(19)
(11) EP 4 409 070 B1

(12) EUROPEAN PATENT SPECIFICATION

(45) Mention of the grant of the patent:
05.03.2025 Bulletin 2025/10

(21) Application number: 22789233.8

(22) Date of filing: 27.09.2022
(51) International Patent Classification (IPC): 
D21H 19/58(2006.01)
D21H 19/82(2006.01)
 B65D 65/42(2006.01)
D21H 27/10(2006.01)
(52) Cooperative Patent Classification (CPC):
D21H 19/822; D21H 27/10; D21H 19/58; B65D 65/42
(86) International application number:
PCT/EP2022/076813
(87) International publication number:
WO 2023/046985 (30.03.2023 Gazette 2023/13)

(54)

COATED PAPER

BESCHICHTETES PAPIER

PAPIER COUCHÉ

(84) Designated Contracting States:
AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR

(30) Priority: 27.09.2021 EP 21199210

(43) Date of publication of application:
07.08.2024 Bulletin 2024/32

(73) Proprietor: Billerud Aktiebolag (publ)
169 27 Solna (SE)

(72) Inventors:
  • GILLGREN, Thomas
    703 57 Örebro (SE)
  • LARSSON, Johan
    805 98 Gävle (SE)
  • PROSPER, Wouter
    714 93 Kopparberg (SE)

(74) Representative: Kransell & Wennborg KB 
P.O. Box 2096
403 12 Göteborg
403 12 Göteborg (SE)


(56) References cited: : 
US-A1- 2018 058 010
 US-A1- 2020 149 222
   
       
    Note: Within nine months from the publication of the mention of the grant of the European patent, any person may give notice to the European Patent Office of opposition to the European patent granted. Notice of opposition shall be filed in a written reasoned statement. It shall not be deemed to have been filed until the opposition fee has been paid. (Art. 99(1) European Patent Convention).


    Description

    TECHNICAL FIELD



    [0001] The present disclosure relates to the field of paper-based materials.

    BACKGROUND



    [0002] The current legislative trends regarding packaging are driving consumers and brands to change their packaging from plastic to paper. There are many large market segments where barrier papers are required to effectively replace traditional plastic packaging and demand for paper-based solutions is growing strongly. Examples include flow wrapped products, bags and other wrappings.

    [0003] Flow wrapping is a horizontal-motion process in which products of any shape are wrapped in a wrapping material. It is used to pack single solid items, such as confectionery bars or multiple products already collated in trays. Traditionally, the wrapping material has been a clear plastic film or a printed opaque plastic film. The package resulting from the flow wrapping process has a longitudinal fin seal and end fin seals. The longitudinal fin seal is typically folded over so that the fin lies flat on the backside wall of the package rather than projecting from it.

    [0004] The vertical form fill sealing (VFFS) machine is a type of automated assembly-line product packaging system. It is commonly used in the packaging industry for food and a wide variety of other products. The machine often constructs plastic bags out of a flat roll of plastic film, while simultaneously filling the bags with product and sealing the filled bags. Both solids and liquids can be bagged using this packaging system.

    SUMMARY



    [0005] The present disclosure aims to provide a paper-based material that can replace plastic films in packaging in for example flow wrapping processes, sealed paper bags, e-commerce bags, tissue wrapping and bedding wrappings. The inventors have realized that such a paper-based material, to be commercially successful, should meet the majority, preferably all, of the following criteria:
    • ductility of the coating, i.e. cracking resistance during processing or usage;
    • minor or even non-existing blocking during processing;
    • providing a grease barrier (preventing fat from the packed/wrapped product from staining and/or weakening the paper-based material);
    • recyclable according to applicable standards;
    • protecting the packed/wrapped product from ambient moisture;
    • heat-sealable so that a sealed package can be produced without further sealant layers;
    • satisfactory printability when using existing printing technology; and
    • acceptable cost of production, preferably on existing machinery or requiring only minor investments in new equipment.
    • sealant layer adhesion (i.e. capable of binding a sealant composition applied in a high-speed process).


    [0006] Accordingly, the present disclosure provides the following listing of itemized embodiments:
    1. 1. A coated paper product comprising:
      • a paper substrate comprising a first and second side;
      • a first coating layer on the first side of the paper substrate, wherein the first coating layer comprises ethylene-acrylic acid (EAA) or vinyl acetate acrylate copolymer (VAcA) or styrene-acrylate (SA) or acrylic latex; and
      • a second coating layer on the first coating layer, wherein the second coating layer comprises EAA and talc, and wherein the dry weight ratio of EAA to talc in the second coating layer is between 100:5 and 100:70,
      • wherein the coat weight of the first coating layer is at least 4 g/m2, and
      • wherein the coat weight of the second coating layer is at least 3 g/m2.
    2. 2. The coated paper product of item 1, wherein the coat weight of the first coating layer is 4-10 g/m2.
    3. 3. The coated paper product of any of the preceding items, wherein the coat weight of the second coating layer is 3-9 g/m2.
    4. 4. The coated paper product of any one of the preceding items, wherein the grammage measured according to ISO 536:2020 of the paper substrate is 40-135 g/m2, 40-100 g/m2, such as 40-90 g/m2, such as 40-60 g/m2, such as 42-55 g/m2.
    5. 5. The coated paper product of any one of the preceding items, wherein the grammage measured according to ISO 536:2020 of the coated paper product is 52-142 g/m2, 52-110 g/m2, such as 52-95 g/m2, such as 52-71 g/m2, such as 56-68 g/m2.
    6. 6. The coated paper product of any one of the preceding items, wherein the paper substrate is a machine-glazed (MG) kraft paper or a machine finished (MF) kraft paper.
    7. 7. The coated paper product of item 6, wherein the paper substrate is a MG paper and the first side of the paper substrate is the non-glazed side of the MG paper and wherein the glazed side is optionally printed.
    8. 8. The coated paper product of item 6 or 7, wherein the paper substrate is a MG paper and the Bendtsen roughness according to ISO 8791-2:2013 of the glazed side of the paper substrate is below 90 ml/min, preferably 70 ml/min or lower, more preferably below 55 ml/min.
    9. 9. The coated paper product of items 6-8, wherein the paper substrate is a MG paper and the Bendtsen roughness according to ISO 8791-2:2013 of the glazed side of the coated paper product is below 90 ml/min, preferably 70 ml/min or lower, more preferably below 55 ml/min.
    10. 10. The coated paper product of items 6-9, wherein the paper substrate is a MG paper and the PPS roughness according to ISO 8791-4:2007 of the glazed side of the coated paper product is below 6.00 µm, such as below 5.00 µm, such as below 4.00 µm.
    11. 11. The coated paper product of any one of the preceding items, wherein at least 80 dry wt.% of the fibres used to form the paper substrate are never-dried.
    12. 12. The coated paper product of any one of the preceding items, wherein the first coating layer comprises talc and/or calcium carbonate (CaCO3).
    13. 13. The coated paper product of item 12, wherein the first coating comprises talc in a EAA or VAcA or SA or acrylic latex to talc ratio between 100:30 and 100:110, such as between 100:30 and 100:75 or CaCO3 in a EAA or VAcA or SA or acrylic latex to CaCO3 ratio between 100:20 and 100:70, such as between 100:30 and 100:65.
    14. 14. The coated paper product of any one of the preceding items, wherein the dry weight ratio of EAA to talc in the second coating layer is between 100:10 and 100:70, such as between 100:10 and 100:60, such as between 100:15 and 100:60, such as between 100:15 and 100:40.
    15. 15. The coated paper product of any one of the preceding items, wherein the paper product is heat-sealable.
    16. 16. The coated paper product of item 15, wherein the maximum heat seal strength measured according to ASTM F88 & EN 868-5 of the coated paper product is at least 2.8 N measured on a 15 mm test strip sealed for 0.5 s at 160 °C and 3 bar.
    17. 17. The coated paper product of any of the preceding items, wherein the first and/or second coating layer comprises clay, such as kaolin clay.
    18. 18. The coated paper product of item 17, wherein the clay is a platy clay, preferably having a form factor of at least 20, such as at least 30, such as at least 40.
    19. 19. The coated paper product of any one of the preceding items, wherein the density measured according to ISO 534:2011 of the paper substrate is 800-900 kg/m3.
    20. 20. The coated paper product of any one of the preceding items, wherein the thickness measured according to ISO 534:2011 of the paper substrate is 50-150 µm, such as 50-120 µm, such as 50-64 µm, such as 52-61 µm.
    21. 21. The coated paper product of any one of the preceding items, wherein the thickness measured according to ISO 534:2011 of the coated paper product is 55-156 µm, such as 55-126 µm, such as 55-70 µm, such as 57-67 µm.
    22. 22. The coated paper product of any one of the preceding items, wherein the density measured according to ISO 534:2011 of the coated paper product is 950-1100 kg/m3.
    23. 23. The coated paper product of any one of the preceding items, wherein the paper substrate is bleached, e.g. has an ISO Brightness according to ISO 2470 of at least 77.
    24. 24. The coated paper product of any one of the preceding items, wherein the recyclability measured according to PTS Method PTS-RH 021/97 of the coated paper product is at least 80%.
    25. 25. The coated paper product of any one of the preceding items, wherein the hexane/heptane vapor transmission rate (HVTR) measured according to the method described in the description of the coated paper product is below 200 g/(m2 day).
    26. 26. The coated paper product of any one of the preceding items, wherein the water vapor transmission rate (WVTR) measured according to ISO 15106-1 at 23°C and 50% relative humidity (RH) of the coated paper product is below 30 g/(m2 day).
    27. 27. The coated paper product of any one of the preceding items, wherein the water vapor transmission rate (WVTR) measured according to ISO 15106-1 at 30°C and 80% relative humidity (RH) of the coated paper product is below 105 g/(m2 day).
    28. 28. The coated paper product of any one of the preceding items, wherein average show through time of palm kernel oil measured according to Standard ISO 16532-1 of the coated paper product is at least 45 minutes.
    29. 29. The coated paper product of any one of the preceding items, wherein minimum show through time of palm kernel oil measured according to Standard ISO 16532-1 of the coated paper product is at least 10 minutes.
    30. 30. The coated paper product of any one of the preceding items, wherein a contact angle measured according to TAPPI T 558 between water and the surface formed by the second coating layer is less than 95° at the 1.0 s checkpoint.
    31. 31. The coated paper product of any one of the preceding items, wherein a contact angle measured according to TAPPI T 558 between di-iodomethane (DIM) and the surface formed by the second coating layer is less than 60° at the 1.0 s checkpoint.
    32. 32. The coated paper product of any one of the preceding items, wherein the surface energy derived from the contact angle measurements of water and di-iodomethane (DIM) measured according to TAPPI T 558 is at least 30 mJ/m2 at the 1.0 s checkpoint.
    33. 33. The coated paper product of any one of the preceding items, wherein a sealant layer, such as cold-seal layer, is arranged on part of the second coating layer.
    34. 34. The coated paper product of any one of the preceding items, wherein the ash content is below 10 % calculated according:

