Technical Field
[0001] The present invention relates to a high-strength cold-rolled steel sheet used in
structural members with a large amount of forming, such as pillars, seat rails, members,
and the like, of a vehicle body and a method for manufacturing the same, and more
specifically to a high-strength cold-rolled steel sheet that has excellent surface
quality and low material deviation and can be suitably used for automotive parts and
method for a manufacturing the same.
Background Art
[0002] In recent years, as safety and environmental regulations are being strengthened in
the automobile industry, the use of high-strength steel with a tensile strength of
780 MPa or more is increasing when manufacturing vehicle bodies to improve vehicle
fuel efficiency and protect passengers.
[0003] High-strength steel used in conventional vehicle bodies includes a dual phase (DP)
steel, comprising dual phases, which are a soft ferrite matrix and hard martensite
phase, a transformation induced plasticity (TRIP) steel using transformation-induced
plasticity of retained austenite, a complex phase (CP) steel, comprising a complex
structure of ferrite and hard bainite or martensite, and the like.
[0004] However, in high-strength steel, when a large amount of Si, Al, Mn, or the like are
added, there may be a problem in that weldability is poor and surface defects of the
steel sheet occur due to dents in a furnace during annealing. In addition, when a
large amount of hardenable elements such as Mn, Cr, Mo, or the like are added, there
may be a problem in that material deviation of a hot-rolled coil occurs, so that thickness
quality may deteriorate during cold rolling. In this case, the surface defects due
to dents of the steel sheet in a furnace refer to surface defects of the steel sheet
formed when metal-based oxides on a surface of the steel sheet are adsorbed and accumulated
on rolls of an annealing furnace, and by contact between the steel sheet and the rolls
during rolling.
[0005] The contents of the prior art related to manufacturing technology of high-strength
cold-rolled steel sheets and hot-dip galvanized steel sheets to solve the above-described
problems are briefly described as follows.
[0006] Among the prior art, Patent Document 1 discloses a high-strength cold-rolled steel
sheet and a manufacturing method thereof, through a process of cold rolling a hot-rolled
steel sheet including a low-temperature transformation phase of 60% or more, by volume,
at a cold rolling reduction rate of more than 60% and less than 80%, and a process
of continuously annealing a steel sheet after cold rolling in a ferrite and austenite
dual-phase zone. However, the cold-rolled steel sheet obtained from Patent Document
1 had a strength as low as 370 to 590 MPa, causing a problem in that it is difficult
to be applied to vehicle impact-resistant members and limited to use only for interior
and exterior panels.
[0007] In addition, Patent Document 2 discloses a method of manufacturing a cold-rolled
steel sheet simultaneously obtaining high strength and high ductility by utilizing
a tempered martensite phase, and having an excellent plate shape after continuous
annealing. However, the technology of Patent Document 2 had a problem of poor weldability
due to a high carbon content in steel, which is 0.2% or more, and a problem of the
occurrence of surface defects due to dents in the furnace due to a large amount of
Si contained therein.
(Patent Document 1) Korean Patent Publication No. 2004-0066935
(Patent Document 2) Japanese Patent Publication No. 2010-090432
Summary of Invention
Technical Problem
[0008] An aspect of the present disclosure is to provide a high-strength cold-rolled steel
sheet having excellent surface quality and low material deviation and a method for
manufacturing thereof.
[0009] An object of the present disclosure is not limited to the above description. The
object of the present disclosure will be understood from the entire content of the
present specification, and a person skilled in the art to which the present disclosure
pertains will understand an additional object of the present disclosure without difficulty.
Solution to Problem
[0010] According to an aspect of the present disclosure, provided is a high-strength cold-rolled
steel sheet,
the high-strength cold-rolled steel sheet including: by weight%, C: 0.05 to 0.3%,
Si: 0.01 to 2.0%, Mn: 1.5 to 3.0%, Al: 0.01 to 0.1%, P: 0.001 to 0.015%, S: 0.001
to 0.01%, N: 0.001 to 0.01%, with a remainder of Fe, and other unavoidable impurities,
wherein a value defined by Relational Expression 1 satisfies 0.6 or more and less
than 0.9,
as a microstructure, by area%, ferrite: 50% or more, and a remainder including bainite
and martensite,
wherein an average number of surface defects satisfying one or more conditions of
a depth of 100 um or more and a short side length of 1 mm or more, is less than 10/m2.
[Relational Expression 1] C + (1.3×Si+Mn)/6 + (Cr+1.2×Mo)/5 + 100×
B
[0011] In Relational Expression 1, C, Si, Mn, Cr, Mo, and B represent an average weight
percentage for each element. when each of the above-described elements is not added,
0 is substituted.
[0012] According to another aspect of the present disclosure, provided is a method for manufacturing
a high-strength cold-rolled steel sheet,
the method, including reheating a steel slab including, by weight%: C: 0.05 to 0.3%,
Si: 0.01 to 2.0%, Mn: 1.5 to 3.0%, Al: 0.01 to 0.1%, P: 0.001 to 0.015%, S: 0.001
to 0.01%, N: 0.001 to 0.01%, with a remainder of Fe, and other unavoidable impurities,
wherein a value defined by Relational Expression 1 satisfies 0.6 or more and less
than 0.9, to a temperature within a range of 1100 to 1350°C;
hot rolling the reheated steel slab at a temperature within a range of 850 to 1150°C;
cooling the hot-rolled steel sheet to a temperature within a range of 450 to 700°C
at an average cooling rate of 10 to 70°C/s;
coiling the cooled steel sheet at a temperature within a range of 450 to 700°C;
cold rolling the wound steel sheet at a reduction rate of 40 to 70%; and
continuously annealing the cold-rolled steel sheet at a temperature within a range
of 740 to 900°C,
wherein in the coiling, based on an entire width of the steel sheet, a surface temperature
(Te) of both end portions in the width direction is controlled to satisfy 601 to 700°C,
and a surface temperature (Tc) of a center portion is controlled to satisfy 450 to
600°C.
[Relational Expression 1] C + (1.3×Si+Mn)/6 + (Cr+1.2×Mo)/5 + 100×B
[0013] In Relational Expression 1, C, Si, Mn, Cr, Mo and B represent an average weight percentage
of each element. In addition, if each of the above-described elements is not added,
0 is substituted.
Advantageous Effects of Invention
[0014] According to an aspect of the present disclosure, a high-strength cold-rolled steel
sheet having excellent surface quality and low material deviation and a manufacturing
method thereof may be provided.
[0015] Various and beneficial advantages and effects of the present disclosure are not limited
to the above-described content, and may be more easily understood through description
of specific embodiments of the present disclosure.
Brief Description of the Drawings
[0016]
FIG. 1 illustrates an image captured with a general low-magnification camera of surface
defects of each cold-rolled steel sheet obtained from Inventive Example 1 and Comparative
Example 1 of the present disclosure.
FIG. 2 illustrates an image captured with a high-magnification scanning cell microscope
(SEM) of the surface defects defined in the present disclosure.
Best Mode for Invention
[0017] Hereinafter, preferred embodiments of the present disclosure will be described. However,
the embodiments of the present disclosure can be modified into various other forms,
and the scope of the present disclosure is not limited to the embodiments described
below. In addition, the embodiments of the present disclosure are provided to more
completely explain the present disclosure to those with average knowledge in the related
technical literature.
