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EP 0 808 379 B1 |
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EUROPEAN PATENT SPECIFICATION |
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Mention of the grant of the patent: |
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20.10.1999 Bulletin 1999/42 |
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Date of filing: 06.02.1996 |
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International application number: |
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PCT/SE9600/143 |
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International publication number: |
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WO 9624/700 (15.08.1996 Gazette 1996/37) |
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METHOD AND DEVICE FOR SEPARATING MERCURY VAPOUR IN CONNECTION WITH CREMATION
VERFAHREN UND VORRICHTUNG ZUR ABSCHEIDUNG VON QUECKSILBERDAMPF IN VERBINDUNG MIT KREMATIONEN
PROCEDE ET DISPOSITIF POUR SEPARER LES VAPEURS DE MERCURE DANS DES OPERATIONS DE CREMATION
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Designated Contracting States: |
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AT DE DK FR GB NL |
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Priority: |
07.02.1995 SE 9500429
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Date of publication of application: |
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26.11.1997 Bulletin 1997/48 |
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Proprietor: Ing. Firma Folke Ericsson |
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753 14 Uppsala (SE) |
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Inventor: |
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- ERICSSON, Folke
S-753 14 Uppsala (SE)
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Representative: Waldinger, Ake |
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Svenska Rotor Maskiner AB
Box 15085 104 65 Stockholm 104 65 Stockholm (SE) |
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References cited: :
WO-A-91/12877 US-A- 2 365 983
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DE-B- 2 117 593
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- PATENT ABSTRACTS OF JAPAN, Vol. 10, No. 185, C-357; & JP,A,61 034 129, (EBARA CORP),
18 February 1986.
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Note: Within nine months from the publication of the mention of the grant of the European
patent, any person may give notice to the European Patent Office of opposition to
the European patent
granted. Notice of opposition shall be filed in a written reasoned statement. It shall
not be deemed to
have been filed until the opposition fee has been paid. (Art. 99(1) European Patent
Convention).
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[0001] The present invention relates to a method to separate mercury vapors from the combustion
gases created during cremation.
[0002] The mercury vapors created during cremation originate from with amalgam performed
teeth repairs. In Sweden, about 70 crematories are inspite of environmental ventures
in this field during several years the largest mercury pollution source in the country.
[0003] Purification plants have been installed in several larger crematories possibly achieving
a purification effect of 90 %. The costs, however, are high and it is considered unreasonable
to provide also smaller crematories with purification plants of this kind inspite
of that the pollution from these will increase.
[0004] The measurments carried out have shown that during a combustion of a known quantity
of mercury only about 35 % of the mercury are possibly separated from the combustion
gases, inspite of that the purification had been perfect. Explanations have involved
that the mercury vapors had to a large extent diffused through the oven walls to the
walls outside. Similar phenomena have been observed in zink ovens, where the zink
vapors had passed through a 40 cm thick oven wall and had condensated on its outside.
Furthermore, it has been stated that the low measurement values could be due to that
the mercury during the measurements during 4 to 5 hours each time could have been
fixed to the oven walls to be blown out through the chimney later on, when no measurements
were performed.
[0005] The object of the present invention is to provide a method and a device of the kind
mentioned in the beginning achieving a better and a safer purification of the flue
gases with costs for the necessary equipment being lower than for said conventional
equipment, thereby enabling installations even in smaller cremation ovens, alternatively
in smaller crematories.
[0006] According to the invention this has been achieved in that a local evacuation of essentially
only the mercury vapors is provided directly on top of the source of a possible mercury
vapor formation, these being thereafter separately purified. Thus, the flue gases
without any mercury vapors can be purified in a usual way without any larger complications,
in spite of a comparatively large flow. Whereas the mercury vapors together with a
smaller amount of flue gases provide a minor flow during only a short period, being
separately evacuated, and possibly being purified very efficiently by means of a process
especially adapted for separating the mercury vapors.
