activated, the aerosol
was pulled into the Spraytec laser diffraction system 3310 via a silicone connector
3320 for particle size measurement.
[0165] Three smoking substitute apparatuses (referred to as "pods") were tested in the study:
pod 1 is the commercially available "myblu optimised" pod (Figure 6); pod 2 is a pod
featuring an extended inflow path upstream of the wick (Figure 7); and pod 3 is pod
with the wick located in a stagnant vaporisation chamber and the inlet air bypassing
the vaporisation chamber but entraining the vapour from an outlet of the vaporisation
chamber (Figures 8A and 8B).
[0166] Pod 1, shown in longitudinal cross sectional view (in the width plane) in Figure
6, has a main housing that defines a tank 160x holding an e-liquid aerosol precursor.
Mouthpiece 154x is formed at the upper part of the pod. Electrical contacts 156x are
formed at the lower end of the pod. Wick 162x is held in a vaporisation chamber. The
air flow direction is shown using arrows.
[0167] Pod 2, shown in longitudinal cross sectional view (in the width plane) in Figure
7, has a main housing that defines a tank 160y holding an e-liquid aerosol precursor.
Mouthpiece 154y is formed at the upper part of the pod. Electrical contacts 156y are
formed at the lower end of the pod. Wick 162y is held in a vaporisation chamber. The
air flow direction is shown using arrows. Pod 2 has an extended inflow path (plenum
chamber 157y) with a flow conditioning element 159y, configured to promote reduced
turbulence at the wick 162y.
[0168] Figure 8A shows a schematic longitudinal cross sectional view of pod 3. Figure 8B
shows a schematic longitudinal cross sectional view of the same pod 3 in a direction
orthogonal to the view taken in Figure 8A. Pod 3 has a main housing that defines a
tank 160z holding an e-liquid aerosol precursor. Mouthpiece 154z is formed at the
upper part of the pod. Electrical contacts 156z are formed at the lower end of the
pod. Wick 162z is held in a vaporisation chamber. The air flow direction is shown
using arrows. Pod 3 uses a stagnant vaporiser chamber, with the air inlets bypassing
the wick and picking up the vapour/aerosol downstream of the wick.
[0169] All three pods were filled with the same e-liquid (1.6% freebase nicotine, 65:35
PG/VG ratio, no added flavour). Three experiments were carried out for each pod: 1)
standard measurement in ambient temperature; 2) only the inlet air was heated to 50
°C; and 3) both the inlet air and the pods were heated to 50 °C. Five repetition runs
were carried out for each experiment and the Dv50 results were taken and averaged.
3. Modelling work
[0170] In this study, modelling work was performed using COMSOL Multiphysics 5.4, engaged
physics include: 1) laminar single-phase flow; 2) turbulent single-phase flow; 3)
laminar two-phase flow; 4) heat transfer in fluids; and (5) particle tracing. Data
analysis and data visualisation were mostly completed in MATLAB R2019a.
3.1. Velocity modelling
[0171] Air velocity in the vicinity of the wick is believed to play an important role in
affecting particle size. In section 2.1, the air velocity was calculated by dividing
the flow rate by the intersection area, which is referred to as "calculated velocity"
in this work. This involves a very crude simplification that assumes velocity distribution
to be homogeneous across the intersection area.
[0172] In order to increase reliability of the work, computational fluid dynamics (CFD)
modelling was performed to obtain more accurate velocity values:
- 1) The average velocity in the vicinity of the wick (defined as a volume from the
wick surface to 1mm away from the wick surface)
- 2) The maximum velocity in the vicinity of the wick (defined as a volume from the
wick surface to 1mm away from the wick surface)
Table 2. Average and maximum velocity in the vicinity of wick surface obtained from
CFD modelling
|
Tube size |
Flow rate |
Calculated velocity* |
Average velocity** |
Maximum Velocity** |
[mm] |
[lpm] |
[m/s] |
[m/s] |
[m/s] |
1.3 Ipm constant flow rate |
4.5 |
1.3 |
1.17 |
0.99 |
1.80 |
6 |
1.3 |
0.71 |
0.66 |
1.22 |
7 |
1.3 |
0.56 |
0.54 |
1.01 |
8 |
1.3 |
0.47 |
0.46 |
0.86 |
10 |
1.3 |
0.35 |
0.35 |
0.66 |
12 |
1.3 |
0.28 |
0.27 |
0.54 |
20 |
1.3 |
0.15 |
0.15 |
0.32 |
50 |
1.3 |
0.06 |
0.05 |
0.12 |
2.0 Ipm constant flow rate |
4.5 |
2.0 |
1.81 |
1.52 |
2.73 |
5 |
2.0 |
1.48 |
1.31 |
2.39 |
6 |
2.0 |
1.09 |
1.02 |
1.87 |
8 |
2.0 |
0.72 |
0.71 |
1.31 |
12 |
2.0 |
0.42 |
0.44 |
0.83 |
20 |
2.0 |
0.23 |
0.24 |
0.49 |
50 |
2.0 |
0.09 |
0.08 |
0.19 |
* Calculated by dividing flow rate with intersection area |
** Obtained from CFD modelling |
[0173] The CFD model uses a laminar single-phase flow setup. For each experiment, the outlet
was configured to a corresponding flowrate, the inlet was configured to be pressure-controlled,
the wall conditions were set as "no slip". A 1 mm wide ring-shaped domain (wick vicinity)
was created around the wick surface, and domain probes were implemented to assess
the average and maximum magnitudes of velocity in this ring-shaped wick vicinity domain.