      (A% ash in B g/m2 base paper + X1 % pigment in Y1 g/m2 in first coating layer + X2 % pigment in Y2 g/m2 second coating layer) / Z g/m2; wherein

      A is the total ash content in the base paper and B is the grammage of the base paper;

      X1 and X2 are the pigment contents in the first and second coating layers, respectively;

      Y1 and Y2 are the coating grammages of the first and second coating layers, respectively; and

      Z is the total grammage of the coated paper.

    35. 35. A flow-wrapped product obtained by flow-wrapping a product in a coated paper product according to any one of the preceding items, wherein the flow-wrapped product has a longitudinal fin seal and end fin seals.
    36. 36. A sealed bag produced from a coated paper product according to any one of the items 1-34, such as a gusseted bag or a pillow bag, having a longitudinal seal and each end portion is sealed by a fin seal.
    37. 37. Use of a coated paper product according to any one of the items 1-34 for wrapping a product, such as flow-wrapping a product, in sealable paper bags, such as a gusseted bag or a pillow bag, in e-commerce packaging, in bedding packaging, such as pillow packaging, or in tissue wrapping.
    38. 38. A method of producing a coated paper comprising the steps of:
      • providing a paper substrate comprising a first and second side; and
      • coating the first side of the paper substrate with a first coating layer, wherein the first coating layer comprises ethylene-acrylic acid (EAA) latex or vinyl acetate acrylate copolymer (VAcA) latex or styrene-acrylate (SA) or acrylic latex; and
      • coating a second coating layer on the first coating layer, wherein the second coating layer comprises ethylene-acrylic acid (EAA) latex and talc, and wherein the dry weight ratio of EAA latex to talc in the second coating layer is between 100:5 and 100:70
      • wherein the coat weight of the first coating layer is at least 4 g/m2, and
      • wherein the coat weight of the second coating layer is at least 3 g/m2.
    39. 39. A method of producing a coated paper product according to item 38, wherein the first and second coating layers are applied in-line.
    40. 40. The method of item 38 or 39 comprising drying between coating with the first coating layer and coating the second coating layer
    41. 41. A method of flow-wrapping a product comprising a step of flow-wrapping the product in a coated paper product according to any one of the items 1-34, wherein said flow-wrapping step comprises formation of a fin seal by sealing the coated paper product.
    42. 42. The method of flow wrapping a product of item 41, wherein the sealing is conducted by heat-sealing.
    43. 43. The method of flow wrapping a product of item 41, wherein the method further comprises the step of applying a sealant layer, preferably a cold-seal layer, onto part of the second coating layer prior to formation of a fin seal and sealing is conducted by sealing said sealant layer.
    44. 44. The method of flow wrapping a product of items 41-43 further comprising printing the glazed side of the coated paper product.
    45. 45. The method of flow wrapping a product of item 43 further comprising printing the glazed side of the coated paper product and the printing and the application of the sealant layer are carried out in the same machine.
    46. 46. Method of forming a filled bag, in which the paper of any one of items 1-34 is formed into a bag, filled and sealed in a machine, such as a form fill sealing (FFS) machine, such as a vertical form fill sealing (VFFS) machine.
    47. 47. A coated paper product for use in a flow wrapping process comprising:
      • a paper substrate comprising a first and second side;
      • a first coating layer on the first side of the paper substrate, wherein the first coating layer comprises ethylene-acrylic acid (EAA) or vinyl acetate acrylate copolymer (VAcA) or styrene-acrylate (SA); and
      • a second coating layer on the first coating layer, wherein the second coating layer comprises EAA and talc, and wherein the dry weight ratio of EAA to talc in the second coating layer is between 100:5 and 100:100.
    48. 48. The coated paper product of item 47, wherein the coat weight of the first coating layer is at least 4 g/m2, such as 4-10 g/m2.
    49. 49. The coated paper product of any one of items 47 or 48, wherein the coat weight of the second coating layer is at least 3 g/m2, such as 3-9 g/m2.
    50. 50. The coated paper product of any one of items 47-49, wherein the grammage measured according to ISO 536:2020 of the paper substrate is 40-60 g/m2, such as 42-55 g/m2.
    51. 51. The coated paper product of any one of items 47-50, wherein the grammage measured according to ISO 536:2020 of the coated paper product is 52-71 g/m2, such as 56-68 g/m2.
    52. 52. The coated paper product of any one of items 47-51, wherein the paper substrate is a machine-glazed (MG) kraft paper.
    53. 53. The coated paper product of item 52, wherein the first side of the paper substrate is the non-glazed side of the MG paper and wherein the glazed side is optionally printed.
    54. 54. The coated paper product of any one of items 47-53, wherein at least 80 dry wt.% of the fibres used to form the paper substrate are never-dried.
    55. 55. The coated paper product of any one of items 47-54, wherein the first coating layer comprises talc and/or calcium carbonate (CaCO3).
    56. 56. The coated paper product of item 55, wherein the first coating layer comprises talc in a EAA or VAcA or SA to talc ratio between 100:30 and 100:110, such as between 100:30 and 100:75, or CaCO3 in a EAA or VAcA or SA to CaCO3 ratio between 100:20 and 100:70, such as between 100:30 and 100:65.
    57. 57. The coated paper product of any one of items 47-56, wherein the dry weight ratio of EAA to talc in the second coating layer is between 100:5 and 100:70, such as 100:10 and 100:60, such as 100:15 and 100:60, such as 100:15 and 100:40.
    58. 58. The coated paper product of any one of items 47-57, wherein the paper product is heat-sealable.
    59. 59. The coated paper product of item 58, wherein the maximum heat seal strength measured according to ASTM F88 & EN 868-5 of the coated paper product is at least 2.8 N measured on a 15 mm test strip sealed for 0.5 s at 160 °C and 3 bar.
    60. 60. A flow-wrapped product obtained by flow-wrapping a product in a coated paper product according to any one of items 47-59.
    61. 61. A method of producing a coated paper product for use in a flow wrapping process comprising the steps of:
      • providing a paper substrate comprising a first and second side; and
      • coating the first side of the paper substrate with a first coating layer, wherein the first coating layer comprises ethylene-acrylic acid (EAA) latex or vinyl acetate acrylate copolymer (VAcA) latex or styrene-acrylate (SA) latex; and
      • coating a second coating layer on the first coating layer, wherein the second coating layer comprises ethylene-acrylic acid (EAA) latex and talc, and wherein the dry weight ratio of EAA latex to talc in the second coating layer is between 100:5 and 100:100.

