TECHNICAL FIELD
[0001] The present disclosure relates to steel components, for example, steel components
used in the undercarriages of automobiles and trucks, more specifically knuckles and
front axles, and methods of producing same.
BACKGROUND
[0002] In recent years, concerns about global warming have led to calls in the industrial
world for the curbing of CO
2 emissions. In response to this demand, the automobile industry is not only promoting
the curbing of CO
2 emissions as exhaust gas from automobiles themselves, but is also considering various
ways to curb CO
2 emissions in the component production process. As one technology to curb CO
2 emissions in the production process of such automobile components, development of
non-heat-treated components has been active. Non-heat-treated components are those
for which heat treatment to build up component strength is omitted, that is, thermal
refinement processing of steel is omitted. The omission of heat treatment is made
possible, for example, by technology that allows component strength to be built up
during cooling of the component after the hot forging process in the component production
process.
[0003] Non-heat-treated components are broadly classified into two categories based on their
metallic microstructure. That is, the main metallic microstructure consists of two
phases, ferrite and pearlite, or the main metallic microstructure consists of bainite.
In the former, non-heat-treated steel mainly consisting of ferrite and pearlite, strengthening
by precipitation entirely due to vanadium is used. In other words, vanadium carbides
precipitate finely during the cooling process after hot forging of the component,
strengthening the microstructure by precipitation, and therefore component strength
equivalent to when thermal refining treatment is performed in the state after hot
forging is obtainable. On the other hand, the strengthening mechanism for non-heat-treated
components with bainitic microstructure is transformation strengthening. That is,
the bainite transformation in the cooling process after hot forging creates a microstructure
that is excellent in both strength and toughness. Which non-heat-treated steel is
used depends on the required properties of the component, but typically, non-heat-treated
steel with a bainitic microstructure tends to be used for components that require
both strength and toughness.
[0004] Non-heat-treated steel that has a bainitic microstructure has a good balance of strength
and toughness as above, but yield stress is typically lower, and the ratio of yield
stress to tensile strength, the ultimate strength of steel material, or the so-called
yield ratio, tends to be low. Further, yield stress varies more than tensile strength.
It is arguable that yield stress, the strength at which plastic deformation begins,
is more important than the ultimate strength of steel material in the design of steel
for mechanical structure. From such a design perspective, steel with low yield stress
is difficult to use, no matter how good tensile strength and toughness are. This is
a technical problem for steels that have bainitic microstructure.
[0005] As technologies to address such a technical problem, the techniques of Patent Literature
(PTL) 1 and PTL 2 have been proposed. In PTL 1, a technique is proposed to improve
yield ratio and fatigue ratio (ratio of fatigue strength to tensile strength at 10
7 rpm in the Ono-type rotary bending fatigue test) by controlling cooling to room temperature
after hot forging and then tempering in a temperature range from 400 °C to 700 °C.
Further, in PTL 2, a technique is proposed to increase yield stress by controlling
a cooling rate to room temperature after hot working and then tempering at 200 °C
to 600 °C.
[0006] However, these techniques require tempering after hot forging, which greatly reduces
the benefits of non-heat-treated processing. Therefore, there has also been a pursuit
of techniques to satisfy the required properties without tempering.
[0007] For example, in PTL 3, a technique is proposed to improve yield stress by slow cooling
at a specified cooling rate between 200 °C and 500 °C during cooling after hot forging.
However, in order to perform slow cooling in a specified temperature range, investing
in equipment to modify existing cooling facilities is essential. In recent years,
assembly plants for automobiles and trucks have been built in Southeast Asia and other
regions outside of Japan, which has led to more local procurement of hot forging components.
In plants being built in Southeast Asian countries and elsewhere, forged products
after hot forging are often stacked in steel boxes. In such cases, it may be assumed
that there is a significant difference in cooling rates between forged products near
the bottom of a box and forged products stacked in an upper portion of the box. Further,
most boxes are cuboid, and therefore cooling rates will differ among forged products
near the four corners of a box, forged products near the sides of the box, and forged
products near the center of the box. The strength building process of non-heat-treated
steel is mainly a cooling process after hot forging, and therefore controlling the
cooling rate during the cooling process is important. The problem in local procurement
is that this cooling rate might not be adequately controlled. To address this problem,
the introduction of the technique according to PTL 3 requires that plants in such
countries have dedicated facilities for slow cooling after hot forging. However, it
is extremely difficult to newly introduce such facilities to the improvement of such
countries. Therefore, there is a demand for non-heat-treated steel that can achieve
a defined strength without needing to strictly control cooling rate after hot forging.
In other words, there is a demand for non-heat-treated steel that has mechanical properties
that do not vary too much even when cooling rate varies a little.
[0008] Further, in PTL 4, a microstructural factor that impairs yield ratio and fatigue
ratio is identified as martensite austenite constituent-retained austenite mixed microstructure,
and a technique is proposed to reduce the amount of Si added as a method to reduce
this factor. However, in order to realize steel with Si reduced to the level specified
in PTL 4 in an actual steelmaking process, steel must be produced by a refining method
where Si is not used in the steelmaking process, which incurs high production costs
and is undesirable from an economic viewpoint.
[0009] In PTL 5, a technique is proposed to simultaneously improve toughness and free-cutting
by causing sulfide inclusions having a cross-section area of 3 µm
2 or more to be contained at 200 per mm
2 or more. However, in order to achieve this sulfide content, sulfide must be precipitated
and coarsened prior to hot working, which requires heat treatment or holding at high
temperature for a long time when heating for hot working.
CITATION LIST
Patent Literature
SUMMARY
(Technical Problem)
[0011] The present disclosure is made in view of the above circumstances. That is, it would
be helpful to provide a way to achieve a high yield ratio, specifically a yield ratio
of 0.60 or more, in components from non-heat-treated steel, which is steel that is
not subjected to thermal refining treatment after hot forging, and in particular non-heat-treated
steel having bainitic microstructure. The target value for the yield ratio is 0.60
or more from the viewpoint of suppressing variation in mechanical properties. That
is, yield stress is more sensitive than tensile stress in terms of cooling rate dependence
of mechanical properties of steel having bainitic microstructure as the main microstructure.
In other words, yield stress has a greater effect than tensile strength on variation
in mechanical properties due to variation in cooling rate. Here, tensile stress is
the ultimate stress value in a nominal stress-nominal strain curve obtained in a tensile
test. Further, yield stress is the 0.2 % offset stress from the elastic range in the
same curve. That is, when the yield ratio, the ratio of yield stress to tensile stress,
is a certain value or more, the steel may be regarded as a steel with controlled yield
stress variation, even when the steel is a non-heat-treated steel having a mainly
bainitic microstructure. From this perspective, a yield ratio of 0.60 or more for
a non-heat-treated steel having a bainitic microstructure may be considered to have
a low sensitivity to cooling rate.
