Technical Field
[0001] The present invention relates to a tube glass packaging body.
Background Art
[0002] Patent Literature 1 describes a tube glass packaging body including a base, a plurality
of tube glasses stacked on the base, and a shrink film wrapping the tube glasses.
Citation List
Patent Literature
Summary of Invention
Technical Problem
[0004] In the above-described tube glass packaging body, depending on storage conditions,
water droplets may be deposited on inner surfaces of the tube glasses due to dew condensation
of the tube glasses. Due to the water droplets deposited on the inner surfaces of
the tube glasses, an alkali component contained in the tube glasses may be eluted
into the water droplets. In this case, when the water droplets deposited on the inner
surfaces of the tube glasses evaporate, the alkali component that has eluted into
the water droplets may precipitate, as powdery foreign matter. This powdery foreign
matter is referred to as "alkali blooming" in the present specification.
[0005] An object of the present invention is to provide a tube glass packaging body in which
powdery foreign matter due to storage conditions is less likely to be formed in tube
glasses.
Solution to Problem
[0006] Hereinafter, means for solving the above problem will be described.
A tube glass packaging body of the present disclosure includes: a plurality of tube
glass assemblies each including a tube glass group including a plurality of accumulated
tube glasses and a binding film covering at least one end portion of the tube glass
group and binding the tube glass group; a packaging film wrapping the tube glass assemblies;
and a dehumidifying agent disposed inside the packaging film.
[0007] In the tube glass packaging body, the dehumidifying agent may be disposed between
the packaging film and the binding film.
In the tube glass packaging body, the dehumidifying agent disposed between the packaging
film and the binding film may be disposed in a region of the binding film that covers
a side surface of the tube glass group.
[0008] In the tube glass packaging body, the tube glass assemblies may be stacked in a vertical
direction, and the dehumidifying agent may be disposed in an upper region, the upper
region being at the same level as or above a middle position in the vertical direction
of the stacked tube glass assemblies.
[0009] In the tube glass packaging body, the dehumidifying agent may be disposed between
the binding film and at least one end surface of the tube glass group.
In the tube glass packaging body, the tube glasses may each have a length of 500 mm
or greater.
[0010] In the tube glass packaging body, the tube glasses may be any system of borosilicate
glass, soda lime glass, and aluminosilicate glass.
Specifically, the tube glass packaging body, when having a composition containing,
in mass%, from 50 to 80% of SiO
2, from 1 to 20% of Al
2O
3, from 1 to 20% of B
2O
3, and 5% or more of Li
2O+Na
2O+K
2O, corresponds to these glass systems.
[0011] In the tube glass packaging body, the tube glasses may be for a use in a pharmaceutical
container or a physicochemical container. These intended applications require a high
degree of cleanliness on the inner surfaces of the tube glasses.
Advantageous Effects of Invention
[0012] The tube glass packaging body according to the present disclosure can suppress formation
of powdery foreign matter in the tube glasses caused by storage conditions.
Brief Description of Drawings
[0013]
FIG. 1 is a perspective view of a tube glass packaging body according to an embodiment.
FIG. 2 is a perspective view of a tube glass assembly of the tube glass packaging
body.
FIG. 3 is a perspective view of the tube glass packaging body in the middle of packaging.
FIG. 4 is a perspective view of the tube glass packaging body in the middle of packaging.
FIG. 5 is an enlarged photograph of a tube glass in the tube glass packaging body
of the present embodiment left in a high humidity environment.
FIG. 6 is an enlarged photograph of a tube glass in a tube glass packaging body of
a comparative example left in a high humidity environment.
FIG. 7 is a perspective view of a tube glass assembly according to a modified example.
Description of Embodiments
[0014] An embodiment of the tube glass packaging body will be described below.
FIG. 1 illustrates a tube glass packaging body 10 disposed on a pallet 100.
As illustrated in FIG. 1, the tube glass packaging body 10 includes: a plurality of
tube glass assemblies 20, which is stacked in a plurality of layers, in a state of
being arranged in a plurality of rows; a first sheet 30 disposed under the tube glass
assemblies 20 at the lowermost layer; and a second sheet 40 disposed on the tube glass
assemblies 20 at each layer. The tube glass packaging body 10 includes: a plurality
of protective members 50 that are positioned at four corners of the tube glass packaging
body 10 and protect the tube glass assemblies 20; a plurality of binding members 60
that bind the stacked tube glass assemblies 20; a dehumidifying agent 70 that absorbs
moisture contained in gas; and a packaging film 80 that wraps the tube glass assemblies
20.
