[0001] The present invention is directed to improved migration imaging members. More specifically,
the present invention is directed to migration imaging members with improved optical
contrast density.
[0002] While known apparatus and processes are suitable for their intended purposes, a need
remains for improved migration imaging members. In addition, a need remains for migration
imaging members with improved optical contrast density. Further, there is a need for
migration imaging members wherein the optical density of the D
min areas of the imaged member is decreased without a corresponding decrease in the optical
density of the D
max areas of the imaged member. Additionally, there is a need for migration imaging members
wherein the optical density of the D
min areas of the imaged member with respect to ultraviolet light passing through the
imaging member is decreased without a corresponding decrease in the optical density
of the D
max areas of the imaged member with respect to ultraviolet light passing through the
imaging member.
[0003] It is an object of the present invention to provide migration imaging members with
the above noted advantages.
[0004] These and other objects of the present invention (or specific embodiments thereof)
can be achieved by providing a migration imaging member comprising (a) a substrate,
(b) a softenable layer comprising a softenable material and a photosensitive migration
marking material, and (c) a transparentizing agent which transparentizes migration
marking material in contact therewith contained in at least one layer of the migration
imaging member wherein the transparentizing agent affects the migration marking material
which comes into contact therewith by reducing the optical density of the softenable
layer containing the migration marking material. Another embodiment of the present
invention is directed to a process which comprises (1) providing a migration imaging
member comprising (a) a substrate, (b) a softenable layer comprising a softenable
material and a photosensitive migration marking material, and (c) a transparentizing
agent which transparentizes migration marking material in contact therewith contained
in at least one layer of the migration imaging member; (2) uniformly charging the
imaging member; (3) subsequent to step (2), exposing the charged imaging member to
activating radiation at a wavelength to which the migration marking material is sensitive;
(4) subsequent to step (3), causing the softenable material to soften and enabling
a first portion of the migration marking material to migrate through the softenable
material toward the substrate in an imagewise pattern while a second portion of the
migration marking material remains substantially unmigrated within the softenable
layer, wherein subsequent to migration of the first portion of migration marking material,
either (a) the first portion of migration marking material contacts the transparentizing
agent and the second portion of migration marking material does not contact the transparentizing
agent; or (b) the second portion of migration marking material contacts the transparentizing
agent and the first portion of migration marking material does not contact the transparentizing
agent.
[0005] Other embodiments of the invention are defined in the appended claims.
[0006] The present invention will be described further, by way of examples, with reference
to the accompanying drawings, in which:-
Figure 1 illustrates schematically one migration imaging member suitable for the present
invention, wherein a transparentizing agent is included within one or more layers
of the imaging member;
Figures 2 and 3 illustrate schematically infrared-sensitive migration imaging members
suitable for the present invention, wherein a transparentizing agent is included within
one or more layers of the imaging member; and
Figures 4, 5, 6, 7, 8, 9, and 10 illustrate schematically migration imaging members
suitable for the present invention, wherein a transparentizing agent is present in
a separate transparentizing layer within the imaging member.
[0007] The present invention encompasses migration imaging members containing an agent for
transparentizing migration marking material in at least one layer of the migration
imaging member. The transparentizing agent is a material that affects migration marking
material which comes into contact therewith by reducing the optical density of the
softenable layer containing the migration marking material in said areas. Thus, in
one embodiment of the present invention, when migration marking material migrates
selectively through the softenable layer in imagewise fashion, the migrated marking
material contacts the transparentizing agent while the unmigrated marking material
does not contact the transparentizing agent (or contacts it to a lesser degree than
the migrated marking material contacts it), thereby reducing the optical density of
the softenable layer in areas wherein the migration marking material has migrated
(i.e., in D
min areas). In another embodiment of the present invention, when migration marking material
migrates selectively through the softenable layer in imagewise fashion, the unmigrated
marking material contacts the transparentizing agent while the migrated marking material
does not contact the transparentizing agent (or contacts it to a lesser degree than
the unmigrated marking material contacts it), thereby reducing the optical density
of the softenable layer in areas wherein the migration marking material has not migrated.
[0008] An example of a migration imaging member suitable for the present invention is illustrated
schematically in Figure 1. As illustrated schematically in Figure 1, migration imaging
member 1 comprises a substrate 2, an optional adhesive layer 3 situated on the substrate
2, an optional charge blocking layer 4 situated on optional adhesive layer 3, an optional
charge transport layer 5 situated on optional charge blocking layer 4, and a softenable
layer 6 situated on optional charge transport layer 5, said softenable layer 6 comprising
softenable material 7, migration marking material 8 situated at or near the surface
of the layer spaced from the substrate, and optional charge transport material 9 dispersed
throughout softenable material 7. Optional overcoating layer 10 is situated on the
surface of softenable layer 6 spaced from the substrate 2. Any or all of the optional
layers and materials can be absent from the imaging member. In addition, any of the
optional layers present need not be in the order shown, but can be in any suitable
arrangement. The migration imaging member can be in any suitable configuration, such
as a web, a foil, a laminate, a strip, a sheet, a coil, a cylinder, a drum, an endless
belt, an endless mobius strip, a circular disc, or any other suitable form.
[0009] The substrate can be either electrically conductive or electrically insulating. When
conductive, the substrate can be opaque, translucent, semitransparent, or transparent,
and can be of any suitable conductive material, including copper, brass, nickel, zinc,
chromium, stainless steel, conductive plastics and rubbers, aluminum, semitransparent
aluminum, steel, cadmium, silver, gold, paper rendered conductive by the inclusion
of a suitable material therein or through conditioning in a humid atmosphere to ensure
the presence of sufficient water content to render the material conductive, indium,
tin, metal oxides, including tin oxide and indium tin oxide, and the like. When insulative,
the substrate can be opaque, translucent, semitransparent, or transparent, and can
be of any suitable insulative material, such as paper, glass, plastic, polyesters
such as Mylar® (available from Du Pont) or Melinex® 442 (available from ICI Americas,
Inc.), and the like. In addition, the substrate can comprise an insulative layer with
a conductive coating, such as vacuum-deposited metallized plastic, such as titanized
or aluminized Mylar® polyester, wherein the metallized surface is in contact with
the softenable layer or any other layer situated between the substrate and the softenable
layer. The substrate has any effective thickness, typically from about 6 to about
250 microns, and preferably from about 50 to about 200 microns, although the thickness
can be outside these ranges.
[0010] The softenable layer can comprise one or more layers of softenable materials, which
can be any suitable material, typically a plastic or thermoplastic material which
is soluble in a solvent or softenable, for example, in a solvent liquid, solvent vapor,
heat, or any combinations thereof. When the softenable layer is to be softened or
dissolved either during or after imaging, it should be soluble in a solvent that does
not attack the migration marking material. By softenable is meant any material that
can be rendered by a development step as described herein permeable to migration material
migrating through its bulk. This permeability typically is achieved by a development
step entailing dissolving, melting, or softening by contact with heat, vapors, partial
solvents, as well as combinations thereof. Examples of suitable softenable materials
include styrene-acrylic copolymers, such as styrene-hexyl methacrylate copolymers,
styrene acrylate copolymers, styrene butylmethacrylate copolymers, styrene butylacrylate
ethylacrylate copolymers, styrene ethylacrylate acrylic acid copolymers, and the like,
polystyrenes, including polyalphamethyl styrene, alkyd substituted polystyrenes, styrene-olefin
copolymers, styrene-vinyltoluene copolymers, polyesters, polyurethanes, polycarbonates,
polyterpenes, silicone elastomers, mixtures thereof, copolymers thereof, and the like,
as well as any other suitable materials as disclosed, for example, in U.S. Patent
3,975,195 and other U.S. patents directed to migration imaging members. The softenable
layer can be of any effective thickness, typically from about 1 to about 30 microns,
preferably from about 2 to about 25 microns, and more preferably from about 2 to about
10 microns, although the thickness can be outside these ranges. The softenable layer
can be applied to the conductive layer by any suitable coating process. Typical coating
processes include draw bar coating, spray coating, extrusion, dip coating, gravure
roll coating, wire-wound rod coating, air knife coating and the like.
[0011] The softenable layer also contains migration marking material. The migration marking
material can be electrically photosensitive, photoconductive, or of any other suitable
combination of materials, or possess any other desired physical property and still
be suitable for use in the migration imaging members of the present invention. The
migration marking materials preferably are particulate, wherein the particles are
closely spaced from each other. Preferred migration marking materials generally are
spherical in shape and submicron in size. The migration marking material generally
is capable of substantial photodischarge upon electrostatic charging and exposure
to activating radiation and is substantially absorbing and opaque to activating radiation
in the spectral region where the photosensitive migration marking particles photogenerate
charges. The migration marking material is generally present as a thin layer or monolayer
of particles situated at or near the surface of the softenable layer spaced from the
conductive layer. When present as particles, the particles of migration marking material
preferably have an average diameter of up to 2 microns, and more preferably of from
about 0.1 to about 1 micron. The layer of migration marking particles is situated
at or near that surface of the softenable layer spaced from or most distant from the
conductive layer. Preferably, the particles are situated at a distance of from about
0.01 to 0.1 micron from the layer surface, and more preferably from about 0.02 to
0.08 micron from the layer surface. Preferably, the particles are situated at a distance
of from about 0.005 to about 0.2 micron from each other, and more preferably at a
distance of from about 0.05 to about 0.1 micron from each other, the distance being
measured between the closest edges of the particles, i.e. from outer diameter to outer
diameter. The migration marking material contiguous to the outer surface of the softenable
layer is present in any effective amount, preferably from about 5 to about 80 percent
by total weight of the softenable layer, and more preferably from about 25 to about
80 percent by total weight of the softenable layer, although the amount can be outside
of this range.
[0012] Examples of suitable migration marking materials include selenium, alloys of selenium
with alloying components such as tellurium, arsenic, antimony, thallium, bismuth,
or mixtures thereof, selenium and alloys of selenium doped with halogens, as disclosed
in, for example, U.S. Patent 3,312,548, and the like, phthalocyanines, and any other
suitable materials as disclosed, for example, in U.S. Patent 3,975,195 directed to
migration imaging members.
[0013] The migration imaging members can optionally contain a charge transport material.
The charge transport material can be any suitable charge transport material either
capable of acting as a softenable layer material or capable of being dissolved or
dispersed on a molecular scale in the softenable layer material. When a charge transport
material is also contained in another layer in the imaging member, preferably there
is continuous transport of charge through the entire film structure. The charge transport
material is defined as a material which is capable of improving the charge injection
process for one sign of charge from the migration marking material into the softenable
layer and also of transporting that charge through the softenable layer. The charge
transport material can be either a hole transport material (transports positive charges)
or an electron transport material (transports negative charges). The sign of the charge
used to sensitize the migration imaging member during imaging can be of either polarity.
Charge transporting materials are well known in the art. Typical charge transporting
materials include the following:
[0014] Diamine transport molecules of the type described in U.S. Patent 4,306,008, U.S.
Patent 4,304,829, U.S. Patent 4,233,384, U.S. Patent 4,115,116, U.S. Patent 4,299,897,
and U.S. Patent 4,081,274. Typical diamine transport molecules include N,N'-diphenyl-N,N'-bis(3"-methylphenyl)-(1,1'-biphenyl)-4,4'-diamine,
N,N'-diphenyl-N,N'-bis(4-methylphenyl)-(1,1'-biphenyl)-4,4'-diamine, N,N'-diphenyl-N,N'-bis(2-methylphenyl)-(1,1'-biphenyl)-4,4'-diamine,
N,N'-diphenyl-N,N'-bis(3-ethylphenyl)-(1,1'-biphenyl)-4,4'-diamine, N,N'-diphenyl-N,N'-bis(4-ethylphenyl)-(1,1'-biphenyl)-4,4'-diamine,
N,N'-diphenyl-N,N'-bis(4-n-butylphenyl)-(1,1'-biphenyl)-4,4'-diamine, N,N'-diphenyl-N,N'-bis(3-chlorophenyl)-[1,1'-biphenyl]-4,4'-diamine,
N,N'-diphenyl-N,N'-bis(4-chlorophenyl)-[1,1'-biphenyl]-4,4'-diamine, N,N'-diphenyl-N,N'-bis(phenylmethyl)-[1,1'-biphenyl]-4,4'-diamine,
N,N,N',N'-tetraphenyl-[2,2'-dimethyl-1,1'-biphenyl]-4,4'-diamine, N,N,N',N'-tetra-(4-methylphenyl)-[2,2'-dimethyl-1,1'-biphenyl]-4,4'-diamine,
N,N'-diphenyl-N,N'-bis(4-methylphenyl)-[2,2'-dimethyl-1,1'-biphenyl]-4,4'-diamine,
N,N'-diphenyl-N,N'-bis(2-methylphenyl)-[2,2'-dimethyl-1,1'-biphenyl]-4,4'- diamine,
N,N'-diphenyl-N,N'-bis(3-methylphenyl)-[2,2'-dimethyl-1,1'-biphenyl]-4,4'-diamine,
N,N'-diphenyl-N,N'-bis(3-methylphenyl)-pyrenyl-1,6-diamine, and the like.
[0015] Pyrazoline transport molecules as disclosed in U.S. Patent 4,315,982, U.S. Patent
4,278,746, and U.S. Patent 3,837,851. Typical pyrazoline transport molecules include
1-[lepidyl-(2)]-3-(p-diethylaminophenyl)-5-(p-diethylaminophenyl)pyrazoline, 1-[quinolyl-(2)]-3-(p-diethylaminophenyl)-5-(p-diethylaminophenyl)pyrazoline,
1-[pyridyl-(2)]-3-(p-diethylaminostyryl)-5-(p-diethylaminophenyl)pyrazoline, 1-[6-methoxypyridyl-(2)]-3-(p-diethylaminostyryl)-5-(p-diethylaminophenyl)
pyrazoline, 1-phenyl-3-[p-dimethylaminostyryl]-5-(p-dimethylaminostyryl)pyrazoline,
1-phenyl-3-[p-diethylaminostyryl]-5-(p-diethylaminostyryl)pyrazoline, and the like.
[0016] Substituted fluorene charge transport molecules as described in U.S. Patent 4,245,021.
Typical fluorene charge transport molecules include 9-(4'-dimethylaminobenzylidene)fluorene,
9-(4'-methoxybenzylidene)fluorene, 9-(2',4'-dimethoxybenzylidene)fluorene, 2-nitro-9-benzylidenefluorene,2-nitro-9-(4'-diethylaminobenzylidene)fluorene,
and the like.
[0017] Oxadiazole transport molecules such as 2,5-bis(4-diethylaminophenyl)-1,3,4-oxadiazole,
pyrazoline, imidazole, triazole, and the like. Other typical oxadiazole transport
molecules are described, for example, in German Patent 1,058,836, German Patent 1,060,260,
and German Patent 1,120,875.
[0018] Hydrazone transport molecules, such as p-diethylamino benzaldehyde(diphenylhydrazone),
o-ethoxy-p-diethylaminobenzaldehyde-(diphenylhydrazone), o-methyl-p-diethylaminobenzaldehyde-(diphenylhydrazone),
o-methyl-p-dimethylaminobenzaldehyde-(diphenylhydrazone), 1-naphthalenecarbaldehyde
1-methyl-1-phenylhydrazone, 1-naphthalenecarbaldehyde 1,1-phenylhydrazone, 4-methoxynaphthlene-1-carbaldeyde
1-methyl-1-phenylhydrazone, and the like. Other typical hydrazone transport molecules
are described, for example in U.S. Patent 4,150,987, U.S. Patent 4,385,106, U.S. Patent
4,338,388, and U.S. Patent 4,387,147.
[0019] Carbazole phenyl hydrazone transport molecules such as 9-methylcarbazole-3-carbaldehyde-1,1-diphenylhydrazone,
9-ethylcarbazole-3-carbaldehyde-1-methyl-1-phenylhydrazone, 9-ethylcarbazole-3-carbaldehyde-1-ethyl-1-phenylhydrazone,
9-ethylcarbazole-3-carbaldehyde-1-ethyl-1-benzyl-1-phenylhydrazone, 9-ethylcarbazole-3-carbaldehyde-1,1-diphenylhydrazone,
and the like. Other typical carbazole phenyl hydrazone transport molecules are described,
for example, in U.S. Patent 4,256,821 and U.S. Patent 4,297,426.
[0020] Vinyl-aromatic polymers such as polyvinyl anthracene, polyacenaphthylene; formaldehyde
condensation products with various aromatics such as condensates of formaldehyde and
3-bromopyrene; 2,4,7-trinitrofluorenone, and 3,6-dinitro-N-t-butylnaphthalimide as
described, for example, in U.S. Patent 3,972,717.
[0021] Oxadiazole derivatives such as 2,5-bis-(p-diethylaminophenyl)-oxadiazole-1,3,4 described
in U.S. Patent 3,895,944.
[0022] Tri-substituted methanes such as alkyl-bis(N,N-dialkylaminoaryl)methane, cycloalkyl-bis(N,N-dialkylaminoaryl)methane,
and cycloalkenyl-bis(N,N-dialkylaminoaryl)methane as described in U.S. Patent 3,820,989.
[0023] 9-Fluorenylidene methane derivatives having the formula

