TECHNICAL FIELD
[0001] The present disclosure relates to an air conditioner.
BACKGROUND ART
[0003] It is disclosed in PTL 1 that the heat exchanger is formed by brazing heat-exchange
tubes and fins that are made of aluminum and an aluminum alloy; the potentials of
the fins, the surfaces of the heat-exchange tubes, and the core portions of the heat-exchange
tubes after the brazing satisfy the following relationship: (more noble) heat-exchange
tube core portions > heat-exchange tube surface > fins (less noble); and the potential
differences between the core portions of the heat-exchange tubes and the surfaces
of the heat-exchange tubes and between the surfaces of the heat-exchange tubes and
the fins after the brazing are each in a range of 40 mV to 60 mV.
SUMMARY OF INVENTION
<Technical Problem>
[0004] However, there is a problem, on which the inventor of the present invention has focused,
in that when the heat exchanger in PTL 1 described above is used for an indoor unit,
aluminum hydroxide, which is a corrosion product, may be generated and scattered into
the room.
<Solution to Problem>
[0005] An air conditioner according to a first aspect includes an indoor unit and an outdoor
unit. The indoor unit includes a first heat exchanger. The outdoor unit includes a
second heat exchanger. The first heat exchanger includes a first flat tube and a first
fin. The first fin is joined to the first flat tube. The second heat exchanger includes
a second flat tube and a second fin. The second fin is joined to the second flat tube.
A potential (electric potential) difference between the first fin and the first flat
tube is smaller than a potential difference between the second fin and the second
flat tube.
[0006] With the air conditioner of the first aspect, since the potential difference between
the first fin and the first flat tube of the indoor unit is made smaller than the
potential difference between the second fin and the second flat tube of the outdoor
unit, corrosion of the first fin and the first flat tube of the indoor unit can be
effectively suppressed. As a result, generation of aluminum hydroxide due to corrosion
of the first fin and the first flat tube can be reduced. Therefore, it is possible
to suppress the scattering of the aluminum hydroxide into a room.
[0007] An air conditioner according to a second aspect is the air conditioner according
to the first aspect, in which a potential of the first fin is higher than a potential
of the second fin.
[0008] In the air conditioner of the second aspect, by making the potential of the first
fin of the indoor unit higher than the potential of the second fin of the outdoor
unit, it is possible to further suppress the scattering of the aluminum hydroxide
into the room by suppressing the corrosion of the first fin.
[0009] An air conditioner according to a third aspect is the air conditioner of the first
aspect or the second aspect, in which a potential of the first fin is higher than
a potential of the first flat tube.
[0010] In the air conditioner of the third aspect, by making the potential of the first
fin higher than the potential of the first flat tube, it is possible to further suppress
the scattering of the aluminum hydroxide into the room by suppressing the corrosion
of the first fin.
[0011] An air conditioner according to a fourth aspect is the air conditioner according
to any one of the first aspect to the third aspect, in which the potential difference
between the first fin and the first flat tube is not less than 20 mV and not more
than 60 mV.
[0012] In the air conditioner of the fourth aspect, the potential difference between the
first fin and the first flat tube of the indoor unit is made as small as not less
than 20 mV and not more than 60 mV. Accordingly, it is possible to further reduce
the generation of aluminum hydroxide due to the corrosion of the first fin and the
first flat tube.
[0013] An air conditioner according to a fifth aspect is the air conditioner according to
any one of the first aspect to the fourth aspect, in which a potential of the first
fin is not less than -890 mV and not more than -750 mV.
[0014] In the air conditioner of the fifth aspect, the first fin of the first heat exchanger
of the indoor unit has a high potential of not less than -890 mV and not more than
-750 mV. Thus, excessive corrosion of the first fin can be suppressed.
[0015] An air conditioner according to a sixth aspect is the air conditioner according to
any one of the first aspect to the fifth aspect, in which a potential of the first
fin is not less than -890 mV and not more than -800 mV.
[0016] In the air conditioner of the sixth aspect, the first fin of the first heat exchanger
of the indoor unit has a very high potential of not less than -890 mV and not more
than -800 mV. Thus, excessive corrosion of the first fin can be further suppressed.
[0017] An air conditioner according to a seventh aspect is the air conditioner according
to any one of the first aspect to the sixth aspect, in which a cooling operation and
a heating operation are performed.
[0018] In the air conditioner of the seventh aspect, when the cooling operation and the
heating operation are performed, it is possible to reduce the generation of the aluminum
hydroxide due to the corrosion of the first fin and the first flat tube of the indoor
unit.
BRIEF DESCRIPTION OF DRAWINGS
[0019]
Fig. 1 is a schematic configuration diagram of an air conditioner according to an
embodiment of the present disclosure.
Fig. 2 is a schematic view of an outdoor unit.
Fig. 3 is a cross-sectional view of first and second flat tubes.
Fig. 4 is a cross-sectional view of the first and second fins.
Fig. 5 is a diagram illustrating a method of measuring a potential in an example.
Fig. 6 is a diagram illustrating the method of measuring the potential in the example.
