TECHNICAL FIELD
[0001] The present disclosure relates to a facility and method for manufacturing molten
iron, and more particularly, to a facility and method for manufacturing reduced iron
and melting the manufactured reduced iron to manufacture molten iron.
BACKGROUND ART
[0002] Generally, melted iron, i.e., molten iron is manufactured through a furnace process.
The furnace process is carried out by processing iron ore and coal into a form that
is suitable for use, inserting the processed iron ore and coal in a furnace, and blowing
hot air into the furnace. Here, the hot air burns the coal, and a carbon monoxide
gas generated at this time causes a reduction reaction that removes oxygen from the
iron ore. In addition, heat over approximately 1,500°C generated inside the furnace
causes a melting reaction that melts the iron ore or iron reduced by the carbon monoxide
gas to manufacture molten iron. In such a furnace process, the reduction reaction
and the melting reaction are carried out simultaneously within the furnace by the
coal and the carbon monoxide gas generated from the coal. However, the furnace process
has a limitation of generating a large amount of carbon dioxide, which causes environmental
problems such as global warming, due to the reduction reaction between the carbon
monoxide gas and the iron ore.
[0003] To solve this limitation, a hydrogen reduction iron-making process technology, which
manufactures molten iron using a hydrogen gas instead of fossil fuels such as coal,
is being researched and developed. The fossil fuels such as coal generate carbon dioxide
when reacting with the iron ore, but since the hydrogen gas reacts with the iron ore
to generate water or steam, the hydrogen reduction iron-making process may innovatively
reduce carbon emission in manufacturing of the molten iron.
[0004] In the hydrogen reduction iron-making process, the reduced iron may be manufactured
by the reduced iron ore, and the molten iron may be manufactured by melting the manufactured
reduced iron. However, the reduced iron manufactured by the reaction between a hydrogen
gas and iron ore has a very high melting point, and thus, there is a limitation that
a lot of energy is required to melt the reduced iron. In addition, in the process
of melting the reduced iron, a large amount of exhaust gas is generated, and it is
necessary to prepare a method to recycle the large amount of exhaust gas generated
in this manner.
(PRIOR ART DOCUMENTS)
DISCLOSURE OF THE INVENTION
TECHNICAL PROBLEM
[0006] The present disclosure provides a facility and method for manufacturing molten iron,
which are capable of minimizing an amount of energy required for melting.
TECHNICAL SOLUTION
[0007] In accordance with an exemplary embodiment, a facility for manufacturing molten iron
includes: a reducing part configured to manufacture reduced iron; a melting part configured
to melt the reduced iron; and a processing part installed to receive the reduced iron
from the reducing part and an exhaust gas discharged from the melting part so that
the supplied reduced iron and exhaust gas react with each other to supply the reacting
reduced iron to the melting part.
[0008] The facility may further include an exhaust gas supply line installed to connect
the melting part to the processing part, wherein the reducing part may include a reducing
furnace having a reducing space in which a reducing gas is supplied to manufacture
the reduced iron, and the melting part may include an electric furnace having a melting
space in which the reduced iron supplied from the processing part is melted using
electric heat.
[0009] The processing part may include: a main body having a processing space; a reduced
iron inlet provided in the main body to allow the reduced iron to flow into the processing
space; and an exhaust gas inlet provided in the main body and connected to an exhaust
gas supply line so that the exhaust gas is introduced into the processing space, wherein
the exhaust gas inlet may be disposed at a position lower than the reduced iron inlet.
[0010] The processing part may further include a heater installed in the main body to heat
the processing space.
[0011] The processing part may include: a collector connected to the main body to collect
the reduced iron discharged from the main body; and a circulation line configured
to connect the collector to the main body so that the reduced iron collected through
the collector is supplied to the main body.
[0012] The processing part may further include a supplemental gas supply part connected
to the main body so that a supplemental gas having at least a portion of the same
component as the exhaust gas is supplied to the processing space.
[0013] The facility may further include: a raw material supply part having a storage space
in which a raw material is stored and installed to supply the raw material stored
in the storage space to the reducing space; and an exhaust gas branch line branched
from the exhaust gas supply line and configured to supply a portion of the exhaust
gas discharged from the electric furnace to the raw material supply part.
[0014] The exhaust gas branch line may be connected to the raw material supply part to directly
supply the exhaust gas to the storage space or transfer heat of the exhaust gas to
air supplied to the storage space.
[0015] The facility may further include: a purge gas supply line connected to the reducing
furnace to supply a purge gas to the reducing space; and a purge gas branch line branched
from the purge gas supply line and configured to supply a portion of the purge gas
supplied to the reducing space to the processing space.
[0016] In accordance with another exemplary embodiment, a method for manufacturing molten
iron includes: manufacturing reduced iron; allowing the manufactured reduced iron
to react with a processing gas; melting the reacting reduced iron to manufacture a
molten product; and utilizing at least a portion of an exhaust gas generated while
manufacturing the molten iron as a processing gas that reacts with the reduced iron.
[0017] The manufacturing of the reduced iron may include: preheating a raw material using
the exhaust gas; and allowing the preheated raw material to react with the reducing
gas to reduce the raw material.
[0018] The preheating of the raw material may include injecting the exhaust gas into the
raw material or receiving heat of the exhaust gas to inject heated air into the raw
material.
[0019] The raw material may include powdered iron ore having a particle size of more than
approximately 0 mm and less than or equal to approximately 8 mm.
[0020] The processing gas may include a gas containing a carbon component, and the reacting
with the processing gas may include carbonizing at least a portion of the reduced
iron.
[0021] the allowing of the reduced iron to react with the processing gas may include reacting
with the processing gas without performing separate thermal process on the manufactured
reduced iron.
[0022] The allowing of the reduced iron to react with the processing gas may include allowing
the manufactured reduced iron to react with the processing gas at a temperature of
approximately 600°C to approximately 800°C.
[0023] The method may further include: collecting the reduced iron discharged from the processing
space in which the reduced iron reacts with the processing gas; and supplying the
collected reduced iron to the processing space.
[0024] The manufacturing of the molten iron may include supplying a purge gas to a reducing
space, in which the reduced iron is manufactured, and the allowing of the reduced
iron to react with the processing gas may include supplying a portion of a purge gas
supplied to the reducing space to the processing space.
[0025] The utilizing of the at least a portion of the exhaust gas as the processing gas
may include utilizing the exhaust gas and a supplemental gas having at least a portion
of the same component as the exhaust gas as the processing gas.
[0026] The exhaust gas may include a carbon monoxide gas, and the supplemental gas may include
at least one of a natural gas or a biomass gas.
ADVANTAGEOUS EFFECTS
[0027] In accordance with the exemplary embodiment, the melting point of the reduced iron
may be lowered by allowing the exhaust gas generated during the process to react with
the reduced iron to minimize the amount of energy used to melt the reduced iron.
[0028] In addition, the reduced iron manufactured at the high temperature may directly react
with the high-temperature exhaust gas to minimize the facility and resources required
for the reaction.
[0029] In addition, the energy may be efficiently collected by using the sensible heat of
the high-temperature exhaust gas to preheat the raw materials and produce the hydrogen
gas.