[0007] A device for performing the method of the invention with a cremation taking place
in an oven provided with a channel for conveying the flue gases to a purification
device for these is characterized in that a cover of a heat resistent material is
arranged directly on top of the source of a possible mercury vapor formation, the
cover being by means of a channel connected to an evacuating device to convey the
mercury vapors and an accompanying, possibly little amount of the flue gases to a
purificating device especially designed for separating mercury vapors. This device
is very little stressed as the flow is limited and the evacuating device only needs
to perform when any mercury vapors are formed, which normally occurs only each five
to twelve minutes during a combustion period of about 60 minutes. It is then also
essential that the mercury vapors are taken care of directly when they are formed,
thus preventing any spreading in the oven chamber and they thereby cannot create the
above mentioned inconveniences.
[0008] The flue gases from an outlet from the purificating device especially designed for
separating the mercury vapors may contain other impurities provoking damages when
evacuated into the air, the outlet thus preferably being connected to the channel
for conveying the oven flue gases so that a complete purification is achieved in the
ordinary oven purificating device. The flue gases from this outlet may still contain
some mercury vapor residues not possibly being eliminated, some portion of the flue
gases from this outlet therefore being preferably recirculated in that the outlet
is also connected to the channel for evacuating the mercury vapors from the cover.
[0009] For achieving a possibly maximum evacuation of the mercury vapors and for minimizing
the other flue gas portion not containing any mercury vapors the cover is according
to a preferred embodiment riseably and hingedly suspended and controlled to a lowered
position only during some part of the initial cremating period when the mercury vapors
are formed. Then, a concentrated evacuation is preferably achieved in that the cover
has double walls with the space between the walls connected to the cover evacuation
channel and with its lower part provided with an annular evacuation gap.
[0010] A special complication consists in that some larger soot flakes are formed from the
coffin outer layer during ignition when normally designed coffins are burned, the
layer consisting of a wood imitation of paper glued onto a particle board material.
For preventing these to fasten onto the cover and being sucked into the evacuating
gap and further evacuation ports a fine grating in form of bent fingers is arranged
to extend from the lower edge of the double-walled cover outside wall and at a distance
from the evacuation gap a small distance into the cover up to the cover inside wall.
In this way larger soot flakes are kept away from evacuation gaps and the soot flakes
adhering to the grating are disintegrated by the quickly augmenting temperature and
fall down from the grating, and only a minor portion can in form of small particles
be sucked through the evacuation ports without possibly obstructing them. As a further
precaution a blower device can be connected to the channel from the cover for a momentary
purification of the evacuation ports when initiating the cover evacuation device.
This may be performed before the amalgam has started to disintegrate and before any
mercury vapors are formed, any interference of the mercury vapor evacuation then not
occuring.
[0011] The invention will be explained more in detail in the following in connection with
the attached drawing showing an execution example of a device according to the invention
and in which
figure 1 is a schematic side view of the various device components with a combustion oven
shown in section,
figure 2 is a side view, partly in section of a evacuation cover,
figure 3 is a partial section along line A-A in figure 2 and
figure 4 is a partial section of a detail B in figure 2.
[0012] Figure 1 shows a combustion oven 1 of a conventional design with a channel 2 for
flue gas evacuation from the oven and for conveying these to an after-burner 3 with
nozzles 4 for secondary air injection and an eventually required additional fuel admission.
A flue gas channel 5 leads from the after-burner 3 to a conventional flue-gas purification
device 6 with a blower, a cooler and filters, and from there to a chimney 7.
[0013] In the oven 1 a coffin 8 is placed and at its head end a cover 9 is suspended riseably
and hingedly in a vertical, with the cover connected part of a evacuation channel
10 displaceably suspended in a vertical, with a sealing provided port in the cover
roof. The evacuation channel 10 is bent into a horisontal portion 11 provided with
a suspensding device 12 with a driving unit 14 equipped with a control unit 13. The
evacuation channel portion 11 is connected with one end of a compensating bellows
15, with its other end connected to the inlet of a fixed cooler 16. Its outlet is
connected to a purification device 17, especially designed for separating mercury
both in form of particles and vapors. Thereto a circulation blower 18 is connected
evacuating the gases cleaned in the device 17 by means of a channel 19 and conveying
them to the previously mentioned after-burner 3.
[0014] The flue-gases emanating from the purification device 17 are additionally cleaned
in the after-burner 3 and in the normal oven purification device 6 before they are
emitted to the atmosphere by means of a chimney 7. However, some mercury might still
remain and for minimizing this portion it might be convenient to arrange a channel
20 from the channel 19 to the evacuation channel 10, preferably to the inlet of the
cooler 16 for recirculating some of the gases in the channel 19 through the purification
devices 16, 17 for a renewed gas purification.