(Solution to Problem)
[0012] The inventors have made extensive studies to develop a non-heat-treated steel that
has a yield ratio of 0.60 or more without tempering treatment, without using the techniques
described in PTL 4 and PTL 5.
[0013] It is understood that the yielding phenomenon of metal under stress is the beginning
of large-scale dislocation motion. That is, when stress applied to a dislocation source
exceeds a certain threshold, dislocations are generated and propagate from the dislocation
source, and dislocations so generated move in response to the stress and accumulate
at crystal grain boundaries, causing stress at the crystal grain boundaries. When
stress generated this way at a crystal grain boundary exceeds a certain threshold,
macroscopic deformation begins, in which dislocations entangle not only crystal grains
where dislocations accumulate inside the crystal grain boundary but also crystal grains
that are adjacent, causing simultaneous large-scale deformation of many crystal grains.
This is the yielding phenomenon.
[0014] Looking at the process of yielding described above, there are several possible ways
to increase yield stress: (i) reduce dislocation density, (ii) reduce dislocation
sources, (iii) make it harder for dislocations to be generated from dislocation sources,
and (iv) increase the threshold for deformation of crystal grains in which dislocations
accumulate. However, in bainitic microstructure type non-heat-treated steel, controlling
(i), (ii), and (iii) for yield ratio is difficult. This is because in bainitic microstructure
type non-heat-treated steel, dislocation density generated by bainite transformation
is higher than that of ferrite and pearlite microstructures when steel is cooled to
room temperature after hot forging. Further, bainite has a high amount of fine cementite
that is a dislocation source. In the first place, dislocation strengthening obtained
during transformation and strengthening by precipitation by fine cementite are the
strengthening mechanisms of bainite. When the type, shape, and distribution of precipitates
are determined, the threshold and the like for dislocation generation from such dislocation
sources will also be determined. Increasing yield stress by controlling dislocation
sources would contradict the very concept of developing a bainitic microstructure
type non-heat-treated steel in the first place. Given this, it is necessary to allow
dislocations to generate, propagate, and accumulate in the early stages of stress
loading, and for crystal grains to be hard to deform even when dislocations accumulate.
That is, (iv) is important to obtain high yield ratio in steel with mainly bainitic
microstructure.
[0015] In terms of (iv), there are two ways to make crystal grains hard to deform even when
dislocations accumulate.
[0016] The first is to refine crystal grain size. When crystal grain size is fine, distance
from dislocation source to crystal grain boundary is short, which limits the amount
of dislocations that accumulate, and stress due to dislocation accumulation is accordingly
suppressed. That is, fine crystal grain size is basically better.
[0017] That is, in a bainitic microstructure non-heat-treated steel, average diameter of
crystal grains is required to be 25 µm or less, surrounded by crystal grain boundaries
that have an angular difference in crystal orientation of 15° or more between adjacent
crystal grains. On the other hand, when crystal grains become too fine, crystal grain
boundaries themselves will act as dislocation sources, and therefore a lower limit
is necessary. The lower limit is 10 µm in average diameter. For crystal grain size,
the reason for specifying crystal grains surrounded by crystal grain boundaries having
an angular difference in crystal orientation of 15° or more between adjacent crystal
grains is that dislocations tend to pass through crystal grain boundaries with angles
less than this, that is, sufficient dislocations do not accumulate.
[0018] The second is to control a crystal grain shape. The closer crystal grains are to
a true sphere, the less likely the crystal grains are to deform. That is, the closer
the aspect ratio (minor axis length/major axis length) of crystal grains is to 1,
the better. Further, the closer crystal grain boundary lengths are to that of true
circles, the better. For bainitic microstructure non-heat-treated steel, the aspect
ratio (minor axis length/major axis length) of crystal grains needs to be 0.5 or more,
and an average ratio of crystal grain boundary length to crystal grain circumference
needs to be 60 or less.
[0019] Crystal grain circumference means circumference of a cross-section through the center
of a true sphere (that is, a true circle), assuming that the crystal grain is a true
sphere. However, to determine such a circumference, the true volume of the crystal
grain needs to be known. However, calculating such a volume from microstructure observation
of a cross-section, as is currently done in observation of metallic microstructure,
requires mathematical processing, and for microstructures such as that of non-heat-treated
steel, where the presence of texture is expected, accurate calculation is extremely
difficult. As a compromise, as crystal grain circumference, we used the circumference
obtained from the area of an arbitrary cross-section of a crystal grain, under the
assumption that the crystal grain under consideration is a true sphere. That is, the
circumference of a true circle based on the area of a crystal grain, assuming that
the area of the crystal grains is a perfect circle, as observed in metallic microstructure
observation.
[0020] Finally, the amount of retained austenite present in bainitic microstructure is 5
% or less by area fraction. The crystal structure of retained austenite is a face-centered
cubic lattice. In contrast, ferrite, the underlying microstructure of bainite, is
a body-centered cubic lattice, which is more easily deformed than a face-centered
cubic lattice. That is, retained austenite phase in ferrite is not only finer but
also more difficult to deform than ferrite, and acts as a dislocation source. Accordingly,
the smaller the amount of retained austenite, the better.
[0021] Based on the above findings regarding the effect of microstructure on yield stress,
the inventors narrowed down the scope to examining various combinations of steel alloy
component balance and cooling rate after hot forging that are able to obtain the bainitic
microstructure described above, and arrived at the present disclosure.
[0022] Primary features of the present disclosure are as follows.
- 1. A steel component comprising: a chemical composition containing (consisting of),
in mass%,
C: 0.21 % to 0.24 %,
Si: 0.11 % to 0.25 %,
Mn: 1.81 % to 1.99 %,
P: 0.014 % to 0.025 %,
S: 0.035 % to 0.060 %,
Cr: 0.55 % to 0.65 %,
Al: 0.010 % to 0.050 %,
Ti: 0.005 % to 0.020 %,
V: 0.15 % to 0.20 %, and
N: 0.0090 % to 0.0150 %,
in amounts such that a value of F1 obtained by Formula (1) is 0.65 % or more, with
the balance as Fe and inevitable impurity; and a bainitic microstructure area fraction
of 85 % or more and a retained austenite area fraction of 5 % or less, wherein
crystal grains of the bainitic microstructure have an average diameter of 10 µm or
more and 25 µm or less, an average aspect ratio of 0.5 or more, and an average ratio
of crystal grain boundary length to crystal grain circumference of 60 or less,

where each element symbol in Formula (1) is content in mass% of the element, and elements
not included are considered as 0 for F1 calculation.