BRIEF DESCRIPTION OF THE DRAWINGS
[0030]
FIG. 1 is a schematic view of a facility for manufacturing molten iron in accordance
with an exemplary embodiment.
FIG. 2 is a view illustrating an example of a reducing furnace for manufacturing reduced
iron and an electric furnace for melting the reduced iron;
FIG. 3 is a view illustrating an example of a processing part in accordance with an
exemplary embodiment;
FIG. 4 is a view illustrating conditions under which the reduced iron reacts with
an exhaust gas;
FIG. 5 is a view illustrating a state in which a raw material is preheated using the
exhaust gas in a raw material supply part; and
FIG. 6 is a schematic view of a method for manufacturing molten iron in accordance
with an exemplary embodiment.
MODE FOR CARRYING OUT THE INVENTION
[0031] Hereinafter, exemplary embodiments of the present invention will be described in
detail with reference to the accompanying drawings. The present invention may, however,
be embodied in different forms and should not be construed as limited to the embodiments
set forth herein. Rather, these embodiments are provided so that the present invention
will be thorough and complete, and will fully convey the scope of the present invention
to those skilled in the art. In order to explain the present disclosure in detail,
the drawings may be exaggerated, and the same symbols in the drawings refer to the
same elements.
[0032] FIG. 1 is a schematic view of a facility for manufacturing molten iron in accordance
with an exemplary embodiment, FIG. 2 is a view illustrating an example of a reducing
furnace for manufacturing reduced iron and an electric furnace for melting the reduced
iron, and FIG. 3 is a view illustrating an example of a processing part in accordance
with an exemplary embodiment. In addition, FIG. 4 is a view illustrating conditions
under which the reduced iron reacts with an exhaust gas, and FIG. 5 is a view illustrating
a state in which a raw material is preheated using the exhaust gas in a raw material
supply part. In the drawings, an arrow indicated by dotted lines indicates a flow
of raw materials and reduced iron, and an arrow indicated by solid lines indicates
a flows of by-products and gases.
[0033] Referring to FIG. 1 to 5, a facility for manufacturing molten iron in accordance
with an exemplary embodiment may include a reducing part 500 that is capable of manufacturing
reduced iron, a melting part 700 that is capable of melting the reduced iron, and
a processing part 600 that receives the molten iron from the reducing part 500, is
installed to receive an exhaust gas discharged from the melting part 700, and allows
the supplied reduced iron and exhaust gas to react with each other so that the reacting
reduced iron is supplied to the melting part 700. In addition, the facility for manufacturing
the molten iron in accordance with an exemplary embodiment may further include a raw
material supply part installed to supply a raw material to the reducing part 500 and
a reducing gas supply part installed to supply a reducing gas to the reducing part
500.
[0034] The raw material supply part 100 may be installed to supply the raw material to the
reducing part 500. Here, the raw material may include iron ore, and the iron ore may
include reduced fine iron ore, that is, powdered iron ore which has a particle size
greater than approximately 0 mm and less than or equal to approximately 8 mm. The
raw material supply part 100 may include a reservoir 110 having a storage space in
which the raw material is stored. The raw material may be stored in the storage space
of the reservoir 110 for a long time or may be temporarily stored before supplying
the raw material to the reducing part 500. The reservoir 110 may include, for example,
a hopper.
[0035] The raw material may be preheated in the storage space of the reservoir 110, and
the raw material preheated in the storage space may be supplied to the reducing part
500. Here, the reservoir 110 may receive a portion of the exhaust gas discharged from
the melting part 700 to preheat the raw material. For this, the facility for manufacturing
the molten iron in accordance with an exemplary embodiment may further include an
exhaust gas branch line EDL branched from an exhaust gas supply line EL to supply
a portion of the exhaust gas discharged from the melting part 700 to the reservoir
110. The preheating of the raw material using the exhaust gas supplied through the
exhaust gas branch line EDL will be described later with reference to FIG. 5.
[0036] A reducing gas supply part 200 may be installed to store the reducing gas and supply
the reducing gas to the reducing part 500. Here, the reducing gas may include a hydrogen
gas, and the hydrogen gas may be contained at a ratio of approximately 80% to approximately
100% of the total reducing gas. The hydrogen gas stored in the reducing gas supply
part 200 may be produced by electrolyzing water, but is not limited thereto, and may
be produced by various methods such as decomposing an ammonia gas or producing the
hydrogen gas by chemically reacting a natural gas. For example, the ammonia gas may
be decomposed into a hydrogen gas and a nitrogen gas at a high temperature, the decomposed
hydrogen gas may be used as the reducing gas, and the nitrogen gas may be used as
a purge gas, which will be described later.
[0037] The reducing gas supply part 200 may supply the reducing gas to the reducing part
500 through reducing gas supply lines RL1 and RL2 that connect the reducing gas supply
part 200 to the reducing part 500. Here, an amount of reducing gas supplied by the
reducing gas supply part 200 to the reducing part 500 may be more than twice an amount
required to entirely reduce the raw material supplied to the reducing part 500. To
improve reaction efficiency between the raw material and the reducing gas, the amount
of reducing gas may be controlled, for example, to a range of two to three times the
amount required to entirely reduce the raw material supplied to the reducing part
500.
[0038] A heating part 300 may be installed in each of the reducing gas supply lines RL1
and RL2 to heat the reducing gas supplied from the reducing gas supply part 200 to
the reducing part 500. In the reducing part 500, the raw material containing the iron
ore and the reducing gas containing the hydrogen gas may react to reduce the iron
ore. Since the reaction between the iron ore and the hydrogen gas is a strong endothermic
reaction, the reaction efficiency may be improved when the hydrogen gas supplied to
the reducing part 500 is heated and supplied to a temperature of approximately 800°C
or more, more preferably approximately 850°C or more. As a result, the heating part
300 may be connected to the reducing gas supply part 200 through the first reducing
gas supply line RL1 and also be connected to the reducing part 500 through the second
reducing gas supply line RL2 to heat the low-temperature hydrogen gas supplied through
the first reducing gas supply line RL1 to a temperature of approximately 800°C to
approximately 1,200°C, thereby supplying the hydrogen gas to the reducing part 500
through the second reducing gas supply line RL2. Since the heating part 300 may have
various structures for heating the reducing gas in a direct or indirect heating manner,
a detailed description thereof will be omitted.
[0039] The facility for manufacturing the molten iron in accordance with an exemplary embodiment
may further include a purge gas supply part 400 installed to store a purge gas and
supply the purge gas to the reducing part 500. The reducing part 500 may have a reducing
space capable of producing the reduced iron, and the reducing space may need to be
purged for maintenance between processes. In addition, there are cases in which the
purge gas needs to be supplied during the process. For example, when using the powdered
iron ore as the raw material, the purge gas may be supplied to increase in fluidity
of the powdered iron ore, thereby preventing the iron ore from sticking in the reducing
space. Thus, the purge gas supply part 400 may supply the purge gas to the reducing
space through a purge gas supply line PL that connects the purge gas supply part 400
to the reducing part 500, and an inert gas such as nitrogen may be used as the purge
gas.
[0040] The reducing part 500 may produce the reduced iron by reducing the raw material.