[0015] For cooling the evacuation channel 10 nearest to the oven 1 this part of the channel
10 is surrounded by a water cooled primary cooler 21. Furthermore, this part of the
channel 10 is connected to a pressure chamber 22 supplied from a pressurized air source
by means of a valve 23 arranged in the channel 10. The valve 23 is controlled by the
control unit 13 and can briefly close the channel to the evacuation cover 9 from the
channel portion 11 and connect the pressurized air source 22 to the cover 9, its evacuation
edge and other evacuation ports being cleaned by means of a pressurized air pulse.
Thereafter, the valve 23 is reset, thereby disconnecting the pressurized air chamber
22 for a renewed charging, instead connecting the channel portion 11 with the evacuation
cover 9.
[0016] The various operations are controlled by a control unit 13, which before any initiation
of the combustion is actuating the driving device 14 to lift the cover 9. The coffin
with its contents has normally a temperature of about 4°C, any amalgam disintegration
therefore not occuring only minutes later. After 3 to 4 minutes the control unit 13
resets the valve 23 during a few seconds to clean the ports of the cover 9. After
resetting the valve 23 the control unit 13 initiates the driving device 14 and the
circulation blower 18. The cover setting in a vertical direction has been programmed
for various cases and when the combustion has lasted sufficiently long for eliminating
all the amalgam, i.e. after about 12 minutes, the control unit 13 initiates the driving
device 14 to lift the cover 9 and the control unit 13 stops the blower 14, the mercury
separating device then not longer be needed.
[0017] The cover 9 is in accordance with figures 2 to 4 provided with an outside wall 30
and an inside wall 31. The outside wall 30 has on top a port 32, to the edges of which
the evacuation channel 10 is sealingly connected. The inside wall 31 is provided with
small evacuation holes 33. The two wall lower edges form an annular evacuation gap
34, covered by a fine grating in form of bent fingers 35 fastened to the outside wall
lower edge and bent over and with some distance from the gap 34 to the inside of the
inside wall 31, where they are fixed at some distance in from the lower edge. The
evacuation gap achieves an effective mercury vapor evacuation, the vapors being with
a correct lowering of the cover prevented to pass the evacuation gap 34. The previously
mentioned large soot flakes,possibly formed when initiating the combustion, are caught
by the fingers 35, simultaneously acting as a connecting device between the two walls.
[0018] The invention is of course not restricted to the illustrated and described execution
example, but can instead be modified in various ways within the scope the claims.
This refers especially to the operational program and the device 17 especially designed
for separating mercury.
1. A method for separating mercury vapors formed by an amalgam disintegration from the
flue gases created during cremation characterized in that a local evacuation of mainly mercury vapors is achieved directly above the mercury
vapor source, i.e. right above the head end of a coffin or corresponding object, the
mercury vapors thereafter being cleaned, the other portion of flue gases containing
no substantial amount of mercury vapors being separately evacuated and cleaned.
2. A device for performing the method according to claim 1, for a cremation performed
in an oven (1) provided with a channel (2) for conveying the flue gases to a device
(3,6) for their purification, characterized in that a cover (9) of a heat resistant material is provided directly above the mercury
vapor source, i.e. right above the head end of a coffin (8) or corresponding object,
the cover (9) being by means of a separate channel (10) connected with an evacuation
device (18) for conveying the mercury vapors and an accompanying, preferably small
amount of flue gases to a purification device (16,17) especially designed for separating
the mercury.
3. A device according to claim 2, characterized in that an outlet from the purification device (17) especially designed for separating
the mercury, also communicates with the evacuation channel (2) for discharging the
oven flue gases.
4. A device according to claim 2, characterized in that an outlet from the purification device (17) especially designed for separating
the mercury also communicates with the evacuation channel (10) for the mercury vapors
from the cover (9).
5. A device according to any of the claims 1-4, characterized in that the cover (9) is riseably and hingedly suspended and controlled to a lowered
position only during some part of the initial cremating period when the mercury vapors
are formed.
