| (19) |
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(11) |
EP 4 259 997 B1 |
| (12) |
EUROPEAN PATENT SPECIFICATION |
| (45) |
Mention of the grant of the patent: |
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06.11.2024 Bulletin 2024/45 |
| (22) |
Date of filing: 07.12.2021 |
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International Patent Classification (IPC):
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Cooperative Patent Classification (CPC): |
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F41H 3/02 |
| (86) |
International application number: |
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PCT/EP2021/084634 |
| (87) |
International publication number: |
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WO 2022/122753 (16.06.2022 Gazette 2022/24) |
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MULTILAYER ULTRATHIN AND FLEXIBLE UNIT HEATER CELLS FOR INFRARED STEALTH
MEHRSCHICHTIGE, ULTRADÜNNE UND FLEXIBLE HEIZUNGSEINHEITSZELLEN FÜR INFRAROT-STEALTH
CELLULES D'UNITÉ DE CHAUFFAGE MULTICOUCHE ULTRA MINCE ET SOUPLE POUR CAMOUFLAGE INFRAROUGE
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Designated Contracting States: |
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AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL
NO PL PT RO RS SE SI SK SM TR |
| (30) |
Priority: |
10.12.2020 EP 20213140
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| (43) |
Date of publication of application: |
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18.10.2023 Bulletin 2023/42 |
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Proprietor: Centre de Recherches Métallurgiques ASBL -
Centrum voor Research in de Metallurgie VZW |
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1000 Bruxelles (BE) |
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Inventors: |
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- GILON, Louis
4800 VERVIERS (BE)
- GUAINO, Philippe
4000 LIEGE (BE)
- FORTERRE, Jules
4000 LIEGE (BE)
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| (74) |
Representative: AWA Benelux |
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Parc d'affaires Zénobe Gramme - Bât. K
Square des Conduites d'Eau 1-2 4020 Liège 4020 Liège (BE) |
| (56) |
References cited: :
WO-A1-2012/169954 CN-A- 110 398 180 US-B1- 7 102 814
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WO-A1-2015/005852 US-A1- 2010 288 116
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| Note: Within nine months from the publication of the mention of the grant of the European
patent, any person may give notice to the European Patent Office of opposition to
the European patent
granted. Notice of opposition shall be filed in a written reasoned statement. It shall
not be deemed to
have been filed until the opposition fee has been paid. (Art. 99(1) European Patent
Convention).
|
Field of the Invention
[0001] The present invention relates to a multilayer, ultra-thin and flexible system of
unit heater cells, obtained by printed electronic technology, for infrared (IR) stealth.
[0002] The invention could also be used in applications in fields like aeronautics or automotive
industry, for providing customized heating parts regarding localized areas, such as
for example in defrost applications.
Background and Prior Art
[0003] In the context of current military conflicts, and mainly asymmetric conflicts, the
protection of troops and equipment is essential. Military strategies in mission theatres
are also permanently in evolution, mainly due to the emergence of increasingly efficient
and sophisticated technologies. This essential aspect of protection for the troops
is now reinforced by calls for proposals of the European Defence Industrial Development
Programme (EDIDP).
[0004] On the ground, the main objective in terms of protection and therefore stealth is,
according to danger order :
- not to be seen at long distance (12-20 km) ;
- not to be recognized, with change of signature occurring at medium distance (4-12
km) ;
- not to be identified, with possible use of decoy system (<4 km).
[0005] Day or night, a widely used means of detection remains infrared thermography, which
enables to perceive the thermal signature of a soldier, (armoured) vehicle, etc.
[0006] The idea at the basis of the present invention is therefore to be able to couple
both camouflage in the visible while being stealthy in the infrared, either by blending
into the environment (i.e. becoming "invisible") or by adjusting the thermal signature
to dupe the enemy.
[0007] Document
US 8,077,071 B2 (or
US 2010/0288116 A1) discloses a number of systems and assemblies for simultaneous adaptive camouflage,
concealment and deception. The assemblies that can be used in the systems include
a vinyl substrate layer and a miniaturized thermoelectric device array secured to
the vinyl substrate layer. The miniaturized thermoelectric device array is configured
to provide an adaptive thermal signature to a side of the miniaturized thermoelectric
device array that faces outward from the vinyl substrate layer. A flexible image display
matrix can be secured on the vinyl substrate layer, said flexible image display matrix
being configured to display visual images. A laminate layer can be secured over the
vinyl substrate layer covering the flexible image display matrix and the miniaturized
thermoelectric device array to provide protection and strengthen the assemblies. One
or more nanomaterials can be disposed on the vinyl substrate layer or the laminate
layer to provide thermal or radar suppression. This disclosure seems to be only a
concept, a suggestion for combining a succession of new technologies not yet turned
into practice, which would be expensive and lacking flexibility.
[0008] Document
WO 2009/040823 A2 relates to a thermal vision countermeasure system to enable concealment of objects
from identification by thermal imaging night vision systems, including a screen made
of thermoelectric (Peltier effect) modules, disposed between the target object and
an IR detector. The screen, formed of a number of thermoelectric units, is coupled
to the target object, and the thermoelectric unit includes a thermoelectric cooler
(TEC) module coupled to a plate formed of a material selected from aluminium, copper,
or aluminium with copper, the plate being substantially larger than the TEC module.
This technology allows full coverage with interchangeable and bee structure modules,
providing IR cartography and radar stealth. However this solution is complex, expensive
to develop, provides poor cartography resolution and does not allow visible dissimulation.
[0009] Document
WO 2012/169958 A1 discloses a device for signature adaptation, comprising at least one surface element
arranged to assume a determined thermal distribution, wherein said surface element
comprises at least one temperature generating element arranged to generate a predetermined
temperature gradient to a portion of said surface element. The surface element also
comprises at least one radar suppressing element, wherein said radar suppressing element
is arranged to suppress reflections of incident radio waves. The invention also concerns
an object provided with a device for signature adaptation. A full coverage is obtained
thanks to interchangeable and honeycomb-like hexagonal unitary panels structure, with
good spatial resolution. However, this solution is complex, expensive to develop,
not easy to attach on site and does not provide visible dissimulation (not embedded).