[0018] Meanwhile, the terms used herein are intended to describe the present disclosure
and are not intended to limit the present disclosure. For example, the singular forms
used herein include the plural forms unless the related definition clearly dictates
the contrary. In addition, the meaning of "comprising" as used in the specification
specifies a component, and does not exclude the presence or addition of other components.
[0019] In the prior art, a technology has not been developed, the technology for satisfying
advanced demands for a cold-rolled steel sheet having high strength having a tensile
strength (TS) of 780 MPa or more and excellent formability and that can be applied
structural members with a large amount of forming, and having excellent surface quality
and low material deviation.
[0020] Accordingly, the present inventors conducted in-depth studies to provide a cold-rolled
steel sheet satisfying all of the above-described characteristics, while solving the
problems in the prior art, and as a result thereof, the present inventors have confirmed
that the above-described object could be achieved by optimizing the composition and
manufacturing conditions of the steel sheet, and thus the present disclosure was provided.
[0021] That is, according to the present disclosure, it is possible to provide a high-strength
cold-rolled steel sheet having a high strength of 780 MPa or more, a product of tensile
strength and elongation of 12,000 MPa% or more, and that can be suitably applied to
structural member parts such as pillars, or the like, requiring a stable strength-elongation
balance and impact absorption, among parts forming the vehicle body.
[0022] Hereinafter, a high-strength steel sheet having excellent surface quality and low
material deviation according to an aspect of the present disclosure will be described
in detail.
[0023] According to an aspect of the present disclosure, a high-strength cold-rolled steel
sheet includes, by weight%: C: 0.05 to 0.3%, Si: 0.01 to 2.0%, Mn: 1.5 to 3.0%, Al:
0.01 to 0.1%, P: 0.001 to 0.015%, S: 0.001 to 0.01%, N: 0.001 to 0.01%, with a remainder
of Fe, and other unavoidable impurities.
[0024] Hereinafter, the reason for which the components of the cold-rolled steel sheet are
added and the content thereof provided in the present disclosure is limited will be
described in detail. Unless otherwise particularly stated in the present disclosure,
the content of each element is by weight%.
Carbon (C): 0.05 to 0.3%
[0025] Carbon (C) is a very important element in securing a martensite structure, effective
in strengthening steel. When an amount of C added increases, a fraction of a martensite
phase and bainite phase increases, resulting in an increase in tensile strength. Therefore,
to ensure high strength, a lower limit of the C content is controlled to be 0.05%.
However, when the C content increases, an austenite region expands during dual-phase
zone annealing, so the fraction of the martensite phase and bainite phase, which are
hard phases, increases, and a fraction of a ferrite phase, which is a soft phase,
decreases, resulting in inferior formability and weldability. Therefore, an upper
limit of the C content is controlled to be 0.3%. Meanwhile, in terms of further improving
the above-described effect, more preferably, the lower limit of the C content may
be 0.06%, or the upper limit of the C content may be 0.12%.
Silicon (Si): 0.01 to 2.0%
[0026] Silicon (Si) is an element, deoxidizing molten steel and having a solid-solution
strengthening effect, which is advantageous for improving formability by delaying
formation of coarse carbides. However, when the Si content is less than 0.01%, the
above-described effect is low, making it difficult to improve formability. On the
other hand, when the Si content exceeds 2.0%, red scales due to Si is severely formed
on a surface of the steel sheet during hot rolling. As a result, surface defects occur,
or surface thickening occurs during an annealing process, so that non-plating occurs.
In addition, there is a problem in that plating adhesion becomes poor due to the formation
of surface oxide, and the surface quality becomes very poor. Therefore, in the present
disclosure, a Si content is controlled to be 0.01 to 2.0%. Meanwhile, in terms of
further improving the above-described effect, more preferably, a lower limit of the
Si content may be 0.4%, or an upper limit of the Si content may be 1.2%.
Manganese (Mn): 1.5 to 3.0%
[0027] Manganese (Mn), like Si, is an element, which is effective in solid-solution strengthening
steel, and is an element greatly increasing hardenability. However, when a Mn content
is less than 1.5%, the above-described effects due to addition cannot be obtained,
and when the Mn content exceeds 3.0%, the strengthening effect greatly increases and
ductility decreases. In addition, during slab casting in a continuous casting process,
a segregated portion develops significantly in a thickness center portion, and during
cooling after hot rolling, a microstructure thereof in a thickness direction becomes
non-uniform and MnS is formed, resulting in poor formability such as stretch flangeability,
or the like. Therefore, in the present disclosure, the Mn content is controlled to
1.5 to 3.0%. Meanwhile, in terms of further improving the above-described effect,
more preferably, a lower limit of the Mn content may be 1.8%, or an upper limit of
the Mn content may be 2.6%.
Aluminum (Al): 0.01 to 0.1%
[0028] Aluminum (Al) is a component, mainly added for deoxidation. When the Al content is
less than 0.01%, an addition effect thereof is insufficient. On the other hand, when
the Al content exceeds 0.1%, AlN is formed in combination with nitrogen, so it is
likely to cause corner cracks in the slab during continuous casting, and it is likely
to cause defects due to inclusion formation. Therefore, in the present disclosure,
the Al content is controlled to 0.01 to 0.1%. Meanwhile, in terms of further improving
the above-described effect, more preferably, a lower limit of the Al content may be
0.015%, or an upper limit of the Al content may be 0.06%.
Phosphorus (P): 0.001 to 0.015%
[0029] Phosphorus (P) is an alloy element having a significant solid-solution strengthening
effect and may have a characteristic of achieving a significant solid-solution strengthening
effect even with a small content thereof. However, P is added excessively, brittleness
may occur due to grain boundary segregation, microcracks are likely to occur during
forming, and ductility and impact resistance are greatly deteriorated. In addition,
there may be a problem of causing defects on a surface thereof during plating. Therefore,
an upper limit of a P content is controlled to be 0.015%. Meanwhile, if the P content
is less than 0.001%, excessive manufacturing costs may be required to satisfy this
value, which is not only economically disadvantageous, but also secured strength is
insufficient, so a lower limit of the P content is controlled to be 0.001% or more.
Therefore, in the present disclosure, it is preferable to control the P content to
be 0.001 to 0.015%. Meanwhile, in terms of further improving the above-described effect,
more preferably, a lower limit of the P content may be 0.003%, or an upper limit of
the P content may be 0.012%.
Sulfur (S): 0.001 to 0.01%
[0030] Sulfur (S) is an impurity present in steel. When a S content exceeds 0.01%, S combines
with Mn to form non-metallic inclusions, and as a result, there is a problem in that
fine cracks are likely to occur during cutting and processing of steel, and extension
flangeability and impact resistance are greatly reduced. In addition, in order to
form the S content to be less than 0.001%, there is a problem in that a large amount
of time is required during steelmaking operation, which reduces productivity. Therefore,
in the present disclosure, it is preferable to control the S content to 0.001 to 0.01%.
Meanwhile, in terms of further improving the above-described effect, more preferably,
a lower limit of the S content may be 0.002%, or an upper limit of the S content may
be 0.007%.