    BRIEF DESCRIPTION OF THE DRAWINGS



    [0007] Fig 1 is a schematic illustration of an embodiment of the coated paper product 1 of the present disclosure. The paper product consists of a paper substrate 101, a first coating layer 102 and a second coating layer 103.

    DETAILED DESCRIPTION



    [0008] As a first aspect of the present disclosure, there is provided a coated paper product comprising:
    • a paper substrate comprising a first and second side;
    • a first coating layer on the first side of the paper substrate, wherein the first coating layer comprises ethylene-acrylic acid (EAA) or vinyl acetate acrylate copolymer (VAcA) or styrene-acrylate (SA) or acrylic latex; and
    • a second coating layer on the first coating layer, wherein the second coating layer comprises EAA and talc, and wherein the dry weight ratio of EAA to talc in the second coating layer is between 100:5 and 100:70,
    • wherein the coat weight of the first coating layer is at least 4 g/m2, and
    • wherein the coat weight of the second coating layer is at least 3 g/m2.


    [0009] The second coating layer is preferably applied on the first coating layer, i.e. directly on top of the first coating layer forming a dual superposed coating arrangement.

    [0010] The paper substrate is typically a machine-glazed (MG) paper or a machine finished (MF) paper. The paper substrate may be calendered. The MG or MF paper is typically a kraft paper, and typically at least 80%, preferably at least 90%, by dry weight of the fibres used to produce the MG or MF paper are never-dried fibres (i.e. virgin fibres).

    [0011] An MG paper has glazed side and a non-glazed side. The glazed side is the side that faced the Yankee cylinder (a polished metal cylinder sometimes referred to as a MG cylinder) used for drying the paper web in the MG papermaking machine. The contact with the polished metal surface during drying makes the glazed side smoother than the non-glazed side. Typically, the first coating layer is applied to the less smooth, non-glazed, side of the paper substrate. Onto the first coating layer, the second coating layer is applied. The opposite side, i.e. the smooth, glazed side, in such case is typically printed. It is beneficial to apply the coating on the non-glazed side to provide the glazed side for printing. The glazed side may be coated with a thin layer of starch (≤ 1 g/m2) for curl prevention. A lacquer may be provided on the optional print, e.g. to modify gloss, friction and/or release properties.

    [0012] An MF paper is produced by a drying technique using a large number of smaller, steam-heated cylinders to dry the paper which is alternately wrapped one way and then the other way so that both sides of the paper receive the same finish. The finish on both sides of an MF paper is similar to the non-glazed side of an MG paper.

    [0013] The paper substrate may have been treated in a size press or similar to smoothen the surface and thereby avoid too great penetration of the first coating layer into the paper substrate.

    [0014] The grammage measured according to ISO 536:2020 of the paper substrate is typically 40-135 g/m2, 40-100 g/m2, such as 40-90 g/m2, such as 40-60 g/m2, such as 42-55 g/m2. A suitable density (measured according to ISO 534:2011) for the paper substrate is 800-900 kg/m3. A too low density is disadvantageous since such paper is too porous for application of a thin barrier.

    [0015] Typically, if the paper is used for flow wrapping, a suitable thickness (measured according to ISO 534:2011) of the paper substrate is 50-64 µm, such as 52-61 µm. A too high grammage or thickness makes the paper not suitable for a flow wrapping process as the paper should be flexible.

    [0016] The paper substrate may be bleached, e.g. has an ISO Brightness according to ISO 2470 of at least 77.

    [0017] The first coating may comprise a rheology modifier to facilitate the coating operation. The first coating layer typically comprises pigment and the pigment is preferably talc and/or calcium carbonate (CaCO3).

    [0018] Typically, at least 50% by weight of the total pigment content in the second coating layer is talc.

    [0019] It is beneficial for combining coating ductility, barrier properties, non-blocking, recyclability, heat sealability and possibility to coat with a sealant layer that the first coating layer comprises EAA or VAcA or SA or acrylic latex as well as talc and/or CaCO3 in the first coating layer and EAA as well as talc in the second coating layer, wherein the dry weight ratio of EAA to talc in the second coating layer is between 100:5 and 100:70. The first coating layer may also be free of pigments.

    [0020] The first coating layer preferably comprises talc in a EAA or VAcA or SA or acrylic latex to talc ratio of 100:30 and 100:110, such as between 100:30 and 100:75, or CaCO3 in a EAA or VAcA or SA or acrylic latex to CaCO3 ratio of 100:20 and 100:70, such as between 100:30 and 100:65. The dry weight ratio of EAA to talc in the second coating layer is preferably between 100:10 and 100:70, such as between 100:10 and 100:60, such as between 100:15 and 100:60, such as between 100:15 and 100:40. It is advantageous with such filler to EAA or VAcA or SA or acrylic latex ratios in the first and second coating layers with respect to coating ductility, blocking, barrier properties and heat-sealability.

    [0021] The coated paper product is typically heat-sealable. EAA is inherently heat-sealable and by addition of a dry weight ratio of EAA to talc in the second coating layer of between 100:5 and 100:70, this heat-sealability is typically maintained. A higher talc content impairs the sealability as well as the barrier crack resistance. Typically, the maximum heat seal strength measured according to ASTM F88 & EN 868-5 of the coated paper product is at least 2.8 N measured on a 15 mm test strip sealed for 0.5 s at 160 °C and 3 bar. This means that 2.8 N is required to separate the sealed strip. It is advantageous for the coated paper product to be heat-sealable in order to allow the formation of a flow-wrap packaging by sealing the paper to itself.