Fig. 7 is a diagram illustrating the method of measuring the potential in the example.
DESCRIPTION OF EMBODIMENTS
(1) Overall configuration
[0020] An air conditioner 1 according to an embodiment of the present disclosure will be
described with reference to Figs. 1 to 4. As illustrated in Fig. 1, the air conditioner
1 is used for indoor cooling and heating for a building or the like by performing
a vapor compression refrigeration cycle operation.
[0021] The air conditioner 1 mainly includes an indoor unit 2 and an outdoor unit 3, as
well as a liquid-refrigerant connection pipe 4 and a gas-refrigerant connection pipe
5 that connect the indoor unit 2 and the outdoor unit 3. A vapor compression refrigerant
circuit 10 of the air conditioner 1 is configured by connecting the indoor unit 2
and the outdoor unit 3 through the liquid-refrigerant connection pipe 4 and the gas-refrigerant
connection pipe 5.
(1-1) Indoor unit
[0022] The indoor unit 2 is installed in a room. The indoor unit 2 mainly includes a first
heat exchanger 20 and a first fan 11.
[0023] The first heat exchanger 20 is a heat exchanger that functions as an evaporator of
a refrigerant during the cooling operation and functions as a radiator of the refrigerant
during the heating operation. The first heat exchanger 20 has the liquid side connected
to the liquid-refrigerant connection pipe 4, and has the gas side connected to the
gas-refrigerant connection pipe 5.
[0024] The first fan 11 sucks indoor air into the indoor unit 2, supplies the indoor air
to the first heat exchanger 20, and then discharges the indoor air to the outside
of the indoor unit 2.
(1-2) Outdoor unit
[0025] The outdoor unit 3 is installed outdoors. The outdoor unit 3 mainly includes a compressor
12, a flow path switching mechanism 13, a second heat exchanger 30, and an expansion
mechanism 14.
[0026] The compressor 12 is a mechanism that compresses a low-pressure refrigerant in the
refrigeration cycle until the refrigerant reaches a high pressure.
[0027] The flow path switching mechanism 13 is a mechanism that switches the direction of
the flow of the refrigerant when switching between the cooling operation and the heating
operation. During the cooling operation, the flow path switching mechanism 13 connects
the discharge side of the compressor 12 to the gas side of the second heat exchanger
30, and connects the gas side of the first heat exchanger 20 to the suction side of
the compressor 12 through the gas-refrigerant connection pipe 5 (see the solid line
of the flow path switching mechanism 13 in Fig. 1). During the heating operation,
the flow path switching mechanism 13 connects the discharge side of the compressor
12 to the gas side of the first heat exchanger 20 through the gas-refrigerant connection
pipe 5, and connects the gas side of the second heat exchanger 30 to the suction side
of the compressor 12 (see the broken line of the flow path switching mechanism 13
in Fig. 1).
[0028] The second heat exchanger 30 is a heat exchanger that functions as a radiator of
the refrigerant during the cooling operation and functions as an evaporator of the
refrigerant during the heating operation. The second heat exchanger 30 has the liquid
side connected to the expansion mechanism 14, and has the gas side connected to the
flow path switching mechanism 13.
[0029] The expansion mechanism 14 is a mechanism that decompresses the high-pressure liquid
refrigerant that has radiated heat in the second heat exchanger 30 before being sent
to the first heat exchanger 20 during the cooling operation, and decompresses the
high-pressure liquid refrigerant that has radiated heat in the first heat exchanger
20 before being sent to the second heat exchanger 30 during the heating operation.
[0030] The outdoor unit 3 is provided with a second fan 15 for sucking outdoor air into
the outdoor unit 3, supplying the outdoor air to the second heat exchanger 30, and
then discharging the outdoor air to the outside of the outdoor unit 3.
(2) Detailed configuration
[0031] The first heat exchanger 20 and the second heat exchanger 30 will be described with
reference to Figs. 2 to 4. The first heat exchanger 20 and the second heat exchanger
30 are micro-channel heat exchangers.
(2-1) First heat exchanger
[0032] As illustrated in Fig. 2, the first heat exchanger 20 includes a first flat tube
21 and a first fin 22. Here, a plurality of the first flat tubes 21 and a plurality
of the first fins 22 are provided. The first fin 22 is joined to the first flat tube
21.
[0033] The first heat exchanger 20 implements heat exchange between the refrigerant flowing
inside the first flat tubes 21 and the indoor air flowing outside the first flat tubes
21. With the first heat exchanger 20, the indoor air and the refrigerant exchange
heat without being mixed with each other.
[0034] The material of the first flat tubes 21 and the first fins 22 is not particularly
limited, and includes, for example, aluminum, copper, and the like. The first flat
tubes 21 and the first fins 22 of the present embodiment are made of aluminum or an
aluminum alloy.
