Process and Apparatus for the mixed production of high and low purity oxygen

Description

BACKGROUND OF THE INVENTION

Field of the Invention:

[0001] The present invention relates to a process and apparatus for simultaneously producing both high and low purity oxygen comprising the features as indicated in the preamble of claim 1, vesp. claim 11.

Description of the Background:

[0002] The double reboiler and double column process was developed to produce relatively low purity oxygen at purities below 97% oxygen content. This process is described in U.S. Patent 3,113,854 and in the Electric Power Research Institute (ERPI) Study 3499. Additionally, U.S. 4,895,583 discloses a modification of an earlier process in order to improve the overall recovery of oxygen.

[0003] Another example of a conventional double column and double reboiler process for producing relatively low purity oxygen is that disclosed in U.S. 4,705,548. However, this process is disadvantageous as it requires the use of a compressor for nitrogen recycling.

[0004] Attempts to produce high oxygen purities, such as above 97% oxygen content, using the double reboiler and double column methodology have not been considered interesting due to the sharp reduction in process efficiency and loss of recovery which is entailed. These drawbacks occur because it is necessary to perform the very difficult argon/oxygen separation by cryogenic distillation for oxygen contents of higher than 97%.

[0005] At present, in order to obtain an oxygen content of greater than 97%, the single reboiler, double column process is usually used. Unfortunately, this process has a much higher specific power consumption than the double reboiler and double column process.

[0006] It would be extremely advantageous if a process were known for producing oxygen at both low and high purity. Frequently, an on-site oxygen facility may produce a gaseous oxygen product at 95% purity for a pipeline customer, yet local demand may require a liquid oxygen product having 99.6% oxygen content which is a normal standard grade for liquid oxygen.

[0007] Furthermore, in situations where significant liquid production is required a traditional single reboiler process is used whereby air, expanded through an expander, is injected into the high pressure column. This affords a good recovery of oxygen since the majority of the air is still being treated in the high pressure column and does not by-pass the first step of distillation.

[0008] However, this feature has a major drawback because of the relatively high discharge pressure of the expander which is the high pressure column pressure. The feed air pressure must, therefore, be maintained at a high pressure to achieve the required refrigeration. In such situations, high power consumption would be needed to produce the required liquid.

[0009] Thus, a need exists for a process for producing oxygen at both low and high purity, more precisely, low purity gaseous oxygen and high purity liquid oxygen, and which does not involve a prohibitively high specific power consumption.

[0010] Accordingly, it is an object of the present invention to provide a process for producing oxygen at both low and high purity.

[0011] It is also an object of the present invention to provide a process for producing oxygen at both low and high purity, which does not involve a prohibitively high specific power consumption.

[0012] Moreover, it is a specific object of the present invention to produce simultaneously both high and low purity oxygen using a double reboiler, double column process and optionally with feed stream expansion into the high pressure fractionating means.

[0013] According to the present invention, a process for simultaneously producing both high and low purity oxygen using a double distillation column comprising a high pressure column and a pressure column, comprises :

a) condensing a first compressed and cooled feed stream fraction containing at least nitrogen and oxygen in a first reboiler located at the bottom of the low pressure column ;

b) feeding at least a fraction of the resulting liquefied feed stream to either or both high and low pressure columns as feed ;

c) introducing a second feed stream fraction to the bottom of the high pressure column as gaseous feed, whereby a bottom oxygen-rich liquid stream and an overhead nitrogen-rich gaseous stream are formed ;

d) passing the oxygen-rich liquid stream to the low pressure column as feed ;

e) condensing the nitrogen-rich gaseous stream against a boiling liquid in a second reboiler of the low pressure column, thereby serving as a second reboil for distillation, said second reboiler being positioned above said first reboiler;

f) returning a portion of the condensed nitrogen-rich stream pressure to the high pressure column as reflux, and passing at least a fraction of the remaining portion of the nitrogen-rich stream to the top of the low pressure column as reflux, whereby the low pressure column separates its feeds into bottom stream oxygen products and top stream rich in nitrogen ; and

g) recovering the bottom stream oxygen product from a first outlet as high purity liquid oxygen,
   characterized in that it comprises :

h) drawing from a tray or a stage between the first and second reboilers of the low pressure column, via a second outlet, the stream oxygen product as purity oxygen.

[0014] According to the present invention, there is provided an apparatus for simultaneously producing both high and low purity oxygen, which comprises feed stream input means, a double rectification column in fluid connection with said input means having therein a lower pressure fractionating means with first and second reboilers therein, said first reboiler being positioned below said second reboiler and a higher pressure fractionating means wherein an outlet is provided at the bottom of the lower pressure fractionating means for extracting a high-purity liquid oxygen stream, and characterized in that an intermediate outlet is provided between the two reboilers of the lower pressure fractionating means for extracting a low purity oxygen stream.

[0015] The features of the pre-characterizing portion of the independent claims are to be found in US-A-4,895,583.

[0016] Figure 1 illustrates the relationship between overall oxygen recovery and percentage of high purity liquid produced for 95 % low purity gaseous oxygen and 99.9 % high purity liquid oxygen.

[0017] Figure 2 illustrates an apparatus for practicing the present invention.

[0018] Figure 3 illustrates an alternative apparatus for practicing the present invention using a pumping process where pumped liquid oxygen is vaporized directly in the main exchanger.

[0019] Figure 4 illustrates an apparatus for practicing the present invention using a pumping process where pumped liquid oxygen is vaporized in a separate exchanger against a condensing feed stream.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENT

[0020] In accordance with the present invention, both high and low purity oxygen are simultaneously produced using a double reboiler, double column process with feed stream expansion having reduced power consumption.