That is, the reducing part 500 may receive the iron ore as the raw material from the
raw material supply part 100, receive the reducing gas from the reducing gas supply
part 200, and react the iron ore with the reducing gas to manufacture the reduced
iron. The reducing part 500 may include a reducing furnace having a reducing space
capable of manufacturing the reduced iron using the reducing gas. The reducing furnace
may include fluid reducing furnaces 510, 520, 530, and 540 that manufacture the reduced
iron while allowing the raw material to flow, and the fluid reducing furnaces 510,
520, 530, and 540 may be provided as a single unit. However, to effectively reduce
low-grade iron ore or powdered iron ore having a low iron content, as illustrated
in FIG. 2, the plurality of fluid reducing furnaces 510, 520, 530, and 540 may be
connected to sequentially move the raw material, thereby manufacturing the reduced
iron. Here, there is no limit to the number of fluid reducing furnaces 510, 520, 530,
and 540, but in order to sufficiently reduce the raw material, and as illustrated
in FIG. 2, the reducing part 500 may include four reducing furnaces including a first
fluid reducing furnace 510, a second fluid reducing furnace 520, a third fluid reducing
furnace 530, and a fourth fluid reducing furnace 540. Here, the raw material supply
part 100 may supply the raw material to the first fluid reducing furnace 510, and
the reducing gas supply part 200 may supply the reducing gas to the fourth fluid reducing
furnace 540. The raw material supplied to the first fluid reducing furnace 510 may
be reduced by sequentially moving through the second fluid reducing furnace 520, the
third fluid reducing furnace 530, and the fourth fluid reducing furnace 540 and thus
be manufactured into the reduced iron.
[0041] The reduced iron manufactured in the reducing part 500 may be supplied to a processing
part 800 that will be described later. As illustrated in FIG. 2, the reduced iron
manufactured through the first fluid reducing furnace 510, the second fluid reducing
furnace 520, the third fluid reducing furnace 530, and the fourth fluid reducing furnace
540 may be discharged from the fluid reducing furnace 540 and supplied to the processing
part 800. Here, as described above, the preheated raw material and the reducing gas
having a temperature of approximately 800°C or more may be supplied to the reducing
space to manufacture the reduced iron. Thus, the reduced iron manufactured in the
reducing part 500 may be discharged at a high temperature of, for example, approximately
600°C to approximately 800°C, even in consideration of a heat loss. As described above,
the reduced iron discharged at the high temperature may be directly supplied to the
processing part 800 without passing through a separate thermal processing device.
In the processing part 800, the reduced iron manufactured at a high temperature may
directly react with the high-temperature exhaust gas to minimize the facility and
resources required for the reaction, which will be described later in relation to
the processing part 800.
[0042] In the reducing part 500, a large amount of by-products may be discharged in addition
to the reduced iron. The by-products discharged from the reducing part 500 may include
steam. As described above, in the reducing part 500, the iron ore and the hydrogen
gas may react to manufacture the reduced iron. Here, an oxygen component of the iron
ore and a hydrogen component of the hydrogen gas may react to generate a large amount
of steam in the reducing space, and the generated steam may be discharged from the
reducing part 500 as a by-product. In addition, the by-products discharged from the
reducing part 500 may include the hydrogen gas and the nitrogen gas. As described
above, the reducing gas may be supplied in a range of two to three times the amount
required to entirely reduce the raw material supplied to the reducing part 500, and
thus, the remaining hydrogen gas that does not react with the raw material may be
discharged from the reducing part 500 as the by-product. In addition, as described
above, the purge gas, for example, the nitrogen gas may be supplied to the reducing
part 500 for various reasons. As described above, the nitrogen gas supplied for purge
may be discharged from the reducing part 500 as the by-product. The by-products may
move along a flow of the reducing gas within the reducing part 500 and then be discharged
from the first fluid reducing furnace 510. Then, the discharged by-products may be
supplied to the extracting part 600 through the by-product supply line BL connected
to the reducing part 500.
[0043] That is, the facility for manufacturing the molten iron in accordance with an exemplary
embodiment may further include an extracting part 600 that is installed to receive
the by-products discharged from the reducing part 500 and extracts a hydrogen gas
from the by-products.
[0044] The extracting part 600 may extract the hydrogen gas from the by-products discharged
from the reducing part 500. As described above, the by-products discharged from the
reducing part 500 may include steam, a hydrogen gas, and a nitrogen gas. The extracting
part 600 may be connected to the reducing part 500 through a by-product supply line
BL to extract the hydrogen gas from the by-products supplied through the by-product
supply line BL. This extracting part 600 may extract the hydrogen gas from the by-products
using a pressure swing absorption (PSA) method. That is, in the pressure swing adsorption
method, a gas may be extracted using adsorption selectivity of each component with
respect to an adsorbent, and the extracting part 600 may use a carbon molecular sieve
as the adsorbent that is capable of adsorbing hydrogen components to extract the hydrogen
gas from the by-products including various gases other than the hydrogen gas. Here,
the hydrogen component adsorbed on the adsorbent may be desorbed and extracted as
the hydrogen gas, and the extracting part 600 may extract the hydrogen gas from the
by-products by repeatedly performing adsorption and desorption of the hydrogen component.
[0045] A residue discharged from the extracting part 600 without being adsorbed may include
the steam and the nitrogen gas. Here, the residue containing the steam and the nitrogen
gas may be supplied to the reducing part 500 as a purge gas. The steam may have low
reactivity with the iron ore and the reducing gas as a reaction product produced by
the reaction between the iron ore that is the raw material and the hydrogen gas in
the reducing gas and thus may be supplied to the reducing part 500 as the purge gas.
In addition, when the steam is supplied to the reducing part 500 as the purge gas,
the heat of the steam may be utilized for the reduction reaction to save energy required
for the reduction reaction. To supply the residue as the purge gas to the reducing
part 500, a residue discharge line (not shown) may be connected to the extracting
part 600, and the residue discharge line may be connected to a purge gas supply line
PL or be directly connected to the reducing part 500 to supply the residue to the
reducing part 500 through a path different from that of the purge gas.
[0046] The hydrogen gas extracted from the extracting part 600 may be used for various purposes.
For example, the reducing part 500 may reduce the raw material, that is, the iron
ore using the extracted hydrogen gas. The hydrogen gas may be used in a large amount
more than twice the amount required to entirely reduce the raw material supplied to
the reducing part 500, but is a very expensive gas, and thus, to reduce costs through
resource recycling, the hydrogen gas extracted from the extracting part 600 may be
reused as the reducing gas to reduce the iron ore. For this, the hydrogen gas supply
line HL may be connected to the extracting part 600, and the hydrogen gas supply line
HL may be connected to the first reducing gas supply line RL1, and thus, the extracting
part 600 may supply the hydrogen gas to the first reducing gas supply line RL1, and
the extracted hydrogen gas may be supplied to the reducing part 500 along the hydrogen
gas supply line HL, the first reducing gas supply line RL1, and the second reducing
gas and then be used when reducing the iron ore.