[0010] Document
US 9,777,998 B1 discloses a device provided for camouflaging an object from an infrared detection
apparatus. The device includes a cloak positionable between the object and the infrared
detection apparatus. The cloak includes a layer of infrared absorptive material including
a plurality of silicon nanowires. A flexible substrate has a first surface operatively
connected to an inner surface of the layer. The substrate includes a heat dissipation
arrangement for dissipating heat generated by the cloak during operation. An array
of infrared emitters is operatively connected to a second surface of the substrate.
The array of infrared emitters selectively radiates an infrared pattern to disguise
the object to the infrared detection apparatus. The heat dissipation arrangement includes
a channel formed in the flexible substrate and adapted for receiving a cooling fluid
therein. The heat dissipation arrangement further includes a pump for recirculating
the cooling fluid through the channel. Each IR emitter is electrically connected to
a corresponding contact by a corresponding line, each contact is operatively connected
to a processing unit, e.g. a controller. The controller is configured to selectively
actuate each IR emitter such that each actuated IR emitter transmits an infrared signal
that is visible to IR reader. This disclosure is very conceptual and poor in details.
[0011] Document
FR 2 733 311 A1 discloses a fibre optics network having a grid of fibre optic cables with a section
having the sleeve removed and fed from an input point. Different infrared bands are
generated and radiated from one of the optical lines. The system measures the background
radiance in the different infrared bands and sets the radiated levels to provide camouflage.
The optical cables are embedded in a flexible outer section.
[0012] Document
CN 110058428 A relates to a carbon material based double-sided active infrared emissivity adjustment
thin film, in particular to a thin film material based on a carbon material (including
graphene, carbon nanotubes, amorphous carbon, carbon black and the like) and ionic
liquid. A flexible device with double-sided infrared radiation control can be realized
through a voltage regulation mode, with low working voltage and power consumption,
large emissivity adjusting amplitude and simple structure. The adjustment thin film
is suitable for large-scale production, has good mechanical bending performance, can
be widely applied to infrared camouflage or stealth on the surfaces of automobiles,
ships, airplanes, satellites and the like, and can also be applied to the surfaces
of batteries, micro-nano satellites and the like to realize temperature control.
[0013] Lin Xiao et al., in Fast Adaptive Thermal Camouflage Based on Flexible VO2/Graphene/
CNT Thin Films, Nano Lett. 2015, 15, 8365-8370 (Am. Chem. Soc.), demonstrate an active cloaking device capable of efficient thermal radiance control,
which consists of a vanadium dioxide (VO
2) layer, with a negative differential thermal emissivity, coated on a graphene/carbon
nanotube (CNT) thin film. A slight joule heating drastically changes the emissivity
of the device, achieving rapid switchable thermal camouflage with a low power consumption
and excellent reliability. This device is intended to find wide applications not only
in artificial systems for infrared camouflage or cloaking but also in energy-saving
smart windows and thermo-optical modulators.
[0014] Prior art IR stealth solutions generally present the following drawbacks:
- they are expensive ;
- they have a lack of flexibility in respect of on-site fixing or repair;
- they do not satisfy existing visible and aesthetic constraints ;
- they usually have a heavy and/or cumbersome design.
Aims of the Invention
[0015] The present invention aims to provide an efficient active IR stealth system, which
is inexpensive, light and not bulky as well.
[0016] Another goal of the invention is to provide a flexible, easy-to-attach, embedded,
customizable in terms of shape and/or pattern and object-matching solution.
[0017] Furthermore, the invention is intended to provide a spatial IR mapping with suitable
resolution.
Summary of the Invention
[0018] The above aims of the invention are solved by an ultrathin, multilayer and encapsulated
surface element according to claim 1 as well as the use of one or more surface elements
according to claim 18.
[0019] A first aspect of the present invention relates to an ultrathin multilayer and encapsulated
surface element for providing thermal signature adaptation with the purpose of infrared
stealthing, and being also suited for camouflage in the visible, the element being
flexible and comprising :
- a lower layer made of an insulation substrate ;
- an intermediate layer comprising a plurality of conductive tracks connectable to a
power supply ;
- a plurality of active heat dissipation elements connected to the conductive tracks
in the intermediate layer and capable to irreversibly provide a temperature increase
by Joule effect in a given time interval when a current is fed into said heat dissipation
elements, wherein each dissipation element comprises an electric conductive path extending
between a first connexion and a second connection connecting respectively said dissipation
element to least two of the conductive tracks, said dissipation element being capable
of providing the temperature increase throughout said path from the first connection
to the second connection when the current is fed, the heat dissipation elements and
the conductive tracks being printed on the insulation substrate ;
- an upper layer made of a protective layer;
the heat dissipation elements having a size and being organized according to a spatial
arrangement so as to provide a predetermined infrared spatial resolution, when a current
is fed into said dissipation elements.
[0020] According to preferred embodiments, the surface element additionally comprises one
or a suitable combination of the following features :
- the spatial arrangement is a two-dimensional array of cells or pixels comprising heat
dissipation elements regularly spaced in two orthogonal directions, each cell or pixel
being independently connectable to the power supply via the conductive tracks ;
- the spatial arrangement is a two-dimensional array of cells or pixels comprising heat
dissipation elements regularly spaced in two orthogonal directions, each cell or pixel
being connectable in a multiplexed manner to the power supply via the conductive tracks
;
- the heat dissipation elements are made of carbon containing material, PTC ferroelectric
material or any resistive material having a resistance higher than the resistance
of the conductive tracks ;
- the carbon-containing heat dissipation elements are made of carbon black, amorphous
carbon, graphite, graphene nanoplatelets or carbon nanotubes ;
- the resistive material having a resistance higher than the conductive tracks is made
of tungsten, a metallic alloy such as nichrome (NiCr), a transparent conducting oxide
(TCO) film material such as aluminium-doped zinc oxide (AZO) or indium tin oxide (ITO),
or a transparent conducting polymer such as Poly(3,4-ethylenedioxythiophene) PEDOT:
poly(styrene sulfonate) PSS ;
- the conductive tracks are made of silver, gold, copper, aluminium or zinc ;
- the heat dissipation elements and the conductive tracks attachment to the substrate
is obtained by inkjet, screen printing or serigraphy, flexography or sintering or
other printing electronic deposition methods, possibly combined with heating or radiation
such as oven, IPL, IR, UV, laser, and in particular 3D printing electronic deposition
methods, such as spray with stencil, micro spray, 3D inkjet or ink dispensing ;
- the insulation substrate is made of a glass plate or of a polyimide film ;
- each cell comprises a module of conductive tracks having an input electrode and an
output electrode, said input electrode and said output electrode having the form of
interdigitated combs, and comprising an array of heat dissipation elements having
the form of studs connected between the respective teeth of the interdigitated combs
;
- each cell or pixel is obtained by firstly printing the module of conductive tracks
on the insulation substrate and secondly printing the array of heat dissipation elements
onto both insulation substrate and module of conductive tracks, so that the heat dissipation
elements are brought into close electrical contact with the module of conductive tracks
;
- each heat dissipation element has an essentially squared shape with an upper surface
and a lower surface, said lower surface being provided with a side recess on two parallel
edges, so that the heat dissipation element can be inserted between adjacent teeth
of the first electrode and the second electrode respectively ;
- each cell or pixel has an independent input connection, respectively an independent
output connection with the power supply ;
- each cell or pixel has a multiplexed connection with the power supply, it means that
each cell or pixel of the two-dimensional array is powered by selecting respective
row and column powering tracks corresponding to the (X, Y) position of the cell in
the two-dimensional array ;
- row and column powering tracks overlap with insulation in the array thanks to positioning
dielectric elements preventing unwanted electric contacts at the crossover points
of the row and column powering tracks ;
- a flat or surface-mounted (SMD) diode is mounted on each pixel output, so that no
leakage current could pass to an adjacent pixel and improperly lighten in whole or
in part the corresponding row and column ;
- the protective layer is an encapsulating insulating layer obtained by serigraphy or
spray and made of dielectric material such as an oxide, a polymer or a ceramic material.
