(19)
(11) EP 0 286 773 A3

(12) EUROPEAN PATENT APPLICATION

(88) Date of publication A3:
21.03.1990 Bulletin 1990/12

(43) Date of publication A2:
19.10.1988 Bulletin 1988/42

(21) Application number: 88100045.9

(22) Date of filing: 05.01.1988
(51) International Patent Classification (IPC)4C11D 3/386, C11D 3/395
(84) Designated Contracting States:
AT BE CH DE ES FR GB GR IT LI NL SE

(30) Priority: 17.04.1987 US 40191

(71) Applicant: ECOLAB INC.
St. Paul Minnesota 55102 (US)

(72) Inventor:
  • Olson, Keith Edward
    Apple Valley, MN 55124 (US)

(74) Representative: Maiwald, Walter, Dr. Dipl.-Chem. et al
Maiwald & Partner, Poccistrasse 11
80336 München
80336 München (DE)


(56) References cited: : 
   
       


    (54) Water insoluble encapsulated enzymes protected against deactivation by halogen bleaches


    (57) A composition capable of releasing active enzyme into an aqueous, active chlorine containing media which in a first aspect comprises an enzyme core encapsulated with an initial coating of a time-release substance, a first coating of a bleach-neutralizing substance and a second coating of a time-release substance.
    In a second aspect, the composition comprises an enzyme encapsulated in a time-release substance designed to delay release of the enzyme in dissolution for a first-time delay, and a bleach-neutralizing substance, present as either a core material and/or a first coating on a diluent core, which is encapsulated in a time-release substance designed to delay release of the bleach-neutralizing substance into solution for a second-time delay; the first-time delay being longer than the second-time delay so that the bleach-neutralizing substance will be released and completely neutralize all active chlorine present in the solution before the enzyme is released.
    In a third aspect, the composition comprises an enzyme core encapsulated with a time-release substance, a diluent core encapsulated with a first coating of a bleach­neutralizing substance and a second coating of a time-release substance, and a bleach-neutralizing substance core encapsulated with a time-release substance.
    The invention further includes a cleaning composition which is particularly effective in warewashing which comprises one of the encapsulated enzyme-containing compositions described above, chlorine bleach, and at least one additional detergent component.





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