[0047] The melting part 700 may receive the reduced iron that reacts in a processing part
800 to be described later to melt the reduced iron in various manners. For example,
the melting part 700 may receive the fine or compacted reacting reduced iron from
the processing part 800 to heat and melt the reduced iron. In addition, the melting
part 700 may receive additional iron scrap in addition to the reacting reduced iron
and melt the reacting reduced iron and the iron scrap together. The melting part 700
may include electric furnaces 710 and 720 having a melting space capable of melting
the reacting reduced iron using electric heat. The above-described electric furnaces
710 and 720 may include an electric furnace main body 710 having a melting space and
an electrode rod 720 of which at least a portion is partially disposed in the melting
space to generate the electric heat. When the reacting reduced iron is charged into
the melting space, the electric furnaces 710 and 720 may apply power to the electrode
rod 720 to melt the reacting reduced iron.
[0048] In the melting part 700, a recarburizing agent containing a carbon component may
be introduced to adjust a carbon content of the molten product manufactured by melting
the reacting reduced iron. In addition, the recarburizing agent may be added to generate
a large amount of slag when melting the molten product. In this case, the electrode
rod 720 may generate resistance heat by receiving power while immersed in the slag,
and the reduced iron may be more easily melted by the generated resistance heat. At
least partially unreduced raw material, that is, partially reduced iron or iron ore
may be supplied to the melting part 700. As described above, at least a portion of
the unreduced raw material may have an oxygen component, and the oxygen component
may react with the carbon component of the recarburizing agent or carbon component
of the reacting reduced iron, which will be described later, within the melting space.
Thus, in the melting part 700, the exhaust gas containing the carbon monoxide gas,
that is, the exhaust gas having a high carbon monoxide concentration (CO-rich) may
be discharged while melting the reduced iron by receiving the reacting reduced iron
from the processing part 800. As described above, the exhaust gas discharged from
the melting part 700 may be discharged at a high temperature of approximately 1,200°C
or more.
[0049] When the reduced iron manufactured in the reducing part 500 is charged to the melting
part 700 without separate processing, a lot of energy may be required to melt the
reduced iron in the melting part 700. That is, the reduced iron manufactured in the
reducing part 500 without any additional processing may have a component of metallic
iron (Fe), that is, pure iron, and the pure iron may have a melting point of approximately
1,538°C. In addition, the reduced iron may contain a large amount of gangue in addition
to the pure iron component, and the reduced iron may be melted only when heated to
a temperature above the melting point of the pure iron. In addition, when the reduced
iron manufactured in the reducing part 500 is charged to the melting part 700 without
separate processing, the use of the large amount of recarburizing agent may be required
to control a carbon content of the molten product.
[0050] On the other hand, when the reduced iron is carbonized, the pure iron component may
be changed into a cementite (Fe3C) phase, which has a melting point of approximately
1,200°C or less. As described above, when melting the reduced iron in which at least
a portion of the components is changed to the cementite (Fe3C) phase, the amount of
energy used to melt the reduced iron may be minimized. In addition, when melting the
reduced iron that is carbonized, that is, iron carbide, the molten product may have
some carbon components. Thus, when melting the iron carbide, the amount of recarburizing
agent used to control the carbon content of the melt may be minimized.
[0051] Thus, in an exemplary embodiment, the processing part 800 in which the reduced iron
supplied from the reducing part 500 reacts with the exhaust gas having a high carbon
monoxide concentration (CO-rich) discharged from the melting part 700, and the reacting
iron carbide is supplied to the melting part 700 may be installed. For this, the facility
for manufacturing the molten iron in accordance with an exemplary embodiment may further
includes an exhaust gas supply line EL installed to connect the melting part 700 to
the processing part 800.
[0052] Here, the processing part 800 may include a main body 810 having a processing space
as illustrated in FIG. 3, a reduced iron inlet 812 provided in the main body 810 to
allow the reduced iron to flow into the processing space, and an exhaust gas inlet
816 provided in the main body 810 and connected to the exhaust gas supply line EL
so that the exhaust gas is introduced into the processing space.
[0053] The main body 810 may have a processing space in which the reduced iron supplied
from the reducing part 500 is accommodated. To introduce the reduced iron into the
processing space, the reduced iron inlet 812 may be provided in the main body 810,
and a reduced iron supply tube FL may be connected to the reduced iron inlet 812 so
that the reduced iron manufactured and transferred from the reducing part 500 is introduced
into the processing space through the reduced iron supply tube FL. In addition, the
exhaust gas discharged from the melting part 700 may be introduced into the processing
space of the main body 810. For this, the exhaust gas inlet 816 may be provided in
the main body 810, and the exhaust gas inlet 816 may be connected to the exhaust gas
supply line EL. In FIG. 3, the processing part 800 may be illustrated as being provided
as a single body 810, but the processing part 800 may carbonize the reduced iron while
sequentially moving the reduced iron by connecting a plurality of bodies 810 to each
other.
[0054] Here, the exhaust gas inlet 816 may be provided at a position lower than the reduced
iron inlet 812. For example, as illustrated in FIG. 3, the exhaust gas inlet 816 may
be provided on a bottom surface of the main body 810, and the reduced iron inlet 812
may be provided on a side surface of the main body 810. As described above, the exhaust
gas inlet 816 may be provided at the position lower than the reduced iron inlet 812,
and thus, the reduced iron supplied from the reduced iron inlet 812 may flow within
the main body 810 to react with the exhaust gas. The processing part 800 may further
include a dispersion plate 817 installed in the main body 810 and provided with a
plurality of nozzles (not shown) to uniformly disperse the exhaust gas supplied from
the exhaust gas inlet 816 into the processing space.
[0055] Here, the reduced iron manufactured in the reducing part 500 may be discharged at
a high temperature of, for example, approximately 600°C to approximately 800°C, and
the discharged reduced iron may be directly supplied to the processing part 800 without
passing through a separate thermal processing device. In addition, since the high-temperature
exhaust gas having a temperature of approximately 1,200°C or more is supplied to the
processing space, the processing space may maintain a temperature of approximately
600°C to approximately 800°C even in consideration of a heat loss of the reduced iron
during the transfer process. Thus, the processing part 800 may not be installed with
a separate heating means for heating the processing space. However, since there is
a need to additionally rise a temperature of the processing space during an initial
operation of the facility, the processing part 800 may further include a heater 820
installed in the main body 810 to heat the processing space. Here, the heater 820
may selectively operate to heat the processing space when it is necessary to heat
the processing space. For example, the heater 820 may be installed on the side surface
of the main body 810 to supply an oxygen gas, and the supplied oxygen gas may react
with the exhaust gas in the processing space to rise the temperature of the processing
space. Here, an amount of oxygen gas supplied from the heater 820 may be controlled
to maintain the processing space within a temperature range of approximately 600°C
to approximately 800°C.
[0056] The processing part 800 may carbonize the reduced iron supplied from the reducing
part 500 by reacting the reduced iron with the exhaust gas. As shown in a Bauer-Glaessner
diagram that shows conditions under which the reduced iron illustrated in FIG. 4 reacts
with the exhaust gas, when the processing space is maintained at a temperature of
approximately 600°C to approximately 800°C, when a partial pressure of carbon monoxide
and a partial pressure of carbon dioxide in the processing space specify specific
conditions, the reduced iron may be carbonized by reacting in accordance with the
following reaction formula.