[0021] In more detail, it has been discovered that by adding an intermediate outlet between the two reboilers of the upper distillation column, a low purity oxygen stream can be extracted at this outlet simultaneously with another high purity liquid oxygen stream produced at the bottom of the distillation column. By using the present invention, significant amounts of high purity liquid oxygen can be produced simultaneously with the low purity oxygen product with excellent recovery/efficiency.

[0022] The double reboiler, double column process is characterized by condensing a feed stream against oxygen product. This results in a relatively low operating pressure of about 4 bar for the high pressure column. A conventional single reboiler process would require a pressure of about 6 bar. Therefore, significant power savings are achievable with the double reboiler, double column process if an oxygen purity of less than 97% is acceptable.

[0023] However, poor oxygen recovery would result if higher purity oxygen is required using the double reboiler, double column process.

[0024] That is, the double reboiler, double column process is characterized by a low operating pressure, low purity oxygen and low power consumption. In contrast, the traditional simple reboiler process is characterized by a high operating pressure, high purity oxygen and high power consumption.

[0025] In order to produce a significant amount of liquid oxygen, the feed stream expansion process is frequently used where the feed stream is expanded through an expander into the high pressure column. For the production of a given amount of liquid, feed stream pressure upstream of the expander would be much lower for the double reboiler process since its discharge pressure is the lower of the two processes. Therefore, much lower power consumption can be achieved for the liquid production.

[0026] In accordance with the present invention, it has been surprisingly discovered that the double reboiler process can produce a high proportion of high purity oxygen product while maintaining high overall oxygen recovery. For example, up to 30% of 99.9% purity liquid oxygen can be produced in conjunction with 95% purity gaseous oxygen and with a recovery of between 99.5% and 97.5%, which is, indeed, unexpected. This result is unexpected because 30% is a high proportion for a cryogenic air separation process.

[0027] Of course, the process of feed stream expansion into a high pressure fractionating means is suitable for relatively significant liquid production at 40% or below of the total production. For higher percentages, one must rely upon an independent refrigeration cycle. For small quantities of liquid production, any expansion means is suitable, such as nitrogen-rich gas expansion or air expansion into a low pressure fractionating means.

[0028] As used herein, the term "feed stream" refers to any gaseous mixture containing at least nitrogen and oxygen. For example, the feed stream may be atmospheric air or may be an off-gas mixture.

[0029] As used herein, the term "recovery" is defined as total contained oxygen in products divided by total oxygen contained in the feed stream. The term "percent high purity oxygen" is defined as production of high purity oxygen divided by total oxygen production.

[0030] Furthermore, as used herein, the term "high purity oxygen" means any gas containing at least 97 mol% of oxygen, whereas the term "low purity oxygen" means any gas containing less than 97 mol% of oxygen.

[0031] The present invention provides an intermediate outlet between the two reboilers of the upper distillation column to extract a low purity oxygen stream. Additionally, a high purity liquid oxygen stream is recovered at the bottom.

[0032] In particular, the present method involves various steps which will now be described in general by reference to Figure 2.

[0033] First, a feed stream, such as purified atmospheric air, is compressed and cooled. Thereafter, the feed stream is fed through conduit (101) to a main exchanger (11), where the feed stream is further cooled and then divided into two fractions (A) and (B). First fraction (A) is then expanded in expander (12), and thereafter further divided into two fractions (i) and (ii) at the junction of conduits (106) and (107).

[0034] Feed stream (B) is further cooled in the main exchanger and at least a fraction of this stream is expanded by expansion valve (130a) into a high pressure column (20) as liquid feed stream.

[0035] First fraction (i) is introduced into a reboiler (24) at the bottom of the low pressure distillation column (21) to provide a first reboil for distillation. Thereafter, at least a fraction of the resulting liquefied feed stream is fed to either or both high and low pressure columns as feeding conduits (111) and/or (112).

[0036] Then, the second fraction (ii) is fed to the bottom of the high pressure column (20) as gaseous feed, to form a bottom oxygen-rich liquid stream (108) and an overhead nitrogen rich gaseous stream (114). Thereafter, the oxygen-rich liquid stream is passed to the low pressure column (21) as feed.

[0037] The nitrogen-rich gaseous stream is condensed against a boiling liquid in the upper reboiler (23) of the low pressure column (21), thereby serving as a second reboil for distillation. Then, a portion of the condensed nitrogen-rich stream is returned in conduit (131) to the high pressure column (20) as reflux via conduit (115) and the remaining portion of the nitrogen-rich stream to the top of the low pressure column as reflux via conduit (116), whereby the low pressure column (21) separates its feeds into bottom stream oxygen products and top stream (120) rich in nitrogen.

[0038] Thereafter, bottom stream oxygen product (118) is recovered as high-purity oxygen. A stream (111) is then drawn at a stage between the two reboilers (23) and (24) of the low pressure column (21) as low purity gaseous oxygen product. Finally, the nitrogen-rich stream is warmed in at least exchanger (11), and optionally exchanger (22), via conduits (120) and (121), with the low purity oxygen stream (119) from the low pressure column.

[0039] Additionally, in Figure 2, a booster compressor (10), driven by the expander (12), may be optionally used to further compress the feed stream entering via conduit (100). The feed stream then is fed via conduit (101) to the main exchanger (11) and therethrough via conduit (102), whereinafter a portion of the feed stream is passed via conduit (103) to expander (12) and then to conduit (105), and thereinafter further divided into two fractions via conduits (106) and (107) as described above.