- 2. The steel component according to 1, above, wherein a ratio of a difference between
the maximum value Hv1 and the minimum value Hv2 of Vickers hardness at 1 mm below the surface of the steel component to the maximum
value Hv1, ((Hv1 - Hv2)/Hv1) × 100, is 10 % or less.
- 3. The steel component according to 1 or 2, above, wherein the chemical composition
further contains, in mass%, at least one selected from the group consisting of:
Cu: 0.25 % or less,
Ni: 0.25 % or less,
Mo: 0.15 % or less, and
Nb: 0.030 % or less.
- 4. A method of producing a steel component, comprising: applying hot forging after
heating and holding at 1150 °C or more to a steel material comprising the chemical
composition according to 1 or 3, above, to obtain a hot forging material, and then
cooling the hot forging material from 1000 °C to 800 °C at an average cooling rate
of 0.7 °C/s or more and 3.5 °C/s or less, and from 800 °C to 550 °C at an average
cooling rate of 0.5 °C/s or more and 2.0 °C/s or less.
- 5. The method of producing a steel component according to 4, above, wherein the cooling
from 800 °C to 550 °C is performed where a ratio of a difference between the maximum
value V1 and the minimum value V2 of cooling rate distribution in the hot forging material to the maximum value V1, ((V1 - V2)/V1) × 100, is 25 % or less.
(Advantageous Effect)
[0023] According to the steel component of the present disclosure, the ratio of yield stress
to tensile strength (yield ratio) can be 0.60 or more without tempering because a
bainitic microstructure satisfying desired conditions is obtainable in an area fraction
of 85 % or more during cooling after hot forging.
DETAILED DESCRIPTION
[0024] A detailed description is provided below. First, the reasons for limiting the amount
of each element in the chemical composition are explained. Note that the unit "%"
of each chemical component indicates "mass%" unless otherwise specified.
C: 0.21 % to 0.24 %
C (carbon) is a beneficial element that forms a solute or carbide in steel, and improves
steel strength. Bainitic microstructure is a microstructure of precipitated fine cementite,
and therefore when a certain amount of C is not present in steel, there is not enough
cementite to obtain sufficient strengthening by precipitation, resulting in low yield
stress and unsatisfactory yield ratio. C addition of 0.21 % or more is therefore required.
However, when added in excess, the amount of cementite, a dislocation source, becomes
too high, and this too means that a satisfactory yield stress is not maintained. Accordingly,
an upper limit to the amount added is 0.24 %.
Si: 0.11 % to 0.25 %
Si (silicon) is a beneficial element that is a solute in steel, increases steel strength,
improves quench hardenability, and increases bainite area fraction. To obtain these
effects, addition of 0.11 % or more is required. However, Si also has a detrimental
effect, forming a thick coating during preheating for hot forging and degrading scale
separability before hot forging. To avoid this, addition exceeding 0.25 % needs to
be avoided. Content is preferably 0.13 % to 0.23 %.
Mn: 1.81 % to 1.99 %
Mn (manganese) is an important element that is a solute in steel and has a variety
of beneficial effects such as increasing steel strength, increasing quench hardenability
of steel, and combining with S to form sulfides to improve machinability by cutting
of steel. To obtain these effects, addition of 1.81 % or more is required. However,
when Mn is added in excess, the amount of retained austenite becomes too high and
satisfactory yield stress is not maintained. Accordingly, an upper limit to the amount
added is 1.99 %. Content is preferably 1.83 % to 1.97 %.
P: 0.014 % to 0.025 %
P (phosphorus) is a beneficial element that is a solute in steel and increases steel
yield stress. To obtain this effect, addition of 0.014 % or more is required. However,
P segregates at crystal grain boundaries of austenite after hot forging and has an
aspect of deteriorating toughness at room temperature. To avoid this, P content is
0.025 % or less. Content is preferably 0.014 % to 0.022 %.
S: 0.035 % to 0.060 %
S (sulfur) is a beneficial element that combines with Mn to form sulfides in steel,
and has an effect of increasing machinability by cutting of steel. To obtain this
effect, addition of 0.035 % or more is required. However, excessive addition of S
not only reduces the beneficial effects of Mn, such as increased strength and improved
quench hardenability, by forming a large amount of MnS and reducing the amount of
Mn forming a solute in Fe, but MnS also acts as a dislocation source, resulting in
lower steel yield stress. To avoid this, an upper limit of S to be added is 0.060
%. Content is more preferably less than 0.050 %.
Cr: 0.55 % to 0.65 %
Cr (chromium) is an important element that is a solute in steel and has a variety
of beneficial effects, such as increasing steel strength and increasing steel quench
hardenability. To obtain these effects, addition of 0.55 % or more is required. However,
when Cr is added in excess, the amount of retained austenite becomes too high and
high yield stress is not maintained. Accordingly, an upper limit to the amount added
is 0.65 %.
Al: 0.010 % to 0.050 %
Al (aluminum) is a beneficial element that combines with oxygen, which inevitably
enters molten steel from the air during steel refining and casting, to render the
oxygen harmless. When deoxidation by Al is not sufficient, excess oxygen in steel
combines with Ti, and an effect of Ti described below is not fully realized. Addition
of 0.010 % or more is required to render oxygen harmless. However, when more than
0.050 % is added, instead aluminum oxide itself becomes included in large amounts
in steel, deteriorating steel toughness, and therefore addition exceeding 0.050 %
is to be avoided. Content is preferably 0.020 % to 0.045 %.
Ti: 0.005 % to 0.020 %
Ti (titanium) is a beneficial element that forms very fine precipitates in steel and
acts to prevent deterioration of toughness by inhibiting coarsening of austenite grains
before and after hot forging. To obtain this effect, addition of 0.005 % or more is
required. However, when more than 0.020 % is added, precipitates coarsen during heating
before hot forging and no beneficial effect is obtained. Addition exceeding 0.020
% therefore needs to be avoided. Content is preferably 0.006 % to 0.017 %.
V: 0.15 % to 0.20 %
V (vanadium) is a beneficial element that is a solute in steel, and causes solid solution
strengthening of steel as well as increasing steel quench hardenability. To obtain
such effects, addition of 0.15 % or more is required. However, V also acts to deteriorate
steel toughness by combining with C to form precipitates. To avoid this, an amount
of V added is 0.20 % or less. Content is preferably 0.16 % to 0.19 %.