[0021] A second aspect of the present invention relates to the use of one or more surface
elements as described above, for providing an object or a person with a cover, sheet,
blanket, casing or roofing capable of adapting the thermal signature of said object
or person with the purpose of infrared stealthing, deception, camouflage, decoying
or concealment.
[0022] Preferably, the plurality of heat dissipation elements selectively radiate a surface
infrared pattern allowing to avoid the person or the object covered by said one or
more surface elements to be detected by an infrared detection device.
Brief Description of the Drawings
[0023]
FIG. 1 schematically represents the principle of an active system of heating resistors
printed on a thermally and electrically resistive substrate, according to the present
invention.
FIG. 2A and FIG. 2B schematically represent architectures for an active system according
to the present invention, under the form of 3X3 independent heater modules, respectively
of 10x10 multiplexed modules.
FIG. 3A and FIG. 3B schematically represent embodiments according to FIG. 1, wherein
the thermally and electrically resistive substrate is a metal substrate covered with
a dielectric layer, respectively a glass substrate.
FIG. 4A schematically represents an embodiment according to FIG. 1, wherein the active
material is a ferroelectric positive temperature coefficient (PTC) material. FIG.
4B schematically represents a module comprising the active material of FIG. 4A, wherein
the module is obtained by the superposition of a conductive layout and a T-dependent
resistive layout.
FIG. 5A schematically represents an embodiment according to FIG. 4A, wherein the substrate
is made of glass. FIG. 5B is a picture of a demonstrator according to FIG. 5A, with
3x3 independent heater modules.
FIG. 6A schematically represent an embodiment especially designed to be used in the
case of multiplexed modules and wherein the substrate is made of a polyimide layer
(Kapton®). FIG. 6B represents a detail view showing the dielectric elements provided for track
separation in the embodiment of FIG. 6A.
FIG. 7 shows a video excerpt of a IR pattern radiated using a 3x3 independent cells
demonstrator according to an embodiment of the invention, said pattern being visualized
with a computer equipped with a IR camera.
FIG. 8 shows a multiplexed cells demonstrator in which the activation of a pixel induces
leakage current and residual lightning in the row and the column corresponding to
this pixel.
FIG. 9 is a picture of a demonstrator corresponding to the configuration of FIG. 8,
in which a SMD diode has been inserted at the output of each pixel in order to solve
the above-mentioned leakage issue.
FIG. 10 shows an example of IR pattern radiated using a multiplexed cells demonstrator
according to an embodiment of the invention, said pattern being visualized with a
tablet computer equipped with a thermal camera (FLIR Systems, Inc.).
Detailed Description of the Invention
[0024] The present invention is based on an active (i.e. controllable) system 1 of heating
resistors 2 printed on a thermally and electrically resistive substrate 3, as shown
in FIG. 1. For example the resistive heating layer 2 printed on the resistive substrate
3 can be made of metal itself (e.g. silver conductive paste) or of a carbon-based
material with power feeds under the form of a conductive layer 4 made of silver (or
copper, aluminium, etc.). The underlying principle is that the heating element 2 is
based on different resistivity between carbon and silver. Useful printing techniques
are for example serigraphy (also called screen printing or silkscreen), inkjet, flexography,
sintering and other printing electronic deposition methods, possibly combined with
heating or radiation (oven, IPL, IR, UV, laser, etc.). In addition, other new 3D printing
electronic deposition methods can also be used, such as spray (with stencil), micro
spray, 3D inkjet , ink dispensing, etc. In this case, direct printing can be performed
on 3D objects.
[0025] The whole multilayer system is finally encapsulated by an insulating protective layer
5 obtained for example by serigraphy or spraying and made of off-the-shelf dielectric
components such as oxides (e.g. Al
2O
3, ZnO, TiO
2, etc.), polymers (polycarbonate, polyimide, PE, PP, PET, PVC, etc.) or ceramic-based
materials.
[0026] The IR stealth technology according to the invention is intended to provide two functions
:
- firstly, using active material in which temperature variation is a function of a controlled
applied voltage and current;
- secondly, achieving an IR mapping having a given resolution by using a matrix of IR
printed unit modules globally radiating IR pattern.
[0027] The following examples provide matrix/2D architectures that illustrate the general
idea of the present invention. A first example (FIG. 2A) shows 3x3 independent modules
10 (from the point of view of power feeding) and a second example (FIG. 2B) shows
10x10 multiplexed modules 100. The independent modules 10 have each an independent
power feed while in the multiplexed module 100, a specific module is chosen by power
feeding a specific line and a specific column (matrix power feed).
[0028] Further, considering a multiplexed configuration of functionally independent modules/cells,
one module 10 equals one pixel (FIG. 2A). The resistive elements 2 (e.g. made of carbon
containing material) are under the form of a regularly spaced studs layout embedded
in conductive tracks 4 (e.g. made of silver) under the form of combs (see detailed
description below). In this array configuration, each cell or pixel 10 can be activated
independently.