[0040] Further, in Figure 2, oxygen-rich liquid stream (108) is optionally subcooled in exchanger (22) and then transferred to the low pressure column (21) via conduit (109). Moreover, the liquefied feed stream (112) may be subcooled in exchanger (22), and then transferred to the low pressure column via conduit (113). However, the liquefied feed stream may be fed directly to the low pressure column.

[0041] In more detail, a feed stream, containing at least nitrogen and oxygen, which has been compressed and cooled is passed to a main exchanger. The feed stream is compressed in compressing means and cooled. For example, the compressing means may comprise a booster (10) driven by a turbine (12). Generally, the feed stream after compression is at a pressure in the range of about 6 to 50 bar. The preferred pressure depends upon the percentage of liquid produced. If a higher percentage of liquid is needed then higher pressure is required. However, in general, the preferred pressure is in the range of about 10 to 35 bar. Then, the compressed, cooled and purified feed stream is further cooled in a main exchanger, where it is divided into two fractions (A) and (B). Generally, the feed stream is at a temperature in the range of about -120°C to -150°C. It is preferred, however, that the feed stream be at a temperature of about -125°C to -145°C. Thereafter, the first fraction (A) is expanded in step b) in an expander and subsequently divided into two further fractions (i) and (ii). Generally, the preferred discharge pressure range of the expander is 3 to 5 bar. Then, the second fraction (B) is further cooled in step c) in the main exchanger and at least a fraction of this stream is expanded by an expansion valve into the high pressure column as liquid feed stream.

[0042] In step c), fraction (B) is generally subcooled beyond the bubble point. It is preferred, however, that it be subcooled to a temperature in the range of about -150°C to -180°C.

[0043] Then, in step d), the first fraction (i) is introduced into a reboiler located at the bottom of the low pressure distillation column, whereby the feed stream condenses in the reboiler providing a first reboil for distillation. At least a fraction of the resulting liquefied feed stream is then fed to either or both high and low pressure columns as feed. The temperature of the resulting liquefied feed stream to the high pressure column is generally near the bubble point, preferably at the bubble point. The temperature of the liquefied feed stream to the low pressure column is generally subcooled below the bubble point. The second fraction (ii) is introduced to the bottom of the high pressure column as gaseous feed, whereby a bottom oxygen-rich liquid stream and an overhead nitrogen-rich gaseous stream are formed. The temperature is near the dew point. The oxygen-rich liquid stream is then passed to the low pressure column as feed.

[0044] Generally, in passing the oxygen-rich liquid stream to the low pressure column as feed, the stream is preferably subcooled before expanding into the low pressure column.

[0045] The nitrogen-rich gaseous stream is then condensed against a boiling liquid in the upper reboiler of the low pressure column, thereby serving as a second reboil for distillation. A portion of the condensed nitrogen-rich stream is returned to the high pressure column as reflux, and the remaining portion of the nitrogen-rich stream is passed to the top of the low pressure column as reflux, whereby the low pressure column separates its feeds into bottom oxygen products and top stream rich in nitrogen.

[0046] Then, the bottom oxygen product (118) is recovered as high purity liquid oxygen. Generally, for the bottom stream oxygen products purities in the range of 97% to 99.99% are obtained. Thereafter, a stream (119) is drawn at a tray located between the two reboilers of the low pressure column as low purity oxygen. In this step, the vapor product can be extracted as part of the vapor leaving the tray or stage in the case that structured packings are used or, an equivalent means which is conventionally so used. If the product is liquid, the liquid product is extracted as part of the liquid leaving the tray or stage. Finally, in the main exchanger, the low purity oxygen stream and the nitrogen-rich stream are warmed to ambient conditions.

[0047] However, in addition to the exemplary process scheme described above, various modifications may also be made. For example, argon may be recovered by means of an argon sidearm column at a tray between the two oxygen product outlets or a stage in the case of structured packings.

[0048] As used herein, the term "tray" refers to any means or device for effecting intimate contact and mass transfer between a descending liquid phase and an ascending vapor phase. These various trays are well known to those skilled in the art.

[0049] The term "tray" as used herein also includes means known as structured packings or equivalent means which are devices equivalent to trays to effect such intimate contact for cryogenic air separation. Examples of structured packings are disclosed, e.g. in U.S. Patents 2,047,444; 4,186,156 and 4,296,050, each patent being incorporated herein by reference in the entirety, and Ellis et al, Trans. Instn. Chem. Engrs., 41, 1963, known as Goodloe packings. These structured packings are known as means to promote liquid and/or vapor mixing in a direction perpendicular to the primary flow direction, i.e., the vertical direction. Furthermore, a combination of trays and packings can be used as mass transfer means.

[0050] Reference will now be made to each of Figures 1-4 in detail.

[0051] Figure 1 illustrates the relationship between overall oxygen recovery and percentage of high purity liquid produced for 95% low purity gaseous oxygen and 99.9% high purity liquid oxygen.

[0052] As may be seen from Figure 1, recovery remains rather constant up to about 30% high-purity liquid oxygen production, and drops sharply beyond this point. Generally, in accordance with the present invention, recoveries of high purity liquid oxygen of equal to or less than 35% are obtained.

[0053] Figure 2 illustrates an embodiment of the present invention as described above.

[0054] Figure 3 illustrates another embodiment of the present invention using a pumping process where pumped liquid oxygen is vaporized directly in the main exchanger.

[0055] In Figure 3, the low purity oxygen stream (119) is produced in the liquid form directly off the low pressure column (21). This liquid is then pumped to a higher pressure using a pumping means (140) and then vaporized and warmed in the main exchanger (11). At the same time, a high pressure feed stream (104) is condensed in the main exchanger (11) to provide necessary heat for the vaporization of the oxygen stream.