(2-1-1) First flat tube
[0035] The plurality of first flat tubes 21 are arranged in the vertical direction. The
refrigerant flows inside the first flat tubes 21. As illustrated in Figs. 2 and 3,
the first flat tube 21 is a heat transfer tube having a flat shape. Here, the first
flat tube 21 is a flat perforated tube. In the first flat tube 21, a plurality of
through holes 211 through which the refrigerant to exchange heat with the indoor air
in the first heat exchanger 20 passes are formed to be arranged side by side in a
predetermined direction. The plurality of through holes 211 penetrate along the longitudinal
direction.
[0036] As illustrated in Fig. 3, the first flat tube 21 includes a first base material 212
and a first surface layer 213.
[0037] The first surface layer 213 is provided on the surface of the first flat tube 21.
The first surface layer 213 may be provided entirely on the surface of the first flat
tube 21, or may be provided partially on the surface of the first flat tube 21 (not
illustrated). In other words, the first surface layer 213 may be formed entirely on
the exposed outer surface, or may be formed partially on the exposed outer surface
(not illustrated). The first surface layer 213 is formed partially in the thickness
direction from the outer surface of the first flat tube 21 toward the inner surface
on which the refrigerant flows, and is not formed entirely over the thickness. In
other words, in the first flat tube 21, the first surface layer 213 is not formed
on at least a part of the inner surface on which the refrigerant flows. In the present
embodiment, the first surface layer 213 is not formed entirely on the inner surface
of the first flat tube 21.
[0038] The first surface layer 213 is less noble in potential than the first base material
212. Therefore, in the first flat tube 21, the first surface layer 213 on the outer
surface side is a sacrificial layer that prevents the progress of corrosion of the
first base material 212 on the inner surface side.
[0039] The first surface layer 213 contains a metal such as zinc in order to lower the potential.
The first surface layer 213 of the present embodiment is a zinc diffusion layer in
which zinc is thermally sprayed.
(2-1-2) First fin
[0040] As illustrated in Fig. 2, the first fins 22 are joined to the plurality of first
flat tubes 21. Here, the first flat tubes 21 and the first fins 22 are joined to each
other by brazing. The first fins 22 may or may not be in contact with the first flat
tubes 21. The first fins 22 increase the heat transfer area between the first flat
tubes 21 and the indoor air to facilitate the heat exchange between the refrigerant
and the indoor air.
[0041] The first fins 22 are stacked in the longitudinal direction in which the first flat
tubes 21 extend. Here, the plurality of first fins 22 extend in the vertical direction
so as to intersect (orthogonally in Fig. 2) with the first flat tubes 21.
[0042] The first fin 22 is a flat plate-shaped member. Further, the first fin 22 has notches
for allowing insertion of the plurality of first flat tubes 21. These plurality of
notches are arranged in the vertical direction. The first fin 22 may have a collar
portion.
[0043] As illustrated in Fig. 4, the first fin 22 includes a first body portion 221 and
a first surface layer 222.
[0044] The first surface layer 222 is provided on the surface of the first body portion
221. Here, the first surface layer 222 is provided on both surfaces extending in the
longitudinal direction of the first body portion 221.
[0045] The thickness of the first surface layer 222 is smaller than the thickness of the
first body portion 221. The thickness of each of the first fins 22 is the maximum
value of the distance from the outer surface toward the inside.
[0046] The first surface layer 222 is less noble in potential than the first body portion
221. Therefore, in the first fin 22, the first surface layer 222 on the outer surface
side is a sacrificial layer that prevents the progress of corrosion of the first body
portion 221 on the inner surface side.
[0047] The first fin 22 contains a metal such as zinc in order to lower the potential. The
first surface layer 222 of the present embodiment is a zinc diffusion layer in which
zinc is thermally sprayed. The first fin 22 may further contain magnesium, copper,
and the like.
[0048] The first fin 22 may be electrically less noble or more noble than the first flat
tube 21. Specifically, the first surface layer 222 of the first fin 22 may be electrically
less noble or more noble than the first surface layer 213 of the first flat tube 21.
In other words, the potential may increase in the order of the first surface layer
213 of the first flat tube 21, the first fin 22, and the first base material 212 of
the first flat tube 21, or the potential may increase in the order of the first fin
22, the first surface layer 213 of the first flat tube 21, and the first base material
212 of the first flat tube 21. Still, the first fin 22 is electrically less noble
than the first base material 212. In the present embodiment, the potential of the
first fin 22 is higher than the potential of the first flat tube 21.
[0049] The potential of the first fin 22 of the present embodiment is not less than -890
mV and not more than -750 mV, preferably not less than -890 mV and not more than -800
mV, and more preferably not less than -850 mV and not more than -800 mV. The potential
of the first fin 22 is the potential of the outermost surface. Therefore, the potential
of the first fin 22 is the potential of the first surface layer 222 when the first
fin 22 includes the first surface layer 222, and is the potential of the first body
portion 221 when the first fin 22 does not include the first surface layer 222.
[0050] Such a potential of the first fin 22 is achieved by adjusting the amount of metal
such as zinc contained to lower the potential.