[0029] In another example of multiplexed modules configuration (FIG. 2B), each module may
comprise 4 pixels. A power supply distributes the current to the pixels either sequentially
or by selecting/programming a specific pixel to heat in a matrix way (selection of
a row and a column). Each cell or pixel has a multiplexed connection with the power
supply, it means that each cell or pixel of the two-dimensional array is connected
to a "column" input electrode and to a "row" output electrode (or vice versa) so that
a determined pixel in position (X, Y) is powered by selecting respective row and column
powering tracks in the two-dimensional array. Row and column powering tracks suitably
overlap in the array thanks to positioning dielectric elements 7 preventing electric
contacts at the crossover points of the row and column powering tracks (see below).
Description of Preferred Embodiments of the Invention
[0030] In a first embodiment (FIG. 3A), the inventors used a metallic support 3 as a substrate
covered with an insulating layer (dielectric) 6. The dielectric layer 6 was a PVC
material layer having a thickness up to 200µm. Conductive tracks 4 were obtained by
screen printing of silver-based microparticles. The layout (architecture) was made
of linear simple tracks. Simulations showed an important heat dissipation through
the underlying metal substrate and a non-uniform increase of temperature in a hexagonal
full silver motif/heater module was observed (not shown).
[0031] In a second embodiment (FIG. 3B), the metallic substrate covered with a dielectric
insulating layer was replaced with a glass substrate 3, which is a good thermal and
electric insulator. The conductive tracks 4 and architecture layout were unchanged.
[0032] The use of a substrate material having a drastically reduced thermal conductivity
led to a much better spatial IR resolution (but with some local increase of temperature).
Silver based heater tracks gave high ΔT but also gave uniform T mapping and further
good IR spatial resolution. Different motifs/heater modules were investigated (hexagonal
Ag/C, spiral Ag, ...) with the occurrence of non-uniform temperature and current distribution
(not shown). This showed the need of further increasing IR spatial resolution.
[0033] In a third embodiment, while still utilizing a glass substrate 3 as a thermal insulator,
an active material 20, under the form of a ferroelectric positive temperature coefficient
(PTC) material, was used as carbon resistive material, in combination with conductive
silver tracks 4, as described above (FIG. 4A). Each cell belongs to an array making
a heat dissipation element and is obtained by the superposition of a silver layout
4 on a carbon layout 20 (FIG. 4B), which will be described with more details here
below.
[0034] Each cell 10, 100 comprises a module of conductive tracks 4 having an input electrode
11, 101 and an output electrode 12, 102, having the form of two interdigitated combs,
and comprising an array of heat dissipation elements 20 connected between the respective
teethes 13, 103 of the interdigitated combs. Note that respective 10, 11, 12, etc.
and 100, 101, 102, etc. reference signs refer to the embodiments with 3X3 independent
heater modules and 10x10 multiplexed heater modules. The "cell" element can also be
referred to as a "pixel" with reference to the IR spatial resolution of the device.
[0035] Preferably, each cell or pixel 10, 100 is obtained by firstly printing, for example
by screen printing, the module of conductive tracks 4 on the insulating substrate
3, 30 and secondly printing the array of heat dissipation elements 20 onto both insulation
substrate 3, 30 and module of conductive tracks 4, so that the heat dissipation elements
are brought into close electrical contact with the module of conductive tracks 4.
Each heat dissipation element has preferably a squared shape with an upper surface
and a lower surface, said lower surface being provided with a side recess 21 on two
edges, so that the heat dissipation element can be inserted between adjacent teethes
13, 103 of the first electrode 11, 101 and the second electrode 12, 102 respectively
(see FIG. 4A).
EXAMPLE 1
[0036] The non-multiplexed heater motif size is: 4x4 cm
2 (see FIG. 5A and FIG. 5B). The material is composed of silver tracks having outside
input/output electrode width of 10mm and interdigitated width of 0.4mm. The PTC carbon
resistor is made of 100 small square units (2×2mm
2). A temperature of about 50°C was obtained after 30s with a current of 210mA. A high
spatial resolution is obtained with self-regulation, low current, homogeneity. The
drawbacks are wide current feeds and a non-flexible substrate (glass).
[0037] In a fourth embodiment, Kapton
® (polyimide film, DuPont
™) has been used as a thermal insulator and flexible substrate 30 (FIG. 5A). The active
material is again PTC (ferroelectrics) material 20 combined with conductive silver
tracks 4.
[0038] The coupling of track width reduction with a PTC effect allows to perfectly localize
the increase of temperature and thus provides high spatial resolution, with good time
response (ΔT/Δt high, low current) and self-regulation (I~40mA, V~24V). The tracks
were initially chosen very large (10 mm) outside the patch but their width could be
reduced/optimized later on up to 10 times (not shown). As an additional advantage,
the device is flexible.
EXAMPLE 2
[0039] In an example demonstrator with 3x3 independent cells (not shown), a heater motif
of 4×4cm
2 is provided with 9 stealth cells with Ag tracks of 10mm width, Ag interdigitated
tracks of 0.4 mm width and 100 units PTC-C resistors pixels of 2×2mm
2. The substrate is Kapton
®.
[0040] The (T, I, V) characteristics are the following :
- ΔT ~50°C after 30s ;
- 1=210mA.
[0041] An example of obtainable IR pattern is shown on FIG. 7.
[0042] In an alternative embodiment (FIG. 6A), the architecture is a 10x10 multiplexed configuration.
The multiplexed solution has a number of advantages : save space, reduce the number
of connectors needed to power the device (for 10x10 multiplexed, 20 connectors instead
of 200 connectors for 10x10 independent cells and no space available in the center),
easier control of IR cartography. Further, in this embodiment, a dielectric layer
7 (e.g. Al
2O
3) is provided for electrode separation (FIG. 6B).
EXAMPLE 3
[0043] In an example demonstrator with 10x10 multiplexed cells (not shown), the stealth
cells are provided with Ag tracks of 1mm width, Ag interdigitated of 0.4 mm width
and 9 units PTC-C resistors pixels of 2×2mm
2. The substrate is Kapton
®. The heater motif unit is 1.2×1.2cm
2.
[0044] The (T, I, V) characteristics are the following :
- ΔT 20-30°C after 30s ;
- I=100mA@60V.