[0015] As illustrated in FIG. 2, the tube glass assembly 20 includes a tube glass group
22 including a plurality of accumulated tube glasses 21 and a binding film 23 that
binds the tube glass group 22.
The tube glass 21 has a cylindrical shape with both end portions open. The tube glass
21 has an inner diameter of, for example, several mm to ten and several mm, and a
full length of, for example, 500 mm or greater. The tube glass 21 is for a use in,
for example, pharmaceutical containers and physicochemical containers such as ampules,
syringes, and vials.
[0016] The tube glass 21 is made of borosilicate glass and contains SiO
2, Al
2O
3, B
2O
3, and R
2O as essential components. Here, R is one or more elements selected from Li, Na, and
K. The composition of the borosilicate glass serving as the material of the tube glass
21 is not particularly limited, but preferably contains, in mass%, from 50 to 80%
of SiO
2, from 1 to 20% of Al
2O
3, from 1 to 20% of B
2O
3, and 5% or more of "Li
2O+Na
2O+K
2O". Here, the "Li
2O+Na
2O+K
2O" means a total content value of Li
2O, Na
2O, and K
2O. Hereinafter, the reason why the composition range of each component is defined
as described above will be described. In the description below, the symbol "%" means
"mass%" unless otherwise indicated.
[0017] SiO
2 is one of the components that form a glass network. A content of SiO
2 is preferably from 50% to 80%, from 55% to 78%, or from 60% to 76%, and particularly
preferably from 65% to 75%. When the content of SiO
2 is too low, the chemical durability decreases, and the acid resistance and water
resistance required of the container decrease. In addition, an alkali component such
as Na
2O easily moves out from the glass network, which causes alkali blooming. On the other
hand, when the content of SiO
2 is too large, liquid phase viscosity decreases, and devitrification easily occurs
in the production process, leading to decrease in productivity.
[0018] Al
2O
3 is a component that suppresses devitrification of glass and improves chemical durability
and hydrolysis resistance. In addition, it is a component that reinforces the glass
network and prevents an alkali component such as Na
2O moving out from the glass network, that is, prevents alkali blooming. A content
of Al
2O
3 is preferably from 1 to 20%, from 2 to 18%, or 4 to 15%, and particularly preferably
from 6 to 12%. When the content of Al
2O
3 is too low, the effects described above may not be obtained. Meanwhile, when the
content of Al
2O
3 is too large, the viscosity of glass increases. This increases a working temperature
and also increases an amount of heat required for processing into a container.
[0019] B
2O
3 is a component that not only lowers a melting point of the glass, but also raises
the liquid phase viscosity, and suppresses devitrification. A content of B
2O
3 is preferably from 1 to 20%, from 3 to 18%, or from 5 to 16%, and particularly preferably
from 7 to 14%. Too low a content of B
2O
3 increases the working temperature and also increases the amount of heat required
for processing into a container. On the other hand, when the content of B
2O
3 is too large, hydrolysis resistance and chemical durability are reduced, and thus
an alkali component such as Na
2O easily moves out from the glass network and alkali blooming easily occurs.
[0020] Na
2O is a component that lowers the viscosity of glass. A content of Na
2O is preferably from 1 to 15%, 2 to 12%, or 3 to 10%, and particularly preferably
from 4 to 8%. Too low a content of Na
2O increases the working temperature and also increases the amount of heat required
for processing into a container. On the other hand, when the content of Na
2O is too large, the hydrolysis resistance is reduced. Na
2O is a component that causes alkali blooming. Therefore, the tube glass packaging
body of the present disclosure is particularly effective for tube glasses containing
Na
2O.
[0021] Similarly to Na
2O, K
2O is also a component that lowers the viscosity of glass. A content of K
2O is preferably from 0 to 10%, from 0.1 to 8%, from 0.2 to 6%, or from 0.5 to 5%,
and particularly preferably from 1 to 4%. Too low a content of K
2O increases the working temperature and also increases the amount of heat required
for processing into a container. On the other hand, when the content of K
2O is too large, the hydrolysis resistance is reduced. K
2O is also a component that causes alkali blooming. Therefore, the tube glass packaging
body of the present disclosure is particularly effective for tube glasses containing
K
2O.