[0174] The CFD model outputs the average velocity and maximum velocity in the vicinity of
the wick for each set of experiments carried out in section 2.1. The outcomes are
reported in Table 2.
3.2. Turbulence modelling
[0175] Turbulence intensity (
I) is a quantitative value that represents the level of turbulence in a fluid flow
system. It is defined as the ratio between the root-mean-square of velocity fluctuations,
u', and the Renolds-averaed mean flow velocity
U:

where
ux, uy and
uz are the x-, y- and z-components of the velocity vector,
ux, uy, and
uz represent the average velocities along three directions.
[0176] Higher turbulence intensity values represent higher levels of turbulence. As a rule
of thumb, turbulence intensity below 1% represents a low-turbulence case, turbulence
intensity between 1% and 5% represents a medium-turbulence case, and turbulence intensity
above 5% represents a high-turbulence case.
[0177] In this study, turbulence intensity was obtained from CFD simulation using turbulent
single-phase setup in COMSOL Multiphysics. For each of the four experiments explained
in section 2.2, the outlet was set to 1.3 Ipm, the inlet was set to be pressure-controlled,
and all wall conditions were set to be "no slip".
[0178] Turbulence intensity was assessed within the volume up to 1 mm away from the wick
surface (defined as the wick vicinity domain). For the four experiments explained
in section 2.2, the turbulence intensities are 0.55%, 0.77%, 1.06% and 1.34%, respectively,
as also shown in Figures 4A-4D.
3.3. Cooling rate modelling
[0179] The cooling rate modelling involves three coupling models in COMSOL Multiphysics:
1) laminar two-phase flow; 2) heat transfer in fluids, and 3) particle tracing. The
model is setup in three steps:
1) Set up two phase flow model
[0180] Laminar mixture flow physics was selected in this study. The outlet was configured
in the same way as in section 3.1. However, this model includes two fluid phases released
from two separate inlets: the first one is the vapour released from wick surface,
at an initial velocity of 2.84 cm/s (calculated based on 5 mg total particulate mass
over 3 seconds puff duration) with initial velocity direction normal to the wick surface;
the second inlet is air influx from the base of tube, the rate of which is pressure-controlled.
2) Set up two-way coupling with heat transfer physics
[0181] The inflow and outflow settings in heat transfer physics was configured in the same
way as in the two-phase flow model. The air inflow was set to 25 °C, and the vapour
inflow was set to 209 °C (boiling temperature of the e-liquid formulation). In the
end, the heat transfer physics is configured to be two-way coupled with the laminar
mixture flow physics. The above model reaches steady state after approximately 0.2
second with a step size of 0.001 second.
3) Set up particle tracing
[0182] A wave of 2000 particles were release from wick surface at t = 0.3 second after the
two-phase flow and heat transfer model has stabilised. The particle tracing physics
has one-way coupling with the previous model, which means the fluid flow exerts dragging
force on the particles, whereas the particles do not exert counterforce on the fluid
flow. Therefore, the particles function as moving probes to output vapour temperature
at each timestep.
[0183] The model outputs average vapour temperature at each time steps. A MATLAB script
was then created to find the time step when the vapour cools to a target temperature
(50°C or 75°C), based on which the vapour cooling rates were obtained (Table 3).
