Method for extended conditioning of delayed coke

Description

[0001] This invention relates to the production of coke, particularly to the conditioning of coke in a plurality of drums. Such a process is disclosed in U.S. Patent No. 2199759. In that disclosure a plurality of drums are fed with pre-heated reduced crude petroleum. The coking process in each drum is separately controlled.

[0002] In the production of anisotropic coke, commonly known as needle coke, in the delayed coking process, it is common practice to condition the coke formed in the reaction chamber or coke drum by one of several methods. These are 1) raising the drum temperature while the coke is forming, especially during the latter stages of the coke formation; 2) after the coke is formed, by shutting off the fresh feed portion of the charge to the coke drum and re-cycling coke products or a portion thereof as a hot vapour through the already formed mass of coke; and 3) holding the already formed coke at a temperature above 399°C (750°F). The above procedures, known as "temperature soaking" or "drying out" of the coke, are employed to condition or improve specific properties of the anisotropic coke. The improved properties include 1) lower volatile matter content, 2) increased hardness, and 3) increased crystallinity, resulting in a lower coefficient of thermal expansion.

[0003] In general practice, the amount of in situ coke conditioning is limited by the sizing of the drum to meet the process unit capacity requirements. Since the drum must be fully decoked and prepared to receive feedstock within a fixed operating cycle, the time usually allowed for coke conditioning is typically less than 8 hours. Thus, the amount by which specific properties of the coke can be improved is limited.

[0004] According to the present invention, a process for conditioning coke comprises the steps of: allowing coke to form in a first of three coke drums including feeding coke feedstock to the first drum; conditioning the coke in the first drum to improve one or more of its properties; and decoking the first drum; allowing coke to form in a second coke drum, including feeding coke feedstock to the second drum, simultaneously with conditioning of the coke in the first drum; conditioning the coke in the second drum to improve one or more of its properties simultaneously with decoking of the first drum; and decoking the second drum; allowing coke to form in a third coke drum, including feeding coke feedstock to the third drum, simultaneously with conditioning of the coke in the second drum; conditioning the coke in the third drum to improve one or more of its properties simultaneously with decoking of the second drum; and decoking the third drum, the duration of each step in each drum being substantially the same and the cycle of steps being repeated such that the process is continuous with each drum in a different process stage at any one time.

[0005] In the conditioning step, heat may be applied to the coke. For example, hot conditioning fluid may be passed through the coke.

[0006] The method of the invention utilizes additional reaction chambers or coke drums to enable the allotted time for conditioning the coke to be extended, and thus permit greater improvement in the properties of the coke. For example, if the desired quantity of coke conventionally requires a two coke drum process unit employing an overall cycle of 48 hours for each drum, the use of a third drum permits extended conditioning of the coke. In the conventional process unit, each drum is employed sequentially and alternately for 24 hours of coke formation and 24 hours conditioning and decoking. In the present invention, the third drum sized identically to the other two permits each drum to operate sequentially and alternately in the following mode: 1) 24 hours coke formation, 2) 24 hours conditioning and 3) 24 hours decoking. These time allotments can be varied to achieve desired requirements of process capacity, cycle time and product improvement. When each or any of the three portions of the overall cycle described above is decreased, the required size of the coke drum can also be decreased by an appropriate amount resulting from the number or fractional number of coking formation segments permitted by the overall cycle. In the example given above, if each segment were operated for 18 hours instead of 24 hours, the coke drums could be sized at 75 per cent of the capacity required for the 24 hour cycles. Alternatively, if each drum were capable of holding the coke formed in 24 hours of operation, the overall unit production of coke could be increased by one-third if each of the three operations were reduced to 18 hours from 24 hours.

[0007] The invention will now be described by way of example of embodiments thereof and with reference to the accompanying drawings, wherein:

Figure 1 is a schematic representation of three coke drums and appropriate piping for use in connection with the process according to the present invention;

Figure 2A is a representation of a prior art coking cycle;

Figure 2B is an illustration of an exemplary coking cycle for the process according to the present invention; and

Figure 2C is a schematic representation of an alternate coking cycle according to the present invention.

[0008] As can be seen from Figure 1, the reference numeral 10 generally indicates apparatus for use in connection with the coking process according to the present invention. An inlet line 12 provides coke feedstock from a source, such as the residual bottoms of crude oil from a refining process. The residual bottoms are typically heated to a temperature of about 482-538°C (900°F-1000°F) in a conventional furnace, from which the hot oil is discharged. The inlet line 12 receives such a discharge and directs it through a main inlet valve 14 to a multi-position switch valve 16 which directs the flow of the coke feedstock to one of a plurality of connecting lines 18a, 18b or 18c. The connecting lines connect the valve 16to conditioning chambers or coke drums A, B and C, respectively. Valves 20a, 20b and 20c are positioned in the connecting lines to isolate the flow therethrough. A conditioning feed inlet line 22 is provided to direct hot conditioning fluid, such as coker products or a portion thereof as hot vapor to the coke drums A, B and C through a switch valve 23 and connecting lines 24a, 24b and 24c respectively. The conditioning fluid improves the coke by lowering its volatile matter content, increasing its hardness, and increasing its crystallinity, which lowers its coefficient of thermal expansion.