[0022] When the K
2O and Na
2O components are used in combination, the hydrolysis resistance is improved by virtue
of the mixed alkali effect. In order to improve the hydrolysis resistance, a mass
ratio of K
2O/Na
2O is preferably from 0.0 to 1.0, from 0.1 to 0.8, or from 0.15 to 0.6, and particularly
preferably from 0.2 to 0.5. If this ratio is small, the hydrolysis resistance decreases.
On the other hand, if this ratio is large, the working temperature is increased, and
the amount of heat required for processing into a container is also increased, leading
to deterioration in productivity.
[0023] Similarly to Na
2O and K
2O, Li
2O is a component that lowers the viscosity of glass. However, addition of Li
2O easily causes erosion of refractories at the time of glass melting. Therefore, a
content of Li
2O is preferably from 0 to 5%, from 0 to 3%, or from 0 to 1%, and particularly preferably
from 0 to 0.5%. Unless otherwise specified, it is preferable to use an alkali metal
oxide other than Li
2O.
[0024] A total content value of Li
2O, Na
2O, and K
2O content is preferably 5% or more, and particularly preferably from 5 to 20%. A low
total content value of these components increases the working temperature. In addition,
when the total content value of these components is too large, the chemical durability
and hydrolysis resistance are reduced.
[0025] It should be noted that various components besides those described above can be added
to the borosilicate glass as the material of the tube glass 21. Other materials of
the tube glass 21 include soda lime glass and aluminosilicate glass.
[0026] The binding film 23 is preferably made of a material having high gas barrier properties
and appropriate stretchability. The material for the binding film 23 may be, for example,
a resin material such as polypropylene, polyethylene, or polyvinyl chloride. In the
present embodiment, the binding film 23 is a shrink film that shrinks due to heat,
but may be substituted with a stretch film or the like. The binding films 23 cover
regions excluding a middle region in a longitudinal direction of the tube glass group
22, that is, regions of both end portions of the tube glass group 22, and binds the
tube glass group 22. At a boundary between the region covered with the binding film
23 and the region not covered with the binding film 23, there may be a slight gap
through which gas can pass. In addition, in the tube glass assembly 20, openings at
both ends of the tube glass 21 are not completely covered by the binding film 23.
Therefore, in the tube glass packaging body 10, the gas inside the packaging film
80 can enter the tube glass 21.
[0027] As illustrated in FIG. 2, the tube glass assembly 20 is formed by arranging in parallel
and stacking the plurality of tube glasses 21 with their end portions aligned. In
the example illustrated in FIG. 2, the tube glasses 21 are aligned in six rows and
stacked in five layers, and the tube glass assembly 20 as a whole has a substantially
rectangular parallelepiped shape. In the following description, in the binding film
23, a portion that covers an end surface of the tube glass group 22 is also referred
to as front surface of the binding film 23, and a portion that covers a side surface
of the tube glass group 22 is also referred to as side surface of the binding film
23. Here, the end surface of the tube glass group 22 is a surface formed by a set
of end surfaces of the plurality of tube glasses 21 forming the tube glass group 22.
Further, the side surface of the tube glass group 22 is a surface formed by a set
of surfaces exposed to the outside among the side surfaces of the plurality of tube
glasses 21 forming the tube glass group 22.
[0028] As illustrated in FIG. 1, the plurality of tube glass assemblies 20 are arranged
in parallel and stacked in a state where their end portions are aligned. In the example
illustrated in FIG. 1, the tube glass assemblies 20 are arranged in four rows and
stacked in eight layers.
[0029] As illustrated in FIG. 1, the first sheet 30 and the second sheet 40 each have a
substantially rectangular shape in a plan view, the first sheet 30 has the same size
as the pallet 100, and the second sheet 40 is one size smaller than the pallet 100.
In the vertical direction, the first sheet 30 is disposed between the packaging film
80 including a first film 81 and a second film 82, which will be described later,
and the plurality of tube glass assemblies 20 forming the lowermost layer. On the
other hand, the second sheet 40 is disposed on the plurality of tube glass assemblies
20 forming each layer. In the second sheet 40, both end portions in an arrangement
direction of the tube glass assemblies 20 are bent downward over the longitudinal
direction of the tube glass assemblies 20. Thus, misalignment in the arrangement direction
of the tube glass assemblies 20 forming each layer can be suppressed.