[Reaction Formula] 3
Fe + CO →
Fe3C +
CO2
[0057] That is, when the reduced iron and the exhaust gas at a high temperature are supplied
to the processing space, and the processing space is maintained at a temperature of
approximately 600°C to approximately 800°C, when the partial pressure Pco of the carbon
monoxide is greater than about 90% of the sum (Pco+Pco
2) of the partial pressure Pco of the carbon monoxide and the partial pressure Pco
2 of the carbon dioxide, the reduced iron may react according to the above-described
reaction formula and be carbonized. Here, as described above, the melting part 700
may include electric furnaces 710 and 720 that are capable of melting the reduced
iron, i.e., an electric smelting furnace (ESF) or a submerged arc furnace (SAF), which
is immersed into slag provided in the electric furnace main body 710 to melt the reduced
iron with slag resistance heat. As described above, the electric furnaces 710 and
720 may have a closed structure, and there may be almost no inflow of oxygen or atmosphere,
and thus, a carbon dioxide content in the exhaust gas may be very low, and an oxygen
component of the unreduced raw material may react with the carbon component of the
recarburizing agent, resulting in a high carbon monoxide concentration. That is, the
partial pressure Pco of the carbon monoxide discharged from the electric furnaces
710 and 720 may be approximately 90% or more of the sum (Pco+Pco
2) of the partial pressure Pco of the carbon monoxide and the partial pressure Pco
2 of the carbon dioxide, and thus, the reduced iron may be effectively carbonized under
a temperature condition of approximately 600°C to approximately 800°C.
[0058] The facility for manufacturing the molten iron in accordance with an exemplary embodiment
may further include a supplemental gas supply part 900 installed to supply a supplemental
gas having at least a portion of the same component as the exhaust gas to the processing
space of the processing part 800. The supplemental gas supply part 900 may supply
the supplemental gas, that is, a carbon-containing gas having at least some of the
same components as the exhaust gas, to the processing part 800, and the supplemental
gas supply part 900 may supply a carbon-containing gas to the processing part 800
through the supplemental gas supply line SL. Here, the supplemental gas supply line
SL may be connected to the exhaust gas supply line EL to supply the supplemental gas
together with the exhaust gas or may supply the supplemental gas to the processing
part 800 through a path different from the exhaust gas supply line EL, and the supplemental
gas may include at least one of a natural gas containing carbon or a biomass gas obtained
by gasifying biomass.
[0059] In addition, the facility for manufacturing the molten iron in accordance with an
exemplary embodiment may further include a purge gas branch line PDL that is branched
from the purge gas supply line PL to supply a portion of the purge gas supplied to
the reduction space to the processing space. The processing space needs to be purged
for maintenance, and the purge gas may be supplied to prevent the reduced fine iron
from sticking to the processing space during the process. Thus, the purge gas branch
line PDL may be branched from the purge gas supply line PL to supply the purge gas
to the processing space.
[0060] As described above, the reduced iron, that is, iron carbide reacting in the processing
part 800 may be supplied to the melting part 700. Here, the reaction between the reduced
iron and the exhaust gas in accordance with the above-mentioned reaction equation
may correspond to an exothermic reaction. Thus, the iron carbide supplied from the
processing part 800 to the melting part 700 may be discharged at a high temperature
in a range similar to the temperature of the processing space, for example, approximately
600°C to approximately 800°C, even in consideration of a heat loss. As described above,
the iron carbide discharged in a high temperature state may be directly supplied to
the melting part 700 in a high temperature state without passing through a separate
cooling device to minimize an amount of energy used for melting the reduced iron.
[0061] On the other hand, most of the reduced iron supplied to the processing space may
react in the processing space and then be supplied to the melting part 700, but the
reduced iron in molten fine iron may not react sufficiently with the exhaust gas to
flow by the exhaust gas and then be discharged to the outside of the processing space
together with the exhaust gas. Thus, the processing part 800 may further include a
collector 840 connected to the main body 810 to collect the reduced iron discharged
from the main body 810 and a circulation line CL through which the reduced iron collected
from the collector 840 is supplied to the main body 810. Here, the collector 840 may
be installed to be connected to an upper portion of the main body 810 and connected
to a discharge tube XL through which the exhaust gas is discharged, and the reduced
fine iron collected from the collector 840 may be re-supplied to the processing space
of the main body 810 through the circulation line CL. Here, the circulation line CL
may be directly connected to the processing space, but may also be connected to the
above-mentioned reduced iron supply tube FL to re-supply the reduced fine iron collected
from the collector 840 to the processing space of the main body 810.
[0062] As described above, the exhaust gas discharged from the melting part 700 may be supplied
to the processing part 800 and used to carbonize the reduced iron. However, as described
above, the exhaust gas discharged from the melting part 700 may be discharged at a
high temperature of approximately 1,200°C or more. Thus, in an exemplary embodiment,
the raw material may be preheated by utilizing thermal energy of the exhaust gas.
[0063] As illustrated in FIG. 5, the raw material supply part 100 may include a reservoir
110, and the reservoir 110 may have a storage space for storing the raw material.
The raw material may be preheated in the storage space of the reservoir 110, and the
raw material preheated in the storage space may be supplied to the reducing part 500.
For this, the raw material supply part 100 may further include a preheating gas supply
part 120 installed to supply a preheating gas to the storage space of the reservoir
110. Here, as illustrated in (a) of FIG. 5, the preheating gas supply part 120 may
be connected to the exhaust gas branch line EDL to directly supply the high-temperature
exhaust gas E having a temperature of approximately 1,200°C or more to the storage
space, thereby performing the preheating. In addition, as illustrated in (b) of FIG.
5, the preheating gas supply part 120 may heat external air A supplied to the storage
space with the heat of the exhaust gas having a temperature of approximately 1,200°C
or more to supply the heated air to the storage space, thereby preheating the raw
material. For this, the preheating gas supply part 120 may be disposed on the exhaust
gas branch line EDL to intersect the exhaust gas branch line EDL, and thus, the sensible
heat of the exhaust gas passing through the exhaust gas branch line EDL may be transferred
to the external air A.
[0064] The facility for manufacturing the molten iron in accordance with an exemplary embodiment
may manufacture the molten iron reacting by moving the reduced iron and the exhaust
gas along each of the above-described tubes. The movement of the reduced iron and
the exhaust gas may be controlled through valves (not shown) installed in the tubes,
and the valves may be installed at various positions to control a flow amount and
flow rate of the reduced iron and the exhaust gas, which move along the respective
tubes.
[0065] Hereinafter, a method for manufacturing molten iron in accordance with an exemplary
embodiment will be described. The method for manufacturing the molten iron in accordance
with an exemplary embodiment may be a method for manufacturing molten iron using the
above-described facility for manufacturing the molten iron, and thus, since the above-described
contents in relation to the facility for manufacturing the molten iron are applied
as there are, description of duplicated contents will be omitted.
[0066] FIG. 6 is a schematic view of a method for manufacturing molten iron in accordance
with an exemplary embodiment.
[0067] Referring to FIG. 6, a method for manufacturing molten iron in accordance with an
exemplary embodiment may include a process (S100) of manufacturing reduced iron, a
process (S200) of allowing the manufactured reduced iron to react with a processing
gas, a process (S300) of melting the reacting reduced iron to manufacture a molten
product, and a process (S400) of using at least a portion of the exhaust gas generated
in the process of manufacturing the molten product as a processing gas that reacts
with the reduced iron. Here, since each process are continuously performed to manufacture
the molten iron, it may not correspond to a time-series relationship in which another
process is performed after one process is completed.