    [0022] The second coating layer typically forms a surface to which a sealant layer can be applied, typically a cold-sealant layer. To facilitate the application of the sealant layer, the contact angle between water and the second coating layer surface is preferably less than 95°, such as less than 90°, such as less than 80°. The contact angle may be measured according to TAPPI T 558. This standard stipulates measuring the contact angle at different checkpoints. Suitably, the contact angle at the 1.0 s checkpoint is selected. Moreover, the contact angle between di-iodomethane (DIM) and the second coating layer surface is preferably less than 60° and the surface energy is at least 30 mJ/m2 at the 1.0 s checkpoint measured according to TAPPI T 558. The surface energy is derived from the contact angle measurements by plotting (1+cosθ)/2*(σL/σLd)1/2) vs (σLp/σLd)1/2, wherein θ is the contact angle formed between the liquid drop and solid surface, σL is the liquid surface tension, and superscripts d and p stand respectively for dispersive and polar components of the liquid surface tension. After plotting, the points are fitted to a straight line to calculate σsp and σsd from the slope and intersection with the vertical axis, respectively. σs is the solid surface free energy and the surface energy is the sum of σgp + σsd.

    [0023] It is advantageous that the second coating layer typically can either be heat-sealed without the need for an additional sealant layer or coated by and sealed by an additional sealant layer, typically a cold seal layer.

    [0024] The coat weight of the first coating layer is typically 4-10 g/m2. The coat weight of the second coating layer is typically 3-9 g/m2. There is preferably a higher coat weight of the first coating layer than the second coating layer. This is advantageous especially if the first coating layer comprises a higher filler content thereby making the first coating layer more economically favourable and environmentally friendly.

    [0025] The grammage measured according to ISO 536:2020 of the coated paper product is typically 52-142 g/m2, 52-110 g/m2, such as 52-95 g/m2, such as 52-71 g/m2, such as 56-68 g/m2. A suitable density (measured according to ISO 534:2011) of the coated paper product is 950-1100 kg/m3. Typically, if the paper is used for flow wrapping, a suitable thickness (measured according to ISO 534:2011) of the coated paper product is 52-68 µm, such as 54-66 µm.

    [0026] In a particularly preferred embodiment of the coated paper product the first coating layer comprises EAA to talc in a ratio of between 100:30 and 100:75 and the second coating layer comprises EAA to talc in a ratio of 100:15 to 100:40. Such embodiment is advantageous as it combines barrier properties, barrier crack resistance, blocking resistance, grease resistance, heat sealability and possible application of a sealant layer.

    [0027] In another particularly preferred embodiment of the coated paper product the first coating layer comprises VAcA to pigment in a ratio of between 100:30 and 100:75 and the second coating layer comprises EAA to talc in a ratio of 100:15 to 100:70. Such embodiment is beneficial in terms of combining recyclability with barrier crack resistance, blocking resistance, low ash content and possible application of a sealant layer.

    [0028] In yet another particularly preferred embodiment of the coated paper product the first coating layer comprises VAcA to pigment in a ratio of between 100:30 and 100:75 and the second coating layer comprises EAA to talc in a ratio of 100:15 to 100:40. Such embodiment is beneficial in terms of combining barrier crack resistance, blocking resistance, grease resistance, recyclability, low ash content and possible application of a sealant layer.

    [0029] In yet another particularly preferred embodiment of the coated paper product the first coating layer comprises acrylic latex to pigment in a ratio between 100:30 and 100:110 and the second coating layer comprises EAA to talc in a ratio between 100:50 and 100:70. Such embodiment is beneficial in terms of combining mineral oil barrier properties as well as water vapour barrier properties with barrier crack resistance, blocking resistance, grease resistance, recyclability and possible application of a sealant layer.

    [0030] As a second aspect of the present disclosure, there is provided a flow-wrapped product obtained by flow-wrapping a product in a coated paper product according to the first aspect, wherein the flow-wrapped product has a longitudinal fin seal and end fin seals.

    [0031] The examples and embodiments discussed above in connection to the first aspect apply to the second aspect mutatis mutandis.

    [0032] As a third aspect of the present disclosure, there is provided a sealed bag, such as a gusseted bag or a pillow bag, having a longitudinal seal and each end portion is sealed by a fin seal produced from a coated paper product according to the first aspect.

    [0033] A filled gusseted bag is obtainable from a VFFS machine. Such bag has a longitudinal seal adhering two overlapping ends of the paper material to each other to form a lap seal. In an alternative embodiment of the filled bag, the longitudinal seal is a fin seal. Further, the bag has a top end sealed by a fin seal and a bottom end sealed by a fin seal.

    [0034] A filled pillow bag is obtainable from a VFFS machine. Such bag has a longitudinal seal adhering two overlapping ends of the paper material to each other to form a lap seal. In an alternative embodiment of the filled bag, the longitudinal seal is a fin seal. Further, the bag has a top end sealed by a fin seal and a bottom end sealed by a fin seal.

    [0035] The examples and embodiments discussed above in connection to the first and second aspect apply to the third aspect mutatis mutandis.

    [0036] As a fourth aspect of the present disclosure, there is provided use of a coated paper product according to the first aspect for wrapping a product, such as flow-wrapping a product, in sealable paper bags, such as a gusseted bag or a pillow bag, in e-commerce packaging, in bedding packaging, such as pillow packaging, or in tissue wrapping.

    [0037] The examples and embodiments discussed above in connection to the first, second and third aspect apply to the fourth aspect mutatis mutandis.

    [0038] As a fifth aspect of the present disclosure there is provided a method of producing a coated paper product comprising the steps of:
    • providing a paper substrate comprising a first and second side; and
    • coating the first side of the paper substrate with a first coating layer, wherein the first coating layer comprises ethylene-acrylic acid (EAA) latex or vinyl acetate acrylate copolymer (VAcA) latex or styrene-acrylate (SA) latex or acrylic latex; and
    • coating a second coating layer on the first coating layer, wherein the second coating layer comprises ethylene-acrylic acid (EAA) latex and talc, and wherein the dry weight ratio of EAA latex to talc in the second coating layer is between 100:5 and 100:70
    • wherein the coat weight of the first coating layer is at least 4 g/m2, and
    • wherein the coat weight of the second coating layer is at least 3 g/m2.


    [0039] In one embodiment, the method comprises drying between the application of the first coating layer and the application of the second coating layer. Drying is typically performed with non-contact drying, such as IR and/or hot air, or contact drying, such as a drying cylinder, or a combination of non-contact and contact drying.

    [0040] The coating is typically conducted with blade coating. The coating may also be conducted with rod coating, air-knife coating, rotogravure coating and/or curtain coating. The first and second coating layers may be applied with the same coating technique or different coating techniques.

    [0041] The first and second coating layers may be applied in-line (also referred to as on-line). In such case, the productivity is increased by eliminating the handling operations linked to off-line treatment and by eliminating, or at least reducing, the amount of waste. When an in-line process is conducted, the coating weight is typically below 10 g/m2 in both the first and second coating layers to allow for sufficient drying between coating steps as well as prior to reeling. A non-blocking coating is in such case also advantageous.

    [0042] The examples and embodiments discussed above in connection to the first, second, third and fourth aspects apply to the fifth aspect mutatis mutandis.

    [0043] A typical product to be flow-wrapped in the paper-based material of the present disclosure is a protein bar, a snack bar or a chocolate bar.

    [0044] A typical product to be packed in a sealed barrier bag made from the paper-based material of the present disclosure are dry foods, such as confectionary or baked goods. Alternatively, the product is cosmetics and toiletries.