[0045] In this last configuration, leakage current was observed, leading to some residual
lightning 9 of the row and the column corresponding to the selected unit cell 8 (see
FIG. 8). The problem was solved by inserting a flat or surface-mounted (SMD) diode
80 on each pixel output, so that the current could not pass to an adjacent pixel (FIG.
9). The insertion is performed, as known in the art, by a "pick & place" method using
a conductive glue in order to ensure proper electric connection. Advantageously the
SMD diode characteristics are 100V/1A (100 diodes for a 10 by 10 multiplexed device).
List of reference symbols
[0046]
- 1
- system of unit heater cells
- 2
- resistive heating layer
- 3
- insulating substrate
- 4
- conductive layer
- 5
- protective layer (encapsulation)
- 6
- dielectric layer
- 7
- dielectric layer element for electrode separation
- 8
- selected pixel
- 9
- pixels with leakage current
- 10
- independent module
- 11
- input electrode
- 12
- output electrode
- 13
- electrode tooth
- 20
- layer of PTC ferroelectrics material
- 21
- recess
- 30
- layer of polyimide substrate (Kapton®)
- 80
- SMD diode
- 100
- multiplexed modules
- 101
- input electrode
- 102
- output electrode
- 103
- electrode tooth
1. An ultrathin, multilayer and encapsulated surface element (1) for providing thermal
signature adaptation with the purpose of infrared stealthing, and being also suited
for camouflage in the visible, the element being flexible and comprising :
- a lower layer made of an insulation substrate (3, 30) ;
- an intermediate layer comprising a plurality of conductive tracks (4) connectable
to a power supply ;
- a plurality of active heat dissipation elements (2, 20) connected to the conductive
tracks (4) in the intermediate layer and capable to irreversibly provide a temperature
increase by Joule effect in a given time interval when a current is fed into said
heat dissipation elements, wherein each dissipation element (2, 20) comprises an electric
conductive path extending between a first connexion and a second connection connecting
respectively said dissipation element (2, 20) to least two of the conductive tracks
(4), said dissipation element (2, 20) being capable of providing the temperature increase
throughout said path from the first connection to the second connection when the current
is fed, the heat dissipation elements (2, 20) and the conductive tracks (4) being
printed on the insulation substrate (3, 30) ;
- an upper layer made of a protective layer (5) ;
the heat dissipation elements (2) having a size and being organized according to a
spatial arrangement so as to provide a predetermined infrared spatial resolution,
when a current is fed into said dissipation elements.
2. The surface element according to Claim 1, wherein the spatial arrangement is a two-dimensional
array of cells or pixels (10) comprising heat dissipation elements (2, 20) regularly
spaced in two orthogonal directions, each cell or pixel (10) being independently connectable
to the power supply via the conductive tracks (4).
3. The surface element according to Claim 1, wherein the spatial arrangement is a two-dimensional
array of cells or pixels (100) comprising heat dissipation elements (2, 20) regularly
spaced in two orthogonal directions, each cell or pixel (100) being connectable in
a multiplexed manner to the power supply via the conductive tracks (4).
4. The surface element according to Claim 1, wherein the heat dissipation elements (2,
20) are made of carbon containing material, PTC ferroelectric material or any resistive
material having a resistance higher than the resistance of the conductive tracks (4).
5. The surface element according to claim 4, wherein the carbon-containing heat dissipation
elements (2, 20) are made of carbon black, amorphous carbon, graphite, graphene nanoplatelets
or carbon nanotubes.
6. The surface element according to claim 4, wherein the resistive material having a
resistance higher than the conductive tracks (4) is made of tungsten, a metallic alloy
such as nichrome (NiCr), a transparent conducting oxide (TCO) film material such as
aluminium-doped zinc oxide (AZO) or indium tin oxide (ITO), or a transparent conducting
polymer such as Poly(3,4-ethylenedioxythiophene) PEDOT: poly(styrene sulfonate) PSS.
7. The surface element according to claim 1, wherein the conductive tracks (4) are made
of silver, gold, copper, aluminium or zinc.
8. The surface element according to claim 1, wherein the heat dissipation elements (2,
20) and the conductive tracks (4) attachment to the substrate (3, 30) is obtained
by inkjet, screen printing or serigraphy, flexography, sintering or other printing
electronic deposition methods, possibly combined with heating or radiation such as
oven, IPL, IR, UV, laser, and in particular 3D printing electronic deposition methods,
such as spray with stencil, micro spray, 3D inkjet or ink dispensing.
9. The surface element according to claim 1, wherein the insulation substrate (3, 30)
is made of a glass plate or of a polyimide film.
10. The surface element according to claim 2 or 3, wherein each cell (10, 100) comprises
a module of conductive tracks (4) having an input electrode (11, 101) and an output
electrode (12, 102), said input electrode (11, 101) and said output electrode (12,
102) having the form of interdigitated combs, and comprising an array of heat dissipation
elements (2, 20) having the form of studs connected between the respective teeth of
the interdigitated combs.
11. The surface element according to claim 10, wherein each cell or pixel (10, 100) is
obtained by firstly printing the module of conductive tracks (4) on the insulation
substrate (3, 30) and secondly printing the array of heat dissipation elements (2,
20) onto both insulation substrate (3, 30) and module of conductive tracks (4), so
that the heat dissipation elements are brought into close electrical contact with
the module of conductive tracks (4).
12. The surface element according to claim 11, wherein each heat dissipation element has
an essentially squared shape with an upper surface and a lower surface, said lower
surface being provided with a side recess (21) on two parallel edges, so that the
heat dissipation element can be inserted between adjacent teeth of the first electrode
and the second electrode respectively.
13. The surface element according to claim 2, wherein each cell or pixel (10) has an independent
input connection, respectively an independent output connection with the power supply.
14. The surface element according to claim 3, wherein each cell or pixel (100) has a multiplexed
connection with the power supply, it means that each cell or pixel (100) of the two-dimensional
array is powered by selecting respective row and column powering tracks corresponding
to the (X, Y) position of the cell (100) in the two-dimensional array.
15. The surface element according to claim 14, wherein row and column powering tracks
overlap insulated in the array thanks to positioning dielectric elements (7) preventing
unwanted electric contacts at the crossover points of the row and column powering
tracks.
16. The surface element according to claim 14, wherein a flat or surface-mounted (SMD)
diode (80) is mounted on each pixel (100) output, so that no leakage current could
pass to an adjacent pixel and improperly lighten in whole or in part the corresponding
row and column.