[0051] In the present embodiment, the potential difference between the first fin 22 and
the first flat tube 21 is not less than 20 mV and not more than 60 mV. This potential
difference is the absolute value of the difference between the potential of the first
flat tube 21 and the potential of the first fin 22. Specifically, this potential difference
is the absolute value of the difference between the potential of the outer surface
of the first flat tube 21 and the potential of the outer surface of the first fin
22.
[0052] Such a potential difference is achieved by adjusting the amount of metal such as
zinc contained in the first fins 22 and the first flat tubes 21 to lower the potential.
[0053] Note that the potentials of the first flat tubes 21 and the first fins 22 are values
obtained by taking out some of the first flat tubes 21 and the first fins 22 from
the first heat exchanger 20, producing test pieces, and measuring the test pieces
by a three-electrode method.
(2-1-3) Brazing material
[0054] The first heat exchanger 20 further includes a brazing material (not illustrated)
connecting the first flat tubes 21 and the first fins 22. The brazing material of
the present embodiment contains aluminum.
(2-2) Second heat exchanger
[0055] As illustrated in Fig. 2, the second heat exchanger 30 includes a second flat tube
31 and a second fin 32. Here, a plurality of the second flat tubes 31 and a plurality
of the second fins 32 are provided. The second fin 32 is joined to the second flat
tube 31.
[0056] The second heat exchanger 30 implements heat exchange between the refrigerant flowing
inside the second flat tubes 31 and the outdoor air flowing outside the second flat
tubes 31. With the second heat exchanger 30, the outdoor air and the refrigerant exchange
heat without being mixed with each other.
[0057] The material of the second flat tubes 31 and the second fins 32 is not particularly
limited, and includes, for example, aluminum, copper, and the like. The second flat
tubes 31 and the second fins 32 of the present embodiment are made of aluminum or
an aluminum alloy.
(2-2-1) Second flat tube
[0058] The plurality of second flat tubes 31 are arranged in the vertical direction. The
refrigerant flows inside the second flat tubes 31. As illustrated in Figs. 2 and 3,
the second flat tube 31 is a heat transfer tube having a flat shape. Here, the second
flat tube 31 is a flat perforated tube. In the second flat tube 31, a plurality of
through holes 311 through which the refrigerant to exchange heat with the outdoor
air in the second heat exchanger 30 passes are formed to be arranged side by side
in a predetermined direction. The plurality of through holes 311 penetrate along the
longitudinal direction.
[0059] As illustrated in Fig. 3, the second flat tube 31 includes a second base material
312 and a second surface layer 313.
[0060] The second surface layer 313 is provided on the surface of the second flat tube 31.
The second surface layer 313 may be provided entirely on the surface of the second
flat tube 31, or may be provided partially on the surface of the second flat tube
31 (not illustrated). In other words, the second surface layer 313 may be formed entirely
on the exposed outer surface, or may be formed partially on the exposed outer surface
(not illustrated). The second surface layer 313 is formed partially in the thickness
direction from the outer surface of the second flat tube 31 toward the inner surface
on which the refrigerant flows, and is not formed entirely over the thickness. In
other words, in the second flat tube 31, the second surface layer 313 is not formed
on at least a part of the inner surface on which the refrigerant flows. In the present
embodiment, the second surface layer 313 is not formed entirely on the inner surface
of the second flat tube 31.
[0061] The second surface layer 313 is less noble in potential than the second base material
312. Therefore, in the second flat tube 31, the second surface layer 313 on the outer
surface side is a sacrificial layer that prevents the progress of corrosion of the
second base material 312 on the inner surface side.
[0062] Note that the potentials of the second base material 312 and the second surface layer
313 are values obtained by taking out some of the second base materials 312 and the
second surface layers 313 from the second heat exchanger 30, producing test pieces,
and measuring the test pieces by the three-electrode method.
[0063] The second surface layer 313 contains a metal such as zinc in order to lower the
potential. The second surface layer 313 of the present embodiment is a zinc diffusion
layer in which zinc is thermally sprayed.
(2-2-2) Second fin
[0064] As illustrated in Fig. 2, the second fins 32 are joined to the plurality of second
flat tubes 31. Here, the second flat tubes 31 and the second fins 32 are joined to
each other by brazing. The second fins 32 may or may not be in contact with the second
flat tubes 31. The second fins 32 increase the heat transfer area between the second
flat tubes 31 and the indoor air to promote heat exchange between the refrigerant
and the indoor air.
[0065] The second fins 32 are stacked in the longitudinal direction in which the second
flat tubes 31 extend. Here, the plurality of second fins 32 extend in the vertical
direction so as to intersect (orthogonally in Fig. 2) with the second flat tubes 31.
[0066] The second fin 32 is a flat plate-shaped member. Further, the second fin 32 has notches
for allowing insertion of the plurality of second flat tubes 31. These plurality of
notches are arranged in the vertical direction. The second fin 32 may have a collar
portion.
[0067] As illustrated in Fig. 4, the second fin 32 includes a second body portion 321 and
a second surface layer 322.