[0030] The protective member 50 is an elongated member having a substantially L-shaped cross-section
orthogonal to the longitudinal direction. A length of the protective member 50 in
the longitudinal direction corresponds to a height of the stacked tube glass assemblies
20. The protective member 50 can be made of, for example, corrugated cardboard. The
protective member 50 covers and protects four sides extending in the vertical direction,
which are formed by stacking the tube glass assemblies 20 in a plurality of layers
while the tube glass assemblies 20 are arranged in a plurality of rows.
[0031] The binding member 60 is, for example, a binding band. The binding member 60 binds
the plurality of tube glass assemblies 20 together with the four protective members
50 inside the packaging film 80. Specifically, the binding member 60 presses the four
protective members 50 against the tube glass assemblies 20 and thus binds the tube
glass assemblies 20. In the present embodiment, two binding members 60 are provided
at an interval in the vertical direction, but any number of binding members 60 can
be employed. The binding member 60 may be substituted with a film member such as a
shrink film or a stretch film, or may be substituted with a rope or a tape for binding.
[0032] The dehumidifying agent 70 contains a substance capable of absorbing moisture, and
the substance include silica gel, calcium oxide, and calcium chloride. The dehumidifying
agent 70 may have a bag shape or may have a sheet shape. The dehumidifying agent 70
keeps low humidity in a space surrounded by the packaging film 80.
[0033] The dehumidifying agent 70 is disposed in an upper region at the same level as or
above a middle position in the vertical direction and a lower region below the middle
position in the stacked tube glass assemblies 20. As illustrated in FIG. 1, when the
height of the stacked tube glass assemblies 20 is "H", the dehumidifying agent 70
disposed in the upper region is disposed at a position of preferably 0.5 H or higher,
more preferably 0.6 H or higher, and even more preferably 0.7 H or higher from the
bottom surface of the lowermost tube glass assembly 20. On the other hand, the dehumidifying
agent 70 disposed in the lower region is preferably disposed at a position of lower
than 0.5 H, more preferably 0.4 H or lower, and even more preferably 0.3 H or lower
from the bottom surface of the lowermost tube glass assembly 20.
[0034] In the present embodiment, the dehumidifying agent 70 is attached to some of the
tube glass assemblies 20 among the plurality of the tube glass assemblies 20. In the
following description, the tube glass assembly 20 to which the dehumidifying agent
70 is attached is referred to as "tube glass assembly 20X".
[0035] Specifically, the dehumidifying agent 70 is attached to be positioned in a region
of the side surface of the binding film 23 that is not covered with the second sheet
40 or the protective member 50 in the tube glass assembly 20X. In the present embodiment,
the dehumidifying agent 70 is inserted between the side surface of the binding film
23 and the binding member 60 and thus attached to the side surface of the binding
film 23. In another embodiment, the dehumidifying agent 70 may be pasted to the side
surface of the binding film 23 using an adhesive tape or an adhesive.
[0036] The packaging film 80 is preferably made of a material having high gas barrier properties
and appropriate stretchability. The material for the packaging film 80 may be, for
example, a resin material such as polypropylene, polyethylene, or polyvinyl chloride.
In the present embodiment, the packaging film 80 is a shrink film that shrinks due
to heat, but may be substituted with a stretch film or the like. The stacked tube
glass assemblies 20 and the dehumidifying agent 70 are disposed in a space covered
with the packaging film 80. In addition, the dehumidifying agent 70 is disposed between
the binding film 23 for the tube glass assembly 20 and the packaging film 80.
(Tube glass packaging method)
[0037] A tube glass packing method for forming the plurality of tube glass assemblies 20
into the tube glass packaging body 10 will be described.
[0038] As illustrated in FIGS. 3 and 4, the tube glass packaging method of the present disclosure
includes: a stacking step of piling up components of the tube glass packaging body
10 on the pallet 100; and a sealing step of forming the packaging film 80.
[0039] As illustrated in FIG. 3, in the stacking step, first, the rectangular first film
81 is stacked on the pallet 100, and then the first sheet 30 is stacked on the first
film 81. The first film 81 is larger than the pallet 100 and the first sheet 30 in
a plan view, and a peripheral edge portion thereof protrudes from the pallet 100.