Nitrogen (N): 0.001 to 0.01%
[0031] Nitrogen (N) is a representative solid-solution strengthening element along with
C, and contributes to forming coarse precipitates along with Ti and Al. In addition,
a solid-solution strengthening effect of N is better than that of carbon, but there
is a problem in that toughness decreases significantly as an amount of N in steel
increases. In addition, in order to manufacture a N content to be less than 0.001%,
there is a problem that productivity is reduced because a large amount of time is
required during steelmaking operation. Therefore, in the present disclosure, it is
preferable to control the N content to be 0.001 to 0.01%. Meanwhile, in terms of further
improving the above-described effect, more preferably, a lower limit of the N content
may be 0.002%, and an upper limit of the N content may be 0.006%.
[0032] Meanwhile, according to an aspect of the present disclosure, although not particularly
limited, optionally, the cold-rolled steel sheet may include, by weight%: one or more
elements selected from Cr: 1.0% or less (including 0%), Mo: 0.2% or less (including
0%), and B: 0.005% or less (including 0%). Hereinafter, the reason for which the selected
element are added and the content thereof provided in the present disclosure is limited
will be described in detail.
Chromium (Cr): 1.0% or less (excluding 0%)
[0033] Chromium (Cr) is a component added to improve hardenability of steel and ensure high
strength, and is an element that plays a very important role in formation of martensite,
which is also advantageous for manufacturing composite steel with high ductility by
minimizing a decrease in elongation compared to an increase in strength. Therefore,
Cr may be selectively added for the above-described effect. However, if the Cr content
exceeds 1.0%, not only are the above-described effects saturated, but there is a problem
in that cold rolling properties are deteriorated due to an excessive increase in hot
rolling strength. In addition, since there is a problem that a fraction of martensite
increases significantly after annealing, resulting in a decrease in elongation, an
upper limit of the Cr content is controlled to be 1.0% or less. Meanwhile, in terms
of further improving the above-described effect, more preferably, a lower limit of
the Cr content may be 0.01%, or an upper limit of the Cr content may be 0.8%.
Molybdenum (Mo): 0.2% or less (including 0%)
[0034] Molybdenum (Mo) is an element that suppresses pearlite formation and increases hardenability.
Therefore, in order to secure the above-described effects, Mo may be selectively added
in the present disclosure. However, if a Mo content exceeds 0.2%, an effect of improving
strength does not increase significantly, but ductility deteriorates, which may be
economically disadvantageous. Therefore, it is preferable to control the Mo content
to be 0.2% or less. Meanwhile, in terms of further improving the above-described effect,
more preferably, a lower limit of the Mo content may be 0.01%, or an upper limit of
the Mo content may be 0.1%.
Boron (B): 0.005% or less (including 0%)
[0035] When boron (B) exists in a solid state in steel, B has an effect of improving brittleness
of steel in a low-temperature range by stabilizing grain boundaries, and greatly increases
hardenability of steel. Therefore, B can be selectively added for the above-described
effect. However, if an upper limit of the B content exceeds 0.005%, recrystallization
is delayed during annealing and oxides are formed on a surface thereof, resulting
in poor plating properties. Therefore, it is preferable to control the B content to
be 0.005% or less. Meanwhile, in terms of further improving the above-mentioned effect,
more preferably, a lower limit of the B content may be 0.0003%, or an upper limit
of the B content may be 0.0025%.
[0036] The remaining component of the present disclosure is iron (Fe). However, since in
the common manufacturing process, unintended impurities may be inevitably incorporated
from raw materials or the surrounding environment, the component may not be excluded.
Since these impurities are known to any person skilled in the common steelmaking manufacturing
process, the entire contents thereof are not particularly mentioned in the present
specification.
[0037] According to an aspect of the present disclosure, the high-strength cold-rolled steel
sheet may have a value defined by Relational Expression 1 of 0.6 or more and less
than 0.9, and by satisfying this value, a desired material may be secured by minimizing
the material deviation of the cold-rolled steel sheet and suppressing the occurrence
of surface defects.

[0038] In Relational Expression 1, C, Si, Mn, Cr, Mo and B represent an average weight percentage
for each element. In this case, when each of the above-described elements is not added,
0 is substituted.
[0039] In the present disclosure, Relational Expression 1 is an expression representing
hardenability of a steel material according to the composition of the present disclosure,
and a coefficient in front of each element quantitatively represents a scale by which
the element contributes to hardenability. If the hardenability of the steel material
is high, it is advantageous to secure hard low-temperature transformation phases such
as bainite phase and martensite phase, which contributes to improving strength. The
lower the hardenability is, ferrite transformation is promoted, which is disadvantageous
in securing strength.
[0040] In particular, in order to secure high strength of 780 MPa or more, which is a target
tensile strength (TS) in the present invention, a value defined from Relational Expression
1 should satisfy 0.6 or more. On the other hand, if the value defined from Relational
Expression 1 is 0.9 or more, the strength becomes too high, so there is a problem
in that an elongation rate deteriorates. In addition, if the value defined by Relational
Expression 1 is 0.9 or more, phase transformation of ferrite is significantly delayed
in an operation of cooling a hot-rolled steel sheet, immediately after hot rolling,
to a temperature within a range of 450 to 700°C at an average cooling rate of 10 to
70°C/s. Accordingly, in a subsequent coiling, among bainite phases in the hot-rolled
steel sheet, a lower bainite phase having high hardness and a martensite phase are
excessively formed, causing material deviation depending on a position thereof in
a width direction to worsen and a shape thereof to deteriorate. Therefore, in the
present disclosure, it is preferable to control the value defined by Relational Expression
1 to satisfy 0.6 or more and less than 0.9. Meanwhile, in terms of maximizing the
above-described effect, a lower limit of the value defined from Relational Expression
1 may be 0.62, or an upper limit of the value defined from Relational Expression 1
may be 0.84.
[0041] Meanwhile, according to an aspect of the present disclosure, the high-strength cold-rolled
steel sheet includes: by area, as a microstructure, ferrite: 50% or more, and a remainder:
bainite and martensite. In the microstructure, if ferrite is less than 50%, there
is a problem of poor formability due to insufficient elongation. In addition, the
remainder, which is bainite and martensite, may be 50% or less. If the sum of bainite
and martensite exceeds 50%, there is a problem of excessively high strength and insufficient
elongation.
[0042] Alternatively, according to an aspect of the present disclosure, although not particularly
limited thereto, in terms of improving elongation and formability, the microstructure
of the high-strength cold-rolled steel sheet may include, by area: ferrite: 50 to
85% and bainite and martensite, and a sum of bainite and martensite: 15 to 50%.
[0043] Among the high-strength cold-rolled steel sheets, if ferrite exceeds 85%, a target
strength may not be achieved, and if the sum of bainite and martensite is less than
15%, the target strength may not be achieved. Meanwhile, in terms of further improving
the above-described effect, the microstructure of the high-strength cold-rolled steel
sheet may more preferably include, by area: ferrite: 66 to 75%.
[0044] In addition, according to an aspect of the present disclosure, although not particularly
limited thereto, the microstructure of the high-strength cold-rolled steel sheet,
may include, by area: bainite: 3 to 7% and/or martensite: 19 to 31%. Among the high-strength
cold-rolled steel sheets, if bainite is less than 3%, a target strength may not be
achieved, and if bainite exceeds 7%, there may be a problem in that the strength is
high but the elongation is low.