    EXAMPLES


    Coating of paper



    [0045] Pigment (talc (Finntalc C15B2), kaolin clay (Barrisurf LX), CaCO3 (Setacarb HG-ME 75%)) was added to and dispersed in an ethylene acrylic acid (EAA) latex (Michem Flex HS 1130) having a solids content of about 45% or vinyl acetate acrylate copolymer (VAcA) latex (CHP 125) having a solids content of about 50% or acrylic latex (Rhobarr 214, DOW) having a solids content of about 45%.

    [0046] A machine-glazed (MG) base paper produced from never-dried bleached SW pulp was coated on the non-glazed side with a pilot-scale blade coater for samples 1-17 & 20-23.

    [0047] The properties of the MG base paper is shown in Table 1 below.
    Table 1. Properties of a MG kraft paper produced from never-dried bleached SW pulp.
    Property Unit Standard method Value
    Grammage g/m2 ISO 536 48.15
    Thickness µm ISO 534 56.80
    Density kg/m3 ISO 534 847.71
    Tensile Strength MD kN/m ISO 1924-3 4.40
    Tensile Strength CD kN/m ISO 1924-3 2.50
    Tensile Index MD kNm/kg ISO 1924-3 91.38
    Tensile Index CD kNm/kg ISO 1924-3 51.92
    Stretch at break MD % ISO 1924-3 1.85
    Stretch at break CD % ISO 1924-3 4.12
    TEA MD J/m2 ISO 1924-3 53.75
    TEA CD J/m2 ISO 1924-3 74.58
    TEA Index MD J/g ISO 1924-3 1.12
    TEA Index CD J/g ISO 1924-3 1.55
    PPS 1 MPa glazed side µm ISO 8791-4 5.80*
    Bendtsen Roughness glazed side ml/min ISO 8791-2 34
    Bendtsen Roughness non-glazed side ml/min ISO 8791-2 254
    Bending Resistance MD mN ISO 2493-1 22
    Bending Resistance CD mN ISO 2493-1 13
    Bending Resistance Index MD Nm6/kg3 ISO 2493-1 197.1
    Bending Resistance Index CD Nm6/kg3 ISO 2493-1 116.5
    Puncture Resistance Force N EN 14477 2.81
    Puncture Resistance Strain mm EN 14477 0.47
    Puncture Resistance Work mJ EN 14477 0.58
    *Unusually high, the value is normally between 2.4 and 4.1 µm.


    [0048] Two samples (sample 18-19) were produced by coating a machine finished (MF) base paper with a grammage of 70 g/m2 (sample 18) and a grammage of 80 g/m2 (sample 19) in the same way as on the MG base paper.

    [0049] A first coating layer comprising latex and pigment (samples 1-16 & 18-22) or latex but no pigment (sample 17) was coated onto the paper. The coated paper was dried by IR and a drying cylinder. Thereafter a second coating layer comprising latex and pigment (samples 1-18 & 22-23) or latex but no pigment (samples 20-21) was coated so that the paper was coated on one side with a dual superposed coating. The coating was dried by IR, hot air and a drying cylinder. The composition of each coating is presented in Table 2.




    Barrier properties


    WVTR



    [0050] To evaluate the barrier properties against water vapour, the water vapour transmission rate (WVTR) was measured according to ISO 15106-1 at 23 °C and 50% relative humidity (RH) as well as at 30°C and 80% RH.

    HVTR



    [0051] To evaluate mineral oil migration barrier properties, the hexane/heptane vapour transmission rate (HVTR) was measured. The determination of the hexane vapour transmission rate (HVTR) was performed in a permeability cup (evaporation chamber) with a sealable closure fixable with screws. The closure has an open surface area which is sealed with the barrier material. A volume of hexane or heptane (9-10 ml) is filled into the evaporation chamber onto a sponge (to reach a liquid/gas equilibrium as quickly as possible) and the weight of hexane/heptane vapour that goes through the exposed surface of a functional barrier, is expressed in gram per square meter of the surface area per day. The samples were prepared by using a punch and visually inspected to see that there were no surface defects or damages (e.g. creases or pin holes). Under controlled experimental conditions (23° ± 1°C and 50 ± 2% relative humidity), the paper sample was fixed into the closure head, the barrier coatings facing the inner side. The chamber was closed as quickly as possible. The filled evaporation chamber is then weighed after 1, 2, 4 hrs and 1 day. The HVTR was then calculated according to:

    HVTR [g/m2 day)] = weight difference [g] * 10000 [cm2/m2] * 24 [h/d]/(area[cm2] * time[h])


    [0052] The results of WVTR and HVTR measurements are presented in Table 3 and the sample numbering is the same as in Table 2.
    Table 3. Results of WVTR and HVTR measurements.
    Sample WVTR (23°C/50%RH) WVTR (30°C/80%RH) HVTR (g/m2*d)
    1 7.86 71.43  
    2 6.67 40.89  
    3 4.10 31.90  
    4 6.19 40.10  
    5 4.91 41.51  
    6 7.15 53.89  
    7 9.58 58.73  
    8 8.78 46.06  
    9 9.02 66.77  
    10 9.00 52.73  
    11 10.42 63.57 179.3
    12 6.80 30.08 191.1
    13 20.45 101.74 57.9
    14 18.64 75.33 91.3
    15 18.92 80.93 43.6
    16 24.40 95.31 98.6
    17 6.6 22.5  
    18 7.1 42.5  
    19 5 67  
    20 4.5 38.8  
    21 5.6 41.8  
    22 15.9 90  
    23 8 39.9 23

    Runnability & handling


    Folded paper oil resistance - crack-resistance measurement



    [0053] By measuring the folded oil resistance from the barrier side, the ductility is measured, i.e. how well the formed barrier resists cracking. The methods is described in detail herein.

    [0054] Rape seed oil was mixed with 1% colorant (Sudan blue II) and stirred on a magnetic stirrer until fully mixed.

    [0055] 3 samples (14x14 cm) of each coated paper were prepared. The samples were one by one arranged in a folding punch with the barrier side downwards. The folding punch has a V-shaped punch and a V-shaped weight is arranged on top so that when the sample is pushed down by the weight, a 90° fold-line along the entire paper is formed. The weight was applied on the opposite side of the paper from the barrier coating pushing the barrier side downwards. Two additional fold-lines were formed on the paper. All three fold-lines were evenly distributed with a distance of about 4 cm. After the third fold-line had been formed, the paper was turned 90° and three additional fold-lines were made in the same way, thereby obtaining a grid pattern.

    [0056] In a cobb ring a blotting paper was arranged with one paper sample on top of the blotting paper. The paper sample had the barrier coated side upwards. The coloured rape seed oil (10 ml) was dosed into the ring and evenly distributed over the paper sample immediately. After 2 minutes the paper sample was taken out from the ring and excess oil was removed with additional blotting papers and lint-free drying paper.

