(19) |
 |
|
(11) |
EP 0 286 773 A3 |
(12) |
EUROPEAN PATENT APPLICATION |
(88) |
Date of publication A3: |
|
21.03.1990 Bulletin 1990/12 |
(43) |
Date of publication A2: |
|
19.10.1988 Bulletin 1988/42 |
(22) |
Date of filing: 05.01.1988 |
|
|
(84) |
Designated Contracting States: |
|
AT BE CH DE ES FR GB GR IT LI NL SE |
(30) |
Priority: |
17.04.1987 US 40191
|
(71) |
Applicant: ECOLAB INC. |
|
St. Paul
Minnesota 55102 (US) |
|
(72) |
Inventor: |
|
- Olson, Keith Edward
Apple Valley, MN 55124 (US)
|
(74) |
Representative: Maiwald, Walter, Dr. Dipl.-Chem. et al |
|
Maiwald & Partner,
Poccistrasse 11 80336 München 80336 München (DE) |
|
|
|
(54) |
Water insoluble encapsulated enzymes protected against deactivation by halogen bleaches |
(57) A composition capable of releasing active enzyme into an aqueous, active chlorine
containing media which in a first aspect comprises an enzyme core encapsulated with
an initial coating of a time-release substance, a first coating of a bleach-neutralizing
substance and a second coating of a time-release substance.
In a second aspect, the composition comprises an enzyme encapsulated in a time-release
substance designed to delay release of the enzyme in dissolution for a first-time
delay, and a bleach-neutralizing substance, present as either a core material and/or
a first coating on a diluent core, which is encapsulated in a time-release substance
designed to delay release of the bleach-neutralizing substance into solution for a
second-time delay; the first-time delay being longer than the second-time delay so
that the bleach-neutralizing substance will be released and completely neutralize
all active chlorine present in the solution before the enzyme is released.
In a third aspect, the composition comprises an enzyme core encapsulated with a time-release
substance, a diluent core encapsulated with a first coating of a bleachneutralizing
substance and a second coating of a time-release substance, and a bleach-neutralizing
substance core encapsulated with a time-release substance.
The invention further includes a cleaning composition which is particularly effective
in warewashing which comprises one of the encapsulated enzyme-containing compositions
described above, chlorine bleach, and at least one additional detergent component.