[0056] The remaining elements depicted in Figure 3 correspond to those already depicted and described for Figure 2.

[0057] In Figure 4, the low purity oxygen stream (119) is produced in the liquid form directly off the low pressure column (21). This liquid is then pumped to a higher pressure using pumping means (140) and then vaporized in a separate exchanger (150) against a condensing feed stream.

[0058] The remaining elements depicted in Figure 4 correspond to those already depicted and described for Figure 2.

[0059] In accordance with the present invention, a process is provided for simultaneously producing both high and low purity oxygen, which entails:

a) condensing a first compressed, cooled and purified feed stream fraction in a reboiler located at the bottom of a low pressure column;

b) feeding at least a fraction of the resulting liquefied feed stream to either or both high and low pressure columns as feed;

c) introducing a second fraction of feed stream to the bottom of the high pressure column as gaseous feed, whereby a bottom oxygen-rich liquid stream and an overhead nitrogen-rich gaseous stream are formed;

d) passing the oxygen-rich liquid stream to the low pressure column as feed;

e) condensing the nitrogen-rich gaseous stream against a boiling liquid in the upper reboiler of the low pressure column, thereby serving as a second reboil for distillation;

f) returning a portion of the condensed nitrogen-rich stream to the high pressure column as reflux, and passing at least a fraction of the remaining portion of the nitrogen-rich stream to the top of the low pressure column as reflux, whereby the low pressure column separates its feeds into bottom stream oxygen products and top stream rich in nitrogen;

g) recovering the bottom stream oxygen product as high purity liquid oxygen; and

h) drawing from a tray or a stage between the two reboilers of the low pressure column, the stream oxygen product as low purity oxygen.

[0060] In the above process, the temperatures and pressures recited for the previous process are also applicable therein.

[0061] As used herein, the term "feed stream" refers to any mixture of gas containing nitrogen and oxygen, such as air or any off-stream gas mixture containing oxygen, nitrogen and other gases. In the present invention, however, it has been found advantageous to use atmospheric air, which has been cleaned and dried, as a feed stream. Further, the present process is of particular advantage when used with any feed stream mixture containing nitrogen, oxygen and argon.

[0062] The present invention also provides an apparatus for simultaneously producing both high and low purity oxygen, which entails a double rectification column having a lower pressure fractionating means with two reboilers therein, and a higher pressure fractionating means, wherein an intermediate outlet is provided between the two reboilers of the lower pressure fractionating means for simultaneously extracting a low-purity oxygen stream and a high-purity liquid oxygen stream.

[0063] In more detail, the apparatus entails a double rectification column having high and low pressure fractionating means with two reboilers in the low pressure fractionating means, and having a first feed stream input means in fluid connection with a first reboiler located at the bottom of the low pressure fractionating means, a second feed stream input means in fluid connection with the bottom of the high pressure fractionating means, and a third feed stream input means in fluid connection with the high pressure column; expanding means in contact with the second and third feed stream input means and being upstream of the double rectification column; conduit means for feeding liquefied feed stream to both high and low pressure fractionating means from the lower reboiler of the low pressure fractionating means; conduit means for feeding part of a nitrogen-rich stream from the upper reboiler of the low pressure fractionating means to the high pressure fractionating means, and conduit means for feeding a remaining part of the nitrogen-rich stream to the top of the low pressure fractionating means; conduit means for feeding an oxygen-rich liquid stream to the low pressure fractionating means; and output means for recovering high-purity oxygen. Such an apparatus is depicted in Figure 2, and has already been described in detail above.

[0064] A further embodiment of the apparatus is provided wherein the low purity oxygen stream is produced in liquid form directly off the low pressure column. This liquid is then pumped to a higher pressure using pumping means and then vaporized and warmed in the main exchanger. At the same time, a high pressure feed stream is condensed in the main exchanger to provide necessary heat for the vaporization of the oxygen stream. Such an apparatus is depicted in Figure 3.

[0065] Additionally, an apparatus is provided wherein the low purity oxygen stream is produced in the liquid form directly off the low pressure column. This liquid is then pumped to a higher pressure using pumping means and then vaporized in a separate exchanger against a condensing feed stream. Such an apparatus is depicted in Figure 4.

Claims

1. Process for simultaneously producing both high and low purity oxygen, using a double distillation column comprising a high pressure column (20) and a low pressure column (21) which comprises :

a) condensing a first compressed and cooled feed stream fraction (106) containing at least nitrogen and oxygen in a first reboiler (24) located at the bottom of the low pressure column (21) ;

b) feeding at least a fraction of the resulting liquefied feed stream (110) to either or both high and low pressure columns (20, 21) as feed ;

c) introducing a second feed stream fraction (107) to the bottom of the high pressure column as gaseous feed, whereby a bottom oxygen-rich liquid stream and an overhead nitrogen-rich gaseous stream are formed ;

d) passing the oxygen-rich liquid stream to the low pressure column as feed ;

e) condensing the nitrogen-rich gaseous stream against a boiling liquid in a second reboiler (23) of the low pressure column, thereby serving as a second reboil for distillation, said second reboiler (23) being positioned above said first reboiler (24) ;

f) returning a portion (115) of the condensed nitrogen-rich stream pressure to the high pressure column (20) as reflux, and passing at least a fraction (116) of the remaining portion of the nitrogen-rich stream to the top of the low pressure column as reflux, whereby the low pressure column separates its feeds into bottom stream oxygen products and top stream rich in nitrogen ; and

g) recovering the bottom stream oxygen product (118) from a first outlet as high purity liquid oxygen,
   characterized in that it comprises :

h) drawing from a tray or a stage between the first and second reboilers (23, 24) of the low pressure column, via a second outlet, the stream oxygen product (119) as low purity oxygen.

