CROSS-REFERENCE TO RELATED APPLICATIONS
TECHNICAL FIELD
[0002] This disclosure relates to the field of battery technologies, and in particular,
to an electrode assembly, a battery cell, a battery, and an electric apparatus.
BACKGROUND
[0003] A rechargeable battery cell may be referred to as a secondary battery cell, and is
a battery cell that can be charged after being discharged to activate active substances
for continuous use. Rechargeable battery cells are widely used in electronic devices,
such as mobile phones, notebook computers, battery motorcycles, electric vehicles,
electric airplanes, electric ships, electric toy cars, electric toy ships, electric
toy airplanes, and electric tools.
[0004] As a key component of a battery cell, an electrode assembly may be formed by winding
positive and negative electrode plates. A wound electrode assembly has problems such
as lithium precipitation or poor electrolyte infiltration, which affect the safety
performance or cycling performance.
SUMMARY
[0005] According to an aspect of this disclosure, an electrode assembly is provided, including
a first electrode plate, a second electrode plate, and a separator provided between
the first electrode plate and the second electrode plate, where the first electrode
plate, the separator, and the second electrode plate are wound in a winding direction
to form a wound structure. At least one first surface of the first electrode plate
and second electrode plate at a side closer to the separator includes a first surface
region, a second surface region, and a third surface region divided along the winding
direction. The first surface region, the second surface region, and the third surface
region each have a length greater than 0 in the winding direction. The second surface
region has a plurality of second protrusion structures distributed discretely, the
first surface region has no protrusion structure or a plurality of first protrusion
structures distributed discretely, the third surface region has no protrusion structure
or a plurality of third protrusion structures distributed discretely, and a protrusion
height h1 of the plurality of first protrusion structures and/or a protrusion height
h3 of the plurality of third protrusion structures is less than or greater than a
protrusion height h2 of the plurality of second protrusion structures.
[0006] In this embodiment, the electrode plate swells during use of a battery. The protrusion
structures discretely distributed on the side of the electrode plate closer to the
separator support the separator, forming a buffer gap between the electrode plate
and the separator. This buffer gap provides space for the swelling of the electrode
plate, avoiding lithium precipitation caused by a large-area close contact between
the electrode plate and the separator when the electrode plate swells. Additionally,
the buffer gap between the protrusion structures and the separator retains the electrolyte
to guarantee the infiltration effect of the electrolyte within the wound structure,
facilitating full reaction with the active substance on the electrode plate during
the charge and discharge processes of the battery, thereby optimizing the cycling
performance of the battery.
[0007] In terms of distribution of protrusion structures, the second surface region among
the first surface region, the second surface region, and the third surface region
divided along the winding direction is provided with the second protrusion structures,
and the first surface region and the third surface region are not provided with the
protrusion structure or are provided with protrusion structures with the protrusion
height less than or greater than the protrusion height of the second protrusion structures,
thus implementing stronger adaptability to the stress on different regions after the
winding of the wound structure. Higher protrusion structures provide sufficient swelling
space and pathways for electrolyte infiltration and absorption in regions with greater
swelling forces. Conversely, in regions with smaller swelling forces, no protrusion
structure is provided or lower protrusion structures are provided to simplify processing
or reduce processing difficulty, or minimize processing of the electrode plate to
guarantee strength and rigidity performance of the electrode plate.
[0008] In some embodiments, the protrusion height h1 of the plurality of first protrusion
structures and the protrusion height h3 of the plurality of third protrusion structures
are both less than or greater than the protrusion height h2 of the plurality of second
protrusion structures.
[0009] In the wound structure (such as the hollow cylindrical structure) of some batteries,
the swelling forces of the first surface region and the third surface region on the
inner side and outer side of the electrode plate respectively in the winding direction
are both lower than the swelling force of the second surface region in the middle.
Therefore, with the protrusion height of the first protrusion structures and the protrusion
height of the third protrusion structures both set to be smaller than the protrusion
height of the second protrusion structures, the influence of the processing processes
of the electrode plate, for which protrusion structures are implemented in the first
surface region and the third surface region, on the strength or rigidity of the electrode
plate itself can be reduced. In the wound structure of some other batteries, the swelling
forces of the first surface region and the third surface region on the inner side
and the outer side of the electrode plate respectively in the winding direction are
both higher than the swelling force of the second surface region in the middle. Therefore,
with the protrusion height of the first protrusion structures and the protrusion height
of the third protrusion structures both set to be greater than the protrusion height
of the second protrusion structure, the influence of the processing processes of the
electrode plate, for which protrusion structures are implemented in the second surface
region, on the strength or rigidity of the electrode plate itself can be reduced.
[0010] In some embodiments, the protrusion height h1 of the plurality of first protrusion
structures and the protrusion height h3 of the plurality of third protrusion structures
are basically equal.
[0011] With the heights of the first protrusion structures and the third protrusion structures
basically equal, the first protrusion structures and the third protrusion structures
can be implemented through the same processing procedure according to basically the
same processing parameters when the electrode plate is processed, reducing the number
of processing steps and the processing difficulty.
[0012] In some embodiments, the protrusion height h1 of the plurality of first protrusion
structures is greater than the protrusion height h3 of the plurality of third protrusion
structures.
[0013] In the wound structure of some batteries, the swelling force of the first surface
region on the inner side of the electrode plate in the winding direction when the
electrode plate swells is greater than the swelling force of the second surface region
on the outer side when the electrode plate swells. With the protrusion height of the
first protrusion structures set to be greater than the protrusion height of the third
protrusion structures, the actual swelling force in each region can be adapted to
the protrusion height of the protrusion structures provided in this region, thus further
improving the battery performance.
[0014] In some embodiments, the protrusion height h1 of the plurality of first protrusion
structures is less than the protrusion height h3 of the plurality of third protrusion
structures.
[0015] In the wound structure of some batteries, the swelling force of the first surface
region on the inner side of the electrode plate in the winding direction when the
electrode plate swells is less than the swelling force of the second surface region
on the outer side when the electrode plate swells. With the protrusion height of the
first protrusion structures set to be less than the protrusion height of the third
protrusion structures, the actual swelling force in each region can be adapted to
the protrusion height of the protrusion structures provided in this region, thus further
improving the battery performance.
[0016] In some embodiments, the protrusion height h1 of the plurality of first protrusion
structures is greater than the protrusion height h2 of the plurality of second protrusion
structures, and the protrusion height h3 of the plurality of third protrusion structures
is less than the protrusion height h2 of the plurality of second protrusion structures.
[0017] The wound structure (such as the prismatic structure) of some batteries needs to
be flattened after winding. However, after the wound structure is flattened, there
will be a concentration of swelling force in the first surface region on the inner
side of the electrode plate in the winding direction when the electrode plate swells,
while the swelling force of the third surface region at the outer side is relatively
smaller compared to the swelling force of both the first surface region and the second
surface region. Therefore, with the protrusion height of the first protrusion structures
being made greater than the protrusion height of the second protrusion structures
and the protrusion height of the third protrusion structures being made smaller than
the protrusion height of the second protrusion structures, sufficient buffer space
can be provided for the swelling forces in different regions, reducing lithium precipitation
and improving the infiltration effect of the electrolyte.
[0018] In some embodiments, the protrusion height h1 of the plurality of first protrusion
structures is less than the protrusion height h2 of the plurality of second protrusion
structures, and the protrusion height h3 of the plurality of third protrusion structures
is greater than the protrusion height h2 of the plurality of second protrusion structures.
[0019] In the wound structure of some batteries, there is a concentration of swelling force
in the outer region of the wound structure when the electrode plate swells, while
the internal hollow region experiences relatively smaller swelling force. Therefore,
with the protrusion height of the first protrusion structures being made smaller than
the protrusion height of the second protrusion structures and the protrusion height
of the third protrusion structures being made greater than the protrusion height of
the second protrusion structures, sufficient buffer space can be provided for the
swelling forces in different regions, reducing lithium precipitation and improving
the infiltration effect of the electrolyte.