[0068] The second surface layer 322 is provided on the surface of the second body portion
321. Here, the second surface layer 322 is provided on both surfaces extending in
the longitudinal direction of the second body portion 321.
[0069] The thickness of the second surface layer 322 is smaller than the thickness of the
second body portion 321. The thickness of each of the second fins 32 is the maximum
value of the distance from the outer surface toward the inside.
[0070] The second surface layer 322 is less noble in potential than the second body portion
321. Therefore, in the second fin 32, the second surface layer 322 on the outer surface
side is a sacrificial layer that prevents the progress of corrosion of the second
body portion 321 on the inner surface side.
[0071] The second fin 32 contains a metal such as zinc in order to lower the potential.
The second surface layer 322 of the present embodiment is a zinc diffusion layer in
which zinc is thermally sprayed. The second fin 32 may further contain magnesium,
copper, and the like.
[0072] The second fin 32 may be electrically less noble or more noble than the second flat
tube 31. Specifically, the second surface layer 322 of the second fin 32 may be electrically
less noble or more noble than the second surface layer 313 of the second flat tube
31. In other words, the potential may increase in the order of the second surface
layer 313 of the second flat tube 31, the second fin 32, and the second base material
312 of the second flat tube 31, or the potential may increase in the order of the
second fin 32, the second surface layer 313 of the second flat tube 31, and the second
base material 312 of the second flat tube 31. Still, the second fin 32 is electrically
less noble than the second base material 312.
[0073] The potential of the second fin 32 is a value obtained by taking out some of the
second fins 32 from the second heat exchanger 30, producing test pieces, and measuring
the test pieces by the three-electrode method.
(2-2-3) Brazing material
[0074] The second heat exchanger 30 further includes a brazing material (not illustrated)
connecting the second flat tubes 31 and the second fins 32. The brazing material of
the present embodiment contains aluminum.
(2-3) Relationship between first heat exchanger and second heat exchanger
[0075] The potential of the first fin 22 is higher than the potential of the second fin
32, and is preferably not less than 110% of the potential of the second fin 32. The
potential of the first fin 22 is the potential of the outer surface of the first fin
22. The potential of the second fin 32 is the potential of the outer surface of the
second fin 32.
[0076] Further, the potential difference between the first fin 22 and the first flat tube
21 is smaller than the potential difference between the second fin 32 and the second
flat tube 31, and is preferably not larger than 90% of the potential difference between
the second fin 32 and the second flat tube 31. For example, the potential difference
between the first fin 22 and the first flat tube 21 is lower than the potential difference
between the second fin 32 and the second flat tube 31 by not less than 20 mV and not
more than 60 mV, and preferably by not less than 30 mV and not more than 50 mV. Here,
the potential difference between the first fin 22 and the first flat tube 21 is the
absolute value of the difference between the potential of the first flat tube 21 and
the potential of the first fin 22. The potential difference between the second fin
32 and the second flat tube 31 is the absolute value of the difference between the
potential of the second fin 32 and the potential of the second flat tube 31. Specifically,
the potential difference between the first fin 22 and the first flat tube 21 is the
absolute value of the difference between the potential of the outer surface of the
first flat tube 21 and the potential of the outer surface of the first fin 22. The
potential difference between the second fin 32 and the second flat tube 31 is the
absolute value of the difference between the potential of the outer surface of the
second flat tube 31 and the potential of the outer surface of the second fin 32.
[0077] Such a potential is achieved by adjusting the amount of metal such as zinc contained
in the first flat tubes 21, the first fins 22, the second flat tubes 31, and the second
fins 32 in order to lower the potential.
(3) Operation
(3-1) Cooling operation
[0078] When the air conditioner 1 performs the cooling operation, a low-pressure refrigerant
in the refrigeration cycle is sucked into the compressor 12, compressed to a high
pressure in the refrigeration cycle, and then discharged. The high-pressure refrigerant
discharged from the compressor 12 is sent to the second heat exchanger 30 through
the flow path switching mechanism 13. The high-pressure refrigerant sent to the second
heat exchanger 30 exchanges heat with the outdoor air supplied by the second fan 15
and radiates heat in the second heat exchanger 30. The high-pressure refrigerant having
radiated heat in the second heat exchanger 30 is sent to the expansion mechanism 14
and is decompressed to a low pressure in the refrigeration cycle. The low-pressure
refrigerant decompressed in the expansion mechanism 14 is sent to the first heat exchanger
20 through the liquid-refrigerant connection pipe 4. The low-pressure refrigerant
sent to the first heat exchanger 20 exchanges heat with the indoor air supplied by
the first fan 11 and evaporates in the first heat exchanger 20. As a result, the indoor
air is cooled and blown into the room. The low-pressure refrigerant having evaporated
in the first heat exchanger 20 is sucked into the compressor 12 again through the
gas-refrigerant connection pipe 5 and the flow path switching mechanism 13.
