(19)
(11) EP 0 321 307 A3

(12) EUROPEAN PATENT APPLICATION

(88) Date of publication A3:
30.08.1989 Bulletin 1989/35

(43) Date of publication A2:
21.06.1989 Bulletin 1989/25

(21) Application number: 88311989.3

(22) Date of filing: 16.12.1988
(51) International Patent Classification (IPC)4C10G 67/04
(84) Designated Contracting States:
BE DE ES FR GB IT NL

(30) Priority: 18.12.1987 US 135150

(71) Applicant: EXXON RESEARCH AND ENGINEERING COMPANY
Florham Park, New Jersey 07932-0390 (US)

(72) Inventors:
  • Achia, Biddanda Umesh
    Sarnia Ontario N7S 5P8 (CA)
  • Bell, James David
    Toronto Ontario M4R 1K2 (CA)
  • Cody, Ian Alfred
    Clearwater Ontario N7T 7H6 (CA)
  • Wachter, William Augusta
    Baton Rouge Louisiana 70817 (US)
  • West, Theodore Harvey
    Sarnia Ontario N7T 7H4 (CA)

(74) Representative: Somers, Harold Arnold et al
ESSO Engineering (Europe) Ltd. Patents & Licences Mailpoint 72 Esso House Ermyn Way
Leatherhead, Surrey KT22 8XE
Leatherhead, Surrey KT22 8XE (GB)


(56) References cited: : 
   
       


    (54) Method for isomerizing wax to lube base oils


    (57) Slack waxes and synthetic wax (1) are isomerized and processed into high viscosity index (VI) and very low pour point lube base stock oils and blending stocks (11) by the process comprising the steps of optionally hydrotreating (3) the wax, if necessary, to remove heteroatom and polynuclear aromatic compounds and/or optionally deoiling the wax , if necessary, to an oil content between about 5-20% oil, isomerizing (5, 7) the wax over a catalyst of Group VI-Group VIII metal on a halogenated refractory metal oxide support, said isomeriza­tion being conducted to a level of conversion such that about 40% or less unconverted wax remains in the 330°C+ (preferably the 370°C+) fraction sent to the dewaxer. The total isomerate from the isomeriza­tion unit is fractionated (8) into a lube oil fraction (9) boiling at 330°C+, preferably 370°C+. This oil fraction is solvent dewaxed (10), preferably using MEK/MIBK at 20/80 ratio, and unconverted wax (12) is recycled (12A, 12B) to the isomerization unit. Operating in this manner permits one to obtain isomerate oil (11) of very high VI (in excess of 130) possessing a low pour point (-21°C, preferably -24°C, most preferably -27°C).







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