wherein X and Y are cyano groups or alkoxycarbonyl groups; A, B, and W are electron
withdrawing groups independently selected from the group consisting of acyl, alkoxycarbonyl,
nitro, alkylaminocarbonyl, and derivatives thereof; m is a number of from 0 to 2;
and n is the number 0 or 1 as described in U.S. Patent 4,474,865. Typical 9-fluorenylidene
methane derivatives encompassed by the above formula include (4-n-butoxycarbonyl-9-fluorenylidene)malonontrile,
(4-phenethoxycarbonyl-9-fluorenylidene)malonontrile, (4-carbitoxy-9-fluorenylidene)malonontrile,
(4-n-butoxycarbonyl-2,7-dinitro-9-fluorenylidene)malonate, and the like.
[0024] Other charge transport materials include poly-1-vinylpyrene, poly-9-vinylanthracene,
poly-9-(4-pentenyl)-carbazole, poly-9-(5-hexyl)-carbazole, polymethylene pyrene, poly-1-(pyrenyl)-butadiene,
polymers such as alkyl, nitro, amino, halogen, and hydroxy substitute polymers such
as poly-3-amino carbazole, 1,3-dibromo-poly-N-vinyl carbazole, 3,6-dibromo-poly-N-vinyl
carbazole, and numerous other transparent organic polymeric or non-polymeric transport
materials as described in U.S. Patent 3,870,516. Also suitable as charge transport
materials are phthalic anhydride, tetrachlorophthalic anhydride, benzil, mellitic
anhydride, S-tricyanobenzene, picryl chloride, 2,4-dinitrochlorobenzene, 2,4-dinitrobromobenzene,
4-nitrobiphenyl, 4,4-2,4,6-trinitroanisole, trichlorotrinitrobenzene, trinitro-O-toluene,
4,6-dichloro-1,3-dinitrobenzene, 4,6-dibromo-1,3-dinitrobenzene, P-dinitrobenzene,
chloranil, bromanil, and mixtures thereof, 2,4,7-trinitro-9-fluorenone, 2,4,5,7-tetranitrofluorenone,
trinitroanthracene, dinitroacridene, tetracyanopyrene, dinitroanthraquinone, polymers
having aromatic or heterocyclic groups with more than one strongly electron withdrawing
substituent such as nitro, sulfonate, carboxyl, cyano, or the like, including polyesters,
polysiloxanes, polyamides, polyurethanes, and epoxies, as well as block, graft, or
random copolymers containing the aromatic moiety, and the like, as well as mixtures
thereof, as described in U.S. Patent 4,081,274.
[0025] Also suitable are charge transport materials such as triarylamines, including tritolyl
amine, of the formula

and the like, as disclosed in, for example, U.S. Patent 3,240,597 and U.S. Patent
3,180,730, and substituted diarylmethane and triarylmethane compounds, including bis-(4-diethylamino-2-methylphenyl)phenylmethane,
of the formula

and the like, as disclosed in, for example, U.S. Patent 4,082,551, U.S. Patent 3,755,310,
U.S. Patent 3,647,431, British Patent 984,965, British Patent 980,879, and British
Patent 1,141,666.
[0026] When the charge transport molecules are combined with an insulating binder to form
the softenable layer, the amount of charge transport molecule which is used can vary
depending upon the particular charge transport material and its compatibility (e.g.
solubility) in the continuous insulating film forming binder phase of the softenable
matrix layer and the like. Satisfactory results have been obtained using between about
5 percent to about 50 percent by weight charge transport molecule based on the total
weight of the softenable layer. A particularly preferred charge transport molecule
is one having the general formula