[0020] In some embodiments, the protrusion height h2 of the plurality of second protrusion
structures gradually increases or gradually decreases along the winding direction.
[0021] For the second surface region, which is located in the middle along the winding direction
of the electrode plate, different wound structures exhibit varying trends in swelling
force in the surface region. For wound structures where the swelling force gradually
increases from the inner to the outer part of the second surface region, gradually
increasing the protrusion height h2 of the second protrusion structures along the
winding direction can make the protrusion height of the second protrusion structures
be adapted to the swelling force. Conversely, for wound structures where the swelling
force gradually decreases from the inner to the outer part of the second surface region,
gradually decreasing the protrusion height h2 of the second protrusion structures
along the winding direction can make the protrusion height of the second protrusion
structures be adapted to the swelling force. In this way, sufficient buffer space
can be provided for the swelling forces in different regions, reducing lithium precipitation
and improving the infiltration effect of the electrolyte.
[0022] In some embodiments, the protrusion height h1 of the plurality of first protrusion
structures and/or the protrusion height h3 of the plurality of third protrusion structures
gradually increases or gradually decreases along the winding direction.
[0023] For the first surface region and the third surface region, different wound structures
exhibit varying trends in swelling force in this region. Depending on whether the
swelling force gradually increases or decreases, gradually increasing or decreasing
the height of the first protrusion structures and/or the height of the third protrusion
structures along the winding direction can make the protrusion height of the first
protrusion structures and/or the third protrusion structures be adapted to the swelling
force. In this way, sufficient buffer space can be provided for the swelling forces
in different regions, reducing lithium precipitation and improving the infiltration
effect of the electrolyte.
[0024] In some embodiments, the range of the protrusion height h1 of the plurality of first
protrusion structures, the range of the protrusion height h2 of the plurality of second
protrusion structures, and/or the range of the protrusion height h3 of the plurality
of third protrusion structures is less than or equal to 30 µm. The ranges of the protrusion
heights being less than or equal to 30 µm can reduce the processing difficulty and
lower manufacturing costs for forming protrusion structures.
[0025] In some embodiments, the range of the protrusion height h1 of the plurality of first
protrusion structures, the range of the protrusion height h2 of the plurality of second
protrusion structures, and/or the range of the protrusion height h3 of the plurality
of third protrusion structures is less than or equal to 20 µm. The ranges of the protrusion
heights being less than or equal to 20 µm can simultaneously reduce processing difficulty
for forming protrusion structures and guarantee consistency in the formed swelling
buffer space and pathways for electrolyte infiltration and absorption.
[0026] In some embodiments, the range of the protrusion height h1 of the plurality of first
protrusion structures, the range of the protrusion height h2 of the plurality of second
protrusion structures, and/or the range of the protrusion height h3 of the plurality
of third protrusion structures is less than or equal to 10 µm. The ranges of the protrusion
heights being less than or equal to 10 µm can increase the uniformity and consistency
in the swelling buffer space and pathways for electrolyte infiltration and absorption
formed by the protrusion structures, thus improving the battery performance.
[0027] In some embodiments, the wound structure is a hollow cylindrical or prismatic structure.
Combining the aforementioned provision or no provision of the protrusion structures
in different surface regions, as well as the relationships between protrusion heights
of the protrusion structures, adaptively choosing between hollow cylindrical or prismatic
structures can enhance battery performance.
[0028] In some embodiments, the first surface region is a portion of the first surface from
an innermost end of the wound structure to a division position at an m-th layer of
the wound structure; the second surface region is a portion of the first surface from
the division position at the m-th layer of the wound structure to a division position
at an n-th layer of the wound structure; and the third surface region is a portion
of the first surface from the division position at the n-th layer of the wound structure
to an outermost end of the wound structure, where n > m > 1.
[0029] Through the division of the electrode plate along the winding direction from the
innermost end to the outermost end into three surface regions, and setting the surface
region between the division position at the m-th layer and the division position at
the n-th layer as the second surface region, distinct from the situation when the
first surface of the electrode plate is divided into only two regions along the winding
direction or is not divided at all, in conjunction with the foregoing settings of
the protrusion structures, the adaptability of the wound structure is effectively
increased, enhancing battery performance.
[0030] In some embodiments, a shape of the plurality of first protrusion structures and/or
a shape of the plurality of third protrusion structures is different from a shape
of the plurality of second protrusion structures.
[0031] Combined with the settings of the protrusion heights of the protrusion structures,
the adaptability of the wound structure is further improved through the shape differences
in the protrusion structures in different surface regions, improving the battery performance.
[0032] In some embodiments, the second surface region includes at least two surface region
segments divided in a direction perpendicular to the winding direction, and the plurality
of second protrusion structures are located in a part of the at least two surface
region segments.
[0033] Through the division of the second surface region into at least two surface region
segments perpendicular to the winding direction, and the provision of the second protrusion
structures in a part of the surface region segments, the surface region segment(s)
provided with the second protrusion structures are provided with larger swelling buffer
space and electrolyte pathways. This helps to overcome local lithium precipitation
in these surface region segments during battery usage due to factors such as large
local swelling force or insufficient electrolyte flow.
[0034] In some embodiments, the at least two surface region segments include three surface
region segments, and the plurality of second protrusion structures are all located
in a surface region segment in the middle of the three surface region segments.
[0035] For some wound structures (such as the hollow cylindrical structure), the swelling
force is mainly concentrated in the middle part in the direction perpendicular to
the winding direction. Through the provision of the second protrusion structures in
the middle surface region segment, the swelling buffer space in the middle part can
be improved and the phenomenon of lithium precipitation in the middle part of the
wound structure can be eliminated.
[0036] In some embodiments, the at least two surface region segments include five surface
region segments, and the plurality of second protrusion structures are located in
three surface region segments at two ends and in the middle among the five surface
region segments.
[0037] For some wound structures (such as the hollow cylindrical structure), besides the
concentration of the swelling force in the middle along the direction perpendicular
to the winding direction leading to lithium precipitation, there is also lithium precipitation
caused by the concentration of swelling force and insufficient electrolyte flow at
corner positions. Therefore, through the provision of the second protrusion structures
in three surface region segments at the two ends and in the middle among the five
surface region segments, the swelling buffer space and electrolyte flow pathways at
the two ends and in the middle can be improved, eliminating lithium precipitation
in the middle and at the corner positions of the wound structure.
[0038] In some embodiments, at least one second surface of the first electrode plate and
second electrode plate at a side farther away from the separator has a second recess
portion aligned with each of at least a part of the plurality of second protrusion
structures.
[0039] A protrusion structure with one side concave and the other side convex can be formed
through punching or extrusion of the plate-shaped electrode plate, and the second
recess portion is correspondingly present on the opposite back side of the second
protrusion structure. This structure has relatively low processing difficulty, which
is beneficial to large-scale centralized processing, improving processing efficiency
and reducing processing costs.
[0040] In some embodiments, at least one second surface of the first electrode plate and
second electrode plate at a side farther away from the separator has a first recess
portion aligned with each of at least a part of the plurality of first protrusion
structures and/or has a third recess portion aligned with each of at least a part
of the plurality of third protrusion structures.
[0041] A protrusion structure with one side concave and the other side convex can be formed
through punching or extrusion of the plate-shaped electrode plate, and the first recess
portion is correspondingly present on the opposite back side of the first protrusion
structure, and/or the third recess portion is correspondingly present on the opposite
back side of the third protrusion structure. This structure has relatively low processing
difficulty, which is beneficial to large-scale centralized processing, improving processing
efficiency and reducing processing costs.
[0042] In some embodiments, each of at least a part of the plurality of second protrusion
structures is a polymer particle attached to or formed on the second surface region.