[0068] The process (S100) of manufacturing the reduced iron may be performed by supplying
a raw material and the reducing gas to a reducing part 500. That is, the process (S100)
of manufacturing the reduced iron may include a process of supplying the raw material
to the reducing part 500, a process of supplying a reducing gas to the reducing part
500, and a process of reducing the raw material by allowing the raw material to react
with the reducing gas.
[0069] The process of supplying the raw material may be performed by a raw material supply
part 100, which is installed to supply the raw material to the reducing part 500 so
as to supply the raw materials to the reducing part 500. Here, the raw material may
include iron ore, and the iron ore may include reduced fine iron ore, that is, powdered
iron ore which has a particle size greater than approximately 0 mm and less than or
equal to approximately 8 mm. The process of supplying the raw material may include
a process of preheating the raw material. In an exemplary embodiment, energy required
for the reduction may be minimized by supplying and reducing the preheated raw materials,
that is, the iron ore.
[0070] The process of supplying the reducing gas may be performed by a reducing gas supply
part 200 supplying the reducing gas to the reducing part 500. Here, the reducing gas
may include a hydrogen gas, and the hydrogen gas may be contained at a ratio of approximately
80% to approximately 100% of the total reducing gas. The process of supplying the
reducing gas may be performed by allowing the reducing gas supply part 200 to supply
the reducing gas to the reducing part 500 through reducing gas supply lines RL1 and
RL2 that connect the reducing gas supply part 200 to the reducing part 500. Here,
in the process of supplying the reducing gas, an amount of reducing gas supplied to
the reducing part 500 may be controlled to be in a range of more than 2 times and
less than 3 times an amount required to entirely reduce the raw material supplied
to the reducing part 500.
[0071] In the process of supplying the reducing gas, the reducing gas may be heated to a
temperature of approximately 800°C to approximately 1,200°C and then supplied to the
reducing part 500. When the hydrogen gas is used as the reducing gas, the reduced
iron may be manufactured by allowing the iron ore and the hydrogen gas supplied to
the reducing part 500 to react with each other. Since the reaction between the iron
ore and the hydrogen gas is a strong endothermic reaction, the iron ore supplied to
the reducing part 500 may be heated at a temperature of approximately 800°C or more,
more preferably approximately 850°C or more, and when the heated reducing gas is supplied,
reduction efficiency may be improved.
[0072] In addition, the process (S100) of manufacturing the reduced iron may further include
a process of supplying a purge gas to the reducing part 500. Here, the process of
supplying the purge gas may be performed by a purge gas supply part 400, which is
installed to supply the purge gas to the reducing part 500, so as to supply the purge
gas to a reducing space through the purge gas supply line PL. Here, an inert gas such
as nitrogen may be used as the purge gas.
[0073] In the process of reducing the raw material by allowing the raw material to react
with the reducing gas, the reducing part 500 may receive the raw material from the
raw material supply part 100, receive the reducing gas from the reducing gas supply
part 200, and react the iron ore with the reducing gas to reduce the iron ore. The
reducing part 500 may include a reducing furnace having a reducing space capable of
manufacturing the reduced iron using the reducing gas. The reducing furnace may be
provided as a single unit, but to effectively reduce low-grade iron ore or powdered
iron ore having a low iron content, the plurality of reducing furnaces may be connected
to sequentially move the raw material, thereby manufacturing the reduced iron, as
described above.
[0074] In the process of reducing the raw material by allowing the raw material to react
with the reducing gas, a large amount of by-products may be generated in addition
to the reduced iron. The by-products generated and discharged from the reducing part
500 may include steam generated by the reaction of the iron ore and the hydrogen gas
and also may include the hydrogen gas that does not react with the raw material and
the nitrogen gas supplied as the purge gas. In addition, dust generated in the reducing
part 500 may be contained in the by-products and discharged, and the by-products may
move along a flow of the reducing gas within the reducing part 500 and be discharged
from the reducing furnace.
[0075] As described above, the by-products discharged from the reducing furnace may be used
to produce a hydrogen gas. That is, the method for manufacturing the molten iron in
accordance with an exemplary embodiment may further include a process of collecting
by-products generated in the process of manufacturing the reduced iron and a process
of extracting a hydrogen gas from the collected by-products. As described above, the
by-products discharged from the reducing part 500 may include steam, a hydrogen gas,
a nitrogen gas, and dust, and the reducing part 500 may be provided with an extracting
part 600 to receive the by-products discharged from the reducing part 500. Here, the
dust may be removed before the by-products are supplied to the extracting part 600
or within the extracting part 600. The extracting part 600 may extract the hydrogen
gas from the by-products supplied through a by-product supply line BL using a pressure
swing adsorption method.
[0076] The hydrogen gas extracted during the process of extracting the hydrogen gas may
be used for various purposes. However, the reducing part 500 may use the hydrogen
gas to reduce the raw material, that is, the iron ore, and the hydrogen gas may be
used in a large amount more than twice the amount required to entirely reduce the
raw material supplied to the reducing part 500, but is a very expensive gas, and thus,
to reduce costs through resource recycling, the hydrogen gas extracted from the extracting
part 600 may be reused as the reducing gas to reduce the iron ore. For this, the method
for manufacturing the molten iron in accordance with an exemplary embodiment may be
used to reduce the iron ore by supplying the extracted hydrogen gas as the reducing
gas during the process (S100) of manufacturing the reduced iron. The residue that
is not extracted and discharged during the process of extracting the hydrogen gas
may be supplied to the reducing part 500 as a purge gas. The steam of the residue
may have low reactivity with the iron ore and the reducing gas as a reaction product
produced by the reaction between the iron ore that is the raw material and the hydrogen
gas in the reducing gas and thus may be supplied to the reducing part 500 as the purge
gas. In addition, when the steam is supplied to the reducing part 500 as the purge
gas, the heat of the steam may be utilized for the reduction reaction to save energy
required for the reduction reaction.
[0077] In the process (S200) of reacting with the processing gas, the reduced iron manufactured
in the reducing part 500 may react with a processing gas. Here, the processing gas
may include a gas containing a carbon component, and the process (S200) of reacting
with the processing gas may include a process of carbonizing at least a portion of
the reduced iron manufactured in the reducing part 500.
[0078] That is, as described above, when the reduced iron manufactured in the reducing part
500 is melted without any additional processing, a melting point of the reduced iron
may be very high, and thus, a lot of energy may be required to melt the reduced iron.
In contrast, when the reduced iron is carbonized, the melting point may be lowered
to a temperature of several hundreds of degrees (°C) or more. Thus, in the method
for manufacturing the molten iron in accordance with an exemplary embodiment, the
reduced iron may react with the processing gas, and the reacting reduced iron, that
is, iron carbide may be supplied to the melting part 700 for melting to minimize an
amount of energy used for the melting. Here, the processing gas may include a gas
containing a carbon component.