2. Process according to Claim 1, wherein the feed stream further contains argon.

3. Process according to Claim 2, wherein the feed stream is atmospheric air.

4. Process according to Claim 2, which further comprises recovering argon by means of an argon sidearm column and withdrawing an argon-rich stream at a tray or a stage between the two oxygen product outlets.

5. Process according to one of Claims 1 to 4, wherein in step a) the first feed stream fraction (106) is compressed to a pressure of about 6 to 50 bar.

6. Process according to Claim 5, wherein the first feed stream fraction (106) is compressed to a pressure of about 10 to 35 bar.

7. Process according to any preceding claim wherein part of a feed stream which constitutes a third feed stream fraction (104, 130) at a higher pressure than that of the first and second stream fractions (106, 107) is cooled and fed to the high pressure column (20).

8. Process according to Claim 7 wherein said third feed stream (104, 130) is condensed by heat exchange with at least one product liquid of the process.

9. Process according to any preceding claim wherein the first feed stream fraction is expanded in an expander (12) prior to condensation.

10. Process according to any preceding claim wherein said first and second feed stream fractions (106, 107) are at substantially the same pressure.

11. Apparatus for simultaneously producing both high and low purity oxygen, which comprises feed stream input means, a double rectification column in fluid connection with said input means having therein a lower pressure fractionating means (21) with first and second reboilers (24, 23) therein, said first reboiler (24) being positioned below said second reboiler (23) and a higher pressure fractionating means (20) wherein an outlet is provided at the bottom of the lower pressure fractionating means (21) for extracting a high-purity liquid oxygen stream, and characterized in that an intermediate outlet is provided between the two reboilers of the lower pressure fractionating means for extracting a low purity oxygen stream.

12. Apparatus according to Claim 11, comprising a first feed stream input means (106) in fluid connection with the first reboiler (24) located at the bottom of the lower pressure fractionating means (21), a second feed stream input means (107) in fluid connection with the bottom of the higher pressure fractionating means (20) and a third feed stream input means (104, 131) in fluid connection with the higher pressure fractionating means (20).

13. Apparatus according to Claims 11 or 12, comprising expanding means (12) in contact or connection with all of said feed stream input means (103, 104, 106, 107, 131) upstream of said double rectification column.

14. Apparatus according to one of Claims 11 to 13, comprising conduit means (111, 112, 113) for feeding at least a fraction of liquefied feed stream from the bottom of the lower pressure fractionating means (21) to either or both of higher or lower pressure fractionating means (21, 20) as feed.

15. Apparatus according to one of Claims 11 to 14, comprising conduit means (115) for feeding a portion of a condensed nitrogen-rich stream for the second reboiler (23) of the lower pressure fractionating means (21) to the higher pressure fractionating means (20) as reflux.

16. Apparatus according to Claim 15, comprising conduit means (116, 117) for feeding the remaining portion of the nitrogen rich stream to the top of the lower pressure fractionating means (21) as reflux.

17. Apparatus according to one of Claims 11 to 16, comprising output means (118) for recovering high-purity liquid oxygen product.

18. Apparatus according to one of Claims 11 to 17, comprising a main feed stream input means (100) feeding said first, second and third feed stream input means and being upstream thereof, said main feed stream input means being in fluid connection with a booster compressor (10) driven by an expander (12).

19. Apparatus according to one of Claims 11 to 18, comprising output means (119) from said lower pressure fractionating means (21) for obtaining said low purity oxygen stream, said output means being in fluid connection with pumping means (140) downstream thereof and heat exchanging means (11) downstream of said pumping means.

20. Apparatus according to one of Claims 11 to 19, comprising output means (119) from said lower pressure fractionating means (21) for obtaining said low purity oxygen stream, said output means (119) being in fluid connection with pumping means (140) downstream thereof and a separate exchanging means (150), other than a main exchanger (11), downstream of said pumping means.

21. Apparatus according to Claim 20 comprising means (130, 131) for sending a feed stream to said double rectification column via said separate exchanging means (150).

22. Apparatus according to one of Claims 11 to 20 comprising an argon sidearm column and means to provide an argon-enriched feed stream to said sidearm column from said lower pressure fractionating means (21).

Ansprüche

1. Verfahren zur gleichzeitigen Herstellung von hochreinem Sauerstoff und niedrig reinem Sauerstoff, mit einer Zweifach-Destillationssäule, die eine Hochdruck-Säule (20) und eine Niederdruck-Säule (21) umfaßt, mit folgenden Schritten

a) Kondensieren einer ersten komprimierten und gekühlten Zustrom-Fraktion (106), die wenigstens Stickstoff und Sauerstoff in einem ersten Verdampfer (24) beinhaltet, wobei der Verdampfer (24) am unteren Teil der Niederdruck-Säule (21) angeordnet ist;

b) Zuführen wenigstens einer Fraktion des resultierenden verflüssigten Zustroms (110) zu einer oder beiden Hochdruck- und Niederdruck-Säulen (20,21) als Einspeisung;

c) Zuführen einer zweiten Zustrom-Fraktion (107) am unteren Teil der Hochdruck-Säule als gasförmige Einspeisung, wobei ein unterer sauerstoffreicher Flüssigkeitsstrom und ein oberer stickstoffreicher Gasstrom gebildet werden;