wherein X, Y and Z are selected from the group consisting of hydrogen, an alkyl group
having from 1 to about 20 carbon atoms and chlorine, and at least one of X, Y and
Z is independently selected to be an alkyl group having from 1 to about 20 carbon
atoms or chlorine. If Y and Z are hydrogen, the compound can be named N,N'-diphenyl-N,N'-bis(alkylphenyl)-[1,1'-biphenyl]-4,4'-diamine
wherein the alkyl is, for example, methyl, ethyl, propyl, n-butyl, or the like, or
the compound can be N,N'-diphenyl-N,N'-bis(chlorophenyl)-[1,1'-biphenyl]-4,4'-diamine.
Results can be obtained when the softenable layer contains between about 8 percent
to about 40 percent by weight of these diamine compounds based on the total weight
of the softenable layer. Optimum results are achieved when the softenable layer contains
between about 16 percent to about 32 percent by weight of N,N'-diphenyl-N,N'-bis(3''-methylphenyl)-(1,1'-biphenyl)-4,4'-diamine
based on the total weight of the softenable layer.
[0027] The charge transport material is present in the softenable material in any effective
amount, typically from about 5 to about 50 percent by weight and preferably from about
8 to about 40 percent by weight, although the amount can be outside these ranges.
Alternatively, the softenable layer can employ the charge transport material as the
softenable material if the charge transport material possesses the necessary film-forming
characteristics and otherwise functions as a softenable material. The charge transport
material can be incorporated into the softenable layer by any suitable technique.
For example, it can be mixed with the softenable layer components by dissolution in
a common solvent. If desired, a mixture of solvents for the charge transport material
and the softenable layer material can be employed to facilitate mixing and coating.
The charge transport molecule and softenable layer mixture can be applied to the substrate
by any conventional coating process. Typical coating processes include draw bar coating,
spray coating, extrusion, dip coating, gravure roll coating, wire-wound rod coating,
air knife coating, and the like.
[0028] The optional adhesive layer can include any suitable adhesive material. Typical adhesive
materials include copolymers of styrene and an acrylate, polyester resin such as DuPont
49000 (available from E.I. duPont de Nemours Company), copolymer of acrylonitrile
and vinylidene chloride, polyvinyl acetate, polyvinyl butyral and the like and mixtures
thereof. The adhesive layer can have any thickness, typically from about 0.05 to about
1 micron, although the thickness can be outside of this range. When an adhesive layer
is employed, it preferably forms a uniform and continuous layer having a thickness
of about 0.5 micron or less to ensure satisfactory discharge during the imaging process.
It can also optionally include charge transport molecules.
[0029] The optional charge transport layer can comprise any suitable film forming binder
material. Typical film forming binder materials include styrene acrylate copolymers,
polycarbonates, co-polycarbonates, polyesters, co-polyesters, polyurethanes, polyvinyl
acetate, polyvinyl butyral, polystyrenes, alkyd substituted polystyrenes, styrene-olefin
copolymers, styrene-co-n-hexylmethacrylate, an 80/20 mole percent copolymer of styrene
and hexylmethacrylate having an intrinsic viscosity of 0.179 dl/gm; other copolymers
of styrene and hexylmethacrylate, styrene-vinyltoluene copolymers, polyalpha-methylstyrene,
mixtures thereof, and copolymers thereof. The above group of materials is not intended
to be limiting, but merely illustrative of materials suitable as film forming binder
materials in the optional charge transport layer. The film forming binder material
typically is substantially electrically insulating and does not adversely chemically
react during the imaging process. Although the optional charge transport layer has
been described as coated on a substrate, in some embodiments, the charge transport
layer itself can have sufficient strength and integrity to be substantially self supporting
and can, if desired, be brought into contact with a suitable conductive substrate
during the imaging process. As is well known in the art, a uniform deposit of electrostatic
charge of suitable polarity can be substituted for a conductive layer. Alternatively,
a uniform deposit of electrostatic charge of suitable polarity on the exposed surface
of the charge transport spacing layer can be substituted for a conductive layer to
facilitate the application of electrical migration forces to the migration layer.
This technique of "double charging" is well known in the art. The charge transport
layer is of any effective thickness, typically from about 1 to about 25 microns, and
preferably from about 2 to about 20 microns, although the thickness can be outside
these ranges.
[0030] Charge transport molecules suitable for the charge transport layer are described
in detail hereinabove. The specific charge transport molecule utilized in the charge
transport layer of any given imaging member can be identical to or different from
the charge transport molecule employed in the adjacent softenable layer. Similarly,
the concentration of the charge transport molecule utilized in the charge transport
spacing layer of any given imaging member can be identical to or different from the
concentration of charge transport molecule employed in the adjacent softenable layer.
When the charge transport material and film forming binder are combined to form the
charge transport spacing layer, the amount of charge transport material used can vary
depending upon the particular charge transport material and its compatibility (e.g.
solubility) in the continuous insulating film forming binder. Satisfactory results
have been obtained using between about 5 percent and about 50 percent based on the
total weight of the optional charge transport spacing layer, although the amount can
be outside this range. The charge transport material can be incorporated into the
charge transport layer by techniques similar to those employed for the softenable
layer.
[0031] The optional charge blocking layer can be of various suitable materials, provided
that the objectives of the present invention are achieved, including aluminum oxide,
polyvinyl butyral, silane and the like, as well as mixtures thereof. This layer, which
is generally applied by known coating techniques, is of any effective thickness, typically
from about 0.05 to about 0.5 micron, and preferably from about 0.05 to about 0.1 micron.
Typical coating processes include draw bar coating, spray coating, extrusion, dip
coating, gravure roll coating, wire-wound rod coating, air knife coating and the like.
[0032] The optional overcoating layer can be substantially electrically insulating, or have
any other suitable properties. The overcoating preferably is substantially transparent,
at least in the spectral region where electromagnetic radiation is used for imagewise
exposure step in the imaging process. The overcoating layer is continuous and preferably
of a thickness up to about 1 to 2 microns. More preferably, the overcoating has a
thickness of between about 0.1 and about 0.5 micron to minimize residual charge buildup.
Overcoating layers greater than about 1 to 2 microns thick can also be used. Typical
overcoating materials include acrylic-styrene copolymers, methacrylate polymers, methacrylate
copolymers, styrene-butylmethacrylate copolymers, butylmethacrylate resins, vinylchloride
copolymers, fluorinated homo or copolymers, high molecular weight polyvinyl acetate,
organosilicon polymers and copolymers, polyesters, polycarbonates, polyamides, polyvinyl
toluene and the like. The overcoating layer generally protects the softenable layer
to provide greater resistance to the adverse effects of abrasion during handling and
imaging. The overcoating layer preferably adheres strongly to the softenable layer
to minimize damage. The overcoating layer can also have abhesive properties at its
outer surface which provide improved resistance to toner filming during toning, transfer,
and/or cleaning. The abhesive properties can be inherent in the overcoating layer
or can be imparted to the overcoating layer by incorporation of another layer or component
of abhesive material. These abhesive materials should not degrade the film forming
components of the overcoating and preferably have a surface energy of less than about
20 ergs/cm
2. Typical abhesive materials include fatty acids, salts and esters, fluorocarbons,
silicones, and the like. The coatings can be applied by any suitable technique such
as draw bar, spray, dip, melt, extrusion or gravure coating. It will be appreciated
that these overcoating layers protect the imaging member before imaging, during imaging,
after the members have been imaged.
[0033] As illustrated schematically in Figure 2, migration imaging member 11 comprises in
the order shown a substrate 12, an optional adhesive layer 13 situated on substrate
12, an optional charge blocking layer 14 situated on optional adhesive layer 13, an
optional charge transport layer 15 situated on optional charge blocking layer 14,
a softenable layer 16 situated on optional charge transport layer 15, said softenable
layer 16 comprising softenable material 17, charge transport material 18, and migration
marking material 19 situated at or near the surface of the layer spaced from the substrate,
and an infrared or red light radiation sensitive layer 20 situated on softenable layer
16 comprising infrared or red light radiation sensitive pigment particles 21 optionally
dispersed in polymeric binder 22. Alternatively (not shown), infrared or red light
radiation sensitive layer 20 can comprise infrared or red light radiation sensitive
pigment particles 21 directly deposited as a layer by, for example, vacuum evaporation
techniques or other coating methods. Optional overcoating layer 23 is situated on
the surface of imaging member 11 spaced from the substrate 12.
[0034] As illustrated schematically in Figure 3, migration imaging member 24 comprises in
the order shown a substrate 25, an optional adhesive layer 26 situated on substrate
25, an optional charge blocking layer 27 situated on optional adhesive layer 26, an
infrared or red light radiation sensitive layer 28 situated on optional charge blocking
layer 27 comprising infrared or red light radiation sensitive pigment particles 29
optionally dispersed in polymeric binder 30, an optional charge transport layer 31
situated on infrared or red light radiation sensitive layer 28, and a softenable layer
32 situated on optional charge transport layer 31, said softenable layer 32 comprising
softenable material 33, charge transport material 34, and migration marking material
35 situated at or near the surface of the layer spaced from the substrate. Optional
overcoating layer 36 is situated on the surface of imaging member 24 spaced from the
substrate 25.
[0035] The infrared or red light sensitive layer generally comprises a pigment sensitive
to infrared and/or red light radiation. While the infrared or red light sensitive
pigment may exhibit some photosensitivity in the wavelength to which the migration
marking material is sensitive, it is preferred that photosensitivity in this wavelength
range be minimized so that the migration marking material and the infrared or red
light sensitive pigment exhibit absorption peaks in distinct, different wavelength
regions. This pigment can be deposited as the sole or major component of the infrared
or red light sensitive layer by any suitable technique, such as vacuum evaporation
or the like. An infrared or red light sensitive layer of this type can be formed by
placing the pigment and the imaging member comprising the substrate and any previously
coated layers into an evacuated chamber, followed by heating the infrared or red light
sensitive pigment to the point of sublimation. The sublimed material recondenses to
form a solid film on the imaging member. Alternatively, the infrared or red light
sensitive pigment can be dispersed in a polymeric binder and the dispersion coated
onto the imaging member to form a layer. Examples of suitable red light sensitive
pigments include perylene pigments such as benzimidazole perylene, dibromoanthranthrone,
crystalline trigonal selenium, beta-metal free phthalocyanine, azo pigments, and the
like, as well as mixtures thereof. Examples of suitable infrared sensitive pigments
include X-metal free phthalocyanine, metal phthalocyanines such as vanadyl phthalocyanine,
chloroindium phthalocyanine, titanyl phthalocyanine, chloroaluminum phthalocyanine,
copper phthalocyanine, magnesium phthalocyanine, and the like, squaraines, such as
hydroxy squaraine, and the like as well as mixtures thereof. Examples of suitable
optional polymeric binder materials include polystyrene, styrene-acrylic copolymers,
such as styrene-hexylmethacrylate copolymers, styrene-vinyl toluene copolymers, polyesters,
such as PE-200, available from Goodyear, polyurethanes, polyvinylcarbazoles, epoxy
resins, phenoxy resins, polyamide resins, polycarbonates, polyterpenes, silicone elastomers,
polyvinylalcohols, such as Gelvatol 20-90, 9000, 20-60, 6000, 20-30, 3000, 40-20,
40-10, 26-90, and 30-30, available from Monsanto Plastics and Resins Co., St. Louis,
MO, polyvinylformals, such as Formvar 12/85, 5/95E, 6/95E, 7/95E, and 15/95E, available
from Monsanto Plastics and Resins Co., St. Louis, MO, polyvinylbutyrals, such as Butvar
B-72, B-74, B-73, B-76, B-79, B-90, and B-98, available from Monsanto Plastics and
Resins Co., St. Louis, MO, Zeneca resin A622, available from Zeneca Colours, Wilmington,
DE, and the like as well as mixtures thereof. When the infrared or red light sensitive
layer comprises both a polymeric binder and the pigment, the layer typically comprises
the binder in an amount of from about 5 to about 95 percent by weight and the pigment
in an amount of from about 5 to about 95 percent by weight although the relative amounts
can be outside this range. Preferably, the infrared or red light sensitive layer comprises
the binder in an amount of from about 40 to about 90 percent by weight and the pigment
in an amount of from about 10 to about 60 percent by weight. Optionally, the infrared
sensitive layer can contain a charge transport material as described herein when a
binder is present; when present, the charge transport material is generally contained
in this layer in an amount of from about 5 to about 30 percent by weight of the layer.
The optional charge transport material can be incorporated into the infrared or red
light radiation sensitive layer by any suitable technique. For example, it can be
mixed with the infrared or red light radiation sensitive layer components by dissolution
in a common solvent. If desired, a mixture of solvents for the charge transport material
and the infrared or red light sensitive layer material can be employed to facilitate
mixing and coating. The infrared or red light radiation sensitive layer mixture can
be applied to the substrate by any conventional coating process. Typical coating processes
include draw bar coating, spray coating, extrusion, dip coating, gravure roll coating,
wire-wound rod coating, air knife coating, and the like. An infrared or red light
sensitive layer wherein the pigment is present in a binder can be prepared by dissolving
the polymer binder in a suitable solvent, dispersing the pigment in the solution by
ball milling, coating the dispersion onto the imaging member comprising the substrate
and any previously coated layers, and evaporating the solvent to form a solid film.
When the infrared or red light sensitive layer is coated directly onto the softenable
layer containing migration marking material, preferably the selected solvent is capable
of dissolving the polymeric binder for the infrared or red sensitive layer but does
not dissolve the softenable polymer in the layer containing the migration marking
material. One example of a suitable solvent is isobutanol with a polyvinyl butyral
binder in the infrared or red sensitive layer and a styrene/ethyl acrylate/acrylic
acid terpolymer softenable material in the layer containing migration marking material.
The infrared or red light sensitive layer can be of any effective thickness. Typical
thicknesses for infrared or red light sensitive layers comprising a pigment and a
binder are from about 0.05 to about 2 microns, and preferably from about 0.1 to about
1.5 microns, although the thickness can be outside these ranges. Typical thicknesses
for infrared or red light sensitive layers consisting of a vacuum-deposited layer
of pigment are from about 200 to about 2,000 Angstroms, and preferably from about
300 to about 1,000 Angstroms, although the thickness can be outside these ranges.
[0036] The transparentizing agent can be contained in any of the migration imaging member
layers so that upon migration of the migration marking material through the softenable
layer, either the migrated particles or the unmigrated particles are selectively transparentized
by the transparentizing agent. For example, in the embodiment illustrated in Figure
1, when the optional adhesive layer 3, optional charge blocking layer 4, and optional
charge transport layer 5 are all absent, the transparentizing agent can be contained
in part or all of the substrate layer 2. Upon migration of the migration marking material
8 through the softenable layer 6, migrated particles contact the transparentizing
agent in substrate 2 and become transparentized, thereby reducing the D
min value of the imaging member subsequent to development. When one or more of the optional
layers is present, the transparentizing agent can be present in one or more of these
layers so that upon migration of the migration marking material 8 through the softenable
layer 6, migrated particles contact the transparentizing agent in one or more of the
optional layers and become transparentized, thereby reducing the D
min value of the imaging member subsequent to development. Further, in the embodiment
illustrated in Figure 2, when the optional adhesive layer 13, optional charge blocking
layer 14, and optional charge transport layer 15 are all absent, the transparentizing
agent can be contained in part or all of the substrate layer 12. Upon migration of
the migration marking material 19 through the softenable layer 16, migrated particles
contact the transparentizing agent in substrate 12 and become transparentized, thereby
reducing the D
min value of the imaging member subsequent to development. When one or more of the optional
layers is present, the transparentizing agent can be present in one or more of these
layers so that upon migration of the migration marking material 19 through the softenable
layer 16, migrated particles contact the transparentizing agent in one or more of
the optional layers and become transparentized, thereby reducing the D
min value of the imaging member subsequent to development. Additionally, in the embodiment
illustrated in Figure 3, when the optional adhesive layer 26, optional charge blocking
layer 27, and optional charge transport layer 31 are all absent, the transparentizing
agent can be contained in part or all of the infrared or red light sensitive layer
28. Upon migration of the migration marking material 35 through the softenable layer
32, migrated particles contact the transparentizing agent in infrared or red light
sensitive layer 28 and become transparentized, thereby reducing the D
min value of the imaging member subsequent to development. When one or more of the optional
layers is present, the transparentizing agent can be present in one or more of these
layers, such as charge transport layer 31, so that upon migration of the migration
marking material 35 through the softenable layer 32, migrated particles contact the
transparentizing agent in one or more of the optional layers and become transparentized,
thereby reducing the D
min value of the imaging member subsequent to development.
[0037] The transparentizing agent can also be present in the softenable layer itself. For
example, in the embodiment illustrated in Figure 1, the transparentizing agent can
be present in softenable layer 6; in the embodiment illustrated in Figure 2, the transparentizing
agent can be present in softenable layer 16; in the embodiment illustrated in Figure
3, the transparentizing agent can be present in softenable layer 32. When present
in the softenable layer, the transparentizing agent can be contained throughout the
softenable layer without being uniformly distributed therein. For example, the transparentizing
agent can be situated or concentrated near the bottom of the softenable layer (i.e.,
that part of the softenable layer in closest proximity to the substrate) so that subsequent
to image formation and development, migrated migration marking particles contact the
transparentizing agent and become transparentized, while unmigrated migration marking
particles contact the transparentizing agent either not at all or in a manner such
that the concentration of transparentizing agent contacting the unmigrated marking
particles is less than the concentration of transparentizing agent contacting the
migrated marking particles. Further, the transparentizing agent can be situated or
concentrated near the top of the softenable layer (i.e., that part of the softenable
layer spaced from the substrate) so that subsequent to image formation and development,
unmigrated migration marking particles contact the transparentizing agent and become
transparentized, while migrated migration marking particles contact the transparentizing
agent either not at all or in a manner such that the concentration of transparentizing
agent contacting the migrated marking particles is less than the concentration of
transparentizing agent contacting the unmigrated marking particles. The concentration
of transparentizing agent within the softenable layer can be varied according to depth
within the layer by any suitable method, such as by applying the softenable layer
by a series of solvent coating steps, wherein the concentration of transparentizing
agent dispersed with the softenable material and solvent is varied to increase or
decrease the concentration of transparentizing agent as successive coatings are applied.
Thereafter, the migration marking material is applied to the softenable layer by any
suitable or desired method, such as solvent coating, evaporation coating, or the like.
[0038] The transparentizing agent can further be present in a separate layer or coating
within the migration imaging member structure. For example, as illustrated schematically
in Figure 4, migration imaging member 40 comprises a substrate 41, an optional adhesive
layer 42 situated on the substrate 41, an optional charge blocking layer 43 situated
on optional adhesive layer 42, an optional charge transport layer 44 situated on optional
charge blocking layer 43, a transparentizing layer 45 situated on optional charge
transport layer 44, and a softenable layer 46 situated on transparentizing layer 45,
said softenable layer 46 comprising softenable material 47, migration marking material
48 situated at or near the surface of the layer spaced from the substrate, and optional
charge transport material 49 dispersed throughout softenable material 47. Optional
overcoating layer 50 is situated on the surface of softenable layer 46 spaced from
the substrate 41. Any or all of the optional layers and materials can be absent from
the imaging member. In addition, any of the optional layers present need not be in
the order shown, but can be in any suitable arrangement. For example, if the optional
adhesive layer 42, optional charge blocking layer 43, and optional charge transport
layer 44 are absent, transparentizing layer 46 is coated directly onto substrate 41
and is situated between and in contact with substrate 41 and softenable layer 46.
[0039] Similarly, in the embodiment illustrated in Figure 5, migration imaging member 51
comprises in the order shown a substrate 52, an optional adhesive layer 53 situated
on substrate 52, an optional charge blocking layer 54 situated on optional adhesive
layer 53, an optional charge transport layer 55 situated on optional charge blocking
layer 54, a transparentizing layer 56 situated on optional charge transport layer
55, a softenable layer 57 situated on transparentizing layer 56, said softenable layer
57 comprising softenable material 58, charge transport material 59, and migration
marking material 60 situated at or near the surface of the layer spaced from the substrate,
and an infrared or red light radiation sensitive layer 61 situated on softenable layer
57 comprising infrared or red light radiation sensitive pigment particles 62 optionally
dispersed in polymeric binder 63. Alternatively (not shown), infrared or red light
radiation sensitive layer 61 can comprise infrared or red light radiation sensitive
pigment particles 62 directly deposited as a layer by, for example, vacuum evaporation
techniques or other coating methods. Optional overcoating layer 64 is situated on
the surface of imaging member 51 spaced from the substrate 52. Any or all of the optional
layers and materials can be absent from the imaging member. In addition, any of the
optional layers present need not be in the order shown, but can be in any suitable
arrangement. For example, if the optional adhesive layer 53, optional charge blocking
layer 54, and optional charge transport layer 55 are absent, transparentizing layer
56 is coated directly onto substrate 52 and is situated between and in contact with
substrate 52 and softenable layer 57.
[0040] Similarly, as illustrated schematically in Figure 6, migration imaging member 65
comprises in the order shown a substrate 66, an optional adhesive layer 67 situated
on substrate 66, an optional charge blocking layer 68 situated on optional adhesive
layer 67, an infrared or red light radiation sensitive layer 69 situated on optional
charge blocking layer 68 comprising infrared or red light radiation sensitive pigment
particles 70 optionally dispersed in polymeric binder 71, an optional charge transport
layer 72 situated on infrared or red light radiation sensitive layer 69, a transparentizing
layer 73 situated on optional charge transport layer 72, and a softenable layer 74
situated on transparentizing layer 73, said softenable layer 74 comprising softenable
material 75, charge transport material 76, and migration marking material 77 situated
at or near the surface of the layer spaced from the substrate. Optional overcoating
layer 78 is situated on the surface of imaging member 65 spaced from the substrate
66. Any or all of the optional layers and materials can be absent from the imaging
member. In addition, any of the optional layers present need not be in the order shown,
but can be in any suitable arrangement. For example, if the optional adhesive layer
67, optional charge blocking layer 68, and optional charge transport layer 72 are
absent, transparentizing layer 73 is coated directly onto infrared or red light sensitive
layer 69 and is situated between and in contact with infrared or red light sensitive
layer 69 and softenable layer 74.
[0041] In the embodiments illustrated in Figures 4, 5, and 6, the transparentizing layer
is situated below the softenable layer (i.e., is situated between the softenable layer
and the substrate), so that subsequent to image formation and development, migrated
migration marking particles contact the transparentizing agent in the transparentizing
layer and become transparentized, while unmigrated migration marking particles do
not contact the transparentizing agent in the transparentizing layer and thus are
not transparentized. The transparentizing agent can also be situated above the softenable
layer (i.e., situated so that the softenable layer is between the transparentizing
layer and the substrate). For example, as illustrated schematically in Figure 7, migration
imaging member 79 comprises a substrate 80, an optional adhesive layer 81 situated
on the substrate 80, an optional charge blocking layer 82 situated on optional adhesive
layer 81, an optional charge transport layer 83 situated on optional charge blocking
layer 82, a softenable layer 84 situated on optional charge transport layer 83, said
softenable layer 84 comprising softenable material 85, migration marking material
86 situated at or near the surface of the layer spaced from the substrate, and optional
charge transport material 87 dispersed throughout softenable material 85, and a transparentizing
layer 88 situated on softenable layer 84. Optional overcoating layer 89 is situated
on the surface of transparentizing layer 88 spaced from the substrate 80. Any or all
of the optional layers and materials can be absent from the imaging member. In addition,
any of the optional layers present need not be in the order shown, but can be in any
suitable arrangement.
[0042] Similarly, in the embodiment illustrated in Figure 8, migration imaging member 90
comprises in the order shown a substrate 91, an optional adhesive layer 92 situated
on substrate 91, an optional charge blocking layer 93 situated on optional adhesive
layer 92, an optional charge transport layer 94 situated on optional charge blocking
layer 93, a softenable layer 95 situated on optional charge transport layer 94, said
softenable layer 95 comprising softenable material 96, charge transport material 97,
and migration marking material 98 situated at or near the surface of the layer spaced
from the substrate, a transparentizing layer situated on softenable layer 95, and
an infrared or red light radiation sensitive layer 100 situated on transparentizing
layer 99 comprising infrared or red light radiation sensitive pigment particles 101
optionally dispersed in polymeric binder 102. Alternatively (not shown), infrared
or red light radiation sensitive layer 100 can comprise infrared or red light radiation
sensitive pigment particles 101 directly deposited as a layer by, for example, vacuum
evaporation techniques or other coating methods. Optional overcoating layer 103 is
situated on the surface of imaging member 90 spaced from the substrate 91. Any or
all of the optional layers and materials can be absent from the imaging member. In
addition, any of the optional layers present need not be in the order shown, but can
be in any suitable arrangement.
[0043] Similarly, as illustrated schematically in Figure 9, migration imaging member 104
comprises in the order shown a substrate 105, an optional adhesive layer 106 situated
on substrate 105, an optional charge blocking layer 107 situated on optional adhesive
layer 106, an infrared or red light radiation sensitive layer 108 situated on optional
charge blocking layer 107 comprising infrared or red light radiation sensitive pigment
particles 109 optionally dispersed in polymeric binder 110, an optional charge transport
layer 111 situated on infrared or red light radiation sensitive layer 108, a softenable
layer 112 situated on optional charge transport layer 111, said softenable layer 112
comprising softenable material 113, charge transport material 114, and migration marking
material 115 situated at or near the surface of the layer spaced from the substrate,
and transparentizing layer 116 situated on softenable layer 112. Optional overcoating
layer 117 is situated on the surface of imaging member 104 spaced from the substrate
105. Any or all of the optional layers and materials can be absent from the imaging
member. In addition, any of the optional layers present need not be in the order shown,
but can be in any suitable arrangement.
[0044] In embodiments of the present invention wherein two or more softenable layers, each
containing a migration marking material, are present in the migration imaging member,
the transparentizing agent can be present within one or both of the softenable layers
as illustrated schematically in Figures 1 through 3. Additionally, the transparentizing
agent can be present as a separate layer as illustrated in Figures 4 through 9. Further,
the transparentizing agent can be present as a separate layer situated between the
two softenable layers, as illustrated schematically in Figure 10. As illustrated schematically
in Figure 10, migration imaging member 118 comprises in the order shown a substrate
119, an optional adhesive layer 120 situated on substrate 119, an optional charge
blocking layer 121 situated on optional adhesive layer 120, an optional charge transport
layer 122 situated on optional charge blocking layer 121, a first softenable layer
123 situated on optional charge transport layer 122, said first softenable layer 123
comprising first softenable material 124, optional first charge transport material
125, and first migration marking material 126 situated at or near the surface of the
first softenable layer spaced from the substrate, a transparentizing layer 127 situated
on first softenable layer 123, and a second softenable layer 128 situated on transparentizing
layer 127 comprising second softenable material 129, optional second charge transport
material 130, and second migration marking material 131 situated at or near the surface
of second softenable layer 128 in contact with transparentizing layer 127. Alternatively
(not shown), second migration marking material can be situated at or near the surface
of second softenable layer 128 spaced from substrate 119, or can be dispersed uniformly
within second softenable layer 128. Optional overcoating layer 132 is situated on
the surface of the imaging member spaced from the substrate 119. Further (not shown),
an infrared or red light sensitive layer can be situated within the migration imaging
member having two softenable layers in configurations as illustrated, for example,
in Figures 2, 3, 5, 6, 8, and 9.
[0045] The transparentizing layer as illustrated in Figures 4 through 10 can be applied
to the imaging member by any desired or suitable method. For example, a layer of softenable
material (either the same as or different from the softenable material employed in
the softenable layer) can be prepared by admixing the softenable material and the
transparentizing agent and applying the mixture to the imaging member by any desired
method, such as draw bar coating, spray coating, extrusion, dip coating, gravure roll
coating, wire-wound rod coating, air knife coating and the like. Alternatively, the
transparentizing agent can be coated directly onto the underlying layer in the migration
imaging member, with no need for a binder or matrix, by dissolving or dispersing the
transparentizing agent into a solvent, coating the solution or dispersion onto the
underlying layer, and allowing the solvent to evaporate. For transparentizing agents
suitable for evaporation coating techniques, the transparentizing agent can be vacuum
evaporated onto the underlying layer of the migration imaging member. When the transparentizing
agent is incorporated into another layer of the migration imaging member, or when
the transparentizing agent is admixed with a binder and/or any additional materials
to form a separate transparentizing layer within the migration imaging member, the
transparentizing agent preferably is present within the layer in an amount of from
about 1 to about 50 percent by weight, and more preferably 5 to about 20 percent by
weight, although the amount can be outside these ranges. When the transparentizing
agent is present in a separate transparentizing layer, preferably the layer is of
a thickness of from about 2 to about 4 microns, although the thickness can be outside
this range.
[0046] The transparentizing agent preferably is a monomeric material. In some instances,
oligomeric materials (i.e., molecules having up to about four repeating monomer units)
can also be employed as the transparentizing agent. Some polymeric materials may also
be suitable if they contain some functional groups similar to those contained in suitable
monomeric or oligomeric materials. While not being limited to any particular theory,
it is believed that the transparentizing agent may chelate with the migration marking
material, thereby rendering it transparent, or may enhance the ability of the migration
marking material to agglomerate, or may oxidize the migration marking material, thereby
rendering it transparent.
[0047] Examples of transparentizing agents suitable for the present invention include the
following:
[0048] I. Azacyclic and azaheterocyclic compounds, including (A) piperidines and piperidine
derivatives, including those of the general formulae:

wherein R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
14, R
15, R
16, R
17, R
18, R
19, R
20, R
21, R
22, R
23, R
24, R
25, R
26, R
27, R
28, R
29, R
30, R
31, R
32, R
33, R
34, R
35, R
36, R
37, R
38, and R
39 each, independently of the others, can be (but are not limited to) hydrogen atoms,
alkyl groups, preferably with from 1 to about 6 carbon atoms and more preferably with
from 1 to about 3 carbon atoms, substituted alkyl groups, preferably with from 1 to
about 12 carbon atoms and more preferably with from 1 to about 6 carbon atoms, aryl
groups, preferably with from about 6 to about 24 carbon atoms and more preferably
with from about 6 to about 12 carbon atoms, substituted aryl groups, preferably with
from about 6 to about 30 carbon atoms and more preferably with from about 6 to about
18 carbon atoms, arylalkyl groups, preferably with from about 7 to about 31 carbon
atoms and more preferably with from about 7 to about 20 carbon atoms, substituted
arylalkyl groups, preferably with from about 7 to about 32 carbon atoms and more preferably
with from about 7 to about 21 carbon atoms, hydroxy groups, amine groups, imine groups,
ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde groups,
ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl groups,
thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups,
phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups,
mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl
groups, acid anhydride groups, azide groups, and the like, wherein two or more of
R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
14, R
15, R
16, R
17, R
18, R
19, R
20, R
21, R
22, R
23, R
24, R
25, R
26, R
27, R
28, R
29, R
30, R
31, R
32, R
33, R
34, R
35, R
36, R
37, R
38, and R
39 can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, I
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, lO
3-, ClO
3-, or the like, as well as mixtures thereof.
[0049] Examples of suitable piperadine compounds and derivatives include (1) homopiperidine,
(2) piperidinethiocyanate, (3) (±)-2-piperidinemethanol, (4) 3-piperidinemethanol,
(5) 2-piperidineethanol, (6) 4-piperidineethanol, (7) 4-piperidine monohydrate hydrochloride,
(8) 1-aminopiperidine, (9) 1-(2-aminoethyl)piperidine,(10) 4-(aminomethyl)piperidine,
(11) 3-piperidino-1,2-propanediol, (12) 1-piperidine propionic acid, (13) 1-methyl-4-(methylamino)piperidine,
(14) 1-acetyl-3-methylpiperidine, (15) 4'-piperidinoacetophenone, (16) 4-phenylpiperidine,
(17) 4-piperidinopiperidine, (18) 4-benzylpiperidine, (19) 4-(4-methylpiperidino)pyridine,
(20) 4-piperidone ethylene ketal, (21) bis(pentamethylene)urea, (22) 1-benzyl-4-hydroxypiperidine,
(23) 1-benzoyl-4-piperidone, (24) 1,1'-methylenebis(3-methylpiperidine), (25) 4,4'-trimethylenedipiperidine,
(26) 4,4'-trimethylenebis(1-menthylpiperidine), (27) 4,4'-trimethylenebis(1-piperidinepropionitrile),
(28) 4,4'-trimethylenebis(1-piperidineethanol), (29) 2,2,6,6-tetramethylpiperidine,
(30) 4-amino-2,2,6,6-tetramethylpiperidine, (31) 4-(dimethylamino)-1,2,2,6,6-pentamethylpiperidine,
(32) N,N'-bis(2,2,6,6-tetramethyl-4-piperidinyl)-1,6-hexanediamine, (33) tripiperidinophosphine
oxide, (34) tropane, (35) tropinehydrate, (36) tropinone, (37) 8-hydroxytropinone,
(38) 2-piperidine carboxylic acid, (39) 2-piperidone, (40) 4,4'-trimethylene bis (1-piperidine
carboxamide), (41) 4-methyl-2-(piperidinomethyl) phenol, (42) 1-methyl-4-piperidinyl
bis (chlorophenoxy) acetate, (43) 2-(hexamethylene imino) ethyl chloride monohydrochloride,
(44) 3-(hexahydro-1H-azepin-1-yl)-3'-nitropropiophenone hydrochloride, (45) imipramine
hydrochloride [5-(3-dimethyl aminopropyl)-10,11-dihydro 5H-dibenz-(b,f) azepine hydrochloride],
(46) carbamezepine [5H-dibenzo (b,f)-azepine-5-carboxamide], (47) 5,6,11,12-tetrahydro
dibenz [b,f] azocine hydrochloride, (48) quinuclidine hydrochloride, (49) 3-quinuclidinol
hydrochloride, (50) 3-quinuclidinone hydrochloride, (51) 2-methylene-3-quinuclidinone
dihydrate hydrochloride, (52) 3-amino quinuclidine dihydrochloride, (53) 3-chloro
quinuclidine hydrochloride, (54) quinidine sulfate dihydrate, (55) quinine monohydrochloride
dihydrate, (56) quinine sulfate monohydrate, (57) hydroquinidine hydrochloride, (58)
hydroquinine hydrobromide dihydrate, and the like;
[0050] (B) piperazines and piperazine derivatives, including those of the general formulae