[0045] According to an aspect of the present disclosure, the high-strength cold-rolled steel
sheet has an average number of surface defects satisfying one or more conditions of
a depth of 100 um or more and a short side length of 1 mm or more of less than 10/m
2 (including 0/m
2). In measuring the average number of surface defects, the conditions that the 'depth
is 100 um or more' or 'short side length is 1mm or more' are merely sufficient determination
criteria as long as they are satisfiedto measure the average number of surface defects.
Therefore, in this specification, an upper limit value for each of the depth and short
side length described above is not particularly limited.
[0046] In the present disclosure, a surface defect refers to a defect having a groove shape,
and specifically, a defect in a form of a dent in a thickness direction, which is
a defect that can be confirmed when observing the surface of the steel sheet with
a naked eye. In addition, the depth of the surface defect may mean a 'maximum depth'
in the thickness direction for the defect having the groove shape, based on a cross-section
of the cold-rolled steel sheet in the thickness direction (i.e., a direction perpendicular
to a rolling direction, based on the cross-section). In addition, the short side length
of the surface defect may mean a shortest length passing through a point of the maximum
depth, based on the surface of the cold-rolled steel sheet. Meanwhile, in order to
observe surface defect having the groove shape existing on the surface of the above-described
steel sheet and confirm the depth and short side length of each surface defect, an
image captured using a high-magnification scanning electron microscope (SEM) is shown
in FIG. 2.
[0047] The present inventors have repeatedly conducted extensive research to solve the problems
in the prior art, and to provide a cold-rolled steel sheet that can minimize surface
defects and material deviation while securing a desired level of strength and formability.
[0048] As a result thereof, the present inventors have found that the above-described effects
may be secured, by controlling that an average number of surface defects satisfying
one or more of the above-described depth is 100 um or more and short side length of
1mm or more to be less than 10/m
2. That is, in the present disclosure, if the average number of surface defects is
10/m
2 or more, a problem of surface dents may occur. Meanwhile, in terms of further improving
the above-described effect, preferably, the average number of surface defects described
above may be 8/m
2 or less.
[0049] Meanwhile, according to an aspect of the present disclosure, the present inventors
have repeatedly conducted additional research to provide a cold-rolled steel sheet
that can simultaneously secure a desired level of strength and formability without
affecting material deviation, or the like, even if there are surface defects in the
surface of the steel sheet. As a result thereof, in the present disclosure, the present
inventors have additionally found that surface defect characteristics at a level,
without affecting material deviation, or the like, even if surface defects exist.
Specifically, although not particularly limited in the present disclosure, a maximum
depth of the surface defects may be 500 um or less. In this case, the maximum depth
of the surface defects may be a maximum value of the depth for each surface defect
existing on the surface of the steel sheet.
[0050] Meanwhile, according to an aspect of the present disclosure, a difference in yield
strength (YS) between both end portions and a center portion in a width direction
of the cold-rolled steel sheet may be 100 MPa or less. By satisfying the difference
in the yield strength between both end portions and the center portion to be 100 MPa
or less, a steel sheet having reduced material deviation in the width direction may
be provided, and a material thereof may be uniform in the width direction. In this
case, the 'both end portions' may refer to sections, corresponding 30% (corresponding
to a sum of: 60%) from both ends based on a total width (referred to as 100%) of the
cold-rolled steel sheet in a width direction thereof, and the 'center portion' may
refer to a section, corresponding to 40% excluding the both end portions, based on
the total width of the cold-rolled steel sheet in the width direction thereof.
[0051] Meanwhile, according to an aspect of the present disclosure, the cold-rolled steel
sheet may have a tensile strength (TS) of 780 MPa or more, preferably 780 MPa or more
and less than 1180 MPa, and more preferably 800 MPa or more and 1100 MPa or less.
If the tensile strength of the cold-rolled steel sheet is less than 780 MPa, there
may be a problem in that the target strength required for parts applied thereto, may
not be achieved, and if the tensile strength of the cold-rolled steel sheet exceeds
1100 MPa, there may be a problem in that cracks occur during molding parts, or impact
resistant of the parts is significantly reduced.
[0052] In addition, according to an aspect of the present disclosure, the cold-rolled steel
sheet may have a yield strength (YS) of 380MPa or more, and more preferably 390 MPa
or more and 650 MPa or less. If the yield strength of the cold-rolled steel sheet
is less than 380 MPa, there may be a problem in that impact resistance of the parts
deteriorates, and if the yield strength of the cold-rolled steel sheet exceeds 650
MPa, there may be a problem in that formability deteriorates.
[0053] In addition, according to an aspect of the present disclosure, the cold-rolled steel
sheet has a product of tensile strength and elongation of 12,000 MPa% or more (more
preferably, 12,000 MPa% or more and 16,500 MPa% or less, most preferably 12,000 MPa%
or more and 16,200 MPa% or less). By satisfying the above-described physical properties,
it is possible to secure an effect that can be suitably applied to structural member
parts such as a filler, or the like, requiring a stable strength-elongation balance
and impact absorption among the parts constituting the vehicle body.
[0054] Although not particularly limited thereto, the cold-rolled steel sheet may optionally
further include a plating layer formed on the surface. In this case, the plating layer
may be formed through a plating process described later. In addition, since the composition
of the plating layer can be applied differently depending on the purpose thereof,
it is not particularly limited in this specification, and an example of the plating
layer includes a zinc-based plating layer.
[0055] Hereinafter, a manufacturing method of a high-strength cold-rolled steel sheet according
to an aspect of the present disclosure will be described in detail. However, the manufacturing
method of the cold-rolled steel sheet according to the present disclosure does not
necessarily mean that it should be manufactured by the following manufacturing method.
Steel slab reheating
[0056] A steel slab satisfying the above-described composition is reheated to a temperature
of 1100 to 1350°C. The composition of the steel slab is the same as that of the cold-rolled
steel sheet described above, and in this case, the description for the above-described
cold-rolled steel sheet is equally applied to a reason for adding each component and
limiting a content thereof in the steel slab. Meanwhile, when a reheating temperature
of the steel slab is less than 1100°C, segregated alloy elements in a center portion
of the slab remain, and an initiation temperature of hot rolling is too low, causing
a problem in increased rolling load. On the other hand, when the reheating temperature
of the steel slab exceeds 1350°C, there is a problem in that strength is reduced due
to coarsening of austenite grains. Therefore, in the present disclosure, the reheating
temperature of the steel slab is preferably controlled to 1100 to 1350°C.
Hot rolling
[0057] The reheated steel slab is hot rolled at a temperature of 850 to 1150°C. When the
temperature of hot rolling exceeds 1150°C, a temperature of a hot-rolled steel sheet
increases, so a size of grains becomes coarse, surface quality of the hot-rolled steel
sheet deteriorates. When the temperature of hot rolling is less than 850°C, due to
development of stretched grains due to excessive recrystallization delay, a load during
rolling increases and a temperature at both ends decreases significantly, so an uneven
microstructure during cooling is formed, thereby increasing material deviation and
deteriorating formability.
Cooling, after hot rolling
[0058] The hot-rolled steel sheet is cooled to a temperature of 450 to 700°C at an average
cooling rate of 10 to 70°C/s (more preferably, to a temperature of 20 to 50°C/s).