[0009] Isolation valves 26a, 26b and 26c are provided in the connecting lines 24a-c, respectively. It should be noted that the conditioning feed lines 24a-c are not required for all types of conditioning processes. For example, the coke can be conditioned merely by maintaining it at a high temperature, such as above 750°F. Outlet lines 28a, 28b and 28c extend from the coke drums A, B and C to permit the removal of light products from the coking process, thereby leaving only coke in the coke drums. The outlets 28a, 28b and 28c are connected to a common delivery line 30 through pairs of isolation valves 29a, 29b and 29c, the isolation valves being employed in pairs to account for valve leakage. A warm-up line 32 is connected directly from the coke feedstock inlet 12 to the delivery line 30, and flow therethrough is controlled by valves 34 and 36. During start up of the apparatus 10, before coke feedstock is fed to any of the coke drums, the hot vapors of the feedstock are allowed to flow into one of the coke drums A, B or C through its respective outlet line 28a, b or c to preheat the coke drum and, thereby, to avoid the thermal shock that can result if the hot feedstock is fed to a drum which is at ambient temperatures.

[0010] In operation, the main inlet valve 14 is opened to allow the flow of coke feedstock through the inlet line 12 to the switch valve 16. The switch valve 16 directs the flow to one of the three coke drums, for example, coke drum A, through the associated valve, in this case valve 20a. Atthistime, the switch valve 16 prevents the flow of feedstock to any other drum. When the coke drum A is full of coke, the valve 20b controlling the flow of feedstock to coke drum B is opened, the switch valve 16 is operated to direct the incoming feedstock through the line 18b and the valve 20b, and the valve 20a controlling the flow to the coke drum A is closed. When coke drum B is full of coke, the valve 20c is opened, the switch valve 16 is operated to direct the flow of feedstock through the line 18c, and the valve 20b is closed. When the coking operation in coke drum B is completed, the same operation takes place with respect to coke drum C. The switch valve 16 may be operated manually, or automatically.

[0011] While the coking operation is taking place in drum A, coke which has already formed in drum C is being conditioned. The conditioning may include the flow of coker products comprising hot vapor derived from a coker fractionator through the coke drum containing the formed coke. As an alternative, steam can be used as a conditioning fluid. The conditioning fluid strips the highly volatile matter from the coke and maintains the coke at a high temperature. Without the flow of the conditioning material or the application of heat from some other source, the temperature of the coke would fall rapidly. Thus, the feed of conditioning fluid through the inlet line 22 to the switch valve 23 is directed by the switch valve through the isolation valve 26c and the connecting line 24c to the coke drum. When the conditioning of the coke in coke drum C is complete, the switch valve 23 is moved to a position in which the flow of conditioning fluid is directed to coke drum A. Similarly, when the conditioning of the coke in coke drum A is completed, the switch valve 23 can be operated to directthe flow of conditioning fluid to coke drum B. The switch valve 23 may be operated manually or automatically.

[0012] While coke is being. allowed to form in coke drum A and conditioned in coke drum C, coke drum B can be decoked. Decoking involves the removal of the coke from the drum, such as by the use of high impact water jets to hydraulically bore and cut the coke.

[0013] In a conventional coking process, as can be seen from Fig. 2A, only two conditioning chambers or coke drums A and B are employed, and the coke forming process, including the feeding of the coke feedstock to the coke drum, occurs in one coke drum, while conditioning and decoking take place in the other drum. Thus, in a typical 48 hour cycle, coking takes place for approximately 24 hours and conditioning and decoking combined take place for 24 hours. As a result, the time available for conditioning is typically less than 8 hours.

[0014] As can be seen from Figs. 2B and 2C, the use of an additional coke drum, drum C, in connection with the process according to the present invention, permits a much greater conditioning time. For example, in the exemplary 72 hour cycle illustrated in Fig. 2B, coking or coke formation is allowed to occur for 24 hours, as it was in the prior art process. However, conditioning and decoking are each able to last for a 24 hour period. The same amount of conditioned coke is delivered from the process of Fig. 2B as was delivered from the process of Fig. 2A, but a much greater conditioning time is available.

[0015] In the process of Fig. 2B, the allowing of the coke to form in coke drum A, including the feeding of the coke feedstock to the chamber, is simultaneous, for the same 24 hour period, with the decoking of coke drum B and the conditioning of the coke in coke drum C to improve one or more of its properties. Similarly, the conditioning of the coke in coke drum A is simultaneous for a 24 hour period with the coking in coke drum B and the decoking of coke drum C; and the decoking of coke drum A is simultaneous with the conditioning of coke drum B and the coking in coke drum C.

[0016] As can be seen from Fig. 2C, the overall operating cycle of the process according to the present invention can be reduced, for example, to 54 hours and, thus, provide a greater output of conditioned coke than was possible with the prior art system. In the example of Fig. 2C, the coking period is reduced from 24 hours to approximately 18 hours, as are the conditioning and .decoking periods. However, the 36 hours provided for the conditioning and decoking periods together is still 50% greater than the 24 hour combined conditioning.

