Technical Field
[0001] The technology relates to the field of semiconductor structures, specifically for
microLEDs (micro light-emitting diodes) used in display and lighting applications.
This field focuses on improving the efficiency, performance, and manufacturing processes
of microLEDs, which are known for their high brightness, low power consumption, long
lifetimes, and very fast response time and high modulation speeds.
Background
[0002] MicroLEDs have emerged as a promising technology for high-resolution displays in
various applications, such as augmented reality (AR), virtual reality (VR), mixed
reality (MR), smartwatches, and head-up displays (HUDs). These applications require
small pixel sizes, typically below 10 µm, to achieve high resolution and compact form
factors. The use of microLEDs offers several advantages over competing technologies,
such as liquid crystal displays (LCDs) and organic light-emitting diodes (OLEDs),
including higher brightness, longer lifetime, and lower power consumption.
[0003] However, there are several challenges associated with the fabrication and performance
of microLEDs at small pixel sizes. One significant issue is the drastic loss of external
quantum efficiency as pixel size decreases. This efficiency loss is mainly due to
increased influence of side-wall damages caused by dry etching.. As a result, the
development of efficient microLEDs with sub-10 µm pixel sizes remains a challenge.
The other issue is the microLEDs emitting red light, where both nitride microLEDs
and AlInGaP ones are not satisfying in terms of efficiency brightness.
[0004] Another challenge in the fabrication of microLEDs is the assembly of red, green,
and blue (RGB) pixels for high-resolution displays. Currently, the three colours are
fabricated on separate wafers using epitaxial methods and need to be picked out of
those wafers and placed on the backplane/driving circuits of the display to build
up the array of RGB pixels. Various techniques exist to accomplish this, many of which
are not yet technologically mature. To date, no pick and place methods can successfully
be used in production to assemble displays having pixel sizes below 10 µm.
[0005] For small displays, like AR/VR/MR, smartwatches, etc., a possibility is to bond the
LED wafers directly to Si CMOS active drive circuitry. This still requires the assembly
of all three colours into RGB pixels. For pixel sizes above 10 µm, this can be achieved
through several approaches, including pick and place methods, mechanical stacking
of all three colour sources on top of each other, or multi-junction epilayers connected
via e.g., tunnel junctions during epitaxy. However, these approaches are not suitable
for pixel sizes below 10 µm.
[0006] Several approaches have been proposed to address these challenges, such as direct
growth of red, green, and blue LEDs on the same epiwafer, i.e., a semiconductor wafer
having a common growth layer, so that pick and place mass transfer can be avoided
and instead a single step wafer bonding could be used to attach the LEDs to the CMOS
chips. However, a technology is still missing to accomplish an RGB epiwafer with pixel
sizes below 10 µm and as small as sub-1-µm with external quantum efficiencies in the
double-digit range for all three colours.
Summary
[0007] The proposed solution relates to devices and methods as outlined in the independent
claims. Further aspects and features are outlined below, and at least partly set out
in the dependent claims.
[0008] According to a first aspect of the disclosure, a semiconductor structure for microLEDs
is provided. The structure comprises an epiwafer and a plurality of InGaN platelets
grown through mask openings of the epiwafer. The InGaN platelets include a quantum
well layer, which quantum well layer may comprise a plurality of quantum wells. Optionally,
each InGaN platelet has a top c-plane surface connectable to a driver circuit for
generating light emission. The quantum well layer may be formed in the InGaN platelets
and can be sandwiched between two InGaN layers, such as a lower n-InGaN part and an
upper p-InGaN part. The quantum well layer can be configured at a height in the InGaN
platelets correlating with an emission wavelength.
[0009] The proposed solution is based on the inventors' research which indicates that when
the quantum well layer is formed closer to the top portion of the pyramid, where the
diameter is also smaller, the quantum well grows thicker, possibly also with higher
concentration of indium, meaning that its emission shifts to longer wavelengths. The
proposed solution thus involves fabrication of a microLED arranged for emission of
a certain wavelength, configured by careful selective epitaxial growth of the quantum
well layer at a certain height. Specifically, this is used for monolithic growth of
RGB triplets from a common epiwafer, where InGaN platelets with the quantum well layer
at different height at least partly dictates the emission color.
[0010] The InGaN platelets may be arranged in groups on the epiwafer for red, green, and
blue light emission. The InGaN platelets can be arranged in a trigonal pattern, and
the InGaN platelets configured for emission of the same colour can be arranged in
a hexagonal pattern. The InGaN platelets can be arranged in groups configured for
different emission wavelengths, and the emission wavelength of the InGaN platelets
may increase with the spacing within the group. The InGaN platelets configured for
emission of red light can have a base layer, adjacent to the epiwafer, of InGaN with
a first Indium concentration, and a buffer layer between the base layer and the quantum
well layer, of InGaN with a second Indium concentration which is higher than the first
Indium concentration.
[0011] According to a second aspect of the disclosure, a method of fabricating a semiconductor
structure for microLEDs is provided. The method includes epitaxial growth of InGaN
pyramids through mask openings of an epiwafer, truncating the InGaN pyramids, e.g.,
by etching or annealing, to form truncated InGaN pyramids, and growing individual
quantum well layers over the truncated pyramids to form individual InGaN platelets.
The originally grown InGaN pyramids may be grown concurrently with a common composition,
and thus the same indium concentration. The truncated pyramids, which comprise the
remainder of the originally grown pyramids after truncation, form respective base
layers for forming the respective and individual monolithically grown InGaN platelets.
Optionally, the method may comprise growing a buffer layer, on each base layer, before
growing the quantum well layer. Indium concentration of the respective buffer layer
may be tailored to the colour of emission of the respective InGaN platelet. Selective
masking of the InGaN platelets may be employed for epitaxial growth of quantum well
layers, and the optional buffer layers, for emission in a wavelength region of one
of red, green, and blue. Growth of the quantum well layers can be performed at a height
over the epiwafer correlating with an intended emission wavelength. The formation
of quantum well layers on the InGaN platelets for different emission wavelengths can
be performed in a common epitaxy process.
[0012] The proposed solution thus offers a semiconductor structure with a plurality of InGaN
platelets monolithically grown from a common epiwafer, wherein the InGaN platelets
are usable for forming RGB pixels. The proposed solution further offers a microLED
device comprising the semiconductor structure connected to a driver circuit.