6. A device according to any of claims 2-5, characterized in that the cover (9) has double walls, the space between the walls (30,31) being connected
to the special cover evacuation channel (10) and its lower part provided with an annular
evacuation gap (34).
7. A device according to claim 6, characterized in that a fine grating in form of bent fingers (35) is arranged to extent from the lower
edge of the cover outside wall (30) and at some distance from the evacuation gap (34)
some distance into the cover up to the cover inside wall (31).
8. A device according to claim 6 or 7,characterized in that the cover inside wall (31) is perforated.
9. A device according to any of claims 2-8, characterized in that a blower device (22) for a momentary purification of the cover evacuation gap
(34) and the perforations (33) is connected to the special channel (10) from the cover
(9) and arranged to momentarily perform immediately before each initiation of the
cover evacuation device (18).
1. Verfahren zum Abtrennen von Quecksilberdämpfen, die bei der Zersetzung von Amalgam
entstehen, aus den während einer Einäscherung erzeugten Verbrennungsgasen, dadurch gekennzeichnet, daß eine lokale Evakuierung von hauptsächlich Quecksilberdämpfen unmittelbar oberhalb
der Quecksilberdampfquelle, d. h. genau oberhalb des Kopfendes eines Sarges oder entsprechenden
Gegenstandes durchgeführt wird und die Quecksilberdämpfe anschließend gereinigt werden,
wobei der übrige Teil der Verbrennungsgase, der keine wesentlichen Mengen an Quecksilberdämpfen
enthält, getrennt evakuiert und gereinigt wird.
2. Vorrichtung zur Durchführung des Verfahrens nach Anspruch 1 für eine in einem Ofen
(1) durchgeführte Einäscherung, der mit einem Kanal (2) zum Abführen der Verbrennungsgase
an eine Vorrichtung (3, 6) für deren Reinigung versehen ist, dadurch gekennzeichnet, daß eine Haube (9) aus einem hitzebeständigen Material unmittelbar oberhalb der
Quecksilberdampfquelle, d. h. genau oberhalb des Kopfendes eines Sarges (8) oder eines
entsprechenden Gegenstandes vorgesehen ist und die Haube (9) mittels eines separaten
Kanals (10) mit einer Evakuierungsvorrichtung (18) zum Abführen der Quecksilberdämpfe
und einer begleitenden, vorzugsweise kleinen Menge an Verbrennungsgasen an eine Reinigungsvorrichtung
(16, 17) verbunden ist, die speziell zum Abtrennen des Quecksilbers ausgelegt ist.
3. Vorrichtung nach Anspruch 2, dadurch gekennzeichnet, daß ein Auslaß der speziell zum Abtrennen des Quecksilbers ausgelegten Reinigungsvorrichtung
(17) auch mit dem Evakuierungskanal (2) zum Abziehen der Verbrennungsgase des Ofens
in Verbindung steht.
4. Vorrichtung nach Anspruch 2, dadurch gekennzeichnet, daß ein Auslaß der speziell zum Abtrennen des Quecksilbers ausgelegten Reinigungsvorrichtung
(17) auch mit dem Evakuierungskanal (10) von der Haube (9) für die Quecksilberdämpfe
verbunden ist.
5. Vorrichtung nach einem der Ansprüche 2 bis 4, dadurch gekennzeichnet, daß die Haube (9) anhebbar aufgehängt ist und nur während eines Teils der anfänglichen
Einäscherung, wenn die Quecksilberdämpfe entstehen, auf eine abgesenkte Position eingestellt
ist.
6. Vorrichtung nach einem der Ansprüche 2 bis 5, dadurch gekennzeichnet, daß die Haube (9) eine doppelte Wandung besitzt, wobei der Raum zwischen den Wänden
(30, 31) mit dem besonderen Evakuierungskanal (10) der Haube verbunden und sein unterer
Teil mit einem ringförmigen Evakuierungsspalt (34) versehen ist.
7. Vorrichtung nach Anspruch 6, dadurch gekennzeichnet, daß ein feines Gitter in der Form gebogener Finger (35) angeordnet ist, die sich
von der Unterkante der Außenwand (30) der Haube und in einem bestimmten Abstand von
dem Evakuierungsspalt (34) um einen bestimmten Weg in die Haube bis zu der Innenwand
(31) der Haube erstrecken.