Through the usage of the polymer particle attached to or formed on the second surface
region as the second protrusion structure, the influence of processes, like punching
or extrusion, on parameters of the electrode plate, such as strength or rigidity,
can be reduced.
[0043] In some embodiments, each of at least a part of the plurality of first protrusion
structures is a polymer particle attached to or formed on the first surface region,
and/or each of at least a part of the plurality of third protrusion structures is
a polymer particle attached to or formed on the third surface region.
[0044] Through the usage of the polymer particle attached to or formed on the first surface
region as the first protrusion structure and/or the usage of the polymer particle
attached to or formed on the third surface region as the third protrusion structure,
the influence of processes, like punching or extrusion, on parameters of the electrode
plate, such as strength or rigidity, can be reduced.
[0045] According to an aspect of this disclosure, a battery cell is provided, including
the foregoing electrode assembly. The battery cell with the foregoing electrode assembly
has better performance.
[0046] According to an aspect of this disclosure, a battery is provided, including the foregoing
battery cell. The battery with the foregoing battery cell has better performance.
[0047] According to an aspect of this disclosure, an electric apparatus is provided, including
the foregoing battery. The electric apparatus with the foregoing battery has better
performance.
BRIEF DESCRIPTION OF DRAWINGS
[0048] To describe the technical solutions of the embodiments of this disclosure more clearly,
the following briefly describes the accompanying drawings required for describing
the embodiments of this disclosure. Apparently, the accompanying drawings described
below show merely some embodiments of this disclosure, and persons of ordinary skill
in the art may still derive other drawings from the accompanying drawings without
creative efforts.
[0049] This disclosure can be more clearly understood from the following detailed description
with reference to the accompanying drawings, where:
FIG. 1 is a schematic structural diagram of an electric apparatus according to some
embodiments of this disclosure;
FIG. 2 is a schematic structural exploded view of a battery according to some embodiments
of this disclosure;
FIG. 3 is a schematic structural diagram of a formed wound structure of an electrode
assembly according to some embodiments of this disclosure;
FIG. 4 is a schematic structural exploded view of a battery according to some other
embodiments of this disclosure;
FIG. 5 is a schematic structural diagram of a formed wound structure of an electrode
assembly according to some other embodiments of this disclosure;
FIG. 6 is a schematic diagram of an electrode plate being provided with a second surface
region having second protrusion structures and a first surface region and third surface
region having no protrusion structure in an electrode assembly according to some embodiments
of this disclosure;
FIG. 7 is a schematic diagram of an electrode plate being provided with a first surface
region, a second surface region, and a third surface region having first protrusion
structures, second protrusion structures, and third protrusion structures respectively
in an electrode assembly according to some embodiments of this disclosure;
FIGs. 8 to 13 are schematic diagrams of protrusion heights of first protrusion structures,
second protrusion structures, and third protrusion structures in an electrode assembly
according to some embodiments of this disclosure;
FIG. 14 is a schematic diagram of an electrode plate being provided with a first surface
region, a second surface region, and a third surface region being arranged with polymer
particles in an electrode assembly according to some embodiments of this disclosure;
FIGs. 15 and 16 are schematic diagrams of an electrode plate being provided with a
second surface region having second protrusion structures and a first surface region
and third surface region having no protrusion structure in an electrode assembly according
to some other embodiments of this disclosure; and
FIG. 17 is a schematic diagram of an electrode plate being provided with a first surface
region, a second surface region, and a third surface region having first protrusion
structures, second protrusion structures, and third protrusion structures respectively
in an electrode assembly according to some other embodiments of this disclosure;
[0050] It should be understood that the dimensions of the various parts shown in the accompanying
drawings are not drawn to scale. In addition, same or similar reference numerals denote
same or similar members.
[0051] Description of reference signs:
10, 10': battery cell; 10A: first electrode plate; 10B: second electrode plate; 10C:
separator; 100, 100': wound structure; 11: current collector; 12: active substance
layer;
21: first surface region; 22: second surface region; 23: third surface region; 2e:
outermost end of a wound structure; 2m: division position at an m-th layer of a wound
structure; 2n: division position at an n-th layer of a wound structure; 2s: innermost
end of a wound structure; 21a, 21b, 21c, 22a, 22b, 22c, 22d, 22e, 23a, 23b, 23c: surface
region segment;
31: first protrusion structure; 32: second protrusion structure; 33: third protrusion
structure; 31', 32', 33': polymer particle;
41: first recess portion; 42: second recess portion; 43: third recess portion;
50: battery; 51: box body; 52: end cover; 521: electrode terminal; and
60: vehicle.
DESCRIPTION OF EMBODIMENTS
[0052] The following further describes the embodiments of this disclosure in detail with
reference to the accompanying drawings and implementations. The detailed description
and accompanying drawings of the following embodiments are used to exemplarily illustrate
the principle of this disclosure, but are not intended to limit the scope of this
disclosure, that is, this disclosure is not limited to the described embodiments.
[0053] In the description of this disclosure, it should be noted that, unless otherwise
stated, "multiple" means at least two; and the orientations or positional relationships
indicated by the terms "upper", "lower", "left", "right", "inside", "outside", and
the like are merely for ease and brevity of description of this disclosure rather
than indicating or implying that the means or components mentioned must have specific
orientations or must be constructed or manipulated according to particular orientations.
These terms shall therefore not be construed as limitations on this disclosure. In
addition, the terms "first", "second", "third", and the like are merely for the purpose
of description and shall not be understood as any indication or implication of relative
importance. "Perpendicular" is not perpendicular in the strict sense but within an
allowable range of error. "Parallel" is not parallel in the strict sense but within
an allowable range of error.
[0054] The orientation terms appearing in the following description all are directions shown
in the figures, and do not limit the specific structure of the disclosure. In the
description of this disclosure, it should also be noted that unless otherwise specified
and defined explicitly, the terms "mount", "connect", and "join" should be understood
in their general senses. For example, they may refer to a fixed connection, a detachable
connection, or an integral connection, and may refer to a direct connection or an
indirect connection via an intermediate medium. Persons of ordinary skill in the art
can understand specific meanings of these terms in this disclosure as appropriate
to specific situations.
[0055] The following describes in detail some embodiments of the present invention with
reference to the accompanying drawings. In absence of conflicts, the following features
in the embodiments may be combined.
[0056] In some related technologies, electrode assemblies are formed by winding positive
and negative electrode plates. The inventors have found through research that a wound
electrode assembly swells during battery charging, leading to concentration of swelling
force in certain parts of the wound structure. This results in a lack of gaps in these
parts, causing electrolyte to be squeezed out and reducing infiltration performance.
Some related technologies address this issue by providing patterns of protrusions
and recesses on the electrode plates in prismatic wound structures to create gaps
between the electrode plates and the separator, providing swelling buffer space. However,
such wound structures lack adaptability and are difficult to apply to other forms
of wound structures. Additionally, the design of patterns of protrusions and recesses
does not consider the characteristics of different parts of the electrode assembly,
thus failing to effectively balance battery performance and processing technologies.
[0057] In view of this, the embodiments of this disclosure provide an electrode assembly,
a battery cell, a battery, and an electric apparatus, capable of enhancing battery
performance and improving adaptability.
[0058] The electrode assembly in the embodiments of this disclosure can be applied to various
types of battery cells. The battery cell may include a lithium-ion secondary battery,
a lithium-ion primary battery, a lithium-sulfur battery, a sodium/lithium-ion battery,
a sodium-ion battery, a magnesium-ion battery, or the like. This is not limited in
the embodiments of this disclosure. The battery cell may be cylindrical, flat, cuboid,
or of other shapes, which is not limited in the embodiments of this application either.
Battery cells are typically divided into cylindrical cells, prismatic cells, and pouch
cells by packaging method. The type of battery is not limited in the embodiments of
this application either.