[0013] The proposed solution offers a huge advantage over prior art solutions. In state-of-the-art
LED growth, one color LED, either blue, green or red, can be made on one wafer (or
one growth run). To fabricate full color microLED displays, mass transfer needs to
be used to transfer sub-pixels of R, G, B microLEDs. This is a very challenging step,
specifically not practical for the microLED below 10 um. In contrast, the proposed
solution provides RGB sub-pixels on the same wafer by consecutive growths. This way,
each full RGB pixel, containing three R/G/B sub-pixels, can be directly bonded to
the driving circuit, avoiding the usage of mass transfer. This provides monolithic
integration of RGB platelet microLEDs by epitaxy, such as Metal-Organic Chemical Vapor
Deposition (MOCVD).
Brief Description of the Drawings
[0014]
Fig. 1 schematically illustrates three epitaxially grown semiconductor structures,
in the form of hexagonal InGaN pyramids, based on which various embodiments of the
proposed solution may be obtained.
Fig. 2 schematically illustrates an example of an InGaN platelet having a single quantum
well according to one embodiment.
Fig. 3 schematically illustrates an example of having a single quantum well sandwiched
in between two InGaN layers having lower indium-contents and close to the top c-plane,
according to one embodiment.
Fig. 4 schematically illustrates a first example of a process flow for making red,
green, and blue InGaN platelets on the same epiwafer, i.e., from the same growth layer,
according to the proposed solution.
Fig. 5 schematically illustrates a second example of a process flow for making red,
green, and blue InGaN platelet LEDs on the same epiwafer.
Fig. 6 schematically illustrates InGaN platelet composition for RGB growth according
to an example of the proposed solution.
Fig. 7 Illustrates an example of the proposed solution, comprising a growth mask hole
centre-centre spacing design on the epiwafer for local tuning of growth rate and resulting
emission light colour.
Fig. 8A shows a top view of an arrangement of contact on the semiconductor structure
for attachment to a driver circuit according to one example.
Fig. 8B schematically illustrates a side view showing the contacts to the semiconductor
structure according to one example.
Fig. 8C schematically illustrates a semiconductor device, in which the semiconductor
structure is connected to a driver circuit for generating emission of RGB light, according
to one example.
Fig. 9 schematically illustrates hexagonal InGaN RGB platelet array design according
to one embodiment.
Fig. 10A illustrates a first example of an RGB pixel based on the pattern of Fig.
9.
Fig. 10B illustrates a second example of an RGB pixel based on the pattern of Fig.
9.
Fig. 11 shows an exemplary pixel array layout for a display based on the example of
Fig. 10A.
Detailed Description
[0015] The detailed description set forth below provides information and examples of the
disclosed technology with sufficient detail to enable those skilled in the art to
practice the disclosure.
[0016] Ternary InGaN alloys are widely used as active layers (or quantum wells) in nitride
LEDs and laser diodes. The thickness of the InGaN active layers is usually no more
than 3 nm, mainly in order to limit impacts of quantum confined Stark effect (QCSE)
which reduces the spatial overlap between the electron and hole wave functions in
the quantum wells. Another reason is that the crystal quality of InGaN can deteriorate
quickly when the layer is grown thick, partly due to a large miscibility gap between
GaN and InN but mainly due to strain effects from the growth on mismatched substrates.
However, the prospect of thick and relaxed InGaN films is highly desirable, for the
use as a substrate for nitride optoelectronic devices where high indium-content InGaN
active layers are needed.
[0017] Selective area growth has been widely used to fabricate GaN in order to reduce density
of dislocations arising from the lattice mismatch between the substrate and epitaxial
GaN layers. Dislocation-free GaN structures, including nanowires and pyramids, can
be grown if the mask holes are made sufficiently small, such as 200 nm or less.
[0018] Fig. 1 shows three epitaxially grown semiconductor structures in the form of hexagonal
InGaN pyramids, which can be used as a basis for various embodiments of the proposed
solution. This drawing illustrates a semiconductor structure which may be fabricated
and used as a starting structure for fabricating the InGaN platelets according to
the proposed solution. A base substrate 1 of e.g., sapphire or Si, is provided with
one or more layers of c-oriented GaN as growth layer 2, such as a (0001)-oriented
GaN film. A mask layer 3 of e.g., SiN
x is formed on top of the GaN layer. Holes (or openings/apertures) 4 are provided in
the mask layer. The holes 4 may be manufactured by means of various types of lithography,
such as EBL (electron beam lithography), nanoimprint, DUV (Deep UltraViolet) lithography,
etc. The holes 4 may be very narrow, e.g., with a diameter of 20-200 nm, 50-150 nm,
or 60-100 nm. Growth of a seed of a first III-nitride material, such as GaN, may optionally
be performed. In a subsequent step, hexagonal pyramids 5 of InGaN are epitaxially
grown over the holes, from the growth layer (optionally from the seeds). The growth
takes place with gallium and indium species primarily diffusing from the SiN mask
surface to the holes, without any nucleation on the mask surface. This way, growth
of InGaN pyramids with an indium composition up to 20% has been realized, as determined
by photoluminescence (PL) measurements. The growth of the InGaN pyramids may be carried
out with selective doping, such that negatively doped n-InGaN pyramids 5 are obtained.
Various examples and aspects related to the prefabrication of the structure of Fig.
1 are disclosed in
WO2020187986A1, which is incorporated herein by reference.
[0019] The hexagonal InGaN pyramids with a diagonal base size of several hundred nanometers,
such as >400 nm, may be used. These pyramids have {101 1} side facets, and occasionally
a small flat (0001) top facet. Each of the pyramids is a homogeneous InGaN semiconductor
structure. In some examples, one or more of the pyramids may be epitaxially grown
in two or more epitaxy stages with different, e.g., increasing, indium concentration,
as will be described.
[0020] The pre-fabrication step of epitaxial growth from the mask holes results in the InGaN
pyramids being free, or substantially free, from dislocations. As a result, emission
non-uniformity caused by dislocations between pixels (individual semiconductor devices)
is avoided. This contributes positively to obtain high quantum efficiency, such as
more than 10%. In addition, a very thin GaN buffer/growth layer 2 may be used, e.g.,
below 1 µm, which results in very low wafer bow. This provides the benefit of high
yield processing.