d) Leiten des sauerstoffreichen Flüssigkeitsstroms als Einspeisung zur Niederdruck-Säule;

e) Kondensieren des stickstoffreichen Gasstroms gegen eine siedende Flüssigkeit in einem zweiten Verdampfer (23) der Niederdruck-Säule, wobei dies als zweites Verdampfen zur Destillation dient und der zweite Verdampfer (23) über dem ersten Verdampfer (24) angeordnet ist;

f) Rückführen eines Teils (115) des kondensierten stickstoffreichen Stromdruckes zur Hochdruck-Säule (20) als Rückstrom und Leiten wenigstens einer Fraktion (116) des restlichen Teils des stickstoffreichen Stroms zu dem oberen Teil der Niederdruck-Säule als Rückstrom, wobei die Niederdruck-Säule ihre Zuströme in einen Bodenstrom von Sauerstoffprodukten und in einen stickstoffreichen Kopfstrom teilt; und

g) Sammeln des Bodenstrom-Sauerstoffproduktes (118) als hochreinen flüssigen Sauerstoff aus einem ersten Auslaß,
gekennzeichnet durch weiterhin

h) Abziehen des Sauerstoffprodukt-Stromes (119) von einem Säulenboden oder einer Stufe zwischen dem ersten und zweiten Verdampfer (23,24) der Niederdruck-Säule über einen zweiten Auslaß als niedrig reinen Sauerstoff.

2. Verfahren gemäß Anspruch 1, wobei der Zustrom weiterhin Argon beinhaltet.

3. Verfahren gemäß Anspruch 2, wobei der Zustrom atmosphärische Luft ist.

4. Verfahren gemäß Anspruch 2, weiterhin umfassend Gewinnen von Argon mittels einer Argon-Seitenarmsäule und Entnehmen eines argonreichen Stroms von einem Säulenboden oder einer Stufe zwischen den beiden Sauerstoffprodukt-Auslässen.

5. Verfahren gemäß einem der Ansprüche 1 bis 4, wobei in Schritt a) die erste Zustrom-Fraktion (106) auf einen Druck von etwa 6 bis 50 bar komprimiert wird.

6. Verfahren gemäß Anspruch 5, wobei die erste Zustrom-Fraktion (106) auf einen Druck von etwa 10 bis 35 bar komprimiert wird.

7. Verfahren gemäß einem der vorstehenden Ansprüche, wobei ein Teil des Zustromes, der eine dritte Zustrom-Fraktion (104,130) mit einem höheren Druck als der von der ersten und zweiten Strom-Fraktion (106,107) bildet, gekühlt und der Hochdruck-Säule (20) zugeführt wird.

8. Verfahren gemäß Anspruch 7, wobei dieser dritte Strom (104,130) durch Wärmeaustausch gegen wenigstens eine Produktflüssigkeit des Verfahrens kondensiert wird.

9. Verfahren gemäß einem der vorstehenden Ansprüche, wobei die erste Zustrom-Fraktion vor der Kondensation in einer Entspannungsvorrichtung (12) entspannt wird.

10. Verfahren gemäß einem der vorstehenden Ansprüche, wobei die erste und die zweite Zustrom-Fraktion (106,107) im wesentlichen unter gleichem Druck stehen.

11. Vorrichtung zur gleichzeitigen Herstellung von hochreinem Sauerstoff und niedrig reinem Sauerstoff mit Zustrom-Eingabe-Mitteln, einer Zweifach-Rektifiziersäule, die in Flüssigkeit leitender Verbindung mit den Eingabemitteln steht, mit Niederdruck-Fraktioniermittel (21) mit erstem und zweitem Verdampfer (24,23), wobei der erste Verdampfer (24) unter dem zweiten Verdampfer (23) angeordnet ist und mit einem Hochdruck-Fraktioniermittel (20), worin ein Auslaß am unteren Teil des Niederdruck-Fraktioniermittels (21) vorgesehen ist zum Extrahieren eines Stromes hochreinen flüssigen Sauerstoffs, und dadurch gekennzeichnet, daß ein Zwischenauslaß zwischen den beiden Verdampfern des Niederdruck-Fraktioniermittels vorgesehen ist zum Extrahieren eines Stromes niedrig reinen Sauerstoffs.

12. Vorrichtung gemäß Anspruch 11, mit einem ersten Zustrom-Eingabemittel (106) in Flüssigkeit leitender Verbindung mit dem ersten Verdampfer (24), der am unteren Teil des Niederdruck-Fraktioniermittels (21) angeordnet ist, mit einem zweiten Zustrom-Eingabemittel (107) in Flüssigkeit leitender Verbindung mit dem unteren Teil des Hochdruck-Fraktioniermittels (20) und einem dritten Zustrom-Eingabemittel (104,131) in Flüssigkeit leitender Verbindung mit dem Hochdruck-Fraktioniermittel (20).

13. Vorrichtung gemäß Anspruch 11 oder 12, mit Expansionsmittel (12), das stromauf der Zweifach-Rektifiziersäule in Kontakt oder Verbindung mit allen Zustrom-Eingabemitteln (103,104,106,107,131) steht.

14. Vorrichtung gemäß einem der Ansprüche 11 bis 13, mit Leitungsmitteln (111,112,113) zum Zuführen wenigstens einer Fraktion des verflüssigten Zustroms von dem unteren Teil des Niederdruck-Fraktioniermittels (21) als Einspeisung zu einer oder beiden der Hochdruck- oder Niederdruck-Fraktioniermittel (21,20).