Thereafter, the tube glass assemblies 20 are stacked on the first sheet 30.
[0040] In the example illustrated in FIG. 3, the tube glass assemblies 20 arranged in four
rows are stacked in eight layers. The second sheet 40 is disposed on the tube glass
assemblies 20 at each layer, so that the tube glass assemblies 20 and the second sheets
40 are alternately stacked in the vertical direction.
[0041] As illustrated in FIG. 3, after all of the tube glass assemblies 20 are stacked on
the pallet 100, the four protective members 50 are assembled to the four corners of
the stacked tube glass assemblies by the two binding members 60, and bound together
with the tube glass assemblies 20. Thereafter, the dehumidifying agent 70 is inserted
between the tube glass assembly 20X and the binding member 60. Finally, as illustrated
in FIG. 4, this is covered with the bag-shaped second film 82.
[0042] In the sealing step, the tube glass assemblies 20 covered with the second film 82
are put into a heating device (not illustrated) together with the pallet 100. As a
result, as illustrated in FIG. 1, the first film 81 and the second film 82 thermally
shrinks. Specifically, the first film 81 and the second film 82 are thermally welded
to each other to form a single integrated film, and this integrated film, the packaging
film 80, is brought into close contact with the tube glass assemblies 20. Thus, the
packing of the tube glass assembly 20 is completed, and, as a result, with this packing,
the displacement of the tube glass assemblies 20 in the space covered with the packaging
film 80 is restricted.
[0043] Next, a comparison result between the present embodiment and a comparative example
will be described with reference to FIGS. 5 and 6. The glass used for the test was
borosilicate glass containing, in mass%, 70% of SiO
2, 20% of B
2O
3, 5% of Al
2O
3, 1% of CaO, 1% of BaO, 2% of Na
2O, and 1% of K
2O.
[0044] FIG. 5 is an enlarged photograph of the surface of the tube glass 21 of the present
embodiment, when the tube glass packaging body 10 including the dehumidifying agent
70 was left in an atmosphere at a temperature of 20°C and a humidity of 65% for 720
hours. On the other hand, FIG. 6 is an enlarged photograph of the surface of the tube
glass 21 of the comparative example, when a tube glass packaging body including no
dehumidifying agent 70 was left in the atmosphere under the same conditions.
[0045] As shown in FIG. 5, in the case where the dehumidifying agent 70 was provided, even
if the tube glass 21 was left in the high-humidity environment, dew condensation was
not likely to occur on the inner surface of the tube glass 21, and thus foreign matter
caused by alkali blooming was not observed on the inner surface of the tube glass
21.
[0046] On the other hand, as shown in FIG. 6, in the case where the dehumidifying agent
70 was not provided, when the tube glass 21 was left in the high-humidity environment,
dew condensation was likely to occur on the inner surface of the tube glass 21, and
thus foreign matter caused by alkali blooming was generated on the inner surface of
the tube glass 21. In FIG. 6, a large number of white dots are foreign matters caused
by alkali blooming.
[0047] From the above results, it was demonstrated that, in the case of the present embodiment,
the problem of generation of foreign matter due to alkali blooming is suppressed during
storage of the tube glass 21.
[0048] Next, the effects of the present embodiment will be described.
- (1) When the gas inside the tube glass 21 contains a large amount of moisture due
to the production process of the tube glass 21, dew condensation may occur on the
inner surface of the tube glass 21 depending on the storage environment of the tube
glass packaging body 10. In this case, an alkali component such as Na present in the
material of the tube glass 21 is eluted into the moisture deposited on the inner surface
of the tube glass 21. Then, when the moisture evaporates, the alkali component such
as Na precipitates, as powdery foreign matter, on the inner surface of the tube glass
21.
In the tube glass packaging body 10 of the present disclosure, the tube glass assemblies
20 and the dehumidifying agent 70 are disposed in the interior of the packaging film
80, and thus, when the gas present in the space inside the tube glass 21 contains
moisture, the moisture can be removed by the dehumidifying agent 70. As a result,
the tube glass packaging body 10 can suppress dew condensation on the inner surface
of the tube glass 21 and can also suppress generation of powdery foreign matter on
the tube glass 21, regardless of the storage condition.