[0021] Various aspects of the proposed solutions are based on creating quantum wells (QWs)
embedded within InGaN pyramids or truncated InGaN pyramids to obtain InGaN platelets
configured to operate as microLEDs, each configured to emit light of one of red, green
and blue. Each such InGaN platelet, i.e., for each colour, is in some embodiments
processed from an array of InGaN pyramids which are substantially identical, by being
concurrently grown from respective mask holes in an epitaxy process.
[0022] According to some aspects, the InGaN pyramids are arranged/grown in a first trigonal
pattern on the carrier, wherein each InGaN platelet has six neighbour InGaN platelets
at the same distance. This way, uniformity in growth of the InGaN pyramids, based
on which the InGaN platelets are formed, is obtained. In such embodiments, an RGB
triplet may e.g., be defined in a straight line, or in a triangular arrangement.
[0023] Use of epitaxially grown InGaN pyramids, grown from small holes to a common growth
layer, provides advantages of high crystal quality and high production efficiency
of the InGaN platelets.
[0024] According to some examples, the pyramid shape of the starting structure is advantageously
used, based on the understanding that truncation to create a top c-plane of different
truncated pyramid height, i.e., at different elevation over the carrier, or epiwafer,
will also provide basis for preparing QWs for emission at different wavelengths (different
colours), correlating with the surface size of the c-plane. This example provides
for the possibility to grow QW layers (each QW layer comprising one or more QW and
associated layers) for all three colours in a common growth process step.
[0025] According to some examples, the pre-disposition of separate InGaN pyramids for each
pixel according to a growth mask provides an efficient basis for separately masking
or not masking selected pyramids, so as to either remove material or epitaxially grow
selected InGaN platelet for the purpose of creating InGaN platelet for emission of
light in a desired wavelength, such as red, green, or blue.
[0026] According to some examples, the pyramids may be configured with a tailored pattern,
defined by the arrangement of the mask holes on the epiwafer. In some examples, the
pattern may define groups of pixels of the same colour (i.e., configured to emit light
of the same colour) having a pre-configured pixel pitch within the group, wherein
the pixel pitch is different dependent on colour. Specifically, the pixel pitch PP
(e.g., centre to centre distance of the mask holes) within each group is preconfigured
to promote different growth of QW layers for different colour groups. This way, QW
layers of two or three groups may be grown concurrently in the same epitaxy process.
[0027] Figs 2 and 3 show different types of InGaN platelets, i.e., InGaN pyramids which
have been truncated and subjected to subsequent epitaxial growth to form QW layers
and upper p-InGaN growth, according to various examples of the proposed solution.
[0028] Fig. 2 illustrates an example of an InGaN platelet 100 comprising a QW layer 110
having a single QW according to one embodiment. The InGaN platelet 100 has a truncated
pyramid shape with a substantially planar top surface 120. The InGaN platelet 100
is fabricated from a pyramid grown through mask openings to the growth layer 2, of
which a portion is indicated. The QW layer 110 is formed in the InGaN platelet 100
and is configured at a height correlating with an intended emission wavelength. The
figure shows an example of an InGaN platelet having a single QW sandwiched in between
two InGaN layers having lower indium-contents. Light emission from QW is around 620
nm.
[0029] Fig. 3 shows an example of an InGaN platelet 100 having a QW layer 110 comprising
a single QW sandwiched in between two InGaN layers with lower indium contents and
close to the top c-plane. Light emission from QW has shifted to 750nm due to thicker
QW and higher indium contents as compared to Fig. 2, indicating that emission wavelength
can be shifted depending on distance to the tip/apex of the pyramid for fixed growth
conditions.
[0030] The proposed solution includes a method for fabrication of a semiconductor device
comprising InGaN platelets configured for red, green, and blue (RGB) emission on the
same carrier, which is a common semiconductor substrate, herein also referred to as
epiwafer. Each InGaN platelet is thus configured to operate as a microLED, upon connection
to a driver circuit.
[0031] By employing bottom-up growth, rather than using state of the art plasma etching
to remove InGaN material to form InGaN mesas of a certain pixel size, the risk for
damaging remaining material for the pixels is minimized, which provides high efficiency.
[0032] Fig. 4 presents various stages of a first example of a process flow for making red,
green, and blue InGaN platelets 100 on the same epiwafer 10 according to the proposed
solution. The process includes, or succeeds, epitaxial growth of InGaN pyramids 5
through mask openings 4 of the epiwafer 10. In this context, it may be noted that
the epiwafer 10 (or carrier) comprises at least the mask layer 3, whereas the underlying
growth layer 2, used for growing the InGaN pyramids through the mask holes, may be
removed or thinned after finalizing the InGaN platelets.
[0033] The process involves truncation of the InGaN pyramids to form truncated InGaN pyramids,
and growing QW layers to form truncated InGaN platelets 100 (100B, 100G, 100R). In
the context of the proposed solution, truncation may be obtained using one or more
of various types of processes for material removal or redisposition to obtain a truncated
pyramid shape. Etching is one example, whereas chemical mechanical polishing (CMP)
is another example.
[0034] The top image depicts InGaN pyramids of certain indium contents, such as 8-12%, e.g.,
10%. This may correspond to Fig. 1. The middle image shows the result after stepwise
truncation to define groups of three truncated pyramids 40B, 40G, 40R with exposed
top c-planes at three different truncation heights, i.e., with exposed c-planes at
different elevation over the carrier, such as over a top surface of the mask layer
3. Truncation involves material removal, e.g., by back-etching, annealing or polishing.
[0035] In some examples (as will be described with reference to Figs 5 and 6), this involves
truncation of all pyramids to leave respective base layers of a common height, such
as 80-120 nm, or about 100 nm, over the carrier top surface. Additional growth of
a buffer layer may then subsequently be carried out over the respective base layer.
This provides improvement of the upper c-plane surface before QW growth. The indium
concentration of the buffer layer may be tailored dependent on the intended emission
colour.
[0036] The middle image thus shows a group of three truncated pyramids 40B, 40G, 40R with
exposed top c-planes at three different truncation heights, i.e., with exposed c-planes
at different elevation over the carrier, such as over a top surface of the mask layer
3. Herein, all platelets are thus processed to expose c-planes at three different
heights; truncated pyramids 40B with height h
B configured for formation of a QW layer for blue emission, truncated pyramids 40G
with height h
G configured for formation of a QW layer for green emission, and truncated pyramids
40R with height h
R configured for formation of a QW layer for red emission.