    [0057] Within 10 minutes from the removal, the paper sample was scanned in a computer scanner and the number of visible blue dots counted manually. The blue dots appear where the barrier has cracked and oil could enter into the paper. The criteria for evaluation are shown in Table 4 below. The analysis was performed in triplicate and the presented result in Table 6 is the average result.
    Table 4. Criteria for evaluation of barrier ductility measurements.
    Number of dots Category
    <5 Excellent
    <15 Good
    15-30 Average
    >30 Poor

    Blocking



    [0058] After coating of the paper with the first and second coatings layers the paper was reeled up. After about 24 h, the paper was reeled out and blocking was evaluated according to the following criteria presented in Table 4.
    Table 5. Criteria for evaluation of blocking resistance.
      Blocking
    Possible to reel out the paper without any sticking of the coating No
    Possible to reel out the paper but the coating was sticking to some extent Yes, some
    Not possible to reel out the paper due to major sticking of the coating Yes

    Heat-sealing



    [0059] The maximum heat seal strength was measured according to ASTM F88 & EN 868-5 and settings were 0.5 s, 160 °C and 3 bar on 15 mm wide samples. The results are presented in Table 6.
    Table 6. Results from evaluation of runnability & handling properties.
    Sample Barrier crack resistance Blocking Heat seal Fmax (N)
    1 Poor No 2.86±0.15
    2 Poor No 2.85±0.21
    3 Poor No 2.90±0.19
    4 Average No 2.86±0.12
    5 Poor No  
    6 Good No  
    7 Average No  
    8 Good No  
    9 Poor No  
    10 Average No  
    11 Good No 2.95±0.21
    12 Excellent No 3.02±0.27
    13 Good No  
    14 Excellent No  
    15 Excellent No  
    16 Excellent No  
    17 Excellent No  
    18 Excellent No 3.9
    19 Good   5
    20 Poor    
    21 Poor    
    22 Poor Yes, some  
    23 Good No  


    [0060] A high barrier crack resistance in combination with blocking resistance as well as good barrier properties against both water vapour and mineral oil was obtained for both pigmented pre-coating (samples 11-16, 18-19 & 23) as well as a pre-coating free of pigments (sample 17). The same applies to the lower grammage MG paper (samples 11-17 & 23) as well as the higher grammage MF paper (samples 18-19), and heat-sealibilty was obtained independently of MG paper (samples 11-12) or MF paper (sample 18).

    Contact angle and surface energy



    [0061] Water and di-iodomethane (DIM) contact angle was measured according to TAPPI T 558 on the surface of the second coating layer to evaluate the wetting of the surface. The surface energy is derived from the contact angle measurements by plotting (1+cosθ)/2*(σL/σLd)½) vs (σLp/σLd)½, wherein θ is the contact angle formed between the liquid drop and solid surface, σL is the liquid surface tension, and superscripts d and p stand respectively for dispersive and polar components of the liquid surface tension. After plotting, the points were fitted to a straight line to calculate σsp and σsd from the slope and intersection with the vertical axis, respectively. σs is the solid surface free energy and the surface energy is the sum of σsp + σsd.

    [0062] The contact angle as well as surface energy reflects the ability of the surface to be coated, i.e. wetted, with a sealant layer. The measurement was conducted at the 1.0 s checkpoint. The results are presented in Table 7.

    Cold-seal wetting



    [0063] To further evaluate the possibility to coat the surface with an additional sealant, a cold-seal (Loctite Liofol CS 22-422, Henkel) was applied onto the second coating by using a lab rod coater. If a uniform coating was formed, i.e. did coating did not form pearls, the surface could be wet by the cold-seal.

    [0064] The total surface energy is the key factor to wetting. Moreover, it is believed by the inventors that it is the top-coating that contributes the most to the total surface energy. A similar top-coat to that in samples 9-11 is therefore fair to assume that such top-coat is also wettable with a cold-seal.
    Table 7. Water contact angle, Di-iodomethane (DIM) contact angle and surface energy.
    Sample Water contact angle (°) DIM contact angle (°) Total surface energy (mJ/m2) Cold-seal wetting
    1        
    2        
    3        
    4        
    5        
    6        
    7        
    8        
    9 76.9 52.7 36.2 Yes
    10 96.1 59.0 29.2 Yes
    11 90.9 54.6 32.0 Yes
    12 89.6 55.2 31.8  
    13 92.2 55.8 31.2  
    14 91.4 56.8 30.8  
    15 92.5 55.6 31.3  
    16 93.1 56.9 30.5  
    17        
    18 97   25.9  
    19        
    20        
    21        
    22        
    23        

    Grease resistance


    Show through time



    [0065] The show through times of palm kernel oil is a measure of grease resistance and was measured according to Standard ISO 16532-1. Minimum time as well as average time are presented in Table 8.
    Table 8. Show through time of palm kernel oil.
    Sample Average show through (min) Minimum show through (min)
    1 313 190
    2 130 80
    3 243 120
    4 213 120
    5 165 113
    6 189 109
    7 103 103
    8 70 53
    9 193 115
    10 160 148
    11 90 54
    12 537 43
    13 48 36
    14 576 335
    15 60 10
    16 182 34
    17    
    18 1044 281
    19 603  
    20    
    21    
    22 49 37
    23 379 93

    Recyclability & ash content


    Recyclability



    [0066] The recyclability was measured according to PTS Method PTS-RH 021/97 and the results are presented in Table 8.

    Ash content



    [0067] To fulfil food-grade packaging legislation in Italy it is required that the ash content is below 10 %.

    [0068] The ash content was calculated according: (3% ash in 48 g/m2 base paper + X1 % pigment in Y1 g/m2 in first coating layer + X2 % pigment in Y2 g/m2 second coating layer) / Z g/m2; wherein
    • X1 and X2 are the pigment contents in the first and second coating layer, respectively;
    • Y1 and Y2 are the coating grammages of the first and second coating layer, respectively; and
    • Z is the total grammage of the coated paper.


    [0069] The calculated ash contents are presented in Table 8.
    Table 8. Recyclability according to PTS Method PTS-RH 021/97 and ash content.
    Sample Recyclability Ash content (total)
    1   14%
    2   13%
    3   15%
    4   9%
    5   17%
    6   11%
    7   10%
    8 80.1% 7%
    9   16%
    10 77.6% 10%
    11 79.7% 8%
    12 81.0% 7%
    13 86.9% 8%
    14 84.6% 7%
    15 84.9% 9%
    16 85.1% 8%
    17    
    18 80.0%  
    19    
    20    
    21    
    22    
    23 86.4%  


    [0070] There are four sublevels of recyclability (level A+, A, B, C). The result of the assessment according to the PTS Method PTS-RH 021/97 was that the coated paper product samples having a recyclability of at least 80 % were classified as level A recyclable.

    [0071] Both for the lower grammage MG paper and the higher grammage MF paper a level A recyclable classification was measured and obtained for samples 8, 12-16, 23 (MG paper) and 18 (MF paper).


    Claims

    1. A coated paper product comprising:

    - a paper substrate comprising a first and second side;

    - a first coating layer on the first side of the paper substrate, wherein the first coating layer comprises ethylene-acrylic acid (EAA) or vinyl acetate acrylate copolymer (VAcA) or styrene-acrylate (SA) or acrylic latex; and

    - a second coating layer on the first coating layer, wherein the second coating layer comprises EAA and talc, and wherein the dry weight ratio of EAA to talc in the second coating layer is between 100:5 and 100:70,

    - wherein the coat weight of the first coating layer is at least 4 g/m2, and

    - wherein the coat weight of the second coating layer is at least 3 g/m2.


     
    2. The coated paper product of claim 1, wherein the coat weight of the first coating layer is 4-10 g/m2.
     
    3. The coated paper product of any of the preceding claims, wherein the coat weight of the second coating layer is 3-9 g/m2.
     
    4. The coated paper product of any one of the preceding claims, wherein the grammage measured according to ISO 536:2020 of the paper substrate is 40-135 g/m2, such as 40-100 g/m2, such as 40-90 g/m2, such as 40-60 g/m2, such as 42-55 g/m2.
     
    5. The coated paper product of any one of the preceding claims, wherein the grammage measured according to ISO 536:2020 of the coated paper product is 52-142 g/m2, such as 52-110 g/m2, such as 52-95 g/m2, such as 52-71 g/m2, such as 56-68 g/m2.
     