[0059] The battery cell of embodiments of this disclosure can be applied to various batteries.
Batteries can be used to supply power to electric devices such as vehicles, for example,
providing power for vehicle control or driving. The battery may include a housing
and a battery module, where the housing provides space for accommodating the battery
module, and the battery module is installed inside the housing. The housing may be
made of metal material. The battery module may the multiple battery cells connected
in series, parallel, or series-parallel. The battery cell is a smallest unit constituting
a battery. The battery cell includes an electrode assembly capable of undergoing electrochemical
reactions.
[0060] The battery of embodiments of this disclosure can be applied to various electric
apparatuses using batteries. The electric apparatuses may be mobile phones, portable
devices, notebook computers, electric bicycles, electric vehicles, ships, spacecrafts,
electric toys, electric tools, and the like. For example, the spacecraft includes
an airplane, a rocket, a space shuttle, and a spaceship; the electric toy includes
a fixed or mobile electric toy, for example, a game console, an electric vehicle toy,
an electric ship toy, an electric airplane toy, and the like; and the electric tool
includes an electric metal cutting tool, an electric grinding tool, an electric assembly
tool, and an electric railway-specific tool, for example, an electric drill, an electric
grinder, an electric wrench, an electric screwdriver, an electric hammer, an electric
impact drill, a concrete vibrator, an electric planer, and the like. The embodiments
of the present invention impose no special limitation on the foregoing electric apparatus.
[0061] FIG. 1 is a schematic structural diagram of an electric apparatus according to some
embodiments of this disclosure. For convenience, the electric apparatus being a vehicle
is used as an example for description. Referring to FIG. 1, the vehicle 60 is provided
with a battery 50 inside, where the battery 50 is disposed at the bottom, front, or
rear of the vehicle. The battery 50 supplies power to the vehicle. For example, the
battery 50 is used as an operational power source for the vehicle. The battery 50
can be used as a power supply for new energy vehicles, ships, smart electric appliances
cabinets, and other apparatuses. The battery 50 can also serve as a power supply component,
providing the necessary electric energy to various electric components of the apparatus.
[0062] FIG. 2 is a schematic structural exploded view of a battery according to some embodiments
of this disclosure. FIG. 3 is a schematic structural diagram of a formed wound structure
of an electrode assembly according to some embodiments of this disclosure. FIG. 4
is a schematic structural exploded view of a battery according to some other embodiments
of this disclosure. FIG. 5 is a schematic structural diagram of a formed wound structure
of an electrode assembly according to some other embodiments of this disclosure.
[0063] Referring to FIGs. 2 and 4, in some embodiments, the battery 50 includes a box body
51, an end cover 52, and one or more battery cells 10 or 10' provided in the box body
51. The battery cells are electrically connected, such as in series, parallel, or
series-parallel, to implement the required electric performance parameters of the
battery 50. A plurality of battery cells are provided in rows, and one or more rows
of battery cells may be provided in the box body as required. Electrode terminals
521 respectively electrically connected to the anode and cathode of the battery cell
may be provided on the end cover 52.
[0064] In some embodiments, battery cells of the battery 50 may be arranged along at least
one of the length and width directions of the box body. At least one row or one column
of battery cells can be provided according to actual needs. Additionally, one or more
layers of battery cells may further be provided in the height direction of the battery
50 as needed.
[0065] In some embodiments, the battery module may be first formed by connecting the plurality
of battery cells in series, parallel, or series-parallel, and then a plurality of
battery modules are connected in series, parallel, or series-parallel to form an entirety
which is accommodated in the box body 51. In some other embodiments, all the battery
cells are directly connected in series, parallel, or series-parallel to form an entirety
which is then accommodated in the box body.
[0066] Referring to FIGs. 2 to 5, in some embodiments, the battery cell 10 or 10' may include
a housing, an end cover, and an electrode assembly. The housing has a cavity for accommodating
the electrode assembly, and the end of the housing may be constructed as open for
providing an end cover assembly. The electrode assembly is installed in the cavity
of the housing. In addition to the electrode assembly, the end cover, and the housing,
the battery cell 10 or 10' further includes an electrolyte.
[0067] Referring to FIGs. 3 and 5, in some embodiments, an electrode assembly includes a
first electrode plate 10A, a second electrode plate 10B, and a separator 10C provided
between the first electrode plate 10A and the second electrode plate 10B. The first
electrode plate 10A, the separator 10C, and the second electrode plate 10B are wound
in a winding direction r to form a wound structure. The wound structure 100 shown
in FIG. 3 is pressed into a prismatic structure after winding, which has a flat portion
in the center and corner portions located on two sides of the flat portion. Accordingly,
the battery cell including the electrode assembly adopts a prismatic housing structure.
The wound structure 100' shown in FIG. 5 is a hollow cylindrical structure after winding.
Accordingly, the battery cell including the electrode assembly adopts a cylindrical
housing structure.
[0068] Working of the battery cell 10 or 10' mainly relies on migration of metal ions between
the positive electrode plate and the negative electrode plate. The separator 10C may
be made of PP (polypropylene, polypropylene), PE (polyethylene, polyethylene), or
the like.
[0069] The positive electrode plate includes a positive electrode current collector and
a positive electrode active substance layer. The positive electrode active substance
layer is applied on a surface of the positive electrode current collector. The part
of positive electrode current collector uncoated with the positive electrode active
substance layer protrudes out of the part of positive electrode current collector
coated with the positive electrode active substance layer and serves as a positive
tab. A lithium-ion battery is used as an example, for which, the positive electrode
current collector may be made of aluminum and the positive electrode active substance
may be lithium cobaltate, lithium iron phosphate, ternary lithium, lithium manganate,
or the like.
[0070] The negative electrode plate includes a negative electrode current collector and
a negative electrode active substance layer. The negative electrode active substance
layer is applied on a surface of the negative electrode current collector. The part
of negative electrode current collector uncoated with the negative electrode active
substance layer protrudes out of the part of negative electrode current collector
coated with the negative electrode active substance layer and serves as a negative
tab. The negative electrode current collector may be made of copper, and the negative
electrode active substance may be carbon, silicon, or the like. To allow a large current
to pass through without any fusing, multiple positive tabs are provided and stacked
together, and multiple negative tabs are provided and stacked together.
[0071] FIG. 6 is a schematic diagram of an electrode plate being provided with a second
surface region having second protrusion structures and a first surface region and
third surface region having no protrusion structure in an electrode assembly according
to some embodiments of this disclosure. FIG. 7 is a schematic diagram of an electrode
plate being provided with a first surface region, a second surface region, and a third
surface region having first protrusion structures, second protrusion structures, and
third protrusion structures respectively in an electrode assembly according to some
embodiments of this disclosure. FIGs. 8 to 13 are schematic diagrams of protrusion
heights of first protrusion structures, second protrusion structures, and third protrusion
structures in an electrode assembly according to some embodiments of this disclosure.
[0072] Referring to FIGs. 6 and 7, in some embodiments, at least one first surface of the
first electrode plate 10A and second electrode plate 10B at a side closer to the separator
10C includes a first surface region 21, a second surface region 22, and a third surface
region 23 divided along the winding direction. The first surface region 21, the second
surface region 22, and the third surface region 23 each have a length greater than
0 in the winding direction. The second surface region 22 has a plurality of second
protrusion structures 32 distributed discretely.
[0073] Since the electrode plate swells during use of the battery, the protrusion structures
discretely distributed on the side of the electrode plate closer to the separator
support the separator, forming a buffer gap between the electrode plate and the separator.
This buffer gap provides space for the swelling of the electrode plate, avoiding lithium
precipitation caused by a large-area close contact between the electrode plate and
the separator when the electrode plate swells. Additionally, the buffer gap between
the protrusion structures and the separator retains the electrolyte to guarantee the
infiltration effect of the electrolyte within the wound structure, facilitating full
reaction with the active substance on the electrode plate during the charge and discharge
processes of the battery, thereby optimizing the cycling performance of the battery.