[0037] Quantum well layers 111, 112, 113 may thereafter be grown in a single step epi on
the truncated InGaN pyramids 40B, 40G, 40R having different height/top c-plane size,
aiming to have RGB microLEDs fabricated in a common epitaxy process. In other words,
the same recipe may be used for preparing the layers included in the QW, including
an additional InGaN upper layer over the QW, for all colours RGB, which saves processing
time.
[0038] To achieve the structure of the middle image of Fig. 4, based on the structure of
the upper image, a protective layer of resist, or other dielectric material, may first
be deposited on the sample surface (top surface of the epiwafer 10 and pyramids 5).
In some examples, the resist/dielectric protective layer is chosen to have a similar
dry-etching rate as the InGaN material, such as crystalline Al
2O
3. After deposition of the protective layer, the surface may be slightly wave-shaped,
following the shape profile of the pyramids. CMP can be used to planarize the protective
layer.
[0039] According to some examples, where no buffer layer is included, one more layer of
other type resist/hard mask can be deposited on the as-prepared surface for lithography,
patterning the resist/hard mask so that one group of apertures is made on the top
of 1/3 of InGaN pyramids. Then dry etching can be conducted to truncate the InGaN
pyramids exposed under said apertures to form top c-planes for one color microLEDs
(such as blue). Selective masking is as such a known procedure and is therefore not
described or shown in detail.
[0040] In one example, the process may continue by removing the top resist/hard mask, and
then depositing the resist/dielectric layer again to cover the already-truncated pyramids.
By twice repeating procedures above from CMP, two more groups of truncated pyramids
with different heights can be prepared for the other two colour microLEDs (green and
red). After removing all resist material, the structure of the middle image of Fig.
4 is obtained.
[0041] In another example, the first step of etching the top from 1/3 of InGaN pyramids
may be succeeded with a step of removing the resist to form apertures over the second
group of pyramids, wherein etching may proceed on both the first and second groups
of pyramids. Finally, also the remaining pyramids may be uncovered, where after all
three are etched. Selected time for these three process steps may be configured to
obtain selected truncation height of the respective pyramid to three different heights,
according to the middle image of Fig. 4.
[0042] In an example where all pyramids are first etched back to form respective base layers,
the selective masking process may instead be used for growing the buffer layers.
[0043] To end template preparation, the resist/hard mask and the protective layer are removed,
and the sample is cleaned for subsequent epitaxy.
[0044] The as-fabricated sample, corresponding to the middle image of Fig. 4, may be loaded
back to a MOCVD chamber for epitaxy of QW layers 111, 112, 113, which each may comprise
an n-type InGaN buffer, InGaN QW, a GaN or AlGaN electron blocking layer and a p-InGaN
layer. The smaller the top c-plane is upon QW layer growth, the higher indium content
can be obtained in the InGaN QW. By tuning the top c-plane sizes of these three groups
of truncated pyramids 40B, 40G, 40R (i.e., by configuring the height of the truncated
pyramids) and growth conditions, InGaN QWs emitting blue, green and red light can
be obtained in one epitaxy growth process. It shall be noted in this context that
each pyramid may be subjected to epitaxy to grow more than one QW per pyramid.
[0045] The bottom image of Fig. 4 illustrates the result after single shot epitaxy run on
all of the truncated InGaN pyramids 40B, 40G, 40R, resulting in InGaN platelets 100B,
100G, 100R with respective QWs 111, 112, 113 located at three different heights and
configured for emission of three distinct colours, i.e., blue, green, and red. It
shall be noted that single shot epitaxy refers to the same series of epitaxial growth
steps being carried out on all truncated pyramids 40B, 40G, 40R.
[0046] As shown in the bottom image, the process of QW layer growth also comprises additional
growth of an upper InGaN layer, such as doped p-InGaN. In some examples, growth of
the upper InGaN layer is continued to a full pyramid shape of each respective platelet.
Thereafter, all platelets are subjected to truncation, e.g., by annealing, etching
or polishing, to obtain the same height of all InGaN platelets. This provides a simplified
final process, and also results in uniform InGaN height, which simplifies contacting
to a driver circuit.
[0047] Fig 5 shows another example of a process flow for making red, green, and blue InGaN
platelet LEDs on the same epiwafer 10. This process flow includes selective masking
of the InGaN platelets for epitaxial growth of QW layers for emission in a wavelength
region of one of red, green, and blue.
[0048] This process is based on creating QWs of different colours on equally truncated c-plane
height (i.e, the base layer), covering selected platelets, and performing epitaxial
growth on remaining exposed platelets in three consecutive steps forming R, G, and
B LEDs.
- A) depicts pyramids of certain Indium contents, such as 8-12%, of n-InGaN. This may
correspond to Fig. 1.
- B) indicates planarization/truncation of InGaN pyramids to same height (leaving the
base layer). In this drawing, each truncated pyramid 51 is surrounded by an additional
spacer layer 52 of the same height. The spacer layer 52 is a dielectric material or
at least an inorganic material (not resist polymer) as it needs to withstand high
temperatures without degrading and contaminating the InGaN. In various embodiments,
the spacer layer 52 comprises SiNx, Al2O3, TiN or other suitable materials.
- C) indicates addition of growth mask 53 material onto selected 2/3 of all truncated
pyramids followed by epitaxial growth of LED structure comprising a QW layer 111 intended
for one colour, e.g., blue light emission, optionally preceded by growth of a buffer
layer tailored for blue emission, such as with an indium concentration of 5-10%, which
further provides the benefit of reducing any possible band-tail absorption of QW light.
The growth mask material may e.g., comprise atomic layer deposited (ALD) Al2O3 or SiNx.
[0049] In other words, after the InGaN pyramids are truncated with either dry-etching or
CMP to form the structure of B), the sample surface is covered by a layer of the growth
mask material. One group of truncated pyramids is uncovered by lithography and dry
etching for subsequent epitaxy of a QW layer (optionally preceded by buffer layer
growth) and an upper p-InGaN layer, to form microLEDs 100B configured to emit one
colour, such as blue.
D) indicates covering previously grown LED structure 100B in the growth mask material
(i.e., by covering the entire sample again with a mask layer, such as ALD Al2O3 or SiNx), and uncovering half of the remaining truncated pyramids with lithography and dry
etching followed by epitaxial growth of LED structures comprising a QW layer to form
microLEDs 100G configured to emit a second colour, e.g., green light emission.