17. The surface element according to claim 1, wherein the protective layer (5) is an encapsulating
insulating layer obtained by serigraphy or spraying and made of dielectric material
such as an oxide, a polymer or a ceramic-based material.
18. The use of one or more surface elements (1) according to anyone of the preceding claims,
for providing an object or a person with a cover, sheet, blanket, casing or roofing
capable of adapting the thermal signature of said object or person with the purpose
of infrared stealthing, deception, camouflage, decoying or concealment.
19. The use of one or more surface elements (1) according to claim 18, wherein the plurality
of heat dissipation elements (2, 20) selectively radiate a surface infrared pattern
allowing to avoid the person or the object covered by said one or more surface elements
(1) to be detected by an infrared detection device.
1. Ultradünnes, mehrschichtiges und eingekapseltes Oberflächenelement (1) zum Bereitstellen
von Wärmesignaturanpassung zum Zweck von Infrarottarnung, das auch zur Camouflage
im sichtbaren Bereich geeignet ist, wobei das Element flexibel ist und Folgendes umfasst:
- eine untere Schicht, die aus einem Isoliersubstrat (3, 30) gefertigt ist;
- eine Zwischenschicht, umfassend eine Vielzahl von Leiterbahnen (4), die mit einer
Stromversorgung verbindbar sind;
- eine Vielzahl von aktiven Wärmeableitelementen (2, 20), die mit den Leiterbahnen
(4) in der Zwischenschicht verbunden sind und in der Lage sind, in einem gegebenen
Zeitintervall einen irreversiblen Temperaturanstieg durch den Joule-Effekt zu bewirken,
wenn den Wärmeableitelementen ein Strom zugeführt wird, wobei jedes Ableitelement
(2, 20) eine elektrische Leiterbahn umfasst, die sich zwischen einer ersten Verbindung
und einer zweiten Verbindung erstreckt, die jeweils das Ableitelement (2, 20) mit
mindestens zwei der Leiterbahnen (4) verbindet, wobei das Wärmeableitelement (2, 20)
in der Lage ist, den Temperaturanstieg auf dem gesamten Weg von der ersten Verbindung
zu der zweiten Verbindung zu gewährleisten, wenn der Strom eingespeist wird, wobei
die Wärmeableitelemente (2, 20) und die Leiterbahnen (4) auf das Isoliersubstrat (3,
30) gedruckt sind;
- eine obere Schicht, die aus einer Schutzschicht (5) gefertigt ist;
wobei die Wärmeableitelemente (2) eine Größe aufweisen und gemäß einer räumlichen
Anordnung organisiert sind, um eine vorbestimmte räumliche Infrarotauflösung bereitzustellen,
wenn ein Strom in die Ableitelemente eingespeist wird.
2. Oberflächenelement nach Anspruch 1, wobei die räumliche Anordnung eine zweidimensionale
Anordnung von Zellen oder Pixeln (10) ist, umfassend Wärmeableitelemente (2, 20),
die regelmäßig in zwei orthogonalen Richtungen beabstandet sind, wobei jede Zelle
oder jedes Pixel (10) unabhängig über die Leiterbahnen (4) mit der Energieversorgung
verbindbar ist.
3. Oberflächenelement nach Anspruch 1, wobei die räumliche Anordnung eine zweidimensionale
Anordnung von Zellen oder Pixeln (100) ist, umfassend Wärmeableitelemente (2, 20),
die regelmäßig in zwei orthogonalen Richtungen beabstandet sind, wobei jede Zelle
oder jedes Pixel (100) über die Leiterbahnen (4) auf gemultiplexte Weise mit der Stromversorgung
verbindbar ist.
4. Oberflächenelement nach Anspruch 1, wobei die Wärmeableitelemente (2, 20) aus kohlenstoffhaltigem
Material, PTC-ferroelektrischem Material oder einem beliebigen Widerstandsmaterial
gefertigt sind, die einen höheren Widerstand als der der Leiterbahnen (4) aufweisen.
5. Oberflächenelement nach Anspruch 4, wobei die kohlenstoffhaltigen Wärmeableitelemente
(2, 20) aus Ruß, amorphem Kohlenstoff, Graphit, Graphen-Nanoplättchen oder Kohlenstoff-Nanoröhren
gefertigt sind.
6. Oberflächenelement nach Anspruch 4, wobei das Widerstandsmaterial, das einen höheren
Widerstand als die Leiterbahnen (4) aufweist, aus Wolfram, einer metallischen Legierung
wie Nickelchrom (NiCr), einem transparenten leitenden Oxid (TCO)-Filmmaterial, wie
beispielsweise aluminiumdotiertem Zinkoxid (AZO) oder Indiumzinnoxid (ITO) oder einem
transparenten leitenden Polymer, wie beispielsweise Poly(3,4-ethylendioxythiophen)
PEDOT: Poly(styrolsultanat) PSS gefertigt ist.
7. Oberflächenelement nach Anspruch 1, wobei die Leiterbahnen (4) aus Silber, Gold, Kupfer,
Aluminium oder Zink gefertigt sind.
8. Oberflächenelement nach Anspruch 1, wobei die Wärmeableitelemente (2, 20) und das
Anbringen der Leiterbahnen (4) auf dem Substrat (3, 30) durch Tintenstrahl, Siebdruck
oder Serigraphie, Flexodruck, Sintern oder andere elektronische Druckverfahren, möglicherweise
in Kombination mit Heizung oder Strahlung, wie beispielsweise Ofen, IPL, IR, UV, Laser,
und insbesondere durch elektronische 3D-Druckverfahren, wie beispielsweise Sprühen
mit Schablone, Mikrosprühen, 3D-Tintenstrahl oder Tintenauftrag, erlangt wird.
9. Oberflächenelement nach Anspruch 1, wobei das Isolationssubstrat (3, 30) aus einer
Glasplatte oder aus einer Polyimidfolie gefertigt ist.
10. Oberflächenelement nach Anspruch 2 oder 3, wobei jede Zelle (10, 100) ein Modul von
Leiterbahnen (4) umfasst, die eine Eingangselektrode (11, 101) und eine Ausgangselektrode
(12, 102) aufweisen, wobei die Eingangselektrode (11, 101) und die Ausgangselektrode
(12, 102) die Form von ineinandergreifenden Kämmen aufweisen und eine Anordnung von
Wärmeableitelementen (2, 20) umfassen, die die Form von Stiften aufweisen, die zwischen
den jeweiligen Zähnen der ineinandergreifenden Kämme verbunden sind.