[0074] Referring to FIG. 6, in some embodiments, neither the first surface region 21 nor
the third surface region 23 has a protrusion structure. In this way, stronger adaptability
to the stress on different regions after the winding of the wound structure is implemented.
Higher protrusion structures provide sufficient swelling space and pathways for electrolyte
infiltration and absorption in regions with greater swelling forces. Conversely, in
regions with smaller swelling forces, no protrusion structure is provided to simplify
processing or reduce processing difficulty, or minimize processing of the electrode
plate to guarantee strength and rigidity performance of the electrode plate.
[0075] Referring to FIG. 7, in some embodiments, the first surface region 21 has a plurality
of first protrusion structures 31 distributed discretely, and the third surface region
23 has a plurality of third protrusion structures 33 distributed discretely. In some
other embodiments, one of the first surface region 21 and the third surface region
23 is not provided with protrusion structures, and the other is provided with protrusion
structures. The protrusion structures can support the separator, forming a buffer
gap between the electrode plate and the separator. This buffer gap provides space
for the swelling of the electrode plate, avoiding lithium precipitation caused by
a large-area close contact between the electrode plate and the separator when the
electrode plate swells. Additionally, the buffer gap between the protrusion structures
and the separator retains the electrolyte to guarantee the infiltration effect of
the electrolyte within the wound structure, facilitating full reaction with the active
substance on the electrode plate during the charge and discharge processes of the
battery, thereby optimizing the cycling performance of the battery.
[0076] In addition, in FIGs. 6 and 7, the electrode plate includes a current collector substrate
11 and an active substance layer 12 provided on one side surface or two opposite side
surfaces of the current collector substrate 11. At least a part of the plurality of
first protrusion structures 31, the plurality of second protrusion structures 32,
and the plurality of third protrusion structures 33 may be formed by punching or extrusion
of the electrode plate.
[0077] Accordingly, referring to FIG. 6, in some embodiments, at least one second surface
of the first electrode plate 10A and second electrode plate 10B at a side farther
away from the separator 10C has a second recess portion 42 aligned with each of at
least a part of the plurality of second protrusion structures 32. A protrusion structure
with one side concave and the other side convex can be formed through punching or
extrusion of the plate-shaped electrode plate, and the second recess portion is correspondingly
present on the opposite back side of the second protrusion structure. This structure
has relatively low processing difficulty, which is beneficial to large-scale centralized
processing, improving processing efficiency and reducing processing costs. In addition,
the second recess portion can further retain the electrolyte, improving the infiltration
performance of the electrolyte.
[0078] Referring to FIG. 7, in some embodiments, at least one second surface of the first
electrode plate 10A and second electrode plate 10B at a side farther away from the
separator 10C has a first recess portion 41 aligned with each of at least a part of
the plurality of first protrusion structures 31 and/or has a third recess portion
43 aligned with each of at least a part of the plurality of third protrusion structures
33. A protrusion structure with one side concave and the other side convex can be
formed through punching or extrusion of the plate-shaped electrode plate, and the
first recess portion is correspondingly present on the opposite back side of the first
protrusion structure, and/or the third recess portion is correspondingly present on
the opposite back side of the third protrusion structure. This structure has relatively
low processing difficulty, which is beneficial to large-scale centralized processing,
improving processing efficiency and reducing processing costs. In addition, the first
recess portion and the third recess portion can further retain the electrolyte, improving
the infiltration performance of the electrolyte.
[0079] Referring to FIG. 8 to 13, in some embodiments, the protrusion height h1 of the plurality
of first protrusion structures 31 and/or the protrusion height h3 of the plurality
of third protrusion structures 33 is less than or greater than the protrusion height
h2 of the plurality of second protrusion structures 32. In this way, stronger adaptability
to the stress on different regions after the winding of the wound structure is implemented.
Higher protrusion structures provide sufficient swelling space and pathways for electrolyte
infiltration and absorption in regions with greater swelling forces. Conversely, in
regions with smaller swelling forces, lower protrusion structures are provided adaptively
to increase the uniformity of the swelling space, simplifying processing or reduce
processing difficulty of the protrusion structures, or minimizing processing of the
electrode plate to guarantee strength and rigidity performance of the electrode plate.
[0080] FIGs. 8 to 13 show protrusion heights of the first protrusion structures, the second
protrusion structures, and the third protrusion structures in an electrode assembly
according to some embodiments of this disclosure. In FIGs. 8 to 13, the direction
from left to right corresponds to the winding direction of the electrode plate. The
dots corresponding to the plurality of first protrusion structures 31, the plurality
of second protrusion structures 32, and the plurality of third protrusion structures
33 arranged in the winding direction respectively represent protrusion heights h1,
h2, and h3. The protrusion heights herein meet a certain range R due to the accuracy
of the processing technology. According to factors such as processing difficulty and
cost, and the consistency requirement of the protrusion heights, an appropriate range
R can be selected. The range R is a difference between the maximum and minimum values
of the protrusion height.
[0081] In some embodiments, the range of the protrusion height h1 of the plurality of first
protrusion structures, the range of the protrusion height h2 of the plurality of second
protrusion structures, and/or the range of the protrusion height h3 of the plurality
of third protrusion structures is less than or equal to 30 µm. The ranges of the protrusion
heights being less than or equal to 30 µm can reduce the processing difficulty and
lower manufacturing costs for forming protrusion structures.
[0082] In some embodiments, the range of the protrusion height h1 of the plurality of first
protrusion structures, the range of the protrusion height h2 of the plurality of second
protrusion structures, and/or the range of the protrusion height h3 of the plurality
of third protrusion structures is less than or equal to 20 µm. The ranges of the protrusion
heights being less than or equal to 20 µm can simultaneously reduce processing difficulty
for forming protrusion structures and guarantee consistency in the formed swelling
buffer space and pathways for electrolyte infiltration and absorption.
[0083] In some embodiments, the range of the protrusion height h1 of the plurality of first
protrusion structures, the range of the protrusion height h2 of the plurality of second
protrusion structures, and/or the range of the protrusion height h3 of the plurality
of third protrusion structures is less than or equal to 10 µm. The ranges of the protrusion
heights being less than or equal to 10 µm can increase the uniformity and consistency
in the swelling buffer space and pathways for electrolyte infiltration and absorption
formed by the protrusion structures, thus improving the battery performance.
[0084] Referring to FIGs. 8, 10, and 11, in some embodiments, the protrusion height h1 of
the plurality of first protrusion structures 31 and the protrusion height h3 of the
plurality of third protrusion structures 33 are both smaller than the protrusion height
h2 of the plurality of second protrusion structures 32. In the wound structure (such
as the hollow cylindrical wound structure 100' shown in FIG. 5) of some batteries,
since the wound structure 100' has a hollow structure, the swelling forces of the
first surface region and the second surface region on the inner side and the outer
side of the electrode plate respectively in the winding direction are both lower than
the swelling force of the second surface region in the middle. Therefore, with the
protrusion height of the first protrusion structures and the protrusion height of
the third protrusion structures set to be smaller than the protrusion height of the
second protrusion structures, the influence of the processing processes of the electrode
plate, for which protrusion structures are implemented in the first surface region
and the third surface region, on the strength or rigidity of the electrode plate itself
can be reduced.
[0085] Referring to FIG 9, in some embodiments, the protrusion height h1 of the plurality
of first protrusion structures 31 and the protrusion height h3 of the plurality of
third protrusion structures 33 are both greater than the protrusion height h2 of the
plurality of second protrusion structures 32. In the wound structure of some batteries,
the swelling forces of the first surface region and the second surface region on the
inner side and the outer side of the electrode plate respectively in the winding direction
are both higher than the swelling force of the second surface region in the middle.