15. Vorrichtung gemäß einem der Ansprüche 11 bis 14, mit Leitungsmitteln (115) zum Zuführen eines Teils eines kondensierten stickstoffreichen Stromes als Rückfluß vom zweiten Verdampfer (23) vom Niederdruck-Fraktioniermittel (21) zum Hochdruck-Fraktioniermittel (20).

16. Vorrichtung gemäß Anspruch 15, mit Leitungsmitteln (116,117) zum Zuführen des verbleibenden Teils des stickstoffreichen Stromes als Rückfluß an den oberen Teil des Niederdruck-Fraktioniermittels (21).

17. Vorrichtung gemäß einem der Ansprüche 11 bis 16, mit Ausgabemitteln (118) zum Sammeln des hochreinen flüssigen Sauerstoffproduktes.

18. Vorrichtung gemäß einem der Ansprüche 11 bis 17, mit Haupt-Zustrom-Eingabemittel (100) stromauf von und zum Zuführen zu den ersten, zweiten und dritten Zustrom-Eingabemitteln, wobei die Haupt-Zustrom-Eingabemittel in Flüssigkeit leitender Verbindung mit einem Zusatzkompressor (10) stehen, der von einer Expansionsvorrichtung angetrieben wird.

19. Vorrichtung gemäß einem der Ansprüche 11 bis 18, mit Ausgabemitteln (119) an dem Niederdruck-Fraktioniermittel (21) zum Erhalten des Stroms niedrig reinen Sauerstoffs, wobei das Ausgabemittel stromauf von und in Flüssigkeit leitender Verbindung mit Pumpmitteln (140) angeordnet ist, sowie mit Wärmetauschermitteln (11) stromab von besagten Pumpmitteln.

20. Vorrichtung gemäß einem der Ansprüche 11 bis 19, mit Ausgabemitteln (119) an dem Niederdruck-Fraktioniermittel (21) zum Erhalten des Stroms niedrig reinen Sauerstoffs, wobei das Ausgabemittel (119) stromauf von und in Flüssigkeit leitender Verbindung mit dem Pumpmittel (140) angeordnet ist, sowie mit einem separaten Austauschmittel (150), welches verschieden von einem Hauptaustauschmittel (11)stromab des Pumpmittels ist.

21. Vorrichtung gemäß Anspruch 20, mit Mitteln (130,131) zum Abgeben eines Zustromes an die Zweifach-Rektifizier-Säule über das separate Austauschmittel (150).

22. Vorrichtung gemäß einem der Ansprüche 11 bis 20, mit einer Argon-Seitenarm-Säule und Mitteln zum Abgeben eines argonreichen Zustromes an die Seitenarm-Säule von dem Niederdruck-Fraktioniermittel (21).

Revendications

1. Procédé pour la production simultanée d'oxygène à la fois à haute et basse pureté, en utilisant une colonne de distillation double comprenant une colonne haute pression (20) et une colonne basse pression (21) qui comprend:

a) la condensation d'une première fraction de courant d'alimentation comprimée et refroidie (106) contenant au moins de l'azote et de l'oxygène dans un premier rebouilleur (24) situé au bas de la colonne basse pression (21);

b) l'alimentation d'au moins une fraction du courant d'alimentation liquéfié résultant (110) à l'une ou aux deux colonnes haute pression et basse pression (20, 21) en tant que charge d'alimentation;

c) l'introduction d'une deuxième fraction de courant d'alimentation (107) au bas de la colonne haute pression (21) en tant que charge d'alimentation gazeuse, un courant de bas de colonne liquide riche en oxygène et un courant de tête gazeux riche en azote étant ainsi formés;

d) le passage du courant liquide riche en oxygène à la colonne basse pression en tant que charge d'alimentation;

e) la condensation du courant gazeux riche en azote contre un liquide bouillant dans une deuxième rebouilleur (23) de la colonne basse pression, servant ainsi de deuxième rebouillissage en vue de la distillation, ledit deuxième rebouilleur (23) étant placé au-dessus dudit premier rebouilleur (24) ;

f) le retour d'une portion (115) du courant riche en azote condensé à la colonne haute pression (20) en tant que reflux, et le passage d'au moins une fraction (116) de la portion restante du courant riche en azote vers le haut de la colonne basse pression en tant que reflux, la colonne basse pression séparant ainsi ses charges d'alimentation en produits d'oxygène de courant de bas de colonne et en produits de courant de haut de colonne riches en azote; et

g) la récupération du produit d'oxygène de courant de bas de colonne (118) à partir d'une première sortie en tant qu'oxygène liquide à haute pureté,
   caractérisé en ce qu'il comprend:

h) le retrait, à partir d'un plateau ou d'un étage entre les premier et deuxième rebouilleurs (23, 24) de la colonne basse pression, par l'intermédiaire d'une deuxième sortie, du produit d'oxygène de courant (119) en tant qu'oxygène à basse pureté.

2. Procédé selon la revendication 1, caractérisé en ce que le courant d'alimentation contient en plus de l'argon.

3. Procédé selon la revendication 2, caractérisé en ce que le courant d'alimentation est de l'air atmosphérique.

4. Procédé selon la revendication 2, qui comprend en outre la récupération d'argon à l'aide d'une colonne argon de type à bras latéral et le retrait d'un courant riche en argon à un plateau ou à un étage entre les deux sorties de produit d'oxygène.

5. Procédé selon l'une quelconque des revendications 1 à 4, caractérisé en ce que dans l'étape a) la première fraction de courant d'alimentation (106) est comprimée à une pression d'environ 6 à 50 bar.

6. Procédé selon la revendication 5, caractérisé en ce que la première fraction de courant d'alimentation (106) est comprimée à une pression d'environ 10 à 35 bar.