11. Oberflächenelement nach Anspruch 10, wobei jede Zelle oder jedes Pixel (10, 100) dadurch
erlangt wird, dass erstens das Modul von Leiterbahnen (4) auf das Isoliersubstrat
(3, 30) gedruckt wird und zweitens die Anordnung von Wärmeableitelementen (2, 20)
sowohl auf das Isoliersubstrat (3, 30) als auch auf das Modul von Leiterbahnen (4)
gedruckt wird, sodass die Wärmeableitelemente in engen elektrischen Kontakt mit dem
Modul von Leiterbahnen (4) gebracht werden.
12. Oberflächenelement nach Anspruch 11, wobei jedes Wärmeableitelement eine im Wesentlichen
quadratische Form mit einer oberen Oberfläche und einer unteren Oberfläche aufweist,
wobei die untere Oberfläche an zwei parallelen Rändern mit einer seitlichen Aussparung
(21) versehen ist, sodass das Wärmeableitelement zwischen benachbarte Zähne der ersten
Elektrode bzw. der zweiten Elektrode eingesetzt werden kann.
13. Oberflächenelement nach Anspruch 2, wobei jede Zelle oder jedes Pixel (10) eine unabhängige
Eingangsverbindung bzw. eine unabhängige Ausgangsverbindung mit der Stromversorgung
aufweist.
14. Oberflächenelement nach Anspruch 3, wobei jede Zelle oder jedes Pixel (100) eine gemultiplexte
Verbindung mit der Stromversorgung aufweist, was bedeutet, dass jede Zelle oder jedes
Pixel (100) der zweidimensionalen Anordnung durch Auswählen der jeweiligen Zeilen-
und Spaltenstromversorgungsspuren entsprechend der (X, Y)-Position der Zelle (100)
in der zweidimensionalen Anordnung mit Strom versorgt wird.
15. Oberflächenelement nach Anspruch 14, wobei sich Zeilen- und Spaltenversorgungsspuren
in der Anordnung dank eines Positionierens dielektrischer Elemente (7), die unerwünschte
elektrische Kontakte an den Kreuzungspunkten der Zeilen- und Spaltenversorgungsspuren
verhindern, isoliert überlappen.
16. Oberflächenelement nach Anspruch 14, wobei eine flache oder oberflächenmontierte (SMD)
Diode (80) an jedem Pixel (100) montiert ist, sodass kein Leckstrom zu einem benachbarten
Pixel fließen und die entsprechende Zeile und Spalte ganz oder teilweise unzulässig
aufhellen kann
17. Oberflächenelement nach Anspruch 1, wobei die Schutzschicht (5) eine einkapselnde
Isolierschicht ist, die durch Serigraphie oder Sprühen erlangt wird und aus dielektrischem
Material wie einem Oxid, einem Polymer oder einem Material auf Keramikbasis gefertigt
ist.
18. Verwendung eines oder mehrerer Oberflächenelemente (1) nach einem der vorherigen Ansprüche,
um ein Objekt oder eine Person mit einer Abdeckung, Folie, Decke, Hülle oder Bedachung
zu versehen, die in der Lage ist, die Wärmesignatur des Objekts oder der Person zum
Zweck von Infrarottarnung, Täuschung, Camouflage, Ablenkung oder Verschleierung anzupassen.
19. Verwendung eines oder mehrerer Oberflächenelemente (1) nach Anspruch 18, wobei die
Vielzahl von Wärmeableitelementen (2, 20) selektiv ein Oberflächeninfrarotmuster ausstrahlen,
das es ermöglicht, zu vermeiden, dass die Person oder das Objekt, das von dem einen
oder den mehreren Oberflächenelementen (1) abgedeckt wird, von einer Infraroterfassungsvorrichtung
erfasst wird.
1. Élément de surface (1) ultramince, multicouche et encapsulé destiné à fournir une
adaptation de signature thermique à des fins de furtivité infrarouge, et étant également
adapté à des fins de camouflage dans le visible, l'élément étant flexible et comprenant
:
- une couche inférieure constituée d'un substrat isolant (3, 30) ;
- une couche intermédiaire comprenant une pluralité de pistes conductrices (4) qui
peuvent être connectées à une alimentation électrique ;
- une pluralité d'éléments actifs de dissipation thermique (2, 20) connectés aux pistes
conductrices (4) dans la couche intermédiaire et capables de produire de manière irréversible
une augmentation de température par effet Joule dans un intervalle de temps donné
lorsqu'un courant est fourni dans lesdits éléments de dissipation thermique, caractérisé en ce que chaque élément de dissipation (2, 20) comprend un chemin conducteur électrique s'étendant
entre une première connexion et une deuxième connexion qui relient respectivement
ledit élément de dissipation (2, 20) à au moins deux des pistes conductrices (4),
ledit élément de dissipation (2, 20) étant capable de produire l'augmentation de température
tout au long dudit chemin de la première connexion à la deuxième connexion lorsque
le courant est fourni, les éléments de dissipation thermique (2, 20) et les pistes
conductrices (4) étant imprimés sur le substrat isolant (3, 30) ;
- une couche supérieure constituée d'une couche protectrice (5) ;
les éléments de dissipation thermique (2) ayant une taille et étant organisés selon
une disposition spatiale telle qu'ils produisent une résolution spatiale infrarouge
prédéterminée, lorsqu'un courant est fourni dans lesdits éléments de dissipation.
2. Élément de surface selon la revendication 1, caractérise en ce que l'agencement spatial est un réseau bidimensionnel de cellules ou pixels (10) comprenant
des éléments de dissipation thermique (2, 20) régulièrement espacés dans deux directions
orthogonales, chaque cellule ou pixel (10) pouvant être connecté indépendamment à
l'alimentation électrique via les pistes conductrices (4).
3. Élément de surface selon la revendication 1, caractérisé en ce que l'agencement spatial est un réseau bidimensionnel de cellules ou pixels (100) comprenant
des éléments de dissipation thermique (2, 20) régulièrement espacés dans deux directions
orthogonales, chaque cellule ou pixel (100) pouvant être connecté de façon multiplexée
à l'alimentation électrique via les pistes conductrices (4).