Therefore, with the protrusion height of the first protrusion structures and the protrusion
height of the third protrusion structures both set to be greater than the protrusion
height of the second protrusion structures, the influence of the processing processes
of the electrode plate, for which protrusion structures are implemented in the second
surface region, on the strength or rigidity of the electrode plate itself can be reduced.
[0086] Referring to FIGs. 8 and 9, in some embodiments, the protrusion height h1 of the
plurality of first protrusion structures 31 and the protrusion height h3 of the plurality
of third protrusion structures 33 are basically equal. Herein, "basically equal" means
that according to the design, protrusion heights h1 and h3 are equal, but due to the
existence of certain ranges, the actual protrusion height h1 is approximately equal
to the protrusion height h3 on the electrode plate. With the heights of the first
protrusion structures and the third protrusion structures being basically equal, the
first protrusion structures and the third protrusion structures can be implemented
through the same processing procedure according to basically the same processing parameters
when the electrode plate is processed, reducing the number of processing steps and
the processing difficulty.
[0087] Referring to FIG. 10, in some embodiments, the protrusion height h1 of the plurality
of first protrusion structures 31 is greater than the protrusion height h3 of the
plurality of third protrusion structures 33. In the wound structure of some batteries,
the swelling force of the first surface region on the inner side of the electrode
plate in the winding direction when the electrode plate swells is greater than the
swelling force of the second surface region on the outer side when the electrode plate
swells. With the protrusion height of the first protrusion structures set to be greater
than the protrusion height of the third protrusion structures, the actual swelling
force in each region can be adapted to the protrusion height of the protrusion structures
provided in this region, thus further improving the battery performance.
[0088] Referring to FIG. 11, the protrusion height h1 of the plurality of first protrusion
structures 31 is less than the protrusion height h3 of the plurality of third protrusion
structures 33. In the wound structure of some batteries, the swelling force of the
first surface region on the inner side of the electrode plate in the winding direction
when the electrode plate swells is less than the swelling force of the second surface
region on the outer side when the electrode plate swells. With the protrusion height
of the first protrusion structures set to be less than the protrusion height of the
third protrusion structures, the actual swelling force in each region can be adapted
to the protrusion height of the protrusion structures provided in this region, thus
further improving the battery performance.
[0089] Referring to the relationship between the protrusion heights of the plurality of
first protrusion structures 31 and the plurality of third protrusion structures 33
shown in FIGs. 10 and 11, the protrusion height h1 of the plurality of first protrusion
structures 31 and the protrusion height h3 of the plurality of third protrusion structures
33 may also both be greater than the protrusion height h2 of the plurality of second
protrusion structures 32.
[0090] Referring to FIG. 12, in some embodiments, the protrusion height h1 of the plurality
of first protrusion structures 31 is greater than the protrusion height h2 of the
plurality of second protrusion structures 32, and the protrusion height h3 of the
plurality of third protrusion structures 33 is less than the protrusion height h2
of the plurality of second protrusion structures 32. In this way, a structure where
the height of the protrusion structures decreases gradually from the inside to the
outside is implemented. The wound structure (such as the prismatic wound structure
100 shown in FIG. 3) of some batteries needs to be flattened after winding. However,
after the wound structure is flattened, there will be a concentration of swelling
force in the first surface region on the inner side of the electrode plate in the
winding direction when the electrode plate swells, while the swelling force of the
third surface region at the outer side is relatively smaller compared to the swelling
force of both the first surface region and the second surface region. Therefore, with
the protrusion height of the first protrusion structures being made greater than the
protrusion height of the second protrusion structures and the protrusion height of
the third protrusion structures being made smaller than the protrusion height of the
second protrusion structures, sufficient buffer space can be provided for the swelling
forces in different regions, reducing lithium precipitation and improving the infiltration
effect of the electrolyte.
[0091] Referring to FIG. 13, in some embodiments, the protrusion height h1 of the plurality
of first protrusion structures 31 is less than the protrusion height h2 of the plurality
of second protrusion structures 32, and the protrusion height h3 of the plurality
of third protrusion structures 33 is greater than the protrusion height h2 of the
plurality of second protrusion structures 32. In the wound structure of some batteries,
there is a concentration of swelling force in the outer region of the wound structure
when the electrode plate swells, while the internal hollow region experiences relatively
smaller swelling force. Therefore, with the protrusion height of the first protrusion
structures being made smaller than the protrusion height of the second protrusion
structures and the protrusion height of the third protrusion structures being made
greater than the protrusion height of the second protrusion structures, sufficient
buffer space can be provided for the swelling forces in different regions, reducing
lithium precipitation and improving the infiltration effect of the electrolyte.
[0092] Referring to FIGs. 8 to 11, the protrusion heights of the plurality of protrusion
structures in the surface regions may be basically equal, thereby facilitating the
consistency of processing of protrusion structures in different surface regions and
reducing the processing difficulty and costs. Referring to FIGs. 12 and 13, the plurality
of protrusion structures of the surface regions may also vary along the winding direction.
In some embodiments, the protrusion height h2 of the plurality of second protrusion
structures 32 gradually increases or gradually decreases along the winding direction.
[0093] For the second surface region, which is located in the middle along the winding direction
of the electrode plate, different wound structures exhibit varying trends in swelling
force in the surface region. For wound structures where the swelling force gradually
increases from the inner to the outer part of the second surface region, gradually
increasing the protrusion height h2 of the second protrusion structures along the
winding direction can make the protrusion height of the second protrusion structures
be adapted to the swelling force. Conversely, for wound structures where the swelling
force gradually decreases from the inner to the outer part of the second surface region,
gradually decreasing the protrusion height h2 of the second protrusion structures
along the winding direction can make the protrusion height of the second protrusion
structures be adapted to the swelling force. In this way, sufficient buffer space
can be provided for the swelling forces in different regions, reducing lithium precipitation
and improving the infiltration effect of the electrolyte.
[0094] Referring to FIGs. 12 and 13, in some embodiments, the protrusion height h1 of the
plurality of first protrusion structures 31 and/or the protrusion height h3 of the
plurality of third protrusion structures 33 gradually increases or gradually decreases
along the winding direction. For the first surface region and the third surface region,
different wound structures exhibit varying trends in swelling force in this region.
Depending on whether the swelling force gradually increases or decreases, gradually
increasing or decreasing the height of the first protrusion structures and/or the
height of the third protrusion structures along the winding direction can make the
protrusion height of the first protrusion structures and/or the third protrusion structures
be adapted to the swelling force. In this way, sufficient buffer space can be provided
for the swelling forces in different regions, reducing lithium precipitation and improving
the infiltration effect of the electrolyte.
[0095] For example, in FIG. 12, the protrusion height h1 of the plurality of first protrusion
structures 31, the protrusion height h2 of the plurality of second protrusion structures
32, and the protrusion height h3 of the plurality of third protrusion structures 33
all gradually decrease along the winding direction. This design can adapt to the trend
of gradually decreasing swelling force present in the surface regions of the wound
structure. However, in FIG. 13, the protrusion height h1 of the plurality of first
protrusion structures 31, the protrusion height h2 of the plurality of second protrusion
structures 32, and the protrusion height h3 of the plurality of third protrusion structures
33 all gradually increase along the winding direction. This design can adapt to the
trend of gradually increasing swelling force present in the surface regions of the
wound structure.
[0096] Referring to FIGs. 3 and 5, the first surface region 21 is a portion of the first
surface from an innermost end 2s of the wound structure 100 or 100' to a division
position 2m at an m-th layer of the wound structure 100 or 100'; the second surface
region 22 is a portion of the first surface from the division position 2m at the m-th
layer of the wound structure 100 or 100' to a division position 2n at an n-th layer
of the wound structure 100 or 100'; and the third surface region 23 is a portion of
the first surface from the division position 2n at the n-th layer of the wound structure
100 or 100' to an outermost end 2e of the wound structure 100 or 100'. Herein, n >
m > 1. In some embodiments, n and m may be positive integers.