E) shows covering previously grown LED structures in growth mask, and uncovering remaining
truncated pyramids followed by epitaxial growth of LED structures 100R having QW intended
for the final colour, e.g., red light emission.
[0050] In this example, separate recipes for epitaxy to create, inter alia, QWs and buffer
layers, may be individually employed for each colour of pixel. This provides greater
freedom of operation for configuration of InGaN platelets for microLEDs of different
colour. This example thus truncates all InGaN pyramids in the same way, then three
epi-growths, aiming to get blue, green and red microLEDs, are conducted on selected
groups of truncated pyramids while others are covered with mask materials.
[0051] Fig. 6 illustrates InGaN platelet composition for RGB growth according to an example
of the proposed solution. The InGaN platelets have a base layer 61, adjacent to the
surface 11 of the epiwafer, such as the top surface of the mask layer 3. As noted,
the base layer 61 may be the remainder of the original pyramid 5, after truncation.
The base layer size, which substantially equals the size of the original pyramid base,
may be in the range of 700-900 nm, such as about 800 nm point to point of its hexagonal
shape. The base layer is made of InGaN (n-InGaN) with a first Indium concentration,
such as about 10% or 8-12%, and may be about 100 nm high, or 80-120 nm. A buffer layer
62 is formed between the base layer 61 and the QW layer 110, wherein said buffer layer
62 is made of InGaN with a second Indium concentration which may be different from
the first Indium concentration.
[0052] For InGaN platelets 100R configured for emission of red light, said buffer layer
62R may be made of InGaN with a second Indium concentration which is higher than the
first Indium concentration, such as 18-20%. The buffer layer may be grown to obtain
a c-plane surface at a height of about 520-550 nm from the surface of the epiwafer.
[0053] According to various embodiments, in order to minimize lattice stress and defect
creations, the n-type bottom platelet segment, i.e., the base 61 of the pyramid closest
to the mask layer, is designed to have an In-composition corresponding to bandgap
luminescence of 420-430nm. For red emitting LEDs 100R the buffer layer 62R of 475nm
luminescence is grown before the QW layer 110, whereas the 425nm luminescence layer
may be used for green and blue. This way, defect creation may be supressed.
[0054] In some examples, either no buffer layer is grown, or a buffer layer with the same
indium concentration as the base layer 61 is grown, in the formation of green 100G
and blue 100B MicroLEDs.
[0055] In other examples, though, buffer layers 62G, 62B of InGaN (n-InGaN) are grown also
on the base layer 61 for formation of InGaN platelets for green 100G and blue 100B
emission.
[0056] For the green InGaN platelet 100G, the buffer layer 62G is formed between the base
layer 61 and the QW layer 110, wherein said buffer layer 62G is made of InGaN with
a second Indium concentration which is the same or higher than the first Indium concentration,
such as 10-15%. The buffer layer may be grown to obtain a c-plane surface at a height
of about 360-400 nm from the surface of the epiwafer.
[0057] For the blue InGaN platelet 100B, the buffer layer 62B is formed between the base
layer 61 and the QW layer 110, wherein said buffer layer 62B is made of InGaN with
a second Indium concentration which is the same or lower than the first Indium concentration,
such as 5-10%. The buffer layer may be grown to obtain a c-plane surface at a height
of about 240-280 nm from the surface of the epiwafer.
[0058] For each InGaN platelet 100R, 100G, 100B, further growth of an upper InGaN layer
(p-InGaN) 63R, 63G, 63B is carried out over the QW layer 110. Where the initial base
layer 61 size is in the range of 700-900 nm, such as about 800 nm point to point,
as mentioned, the overall total height of each InGaN platelet may be in the range
of 720-770 nm. The base of the respective InGaN platelet may, after the growth steps,
have increased to 900-960 nm, according to measurements.
[0059] Fig. 7 shows an example of the proposed solution, comprising a center-center spacing
design for the holes 4 in the growth mask 3 of the epiwafer 10 for local tuning of
growth rate. The drawing schematically illustrates a top view of the mask layer 3.
The holes 4 in the mask layer 3 configured for growing the InGaN platelets are arranged
in groups for red, green, and blue light emission, respectively. This embodiment is
based on the understanding that the emission wavelength of the InGaN platelets increases
with the spacing within the group.
[0060] According to this embodiment of the proposed solution, local hole spacing variation
is thus employed for manufacturing R, G, and B LEDs. By this configuration, a single
step epitaxy process may optionally be employed for QW layer formation and top layer
growth.
[0061] In this context, the proposed lattice design is based on the notion that for selective
area growth of InGaN, the indium incorporation depends on the spacing between the
holes 3. In the drawing, this spacing is referred to as Pixel Pitch PP. Up to 2 µm
or larger spacing, the growth is controlled by adatom diffusion on the mask surface.
All the adatoms landing on the mask surface will diffuse to the nearest InGaN pyramid
and contribute to the growth there. This way, the growth with larger spacing means
a local higher growth rate, leading to an increased indium content (that is, pre-configuration
for longer wavelength). By carefully designing the spacings between holes 4, and thus
the pyramids grown from the growth layer 2 through the holes 4, and tuning the growth
conditions, InGaN pyramids 5 can be grown (and subsequently further truncated and
processed to introduced QW layers) in one epitaxy run, where the indium composition
(concentration) is tailored for the targeted emission wavelength, i.e., blue, green
and red light based on the spacing between the mask openings. In this context, larger
spacing provides InGaN growth suited for longer wavelength InGaN platelets (i.e.,
towards the red). It may be noted that a tailored lattice pattern for this purpose
may be accomplished by design of the pattern of the mask holes 4 in the mask 3 over
the growth layer 2. Grouped trigonal holes with larger c-c distance (Pixel Pitch between
InGaN platelets of same colour) promotes higher indium incorporation and longer wavelength
emission. Thus, a design with three different c-c- spacings will enable red, green,
and blue platelet LEDs on same wafer.
[0062] Figs 8A and 8B schematically illustrate contacting of the semiconductor structure
80 according to the proposed solution, whereas Fig. 8C shows a microLED device 800
where the semiconductor structure 80 is connected to a driver circuit. Where reference
signs are not included in Fig. 8, it shall be noted that they refer to details highlighted
in the other drawings.
[0063] Fig. 8A shows a top view of one example of a triangular arrangement of RGB MircoLEDs,
where an n-contact is centrally configured in the triangular pixel arrangement. Separate
n-contacts to the respective MicroLED is another option.