wherein R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
14, R
15, R
16, R
17, R
18, R
19, R
20, R
21, and R
22 each, independently of the others, can be (but are not limited to) hydrogen atoms,
alkyl groups, preferably with from 1 to about 6 carbon atoms and more preferably with
from 1 to about 3 carbon atoms, substituted alkyl groups, preferably with from 1 to
about 12 carbon atoms and more preferably with from 1 to about 6 carbon atoms, aryl
groups, preferably with from about 6 to about 24 carbon atoms and more preferably
with from about 6 to about 12 carbon atoms, substituted aryl groups, preferably with
from about 6 to about 30 carbon atoms and more preferably with from about 6 to about
18 carbon atoms, arylalkyl groups, preferably with from about 7 to about 31 carbon
atoms and more preferably with from about 7 to about 20 carbon atoms, substituted
arylalkyl groups, preferably with from about 7 to about 32 carbon atoms and more preferably
with from about 7 to about 21 carbon atoms, hydroxy groups, amine groups, imine groups,
ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde groups,
ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl groups,
thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups,
phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups,
mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl
groups, acid anhydride groups, azide groups, and the like, wherein two or more of
R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
14, R
15, R
16, R
17, R
18, R
19, R
20, R
21 and R
22 can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, I
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, IO
3-, ClO
3-, or the like, as well as mixtures thereof.
[0051] Examples of suitable piperazine compounds and derivatives include (1) piperazine
and piperazine hexahydrate, (2) homopiperazine, (3) 1-methylpiperazine, (4) 2-methylpiperazine,
(5) 1-acetylpiperazine, (6) 1-(2-hydroxyethyl)piperazin, (7) 1-(2-aminoethyl)piperazine,
(8) tert-butyl 1-piperazinecarboxylate, (9) N-isopropyl-1-piperazineacetamide, (10)
1-(2-methoxyphenyl)piperazine, (11) 1-(2-pyridyl)piperazine, (12) 1-benzylpiperazine,
(13) 1-cinnamylpiperazine, (14) 1-(4-chlorobenzhydryl)piperazine, (15) 2,6-dimethylpiperazine,
(16) 1-amino-4-methylpiperazine, (17) 1-amino-4-(2-hydroxyethyl)piperazine, (18) 1,4-bis(2-hydroxyethyl)piperazine,
(19) 1,4-bis(3-aminopropyl)piperazine, (20) tert-butyl-4-benzyl-1-piperazinecarboxylate,
(21) 1-piperonyl piperazine, (22) bis(4-methyl-1-homopiperazinylthio-carbonyl)disulfide,
(23) 1-amino-4-methyl piperazine dihydrochloride monohydrate, (24) 1-(3-chloropropyl)-piperazine
dihydrochloride monohydrate, (25) 1-(2,3-xylyl) piperazine monohydrochloride, (26)
1,1-dimethyl-4-phenyl piperazineium iodide, and the like;
[0052] (C) cyclic compounds wherein the ring contains three nitrogen atoms, including (1)
1,4,7-triazacyclononane,(2) 1,5,9-triazacyclododecane,(3) triazoles and triazole derivatives,
including those of the general formulae

wherein R
1, R
2, and R
3 each, independently of the others, can be (but are not limited to) hydrogen atoms,
alkyl groups, preferably with from 1 to about 6 carbon atoms and more preferably with
from 1 to about 3 carbon atoms, substituted alkyl groups, preferably with from 1 to
about 12 carbon atoms and more preferably with from 1 to about 6 carbon atoms, aryl
groups, preferably with from about 6 to about 24 carbon atoms and more preferably
with from about 6 to about 12 carbon atoms, substituted aryl groups, preferably with
from about 6 to about 30 carbon atoms and more preferably with from about 6 to about
18 carbon atoms, arylalkyl groups, preferably with from about 7 to about 31 carbon
atoms and more preferably with from about 7 to about 20 carbon atoms, substituted
arylalkyl groups, preferably with from about 7 to about 32 carbon atoms and more preferably
with from about 7 to about 21 carbon atoms, hydroxy groups, amine groups, imine groups,
ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde groups,
ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl groups,
thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups,
phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups,
mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl
groups, acid anhydride groups, azide groups, and the like, wherein two or more of
R
1, R
2, and R
3 can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, l
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, lO
3-, ClO
3-, or the like, as well as mixtures thereof, such as (a) 1,2,3-triazole,(b) 4-amino-1,2,4-triazole,
(c) 3-amino-5-methylthio-lH-1,2,4-triazole, (d) benzotriazole, (e) 1-aminobenzotriazole,
(f) 1-cyanobenzotriazole, (g) 5-methyl-1H-benzotriazole, (h) 1H-benzotriazole-1-ylmethyl
isocyanide, (i) 2-[3-(2H-benzotriazole-2-yl)-4-hydroxyphenyl]ethyl methacrylate, (j)
1,2,4-triazole, (k) 1,2,4-triazole sodium derivative, (I) 3-amino-1,2,4-triazole,
(m) 3,5-diamino-1,2,4-triazole, (n) 3-amino-5-mercapto-1,2,4-triazole, (o) 3-amino-1,2,4-triazole-5-carboxylic
acid hemihydrate, (p) 4-amino-3-hydrazino-5-mercapto-1,2,4-triazole, (q) 1,2,3-triazole-4,5-dicarboxylic
acid monohydrate, (r) nitron [4,5-dihydro-2,4-diphenyl-5-(phenylimino)-1H-1,2,4-triazolium
hydroxide inner salt], (s) 1-hydroxybenzotriazole hydrate, and the like; (4) triazines
and triazine derivatives, including those of the general formulae

wherein R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, and R
12 each, independently of the others, can be (but are not limited to) hydrogen atoms,
alkyl groups, preferably with from 1 to about 6 carbon atoms and more preferably with
from 1 to about 3 carbon atoms, substituted alkyl groups, preferably with from 1 to
about 12 carbon atoms and more preferably with from 1 to about 6 carbon atoms, aryl
groups, preferably with from about 6 to about 24 carbon atoms and more preferably
with from about 6 to about 12 carbon atoms, substituted aryl groups, preferably with
from about 6 to about 30 carbon atoms and more preferably with from about 6 to about
18 carbon atoms, arylalkyl groups, preferably with from about 7 to about 31 carbon
atoms and more preferably with from about 7 to about 20 carbon atoms, substituted
arylalkyl groups, preferably with from about 7 to about 32 carbon atoms and more preferably
with from about 7 to about 21 carbon atoms, hydroxy groups, amine groups, imine groups,
ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde groups,
ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl groups,
thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups,
phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups,
mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl
groups, acid anhydride groups, azide groups, and the like, wherein two or more of
R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, and R
12 can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, l
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, lO
3-, ClO
3-, or the like, as well as mixtures thereof, such as (a) 1,3,5-triazine, (b) cyanuric
acid, (c) trithiocyanuric acid, (d) 2,4-bis (methylthio)-6-chloro-1,3,5-triazine,
(e) 2-chloro-4,6-dimethoxy-1,3,5-triazine, (f) 2-chloro-4,6-diamino-1,3,5-triazine,
(g) trichloromelamine, (h) cyanuric chloride, (i) 2,4,6-tris(perfluoroheptyl)-1,3,5-triazine,
(j) hexahydro-2,4,6-trimethyl-1,3,5-triazine trihydrate, (k) 1,3,5-trimethylhexahydro-1,3,5-triazine,
(I) 1,3,5-triethylhexahydro-1,3,5-triazine, (m) 1,3,5-triclohexylhexahydro-1,3,5-triazine,
(n) 1,3,5-tribenzylhexahydro-1,3,5-triazine, (o) trichloroisocyanuric acid, (p) tris
(2,3-dibromopropylisocyanurate), (q) cyanuric acid compound with melamine, and the
like; (5) urazoles and urazole derivatives, including those of the general formulae

wherein R
1, R
2, R
3, and R
4 each, independently of the others, can be (but are not limited to) hydrogen atoms,
alkyl groups, preferably with from 1 to about 6 carbon atoms and more preferably with
from 1 to about 3 carbon atoms, substituted alkyl groups, preferably with from 1 to
about 12 carbon atoms and more preferably with from 1 to about 6 carbon atoms, aryl
groups, preferably with from about 6 to about 24 carbon atoms and more preferably
with from about 6 to about 12 carbon atoms, substituted aryl groups, preferably with
from about 6 to about 30 carbon atoms and more preferably with from about 6 to about
18 carbon atoms, arylalkyl groups, preferably with from about 7 to about 31 carbon
atoms and more preferably with from about 7 to about 20 carbon atoms, substituted
arylalkyl groups, preferably with from about 7 to about 32 carbon atoms and more preferably
with from about 7 to about 21 carbon atoms, hydroxy groups, amine groups, imine groups,
ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde groups,
ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl groups,
thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups,
phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups,
mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl
groups, acid anhydride groups, azide groups, and the like, wherein two or more of
R
1, R
2, R
3, and R
4 can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, l
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, lO
3-, ClO
3-, or the like, as well as mixtures thereof, such as (a) urazole, (b) 1-methyl urazole,
(c) 4-phenyl urazole, (d) D,L-5-(4-hydroxyphenyl)-5-phenyl hydantoin, (e) β-tetralone
hydantoin, and the like;
[0053] (D) cyclic compounds wherein the ring contains four nitrogen atoms, including (1)
cyclen (1,4,7,10-tetraazacyclododecane), (2) 1,4,8,11-tetraazacyclotetradecane, (3)
1,4,8,11-tetramethyl- 1,4,8,11 1,4,8,11 -tetraazacyclotetradecane, (4) 1,4,8,11-tetraazacyclotetradecane-5,7-dione,
(5) 1,4,8,12-tetraazacyclopentadecane, (6) porphines and porphine derivatives, including
those of the general formula

wherein R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, and R
14 each, independently of the others, can be (but are not limited to) hydrogen atoms,
alkyl groups, preferably with from 1 to about 6 carbon atoms and more preferably with
from 1 to about 3 carbon atoms, substituted alkyl groups, preferably with from 1 to
about 12 carbon atoms and more preferably with from 1 to about 6 carbon atoms, aryl
groups, preferably with from about 6 to about 24 carbon atoms and more preferably
with from about 6 to about 12 carbon atoms, substituted aryl groups, preferably with
from about 6 to about 30 carbon atoms and more preferably with from about 6 to about
18 carbon atoms, arylalkyl groups, preferably with from about 7 to about 31 carbon
atoms and more preferably with from about 7 to about 20 carbon atoms, substituted
arylalkyl groups, preferably with from about 7 to about 32 carbon atoms and more preferably
with from about 7 to about 21 carbon atoms, hydroxy groups, amine groups, imine groups,
ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde groups,
ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl groups,
thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups,
phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups,
mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl
groups, acid anhydride groups, azide groups, and the like, wherein two or more of
R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, and R
14 can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, l
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, lO
3-, ClO
3-, or the like, as well as mixtures thereof. Examples of suitable porphines and porphine
derivatives include (a) 2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphine, (b) dimethyl
3,7,12,17-tetramethyl-21H,23H-porphine-2,18-dipropionate, (c) dimethyl 7,12-diacetyl-3,8,13,17-tetramethyl-21H,23H-porphine-2,18-dipropionate,
(d) 8,3-divinyl-3,7,12,17-tetramethyl-21H,23H-porphine-2,18-dipropionic acid, disodium
salt, (e) 5,10,15,20-tetraphenyl-21H,23H-porphine, (f) 5,10,1 5,20-tetrakis(4-methoxyphenyl)-21H,23H-porphine,
(g) 5,10,15-20-tetrakis[4-(trimethylamino)phenyl]-21H,23H-porphine tetra-p-tosylate
salt, (h) 5,10,15,20-tetra(4-pyridyl)-21H,23H-porphine, (i) 5,10,15,20-tetrakis(1-methyl-4-pyridyl)-21H,23H-porphine,
tetra-p-tosylate salt), and the like; (7) tetrazoles and tetrazole derivatives, including
those of the general formula

wherein R
1 and R
2 each, independently of the others, can be (but are not limited to) hydrogen atoms,
alkyl groups, preferably with from 1 to about 6 carbon atoms and more preferably with
from 1 to about 3 carbon atoms, substituted alkyl groups, preferably with from 1 to
about 12 carbon atoms and more preferably with from 1 to about 6 carbon atoms, aryl
groups, preferably with from about 6 to about 24 carbon atoms and more preferably
with from about 6 to about 12 carbon atoms, substituted aryl groups, preferably with
from about 6 to about 30 carbon atoms and more preferably with from about 6 to about
18 carbon atoms, arylalkyl groups, preferably with from about 7 to about 31 carbon
atoms and more preferably with from about 7 to about 20 carbon atoms, substituted
arylalkyl groups, preferably with from about 7 to about 32 carbon atoms and more preferably
with from about 7 to about 21 carbon atoms, hydroxy groups, amine groups, imine groups,
ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde groups,
ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl groups,
thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups,
phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups,
mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl
groups, acid anhydride groups, azide groups, and the like, wherein two or more of
R1 and R2 can be joined together to form a ring, and wherein the substituents on the
substituted alkyl groups, substituted aryl groups, and substituted arylalkyl groups
can be (but are not limited to) hydroxy groups, amine groups, imine groups, ammonium
groups, pyridine groups, pyridinium groups, ether groups, aldehyde groups, ketone
groups, ester groups, amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl
groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine
groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups, mercapto
groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl groups,
acid anhydride groups, azide groups, and the like, wherein two or more substituents
can be joined together to form a ring. Other variations are also possible, such as
a double bond between one of the ring carbon atoms and another atom, such as carbon,
oxygen, or the like. These compounds can also be in acid salt form, wherein they are
associated with a compound of the general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, I
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, lO
3-, CIO
3-, or the like, as well as mixtures thereof, including (a) 1,5-pentamethylenetetrazole,
(b) 1-H-tetrazole, (c) 5-amino tetrazole monohydrate, (d) 2,3,5-triphenyl-2H-tetrazolium
chloride, (e) 2-(4-iodophenyl)-5-(4-nitrophenyl)-3-phenyltetrazolium chloride, (f)
1,2,3,3-tetramethyl-3H-indolinium iodide, and the like;
[0054] (E) cyclic compounds wherein the ring contains six nitrogen atoms, including (1)
hexacyclen trisulfate, (2) hexamethylhexacyclen [1,4,7,10,13,16-hexamethyl-1,4,7,10,13-16-hexaazacyclooctadecane],
and the like;
[0055] (F) pyrrole compounds, including those of the general formula