Table 3. Average vapour cooling rate obtained from Multiphysics modelling
|
Tube size |
Flow rate |
Cooling rate to 50°C |
Cooling rate to 75°C |
[mm] |
[lpm] |
[°C/ms] |
[°C/ms] |
1.3 Ipm constant flow rate |
4.5 |
1.3 |
11.4 |
44.7 |
6 |
1.3 |
5.48 |
14.9 |
7 |
1.3 |
3.46 |
7.88 |
8 |
1.3 |
2.24 |
5.15 |
10 |
1.3 |
1.31 |
2.85 |
12 |
1.3 |
0.841 |
1.81 |
20 |
1.3 |
0* |
0.536 |
50 |
1.3 |
0 |
0 |
2.0 Ipm constant flow rate |
4.5 |
2.0 |
19.9 |
670 |
5 |
2.0 |
13.3 |
67 |
6 |
2.0 |
8.83 |
26.8 |
8 |
2.0 |
3.61 |
8.93 |
12 |
2.0 |
1.45 |
3.19 |
20 |
2.0 |
0.395 |
0.761 |
50 |
2.0 |
0 |
0 |
* Zero cooling rate when the average vapour temperature is still above target temperature
after 0.5 second |
4. Results and discussions
[0184] Particle size measurement results for the rectangular tube testing are shown in Table
4. For every tube size and flow rate combination, five repetition runs were carried
out in the Spraytec laser diffraction system. The Dv50 values from five repetition
runs were averaged, and the standard deviations were calculated to indicate errors,
as shown in Table 4.
[0185] In this section, the roles of different factors affecting aerosol particle size will
be discussed based on experimental and modelling results.
Table 4. Particle size measurement results for the rectangular tube testing
|
Tube size |
Flow rate |
Dv50 average |
Dv50 standard deviation |
[mm] |
[lpm] |
[µm] |
[µm] |
1.3 Ipm constant flow rate |
4.5 |
1.3 |
0.971 |
0.125 |
6 |
1.3 |
1.697 |
0.341 |
7 |
1.3 |
2.570 |
0.237 |
8 |
1.3 |
2.705 |
0.207 |
10 |
1.3 |
2.783 |
0.184 |
12 |
1.3 |
3.051 |
0.325 |
20 |
1.3 |
3.116 |
0.354 |
50 |
1.3 |
3.161 |
0.157 |
2.0 Ipm constant flow rate |
4.5 |
2.0 |
0.568 |
0.039 |
5 |
2.0 |
0.967 |
0.315 |
6 |
2.0 |
1.541 |
0.272 |
8 |
2.0 |
1.646 |
0.363 |
12 |
2.0 |
3.062 |
0.153 |
20 |
2.0 |
3.566 |
0.260 |
50 |
2.0 |
3.082 |
0.440 |
1.0 m/s constant air velocity |
5.0 |
1.4 |
1.302 |
0.187 |
8 |
2.8 |
1.303 |
0.468 |
20 |
8.6 |
1.463 |
0.413 |
4.1. Decouple the factors affecting particle size
[0186] The particle size (Dv50) experimental results are plotted against calculated air
velocity in Figure 9. The graph shows a strong correlation between particle size and
air velocity.
[0187] Different size tubes were tested at two flow rates: 1.3 Ipm and 2.0 Ipm. Both groups
of data show the same trend that slower air velocity leads to larger particle size.
The conclusion was made more convincing by the fact that these two groups of data
overlap well in Figure 9: for example, the 6mm tube delivered an average Dv50 of 1.697
µm when tested at 1.3 Ipm flow rate, and the 8mm tube delivered a highly similar average
Dv50 of 1.646 µm when tested at 2.0 Ipm flow rate, as they have similar air velocity
of 0.71 and 0.72 m/s, respectively.
[0188] In addition, Figure 10 shows the results of three experiments with highly different
setup arrangements: 1) 5mm tube measured at 1.4 Ipm flow rate with Reynolds number
of 155; 2) 8mm tube measured at 2.8 lpm flow rate with Reynolds number of 279; and
3) 20mm tube measured at 8.6 Ipm flow rate with Reynolds number of 566. It is relevant
that these setup arrangements have one similarity: the air velocities are all calculated
to be 1 m/s. Figure 10 shows that, although these three sets of experiments have different
tube sizes, flow rates and Reynolds numbers, they all delivered similar particle sizes,
as the air velocity was kept constant. These three data points were also plotted out
in Figure 9 (1 m/s data with star marks) and they tie in nicely into particle size-air
velocity trendline.