4. Élément de surface selon la revendication 1, caractérisé en ce que les éléments de dissipation thermique (2, 20) sont constitués d'un matériau contenant
du carbone, d'un matériau ferroélectrique PTC ou d'un matériau résistif quelconque
ayant une résistance supérieure à la résistance des pistes conductrices (4).
5. Élément de surface selon la revendication 4, caractérisé en ce que les éléments de dissipation thermique contenant du carbone (2, 20) sont constitués
de noir de carbone, de carbone amorphe, de graphite, de nanoplaquettes de graphène
ou de nanotubes de carbone.
6. Élément de surface selon la revendication 4, caractérisé en ce que le matériau résistif ayant une résistance supérieure à celle des pistes conductrices
(4) est constitué de tungstène, d'un alliage métallique tel que le nichrome (NiCr),
d'un matériau de film d'oxyde conducteur transparent (TCO) tel que l'oxyde de zinc
dopé à l'aluminium (AZO) ou l'oxyde d'indium-étain (ITO), ou d'un polymère conducteur
transparent tel que le poly(3,4-éthylènedioxythiophène) PEDOT : poly(sulfonate de
styrène) PSS.
7. Élément de surface selon la revendication 1, caractérisé en ce que les pistes conductrices (4) sont en argent, en or, en cuivre, en aluminium ou en
zinc.
8. Élément de surface selon la revendication 1, caractérisé en ce que la fixation des éléments de dissipation thermique (2, 20) et des pistes conductrices
(4) au substrat (3, 30) est obtenue par jet d'encre, par impression au cadre ou sérigraphie,
par flexographie, par frittage ou par d'autres procédés de dépôt électronique par
impression, éventuellement combinés à un chauffage ou à un rayonnement tels que four,
IPL, IR, UV, laser, et notamment des procédés de dépôt électronique par impression
3D, tels que la pulvérisation avec pochoir, la micropulvérisation, le jet d'encre
ou la distribution d'encre 3D.
9. Élément de surface selon la revendication 1, caractérisé en ce que le substrat isolant (3, 30) est constitué d'une plaque de verre ou d'un film de polyimide.
10. Élément de surface selon la revendication 2 ou 3, caractérisé en ce que chaque cellule (10, 100) comprend un module de pistes conductrices (4) comportant
une électrode d'entrée (11, 101) et une électrode de sortie (12, 102), ladite électrode
d'entrée (11, 101) et ladite électrode de sortie (12, 102) ayant la forme de peignes
interdigités, et comprenant un réseau d'éléments de dissipation thermique (2, 20)
ayant la forme de plots connectés entre les dents respectives des peignes interdigités.
11. Élément de surface selon la revendication 10, caractérisé en ce que chaque cellule ou pixel (10, 100) est obtenu premièrement en imprimant le module
de pistes conductrices (4) sur le substrat isolant (3, 30) et deuxièmement en imprimant
le réseau d'éléments de dissipation thermique (2, 20) à la fois sur le substrat isolant
(3, 30) et sur le module de pistes conductrices (4), de sorte que les éléments de
dissipation thermique sont mis en contact électrique étroit avec le module de pistes
conductrices (4).
12. Élément de surface selon la revendication 11, caractérisé en ce que chaque élément de dissipation thermique a une forme essentiellement carrée avec une
surface supérieure et une surface inférieure, ladite surface inférieure étant pourvue
d'un évidement latéral (21) sur deux bords parallèles, de sorte que l'élément de dissipation
thermique peut être inséré entre les dents adjacentes de la première électrode et
de la deuxième électrode respectivement.
13. Élément de surface selon la revendication 2, caractérisé en ce que chaque cellule ou pixel (10) a une connexion d'entrée indépendante, respectivement
une connexion de sortie indépendante avec l'alimentation électrique.
14. Élément de surface selon la revendication 3, caractérisé en ce que chaque cellule ou pixel (100) a une connexion multiplexée avec l'alimentation électrique,
ce qui signifie que chaque cellule ou pixel (100) du réseau bidimensionnel est alimenté
en sélectionnant des pistes d'alimentation de ligne et de colonne respectives correspondant
à la position (X, Y) de la cellule (100) dans le réseau bidimensionnel.
15. Élément de surface selon la revendication 14, caractérisé en ce que les pistes d'alimentation de rangée et de colonne se chevauchent et sont isolées
dans le réseau grâce au positionnement d'éléments diélectriques (7) empêchant les
contacts électriques indésirables aux points de croisement des pistes d'alimentation
de ligne et de colonne.
16. Élément de surface selon la revendication 14, caractérisé en ce que une diode plate ou montée en surface (SMD) (80) est montée sur chaque sortie de pixel
(100), de sorte qu'aucun courant de fuite ne peut se propager à un pixel adjacent
et éclairer de manière indésirable, en totalité ou en partie, la ligne et la colonne
correspondantes.
17. Élément de surface selon la revendication 1, caractérisé en ce que la couche protectrice (5) est une couche isolante encapsulante obtenue par sérigraphie
ou par pulvérisation et constituée d'un matériau diélectrique tel qu'un oxyde, un
polymère ou un matériau à base de céramique.
18. Utilisation d'un ou plusieurs éléments de surface (1) selon l'une quelconque des revendications
précédentes, pour doter un objet ou une personne d'un recouvrement, d'une feuille,
d'une couverture, d'une enveloppe ou d'une toiture capable d'adapter la signature
thermique dudit objet ou de ladite personne à des fins de furtivité, de tromperie,
de camouflage, de leurrage ou de dissimulation infrarouge.
19. Utilisation d'un ou plusieurs éléments de surface (1) selon la revendication 18, caractérisée en ce que la pluralité d'éléments de dissipation thermique (2, 20) rayonne sélectivement un
motif infrarouge de surface qui permet d'éviter que la personne ou l'objet recouvert
par lesdits un ou plusieurs éléments de surface (1) ne soient détectés par un dispositif
de détection infrarouge.
REFERENCES CITED IN THE DESCRIPTION
This list of references cited by the applicant is for the reader's convenience only.
It does not form part of the European patent document. Even though great care has
been taken in compiling the references, errors or omissions cannot be excluded and
the EPO disclaims all liability in this regard.
Patent documents cited in the description
Non-patent literature cited in the description
- Fast Adaptive Thermal Camouflage Based on Flexible VO2/Graphene/ CNT Thin FilmsLIN XIAO et al.Nano Lett.Am. Chem. Soc.20150000vol. 15, 8365-8370 [0013]