7. Procédé selon l'une quelconque des revendications précédentes, caractérisé en ce qu'une partie d'un courant d'alimentation, qui constitue une troisième fraction de courant d'alimentation (104, 130) à une pression plus élevée que celle de la première fraction de courant (106) et de la deuxième fraction de courant (107), est refroidie et acheminée vers la colonne haute pression (20).

8. Procédé selon la revendication 7, caractérisé en ce que ledit troisième courant d'alimentation (104, 130) est condensé par échange thermique avec au moins un produit liquide du procédé.

9. Procédé selon l'une quelconque des revendications précédentes, caractérisé en ce que la première fraction de courant d'alimentation est détendue dans un dispositif d'expansion (12) avant condensation.

10. Procédé selon l'une quelconque des revendications précédentes, caractérisé en ce que lesdites première et deuxième fractions de courant d'alimentation (106, 107) sont à une pression substantiellement identique.

11. Dispositif pour la production simultanée d'oxygène à la fois à haute et basse pression, qui comprend des moyens d'introduction de courant d'alimentation, une colonne de rectification double en connexion fluide avec lesdits moyens d'introduction ayant en son sein un moyen de fractionnement à pression plus basse (21), avec, en son sein, un premier et un deuxième rebouilleurs (24, 23), ledit premier rebouilleur (24) étant placé en-dessous dudit deuxième rebouilleur (23), et un moyen de fractionnement à pression plus élevée (20), dans lequel une sortie est prévue au bas du moyen de fractionnement à pression plus basse (21) en vue de l'extraction d'un courant d'oxygène liquide à haute pureté, et caractérisé en ce qu'une sortie intermédiaire est prévue entre les deux rebouilleurs du moyen de fractionnement à pression plus basse en vue de l'extraction d'un courant d'oxygène à basse pureté.

12. Dispositif selon la revendication 11, comprenant un premier moyen d'introduction de courant d'alimentation (106) en connexion fluide avec le premier rebouilleur (24) situé au bas du moyen de fractionnement à pression plus basse (21), un deuxième moyen d'introduction de courant d'alimentation (107) en connexion fluide avec le bas du moyen de fractionnement à pression plus élevée (20), et un troisième moyen d'introduction de courant d'alimentation (104, 131) en connexion fluide avec le moyen de fractionnement à pression plus élevée (20).

13. Dispositif selon les revendications 11 ou 12, comprenant un moyen d'expansion (12) en contact ou en connexion avec tous lesdits moyens d'introduction de courant d'alimentation (103, 104, 106, 107, 131) en amont de ladite colonne de rectification double.

14. Dispositif selon l'une des revendications 11 à 13, comprenant des moyens de canalisation (111, 112, 113) pour l'alimentation d'au moins une fraction du courant d'alimentation liquéfié à partir du bas du moyen de fractionnement à pression plus basse (21) vers l'un ou les deux moyens de fractionnement à pression plus basse (21) ou à pression plus élevée (20) en tant que charge d'alimentation.

15. Dispositif selon l'une quelconque des revendications 11 à 14, comprenant des moyens de canalisation (115) pour l'alimentation d'une portion d'un courant riche en azote condensé pour le deuxième rebouilleur (23) du moyen de fractionnement à pression plus basse (21) vers le moyen de fractionnement à pression plus élevée (20) en tant que reflux.

16. Dispositif selon la revendication 15, comprenant des moyens de canalisation (116, 117) pour l'alimentation de la portion restante du courant riche en azote vers le haut du moyen de fractionnement à pression plus basse (21) en tant que reflux.

17. Dispositif selon l'une quelconque des revendications 11 à 16, comprenant un moyen de sortie (118) pour la récupération du produit d'oxygène liquide à haute pureté.

18. Dispositif selon l'une quelconque des revendications 11 à 17, comprenant un moyen principal d'introduction de courant d'alimentation (100) alimentant lesdits premier, deuxième et troisième moyens d'introduction de courant d'alimentation et étant situé en amount de celui-ci, ledit moyen principal d'introduction de courant d'alimentation étant en connexion fluide avec un compresseur d'appoint (10) actionné par un dispositif d'expansion (12).

19. Dispositif selon l'une quelconque des revendications 11 à 18, comprenant un moyen de sortie (119) à partir dudit moyen de fractionnement à pression plus basse (21) pour l'obtention dudit courant d'oxygène à basse pureté, ledit moyen de sortie étant en connexion fluide avec un moyen de pompage (140) en aval de celui-ci, et avec moyen d'échange thermique (11) en aval dudit moyen de pompage.

20. Dispositif selon l'une quelconque des revendications 11 à 19, comprenant un moyen de sortie (119) à partir dudit moyen de fractionnement à pression plus basse (21) pour l'obtention dudit courant d'oxygène à basse pureté, ledit moyen de sortie (119) étant en connexion fluide avec un moyen de pompage (140) en aval de celui-ci, et avec un moyen séparé d'échange (150), différent d'un échangeur principal (11) en aval dudit moyen de pompage.

21. Dispositif selon la revendication 20, comprenant des moyens (130, 131) pour l'envoi d'un courant d'alimentation à ladite colonne de rectification double par l'intermédiaire dudit moyen séparé d'échange (150).

22. Dispositif selon l'une quelconque des revendications 11 à 20, comprenant une colonne argon de type à bras latéral et des moyens pour fournir un courant d'alimentation enrichi en argon à ladite colonne de type à bras latéral à partir dudit moyen de fractionnement à pression plus basse (21).

Drawing