[0189] The above results lead to a strong conclusion that air velocity is an important factor
affecting the particle size of EVP devices. Relatively large particles are generated
when the air travels with slower velocity around the wick. It can also be concluded
that flow rate, tube size and Reynolds number are not necessarily independently relevant
to particle size, providing the air velocity is controlled in the vicinity of the
wick.
4.2. Further consideration of velocity
[0190] In Figure 9 the "calculated velocity" was obtained by dividing the flow rate by the
intersection area, which is a crude simplification that assumes a uniform velocity
field. In order to increase reliability of the work, CFD modelling has been performed
to assess the average and maximum velocities in the vicinity of the wick. In this
study, the "vicinity" was defined as a volume from the wick surface up to 1 mm away
from the wick surface.
[0191] The particle size measurement data were plotted against the average velocity (Figure
11) and maximum velocity (Figure 12) in the vicinity of the wick, as obtained from
CFD modelling.
[0192] The data in these two graphs indicates that in order to obtain an aerosol with Dv50
larger than 1 µm, the average velocity should be less than or equal to 1.2 m/s in
the vicinity of the wick and the maximum velocity should be less than or equal to
2.0 m/s in the vicinity of the wick.
[0193] Furthermore, in order to obtain an aerosol with Dv50 of 2 µm or larger, the average
velocity should be less than or equal to 0.6 m/s in the vicinity of the wick and the
maximum velocity should be less than or equal to 1.2 m/s in the vicinity of the wick.
[0194] It is considered that typical commercial EVP devices deliver aerosols with Dv50 around
0.5 µm, and there is no commercially available device that can deliver aerosol with
Dv50 exceeding 1 µm. It is considered that typical commercial EVP devices have average
velocity of 1.5-2.0 m/s in the vicinity of the wick.
4.3. The role of turbulence
[0195] The role of turbulence has been investigated in terms of turbulence intensity, which
is a quantitative characteristic that indicates the level of turbulence. In this work,
four tubes of different turbulence intensities were used to general aerosols which
were measured in the Spraytec laser diffraction system. The particle size (Dv50) experimental
results are plotted against turbulence intensity in Figure 13.
[0196] The graph suggests a correlation between particle size and turbulence intensity,
that lower turbulence intensity is beneficial for obtaining larger particle size.
It is noted that when turbulence intensity is above 1% (medium-turbulence case), there
are relatively large measurement fluctuations. In Figure 13, the tube with a jetting
panel 10mm below the wick has the largest error bar, because air jets become unpredictable
near the wick after traveling through a long distance.
[0197] The results clearly indicate that laminar air flow is favourable for the generation
of aerosols with larger particles, and that the generation of large particle sizes
is jeopardised by introducing turbulence. In Figure 13, the 12mm standard rectangular
tube (without jetting panel) delivers above 3 µm particle size (Dv50). The particle
size values reduced by at least a half when jetting panels were added to introduce
turbulence.
4.4. Vapour cooling rate
[0198] Figure 14 shows the high temperature testing results. Larger particle sizes were
observed from all 3 pods when the temperature of inlet air increased from room temperature
(23°C) to 50 °C. When the pods were heated as well, two of the three pods saw even
larger particle size measurement results, while pod 2 was unable to be measured due
to significant amount of leakage.
[0199] Without wishing to be bound by theory, the results are in line with the inventors'
insight that control over the vapour cooling rate provides an important degree of
control over the particle size of the aerosol. As reported above, the use of a slow
air velocity can have the result of the formation of an aerosol with large Dv50. It
is considered that this is due to slower air velocity allowing a slower cooling rate
of the vapour.
[0200] Another conclusion related to laminar flow can also be explained by a cooling rate
theory: laminar flow allows slow and gradual mixing between cold air and hot vapour,
which means the vapour can cool down in slower rate when the airflow is laminar, resulting
in larger particle size.
[0201] The results in Figure 14 further validate this cooling rate theory: when the inlet
air has higher temperature, the temperature difference between hot vapour and cold
air becomes smaller, which allows the vapour to cool down at a slower rate, resulting
in larger particle size; when the pods were heated as well, this mechanism was exaggerated
even more, leading to an even slower cooling rate and an even larger particle size.
4.5. Further consideration of vapour cooling rate
[0202] In section 3.3, the vapour cooling rates for each tube size and flow rate combination
were obtained via multiphysics simulation. In Figure 15 and Figure 16, the particle
size measurement results were plotted against vapour cooling rate to 50°C and 75°C,
respectively.