(3-2) Heating operation
[0079] When the air conditioner 1 performs the heating operation, a low-pressure refrigerant
in the refrigeration cycle is sucked into the compressor 12, compressed to a high
pressure in the refrigeration cycle, and then discharged. The high-pressure refrigerant
discharged from the compressor 12 is sent to the first heat exchanger 20 through the
flow path switching mechanism 13 and the gas-refrigerant connection pipe 5. The high-pressure
refrigerant sent to the first heat exchanger 20 exchanges heat with the indoor air
supplied by the first fan 11 and radiates heat in the first heat exchanger 20. As
a result, the indoor air is heated and blown into the room. The high-pressure refrigerant
having radiated heat in the first heat exchanger 20 is sent to the expansion mechanism
14 through the liquid-refrigerant connection pipe 4, and is decompressed to a low
pressure in the refrigeration cycle. The low-pressure refrigerant decompressed in
the expansion mechanism 14 is sent to the second heat exchanger 30. The low-pressure
refrigerant sent to the second heat exchanger 30 exchanges heat with the outdoor air
supplied by the second fan 15 and evaporates in the second heat exchanger 30. The
low-pressure refrigerant having evaporated in the second heat exchanger 30 is sucked
into the compressor 12 again through the flow path switching mechanism 13.
(4) Features
(4-1)
[0080] According to a possible technique, in a cross-fin heat exchanger, a resin layer may
be formed on a surface of a fin to insulate the fin from a heat transfer tube to suppress
corrosion. However, since a fin and a heat transfer tube (flat tube) are brazed in
the microchannel heat exchanger, the resin layer cannot be formed on the surface of
the fin. Therefore, when there is a potential difference between the fin and the heat
transfer tube, the fin or the heat transfer tube corrodes. For example, to prevent
corrosion of the heat transfer tube in order to prevent refrigerant leakage, the potential
of the fin may be made lower than the potential of the heat transfer tube. In this
case, the fin containing aluminum preferentially corrodes to generate aluminum hydroxide.
When this microchannel heat exchanger is provided in an indoor unit, there arises
the problem that white powdery aluminum hydroxide may scatter into the room. The inventor
of the present invention has arrived at the air conditioner 1 of the present disclosure
in view of such a problem.
[0081] Specifically, the problem of scattering of powder derived from corrosion is not a
big problem with the outdoor unit, but is problematic with the indoor unit, and thus
is a problem unique to the indoor unit. On the other hand, there is another problem
in that the outdoor unit is more likely to corrode due to a higher abundance of chloride
ions in the air than the indoor unit. As a result of intensive studies to solve these
problems, the inventor of the present invention has drawn idea from the relationship
between the potential of the fin and the flat tube of the indoor unit and the potential
of the fin and the flat tube of the outdoor unit.
[0082] Thus, the air conditioner 1 according to the present embodiment includes the indoor
unit 2 and the outdoor unit 3. The indoor unit 2 includes the first heat exchanger
20. The outdoor unit 3 includes the second heat exchanger 30. The first heat exchanger
20 includes the first flat tube 21 and the first fin 22. The first fin 22 is joined
to the first flat tube 21. The second heat exchanger 30 includes the second flat tube
31 and the second fin 32. The second fin 32 is joined to the second flat tube 31.
The potential difference between the first fin 22 and the first flat tube 21 is smaller
than the potential difference between the second fin 32 and the second flat tube 31.
[0083] With the air conditioner 1 of the present embodiment, since the potential difference
between the first fin 22 and the first flat tube 21 of the indoor unit 2 is made smaller
than the potential difference between the second fin 32 and the second flat tube 31
of the outdoor unit 3, it is possible to effectively suppress corrosion of the first
fin 22 and the first flat tube 21 of the indoor unit 2 of the microchannel heat exchanger.
Thus, it is possible to further reduce the generation of aluminum hydroxide due to
the first fin 22 and the first flat tube 21. Therefore, scattering of the white powdery
aluminum hydroxide into the room can be suppressed.
[0084] Since the potential difference between the second fin 32 and the second flat tube
31 of the outdoor unit 3 can be made larger than the potential difference between
the first fin 22 and the first flat tube 21 of the indoor unit 2, corrosion of the
second base material 312 of the second flat tube 31 of the outdoor unit 3 can be suppressed.
[0085] In addition, since the outdoor unit 3 is more likely to corrode than the indoor unit
2, the potential of the second fin 32 of the outdoor unit 3 is preferably made lower
than the potential of the second flat tube 31. In this way, in order to suppress corrosion
of the second flat tube 31 and prevent refrigerant leakage, a potential design can
be adopted in which the second fin 32 preferentially corrode. Also in this case, while
the generation of the aluminum hydroxide in the outdoor unit 3 would not be a big
problem, by reducing the potential difference between the first fin 22 and the first
flat tube 21 of the indoor unit 2, powder scattering from the indoor unit 2 can be
suppressed.
[0086] (4-2)
In the air conditioner 1 according to the present embodiment, the potential of the
first fin 22 is higher than the potential of the second fin 32.
[0087] Here, by making the potential of the first fin 22 of the indoor unit 2 higher than
the potential of the second fin 32 of the outdoor unit 3, the corrosion of the first
fin 22 is suppressed, and thus the scattering of aluminum hydroxide into the room
can be further suppressed.