    6. The coated paper product of any one of the preceding claims, wherein the paper substrate is a machine-glazed (MG) kraft paper or a machine finished (MF) kraft paper.
     
    7. The coated paper product of claim 8, wherein paper substrate is a MG paper and the first side of the paper substrate is the non-glazed side of the MG paper and wherein the glazed side is optionally printed.
     
    8. The coated paper product of any one of the preceding claims, wherein at least 80 dry wt.% of the fibres used to form the paper substrate are never-dried.
     
    9. The coated paper product of any one of the preceding claims, wherein the first coating layer comprises talc and/or calcium carbonate (CaCO3).
     
    10. The coated paper product of claim 9, wherein the first coating layer comprises talc in a EAA or VAcA or SA or acrylic latex to talc ratio between 100:30 and 100:110, such as between 100:30 and 100:75, or CaCO3 in a EAA or VAcA or SA or acrylic latex to CaCO3 ratio between 100:20 and 100:70, such as between 100:30 and 100:65.
     
    11. The coated paper product of any one of the preceding claims, wherein the dry weight ratio of EAA to talc in the second coating layer is between 100:10 and 100:70, such as between 100:10 and 100:60, such as between 100:15 and 100:60, such as between 100:15 and 100:40.
     
    12. The coated paper product of any one of the preceding claims, wherein the paper product is heat-sealable.
     
    13. The coated paper product of claim 12, wherein the maximum heat seal strength measured according to ASTM F88 & EN 868-5 of the coated paper product is at least 2.8 N measured on a 15 mm test strip sealed for 0.5 s at 160 °C and 3 bar.
     
    14. A sealed bag produced from a coated paper product according to any one of the claims 1-13, such as a gusseted bag or a pillow bag, having a longitudinal seal and each end portion is sealed by a fin seal.
     
    15. Use of a coated paper product according to any one of the claims 1-13 for wrapping a product, such as flow-wrapping a product, in sealable paper bags, such as such as a gusseted bag or a pillow bag, in e-commerce packaging, in bedding packaging, such as pillow packaging, or in tissue wrapping.
     
    16. A method of producing a coated paper product comprising the steps of:

    - providing a paper substrate comprising a first and second side; and

    - coating the first side of the paper substrate with a first coating layer, wherein the first coating layer comprises ethylene-acrylic acid (EAA) latex or vinyl acetate acrylate copolymer (VAcA) latex or styrene-acrylate (SA) latex or acrylic latex; and

    - coating a second coating layer on the first coating layer, wherein the second coating layer comprises ethylene-acrylic acid (EAA) latex and talc, and wherein the dry weight ratio of EAA latex to talc in the second coating layer is between 100:5 and 100:70,

    - wherein the coat weight of the first coating layer is at least 4 g/m2, and

    - wherein the coat weight of the second coating layer is at least 3 g/m2.


     


    Ansprüche

    1. Beschichtetes Papierprodukt, aufweisend:

    - ein Papiersubstrat, das eine erste und eine zweite Seite aufweist;

    - eine erste Beschichtungsschicht auf der ersten Seite des Papiersubstrats, wobei die erste Beschichtungsschicht Ethylen-Acrylsäure (EAA) oder Vinylacetat-Acrylat-Copolymer (VAcA) oder Styrol-Acrylat (SA) oder Acryllatex aufweist; und

    - eine zweite Beschichtungsschicht auf der ersten Beschichtungsschicht, wobei die zweite Beschichtungsschicht EAA und Talk aufweist, und wobei das Trockengewichtsverhältnis von EAA zu Talk in der zweiten Beschichtungsschicht zwischen 100:5 und 100:70 liegt,

    - wobei das Auftragsgewicht der ersten Beschichtungsschicht mindestens 4 g/m2 beträgt, und

    - wobei das Auftragsgewicht der zweiten Beschichtungsschicht mindestens 3 g/m2 beträgt.


     
    2. Beschichtetes Papierprodukt nach Anspruch 1, wobei das Beschichtungsgewicht der ersten Beschichtungsschicht 4-10 g/m2 beträgt.
     
    3. Beschichtetes Papierprodukt nach einem der vorhergehenden Ansprüche, wobei das Auftragsgewicht der zweiten Beschichtungsschicht 3-9 g/m2 beträgt.
     
    4. Beschichtete Papierprodukt nach einem der vorhergehenden Ansprüche, wobei die Grammatur des Papiersubstrats, gemessen nach ISO 536:2020, 40-135 g/m2, beispielsweise 40-100 g/m2, beispielsweise 40-90 g/m2, beispielsweise 40-60 g/m2, beispielsweise 42-55 g/m2 beträgt.
     
    5. Beschichtetes Papierprodukt nach einem der vorhergehenden Ansprüche, wobei die Grammatur des beschichteten Papierprodukts, gemessen nach ISO 536:2020, 52-142 g/m2, beispielsweise 52-110 g/m2, beispielsweise 52- 95 g/m2, beispielsweise 52-71 g/m2, beispielsweise 56-68 g/m2 beträgt.
     
    6. Beschichtetes Papierprodukt nach einem der vorhergehenden Ansprüche, wobei das Papiersubstrat ein maschinenglasiertes (MG) Kraftpapier oder ein maschinenveredeltes (MF) Kraftpapier ist.
     
    7. Beschichtetes Papierprodukt nach Anspruch 8, wobei das Papiersubstrat ein MG-Papier ist und die erste Seite des Papiersubstrats die nicht-glänzende Seite des MG-Papiers ist und wobei die glänzende Seite optional bedruckt ist.
     
    8. Beschichtetes Papierprodukt nach einem der vorhergehenden Ansprüche, wobei mindestens 80 Trocken-Gew.-% der zur Bildung des Papiersubstrats verwendeten Fasern nie getrocknet sind.
     
    9. Beschichtetes Papierprodukt nach einem der vorhergehenden Ansprüche, wobei die erste Beschichtungsschicht Talk und/oder Calciumcarbonat (CaCO3) aufweist.
     
    10. Beschichtetes Papierprodukt nach Anspruch 9, wobei die erste Beschichtungsschicht Talk in einem Verhältnis von EAA oder VAcA oder SA oder Acryllatex zu Talk zwischen 100:30 und 100:110, beispielsweise zwischen 100:30 und 100:75, oder CaCO3 in einem Verhältnis von EAA oder VAcA oder SA oder Acryllatex zu CaCO3 zwischen 100:20 und 100:70, beispielsweise zwischen 100:30 und 100:65. aufweist.
     
    11. Beschichtetes Papierprodukt nach einem der vorhergehenden Ansprüche, wobei das Trockengewichtsverhältnis von EAA zu Talk in der zweiten Beschichtungsschicht zwischen 100:10 und 100:70, beispielsweise zwischen 100:10 und 100:60, beispielsweise zwischen 100:15 und 100:60, beispielsweise zwischen 100:15 und 100:40 beträgt.
     
    12. Beschichtetes Papierprodukt nach einem der vorhergehenden Ansprüche, wobei das Papierprodukt heißsiegelbar ist.
     
    13. Beschichtetes Papierprodukt nach Anspruch 12, wobei die maximale Heißsiegelfestigkeit, gemessen nach ASTM F88 und EN 868-5, des beschichteten Papierprodukts mindestens 2,8 N beträgt, gemessen an einem 15 mm langen Teststreifen, der 0,5 s lang bei 160° C und 3 bar versiegelt wurde.
     
    14. Versiegelter Beutel, hergestellt aus einem beschichteten Papierprodukt nach einem der Ansprüche 1 bis 13, wie etwa ein Seitenfaltenbeutel oder ein Kissenbeutel, der eine Längsversiegelung aufweist und bei dem jeder Endabschnitt durch eine Flossenversiegelung versiegelt ist.
     