8. Vorrichtung nach Anspruch 6 oder 7, dadurch gekennzeichnet, daß die Innenwand (31) der Haube perforiert ist.
9. Vorrichtung nach einem der Ansprüche 2 bis 8, dadurch gekennzeichnet, daß eine Blaseinrichtung (22) zur augenblicklichen Reinigung des Evakuierungsspaltes
(34) der Haube und der Perforationen (33) an den besonderen Kanal (10) von der Haube
(9) angeschlossen ist, um kurzzeitig unmittelbar vor jeder Auslösung der Evakuierungsvorrichtung
(18) der Haube zu arbeiten.
1. Procédé de séparation de vapeurs de mercure formées par désintégration d'amalgames,
des gaz de fumée dégagés au cours d'une incinération, caractérisé en ce qu'une évacuation
locale constituée principalement de vapeurs de mercure est réalisée directement au-dessus
de la source de vapeurs de mercure, c'est-à-dire juste au-dessus de l'extrémité de
tête d'un cercueil ou d'un objet équivalent, les vapeurs de mercure étant ensuite
épurées, l'autre partie des gaz de fumée qui ne contient pas de quantité importante
de vapeurs de mercure étant évacuée et épurée séparément.
2. Dispositif pour mettre en oeuvre le procédé selon la revendication 1 pour une incinération
effectuée dans un four (1) muni d'une conduite (2) pour acheminer les gaz de fumée
jusqu'à un dispositif (3, 6) pour leur épuration, caractérisé en ce qu'un couvercle
(9) constitué d'un matériau résistant à la chaleur est disposé directement au-dessus
de la source de vapeurs de mercure, c'est-à-dire juste au-dessus de l'extrémité de
tête d'un cercueil (8) ou d'un objet équivalent, le couvercle (9) étant relié, au
moyen d'une conduite séparée (10), à un dispositif d'évacuation (18) pour acheminer
les vapeurs de mercure et une quantité, de préférence faible, de gaz de fumée qui
les accompagne jusqu'à un dispositif d'épuration (16, 17) conçu spécialement pour
séparer le mercure.
3. Dispositif selon la revendication 2, caractérisé en ce qu'une sortie du dispositif
d'épuration (17) spécialement conçu pour séparer le mercure communique également avec
la conduite d'évacuation (2) pour décharger les gaz de fumée du four.
4. Dispositif selon la revendication 2, caractérisé en ce qu'une sortie du dispositif
d'épuration (17) spécialement conçu pour séparer le mercure communique également avec
la conduite d'évacuation (10) pour évacuer les vapeurs de mercure du couvercle (9).
5. Dispositif selon l'une quelconque des revendications 1 à 4, caractérisé en ce que
le couvercle (9) est suspendu de manière articulée et de manière à pouvoir être soulevé,
et est ajusté en position abaissée pendant seulement une certaine partie de la période
initiale d'incinération où sont formées les vapeurs de mercure.
6. Dispositif selon l'une quelconque des revendications 2 à 5, caractérisé en ce que
le couvercle (9) a des doubles parois, l'espace entre les parois (30,31) étant relié
à la conduite spéciale (10) d'évacuation du couvercle et sa partie inférieure étant
munie d'un espacement d'évacuation annulaire (34).
7. Dispositif selon la revendication 6, caractérisé en ce qu'un fin treillis présentant
la forme de doigts repliés (35) est agencé de manière à s'étendre du bord inférieur
de la paroi extérieure (30) du couvercle et à une certaine distance de l'espacement
d'évacuation (34) entre le couvercle et la paroi intérieure (31) du couvercle.
8. Dispositif selon la revendication 6 ou 7, caractérisé en ce que la paroi intérieure
(31) du couvercle est perforée.
9. Dispositif selon l'une quelconque des revendications 2 à 8, caractérisé en ce qu'une
soufflerie (22) pour une épuration momentanée de l'espacement d'évacuation (34) du
couvercle et des perforations (33) est reliée à la conduite spéciale (10) partant
du couvercle (9) et agencée pour fonctionner momentanément immédiatement avant chaque
démarrage du dispositif d'évacuation (18) du couvercle.