[0088] (4-3)
In the air conditioner 1 according to the present embodiment, the potential of the
first fin 22 is higher than the potential of the first flat tube 21.
[0089] Here, by making the potential of the first fin 22 higher than the potential of the
first flat tube 21, it is possible to further suppress scattering of aluminum hydroxide
into the room by suppressing corrosion of the first fin 22.
[0090] (4-4)
In the air conditioner 1 according to the present embodiment, the potential difference
between the first fin 22 and the first flat tube 21 is not less than 20 mV and not
more than 60 mV.
[0091] Here, the potential difference between the first fin 22 and the first flat tube 21
of the indoor unit 2 is made as small as not less than 20 mV and not more than 60
mV. Accordingly, it is possible to further reduce the generation of aluminum hydroxide
due to corrosion of the first fin 22 and the first flat tube 21.
[0092] (4-5)
In the air conditioner 1 according to the present embodiment, the potential of the
first fin 22 is not less than -890 mV and not more than -750 mV.
[0093] Here, the first fin 22 of the first heat exchanger 20 of the indoor unit 2 is designed
to be at a high potential that is not less than -890 mV and not more than -750 mV.
Thus, it is possible to reduce generation of aluminum hydroxide due to corrosion of
the first fin 22 without excessively corroding the first fin 22.
[0094] Further, in the indoor unit 2 of the present embodiment, excessive corrosion of the
first fin 22 can be suppressed, and therefore, a corrosive odor can also be suppressed.
[0095] (4-6)
In the air conditioner 1 according to the present embodiment, the potential of the
first fin 22 is not less than -890 mV and not more than -800 mV.
[0096] Here, the first fin 22 of the first heat exchanger 20 of the indoor unit 2 is designed
to be at a high potential that is not less than -890 mV and not more than -800 mV.
Thus, it is possible to further reduce generation of aluminum hydroxide due to corrosion
of the first fin 22 without excessively corroding the first fin 22.
[0097] (4-7)
The air conditioner 1 according to the present embodiment performs a cooling operation
and a heating operation.
[0098] In the present embodiment, excessive corrosion of the first fin 22 and the first
flat tube 21 can be suppressed even when operation that causes condensation in the
evaporator is performed. Therefore, when the air conditioner 1 performs the cooling
operation and the heating operation, it is possible to reduce the generation of aluminum
hydroxide due to the corrosion of the first fin 22 and the first flat tube 21 of the
indoor unit 2.
(5) Modifications
(5-1) Modification 1
[0099] In the above embodiment, the first fin 22 has the first surface layer 222, and the
second fin 32 has the second surface layer 322, but the present disclosure is not
limited to this. At least one of the first fin 22 and the second fin 32 of the present
disclosure may not have a surface layer.
(5-2) Modification 2
[0100] In the above-described embodiment, the first flat tube 21 has the first surface layer
213, and the second flat tube 31 has the second surface layer 313, but the present
disclosure is not limited to this. At least one of the first flat tube 21 and the
second flat tube 31 of the present disclosure may not have a surface layer.
(5-3) Modification 3
[0101] In the above-described embodiment, the first surface layer 213 of the first flat
tube 21 and the second surface layer 313 of the second flat tube 31 are described
to be a diffusion layer in which zinc is thermally sprayed as an example, but the
present disclosure is not limited to this. In the present modification, a clad material
is used for the base material and the surface layer.
[0102] Specifically, the first flat tube 21 is formed using a clad material in which a metal
to be the first base material 212 and a metal to be the first surface layer 213 are
bonded together. The second flat tube 31 is formed using a clad material in which
a metal to be the second base material 312 and a metal to be the second surface layer
313 are bonded together.
(5-4) Modification 4
[0103] In the above embodiment, the air conditioner 1 performing the cooling operation and
the heating operation is described as an example. However, the air conditioner of
the present disclosure is not limited to this. The air conditioner of the present
disclosure may further perform a dehumidifying operation, or may be dedicated to cooling.
EXAMPLES
[0104] In the examples, the effect of making the potential difference between the first
fin 22 and the first flat tube 21 of the indoor unit 2 smaller than the potential
difference between the second fin 32 and the second flat tube 31 of the outdoor unit
3 was investigated.
(EXAMPLE 1)
[0105] In Example 1, the air conditioner 1 illustrated in Fig. 1 including microchannel
heat exchangers as the first heat exchanger 20 of the indoor unit 2 and the second
heat exchanger 30 of the outdoor unit 3 was manufactured.
[0106] Specifically, for the first flat tube 21, zinc was thermally sprayed on the surface
of the first base material 212 made of aluminum to form the first surface layer 213.
For the first fin 22, zinc was thermally sprayed on the surface of the first body
portion 221 made of aluminum to form the first surface layer 222. The first flat tube
21 and the first fin 22 were joined together using a brazing material containing aluminum
to produce the first heat exchanger 20.