N: 0.0090 % to 0.0150 %
N (nitrogen) is a beneficial element that acts to prevent deterioration of toughness
mainly by combining with Ti and V to inhibit austenite grain coarsening before and
after hot forging. To obtain this effect, addition of 0.0090 % or more is required.
However, when more than 0.0150 % is added, strain aging (an effect in which N segregates
around dislocations and forms a Cottrell atmosphere that significantly hinders dislocation
mobility) occurs at room temperature, and impact value at -50 °C, described below,
is significantly reduced. To avoid this, an upper limit of N to be added is 0.0150
%. Content is preferably 0.0095 % to 0.0130 %.
F1: 0.65 % or more

[0025] Here, each element symbol in Formula (1) is content in mass% of the element, and
elements not included are considered as 0 for F1 calculation.
[0026] A minimum of composition regulation to obtain a bainitic microstructure is as described
above, according to a range of addition for each type of chemical component. Further,
in order to enhance the robustness of mechanical properties obtained when there may
be a range of cooling rates in actual cooling after hot forging, additive alloying
element balance needs to be specified according to Formula (1), indicated as F1. When
the formula that defines this balance is F1, the value of F1 needs to be 0.65 % or
more. That is, when the above value is less than 0.65 %, then even when a mainly bainite
microstructure is obtained, obtaining steel with a yield ratio of 0.60 or more is
difficult.
[0027] Including the above elements, the balance is Fe and inevitable impurity.
[0028] Here, elements considered as inevitable impurity include O (oxygen), B (boron), Mg
(magnesium), Ca (calcium), and REM (rare earth metals). The content of any of these
elements is less than 0.0015 %.
[0029] Further, one or more of Cu, Ni, Mo, or Nb may be added to the chemical composition
described above as required.
Cu: 0.25 % or less
Cu (copper) is an element that is a solute in steel, causes solid solution strengthening
of steel, and may be added to secure strength. When Cu is added, addition of 0.03
% or more is preferred. However, excessive addition of Cu increases retained austenite
and lowers yield stress, resulting in failure to obtain the defined yield ratio. To
avoid this, an upper limit of addition is 0.25 %. The upper limit of addition is more
preferably 0.20 %.
Ni: 0.25 % or less
Ni (nickel) is an element that is a solute in steel, causes solid solution strengthening
of steel, and may be added to secure strength. When Ni is added, addition of 0.03
% or more is preferred. However, excessive addition of Ni increases retained austenite
and lowers yield stress, resulting in failure to obtain the defined yield ratio. To
avoid this, an upper limit of addition is 0.25 %. The upper limit of addition is more
preferably 0.20 %.
Mo: 0.15 % or less
Mo (molybdenum) is an element that is a solute in steel and has a variety of beneficial
effects, such as increasing steel strength and increasing steel quench hardenability,
and is preferably added at 0.10 % or more. However, when Mo is added in excess, the
amount of retained austenite becomes too high and satisfactory yield stress is not
maintained. Accordingly, when added, an upper limit is 0.15 %.
Nb: 0.030 % or less
Nb (niobium) is a beneficial element that forms very fine precipitates in steel and
acts to prevent deterioration of toughness by inhibiting coarsening of austenite grains
before and after hot forging, and is preferably added at 0.013 % or more. However,
excessive addition of Nb causes frequent surface defects in hot rolling. Accordingly,
when added, an upper limit is 0.030 %.
[0030] Specific microstructure requirements are described below.
[Bainitic microstructure area fraction: 85 % or more]
[0031] Bainitic microstructure has a good balance of strength and toughness, and is therefore
appropriate for non-heat-treated steel. Specifically, when steel has a bainitic microstructure,
impact value at -50 °C is 35 J/cm
2 or more, as determined by the Charpy impact test specified in Japanese Industrial
Standard JIS Z2242. That is, an impact value of 35 J/cm
2 or more at -50 °C secures sufficient toughness at the operating temperatures expected
in terrestrial environments where humans use automobiles or heavy-duty vehicles such
as trucks and trailers. To obtain such a property, a bainitic microstructure with
an area fraction of 85 % or more is required. The area fraction is more preferably
90 % or more.
[0032] Microstructure other than bainitic microstructure is not particularly limited, and
may be pearlite, ferrite, or the like, but retained austenite needs to have an area
fraction of 5 % or less.
[Retained austenite area fraction: 5 % or less]
[0033] Retained austenite acts as a dislocation source and lowers yield stress, and therefore
the lower the area fraction, the better, with an upper limit of 5 %. An area fraction
of 0 % is of course possible.
[Average diameter of crystal grains in bainitic microstructure: 10 µm or more and
25 µm or less]
[0034] Bainitic microstructure crystal grain size is a very important factor in making crystal
grains hard to deform. A crystal grain here is a crystal grain surrounded by a crystal
grain boundary having an angular difference in crystal orientation of 15° or more
between the grain boundary and adjacent crystal grains. Further, average diameter
here means a weighted average of diameters of all crystal grains in a field of view
in a range including 20 or more crystal grains as described above in any given observation
plane of a test piece. Further, diameter of a crystal grain is the diameter obtained
from an area of the crystal grain when shape of the crystal grain observed in a microstructure
observation cross-section is assumed to be a true circle.
[0035] That is, in order for a crystal grain to be hard to deform, the average diameter
of the crystal grain needs to be 25 µm or less. Distance from dislocation source to
crystal grain boundary is short, and therefore an amount of dislocations that can
accumulate is limited and stress due to dislocation accumulation is correspondingly
suppressed, resulting in suppression of crystal grain deformation. The average diameter
is more preferably 23 µm or less. However, when too fine, crystal grain boundaries
themselves act as dislocation sources, and therefore a lower limit is 10 µm. The average
diameter is preferably 12 µm or more.
[Average aspect ratio of crystal grains: 0.5 or more]
[0036] In order for a crystal grain to be hard to deform, the closer the shape of the crystal
grain to a true sphere, the better. Accordingly, the aspect ratio of crystal grains
needs to be 0.5 or more. The aspect ratio is preferably 0.55 or more.
[0037] Here, the aspect ratio of a crystal grain is obtained as follows. First, the center
of gravity of a crystal grain obtained by observation is determined. Two arbitrary
straight lines are drawn on the crystal grain orthogonal to each other intersecting
at the center of gravity. When the center of gravity is not located in the crystal
grain, as in a C-shape crystal grain, a point on the crystal grain boundary closest
to the obtained center of gravity is used as the center of gravity. In any line of
two straight lines drawn in this way, a distance between the two points on the line
that intersect the circumference of the crystal grain is an "intersection distance".