[0064] Fig. 8B schematically illustrates the semiconductor structure 80 according to an
example of the proposed solution. As described and exemplified herein, the semiconductor
structure 80 comprises an epiwafer 10, where a plurality of InGaN platelets 100 is
grown through mask openings 4 of the epiwafer 10, each InGaN platelet comprising a
QW layer 110 including one or more QWs. The InGaN platelets 100 have a truncated pyramid
shape. Each InGaN platelet is configured for emission of one colour of RGB, and are
denoted 100B, 100G, 100R. In this drawing, the buffer layer 2 still remains, but this
layer may be stripped or thinned before or after contacting.
[0065] A contact spacer layer 81 may be applied over InGaN platelets 100B, 100G, 100R, wherein
p-contacts 82B, 82G, 82R to the respective InGaN platelet project through the contact
spacer layer 81 and bond to the respective top c-plane surface of the InGaN platelets
100B, 100G, 100R. The contact spacer layer 81 is a dielectric layer, which allows
for the application of leads (not shown) to the p-contacts over the surface of the
microLED device. An n-contact 83 for the group of pixels (or separate contacts) is
formed to extend from a surface of the base side of the pyramids to the top c-plane
side, for convenient connection of the driver circuit. The n-contact 83 may be a metal
connection, according to the shown example.
[0066] Fig. 8C schematically illustrates a microLED device 800, comprising the semiconductor
structure 80 according to the proposed solution. The drawing indicates attachment
and connection of the semiconductor structure 80 to a driver circuit 84. Each InGaN
platelet 100R, 100G, 100B has a top c-plane surface connectable to the driver circuit
84, by means of the respective connector 82R, 82G, 82B for generating light emission.
[0067] The driver circuits 84 are here exemplified by Si CMOS driver circuits. In some examples,
thin film active transistor drivers may instead or additionally be used. While the
top image of Fig. 8A suggests triangular grouping of RGB pixels with a central n-contact,
the lower images show a linear representation for the sake of simplicity. Either is
possible.
[0068] Where the micro-LED device 800 is configured to emit light through the base side
of the InGaN platelets, the p-contacts 82B, 82G, 82R, connected to the upper c-planes
of the respective InGaN platelets, may be reflective to increase light output.
[0069] The base substrate 1 (see Fig. 1) is removed. The original GaN growth layer 2 may,
as mentioned, further be thinned or stripped. The epiwafer 10 of the microLED device
800 thus comprises the mask layer 3, and optionally a part of the growth layer 2.
[0070] Fig. 9 shows an example of InGaN RGB platelet array design according to some examples
of the proposed solution. Epitaxial growth and subsequent QW formation of InGaN platelets
out of trigonally arranged holes in the growth mask, wherein each InGaN platelet has
six neighbour InGaN platelets at a common distance, leads to very uniform growth conditions
resulting in well-controlled compositions.
[0071] A hexagonal array is configured for each colour, as indicated in the drawing. The
hexagonal pattern provides that the same distance/spacing is configured between all
InGaN platelets prepared for the same emission wavelength. This is beneficial for
growth uniformity. Specifically, by keeping trigonal symmetry (and centre-to-centre
spacing) for red, green, and blue platelet LEDs, colour purity and uniformity across
the wafer for each LED colour is very high.
[0072] Fig. 10A shows one example of a pixel group configuration, where a triplet of RGB
InGaN platelets is combined in one pixel group, capable of realizing any colour in
the visible spectrum. In this example, a triangular pixel group is configured.
[0073] Fig. 10B shows, by way of example, an alternative arrangement of a triplet of RGB
InGaN platelets in one pixel group, capable of realizing any colour in the visible
spectrum. In this example, a linear combination is configured.
[0074] Fig. 11 shows an example of several pixel RGB groups, each comprising a triplet in
accordance with the example of Fig. 10A. The pixel array layout demonstrates the arrangement
of InGaN platelets 100 for red, green, and blue light emission in a display application.
[0075] The above-described embodiments provide examples of the proposed solution for a semiconductor
structure for microLEDs and a method of fabricating the same. The disclosed technology
minimizes defects in crystal formation and improves external quantum efficiency for
microLEDs with sub-10 µm pixel size. It should be understood that the specific embodiments
described herein are merely illustrative and not intended to limit the scope of the
disclosure. Various modifications and adaptations may be made by those skilled in
the art without departing from the scope of the disclosure as set forth in the appended
claims.
[0076] With reference to the description above of the proposed solution and its examples
and embodiments, various further related features and examples are outlined below.
[0077] The growth of InGaN pyramids through mask openings 4 of the epiwafer 10 enables the
formation of InGaN platelets 100 with a specific shape and configuration. This controlled
growth process contributes to the overall quality and performance of the resulting
microLEDs, as it allows for the formation of InGaN platelets with minimal defects
and optimized external quantum efficiency.
[0078] The growth mask 3, configured for growing InGaN pyramids, is preferably of a dielectric
material such as Al
2O
3, SiN
x, TiN. Holes 4 opened through the dielectric growth mask are preferably placed in
a trigonal lattice arrangement, as shown in Figs 9-11, with hole dimensions in the
20-200 nm range and spaced 0.5 - 10 µm apart.
[0079] The grown InGaN pyramids 5 are preferably grown as n-type InGaN. The n-type InGaN
pyramids may be doped with e.g., Si to a level of 1-5 × 10
18 cm
-3.
[0080] According to some examples, InGaN pyramids 5 of identical composition are concurrently
grown, as n-type InGaN pyramids of certain indium concentration, wherein the pyramids
are later processed to obtain separate RGB InGaN platelets.
[0081] According to other examples, for the blue LEDs, either GaN or InGaN pyramids with
an indium content below 5% (wavelength <380 nm) may be used. For green LEDs, InGaN
pyramids with an indium content around 10% (wavelength 420-430 nm) is preferred, and
for red LEDs, 18%-20% indium contents (wavelength 480-500 nm) are preferred. Different
content/concentration of indium may be obtained by growing the InGaN pyramids in separate
processes.
[0082] In some examples, e.g., as described with reference to Fig. 6, the n-type InGaN may
comprise more than one segment, separated in elevation over the epiwafer/mask layer.