    15. Verwendung eines beschichteten Papierprodukts nach einem der Ansprüche 1 bis 13 zum Verpacken eines Produkts, beispielsweise zum Verpacken eines Produkts als Schlauchbeutel, in verschließbare Papierbeutel, beispielsweise einen Seitenfaltenbeutel oder einen Kissenbeutel, in Verpackungen für den elektronischen Handel, in Bettwarenverpackungen, wie beispielsweise Kissenverpackungen, oder in Tissueverpackungen.
     
    16. Verfahren zur Herstellung eines beschichteten Papierprodukts, aufweisend die Schritte:

    - Bereitstellen eines Papiersubstrats, das eine erste und eine zweite Seite aufweist; und

    - Beschichten der ersten Seite des Papiersubstrats mit einer ersten Beschichtungsschicht, wobei die erste Beschichtungsschicht Ethylen-Acrylsäure-Latex (EAA) oder Vinylacetat-Acrylat-Copolymer-Latex (VAcA) oder Styrol-Acrylat-Latex (SA) oder Acryllatex aufweist; und

    - Auftragen einer zweiten Beschichtungsschicht auf die erste Beschichtungsschicht, wobei die zweite Beschichtungsschicht Ethylen-Acrylsäure- (EAA) Latex und Talk aufweist, und wobei das Trockengewichtsverhältnis von EAA-Latex zu Talkum in der zweiten Beschichtungsschicht zwischen 100:5 und 100:70 liegt,

    - wobei das Auftragsgewicht der ersten Beschichtungsschicht mindestens 4 g/m2 beträgt, und

    - wobei das Auftragsgewicht der zweiten Beschichtungsschicht mindestens 3 g/m2 beträgt.


     


    Revendications

    1. Produit en papier couché comprenant :

    - un substrat de papier comprenant une première face et une seconde face ;

    - une première couche de revêtement située sur la première face du substrat de papier, dans lequel la première couche de revêtement comprend de l'acide éthylène-acrylique (EAA) ou un copolymère d'acétate de vinyle et d'acrylate (VAcA) ou du styrène-acrylate (SA) ou du latex acrylique ; et

    - une seconde couche de revêtement située sur la première couche de revêtement, dans lequel la seconde couche de revêtement comprend de l'EAA et du talc, et dans lequel le rapport en poids sec entre l'EAA et le talc dans la seconde couche de revêtement est compris entre 100:5 et 100:70,

    - dans lequel le poids de la couche de la première couche de revêtement est d'au moins 4 g/m2, et

    - dans lequel le poids de la seconde couche de couchage est d'au moins 3 g/m2.


     
    2. Produit en papier couché selon la revendication 1, dans lequel le poids de la première couche de couchage est compris entre 4 et 10 g/m2.
     
    3. Produit en papier couché selon l'une quelconque des revendications précédentes, dans lequel le poids de la seconde couche de couchage est compris entre 3 et 9 g/m2.
     
    4. Produit en papier couché selon l'une quelconque des revendications précédentes, dans lequel le grammage mesuré selon la norme ISO 536:2020 du substrat en papier est compris entre 40 et 135 g/m2, par exemple compris entre 40 et 100 g/m2, par exemple compris entre 40 et 90 g/m2, par exemple compris entre 40 et 60 g/m2, par exemple compris entre 42 et 55 g/m2.
     
    5. Produit en papier couché selon l'une quelconque des revendications précédentes, dans lequel le grammage mesuré selon la norme ISO 536:2020 du produit en papier couché est compris entre 52 et 142 g/m2, par exemple compris entre 52 et 110 g/m2, par exemple compris entre 52 et 95 g/m2, par exemple compris entre 52 et 71 g/m2, par exemple compris entre 56 et 68 g/m2.
     
    6. Produit en papier couché selon l'une quelconque des revendications précédentes, dans lequel le substrat de papier est un papier de type kraft glacé à la machine (MG) ou un papier de type kraft fini à la machine (MF).
     
    7. Produit en papier couché selon la revendication 8, dans lequel le substrat de papier est un papier MG et la première face du substrat de papier est la face non glacée du papier MG et dans lequel la face glacée est éventuellement imprimée.
     
    8. Produit en papier couché selon l'une quelconque des revendications précédentes, dans lequel au moins 80 % en poids sec des fibres utilisées pour former le substrat en papier n'ont jamais été séchées.
     
    9. Produit en papier couché selon l'une quelconque des revendications précédentes, dans lequel la première couche de couchage comprend du talc et/ou du carbonate de calcium (CaCO3).
     
    10. Produit en papier couché selon la revendication 9, dans lequel la première couche de couchage comprend du talc dans un rapport EAA ou VAcA ou SA ou latex acrylique/ talc compris entre 100:30 et 100:110, par exemple compris entre 100:30 et 100:75, ou du CaCO3 dans un rapport EAA ou VAcA ou SA ou latex acrylique/ CaCO3 compris entre 100:20 et 100:70, par exemple compris entre 100:30 et 100:65.
     
    11. Produit en papier couché selon l'une quelconque des revendications précédentes, dans lequel le rapport en poids sec entre l'EAA et le talc dans la seconde couche de couchage est compris entre 100:10 et 100:70, par exemple compris entre 100:10 et 100:60, par exemple compris entre 100:15 et 100:60, par exemple compris entre 100:15 et 100:40.
     
    12. Produit en papier couché selon l'une quelconque des revendications précédentes, dans lequel le produit en papier est thermoscellable.
     
    13. Produit en papier couché selon la revendication 12, dans lequel la résistance maximale au thermoscellage mesurée selon la norme ASTM F88 & EN 868-5 du produit en papier couché est d'au moins 2,8 N mesurée sur une bande d'essai de 15 mm scellée pendant 0,5 sat 160 °C et 3 bar.
     
    14. Sac scellé fabriqué à partir d'un produit en papier couché selon l'une quelconque des revendications 1 à 13, tel qu'un sac à soufflet ou un sac coussin, ayant une soudure longitudinale et dont chaque extrémité est scellée par une soudure d'ailette.
     
    15. Utilisation d'un produit en papier couché selon l'une quelconque des revendications 1 à 13 dans le but d'emballer un produit, tel que l'emballage d'un produit, dans des sacs en papier scellables, tels qu'un sac à soufflets ou un sac d'oreiller, dans l'emballage d'un commerce électronique, dans l'emballage d'une literie, tel qu'un emballage d'oreiller, ou dans l'emballage d'un produit en tissu.
     
    16. Procédé de fabrication d'un produit en papier couché comprenant les étapes suivantes :

    - la fourniture d'un substrat de papier comprenant une première face et une seconde face ; et

    - le revêtement de la première face du substrat de papier à l'aide d'une première couche de revêtement, dans lequel la première couche de revêtement comprend du latex d'acide éthylène-acrylique (EAA) ou du latex de copolymère d'acétate de vinyle et d'acrylate (VAcA) ou du latex de styrène et d'acrylate (SA) ou du latex acrylique ; et

    - l'application d'une deuxième couche de revêtement sur la première couche de revêtement, dans laquelle la deuxième couche de revêtement comprend du latex d'acide éthylène-acrylique (EAA) et du talc, et dans laquelle le rapport en poids sec entre le latex EAA et le talc dans la deuxième couche de revêtement est compris entre 100:5 et 100:70,

    - dans lequel le poids de la première couche de revêtement est d'au moins 4 g/m2, et

    - dans lequel le poids de la seconde couche de revêtement est d'au moins 3 g/m2.


     




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