- (2) The dehumidifying agent 70 is disposed between the packaging film 80 and the binding
film 23. That is, since the binding film 23 is interposed between the tube glass 21
and the dehumidifying agent 70, direct contact between the dehumidifying agent 70
and the tube glass 21 can be avoided. Accordingly, it is possible to avoid a problem
such as attachment of foreign matter to the tube glass 21 caused by, for example,
direct contact between the tube glass 21 and the dehumidifying agent 70.
- (3) Assuming a case where a gas containing moisture moves into the space inside the
packaging film 80, the gas is likely to pass through a gap between the tube glass
group 22 and the binding film 23 and enters the inside of the tube glass 21. That
is, in the tube glass group 22, the gas easily goes through a gap at a boundary between
the region covered with the binding film 23 and the region not covered with the binding
film 23, and moves into the interior of the tube glass 21. In the tube glass packaging
body 10, the dehumidifying agent 70 is disposed in the region of the binding film
23 covering the side surface of the tube glass group 22, and thus moisture can be
efficiently removed even when the gas moves into the space inside the packaging film
80 as in the case described above.
- (4) During the storage of the tube glass packaging body 10, the temperature inside
the tube glass packaging body 10 may rise due to a change in outside air temperature.
At this time, the gas heated in the packaging film 80 rises. In the tube glass packaging
body 10, the dehumidifying agent 70 is disposed in an upper region at the same level
as or above the middle position in the vertical direction of the stacked tube glass
assemblies, which makes it possible to efficiently remove the moisture contained in
the gas that rises by being heated in the packaging film 80.
- (5) The gas cooled in the packaging film 80 descends. In the tube glass packaging
body 10, the dehumidifying agent 70 is disposed in the lower region below the middle
position, which makes it possible to efficiently remove the moisture contained in
the gas descending by being cooled in the packaging film 80.
- (6) The longer the length of the tube glass 21, the slower the flow of air inside
the tube glass 21 becomes. However, according to the above-described tube glass packaging
body 10, even when the tube glass 21 to be packaged has a length of 500 mm or greater,
for example, the action and effect described above can be achieved.
[0049] The present embodiment can be modified as follows. The present embodiment and the
following modifications can be implemented in combination as long as there is no technical
contradiction.
· In the tube glass packaging body 10, the dehumidifying agent 70 may also be disposed
at a position different from the position described in the above embodiment as long
as the dehumidifying agent 70 is disposed inside the packaging film 80.
· For example, as illustrated in FIG. 7, a tube glass assembly 20A may include a dehumidifying
agent 70A disposed between at least one end surface of the tube glass group 22 and
a front surface of the binding film 23. In this case, it is preferable that the dehumidifying
agent 70A has a sheet shape. In the tube glass packaging body 10A according to the
modification example, the dehumidifying agent 70A can be disposed at a position very
close to an opening of the tube glass 21. Therefore, the tube glass packaging body
10A according to the modified example can efficiently remove moisture contained in
a gas inside the tube glass 21.
· The dehumidifying agent 70 may be disposed between the front surface of the binding
film 23 and the packaging film 80.
· The dehumidifying agent 70 may be disposed only in the vicinity of the tube glass
assembly 20 disposed at the lowermost layer, or may be disposed only in the vicinity
of the tube glass assembly 20 disposed at the uppermost layer. For example, the dehumidifying
agent 70 may be disposed on the uppermost second sheet 40 or may be disposed under
the first sheet 30.
· As long as one end of the tube glass 21 is open, the other end may not be open.
· The cross-sectional shape of the tube glass 21 orthogonal to the longitudinal direction
may not be circular. The cross-sectional shape of the tube glass 21 orthogonal to
the longitudinal direction may be, for example, elliptical or rectangular.
· The intended application, material, and shape of the tube glass 21 can be changed
from those listed in the above embodiment. Similarly, the number of tube glasses 21
forming the tube glass assembly 20 and the number of tube glass assemblies 20 forming
the tube glass packaging body 10 can be changed as appropriate.
Reference Signs List
[0050]
10, 10A: Tube glass packaging body
20, 20A, 20X: Tube glass assembly
21: Tube glass
22: Tube glass group
23: Binding film
30: First sheet
40: Second sheet
50: Protective member
60: Binding member
70, 70A: Dehumidifying agent
80: Packaging film
100: Pallet