In some examples, a base layer of InGaN, closest to the epiwafer 10, may have the
same indium composition as the original InGaN pyramids. However, for the cases shown
Fig. 6, the fabrication method may start from InGaN pyramids with about 10% indium
content, emitting 420-430nm light. After truncation of the pyramids, the templates
can be used for blue and green microLEDs directly. For the red microLEDs, a buffer
InGaN layer (below active region of QW layers) with indium content of e.g., about
18-20% (480-500 nm light) may be grown, followed by red InGaN QWs, to reduce risk
of introducing stacking mismatch boundaries. The variation in indium concentration
between the base layer and the buffer layer helps in achieving the desired emission
wavelength for red light and improving the crystal quality of the InGaN platelets.
[0083] After the epitaxial growth of InGaN pyramids, the fabrication method may involve
truncating the InGaN pyramids 5 to form truncated InGaN pyramids (and possibly further
InGaN buffer growth). This process helps to create InGaN platelets 100 with a truncated
pyramid shape, which is advantageous for the formation of QW layers at defined c-planes
which are parallel to the epiwafer, and the overall performance of the microLEDs.
[0084] Upon truncating the pyramids 5, before QW layer growth (and buffer layer growth,
where applicable) a protective layer may be applied, as illustrated in Figs 4 and
5, before LED epi. The protective layer should preferably be ALD deposited using a
dielectric material similar to the growth mask (Al
2O
3 etc) since it can be deposited in a conformal manner, covering all facets in the
same thickness. Other deposition methods usually lead to different deposition on different
facets.
[0085] The InGaN platelets 100 comprise a QW layer formed within the platelets, also referred
to as active layer, which as such may comprise one or more QWs. The QW may be about
2-3 nm thick. The compositions (i.e., the Indium concentration) for blue, green and
red are about 10-15%, 25-27% and 35-40%, respectively. For the blue and green LEDs,
an electron blocking layer (EBL) of AlGaN with an Al content of 10-25% and a thickness
of 10-25 nm may be used. For the red LED, GaN or AlGaN with Al contents below 10%
may be used as an EBL.
[0086] According to some examples, the QW layer is configured at a height in the InGaN platelets
100 correlating with emission wavelength, as explained and exemplified with reference
to Fig. 4. This configuration allows for the formation of QW layers on InGaN platelets
100 for different emission wavelengths in a common epitaxy process, or so-called single
shot epitaxy, for at least some layers of the QW layer, which simplifies the fabrication
process and reduces manufacturing costs.
[0087] In some examples, the fabrication method may also comprise selective masking of the
InGaN platelets 100 for epitaxial growth of QW layers for emission in a wavelength
region of one of red, green, and blue. This selective masking process enables separate
and dedicated creation of semiconductor structures with InGaN platelets configured
for different emission wavelengths, allowing for the formation of microLEDs capable
of emitting red, green, and blue light.
[0088] In some examples, the selective masking process may be performed using various techniques,
such as photolithography, electron beam lithography, or nanoimprint lithography, to
create the desired mask pattern on the epiwafer 10. The mask material may be selected
based on its compatibility with the chosen masking technique and its ability to withstand
the epitaxial growth process without degrading or causing unwanted contamination of
the InGaN material. The use of selective masking for wavelength region emission in
the fabrication method for the semiconductor structure for microLEDs offers several
advantages. By enabling the formation of InGaN platelets 100 with different emission
wavelengths on the same epiwafer 10, the selective masking process allows for the
creation of microLEDs capable of emitting a full range of colours, which is for display
applications. Additionally, the selective masking process can help to improve the
efficiency with optimized growth conditions for each colour and uniformity of the
epitaxial growth process, resulting in InGaN platelets 100 with fewer defects and
higher external quantum efficiency. Furthermore, the use of a common epitaxy process
in conjunction with the selective masking process can help to simplify the fabrication
method and reduce the overall processing time and cost associated with producing the
semiconductor structure for microLEDs.
[0089] In some examples, the InGaN platelets may comprise additional layers with varying
indium concentrations to further optimize their performance. These additional layers
may be located between the base layer and the buffer layer, or between the buffer
layer and the QW layer. The additional layers may help in reducing strain, improving
crystal quality, and tailoring the emission wavelength of the InGaN platelets.
[0090] A p-type InGaN top layer is further grown over the QW layer. For blue LED, the p-layer
may be p-GaN, or p-InGaN with only a few percent (<10% or <5%) In, with a thickness
of 100-200 nm. For the green and red LEDs p-InGaN with an indium content of 10% and
18%, respectively, may be used. The p-type doping is accomplished using e.g., Mg at
a level at least above 1×10
19 cm
-3. Rapid thermal annealing may be used to activate the Mg doping.
[0091] The contact spacer layer 81, seen in Fig. 8B, can be a polymer. Preferably a dielectric
spacer layer, such as PECVD SiOx, should be used together with CMP to expose the top
c-plane of p-InGaN layer. Before the PECVD SiOx growth, a thin layer of ALD Al
2O
3 may be deposited first to protect the surface from being damaged by plasma at the
beginning of SiOx deposition by PECVD and also to serve as surface passivation of
the platelet surfaces.
[0092] Preferably, the n-type contacts to the base end of the InGaN platelets (typically
to the growth layer, e.g., GaN buffer, on the opposite side of the mask layer) and
the contacts to the p-type InGaN, may be processed on the platelet side of the epiwafer
10, as shown in Fig. 8B, which allows for convenient bonding to the driver circuits,
such as CMOS driver chips. In this context, the flat c-plane top surface of the truncated
InGaN platelets provides a suitable surface for bonding of the p-contacts.
[0093] In one example, the InGaN platelets 100 are arranged in groups on the epiwafer 10
for red, green, and blue light emission. This arrangement enables the fabrication
of microLEDs with different emission wavelengths on a single epiwafer 10, which simplifies
the manufacturing process and reduces costs.
[0094] In some examples, the InGaN platelets 100 are arranged in groups configured for different
emission wavelengths. The emission wavelength of the InGaN platelets 100 increases
with the spacing within the group. This arrangement allows for the tuning of the emission
wavelength of the InGaN platelets 100 by adjusting the spacing within the group, providing
flexibility in designing microLEDs with desired emission wavelengths already at InGaN
pyramid growth.
[0095] In various examples, the InGaN platelets 100 are arranged in a trigonal pattern.
In some examples, the InGaN platelets 100 configured for emission of the same colour
are further arranged in a hexagonal pattern. These patterns provide an efficient arrangement
of InGaN platelets 100 on the epiwafer 10 for red, green, and blue light emission,
which contributes to the improvement of external quantum efficiency for microLEDs
with sub-10 µm pixel.