When a cooling temperature of the hot-rolled steel sheet is less than 450°C, there
is a problem in that material deviation deteriorates, and when the cooling temperature
exceeds 700°C, there is a problem in that not only does material deviation occur,
but also internal oxidation of the hot-rolled steel sheet occurs, causing surface
defects. In addition, when the average cooling rate is less than 10°C/s, there is
a problem in that crystal grains of a matrix structure become coarse, and a microstructure
becomes non-uniform. In addition, when the average cooling rate exceeds 70°C/s, there
is a problem in that bainite and martensite phases are easily to be formed, causing
increased load during cold rolling.
Coiling
[0059] The cooled steel sheet is wound at a temperature of 450 to 700°C. when a coiling
temperature is less than 450°C and the steel sheet is cooled and wound, bainite and
martensite phases are formed unnecessarily in steel, resulting in non-uniform shapes
and a significant increase in rolling load during cold rolling. when the coiling temperature
exceeds 700°C, ferrite crystal grains becomes larger and a coarse pearlite phase is
easily formed, resulting in forming non-uniform microstructure during annealing, resulting
in a problem of poor formability of steel. In addition, hot-rolled oxides increase
and are adsorbed on a roll during annealing, causing oxides to accumulate in the roll.
When the steel sheet is rolled, there is a problem causing surface defects such as
dent defects on a surface of the steel sheet due to friction between the steel sheet
and the roll. In addition, when hot-rolled oxides remain on the steel sheet, plating
quality and plating adhesion are deteriorated during plating of the steel sheet.
[0060] Typically, after the coiling, cooling proceeds rapidly in both end portions in a
width direction of the wound steel sheet (coil) due to exposure to surrounding atmosphere,
and cooling proceeds slowly in a center portion in the width direction thereof. As
a result, cooling deviation occurs in the width direction of the steel sheet from
the coiling, which causes a difference in microstructure in each position of the wound
steel sheet, ultimately resulting in material deviation for the hot- rolled steel
sheet. In a hot-rolled steel sheet having such high material deviations, in a process
of perform cold rolling, not only does the material deviation of the hot-rolled steel
sheet become worse, but surface defects having a form of grooves, which were not observed
with a naked eye in hot-rolled steel sheet become worse after performing cold rolling,
resulting in a problem of large surface defects occurring. In other words, the hot-rolled
steel sheet having high material deviation not only has inferior shapes during cold
rolling, but also causes material deviation in each position in a width direction
in a final annealed material. Therefore, the present inventors conducted intensive
research to solve the above-described problem. As a result thereof, a manufacturing
method, is provided to control the temperatures in both end portions and in the center
portion, differently during the coiling.
[0061] Specifically, in the present disclosure, as a method for reducing material deviation
of the steel sheet in the width direction, and suppressing surface defects, during
the coiling, based on an entire width of the steel sheet, a surface temperature (Te)
of both end portions in the width direction is controlled to satisfy 601 to 700°C,
and a surface temperature (Tc) of a center portion is controlled to satisfy 450 to
600°C. In this case, the `width direction of the steel sheet' refers to a direction
perpendicular to a transport direction of the steel sheet based on a surface of the
steel sheet. In addition, the above-description is equally applied to the both end
portions and the center portion.
[0062] In this case, if Te is less than 601°C, there is a problem in that material deviation
is worsened due to overcooling at both ends, and if Te exceeds 700°C, there is a problem
in that material deviation and surface defects are worsened due to deterioration of
the center portion. In addition, if Tc is less than 450 °C, a difference in the temperatures
between the center portion and both end portions increases, causing a problem in that
the material deviation worsens, and if Tc exceeds 600°C, the temperature in the center
portion is too high, causing a problem of material deviation and surface defects.
[0063] As described above, in the above-described coiling, in order to differently control
a surface temperature in both end portions and a surface temperature in a center portion
of the steel sheet in a width direction thereof, various methods can be applied, so
this is not particularly limited. For example, during the coiling, in order to control
the temperatures in both end portions and in the center portion of the steel sheet
differently, in the cooling before coiling, a coolant provided onto both ends may
be blocked before reaching the steel sheet, an amount of coolant provided thereonto
may be controlled differently, and the two methods described above, may be used in
parallel. As an example, according to an aspect of the present disclosure, in the
cooling before the coiling, based on a total width of the steel sheet, an amount of
coolant provided into the center portion excluding the both end portions may be controlled
to be greater than an amount of coolant provided onto the both end portions in the
width direction.
[0064] In addition, according to an aspect of the present disclosure, although not particularly
limited thereto, in terms of further improving the effect of further reducing material
deviation and suppressing surface defects, in the coiling, a difference (Te-Tc) between
the surface temperature of both end portions and the surface temperature (Tc) of the
center portion may be 150°C or less. In this case, if the value of Te-Tc exceeds 150°C,
a problem of worsening material deviation in the width direction may occur. However,
the lower the temperature deviation calculated from Te-Tc, the more desirable it is,
so a lower limit thereof may not be specifically limited, and may be preferably 0°C.
Meanwhile, more preferably, the lower limit of the Te-Tc value may be 50°C, and an
upper limit of the Te-Tc value may be 90°C.
Maintaining within heat retaining cover
[0065] After the above-described coiling operation, optionally, a steel sheet may be moved
into a heat retaining cover and maintained at a temperature of 400 to 500°C for more
than 6 hours. After the coiling operation, by being maintained in the heat retaining
cover for a long period of time, if the steel sheet is maintained for a long period
of time at a temperature in a range of 601 to 700°C and 450 to 600°C in both end portions
and in a center portion of the steel sheet, respectively, a large amount of bainite
structure is formed uniformly in both end portions and in the center portion due to
an overall length of a coil, so that it is possible to manufacture a cold-rolled steel
sheet having excellent shape quality and low rolling load and uniform thickness during
cold rolling.
[0066] During the maintenance operation within heat retaining cover, a surface temperature
of the steel sheet can be adjusted to a temperature within a range of 450 to 500°C.
In this case, in the maintenance operation within the heat retaining cover, if the
surface temperature of the steel plate is less than 400°C, the above-described effect
cannot be secured, and if the surface temperature of the steel plate exceeds 500°C,
coarse carbides are formed locally and hot-rolled oxides increase, which may deteriorate
the formability and surface quality of steel.
[0067] In addition, if a holding time within the heat retaining cover is less than 6 hours,
a problem of material deviation may occur. An upper limit of the holding time within
the heat retaining cover is not particularly limited, but may be 8 hours or less as
an example.
[0068] Additionally, in terms of further improving the above-described effect, the wound
steel sheet can be stored in the heat retaining cover within 90 minutes, immediately
after being wound. if a time before being stored in the heat retaining cover exceeds
90 minutes, due to excessive air cooling, overcooling may occur in the center portion
in the width direction, making it impossible to meet the temperature range of 450
to 600°C. Alternatively, after the maintenance operation within the heat retaining
cover, air cooling or water cooling may be further performed to room temperature.
Cold rolling
[0069] Cold rolling is performed on the wound steel sheet at a cold rolling reduction rate
of 40 to 70%. If the cold rolling reduction rate is less than 40%, not only is it
difficult to secure a target thickness but it is also difficult to correct a shape
of the steel sheet. On the other hand, if the cold rolling reduction rate exceeds
70%, there is a high possibility of cracks occurring in an end portion of the steel
sheet, and there is a problem of cold rolling load. Therefore, in the present disclosure,
it is preferable to limit the cold rolling reduction rate to 40 to 70%.
Annealing
[0070] The cold-rolled steel sheet is continuously annealed at a temperature of 740 to 900°C.