[0097] In this way, through the division of the electrode plate along the winding direction
from the innermost end to the outermost end into three surface regions, and setting
the surface region between the division position at the m-th layer and the division
position at the n-th layer as the second surface region, distinct from the situation
when the first surface of the electrode plate is divided into only two regions along
the winding direction or is not divided at all, in conjunction with the foregoing
settings of the protrusion structures, the adaptability of the wound structure is
effectively increased, enhancing battery performance.
[0098] In addition to the protrusion structures shown in FIGs. 6 and 7, other forms of protrusion
structures may further be adopted in some other embodiments. FIG. 14 is a schematic
diagram of an electrode plate being provided with a first surface region, a second
surface region, and a third surface region being arranged with polymer particles in
an electrode assembly according to some embodiments of this disclosure. Referring
to FIG. 14, in some embodiments, each of at least a part of the plurality of second
protrusion structures 32 is a polymer particle attached to or formed on the second
surface region 22. Accordingly, the surface of the electrode plate on the side far
away from the separator may be configured as a plane without recess portions. Through
the usage of the polymer particle attached to or formed on the second surface region
as the second protrusion structure, the influence of processes, like punching or extrusion,
on parameters of the electrode plate, such as strength or rigidity, can be reduced.
[0099] In FIG. 14, each of at least a part of the plurality of first protrusion structures
31 may be a polymer particle attached to or formed on the first surface region 21.
However, each of at least a part of the plurality of third protrusion structures 33
may also be a polymer particle attached to or formed on the third surface region 23.
Through the usage of the polymer particle attached to or formed on the first surface
region as the first protrusion structure and/or the usage of the polymer particle
attached to or formed on the third surface region as the third protrusion structure,
the influence of processes, like punching or extrusion, on parameters of the electrode
plate, such as strength or rigidity, can be reduced.
[0100] In some other embodiments, a part of the plurality of protrusion structures consists
of protrusion structures with a recess portion on the back side, and another part
consists of polymer particles. Alternatively, some surface regions are provided with
protrusion structures with a recess portion on the back side, while other surface
regions are provided with polymer particles.
[0101] Referring to FIGs. 6 and 7, in each surface region, the plurality of protrusion structures
may be uniformly or randomly arranged in the whole surface region, for example, in
an array form, or in an even-odd row staggered arrangement form, and the like. In
some other embodiments, the plurality of protrusion structures may also be discretely
distributed in only a local area in the surface region.
[0102] FIGs. 15 and 16 are schematic diagrams of an electrode plate being provided with
a second surface region having second protrusion structures and a first surface region
and third surface region having no protrusion structure in an electrode assembly according
to some other embodiments of this disclosure. Referring to FIGs. 15 and 16, in some
embodiments, the second surface region 22 includes at least two surface region segments
divided in a direction perpendicular to the winding direction, and the plurality of
second protrusion structures 32 are located in a part of the at least two surface
region segments. Through the division of the second surface region into at least two
surface region segments perpendicular to the winding direction, and the provision
of the second protrusion structures in a part of the surface region segments, the
surface region segment(s) provided with the second protrusion structures are provided
with larger swelling buffer space and electrolyte pathways. This helps to overcome
local lithium precipitation in these surface region segments during battery usage
due to factors such as large local swelling force or insufficient electrolyte flow.
[0103] Referring to FIG. 15, in some embodiments, the at least two surface region segments
include three surface region segments 22a, 22b, and 22c, and the plurality of second
protrusion structures 32 are all located in a surface region segment 22b in the middle
of the three surface region segments 22a, 22b, and 22c. For some wound structures
(such as the hollow cylindrical wound structure 100' shown in FIG. 5), the swelling
force is mainly concentrated in the middle part in the direction perpendicular to
the winding direction. When a battery is being charged, there is a tendency for the
middle region to experience apparent lithium precipitation due to the concentration
of swelling forces. Through the provision of the second protrusion structures in the
middle surface region segment, the swelling buffer space in the middle part can be
improved and the phenomenon of lithium precipitation in the middle part of the wound
structure can be eliminated.
[0104] Referring to FIG. 16, in some embodiments, the at least two surface region segments
include five surface region segments 22a, 22b, 22c, 22d, and 22e, and the plurality
of second protrusion structures 32 are located in three surface region segments 22a,
22c, and 22e at two ends and in the middle among the five surface region segments
22a, 22b, 22c, 22d, and 22e. For some wound structures (such as the hollow cylindrical
wound structure 100' shown in FIG. 5), besides the concentration of the swelling force
in the middle along the direction perpendicular to the winding direction leading to
lithium precipitation, there is also lithium precipitation caused by the concentration
of swelling force and insufficient electrolyte flow at corner positions. Therefore,
through the provision of the second protrusion structures in three surface region
segments at the two ends and in the middle among the five surface region segments,
the swelling buffer space and electrolyte flow pathways at the two ends and in the
middle can be improved, eliminating lithium precipitation in the middle and at the
corner positions of the wound structure.
[0105] FIG. 17 is a schematic diagram of an electrode plate being provided with a first
surface region, a second surface region, and a third surface region having first protrusion
structures, second protrusion structures, and third protrusion structures respectively
in an electrode assembly according to some other embodiments of this disclosure; Referring
to FIG. 17, in some embodiments, the first surface region 21, the second surface region
22, and the third surface region 23 each include at least two surface region segments
divided in a direction perpendicular to the winding direction. The plurality of first
protrusion structures 31 are located in a part 21b of the at least two surface region
segments 21a, 21b and 21c into which the first surface region 21 is divided, the plurality
of second protrusion structures 32 are located in a part 22b of the at least two surface
region segments 22a, 22b and 22c into which the second surface region 22 is divided,
and the plurality of third protrusion structures 33 are located in a part 23b of the
at least two surface region segments 23a, 23b and 23c into which the third surface
region 23 is divided.
[0106] With each surface region divided into at least two surface region segments in a direction
perpendicular to the winding direction, and protrusion structures adaptively provided
in a part of the surface region segments based on the local lithium precipitation
situation or swelling forces of the battery, lithium precipitation at specific locations
of the wound structure can be effectively eliminated, reducing the concentration of
swelling forces, and implementing a more uniform swelling buffer space and electrolyte
infiltration and reflux pathways.
[0107] In the embodiments of the foregoing electrode assemblies, a shape of the plurality
of first protrusion structures 31 may be different from a shape of the plurality of
second protrusion structures 32, and a shape of the plurality of third protrusion
structures 33 may also be different from the shape of the plurality of second protrusion
structures 32. Due to the differences in the support functions provided by different
protrusion structure shapes, in combination with the heights of the protrusion structures,
the adaptability of the wound structure can be effectively increased, and battery
performance can be improved.
[0108] The shape herein may be at least one of an outline shape, a cross-sectional shape,
and a longitudinal sectional shape of the protrusion structures. For example, the
cross-sectional shape of the second protrusion structures 32 is circular, and the
cross-sectional shape of at least one of the first protrusion structures 31 and the
third protrusion structures 33 is regular polygon. For another example, the longitudinal
sectional shape of the second protrusion structures 32 is semicircular ring-shaped,
and the longitudinal sectional shape of at least one of the first protrusion structures
31 and the third protrusion structures 33 is semi-elliptical ring-shaped, and the
like.
[0109] Based on the various embodiments of the foregoing electrode assembly of this disclosure,
embodiments of this disclosure further provide a battery cell, including the foregoing
electrode assembly. The battery cell with the foregoing electrode assembly has better
performance, such as safety performance or cycling performance. In some embodiments,
manufacturing difficulty and manufacturing cost can also be reduced.