When a difference between the intersection distance of one line and the intersection
distance of another line is the maximum difference for the two arbitrary straight
lines, the longer intersection distance is the longest major axis length and the shorter
intersection distance is the shortest minor axis length. The aspect ratio of the crystal
grain is the value obtained by dividing the shortest minor axis length by the longest
major axis length. Further, the average of the aspect ratio is the calculated average
of the aspect ratios of all crystal grains in the same field of view in a range including
20 or more crystal grains in any observation plane of the test piece.
[Average ratio of crystal grain boundary length to crystal grain circumference: 60
or less]
[0038] The ratio of crystal grain boundary length to crystal grain circumference, determined
from the crystal grain diameter described above, needs to be 60 or less on average.
Here, crystal grain boundary length is the length of a crystal grain boundary determined
by converting the total number of pixels judged to be a crystal grain boundary in
a crystal grain measured by electron backscatter diffraction (EBSD), as described
below, into a length by the observation magnification factor. Hereinafter, the ratio
of the crystal grain boundary length to the crystal grain circumference is also referred
to as the crystal grain boundary length ratio. Averaging of the crystal grain boundary
length ratio is also a weighted average of crystal grain boundary length ratios of
all crystal grains in a field of view in a range including 20 or more crystal grains
in any given observation plane of a test piece. The average ratio of crystal grain
boundary length to crystal grain circumference (hereinafter also referred to as crystal
grain boundary length average ratio) may also be determined by EBSD as mentioned above.
When the crystal grain boundary length average ratio exceeds 60, the area of the crystal
grain boundary which is a source of dislocation emission becomes too large, making
obtaining a sufficient yield ratio difficult. The crystal grain boundary length average
ratio is more preferably 55 or less.
[0039] Further, a ratio of a difference between the maximum value Hv
1 and the minimum value Hv
2 of Vickers hardness at 1 mm below the surface of the steel component to the maximum
value Hv
1, that is ((Hv
1 - Hv
2)/Hv
1) × 100, is preferably 10 % or less.

[0040] A steel component that satisfies the above conditions has a desired mechanical property.
The mechanical property thus obtained is preferably uniform in each steel component.
Accordingly, the difference in hardness below the surface of the component ((Hv
1 - Hv
2)/Hv
1) × 100 (hereinafter also referred to as the sub-surface hardness difference) is preferably
10 % or less. That is, deformation of a component is restricted by surface hardness,
a sub-surface hardness difference of 10 % or less results in a more uniform performance
as a component.
[0041] The sub-surface hardness difference may be determined according to a measurement
method described in the Examples below.
[0042] Next, the conditions for producing the steel component described above are explained.
[0043] That is, steel according to the chemical composition described above is melted and
cast into steel material, for example, a steel ingot, which is then heated and held
at a temperature of 1150 °C or more before hot forging into a desired component shape.
Further, it is essential that the hot forging material after hot forging be cooled
at an average cooling rate of 0.7 °C/s or more and 3.5 °C/s or less from 1000 °C to
800 °C and 0.5 °C/s or more and 2.0 °C/s or less from 800 °C to 550 °C.
[Steel material heating temperature: 1150 °C or more]
[0044] First, the steel material is heated to 1150 °C or more. In order to secure forgeability
during hot forging, precipitates that deteriorate forgeability, carbides and nitrides,
need to be heated to 1150 °C or more to be dissolved. Although there is no particular
need to restrict an upper limit, 1300 °C or less is preferable from the viewpoint
of yield rate deterioration due to surface oxide coating.
[0045] The steel material is heated and held at a temperature of 1150 °C or more and then
hot forged into a desired component shape, but the conditions of hot forging are not
particularly limited, and a typical practice of hot forging to form and work each
component may be followed. After the hot forging, the following two-stage cooling
needs to be performed. Incidentally, two-stage cooling is particularly advantageously
adapted to box stacking after hot forging, as practiced in plants of other countries
as mentioned above. That is, the cooling rate from the end of hot forging to 800 °C,
which is the first stage of cooling, is consistent with specifications for a stage
before the forged products are placed in a box. The cooling rate below 800°C, which
is the second stage of cooling, is then consistent with regulations for a stage from
the time the forged products are placed in the box until the start of transformation.
The cooling method may be air cooling, but the cooling method needs to be designed
so that the entire component is within the specified cooling rate.
[Average cooling rate from 1000 °C to 800 °C: 0.7 °C/s or more and 3.5 °C/s or less]
[0046] In the process of imparting desired strength to a non-heat-treated steel component,
the cooling rate during the cooling process of the component after hot forging is
very important. Here, the geometry of hot forging components is not uniform but varies,
and therefore some portions during cooling have a slower cooling rate while others
have a faster cooling rate. In order to obtain somewhat uniform properties throughout
a component during the cooling process when cooling rates vary within a component,
the non-heat-treated steel used as the material needs to be robust with respect to
cooling rate. From this perspective, when the average cooling rate from 1000 °C to
800 °C is less than 0.7 °C/s for a steel having the chemical composition ranges specified
in the present disclosure, prior austenite grains before bainite transformation become
coarse, resulting in an average grain size of bainite exceeding 25 µm. The average
cooling rate from 1000 °C to 800 °C is therefore 0.7 °C/s or more. The average cooling
rate is preferably 0.9 °C/s or more. The average cooling rate is more preferably 1.0
°C/s or more.
[0047] However, when the average cooling rate in the temperature interval described above
exceeds 3.5 °C/s, prior austenite grains before bainite transformation become too
fine, resulting in an average grain size of bainite of less than 10 µm. The cooling
rate from 1000 °C to 800 °C is therefore 3.5 °C/s or less. The cooling rate is preferably
3.2 °C/s or less. The cooling rate is more preferably 3.0 °C/s or less.
[Average cooling rate from 800 °C to 550 °C: 0.5 °C/s or more and 2.0 °C/s or less]
[0048] As described above, from the viewpoint of imparting robustness with respect to cooling
rate for non-heat-treated steel, the average cooling rate from 1000 °C to 800 °C is
controlled to the range of 0.7 °C/s or more and 3.5 °C/s or less. However, even when
this condition is satisfied, average cooling rate in the subsequent temperature range
from 800 °C to 550 °C also needs to be specified. That is, when the average cooling
rate from 800 °C to 550 °C is less than 0.5 °C/s, the crystal grain boundary length
average ratio described above exceeds 60. The average cooling rate from 800 °C to
550 °C is therefore 0.5 °C/s or more. The average cooling rate is preferably 0.7 °C/s
or more. The average cooling rate is more preferably 0.8 °C/s or more.