[0017] The invention may be embodied in other specific forms without departing from its spirit or essential characteristics. The present embodiments are, therefore, to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the claims rather than by the foregoing description and all changes which come within the meaning and range of the equivalents of the claims are therefore intended to be embraced therein.

Claims

1. A process for conditioning coke comprising the steps of: allowing coke to form in a first of three coke drums including feeding coke feedstock to the first drum; conditioning the coke in the first drum to improve one or more of its properties; and decoking the first drum; allowing coke to form in a second coke drum, including feeding coke feedstock to the second drum, simultaneously with conditioning of the coke in the first drum; conditioning the coke in the second drum to improve one or more of its properties simultaneously with decoking of the first drum; and decoking the second drum; allowing coke to form in a third coke drum, including feeding coke feedstock to the third drum, simultaneously with conditioning of the coke in the second drum; conditioning the coke in the third drum to improve one or more of its properties simultaneously with decoking of the second drum; and decoking the third drum, the duration of each step in each drum being substantially the same and the cycle of steps being repeated such that the process is continuous with each drum in a different process stage at any one time.

2. A process according to Claim 1 wherein the steps of conditioning the coke in each drum include applying heat to the coke.

3. A process according to Claim 2 wherein applying heat to the coke comprises flowing hot conditioning fluid through the coke.

Ansprüche

1. Verfahren zum Konditionieren von Koks, gekennzeichnet durch folgende Schritte:

Ausbildung von Koks in einer ersten von drei Kokstrommein einschließlich der Zufuhr von Koksausgangsmaterialien zu der ersten Trommel; Konditionierung des Kokses in der ersten Trommel, um eine oder mehrere seiner Eigenschaften zu verbessern, und Entkokung der ersten Trommel; Ausbildung von Koks in einer zweiten Kokstrommel, einschließlich der Zufuhr von Koksausgangsmaterialien zu der zweiten Trommel, gleichzeitig mit der Konditionierung des Kokses in der ersten Trommel; Konditionierung des Kokses in der zweiten Trommel zur Verbesserung einer oder mehrerer seiner Eigenschaften, gleichzeitig mit der Entkokung der ersten Trommel, und Entkokung der zweiten Trommel; Ausbildung von Koks in einer dritten Trommel einschließlich der Zufuhr von Koksausgangsmaterialien zu der dritten Trommel, gleichzeitig mit der Konditionierung des Kokses in der zweiten Trommel; Konditionierung des Kokses in der dritten Trommel zur Verbesserung einer oder mehrerer seiner Eigenschaften, gleichzeitig mit der Entkokung der zweiten Trommel, und der Entkokung der dritten Trommel, wobei die Dauer jedes Schrittes in jeder Trommel im wesentlichen gleich ist und der Zyklus der Schritte wiederholt wird, so daß das Verfahren derart kontinuierlich abläuft, daß jede Trommel sich jederzeit in einem verschiedenartigen Verfahrenszustand befindet.

2. Verfahren nach Anspruch 1, dadurch gekennzeichnet, daß der Schritt der Konditionierung des Kokses in jeder Trommel die Aufbringung von Wärme auf den Koks umfaßt.

3. Verfahren nach Anspruch 2, dadurch gekennzeichnet, daß das Aufbringen von Wärme auf den Koks das Fließen von heißem Konditionierungsfluid durch den Koks umfaßt.

Revendications

1. Procédé pour le conditionnement du coke, comprenant les étapes consistant à:

- permettre la formation de coke dans un premier de trois tambours à coke, incluant l'introduction de la charge d'alimentation de cokéfaction dans le premier tambour;

- conditionner le coke dans le premier tambour pour améliorer une ou plusieurs de ses propriétés; et

- effectuer le décokage du premier tambour;

- permettre la formation de coke dans un second tambour à coke, incluant l'introduction de la charge d'alimentation de cokéfaction dans le second tambour, simultanément au conditionnement du coke dans le premier tambour;

- conditionner le coke dans le second tambour pour améliorer une ou plusieurs de ses propriétés simultanément au décokage du premier tambour; et

- effectuer le décokage du second tambour;

- permettre la formation de coke dans un troisième tambour à coke, incluant l'introduction de la charge d'alimentation de cokéfaction dans le troisième tambour, simultanément au conditionnement du coke dans le second tambour;

- conditionner le coke dans le troisième tambour pour améliorer une ou plusieurs de ses propriétés simultanément au décokage du second tambour; et

- effectuer le décokage du troisième tambour, la durée de chaque étape dans chaque tambour étant sensiblement la même et le cycle des étapes étant répété, de telle sorte que le procédé soit continu, chaque tambour se trouvant dans une étape de traitement différente à tout instant.

2. Procédé selon la revendication 1, dans lequel l'étape de conditionnement du coke dans chaque tambour comprend l'application de chaleur au coke.

3. Procédé selon la revendication 2, dans lequel l'application de chaleur au coke comprend l'écoulement d'un fluide de conditionnement chaud à travers le coke.

Drawing