| (19) |
 |
|
(11) |
EP 3 950 369 A1 |
| (12) |
EUROPEAN PATENT APPLICATION |
| (43) |
Date of publication: |
|
09.02.2022 Bulletin 2022/06 |
| (22) |
Date of filing: 04.08.2020 |
|
| (51) |
International Patent Classification (IPC):
|
|
| (84) |
Designated Contracting States: |
|
AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL
NO PL PT RO RS SE SI SK SM TR |
|
Designated Extension States: |
|
BA ME |
|
Designated Validation States: |
|
KH MA MD TN |
| (71) |
Applicant: Profile Vox Spolka z orgraniczona
odpowiedzialnoscia Sp. K. |
|
62-004 Czerwonak (PL) |
|
| (72) |
Inventor: |
|
- Voelkel, Piotr Wit
60-638 Poznan (PL)
|
|
| |
|
| (54) |
METHOD OF SURFACE TREATMENT OF A POLYMER WALL OR FACADE PANEL WITH DIGITAL PRINT |
(57) Method of surface treatment of a polymer wall or facade panel with digital print,
in which in the first step the surface of an extruded wall or facade panel made of
polymer material is cleaned mechanically and then with organic solvent or a mixture
of organic solvents - particularly hydrocarbons, alcohols, ketones, esters with boiling
temperatures in the range of 50 - 140°C, preferably 70 - 100°C, preferably based on
ethyl acetate, butyl acetate, ethanol, isopropanol and/or methyl ethyl ketone - following
which, after evaporation of volatile compounds from the panel surface, the panel is
subject to deionization and afterwards a layer of primer based on polymer resins is
applied - preferably acrylic, with photoinitiators, in the amount of 5 - 30 g/m2,
preferably 10 - 20 g/m2; next, the primer is cured with mercury, gallium or iron lamps
with a power of 80 - 140 W/cm, preferably 100-120 W/cm, for no more than 3 s; then,
digital print is applied on the panel prepared in this manner, with the use of industrial
oilbased inks or UV-cured inks containing organic and/or inorganic pigments, and protective
varnish based on polymer resins is applied - preferably acrylic, with photoinitiators
- in the amount of 5 - 30 g/m2, preferably 10 - 20 g/m2; finally, the protective varnish
layer is cured with mercury, gallium or iron lamps with a power of 80 - 140 W/cm,
preferably 100-120 W/cm, for no more than 3 s.
[0001] The subject of the invention is surface treatment of a polymer wall or facade panel
with digital print.
[0002] In the field of applying decorative prints to polymer panels - in particular wall
panels - the most widely used technology is direct printing. However, more and more
often this technology is being substituted by digital printing. Technology-wise, digital
printing is more flexible, allowing for unrestricted customization of decorative patterns
and production of small quantities, also taking into account economic aspects of manufacturing.
[0003] Various methods are currently known for producing panels with decorative prints.
Decorative material that comprises: a substrate; a print layer provided on the substrate;
a protective layer provided on the print layer is known from the American description
US2003113520 (A1), where the protective layer comprises an ionizing radiation-cured resin; and a primer
layer provided between the print layer and the protective layer, for relaxing shrinkage
stress caused at the time of curing of an ionizing radiation-curable resin for the
formation of the ionizing radiation-cured resin constituting the protective layer.
[0004] A method of applying decorative inkjet prints to the surface of base materials is
known from the Japanese description
JP2008265229, where the print is applied to a layer of flexible resin and then covered with a
hard protective layer.
[0005] A method of coating a building panel with a UV curable layer using a digital print
head is known from the patent description
WO2014011110 (A1), where the surface is cured afterwards to form a transparent protective surface
layer.
[0006] A method of producing building panels is known from another description -
US2014144583 (A1) - where digital print is applied in a separate production cycle to a media layer
(e.g. film) and then heat and pressure is applied to form a panel with a protective
layer.
[0007] A method of producing a substrate for directly printed decorative panels is known
from description
WO2016124433, where several layers of resin compositions - consisting of melamine resin and urea
resin - are applied to the panel, following which the panel is dried.
[0008] The description
US2016303867 discloses a method of producing a decorative outer layer by which digital print is
applied directly to the panel and before the print is applied the panel surface is
primed or sanded.
[0009] In digital printing, the most important problem is the pre-treatment of the panel
core. This is due to the fact that the basic problem of printing on PVC profiles or
panels using pigmented acrylic resin-based inks is the very low porosity of plastic
surfaces, which leads to virtually negligible ink penetration into the substrate.