[0096] Overall, the fabrication method for the semiconductor structure for microLEDs described
herein provides a robust and efficient approach to creating high-quality microLEDs
with minimized defects in crystal formation and improved external quantum efficiency.
The various steps and optional features of the method contribute to the formation
of InGaN platelets with precise control over their shape, configuration, and emission
properties, ensuring optimal performance of the resulting microLEDs in a wide range
of applications.
[0097] The use of selective masking for wavelength region emission in the fabrication method
for the semiconductor structure for microLEDs offers several advantages. By enabling
the formation of InGaN platelets 100 with different emission wavelengths on the same
epiwafer 10, the selective masking process allows for the creation of microLEDs capable
of emitting a full range of colours, which is for display applications. Additionally,
the selective masking process can help to improve the efficiency and uniformity of
the epitaxial growth process, resulting in InGaN platelets 100 with fewer defects
and higher external quantum efficiency. Furthermore, the use of a common epitaxy process
in conjunction with the selective masking process can help to simplify the fabrication
method and reduce the overall processing time and cost associated with producing the
semiconductor structure for microLEDs.
[0098] According to various aspects, the proposed solution may be configured in accordance
with any of the items set out below.
[0099] Item 1. A semiconductor structure (80) for micro light-emitting diodes, microLEDs,
comprising:
an epiwafer (10);
a plurality of InGaN platelets (100) monolithically grown on the epiwafer, each comprising
a quantum well, QW, layer;
wherein the plurality of InGaN platelets comprises individual InGaN platelets configured
for red, green, and blue light emission, respectively.
[0100] Item 2. The semiconductor structure according to claim 1, wherein the QW layer is
configured at different height (h) over a surface of the epiwafer in the respective
InGaN platelets (100), wherein said height correlates with emission wavelength.
[0101] Item 3. The semiconductor structure according to claim 1 or 2, wherein the QW layers
are configured at increasing height in the InGaN platelets configured for different
emission wavelength, in the order blue-green-red.
[0102] Item 4. The semiconductor structure according to any of claims 1-3, wherein each
InGaN platelet comprises a base layer with a first indium concentration adjacent to
the epiwafer, and a buffer layer with a second indium concentration between the base
layer and the QW layer, wherein the second indium concentration is different between
InGaN platelets configured for different colour emission.
[0103] Item 5. The semiconductor structure according to claim 4, wherein the base layer
in each InGaN platelet has the same first indium concentration.
[0104] Item 6. The semiconductor structure according to claim 5, wherein the first indium
concentration is 8-12%.
[0105] Item 7. The semiconductor structure according to any of claims 4-6, wherein the second
indium concentration is lower than the first indium concentration in the InGaN platelets
configured for blue emission.
[0106] Item 8. The semiconductor structure according to any of claims 4-7, wherein the second
indium concentration is 5-10% in the InGaN platelets configured for blue emission.
[0107] Item 9. The semiconductor structure according to any of claims 4-8, wherein the second
indium concentration is higher than the first indium concentration in the InGaN platelets
configured for green and red emission, respectively.
[0108] Item 10. The semiconductor structure according to any of claims 4-9, wherein the
second indium concentration is 10-15% in the InGaN platelets configured for green
emission.
[0109] Item 11. The semiconductor structure according to any of claims 4-10, wherein the
second indium concentration is 18-20% in the InGaN platelets configured for red emission.
[0110] Item 12. The semiconductor structure according to any preceding claim, wherein the
InGaN platelets (100) have truncated pyramid shape with a top c-plane surface connectable
to a driver circuit for generating light emission.
[0111] Item 13. The semiconductor structure according to any preceding claim, wherein the
InGaN platelets (100) configured for the same emission wavelength are arranged in
a hexagonal pattern on the epiwafer.
[0112] Item 14. The semiconductor structure according to any preceding claim, wherein the
InGaN platelets are arranged in groups of adjacent InGaN platelets on the epiwafer.
[0113] Item 15. The semiconductor structure according to claim 14, wherein each group comprises
a triplet of adjacent InGaN platelets (100) arranged in a trigonal pattern.
[0114] Item 16. The semiconductor structure according to claim 14 or 15, wherein each group
comprises InGaN platelets (100) configured for blue, green and red emission.
[0115] Item 17. The semiconductor structure according to any of claims 1-15, wherein the
InGaN platelets (100) are arranged in groups configured for the same emission wavelengths,
and wherein spacing (PP) between the InGaN platelets within the respective group correlates
with the emission wavelength for which the InGaN platelets are configured, such that
the spacing increases in the order blue-green-red.
[0116] Item 18. A microLED device (800), comprising:
a semiconductor structure (80) according to any preceding claims; and
a driver circuit (84), connected by p-contacts to respective top portions of each
InGaN platelet and by an n-contact to a base side of the epiwafer, for generating
light emission from the respective InGaN platelet.
[0117] Item 19. A method of fabricating a semiconductor structure for microLEDs, comprising:
epitaxial growth of InGaN pyramids (5) through mask openings of an epiwafer (10);
truncating the InGaN pyramids to form truncated InGaN pyramids having c-plane top
surfaces;
growing quantum well, QW, layers over the respective truncated InGaN pyramids; and
growing top InGaN layers over the respective QW layers to form individual InGaN platelets
configured for red, green, and blue light emission, respectively.
[0118] Item 20. The method according to claim 19, wherein the QW layer is grown at different
height (h) over a surface of the epiwafer in the respective InGaN platelets (100),
wherein said height correlates with emission wavelength.
[0119] Item 21. The method according to claim 19 or 20, wherein the QW layer are grown at
increasing height in the InGaN platelets configured for different emission wavelength,
in the order blue-green-red.
[0120] Item 22. The method according to any of claims 19-21, wherein the truncated InGaN
pyramids form respective base layers with a first indium concentration, the method
further comprising:
growing a buffer layer with a second indium concentration on the base layer prior
to growing the QW layer, wherein the second indium concentration is different between
InGaN platelets configured for different colour emission.
[0121] Item 23. The method according to claim 22, wherein the base layer in each InGaN platelet
has the same first indium concentration.
[0122] Item 24. The method according to any of claims 19 to 23, wherein the growing of quantum
well layers on the InGaN platelets for different emission wavelengths is performed
in a common epitaxy process.