wherein R
1, R
2, R
3, R
4, and R
5 each, independently of the others, can be (but are not limited to) hydrogen atoms,
alkyl groups, preferably with from 1 to about 6 carbon atoms and more preferably with
from 1 to about 3 carbon atoms, substituted alkyl groups, preferably with from 1 to
about 12 carbon atoms and more preferably with from 1 to about 6 carbon atoms, aryl
groups, preferably with from about 6 to about 24 carbon atoms and more preferably
with from about 6 to about 12 carbon atoms, substituted aryl groups, preferably with
from about 6 to about 30 carbon atoms and more preferably with from about 6 to about
18 carbon atoms, arylalkyl groups, preferably with from about 7 to about 31 carbon
atoms and more preferably with from about 7 to about 20 carbon atoms, substituted
arylalkyl groups, preferably with from about 7 to about 32 carbon atoms and more preferably
with from about 7 to about 21 carbon atoms, hydroxy groups, amine groups, imine groups,
ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde groups,
ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl groups,
thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups,
phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups,
mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl
groups, acid anhydride groups, azide groups, and the like, wherein two or more of
R
1, R
2, R
3, R
4, and R
5 can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, I
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, lO
3-, ClO
3-, or the like, as well as mixtures thereof; and (G) pyrrolidine compounds, including
those of the general formula

wherein R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, and R
9 each, independently of the others, can be (but are not limited to) hydrogen atoms,
alkyl groups, preferably with from 1 to about 6 carbon atoms and more preferably with
from 1 to about 3 carbon atoms, substituted alkyl groups, preferably with from 1 to
about 12 carbon atoms and more preferably with from 1 to about 6 carbon atoms, aryl
groups, preferably with from about 6 to about 24 carbon atoms and more preferably
with from about 6 to about 12 carbon atoms, substituted aryl groups, preferably with
from about 6 to about 30 carbon atoms and more preferably with from about 6 to about
18 carbon atoms, arylalkyl groups, preferably with from about 7 to about 31 carbon
atoms and more preferably with from about 7 to about 20 carbon atoms, substituted
arylalkyl groups, preferably with from about 7 to about 32 carbon atoms and more preferably
with from about 7 to about 21 carbon atoms, hydroxy groups, amine groups, imine groups,
ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde groups,
ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl groups,
thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups,
phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups,
mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl
groups, acid anhydride groups, azide groups, and the like, wherein two or more of
R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, and R
9 can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between pyrrole or pyrrolidine and acid (and may be a fraction), and Y is an anion,
such as Cl
-, Br
-, l
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, lO
3-, ClO
3-, or the like, as well as mixtures thereof.
[0056] Examples of suitable pyrrole and pyrrolidine compounds include (1) pyrrole-2-carboxaldehyde,
(2) L-proline amide, (3) 3-pyrrolidino-1,2-propane diol, (4) 1-(pyrrolidino carbonylmethyl)
piperazine, (5) 4-pyrrolidinopyridine, (6) 3-indolylacetonitrile, (7) 6-nitroindoline,
(8) 7-azaindole, (9) indazole, (10) 2-acetyl-pyrrole, (11) 2-acetyl-1-methylpyrrole,
(12) 3-acetyl-1 -methyl pyrrole, (13) 3-acetyl-2,4-dimethylpyrrole, (14) pyrrole-2-carboxylic
acid, (15) 3-carboxy-1,4-dimethyl-2-pyrroleacetic acid, (16) proline, (17) 2-pyrrolidone-5-carboxylic
acid, (18) 4-hydroxy-L-proline, (19) 1,1'-ethylene bis (5-oxo-3-pyrrolidine carboxylic
acid), (20) kainic acid monohydrate (2-carboxy-4-isopropenyl-3-pyrrolidine acetic
acid monohydrate), (21) 1-amino pyrrolidine hydrochloride, (22) 2-(2-chloroethyl)-1-methyl
pyrrolidine hydrochloride, (23) 1-(2-chloroethyl) pyrrolidine hydrochloride, (24)
tremorine dihydrochloride [1,1'-(2-butynylene) dipyrrolidine hydrochloride],(25) L-proline
methyl ester hydrochloride, (26) ammonium pyrrolidine dithiocarbamate, (27) pyrrolidone
hydrotribromide, (28) 1-(4-chlorobenzyl)-2-(1-pyrrolidinyl methyl) benzimidazole hydrochloride,
(29) billverdin dihydrochloride, (30) indole, (31) 4,5,6,7-tetrahydroindole, (32)
3-indolemethanol hydrate, (33) 3-indole ethanol (tryptophol), (34) indole-3-carboxaldehyde,
(35) 3-indolylacetate (3-acetoxyindole), (36) indole-3-acetamide, (37) indole-3-carboxylic
acid, (38) indole-3-acetic acid, (39) 3-Indole propionic acid, (40) 3-indole acrylic
acid, (41) 3-indole glyoxylic acid, (42) indole-3-pyruvic acid, (43) D,L-3-indolelactic
acid, (44) 3-indole butyric acid, (45) N-acetyl-L-tryptophanamide,(46) N-(3-indolylacetyl)-L-alanine,
(47) N-(3-indolyl acetyl)-L-valine, (48) N-(3-indolyl acetyl)-L-isoleucine, (49) N-(3-indolyl
acetyl)-L-leucine, (50) N-(3-indolyl acetyl)-D,L-aspartic acid, (51) N-(3-indolyl
acetyl)-L-phenylalanine, (52) 4-hydroxyindole (4-Indolol), (53) indole-4-carboxylic
acid, (54) 4-indolyl acetate, (55) 4-methyl indole, (56) 5-hydroxy indole (5-indolol),
(57) 5-hydroxy indole-3-acetic acid, (58) 5-hydroxy-2-indole carboxylic acid, (59)
N-acetyl-5-hydroxytryptamine, (60) indole-5-carboxylic acid, (61) 5-methyl indole,
(62) 5-methoxy indole, (63) indole-2-carboxylic acid, (64) D,L-indolene-2-carboxylic
acid, (65) indole-2,3-dione (isatin), (66) 2-methyl indole, (67) 2,3,3-trimethyl indolenine,
(68) tryptamine hydrochloride, (69) 5-methyl tryptamine hydrochloride, (70) serotonin
hydrochloride hemihydrate (5-hydroxy tryptamine hydrochloride hemihydrate), (71) norharman
hydrochloride monohydrate, (72) harmane hydrochloride monohydrate, (73) harmine hydrochloride
hydrate, (74) harmaline hydrochloride dihydrate, (75) harmol hydrochloride dihydrate,
(76) harmalol hydrochloride dihydrate, (77) 3,6-diamino acridine hydrochloride, (78)
S-(3-indolyl) isothiuronium iodide, (79) yohimbine hydrochloride, and the like.
[0057] (H) pyrazoles and pyrazole derivatives, including those of the general formula

wherein R
1, R
2, R
3, and R
4 each, independently of the others, can be (but are not limited to) hydrogen atoms,
alkyl groups, preferably with from 1 to about 6 carbon atoms and more preferably with
from 1 to about 3 carbon atoms, substituted alkyl groups, preferably with from 1 to
about 12 carbon atoms and more preferably with from 1 to about 6 carbon atoms, aryl
groups, preferably with from about 6 to about 24 carbon atoms and more preferably
with from about 6 to about 12 carbon atoms, substituted aryl groups, preferably with
from about 6 to about 30 carbon atoms and more preferably with from about 6 to about
18 carbon atoms, arylalkyl groups, preferably with from about 7 to about 31 carbon
atoms and more preferably with from about 7 to about 20 carbon atoms, substituted
arylalkyl groups, preferably with from about 7 to about 32 carbon atoms and more preferably
with from about 7 to about 21 carbon atoms, hydroxy groups, amine groups, imine groups,
ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde groups,
ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl groups,
thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups,
phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups,
mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl
groups, acid anhydride groups, azide groups, and the like, wherein two or more of
R
1, R
2, R
3, and R
4 can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, I
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, lO
3-, BrO
3-, or the like, as well as mixtures thereof.
[0058] Examples of suitable pyrazole compounds include (1) pyrazole, (2) 3-amino pyrazole,
(3) 5-amino-1-ethylpyrazole, (4) 3-amino-4-carbethoxypyrazole, (5) 3-amino-5-methylpyrazole,
(6) 3-amino-5-phenylpyrazole, (7) ethyl 4-pyrazole carboxylate, (8) diethyl 3,5-pyrazolecarboxylate,
(9) 1,1'-(1-ethylpropylidene)bis 1H-pyrazole, (10) 4-bromopyrazole, (11) 4-bromo-3-methyl
pyrazole, (12) 3,5-dimethyl pyrazole, (13) 4-bromo-3,5-dimethyl pyrazole, (14) 3,5-dimethyl
pyrazole-1-carboxamide, (15) 3,5-dimethylpyrazole-1-methanol, (16) 3-methyl-1-vinylpyrazole,
(17) 4-benzoyl-3-methyl-1-phenyl-2-pyrazolin-5-one, (18) 1-nitropyrazole, (19) 4-pyrazole
carboxylic acid, (20) 3,5-pyrazole dicarboxylic acid monohydrate, (21) 3-amino-5-hydroxypyrazole,
(22) 3-amino-4-pyrazole carbonitrile, (23) 3-amino-4-pyrzaolecarboxylic acid, (24)
4-methyl pyrazole hydrochloride, (25) 3,4-diamino-5-hydroxy pyrazole sulfate, (26)
(3,5-dimethyl pyrazole-1-carboxamidine nitrate), (27) 3-amino-4-pyrazole carboxamide
hemisulfate, (28) acid salt of 6-amino indazole hydrochloride, (29) 4-hydroxypyrazolo
[3,4-d] pyrimidine, (30) 4-mercapto-1H-pyrazolo-[3,4-d]-pyrimidine, (31) indazole,
(32) 5-aminoindazole, (33) 6-aminoindazole, (34) 3-indazolinone, (35) N'-(6-indazolyl)
sulfanilamide, (36) 4,5-dihydro-3-(4-pyridinyl)-2H-benz[g] indazole methane sulfonate,
and the like;
[0059] (I) Imidazoles and imidazole derivatives, including those of the general formula

wherein R
1, R
2, R
3, and R
4 each, independently of the others, can be (but are not limited to) hydrogen atoms,
alkyl groups, preferably with from 1 to about 6 carbon atoms and more preferably with
from 1 to about 3 carbon atoms, substituted alkyl groups, preferably with from 1 to
about 12 carbon atoms and more preferably with from 1 to about 6 carbon atoms, aryl
groups, preferably with from about 6 to about 24 carbon atoms and more preferably
with from about 6 to about 12 carbon atoms, substituted aryl groups, preferably with
from about 6 to about 30 carbon atoms and more preferably with from about 6 to about
18 carbon atoms, arylalkyl groups, preferably with from about 7 to about 31 carbon
atoms and more preferably with from about 7 to about 20 carbon atoms, substituted
arylalkyl groups, preferably with from about 7 to about 32 carbon atoms and more preferably
with from about 7 to about 21 carbon atoms, hydroxy groups, amine groups, imine groups,
ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde groups,
ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl groups,
thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups,
phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups,
mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl
groups, acid anhydride groups, azide groups, and the like, wherein two or more of
R
1, R
2, R
3, and R
4 can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, I
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, lO
3-, ClO
3-, or the like, as well as mixtures thereof.
[0060] Examples of suitable imidazole compounds include (1) imidazole, (2) 4-methylimidazole,
(3) 2-ethylimidazole, (4) 2-propylimidazole, (5) 1-butylimidazole, (6) 2-undecylimidazole,(7)
histamine, (8) 1-(3-aminopropyl) imidazole, (9) 1-acetylimidazole, (10) 2-methyl-1-vinylimidazole,(11)
2-ethyl-4-methylimidazole, (12) 1-benzyl-2-methylimidazole, (13) 1-methylbenzimidazole,
(14) 1-ethyl-3-methyl-1,H-imidazolinium chloride, (15) 2-(aminomethyl) benzimidazole
dihydrochloride hydrate, (16) 2,6-diamino-8-purinol hemisulfate monohydrate, (17)
purin-6-yl-trimethyl ammonium chloride, (18) 4-methyl-5-imidazole methanol hydrochloride,
(19) N,N'-bis[3-(4,5-dihydro-1H-imidazol-2-yl)phenyl]urea dipropanoate, (20) 1-(p-tosyl)-3,4,4-trimethyl-2-imidazolinium
iodide, (21) 1-ethyl-3-methyl-1H-imidazolinium chloride, (22) 2-amino imidazole sulfate,
(23) 4-amino-5-imidazole carboxamide hydrochloride, (24) 2-hydrazino-2-imidazoline
hydrobromide, (25) imidazole hydrochloride, (26) 4-imidazole acetic acid hydrochloride,
(27) 2-benzyl-2-imidazoline hydrochloride, (28) propyl-1-(1-phenyl ethyl imidazole-5-carboxylate
hydrochloride, (29) 2,6-diamino purine sulfate hydrate, (30) 1-tallow amido ethyl-3-methyl-2-heptadecyl
imidazolinium methyl sulfate, (31) isostearyl ethyl imidonium ethyl sulfate, (32)
methyl (1) tallow amido ethyl-2-tallow imidazolinium methyl sulfate, (33) isostearyl
benzyl imidonium chloride, (34) methyl (1) hydrogenated tallow amido ethyl (2) hydrogenated
tallow imidazolinium methyl sulfate, (35) 1-methyl-1-oleyl amido ethyl-2-oleyl-imidazolinium
methyl sulfate, (36) cocohydroxyethyl polyethyleneglycol imidazolinium chloride phosphate,
(37) 1-methyl uric acid, (38) guanine, (39) guanosine hydrate, (40) xanthine, (41)
1-methylxanthine, (42) 3-methyl xanthine, (43) 3-isobutyl-1-methyl xanthine, (44)
hypoxanthine, (45) xanthosine dihydrate, (46) 6-thioxanthene, (47) purine, (48) 6-amino
purine (adenine), (49) 6-methoxy purine hemihydrate, (50) 6-mercaptopurine monohydrate,
(51) 2-amino-6-chloropurine, (52) 2-amino-6,8-dihydroxy purine, (53) theophylline
(3,7 dihydro-1,3-dimethyl-1H-purine-2,6-dione), (54) kinetin (6-furfuryl amino purine),
(55) 1-methyl adenine, (56) 3-methyl adenine, (57) (-)-adenosine, (58) (-)-inosine,
(59) 6-mercaptopurine riboside, (60) 6-amino purine hydrochloride hemihydrate, (61)
6-amino purine sulfate, (62) 2,6-diamino-8-purinol hemisulfate monohydrate, (63) benzimidazole,
(64) 2-aminobenzimidazole, (65) 2-amino-5,6-dimethlybenzimidazole, (66) 5-benzimidazole
carboxylic acid, (67) 2,4,5-trimethyl benzimidazole, (68) 2-guanidinobenzimidazole,
(69) 2-hydroxybenzimidazole, (70) 4-(2-keto-1-benzimidazolinyl) piperidine, (71) 2-imidazolidine
thione, (72) 2-imidazolidone, (73) hydantoin, (74) 1-methyl hydantoin, (75) creatinine,
(76) 2-thiohydrantoin, (77) 5-hydantoin acetic acid, (78) 5-ureidohydantoin (allantoin),
(79) 5,5-dimethyl hydantoin, (80) 2-imidazolidone-4-carboxylic acid, and the like;
[0061] (J) pyridines and pyridine derivatives, including those of the general formula