[0079] Here, in the process (S200) of reacting with the processing gas, the reduced iron
may react with the processing gas without separate thermal processing. That is, the
reduced iron manufactured in the reducing part 500 may be discharged at a high temperature
of, for example, approximately 600°C to approximately 800°C, and the discharged reduced
iron may be directly supplied to the processing part 800 without passing through a
separate thermal processing device. In addition, since the high-temperature exhaust
gas having a temperature of approximately 1,200°C or more is supplied to the processing
space, the processing space may maintain a temperature of approximately 600°C to approximately
800°C even in consideration of a heat loss of the reduced iron during the transfer
process. Thus, in the process (S200) of reacting with the processing gas, the manufactured
reduced iron may react with the processing gas at a temperature of approximately 600°C
to approximately 800°C, and at the beginning of the process or when there is a need
for additional temperature increase, the processing space may be selectively heated
through a heater 820.
[0080] when the processing space is maintained at a temperature of approximately 600°C to
approximately 800°C, when a partial pressure of carbon monoxide and a partial pressure
of carbon dioxide in the processing space specify specific conditions, the reduced
iron may be carbonized by reacting in accordance with the above-described reaction
formula. That is, when the reduced iron and the exhaust gas at a high temperature
are supplied to the processing space, and the processing space is maintained at a
temperature of approximately 600°C to approximately 800°C, when the partial pressure
Pco of the carbon monoxide is greater than about 90% of the sum (Pco+Pco
2) of the partial pressure Pco of the carbon monoxide and the partial pressure Pco
2 of the carbon dioxide, the reduced iron may react according to the above-described
reaction formula and be carbonized.
[0081] Here, to carbonize the reduced iron by reacting with a processing gas, the method
for manufacturing the molten iron in accordance with an exemplary embodiment may include
a process (S400) of using at least a portion of the exhaust gas generated during the
manufacturing of the molten material as the processing gas that reacts with the reduced
iron. That is, in the process (S400) of using the exhaust gas as the processing gas,
at least a portion of the exhaust gas generated in the process (S300) of manufacturing
the molten product may be used as the processing gas that reacts with the reduced
iron in the process (S200) of allowing the manufactured reduced iron to react with
the processing gas. As described above, the melting part 700 may include electric
furnaces 710 and 720 having a melting space capable of melting the reduced iron using
electric heat. In the melting part 700, a recarburizing agent containing a carbon
component may be introduced to adjust a carbon content of the molten product manufactured
by melting the reduced iron. At least partially unreduced raw material, that is, partially
reduced iron or iron ore may be supplied to the melting part 700. As described above,
at least a portion of the unreduced raw material may have an oxygen component, and
the oxygen component may react with the carbon component of the recarburizing agent
within the melting space. Thus, in the melting part 700, the exhaust gas containing
the carbon monoxide gas, that is, the exhaust gas having a high carbon monoxide concentration
(CO-rich) may be discharged while melting the reduced iron. As described above, the
exhaust gas discharged from the melting part 700 may be discharged at a high temperature
of approximately 1,200°C or more.
[0082] At this time, the melting part 700 may include electric furnaces 710 and 720 that
are capable of melting the reduced iron, i.e., an electric smelting furnace (ESF)
or a submerged arc furnace (SAF), which is immersed into slag provided in the electric
furnace main body 710 to melt the reduced iron with slag resistance heat. As described
above, the electric furnaces 710 and 720 may have a very low carbon dioxide content
in the exhaust gas, and an oxygen component of the unreduced raw material may react
with the carbon component of the recarburizing agent, resulting in a high carbon monoxide
concentration. Thus, the partial pressure Pco of the carbon monoxide discharged from
the electric furnaces 710 and 720 may be approximately 90% or more of the sum (Pco+Pco
2) of the partial pressure Pco of the carbon monoxide and the partial pressure Pco
2 of the carbon dioxide, and thus, the reduced iron may be effectively carbonized under
a temperature condition of approximately 600°C to approximately 800°C.
[0083] In the process (S200) of reacting with the processing gas, a supplemental gas having
at least a portion of the same component as the exhaust gas may be used as the processing
gas. As described above, the supplemental gas supply part 900 may supply the supplemental
gas, that is, a carbon-containing gas having at least some of the same components
as the exhaust gas, to the processing part 800, and the supplemental gas supply part
900 may supply a carbon-containing gas to the processing part 800 through the supplemental
gas supply line SL. Here, the supplemental gas supply line SL may be connected to
the exhaust gas supply line EL to supply the supplemental gas together with the exhaust
gas, and the supplemental gas may include at least one of a natural gas containing
carbon or a biomass gas obtained by gasifying biomass.
[0084] Here, most of the reduced iron supplied to the processing space in the process (S200)
of reacting with the processing gas may react with the exhaust gas and be supplied
to the melting part 700, but the reduced iron in reduced fine iron may not react sufficiently
with the exhaust gas to flow by the exhaust gas and then be discharged to the outside
of the processing space together with the exhaust gas.
[0085] Thus, the method for manufacturing the molten iron in accordance with an exemplary
embodiment may further include a process of collecting the reduced iron discharged
from the processing space in which the reduced iron reacts with the processing gas
and a process of supplying the collected reduced iron to the processing space.
[0086] Here, the process of collecting the reduced iron that is discharged may be performed
through a collector 840 connected to the main body 810 to collect the reduced iron
discharged from the main body 810, and the collector 840 may be connected to an upper
portion of the main body 810 and thus be connected to a discharge tube XL through
which the exhaust gas is discharged. In addition, in the process of supplying the
collected reduced iron to the processing space, the reduced fine iron collected from
the collector 840 may be re-supplied to the processing space of the main body 810
through the circulation line CL. Here, the circulation line CL may be directly connected
to the processing space, but may also be connected to the above-mentioned reduced
iron supply tube FL to re-supply the reduced fine iron collected from the collector
840 to the processing space of the main body 810.
[0087] The process (S300) of manufacturing the molten product may be performed by the melting
part 700 receiving the reacting reduced iron, that is, the iron carbide from the processing
part 800 to melt the supplied iron carbide. That is, the melting part 700 may receive
the fine or compacted carbonized iron from the processing part 800 to heat and melt
the reduced iron. In addition, the process (S300) of manufacturing the molten product
may be performed by the melting part 700 receiving the carbonized iron from the reducing
part 800 to melt the supplied carbonized iron using electric heat. Here, the melting
part 700 may include an electric furnace having a melting space capable of melting
the carbonized iron using electric heat. Such an electric furnace may include an electric
furnace main body having a melting space and an electrode rod of which at least a
portion is disposed in the melting space to generate electric heat, and the melting
part 700 may provide electric power to the electrode rod when the reduced iron is
charged into the melting space, thereby melting the carbonized iron.
[0088] Here, the process (S300) of manufacturing the molten product may include the process
of putting a recarburizing agent into the melting part 700, that is, the melting space
of the electric furnace. In the melting part 700, a recarburizing agent containing
a carbon component is introduced to adjust the carbon content of the melt produced
by melting the reduced iron. In addition, the recarburizing agent may be added to
generate a large amount of slag when melting the molten product. The electrode rod
720 may generate resistance heat by being immersed in slag, and the iron carbide may
be more easily melted by the generated resistance heat. Here, since the iron carbide
supplied from the processing part 800 already contains a large amount of carbon components,
the amount of recarburizing agent used may be minimized in the process (S300) of manufacturing
the molten product.
