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(11) |
EP 4 286 418 A8 |
(12) |
CORRECTED EUROPEAN PATENT APPLICATION |
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published in accordance with Art. 153(4) EPC |
(15) |
Correction information: |
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Corrected version no 1 (W1 A1) |
(48) |
Corrigendum issued on: |
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17.01.2024 Bulletin 2024/03 |
(43) |
Date of publication: |
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06.12.2023 Bulletin 2023/49 |
(22) |
Date of filing: 26.01.2022 |
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(51) |
International Patent Classification (IPC):
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(86) |
International application number: |
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PCT/CN2022/074017 |
(87) |
International publication number: |
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WO 2022/161402 (04.08.2022 Gazette 2022/31) |
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(84) |
Designated Contracting States: |
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AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL
NO PL PT RO RS SE SI SK SM TR |
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Designated Extension States: |
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BA ME |
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Designated Validation States: |
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KH MA MD TN |
(30) |
Priority: |
01.02.2021 CN 202110135415 01.02.2021 CN 202110135426 01.02.2021 CN 202110135239
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(71) |
Applicants: |
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- China Petroleum & Chemical Corporation
Beijing 100728 (CN)
- Sinopec Yangzi Petrochemical Co., Ltd.
Nanjing, Jiangsu 210048 (CN)
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(72) |
Inventors: |
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- LI, Chuanfeng
Nanjing, Jiangsu 210048 (CN)
- WANG, Wenrui
Nanjing, Jiangsu 210048 (CN)
- JING, Kun
Nanjing, Jiangsu 210048 (CN)
- XING, Yuejun
Nanjing, Jiangsu 210048 (CN)
- XIA, Huimin
Nanjing, Jiangsu 210048 (CN)
- CHEN, Minghua
Nanjing, Jiangsu 210048 (CN)
- YOU, Zhonglin
Nanjing, Jiangsu 210048 (CN)
- CHEN, Shaohui
Nanjing, Jiangsu 210048 (CN)
- ZHAI, Jianhong
Nanjing, Jiangsu 210048 (CN)
- GUO, Feng
Nanjing, Jiangsu 210048 (CN)
- YANG, Liu
Nanjing, Jiangsu 210048 (CN)
- MEI, Li
Nanjing, Jiangsu 210048 (CN)
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(74) |
Representative: Hoffmann Eitle |
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Patent- und Rechtsanwälte PartmbB
Arabellastraße 30 81925 München 81925 München (DE) |
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(54) |
ETHYLENE POLYMER AND PREPARATION METHOD THEREFOR |
(57) The present invention relates to an ethylene polymer and a process for preparing
the same, wherein the ethylene polymer has an average particle size of 50-3000 µm,
a bulk density of 0.28-0.55 g/cm
3, a true density of 0.930-0.980 g/cm
3, a melt index at a load of 2.16Kg at 190°C of 0.01-2500 g/lOmin, a crystallinity
of 30-90%, a melting point of 105-147°C, a comonomer molar insertion rate of 0.01-5
mol%, a weight-average molecular weight of 2 ×10
4 g/mol - 40 ×10
4 g/mol, and a molecular weight distribution of 1.8-10. In the preparation process,
raw materials containing ethylene, hydrogen gas and a comonomer are subjected to a
tank-type slurry polymerization with an alkane solvent having a boiling point of 5-55°C
or a mixed alkane solvent having a saturated vapor pressure of 20-150KPa at 20°C as
the polymerization solvent in the presence of a polyethylene catalytic system, at
the molar ratio of hydrogen gas to ethylene of 0.01-20:1, preferably 0.015-10:1, at
the molar ratio of hydrogen gas to the comonomer of 0.1-30:1, preferably 0.15-25:1
to prepare the ethylene polymer.