[0049] On the other hand, even when the average cooling rate from 1000 °C to 800 °C is within
the above specified range, when the average cooling rate from 800 °C to 550 °C exceeds
2.0 °C/s, the average aspect ratio of crystal grains as described above becomes less
than 0.5. The average cooling rate from 800 °C to 550 °C is therefore 2.0 °C/s or
less. The average cooling rate is preferably 1.7 °C/s or less. The average cooling
rate is more preferably 1.5 °C/s or less.
[0050] Further, the cooling from 800 °C to 550 °C is preferably performed where a ratio
of a difference between the maximum value V
1 and the minimum value V
2 of cooling rate distribution in the hot forging material to the maximum value V
1, that is ((V
1 - V
2)/V
1) × 100, is 25 % or less for the hot forging material provided with a component shape
by hot forging.

[0051] As mentioned above, mechanical properties are preferably uniform in each steel component,
and for component performance in particular, uniform microstructure and hardness is
preferred. Accordingly, keeping the cooling rate in a certain range even when component
geometry is complex is beneficial. For this purpose, the cooling rate difference in
hot forging material (V
1 - V
2)/V
1 (hereinafter also referred to as cooling rate difference) is preferably 25 % or less.
When the cooling rate difference is 25 % or less, differences in microstructure and
hardness are small and mechanical performance of the component is more uniform.
[0052] The cooling rate difference may be determined according to a measurement method described
in the Examples below.
[Examples 1]
[0053] The following examples are illustrative of the present disclosure. However, each
example in the following examples is only illustrative, and the present disclosure
is not limited to the following examples.
[0054] Steel having the compositions listed in Table 1 was melted in a vacuum melting furnace
and 50 kg steel ingots (steel material) were cast. Resulting steel ingots were hot-worked
at a temperature of 1150 °C or more into cylinders having a diameter of 37 mm. The
resulting cylinders, 37 mm in diameter, were then hot swaged (hot forged) immediately
after being held at 1250 °C for 1 h to make 25 mm diameter round bars. Three round
bars were prepared for each Steel No., produced under the same production conditions.
[0055] The starting temperature for the hot swaging process was 1100 °C or more. When the
starting temperature of the hot swaging process was controlled in this way, the end
temperature of the swaging process was roughly 1000 °C or more. After the swaging
process was completed, the 25 mm diameter round bars were cooled to obtain steel components
from 1000 °C to 800 °C at an average cooling rate range of 0.7 °C/s or more and 3.5
°C/s or less and from 800 °C to 550 °C at an average cooling rate of 0.5 °C/s or more
to 2.0 °C/s or less. Table 2 lists each production condition.
[0056] During the cooling process after the swaging process, a thermo viewer was used to
measure the change in temperature over time at five locations at a pitch of 50 mm
from the tip of the round bar in the axial direction, and the average cooling rate
at each measurement location was determined. The cooling rates from 1000 °C to 800
°C and from 800 °C to 550 °C listed in Table 2 are the average values of the average
cooling rates calculated at the five locations. Further, the cooling rate difference
((V
1 - V
2)/V
1) × 100 in the temperature range from 800 °C to 550 °C in the cooling process was
obtained from the maximum value V
1 and the minimum value V
2 of the average cooling rates from 800°C to 550°C at the five locations.

[0057] Further, the sub-surface hardness and microstructure of the round bars (steel components)
that had undergone cooling rate measurements were investigated.
[0058] The sub-surface hardness was measured with a Vickers hardness tester at two arbitrary
circumferential locations 1 mm radially from the surface in radial cross-sections
(also referred to as C-sections) of each of the five cooling rate measurement locations,
at 10 locations throughout the round bar. The maximum value Hv
1 and minimum value Hv
2 of the measurement results were used to calculate ((Hv
1 - Hv
2)/Hv
1) × 100 as the sub-surface hardness difference. The obtained sub-surface hardness
differences are listed in Table 2 as the maximum values at the five cooling rate measurement
locations.
[0059] Further, microstructure was investigated using the radial cross-sections of the five
cooling rate measurement locations as observation planes.
[0060] That is, the bainite area fraction was determined by a point-counting method from
optical micrographs of observation planes that were appropriately etched with a nital
solution. The point-counting method is an area fraction measurement method that determines
the percentage of points of the microstructure for which the area fraction is to be
determined out of the total number of points appropriately located on an optical micrograph.
Although there are no particular preferred conditions for size or arrangement of the
points, the points are typically arranged at intersections of lines disposed equally
and orthogonally on the micrograph, that is, a grid of points. There is no rule for
line thickness, but grid points are typically configured with lines that are 0.5 pt
to 0.75 pt thick on a slide in Microsoft's PowerPoint application, for example. The
grid points thus configured are overlaid on the micrograph, and the total number of
grid points on the microstructure for which the area fraction determined as above
is to be measured, as a percentage of the total number of grid points, may be regarded
as the area fraction or volume fraction. When a grid point overlapped with a microstructure
border, it was counted as 0.5 points. The bainite area fraction of the steel component
was then determined by subtracting the retained austenite area fraction determined
by EBSD, described below, from the bainite area fraction thus determined. The obtained
bainite area fractions are listed in Table 2 as average values from five cooling rate
measurement locations.
[0061] Further, the retained austenite area fraction, average grain size of the bainitic
microstructure, average aspect ratio of the crystal grains, and crystal grain boundary
length average ratios were measured using electron backscatter diffraction (EBSD).
Each of the above items was measured by EBSD in five randomly selected fields of view,
the average of each was obtained at five cooling rate measurement locations, and this
average value of the five cooling rate measurement locations was used as the value
of the steel component. The definition of a crystal grain in this microstructure investigation
by EBSD was, as mentioned above, a crystal grain surrounded by a crystal grain boundary
where the angular difference in crystal orientation of adjacent crystal grain is 15°
or more.
[0062] Further, from a round bar (steel component) that was not the round bar (steel component)
whose sub-surface hardness was measured, five locations corresponding to the five
cooling rate measurement locations described above were defined (hereinafter also
referred to as "locations corresponding to measurement"). Among the five locations
corresponding to measurement, taking the third location corresponding to measurement
as a boundary, two No. 4 tensile test pieces as specified in JIS Z2241 were collected
from D/2 positions (D: round bar diameter) at one end and the other end of the round
bar. Accordingly, one test piece included the first and second of the locations corresponding
to measurement, and the other test piece included the fourth and fifth of the locations
corresponding to measurement.