[0107] Further, for the second flat tube 31, zinc was thermally sprayed on the surface of
the second base material 312 made of aluminum to form the second surface layer 313.
For the second fin 32, zinc was thermally sprayed on the surface of the second body
portion 321 made of aluminum to form the second surface layer 322. The second flat
tube 31 and the second fin 32 were joined together using a brazing material containing
aluminum to produce the second heat exchanger 30. In Example 1, the zinc content rate
of the first fin 22 was lower than the zinc content rate of the second fin 32.
(Comparative Example 1)
[0108] Comparative Example 1 was basically the same as Example 1, except for the first fin
of the first heat exchanger of the indoor unit. Specifically, the zinc content rate
of a first fin of an indoor unit of Comparative Example 1 was made to be the same
as the zinc content rate of a second fin of an outdoor unit.
(Measurement method and results)
[0109] The potentials of the first base material and the first surface layer of the first
flat tube, the first surface layer of the first fin, the second base material and
the second surface layer of the second flat tube, and the second surface layer of
the second fin of Example 1 and Comparative Example 1 were measured. The measurement
method is as follows.
[0110] A portion of the first base material and the first surface layer of the first flat
tube, the first surface layer of the first fin, the second base material and the second
surface layer of the second flat tube, and the second surface layer of the second
fin were taken out from the first heat exchanger and the second heat exchanger to
produce test pieces, and the test pieces were measured by the three-electrode method.
Specifically, as illustrated in Fig. 5, the length of the test pieces S was set to
40 mm. Then, as illustrated in Fig. 6, epoxy resin R was attached to the test pieces
S, and a test surfaces S1 were exposed. The test surfaces S1 were designed to have
the entire circumference length of 10 mm. A 2.67% aluminum chloride aqueous solution
was used as a test solution. A saturated calomel electrode was used as a reference
electrode. Platinum was used for a counter electrode. As illustrated in Fig. 7, the
test pieces S were connected to the counter electrode using a lead wire. Then, the
potential of the test surfaces S1 was measured by the three-electrode method in a
state of being opened to the atmosphere, at a temperature of 40 °C, and with the pH
of the test solution adjusted.
[0111] Table 1 below lists the results of the measurement of the potentials of Example 1
and Comparative Example 1.
<Table 1>
| |
Indoor unit |
Outdoor unit |
| First fin |
First surface layer |
First base material |
Second fin |
Second surface layer |
Second base material |
| Example 1 |
-800 mV |
-830 mV |
-700 mV |
-900 mV |
-830 mV |
-700 mV |
| Comparative example 1 |
-900 mV |
-830 mV |
-700 mV |
-900 mV |
-830 mV |
-700 mV |
[0112] As listed in Table 1, in Example 1, the potential (-800 mV) of the first fin was
higher than the potential (-900 mv) of the second fin. Further, in Example 1, the
potential difference between the first fin and the first flat tube was 30 mV. In Example
1, the potential difference (30 mV) between the first fin and the first flat tube
was smaller than the potential difference (70 mV) between the second fin and the second
flat tube.
(Evaluation method and results)
[0113] For the air conditioner of Example 1 and the air conditioner of Comparative Example
1, whether aluminum hydroxide scattered from the indoor unit after the cooling operation
and the heating operation were performed was visually confirmed.
[0114] With the air conditioner of Comparative Example 1 in which the potential difference
between the first fin 22 and the first flat tube 21 of the indoor unit 2 was the same
as the potential difference between the second fin 32 and the second flat tube 31
of the outdoor unit 3, aluminum hydroxide scattered from the indoor unit. On the other
hand, with the air conditioner of Example 1 in which the potential difference between
the first fin 22 and the first flat tube 21 of the indoor unit 2 was smaller than
the potential difference between the second fin 32 and the second flat tube 31 of
the outdoor unit 3, aluminum hydroxide did not scatter from the indoor unit.
[0115] From the above, it was confirmed that by making the potential of the first fin 22
and the first flat tube 21 of the indoor unit 2 smaller than the potential of the
second fin 32 and the second flat tube 31 of the outdoor unit 3, the generation of
aluminum hydroxide due to the corrosion of the first fin and the first flat tube is
reduced, and thus the scattering of aluminum hydroxide into the room can be suppressed.
Furthermore, it was also confirmed that when the potential of the first fin is high,
that is, not less than -890 mV and not more than -750 mV, the generation of aluminum
hydroxide due to the corrosion of the first fin was reduced, and thus the scattering
of aluminum hydroxide into the room can be suppressed.
[0116] While embodiments of the present disclosure have been described above, it should
be understood that various changes in mode and detail may be made without departing
from the spirit and scope of the present disclosure as set forth in the claims.
REFERENCE SIGNS LIST
[0117]
- 1
- Air conditioner
- 2
- Indoor unit
- 3
- Outdoor unit
- 20
- First heat exchanger
- 21
- First flat tube
- 22
- First fin
- 30
- Second heat exchanger
- 31
- Second flat tube
- 32
- Second fin
CITATION LIST
PATENT LITERATURE