Another important problem is the issue of inadequate surface tension of inks and varnishes
as well as low free surface energy of the panel, resulting in the lack of satisfactory
print resolution. The essence of the inventive work was to find an optimum solution
for permanent connection of the printed layer with the printed surface. This effect
was achieved by using the right composition of the primer and adjusting the process
to the requirements of its use.
[0010] The essence of the invention is the method of surface treatment of a polymer wall
or facade panel with digital print. In the first step the surface of an extruded polymer
wall or facade panel is cleaned mechanically - for example with brushes or air stream
- and afterwards with organic solvent or a mixture of organic solvents (hydrocarbons,
alcohols, ketones, esters) with boiling temperatures in the range of 50 - 140 °C,
preferably 70 - 100 °C, preferably based on ethyl acetate, butyl acetate, ethanol,
isopropanol and/or methyl ethyl ketone. The aim is to clean the surface from dirt
generated during the production process, e.g. waxes, lubricants. After evaporation
of volatile compounds from the surface of the profile, electric charges are removed
with the use of deionization strips and afterwards a layer of primer based on polymer
resins is applied - preferably acrylic, with photoinitiators - in the amount of 5
- 30 g/m2, preferably 10 - 20 g/m2. The primer is cured with mercury, gallium or iron
lamps with a power of 80 - 140 W/cm, preferably 100-120 W/cm, for no more than 3 s.
Next, digital print is applied to such a surface using industrial oil-based inks or
UV-cured inks containing organic and/or inorganic pigments. Varnish based on polymer
resins - preferably acrylic resins, with photoinitiators - is then applied to the
printed surface in the amount of 5 - 30 g/m2, preferably 10 - 20 g/m2. The protective
varnish layer is cured with mercury, gallium or iron lamps with a power of 80 -140
W/cm, preferably 100-120 W/cm, for no more than 3 s.
[0011] The invention is illustrated by the following embodiment. The surface of an extruded
polymer wall panel was cleaned mechanically with brushes and pressured air, followed
by a mixture of solvents based on butyl and ethyl acetate with a boiling temperature
of 85°C. Next, electrical charges were removed from the cleaned surface using deionization
strips.
[0012] Digital print was then applied using UV-cured inks containing organic and inorganic
pigments. Afterwards, acrylic resin-based varnish with photoinitiators was applied
- 10g/m2, alternatively 15g/m2. Then, the ink layer was UV-cured with 120W/cm mercury
lamps. Exposure to the rays lasted for 3 seconds.
[0013] The product created according to the invention can be used in any room, both indoors
and outdoors. It is characterized by reduced weight compared with competitive products
(e.g. ceramic tiles). The panel is resistant to impacts and other mechanical damage,
and improves acoustic insulation properties of a given room. Moreover, such panels
are moisture and water resistant. The digital printer used in the process has a modular
structure that allows an image of any size to be arranged either vertically or horizontally.
The print can be applied on textured surfaces. The materials to be printed (patterns)
are submitted to the printing device as digital data. This ensures precise control
of coating thickness and allows for printing high-resolution colour graphics from
320 dpi, using CMYK colour modules.
1. Method of method of surface treatment of a polymer wall or facade panel with digital
print characterized in that the surface of an extruded wall or facade panel made of polymer material is cleaned
mechanically and then with organic solvent or a mixture of organic solvents - particularly
hydrocarbons, alcohols, ketones, esters with boiling temperatures in the range of
50 - 140°C, preferably 70 - 100°C, preferably based on ethyl acetate, butyl acetate,
ethanol, isopropanol and/or methyl ethyl ketone - following which, after evaporation
of volatile compounds from the panel surface, the panel is subject to deionization
and afterwards a layer of primer based on polymer resins is applied - preferably acrylic,
with photoinitiators, in the amount of 5 - 30 g/m2, preferably 10 - 20 g/m2; next,
the primer is cured with mercury, gallium or iron lamps with a power of 80 - 140 W/cm,
preferably 100-120 W/cm, for no more than 3 s; then, digital print is applied on the
panel prepared in this manner, with the use of industrial oil-based inks or UV-cured
inks containing organic and/or inorganic pigments, and protective varnish based on
polymer resins is applied - preferably acrylic, with photoinitiators - in the amount
of 5 - 30 g/m2, preferably 10 - 20 g/m2; finally, the protective varnish layer is
cured with mercury, gallium or iron lamps with a power of 80 - 140 W/cm, preferably
100-120 W/cm, for no more than 3 s.


REFERENCES CITED IN THE DESCRIPTION
This list of references cited by the applicant is for the reader's convenience only.
It does not form part of the European patent document. Even though great care has
been taken in compiling the references, errors or omissions cannot be excluded and
the EPO disclaims all liability in this regard.
Patent documents cited in the description