[0110] According to an aspect of this disclosure, a battery is provided, including the foregoing
battery cell. The battery with the foregoing battery cell has better performance,
such as safety performance or cycling performance. In some embodiments, manufacturing
difficulty and manufacturing cost can also be reduced.
[0111] According to an aspect of this disclosure, an electric apparatus is provided, including
the foregoing battery. The electric apparatus with the foregoing battery has better
performance, such as safety performance or cycling performance. In some embodiments,
manufacturing difficulty and manufacturing cost can also be reduced.
[0112] Although this disclosure has been described with reference to the preferred embodiments,
various modifications can be made to this disclosure without departing from the scope
of this disclosure and the components therein can be replaced with equivalents. In
particular, as long as there is no structural conflict, the various technical features
mentioned in the embodiments can be combined in any manner. This disclosure is not
limited to the specific embodiments disclosed in this specification, but includes
all technical solutions falling within the scope of the claims.
1. An electrode assembly, comprising a first electrode plate (10A), a second electrode
plate (10B), and a separator (10C) provided between the first electrode plate (10A)
and the second electrode plate (10B), wherein the first electrode plate (10A), the
separator (10C), and the second electrode plate (10B) are wound in a winding direction
to form a wound structure (100; 100');
wherein at least one first surface of the first electrode plate (10A) and second electrode
plate (10B) at a side closer to the separator (10C) comprises a first surface region
(21), a second surface region (22), and a third surface region (23) divided along
the winding direction, wherein the first surface region (21), the second surface region
(22), and the third surface region (23) each have a length greater than 0 in the winding
direction, the second surface region (22) has a plurality of second protrusion structures
(32) distributed discretely, the first surface region (21) has no protrusion structure
or a plurality of first protrusion structures (31) distributed discretely, the third
surface region (23) has no protrusion structure or a plurality of third protrusion
structures (33) distributed discretely, and a protrusion height h1 of the plurality
of first protrusion structures (31) and/or a protrusion height h3 of the plurality
of third protrusion structures (33) is less than or greater than a protrusion height
h2 of the plurality of second protrusion structures (32).
2. The electrode assembly according to claim 1, wherein the protrusion height h1 of the
plurality of first protrusion structures (31) and the protrusion height h3 of the
plurality of third protrusion structures (33) are both less than or greater than the
protrusion height h2 of the plurality of second protrusion structures (32).
3. The electrode assembly according to claim 2, wherein the protrusion height h1 of the
plurality of first protrusion structures (31) and the protrusion height h3 of the
plurality of third protrusion structures (33) are basically equal.
4. The electrode assembly according to claim 2, wherein the protrusion height h1 of the
plurality of first protrusion structures (31) is greater than the protrusion height
h3 of the plurality of third protrusion structures (33).
5. The electrode assembly according to claim 2, wherein the protrusion height h1 of the
plurality of first protrusion structures (31) is less than the protrusion height h3
of the plurality of third protrusion structures (33).
6. The electrode assembly according to claim 1, wherein the protrusion height h1 of the
plurality of first protrusion structures (31) is greater than the protrusion height
h2 of the plurality of second protrusion structures (32), and the protrusion height
h3 of the plurality of third protrusion structures (33) is less than the protrusion
height h2 of the plurality of second protrusion structures (32).
7. The electrode assembly according to claim 1, wherein the protrusion height h1 of the
plurality of first protrusion structures (31) is less than the protrusion height h2
of the plurality of second protrusion structures (32), and the protrusion height h3
of the plurality of third protrusion structures (33) is greater than the protrusion
height h2 of the plurality of second protrusion structures (32).
8. The electrode assembly according to any one of claims 1 to 7, wherein the protrusion
height h2 of the plurality of second protrusion structures (32) gradually increases
or gradually decreases along the winding direction.
9. The electrode assembly according to any one of claims 1 to 8, wherein the protrusion
height h1 of the plurality of first protrusion structures (31) and/or the protrusion
height h3 of the plurality of third protrusion structures (33) gradually increases
or gradually decreases along the winding direction.
10. The electrode assembly according to any one of claims 1 to 9, wherein a range of the
protrusion height h1 of the plurality of first protrusion structures (31), a range
of the protrusion height h2 of the plurality of second protrusion structures (32),
and/or a range of the protrusion height h3 of the plurality of third protrusion structures
(33) is less than or equal to 30 µm.
11. The electrode assembly according to claim 10, wherein the range of the protrusion
height h1 of the plurality of first protrusion structures (31), the range of the protrusion
height h2 of the plurality of second protrusion structures (32), and/or the range
of the protrusion height h3 of the plurality of third protrusion structures (33) is
less than or equal to 20 µm.
12. The electrode assembly according to claim 11, wherein the range of the protrusion
height h1 of the plurality of first protrusion structures (31), the range of the protrusion
height h2 of the plurality of second protrusion structures (32), and/or the range
of the protrusion height h3 of the plurality of third protrusion structures (33) is
less than or equal to 10 µm.
13. The electrode assembly according to any one of claims 1 to 12, wherein the wound structure
(100; 100') is a hollow cylindrical or prismatic structure.
14. The electrode assembly according to any one of claims 1 to 13, wherein the first surface
region (21) is a portion of the first surface from an innermost end of the wound structure
(100; 100') to a division position at an m-th layer of the wound structure (100; 100');
the second surface region (22) is a portion of the first surface from the division
position at the m-th layer of the wound structure (100; 100') to a division position
at an n-th layer of the wound structure (100; 100'); and the third surface region
(23) is a portion of the first surface from the division position at the n-th layer
of the wound structure (100, 100') to an outermost end of the wound structure (100;
100'), wherein n > m > 1.
15. The electrode assembly according to any one of claims 1 to 14, wherein a shape of
the plurality of first protrusion structures (31) and/or a shape of the plurality
of third protrusion structures (33) is different from a shape of the plurality of
second protrusion structures (32).
16. The electrode assembly according to any one of claims 1 to 15, wherein the second
surface region (22) comprises at least two surface region segments divided in a direction
perpendicular to the winding direction, and the plurality of second protrusion structures
(32) are located in a part of the at least two surface region segments.
17. The electrode assembly according to claim 16, wherein the at least two surface region
segments comprise three surface region segments, and the plurality of second protrusion
structures (32) are all located in a surface region segment in the middle of the three
surface region segments.
18. The electrode assembly according to claim 16, wherein the at least two surface region
segments comprise five surface region segments, and the plurality of second protrusion
structures (32) are located in three surface region segments at two ends and in the
middle among the five surface region segments.
19. The electrode assembly according to any one of claims 1 to 18, wherein at least one
second surface of the first electrode plate (10A) and second electrode plate (10B)
at a side farther away from the separator (10C) has a second recess portion (42) aligned
with each of at least a part of the plurality of second protrusion structures (32).
20. The electrode assembly according to any one of claims 1 to 19, wherein at least one
second surface of the first electrode plate (10A) and second electrode plate (10B)
at a side farther away from the separator (10C) has a first recess portion (41) aligned
with each of at least a part of the plurality of first protrusion structures (31)
and/or has a third recess portion (43) aligned with each of at least a part of the
plurality of third protrusion structures (33).
21. The electrode assembly according to any one of claims 1 to 20, wherein each of at
least a part of the plurality of second protrusion structures (32) is a polymer particle
attached to or formed on the second surface region (22).
22. The electrode assembly according to any one of claims 1 to 21, wherein each of at
least a part of the plurality of first protrusion structures (31) is a polymer particle
attached to or formed on the first surface region (21), and/or each of at least a
part of the plurality of third protrusion structures (33) is a polymer particle attached
to or formed on the third surface region (23).
23. A battery cell, comprising the electrode assembly according to any one of claims 1
to 22.
24. A battery, comprising the battery cell according to claim 23.
25. An electric apparatus, comprising the battery according to claim 24.