[0089] As described above, in the melting part 700, the exhaust gas containing the carbon
monoxide gas, that is, the exhaust gas having a high carbon monoxide concentration
(CO-rich) and a temperature of approximately 1,200°C or more may be discharged while
melting the reduced iron. Thus, the process of preheating the raw material described
above may be performed using the exhaust gas discharged from the melting part 700,
that is, the exhaust gas discharged during the process of manufacturing the molten
product, which will be described later. Since the exhaust gas discharged from the
melting part 700 is discharged at a high temperature of approximately 1,200°C or more,
the raw material may be preheated by utilizing the heat energy of the exhaust gas.
[0090] To explain this in more detail, the process of preheating the raw material may include
a process of directly injecting a portion of the exhaust gas discharged from the melting
part 600 onto the raw material. In the process of supplying the raw material, the
raw material stored in a storage space of a reservoir 110 may be supplied to the reducing
part 500. Thus, a preheating gas supply part 120 may be installed in the reservoir
110 to supply a preheating gas to the storage space of the reservoir 110. Here, the
process of preheating the raw material may be performed by injecting a high-temperature
exhaust gas having a temperature of approximately 1,200°C or more from the preheating
gas supply part 120 to the raw material stored in the storage space. In addition,
the preheating gas supply part 120 may inject heated external air to the raw material
stored in the storage space to preheat the raw material. Here, in the process of preheating
the raw material, the preheating gas supply part 120 may heat the external air using
heat of the exhaust gas having a temperature of approximately 1,200°C or more, and
the heated air may be supplied to the storage space to preheat the raw material.
[0091] As described above, the melting point of the reduced iron may be lowered by allowing
the exhaust gas generated during the process to react with the reduced iron to minimize
the amount of energy used to melt the reduced iron.
[0092] In addition, the reduced iron manufactured at the high temperature may directly react
with the high-temperature exhaust gas to minimize the facility and resources required
for the reaction.
[0093] In addition, the energy may be efficiently collected by using the sensible heat of
the high-temperature exhaust gas to preheat the raw materials and produce the hydrogen
gas.
[0094] Although the specific embodiments are described and illustrated by using specific
terms, the terms are merely examples for clearly explaining the embodiments, and thus,
it is obvious to those skilled in the art that the embodiments and technical terms
can be carried out in other specific forms and changes without changing the technical
idea or essential features. Therefore, it should be understood that simple modifications
in accordance with the embodiments of the present invention may belong to the technical
spirit of the present invention.
1. A facility for manufacturing molten iron, the facility comprising:
a reducing part configured to manufacture reduced iron;
a melting part configured to melt the reduced iron; and
a processing part installed to receive the reduced iron from the reducing part and
an exhaust gas discharged from the melting part so that the supplied reduced iron
and exhaust gas react with each other to supply the reacting reduced iron to the melting
part.
2. The facility of claim 1, further comprising an exhaust gas supply line installed to
connect the melting part to the processing part,
wherein the reducing part comprises a reducing furnace having a reducing space in
which a reducing gas is supplied to manufacture the reduced iron, and
the melting part comprises an electric furnace having a melting space in which the
reduced iron supplied from the processing part is melted using electric heat.
3. The facility of claim 2, wherein the processing part comprises:
a main body having a processing space;
a reduced iron inlet provided in the main body to allow the reduced iron to flow into
the processing space; and
an exhaust gas inlet provided in the main body and connected to an exhaust gas supply
line so that the exhaust gas is introduced into the processing space,
wherein the exhaust gas inlet is disposed at a position lower than the reduced iron
inlet.
4. The facility of claim 3, wherein the processing part further comprises a heater installed
in the main body to heat the processing space.
5. The facility of claim 3, wherein the processing part comprises:
a collector connected to the main body to collect the reduced iron discharged from
the main body; and
a circulation line configured to connect the collector to the main body so that the
reduced iron collected through the collector is supplied to the main body.
6. The facility of claim 3, wherein the processing part further comprises a supplemental
gas supply part connected to the main body so that a supplemental gas having at least
a portion of the same component as the exhaust gas is supplied to the processing space.
7. The facility of claim 2, further comprising:
a raw material supply part having a storage space in which a raw material is stored
and installed to supply the raw material stored in the storage space to the reducing
space; and
an exhaust gas branch line branched from the exhaust gas supply line and configured
to supply a portion of the exhaust gas discharged from the electric furnace to the
raw material supply part.
8. The facility of claim 7, wherein the exhaust gas branch line is connected to the raw
material supply part to directly supply the exhaust gas to the storage space or transfer
heat of the exhaust gas to air supplied to the storage space.
9. The facility of claim 3, further comprising:
a purge gas supply line connected to the reducing furnace to supply a purge gas to
the reducing space; and
a purge gas branch line branched from the purge gas supply line and configured to
supply a portion of the purge gas supplied to the reducing space to the processing
space.
10. A method for manufacturing molten iron, the method comprising:
manufacturing reduced iron;
allowing the manufactured reduced iron to react with a processing gas;
melting the reacting reduced iron to manufacture a molten product; and
utilizing at least a portion of an exhaust gas generated while manufacturing the molten
iron as a processing gas that reacts with the reduced iron.
11. The method of claim 10, wherein the manufacturing of the reduced iron comprises:
preheating a raw material using the exhaust gas; and
allowing the preheated raw material to react with the reducing gas to reduce the raw
material.
12. The method of claim 11, wherein the preheating of the raw material comprises injecting
the exhaust gas into the raw material or receiving heat of the exhaust gas to inject
heated air into the raw material.
13. The method of claim 11, wherein the raw material comprises powdered iron ore having
a particle size of more than approximately 0 mm and less than or equal to approximately
8 mm.
14. The method of claim 10, wherein the processing gas comprises a gas containing a carbon
component, and
the reacting with the processing gas comprises carbonizing at least a portion of the
reduced iron.
15. The method of claim 10, wherein the allowing of the reduced iron to react with the
processing gas comprises reacting with the processing gas without performing separate
thermal process on the manufactured reduced iron.
16. The method of claim 10, wherein the allowing of the reduced iron to react with the
processing gas comprises allowing the manufactured reduced iron to react with the
processing gas at a temperature of approximately 600°C to approximately 800°C.
17. The method of claim 10, further comprising:
collecting the reduced iron discharged from the processing space in which the reduced
iron reacts with the processing gas; and
supplying the collected reduced iron to the processing space.
18. The method of claim 17, wherein the manufacturing of the molten iron comprises supplying
a purge gas to a reducing space, in which the reduced iron is manufactured, and
the allowing of the reduced iron to react with the processing gas comprises supplying
a portion of a purge gas supplied to the reducing space to the processing space.
19. The method of claim 10, wherein the utilizing of the at least a portion of the exhaust
gas as the processing gas comprises utilizing the exhaust gas and a supplemental gas
having at least a portion of the same component as the exhaust gas as the processing
gas.
20. The method of claim 19, wherein the exhaust gas comprises a carbon monoxide gas, and
the supplemental gas comprises at least one of a natural gas or a biomass gas.