wherein R
1, R
2, R
3, R
4, and R
5 each, independently of the others, can be (but are not limited to) hydrogen atoms,
alkyl groups, preferably with from 1 to about 6 carbon atoms and more preferably with
from 1 to about 3 carbon atoms, substituted alkyl groups, preferably with from 1 to
about 12 carbon atoms and more preferably with from 1 to about 6 carbon atoms, aryl
groups, preferably with from about 6 to about 24 carbon atoms and more preferably
with from about 6 to about 12 carbon atoms, substituted aryl groups, preferably with
from about 6 to about 30 carbon atoms and more preferably with from about 6 to about
18 carbon atoms, arylalkyl groups, preferably with from about 7 to about 31 carbon
atoms and more preferably with from about 7 to about 20 carbon atoms, substituted
arylalkyl groups, preferably with from about 7 to about 32 carbon atoms and more preferably
with from about 7 to about 21 carbon atoms, hydroxy groups, amine groups, imine groups,
ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde groups,
ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl groups,
thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups,
phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups,
mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl
groups, acid anhydride groups, azide groups, and the like, wherein two or more of
R
1, R
2, R
3, R
4, and R
5 can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, I
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, lO
3-, ClO
3-, or the like, as well as mixtures thereof.
[0062] Examples of suitable pyridine compounds include (1) N,N-bis (2-hydroxyethyl) isonicotinamide,
(2) 1,2-bis(4-pyridyl) ethylene, (3) 2-(2-piperidinoethyl) pyridine, (4) 1,2-bis (4-pyridyl)ethane,
(5) 4,4'-trimethylene pyridine, (6) aldrithiol-2, (7) aldrithiol-4, (8) 1,3-bis (3-pyridylmethyl)-2-thiourea,
(9) 2,2':6',2"-terpyridine, (10) 2-[N,N-bis(triflouromethylsulfonyl)amino]pyridine,
(11) 2,3-pyridine dicarboxylic acid, (12) 2,4-pyridine dicarboxylic acid monohydrate,
(13) 2,5-pyridine dicarboxylic acid, (14) 2,6-pyridine dicarboxylic acid, (15) 3,4-pyridine
dicarboxylic acid, (16) 3,5-pyridine dicarboxylic acid, (17) 2,6-pyridine dicarboxaldehyde,
(18) 3,4-pyridine carboxamide, (19) 3,4-pyridine carboximide, (20) 2,3-pyridine carboxylic
anhydride, (21) 3,4-pyridine carboxylic anhydride, (22) 2,6-pyridine methanol, (23)
2-pyridine ethane sulfonic acid, (24) 4-pyridine ethane sulfonic acid, (25) 3-pyridine
sulfonic acid, (26) pyridoxic acid, (27) trans-3-(3-pyridyl) acrylic acid, (28) 2-pyridyl
hydroxymethane sulfonic acid, (29) 3-pyridyl hydroxymethane sulfonic acid, (30) 6-methyl-2,3-pyridine
dicarboxylic acid, (31) isonicotinic acid, (32) pyridine hydrobromide, (33) pyridine
hydrochloride, (34) 2-(chloromethyl) pyridine hydrochloride, (35) 2-pyridylacetic
acid hydrochloride, (36) nicotinoyl chloride hydrochloride, (37) 2-hydrazinopyridine
dihydrochloride, (38) 2-(2-methyl aminoethyl) pyridine dihydrochloride, (39) 1-methyl-1,2,3,6-tetrahydropyridine
hydrochloride, (40) 2,6-dihydroxypyridine hydrochloride, (41) 3-hydroxy-2(hydroxymethyl)
pyridine hydrochloride, (42) pyridoxine hydrochloride, (43) pyridoxal hydrochloride,
(44) pyridoxal 5-phosphate monohydrate, (45) 3-amino-2,6-dimethoxy pyridine hydrochloride,
(46) pyridoxamine dihydrochloride monohydrate, (47) iproniazid phosphate (isonicotinic
acid 2-isopropyl hydrazide phosphate), (48) tripelennamine hydrochloride, (49) pyridinium
bromide perbromide, (50) pyridinium 3-nitrobenzenesulfonate, (51) 1-ethyl-3-hydroxy
pyridinium bromide, (52) 1-ethyl-4-(methoxy carbonyl) pyridinium iodide, (53) 1-heptyl-4-(4-pyridyl)
pyridinium bromide, (54) 1-dodecyl pyridinium chloride, (55) 1-hexadecyl pyridinium
chloride monohydrate, (56) 1-hexadecyl pyridinium bromide monohydrate, (57) 1-(carboxymethyl)
pyridinium chloride, (58) 1-(carboxymethyl) pyridinium chloride hydrazide, (59) 1-(3-nitrobenzyloxymethyl)
pyridinium chloride, (60) 1-(3-sulfopropyl) pyridinium hydroxide, (61) N-(lauroyl
colamino formyl methyl) pyridinium chloride, (62) N-(stearoyl colamine formyl methyl)
pyridinium chloride, (63) 2-chloro-1-methyl pyridinium iodide, (64) 2-pyridine aldoxime-1-methyl
methane sulfonate, (65) 2-pyridine aldoxime-1-methyl chloride, (66) 2-[4-(dimethyl
amino) styryl]1-ethylpyridinium iodide, (67) 1-benzyl-3-hydroxy pyridinium chloride,
(68) 1,4 dimethyl pyridinium iodide, (69) 1-ethyl-4-phenyl pyridinium iodide, (70)
4-phenyl-1-propyl pyridinium iodide, (71) 1-docosyl-4-(4 hydroxystyryl) pyridinium
bromide, (72) 1,1'-dimethyl-4-4'-bipyridinium dichloride, (73) 1,1'-diethyl-4-4'-bipyridinium
dibromide, (74) 1,1'-dibenzyl-4,4'-bipyridinium dichloride, (75) 1,1'-diheptyl-4,4'-bipyridinium
dibromide, (76) 1,7-phenanthroline, (77) 1,10-phenanthroline, (78) 5-chloro-1,10-phenanthroline,
(79) 4,5-dihydro-3-(4-pyridinyl)-2H-benz[g] indazole methane sulfonate, and the like;
[0063] (K) quinolines and quinoline derivatives, and isoquinolines and isoquinoline derivatives,
including those of the general formulae

wherein R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, and R
14 each, independently of the others, can be (but are not limited to) hydrogen atoms,
alkyl groups, preferably with from 1 to about 6 carbon atoms and more preferably with
from 1 to about 3 carbon atoms, substituted alkyl groups, preferably with from 1 to
about 12 carbon atoms and more preferably with from 1 to about 6 carbon atoms, aryl
groups, preferably with from about 6 to about 24 carbon atoms and more preferably
with from about 6 to about 12 carbon atoms, substituted aryl groups, preferably with
from about 6 to about 30 carbon atoms and more preferably with from about 6 to about
18 carbon atoms, arylalkyl groups, preferably with from about 7 to about 31 carbon
atoms and more preferably with from about 7 to about 20 carbon atoms, substituted
arylalkyl groups, preferably with from about 7 to about 32 carbon atoms and more preferably
with from about 7 to about 21 carbon atoms, hydroxy groups, amine groups, imine groups,
ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde groups,
ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl groups,
thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups,
phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups,
mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl
groups, acid anhydride groups, azide groups, and the like, wherein two or more of
R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, and R
14 can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, I
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, lO
3-, ClO
3-, or the like, as well as mixtures thereof.
[0064] Examples of suitable quinoline and isoquinoline compounds include (1) 1,2,3,4-tetrahydro
quinoline, (2) 6-ethoxy-1,2,3,4-tetrahydro-2,2,4-trimethyl quinoline, (3) 2-cyanoquinoline,
cyanoquinoline, (4) 1-cyanoisoquinoline, (5) 3-cyanoisoquinoline, (6) 3-amino quinoline,
(7) (8) 7,8-benzoquinoline, (9) 8-hydroxy quinoline, (10) 8-hydroxyquinoline, aluminium
salt, (11) 8-hydroxyquinaldine, (12) 3,4,5,6,7,8-hexahydro 2 (1H)-quinolinone, (13)
julolidine, (14) quinoxaline, (15) ethyl-2-quinoxalinecarboxylate, (16) quinoline,
(17) 2-hydroxyquinoline, (18) 4-hydroxy quinoline, (19) 5-hydroxy quinoline, (20)
5-amino quinoline, (21) 6-amino quinoline, (22) 2-quinoline carboxylic acid, (23)
3-quinoline carboxylic acid, (24) 4-quinoline carboxylic acid, (25) 4-quinoline carboxaldehyde,
(26) 2-quinoline thiol, (27) 2,4-quinoline diol, ((28) quinaldine, (29) 4-aminoquinaldine,
(30) 2,6-dimethyl quinoline, (31) 2,7-dimethyl quinoline, (32) 4-methoxy-2-quinoline
carboxylic acid, (33) methyl-2-phenyl-4-quinoline carboxylate, (34) 2-(N-butyl carbamoyl)-1,2,3,4-tetrahydro-isoquinoline,
(35) 1-hydroxyisoquinoline, (36) 1-isoquinoline carboxylic acid, (37) 3-isoquinoline
carboxylic acid, (38) 1,5-isoquinoline diol, (39) 8-hydroxyquinoline hemisulfate hemihydrate,
(40) 5-amino-8-hydroxy quinoline dihydrochloride, (41) 2-(chloromethyl) quinoline
monohydrochloride, (42) 8-hydroxyquinoline-5-sulfonic acid monohydrate, (43) 8-ethoxy-5-quinoline
sulfonic acid sodium salt hydrate, (44) 1,2,3,4-tetrahydroisoquinoline hydrochloride,
(45) 1,2,3,4-tetrahydro-3-isoquinoline carboxylic acid hydrochloride, (46) 6,7-dimethoxy-1,2,3,4-tetrahydro
isoquinoline hydrochloride, (47) 1-methyl-6,7-dihydroxy-1,2,3,4-tetrahydro isoquinoline
hydrobromide, (48) primaquine diphosphate [8-(4-amino-1-methyl butyl amino)-6-methoxy
quinoline diphosphate], (49) pentaquine phosphate, (50) dibucaine hydrochloride [2-butoxy-N-(2-diethyl
amino ethyl)-4-quinoline carboxamide hydrochloride], (51) 9-aminoacridine hydrochloride
hemihydrate, (52) 3, 6-diamino acridine hemisulfate, (53) 2-quinoline thiol hydrochloride,
(54) (-) sparteine sulfate pentahydrate, (55) papaverine hydrochloride, (56) (+)-emetine
dihydrochloride hydrate, (57) 1,10-phenanthroline monohydrochloride monohydrate, (58)
neocuproine hydrochloride trihydrate, and the like;
[0065] (L) pyrimidines and pyrimidine derivatives, including those of the general formula