If the annealing temperature is less than 740°C, non-recrystallization may occur,
resulting in insufficient strength and elongation. If the annealing temperature exceeds
900°C, there may be a problem in that surface oxides occur. Meanwhile, in terms of
further improving the above-described effect, the annealing temperature may be more
preferably 750 to 850°C.
[0071] In addition, although not particularly limited thereto, according to an aspect of
the present disclosure, after the continuous annealing operation, optionally, an operation
of primary cooling to 650 to 700°C at a cooling rate of 1 to 10°C/sec; and after the
primary cooling operation, and an operation of secondary cooling from Ms-100°C to
Ms+100°C at a cooling rate of 11 to 20°C/sec may be further included. In addition,
after the secondary cooling operation, optionally, an operation of overaging may be
further included while keeping a temperature constant. By satisfying the conditions
of the primary cooling operation; the secondary cooling operation, and the overaging
operation, strength and elongation may be further improved. In this case, Ms may mean
a starting temperature at which martensite is generated when the steel sheet is cooled
after annealing, and may be obtained from Relational Expression 2.

[0072] In Relational Expression 2, C, Mn, Cr, Ni, and Mo represent an average weight percentage
for each element. In this case, when each of the above-described elements is not added,
0 is substituted.
[0073] In addition, according to an aspect of the present disclosure, optionally, an operation
of plating (preferably, hot-dip galvanizing) the cold-rolled steel sheet may be further
included, and a plated steel sheet can be obtained by performing the plating.
Mode for Invention
[0074] Hereinafter, the present disclosure will be specifically described through the following
Examples. However, it should be noted that the following Examples are only for describing
the present disclosure in detail by illustration, and are not intended to limit the
right scope of the present disclosure. The reason is that the right scope of the present
disclosure is determined by the matters described in the claims and reasonably inferred
therefrom.
(Example)
[0075] A steel slab satisfying the composition in Table 1 below were reheated at a temperature
of 1200°C, hot rolled at a temperature of 900°C, and cooled to a temperature of 450
to 700°C at a cooling rate of 20 to 50°C/s and then wound. In this case, during the
coiling, based on a total width in a width direction of a steel sheet, an amount of
coolant provided onto a center portion excluding the both end portions was controlled
to be greater than an amount of coolant provided onto the both end portions of the
steel sheet in the width direction, so that a surface temperature (Te) of the steel
sheet in both end portions of sections, corresponding to 30% from both ends and a
surface temperature (Tc) in a center portion of remaining sections, corresponding
40% from both ends satisfy the hot rolling conditions shown in Table 2 below. In addition,
the wound hot-rolled steel sheet was moved into a heat retaining cover and as heat
retaining cover conditions shown in Table 2 below, the wound hot-rolled steel sheet
was controlled to satisfy an average temperature and holding time before and after
being charged into a cover. Subsequently, the hot-rolled steel sheet was cold rolled
at a cold rolling reduction rate of 50%, subjected to continuous cooling at a temperature
of 800°C, primarily cooled to a temperature of 670°C at an average cooling rate of
8°C/s, and then secondarily cooled to a temperature of Ms+100°C at an average cooling
rate 12°C/s, to obtain a cold-rolled steel sheet.
[0076] For each cold-rolled steel sheet obtained in this manner, a microstructure, mechanical
properties, an average number of surface defects per unit area (number/m
2) observed on a surface of the steel sheet, in Inventive Example and Comparative Example,
were measured and shown in Tables 3 to 5 below. In this case, YS, TS, and El mean
0.2% off-set yield strength, tensile strength, and elongation at break, respectively,
which illustrates that test results obtained by collecting JIS No. 5 standard test
specimens from the center portion and both end portions in a direction, respectively,
in a direction perpendicular to a rolling direction. In addition, the above-described
microstructure was measured using a scanning electron microscope (FE-SEM), and the
microstructure was measured using a photograph observed at 3,000 to 5,000 times magnification,
by area %. In addition, the average number of surface defects was measured by observing
a surface of the manufactured steel sheet with a naked eye and satisfying one or more
conditions of a depth of 100 um or more and a short side length of 1 mm or more. In
particular, a maximum depth for the surface defects was measured in the same manner
as described herein. In addition, for samples taken from the center portion and both
ends of the cold-rolled steel sheet in a width direction, the yield strength was measured
in the same manner as described above, and the material deviation for these samples
in the width direction was measured and shown in Tables 4 and 5 below.
[Table 1]
Classifi cation |
COMPOSITION [WEIGHT %] (REMAINDER OF FE AND IMPURITIES) |
RELATIO NAL EXPRESS ION 1 |
C |
Si |
Mn |
Cr |
Mo |
B |
Al |
P |
S |
N |
INVENTIV E STEEL 1 |
0.1 |
0.4 |
2.5 |
0.1 |
0 |
0 |
0.0 3 |
0.0 10 |
0.0 02 |
0.0 04 |
0.62 |
INVENTIV E STEEL 2 |
0.0 6 |
0.9 |
2.4 |
0.1 |
0.0 2 |
0.0 007 |
0.0 25 |
0.0 08 |
0.0 03 |
0.0 05 |
0.75 |
INVENTIV E STEEL 3 |
0.1 2 |
1.2 |