[0063] Further, from a round bar (steel component) that was not the round bar whose sub-surface
hardness was measured or the round bar from which the tensile test pieces were collected,
five U-notch test pieces for the Charpy impact test specified in JIS Z2242 were collected
from D/4 positions, one from each of the five locations corresponding to measurement.
The notch depth of the Charpy impact test piece was 5 mm.
[0064] From the test pieces thus obtained, mechanical properties were investigated as follows.
[0065] First, tensile tests were conducted at a tensile speed of 0.167 mm/s, in accordance
with JIS Z2241. Through the tensile tests, yield stress (strength obtained by offsetting
the straight line obtained from the slope of elastic deformation by 0.2 % from the
elastic limit, also referred to as 0.2 % proof stress) and ultimate strength (ultimate
strength in the nominal stress-nominal strain curve obtained by the tensile test,
also referred to as tensile strength) were determined. The yield stress and tensile
strength obtained were averaged over the two test pieces. When yield ratio, which
is the ratio of yield stress to tensile strength, was 0.60 or more, it may be said
that variation in mechanical properties of the steel component had been suppressed.
[0066] In the Charpy impact test, the impact value at -50 °C was determined in accordance
with JIS Z2242. The impact values obtained were the minimum values for the five test
pieces. When the impact value was 35 J/cm
2 or more, it may be said that the steel component had excellent toughness.
[0067] The measurement results are listed in Table 2.

[0068] In Table 1 and Table 2, Steel No. 1 to Steel No. 34 are examples that satisfy the
chemical composition of the present disclosure. Steel Nos. 1 to 34 were steel material
that was cooled after hot forging within the cooling rate range according to the present
disclosure, and the resulting Steel component Nos. 1 to 34 had the microstructure
and excellent mechanical properties specified in the present disclosure.
[0069] In the comparative example of Steel component No. 35, Cr was high enough, but C and
P deviated from the specifications of the present disclosure, and therefore sufficient
yield stress was not obtained, resulting in the steel component having a low yield
ratio.
[0070] In the comparative example of Steel component No. 36, C and P, as well as Mn and
Cr, deviated from the specifications of the present disclosure, and therefore sufficient
yield stress was not obtained, resulting in the steel component having a low yield
ratio.
[0071] In the comparative example of Steel component No. 37, P deviated from the specifications
of the present disclosure, and therefore sufficient yield stress was not obtained,
resulting in the steel component having a low yield ratio.
[0072] In the comparative example of Steel component No. 38, C, Si, Mn, and P were low and
deviated from the specifications of the present disclosure, and therefore sufficient
yield stress was not obtained, resulting in the steel component having a low yield
ratio.
[0073] In the comparative example of Steel component No. 39, the specifications of the present
disclosure were satisfied except for P, but the amount of P added was less than specified,
resulting in the steel component having a low yield ratio.
[0074] In the comparative example of Steel component No. 40, C, Mn, and V were added in
excess of the amounts specified, and therefore the retained austenite area fraction
was in excess of that specified, resulting in the steel component having a low yield
ratio.
[0075] In the comparative example of Steel component No. 41, Mn was added in excess of the
amount specified, and therefore the retained austenite area fraction was in excess
of that specified, resulting in the steel component having a low yield ratio.
[0076] In the comparative example of Steel component No. 42, C, Mn, P, and Cr were below
the specifications of the present disclosure, and therefore sufficient yield stress
was not obtained, resulting in the steel component having a low yield ratio.
[0077] In the comparative example of Steel component No. 43, Mn was below the specification
of the present disclosure, and therefore although the F1 value itself satisfied the
specification by addition of other elements, sufficient bainite area fraction was
not obtained, resulting in the impact value at -50 °C being below 35 J/cm
2.
[0078] In the comparative examples of Steel component Nos. 44 and 45, C was higher than
specified and Si was lower than specified, and therefore sufficient yield stress was
not obtained and sufficient bainite area fraction was also not obtained, resulting
in the impact value at -50 °C being below 35 J/cm
2.
[0079] In the comparative example of Steel component No. 46, Si was below the specification
of the present disclosure, and therefore although the F1 value itself satisfied the
specification by addition of other alloying elements, sufficient bainite area fraction
was not obtained, resulting in the impact value at -50 °C being below 35 J/cm
2.
[0080] In the comparative example of Steel component No. 47, C and Si exceeded the specifications
of the present disclosure, and therefore the amount of cementite was too high and
sufficient yield stress was not obtained, resulting in the steel component having
a low yield ratio.
[0081] In the comparative example of Steel component No. 48, C exceeded the specification
of the present disclosure, and therefore the amount of cementite was too high and
sufficient yield stress was not obtained, resulting in the steel component having
a low yield ratio.
[0082] In the comparative examples of Steel component Nos. 49 and 50, C was below the specification
of the present disclosure, and therefore sufficient strengthening by precipitation
was not obtained and yield stress was not increased, resulting in the steel component
having a low yield ratio.
[0083] In the comparative examples of Steel component Nos. 51 and 52, C exceeded the specification
of the present disclosure, and therefore the amount of cementite was too high and
sufficient yield stress was not obtained, resulting in the steel components having
a low yield ratio.
[0084] In the comparative example of Steel component No. 53, S and Cr exceeded the specification
of the present disclosure, and therefore the excess S caused the amount of dislocation
source MnS to become excessive, and the excess Cr caused the amount of retained austenite
to exceed the specification of the present disclosure, resulting in the steel component
having a low yield ratio.
[0085] In the comparative example of Steel component No. 54, the value of F1 was below 0.65,
and therefore a sufficient amount of bainite was not obtained, resulting in an impact
value at -50 °C less than 35 J/cm
2.
[0086] In the comparative example of Steel component No. 55, the added amount of Cu exceeded
the specification of the present disclosure, and therefore the amount of retained
austenite exceeded the specification of the present disclosure, resulting in the steel
component having insufficient yield stress and a low yield ratio.
[0087] In the comparative example of Steel component No. 56, the added amount of Ni exceeded
the specification of the present disclosure, and therefore the amount of retained
austenite exceeded the specification of the present disclosure, resulting in the steel
component having insufficient yield stress and a low yield ratio.
[0088] In the comparative example of Steel component No. 57, the added amount of Al was
below the lower limit specified in the present disclosure, resulting in the effect
of microstructure refinement by Ti being insufficient, and the impact value at -50
°C was below 35 J/cm
2.
[0089] In the comparative example of Steel component No. 58, the added amount of Al was
above the upper limit specified in the present disclosure, resulting in an excess
of aluminum oxides excessively dispersed in the steel, and therefore the impact value
at -50 °C was below 35 J/cm
2.