[0203] The data in these graphs indicates that in order to obtain an aerosol with Dv50 larger
than 1 µm, the apparatus should be operable to require more than 16 ms for the vapour
to cool to 50°C, or an equivalent (simplified to an assumed linear) cooling rate being
slower than 10 °C/ms. From an alternative viewpoint, in order to obtain an aerosol
with Dv50 larger than 1 µm, the apparatus should be operable to require more than
4.5 ms for the vapour to cool to 75°C, or an equivalent (simplified to an assumed
linear) cooling rate slower than 30 °C/ms.
[0204] Furthermore, in order to obtain an aerosol with Dv50 of 2 µm or larger, the apparatus
should be operable to require more than 32 ms for the vapour to cool to 50°C, or an
equivalent (simplified to an assumed linear) cooling rate being slower than 5 °C/ms.
From an alternative viewpoint, in order to obtain an aerosol with Dv50 of 2 µm or
larger, the apparatus should be operable to require more than 13 ms for the vapour
to cool to 75°C, or an equivalent (simplified to an assumed linear) cooling rate slower
than 10 °C/ms.
5. Conclusions of particle size experimental work
[0205] In this work, particle size (Dv50) of aerosols generated in a set of rectangular
tubes was studied in order to decouple different factors (flow rate, air velocity,
Reynolds number, tube size) affecting aerosol particle size. It is considered that
air velocity is an important factor affecting particle size - slower air velocity
leads to larger particle size. When air velocity was kept constant, the other factors
(flow rate, Reynolds number, tube size) has low influence on particle size.
[0206] The role of turbulence was also investigated. It is considered that laminar air flow
favours generation of large particles, and introducing turbulence deteriorates (reduces)
the particle size.
[0207] Modelling methods were used to simulate the average air velocity, the maximum air
velocity, and the turbulence intensity in the vicinity of the wick. A COMSOL model
with three coupled physics has also been developed to obtain the vapour cooling rate.
[0208] All experimental and modelling results support a cooling rate theory that slower
vapour cooling rate is a significant factor in ensuring larger particle size. Slower
air velocity, laminar air flow and higher inlet air temperature lead to larger particle
size, because they all allow vapour to cool down at slower rates.
[0209] The features disclosed in the foregoing description, or in the following claims,
or in the accompanying drawings, expressed in their specific forms or in terms of
a means for performing the disclosed function, or a method or process for obtaining
the disclosed results, as appropriate, may, separately, or in any combination of such
features, be utilised for realising the invention in diverse forms thereof.
[0210] While the invention has been described in conjunction with the exemplary embodiments
described above, many equivalent modifications and variations will be apparent to
those skilled in the art when given this disclosure. Accordingly, the exemplary embodiments
of the invention set forth above are considered to be illustrative and not limiting.
Various changes to the described embodiments may be made without departing from the
spirit and scope of the invention.
[0211] For the avoidance of any doubt, any theoretical explanations provided herein are
provided for the purposes of improving the understanding of a reader. The inventors
do not wish to be bound by any of these theoretical explanations.
[0212] Any section headings used herein are for organizational purposes only and are not
to be construed as limiting the subject matter described.
[0213] Throughout this specification, including the claims which follow, unless the context
requires otherwise, the words "have", "comprise", and "include", and variations such
as "having", "comprises", "comprising", and "including" will be understood to imply
the inclusion of a stated integer or step or group of integers or steps but not the
exclusion of any other integer or step or group of integers or steps.
[0214] It must be noted that, as used in the specification and the appended claims, the
singular forms "a," "an," and "the" include plural referents unless the context clearly
dictates otherwise. Ranges may be expressed herein as from "about" one particular
value, and/or to "about" another particular value. When such a range is expressed,
another embodiment includes from the one particular value and/or to the other particular
value. Similarly, when values are expressed as approximations, by the use of the antecedent
"about," it will be understood that the particular value forms another embodiment.
The term "about" in relation to a numerical value is optional and means, for example,
+/- 10%.
[0215] The words "preferred" and "preferably" are used herein refer to embodiments of the
invention that may provide certain benefits under some circumstances. It is to be
appreciated, however, that other embodiments may also be preferred under the same
or different circumstances. The recitation of one or more preferred embodiments therefore
does not mean or imply that other embodiments are not useful, and is not intended
to exclude other embodiments from the scope of the disclosure, or from the scope of
the claims.