2.6 |
0 |
0.1 |
0 |
0.0 35 |
0.0 09 |
0.0 04 |
0.0 02 |
0.84 |
COMPARAT IVE STEEL 1 |
0.1 8 |
2.1 |
2.2 |
0 |
0 |
0 |
0.0 4 |
0.0 09 |
0.0 05 |
0.0 04 |
1.00 |
COMPARAT IVE STEEL 2 |
0.0 9 |
0.9 |
1.7 |
0 |
0 |
0 |
0.1 |
0.0 Oil |
0.0 07 |
0.0 03 |
0.57 |
[Table 2]
Classification |
COILING CONDITION |
HEAT RETAINING COVER CONDITION |
Te (°C) |
Tc (°C) |
Te-Tc (°C) |
TEMPERATURE (°C) |
TIME (hr) |
INVENTIVE STEEL 1 |
INVENTIVE EXAMPLE 1 |
650 |
580 |
70 |
480 |
8 |
INVENTIVE EXAMPLE 2 |
680 |
590 |
90 |
450 |
7 |
COMPARATIVE EXAMPLE 1 |
720 |
650 |
70 |
490 |
7 |
COMPARATIVE EXAMPLE 2 |
580 |
400 |
180 |
420 |
8 |
COMPARATIVE EXAMPLE 3 |
610 |
490 |
120 |
NOT APPLIED |
COMPARATIVE EXAMPLE 4 |
650 |
590 |
60 |
570 |
10 |
INVENTIVE STEEL 2 |
INVENTIVE EXAMPLE 3 |
640 |
570 |
75 |
490 |
8 |
INVENTIVE EXAMPLE 4 |
680 |
590 |
90 |
450 |
7 |
COMPARATIVE EXAMPLE 5 |
720 |
650 |
70 |
490 |
7 |
COMPARATIVE EXAMPLE 6 |
580 |
400 |
180 |
420 |
8 |
COMPARATIVE EXAMPLE 7 |
610 |
490 |
120 |
NOT APPLIED |
COMPARATIVE EXAMPLE 8 |
650 |
590 |
60 |
570 |
10 |
INVENTIVE STEEL 3 |
INVENTIVE EXAMPLE 5 |
640 |
570 |
75 |
490 |
8 |
INVENTIVE EXAMPLE 6 |
680 |
590 |
90 |
450 |
7 |
COMPARATIVE EXAMPLE 9 |
720 |
650 |
70 |
490 |
7 |
COMPARATIVE EXAMPLE 10 |
580 |
400 |
180 |
420 |
8 |
COMPARATIVE EXAMPLE 11 |
610 |
490 |
120 |
NOT APPLIED |
COMPARATIVE EXAMPLE 12 |
650 |
590 |
60 |
570 |
10 |
COMPARATIVE STEEL 1 |
COMPARATIVE EXAMPLE 13 |
650 |
580 |
70 |
480 |
8 |
COMPARATIVE EXAMPLE 14 |
680 |
590 |
90 |
450 |
7 |
COMPARATIVE STEEL 2 |
COMPARATIVE EXAMPLE 15 |
650 |
580 |
70 |
480 |
8 |
COMPARATIVE EXAMPLE 16 |
680 |
590 |
90 |
450 |
7 |
[Table 3]
Classification |
MICROSTRUCTURE [AREA %] |
FERRITE |
BAINITE |
MARTENSIT E |
INVENTIVE STEEL 1 |
INVENTIVE EXAMPLE 1 |
75 |
5 |
20 |
INVENTIVE EXAMPLE 2 |
74 |
7 |
19 |
COMPARATIVE EXAMPLE 1 |
73 |
6 |
21 |
COMPARATIVE EXAMPLE 2 |
77 |
4 |
19 |
COMPARATIVE EXAMPLE 3 |
79 |
2 |
19 |
COMPARATIVE EXAMPLE 4 |
77 |
6 |
17 |
INVENTIVE STEEL 2 |
INVENTIVE EXAMPLE 3 |
75 |
6 |
19 |
INVENTIVE EXAMPLE 4 |
74 |
7 |
19 |
COMPARATIVE EXAMPLE 5 |
73 |
6 |
21 |
COMPARATIVE EXAMPLE 6 |
77 |
4 |
19 |
COMPARATIVE EXAMPLE 7 |
79 |
2 |
19 |
COMPARATIVE EXAMPLE 8 |
77 |
6 |
17 |
INVENTIVE STEEL 3 |
INVENTIVE EXAMPLE 5 |
66 |
3 |
31 |
INVENTIVE EXAMPLE 6 |
66 |
4 |
30 |
COMPARATIVE EXAMPLE 9 |
66 |
5 |
29 |
COMPARATIVE EXAMPLE 10 |
64 |
3 |
33 |
COMPARATIVE EXAMPLE 11 |
67 |
6 |
27 |
|
COMPARATIVE EXAMPLE 12 |
64 |
6 |
30 |
COMPARATIVE STEEL 1 |
COMPARATIVE EXAMPLE 13 |
59 |
5 |
36 |
COMPARATIVE EXAMPLE 14 |
56 |
7 |
37 |
COMPARATIVE STEEL 2 |
COMPARATIVE EXAMPLE 15 |
85 |
2 |
13 |
COMPARATIVE EXAMPLE 16 |
83 |
1 |
16 |
[Table 4]
Classification |
WIDTH IN CENTER PORTION |
SURFACE DEFECT |
YS (MPa ) |
TS (MPa ) |
El (% ) |
TS*El (MPa% ) |
AVERAGE NUMBER (number/m 2) |
INVENTIVE STEEL 1 |
INVENTIVE EXAMPLE 1 |
440 |
812 |
19 |
15428 |
1 |
INVENTIVE EXAMPLE 2 |
465 |
807 |
20 |
16140 |
1 |
COMPARATIV E EXAMPLE 1 |
423 |
819 |
19 |
15561 |
15 |
COMPARATIV E EXAMPLE 2 |
415 |
829 |
19 |
15751 |
3 |
COMPARATIV E EXAMPLE 3 |
390 |
831 |
20 |
16620 |
2 |
COMPARATIV E EXAMPLE 4 |
397 |
817 |
21 |
17157 |
18 |
INVENTIVE STEEL 2 |
INVENTIVE EXAMPLE 3 |
412 |
825 |
19 |
15675 |
0 |
INVENTIVE EXAMPLE 4 |
399 |
844 |
19 |
16036 |
0 |
COMPARATIV E EXAMPLE 5 |
445 |
835 |
20 |
16700 |
18 |
COMPARATIV E EXAMPLE 6 |
427 |
799 |
21 |
16779 |
1 |
COMPARATIV E EXAMPLE 7 |
399 |
824 |
21 |
17304 |
2 |
COMPARATIV E EXAMPLE 8 |
408 |
809 |
21 |
16989 |
22 |
INVENTIVE STEEL 3 |
INVENTIVE EXAMPLE 5 |
605 |
1028 |
15 |
15420 |
1 |
INVENTIVE EXAMPLE 6 |
635 |
1054 |
15 |
15810 |
1 |
COMPARATIV E EXAMPLE 9 |
645 |
1038 |
16 |
16608 |
14 |
COMPARATIV E EXAMPLE 10 |
607 |
1019 |
16 |
16304 |
1 |
COMPARATIV E EXAMPLE 11 |
616 |
1038 |
14 |
14532 |
1 |
COMPARATIV E EXAMPLE 12 |
635 |
1041 |
15 |
15615 |
22 |
COMPARATIV E STEEL 1 |
COMPARATIV E EXAMPLE 13 |
689 |
1097 |
17 |
18649 |
16 |
COMPARATIV E EXAMPLE 14 |
678 |
1087 |
18 |
19566 |
22 |
COMPARATIV E STEEL 2 |
COMPARATIV E EXAMPLE 15 |
345 |
658 |
26 |
17108 |
1 |
COMPARATIV E EXAMPLE 16 |
332 |
628 |
27 |
16956 |
1 |
[Table 5]
Classification |
MATERIAL IN BOTH END PORTIONS |
YS DEVIATION IN WIDTH DIRECTION (MPa) |
YS (MPa) |
INVENTIVE STEEL 1 |
INVENTIVE EXAMPLE 1 |
480 |
40 |
INVENTIVE EXAMPLE 2 |
475 |
10 |
COMPARATIVE EXAMPLE 1 |
441 |
18 |
COMPARATIVE EXAMPLE 2 |
523 |
108 |
COMPARATIVE EXAMPLE 3 |
502 |
112 |
COMPARATIVE EXAMPLE 4 |
412 |
15 |
INVENTIVE STEEL 2 |
INVENTIVE EXAMPLE 3 |
479 |
67 |
INVENTIVE EXAMPLE 4 |
465 |
66 |
COMPARATIVE EXAMPLE 5 |
448 |
3 |
COMPARATIVE EXAMPLE 6 |
533 |
106 |
COMPARATIVE EXAMPLE 7 |
517 |
118 |
COMPARATIVE EXAMPLE 8 |
432 |
24 |
INVENTIVE STEEL 3 |
INVENTIVE EXAMPLE 5 |
623 |
18 |
INVENTIVE EXAMPLE 6 |
669 |
34 |
COMPARATIVE EXAMPLE 9 |
650 |
5 |
COMPARATIVE EXAMPLE 10 |
726 |
119 |
COMPARATIVE EXAMPLE 11 |
729 |
113 |
COMPARATIVE EXAMPLE 12 |
669 |
34 |
COMPARATIVE STEEL 1 |
COMPARATIVE EXAMPLE 13 |
725 |
36 |
COMPARATIVE EXAMPLE 14 |
700 |
22 |
COMPARATIVE STEEL 2 |
COMPARATIVE EXAMPLE 15 |
355 |
10 |
COMPARATIVE EXAMPLE 16 |
339 |
7 |
[0077] As can be seen from the experimental results in Tables 1 to 5, in the case of Invention
Examples 1 to 6 satisfying the composition and manufacturing conditions of the present
disclosure, it was possible to obtain a cold-rolled steel sheet for securing a tensile
strength (TS) of 780 MPa or more while suppressing material deviation and surface
defects. In this case, it was confirmed that a maximum depth of surface defects measured
in the cold-rolled steel sheets obtained from Invention Examples 1 to 6 of the present
application satisfied 500 um or less.