[0090] In the comparative example of Steel component No. 59, the added amount of N was above
the upper limit specified in the present disclosure, resulting in the impact value
at -50 °C being below 35 J/cm
2.
[Examples 2]
[0091] Next, steel having the chemical composition of Steel No. 11 indicated in Table 1
was melted in a vacuum melting furnace, 50 kg steel ingots (steel material) were cast,
25 mm diameter round bars were obtained by swaging processing under the same conditions
as in Examples 1, and steel components were obtained by cooling under the various
cooling rate conditions listed in Table 3. Some round bars (Steel component Nos. A13,
A14, A15, and A16) were 30 mm in diameter for a 150 mm long end portion. That is,
a cooling rate difference was intentionally added to simulate the case where the component
has a complex shape and to investigate the effect of the cooling rate difference on
properties.
[0092] The results of the investigation of the microstructure, sub-surface hardness, and
mechanical properties of the steel components thus obtained, as in Examples 1, are
listed in Table 3. Here, the cooling rate difference was determined as in Examples
1.
[Table 3]
[0093]
[Table 3]
Steel component No. |
Steel No. |
Cooling rate 1000 °C to 800 °C (°C/s) |
Cooling rate 800 °C to 550 °C (°C/s) |
Cooling rate difference at 800 °C to 550 °C (%) |
Bainite area fraction (%) |
Retained austenite area fraction (%) |
Average grain size (µm) |
Average aspect ratio of crystal grains |
Average ratio of actual crystal grain boundary length to crystal grain circumference |
Hardness difference (%) |
Yield stress (MPa) |
Tensile strength (MPa) |
Yield ratio |
Impact value -50 °C (J/cm2) |
Remarks |
A1 |
11 |
0.6 |
1.2 |
9 |
92 |
4 |
28 |
0.57 |
41 |
3 |
555 |
962 |
0.58 |
51 |
Comparative Example |
A2 |
11 |
0.9 |
1.4 |
8 |
96 |
4 |
24 |
0.60 |
27 |
5 |
636 |
946 |
0.67 |
48 |
Example |
A3 |
11 |
1.0 |
1.4 |
12 |
86 |
1 |
21 |
0.55 |
34 |
4 |
601 |
954 |
0.63 |
59 |
Example |
A4 |
11 |
3.6 |
0.9 |
10 |
88 |
2 |
7 |
0.60 |
29 |
5 |
565 |
975 |
0.58 |
51 |
Comparative Example |
A5 |
11 |
3.2 |
1.0 |
13 |
87 |
4 |
11 |
0.58 |
55 |
6 |
608 |
950 |
0.64 |
47 |
Example |
A6 |
11 |
3.0 |
0.8 |
7 |
88 |
5 |
13 |
0.56 |
41 |
7 |
589 |
959 |
0.61 |
46 |
Example |
A7 |
11 |
1.1 |
0.4 |
5 |
91 |
2 |
23 |
0.55 |
77 |
8 |
577 |
977 |
0.59 |
53 |
Comparative Example |
A8 |
11 |
1.7 |
0.7 |
9 |
92 |
3 |
19 |
0.60 |
43 |
6 |
628 |
901 |
0.70 |
51 |
Example |
A9 |
11 |
2.2 |
0.8 |
12 |
86 |
2 |
13 |
0.55 |
36 |
5 |
575 |
890 |
0.65 |
59 |
Example |
A10 |
11 |
2.7 |
2.1 |
16 |
96 |
3 |
12 |
0.41 |
34 |
6 |
544 |
946 |
0.58 |
46 |
Comparative Example |
A11 |
11 |
1.3 |
1.7 |
14 |
85 |
2 |
22 |
0.55 |
49 |
4 |
620 |
976 |
0.64 |
53 |
Example |
A12 |
11 |
2.4 |
1.5 |
12 |
92 |
4 |
13 |
0.60 |
57 |
5 |
623 |
949 |
0.66 |
51 |
Example |
A13 |
11 |
2.1 |
1.8 |
27 |
93 |
3 |
19 |
0.58 |
51 |
14 |
561 |
967 |
0.64 |
39 |
Example |
A14 |
11 |
2.4 |
1.9 |
28 |
95 |
4 |
20 |
0.59 |
53 |
16 |
552 |
958 |
0.65 |
41 |
Example |
A15 |
11 |
1.6 |
1.0 |
22 |
90 |
2 |
22 |
0.61 |
55 |
8 |
543 |
954 |
0.67 |
51 |
Example |
A16 |
11 |
1.4 |
0.9 |
19 |
88 |
3 |
21 |
0.54 |
52 |
9 |
532 |
941 |
0.69 |
49 |
Example |
[0094] Steel component Nos. A2, A3, A5, A6, A8, A9, A11, and A12 listed in Table 3 are examples
that satisfy the conditions of the present disclosure for chemical composition and
cooling rate condition after hot forging.
[0095] In contrast, Steel component No. A1 is a comparative example where the cooling rate
from 1000 °C to 800 °C was less than the specification of the present disclosure,
where the average bainite crystal grain size exceeded the upper limit of 25 µm specified
in the present disclosure, and the yield ratio of 0.60 or more was not obtained.
[0096] Further, Steel component No. A4 is a comparative example where the cooling rate from
1000 °C to 800 °C was above the specification of the present disclosure, resulting
in the average bainite crystal grain size falling below the lower limit of 10 µm specified
in the present disclosure, and the yield ratio of 0.60 or more not being obtained.
[0097] Steel component No. A7 is a comparative example where the cooling rate from 800 °C
to 550 °C was less than the specification of the present disclosure, resulting in
the average ratio of crystal grain length to circumference length when the crystal
grain is assumed to be a true circle exceeded the upper limit of 60 specified in the
present disclosure, and a yield ratio of 0.60 or more was not obtained.
[0098] Steel component No. A10 is a comparative example where the cooling rate from 800
°C to 550 °C was less than the specification of the present disclosure, resulting
in the average aspect ratio of crystal grains being smaller than the lower limit of
0.5 specified in the present disclosure, and a yield ratio of 0.60 or more was not
obtained.
[0099] Steel component Nos. A13, A14, A15, and A16 were partially 30 mm in diameter. Steel
component Nos. A13 and A14 are examples where cooling rate differences from 800 °C
to 550 °C exceeded 25 %, and therefore sub-surface hardness differences in the components
exceeded 10 %. On the other hand, steel component Nos. A15 and A16 are examples where
the cooling rate differences were less than 25 %, and therefore sub-surface hardness
differences in the components were suppressed to 10 % or less.