[0078] On the other hand, in the case of Comparative Examples 1 to 16, not satisfying one
or more of the composition and manufacturing conditions of the present disclosure,
material deviation was inferior, surface defects occurred, and/or it was difficult
to secure the physical properties desired in the present disclosure.
[0079] In particular, Comparative Steel 1 had a Si addition amount exceeding 2.0% and did
not satisfy Relational Expression 1. Therefore, in the case of Comparative Examples
13 and 14 using Comparative Steel 1, although the manufacturing conditions presented
in the present disclosure were satisfied so the material deviation was good, there
was a problem in that a dent problem occurred due to Si oxide accumulation in an annealing
furnace, so that an average number of surface defects of a product exceeded a target
value.
[0080] In addition, Comparative Steel 2 did not satisfy Relational Expression 1 due to a
small amount of alloy added. Therefore, in the case of Comparative Examples 15 and
16 using Comparative Steel 2, although the manufacturing conditions presented in the
present disclosure were satisfied and surface defects and material deviation were
good, the tensile strength was less than 780 MPa and did not satisfy a target material.
[0081] In addition, Comparative Examples 1, 5, and 9 illustrate an example in which temperatures
in both end portions and a center portion in a width direction are higher than the
temperature presented in the present disclosure, and Comparative Examples 4, 8, and
12 illustrate an example in which a temperature of a heat retaining cover exceeded
a reference temperature. Accordingly, in Comparative Examples, hot-rolled oxides were
excessively generated, and a large number of surface defects of the final steel sheet
occurred due to the oxides.
[0082] In addition, in the case of Comparative Examples 2, 6, and 10, temperatures in both
end portions and a center portion in a width direction were lower than the temperature
suggested in the present disclosure, and Comparative Examples 2, 6, and 10 illustrate
an example in which a difference (Te-Tc) between a surface temperature in both end
portions and a surface temperature in the center portion exceeded 150°C, and Comparative
Examples 3, 7, and 11, illustrates an example in which a heat retaining cover is not
applied. Accordingly, in the above Comparative Examples, a target material of an annealed
steel sheet could be secured and an average number of surface defects was good, but
there was a problem in that deviation of the yield strength of the annealed steel
sheet in the width direction exceeded the target value of 100 MPa.
1. A high-strength cold-rolled steel sheet comprising:
by weight%, C: 0.05 to 0.3%, Si: 0.01 to 2.0%, Mn: 1.5 to 3.0%, Al: 0.01 to 0.1%,
P: 0.001 to 0.015%, S: 0.001 to 0.01%, N: 0.001 to 0.01%, with a remainder of Fe,
and other unavoidable impurities,
wherein a value defined by Relational Expression 1 satisfies 0.6 or more and less
than 0.9,
as a microstructure, by area%, ferrite: 50% or more, a remainder: bainite and martensite,
wherein an average number of surface defects satisfying one or more conditions of
a depth of 100 um or more and a short side length of 1 um or more, is less than 10/m2.

In Relational Expression 1, C, Si, Mn, Cr, Mo, and B represent an average weight percentage
for each element. when each of the above-described elements is not added, 0 is substituted.
2. The high-strength cold-rolled steel sheet of claim 1, wherein the microstructure comprises,
by area%, ferrite: 50 to 85% and a sum of bainite and martensite: 15 to 50%.
3. The high-strength cold-rolled steel sheet of claim 1, wherein the microstructure comprises,
by area%, ferrite: 66 to 75%.
4. The high-strength cold-rolled steel sheet of claim 3, wherein the microstructure comprises,
by area%, bainite: 3 to 7%.
5. The high-strength cold-rolled steel sheet of claim 3, wherein the microstructure comprises,
by area%, martensite: 19 to 31%.
6. The high-strength cold-rolled steel sheet of claim 1, further comprising one or more
selected elements from, by weight%, Cr: 1.0% or less (including 0%), Mo: 0.2% or less
(including 0%), and B: 0.005% or less (including 0%).
7. The high-strength cold-rolled steel sheet of claim 1, wherein a tensile strength is
780MPa or more and a yield strength is 380MPa or more.
8. The high-strength cold-rolled steel sheet of claim 1, wherein a product of the tensile
strength and elongation is 12,000MPa% or more.
9. The high-strength cold-rolled steel sheet of claim 1, wherein a difference in yield
strength between both end portions and a center portion is 100MPa or less, in a width
direction of the cold-rolled steel sheet.
10. A method for manufacturing a high-strength cold-rolled steel sheet, the method comprising:
reheating a steel slab including, by weight%, C: 0.05 to 0.3%, Si: 0.01 to 2.0%, Mn:
1.5 to 3.0%, Al: 0.01 to 0.1%, P: 0.001 to 0.015%, S: 0.001 to 0.01%, N: 0.001 to
0.01%, with a remainder of Fe, and other unavoidable impurities, wherein a value defined
by Relational Expression 1 satisfies 0.6 or more and less than 0.9, to a temperature
of 1100 to 1350°C;
hot rolling the reheated steel slab at a temperature within a range of 850 to 1150°C;
cooling the hot-rolled steel sheet to a temperature within a range of 450 to 700°C
at an average cooling rate of 10 to 70°C/s;
coiling the cooled steel sheet at a temperature within a range of 450 to 700°C;
cold rolling the wound steel sheet at a reduction rate of 40 to 70%; and
continuously annealing the cold-rolled steel sheet at a temperature within a range
of 740 to 900°C,
wherein in the coiling, based on an entire width of the steel sheet, a surface temperature
(Te) of both end portions in a width direction is controlled to satisfy 601 to 700°C,
and a surface temperature (Tc) of a center portion is controlled to satisfy 450 to
600°C.

In Relational Expression 1, C, Si, Mn, Cr, Mo and B represent an average weight percentage
of each element. In addition, if each of the above-described elements is not added,
0 is substituted.
11. The method of claim 10, further comprising:
after the coiling, moving the wound steel sheet into a heat retaining cover and maintaining
at a temperature within a range of 400 to 500°C for more than 6 hours.
12. The method of claim 10, wherein in the coiling, a difference (Te-Tc) between the surface
temperature of both end portions and the surface temperature (Tc) of the center portion
is controlled to satisfy a temperature of 150°C or less.
13. The method of claim 10, wherein in the cooling, based on an entire width of the steel
sheet, an amount of coolant provided onto a center portion excluding the both end
portions is controlled to be greater than an amount of coolant provided onto the both
end portions in a width direction.