wherein R
1, R
2, R
3, and R
4 each, independently of the others, can be (but are not limited to) hydrogen atoms,
alkyl groups, preferably with from 1 to about 6 carbon atoms and more preferably with
from 1 to about 3 carbon atoms, substituted alkyl groups, preferably with from 1 to
about 12 carbon atoms and more preferably with from 1 to about 6 carbon atoms, aryl
groups, preferably with from about 6 to about 24 carbon atoms and more preferably
with from about 6 to about 12 carbon atoms, substituted aryl groups, preferably with
from about 6 to about 30 carbon atoms and more preferably with from about 6 to about
18 carbon atoms, arylalkyl groups, preferably with from about 7 to about 31 carbon
atoms and more preferably with from about 7 to about 20 carbon atoms, substituted
arylalkyl groups, preferably with from about 7 to about 32 carbon atoms and more preferably
with from about 7 to about 21 carbon atoms, hydroxy groups, amine groups, imine groups,
ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde groups,
ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl groups,
thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups,
phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups,
mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl
groups, acid anhydride groups, azide groups, and the like, wherein two or more of
R
1, R
2, R
3, and R
4 can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, I
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, IO
3-, BrO
3-, or the like, as well as mixtures thereof.
[0066] Examples of suitable pyrimidines include (1) pyrimidine, (2) 2 chloropyrimidine,
(3) 4-phenylpyrimidine, (4) 5-bromopyrimidine, (5) 2,4-dichloropyrimidine, (6) 4,6-dichloropyrimidine,
(7) 2,4-dichloro-6-methylpyrimidine, (8) 6-chloro-2,4-dimethoxypyrimidine, (9) 2-amino-4,6-dimethoxypyrimidine,
(10) 2,4,6-trichloropyrimidine, (11) 2,4,5,6-tetrachloropyrimidine, (12) 1,3,4,6,7,8-hexahydro-1-methyl-2H-pyrimido
[1,2-a] pyrimidine, (13) 1,3,4,6,7,8-hexahydro-2H-pyrimido [1,2-a] pyrimidine, (14)
hexetidine, (15) tert-butyl S-(4,6-dimethylpyrimidin-2-yl) thiocarbonate, (16) 4-methoxybenzyl-S(4,6-dimethylpyrimidin-2-yl)
thiocarbonate, (17) 2-amino pyrimidine, (18) 2-amino-4-methyl pyrimidine, (19) 2-amino-5-nitropyrimidine,
(20) 2-amino-5-bromopyrimidine, (21) 2-amino-4-chloro-6-methyl pyrimidine, (22) 2-amino-4,6-dimethyl
pyrimidine, (23) 2-amino-4-hydroxy-6-methyl pyrimidine, (24) 2-amino-4,6-dichloropyrimidine,
(25) 2-amino-5-bromo-6-methyl-4-pyrimidinol, (26) 4-aminopyrimidine, (27) 4,5-diamino
pyrimidine, (28) 4-amino-2,6-dimethyl pyrimidine, (29) 2,4-diamino-6-hydroxypyrimidine,
(30) 2,6-diamino-4-chloro pyrimidine, (31) 4,6-diamino-2-mercaptopyrimidine hemihydrate,
(32) 2,4,6-triamino pyrimidine, (33) 5-nitroso-2,4,6-triamino pyrimidine, (34) 4,6-dihydroxy
pyrimidine, (35) 4,6-dihydroxy-2-amino pyrimidine, (36) 4,6-dihydroxy-2-methyl pyrimidine,
(37) 4,6-dihydroxy-5-nitropyrimidine, (38) 2,4-dihydroxy-5-methyl pyrimidine, (39)
2,4-dihydroxy-6-methyl pyrimidine, (40) 2,4-dihydroxy-5,6-dimethyl pyrimidine, (41)
2,6-dihydroxy pyrimidine-5-carboxylic acid hydrate, (42) 2,6-dihydroxy-4-amino pyrimidine,
(43) 2,4,5-trihydroxy pyrimidine, (44) 2-thiouracil [4-hydroxy-2-mercaptopyrimidine],
(45) 6-amino-5-nitroso-2-thiouracil, (46) folic acid dihydrate, (47) folinic acid,
calcium salt hydrate, (48) 2-hydroxypyrimidine hydrochloride, (49) 2-hydroxy-4-methyl
pyrimidine hydrochloride, (50) 4,6-dimethyl-2-hydroxypyrimidine hydrochloride, (51)
2-mercapto-4-methyl pyrimidine hydrochloride, (52) 4,6-diamino pyrimidine hemisulfate
monohydrate, (53) 4,5,6-triamino pyrimidine sulfate hydrate, (54) 4,5-diamino-6-hydroxy
pyrimidine sulfate, (55) 2,4-diamino-6-mercapto pyrimidine hemisulfate, (56) 2,4-diamino-6-hydroxy
pyrimidine hemisulfate hydrate, (57) 6-hydroxy-2,4,5-triamino pyrimidine sulfate,
(58) 5,6-diamino-2,4-dihydroxy pyrimidine sulfate, (59) N4-(2-amino-4-pyrimidinyl)
sulfanilamide monohydrochloride, (60) 2,4,5,6-tetraamino pyrimidine sulfate, (61)
pyrimidine diones, including those of the general formula

wherein R
1, R
2, R
3, and R
4 each, independently of the others, can be (but are not limited to) hydrogen atoms,
alkyl groups, preferably with from 1 to about 6 carbon atoms and more preferably with
from 1 to about 3 carbon atoms, substituted alkyl groups, preferably with from 1 to
about 12 carbon atoms and more preferably with from 1 to about 6 carbon atoms, aryl
groups, preferably with from about 6 to about 24 carbon atoms and more preferably
with from about 6 to about 12 carbon atoms, substituted aryl groups, preferably with
from about 6 to about 30 carbon atoms and more preferably with from about 6 to about
18 carbon atoms, arylalkyl groups, preferably with from about 7 to about 31 carbon
atoms and more preferably with from about 7 to about 20 carbon atoms, substituted
arylalkyl groups, preferably with from about 7 to about 32 carbon atoms and more preferably
with from about 7 to about 21 carbon atoms, hydroxy groups, amine groups, imine groups,
ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde groups,
ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl groups,
thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups,
phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups,
mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl
groups, acid anhydride groups, azide groups, and the like, wherein two or more of
R
1, R
2, R
3, and R
4 can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, I
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, lO
3-, ClO
3-, or the like, as well as mixtures thereof, such as (a) 2,4 (1H,3H)-pyrimidine dione
(uracil), (b) 5-amino uracil, (c) 5-nitrouracil, (d) 5-iodouracil, (e) 5-(hydroxymethyl)
uracil hydrate, (f) 5,6-dihydrouracil, (g) 6-amino-1-methyl uracil, (h) 5,6-diamino-1,3-dimethyl
uracil hydrate, (i) uridine, (j) 5-methyl uridine, (k) 5-iodouridine, (I) thimidine,
and the like; (62) thiouracils, such as (a) 5-methyl-2-thiouracil, (b) 4-thiouridine,
(c) 2-thiocytidine dihydrate, and the like; (63) orotic acid compounds, such as (a)
orotic acid monohydrate, (b) L-hydroorotic acid, (c) 5-aminoorotic acid, (d) methylorotate
(orotic acid methyl ester), and the like; (64) pyrimidine trione compounds, such as
(a) barbituric acid, (b) 5-nitrobarbituric acid trihydrate, (c) violuric acid monohydrate,
(d) alloxan monohydrate [2,4,5,6-(1H,3H)-pyrimidine-tetrone], (65) 4,5,6-triamino-2(1H)-pyrimidinethione
sulfate, (66) (-)-cyclocytidine hydrochloride, (67) cytosine arabinoside hydrochloride,
and the like;
[0067] (M) pyradizines and pyridazine derivatives, including those of the general formula

wherein R
1, R
2, R
3, and R
4 each, independently of the others, can be (but are not limited to) hydrogen atoms,
alkyl groups, preferably with from 1 to about 6 carbon atoms and more preferably with
from 1 to about 3 carbon atoms, substituted alkyl groups, preferably with from 1 to
about 12 carbon atoms and more preferably with from 1 to about 6 carbon atoms, aryl
groups, preferably with from about 6 to about 24 carbon atoms and more preferably
with from about 6 to about 12 carbon atoms, substituted aryl groups, preferably with
from about 6 to about 30 carbon atoms and more preferably with from about 6 to about
18 carbon atoms, arylalkyl groups, preferably with from about 7 to about 31 carbon
atoms and more preferably with from about 7 to about 20 carbon atoms, substituted
arylalkyl groups, preferably with from about 7 to about 32 carbon atoms and more preferably
with from about 7 to about 21 carbon atoms, hydroxy groups, amine groups, imine groups,
ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde groups,
ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl groups,
thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups,
phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups,
mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl
groups, acid anhydride groups, azide groups, and the like, wherein two or more of
R
1, R
2, R
3, and R
4 can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, l
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, lO
3-, ClO
3-, or the like, as well as mixtures thereof.
[0068] Examples of suitable pyridazines include (1) pyridazine, (2) phthalazine, (3) 4,5-dihydro-6-methyl-3(2H)-pyridazinone
monohydrate, (4) 3,6-dichloropyridazine, (5) 3,4,5-trichloropyridazine, (6) 3,6-dichloro-4-methylpyridazine,
(7) 3-chloro-6-methoxypyridazine, and the like;
[0069] (N) pyrazines and pyrazine derivatives, including those of the general formula

wherein R
1, R
2, R
3, and R
4 each, independently of the others, can be (but are not limited to) hydrogen atoms,
alkyl groups, preferably with from 1 to about 6 carbon atoms and more preferably with
from 1 to about 3 carbon atoms, substituted alkyl groups, preferably with from 1 to
about 12 carbon atoms and more preferably with from 1 to about 6 carbon atoms, aryl
groups, preferably with from about 6 to about 24 carbon atoms and more preferably
with from about 6 to about 12 carbon atoms, substituted aryl groups, preferably with
from about 6 to about 30 carbon atoms and more preferably with from about 6 to about
18 carbon atoms, arylalkyl groups, preferably with from about 7 to about 31 carbon
atoms and more preferably with from about 7 to about 20 carbon atoms, substituted
arylalkyl groups, preferably with from about 7 to about 32 carbon atoms and more preferably
with from about 7 to about 21 carbon atoms, hydroxy groups, amine groups, imine groups,
ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde groups,
ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl groups,
thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups,
phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups,
mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl
groups, acid anhydride groups, azide groups, and the like, wherein two or more of
R
1, R
2, R
3, and R
4 can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, l
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, lO
3-, ClO
3-, or the like, as well as mixtures thereof.
[0070] Examples of suitable pyrazines include (1) pyrazine, (2) acetylpyrazine, (3) aminopyrazine,
(4) 2,6-dichloropyrazine, (5) 2,3,5-trimethylpyrazine, (6) tetramethylpyrazine, (7)
5-methyl-2-pyrazine carboxylic acid, (8) pyrazine amide, (9) 2,3-pyrazine dicarboxamide,
(10) 4-pyridazine carboxylic acid, (11) 2,3-pyrazine dicarboxylic acid, (12) lumazine
monohydrate, (13) xanthopterin monohydrate, (14) 2-quinoxazoline carboxylic acid,
(15) 2-quinoxalinol, (16) 2,3-dihydroxy quinoxaline, (17) phenazine methosulfate,
and the like;
[0071] (O) lactams and lactam derivatives, and thiolactams and thiolactam derivatives, including
those of the general formulae

wherein R
1 can be selected from (but is not limited to) hydrogen atoms, alkyl groups, preferably
with from 1 to about 6 carbon atoms and more preferably with from 1 to about 3 carbon
atoms, substituted alkyl groups, preferably with from 1 to about 12 carbon atoms and
more preferably with from 1 to about 6 carbon atoms, aryl groups, preferably with
from about 6 to about 24 carbon atoms and more preferably with from about 6 to about
12 carbon atoms, substituted aryl groups, preferably with from about 6 to about 30
carbon atoms and more preferably with from about 6 to about 18 carbon atoms, arylalkyl
groups, preferably with from about 7 to about 31 carbon atoms and more preferably
with from about 7 to about 20 carbon atoms, substituted arylalkyl groups, preferably
with from about 7 to about 32 carbon atoms and more preferably with from about 7 to
about 21 carbon atoms, hydroxy groups, amine groups, imine groups, ammonium groups,
pyridine groups, pyridinium groups, ether groups, aldehyde groups, ketone groups,
ester groups, amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl
groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine
groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups, mercapto
groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl groups,
acid anhydride groups, azide groups, and the like, and wherein the curved portion
of the structure represents a hydrocarbon chain or a substituted hydrocarbon chain,
preferably of from about 2 to about 10 carbon atoms, wherein two or more substituents
can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, substituted arylalkyl groups, and substituted
hydrocarbon chain can be (but are not limited to) hydroxy groups, amine groups, imine
groups, ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde
groups, ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl
groups, thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide
groups, phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile
groups, mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups,
acyl groups, acid anhydride groups, azide groups, and the like, wherein two or more
substituents can be joined together to form a ring. Other variations are also possible,
such as a double bond between one of the ring carbon atoms and another atom, such
as carbon, oxygen, or the like. These compounds can also be in acid salt form, wherein
they are associated with a compound of the general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, l
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, lO
3-, ClO
3-, or the like, as well as mixtures thereof.
[0072] Examples of suitable lactams and thiolactams include (1) 2-azetidinone (β-propiolactam),
propiolactam), (2) 2-pyrrolidinone, (3) pyrrolidone hydrotribromide, (4) δ-valerolactam,
(5) ε-caprolactam, (6) amino-ε-caprolactam, (7) N-methyl caprolactam, (8) 2-azacyclooctanone,
(9) 2-azacyclononanone, (10) ω-thiocaprolactam, (11) N-vinylcaprolactam, (12) (±)-2-azabicyclo[2.2.1]hept-5-en-3-one,
and the like;
[0073] (P) imides and imide derivatives, including those of the general formula

wherein R
1 can be selected from (but is not limited to) hydrogen atoms, alkyl groups, preferably
with from 1 to about 6 carbon atoms and more preferably with from 1 to about 3 carbon
atoms, substituted alkyl groups, preferably with from 1 to about 12 carbon atoms and
more preferably with from 1 to about 6 carbon atoms, aryl groups, preferably with
from about 6 to about 24 carbon atoms and more preferably with from about 6 to about
12 carbon atoms, substituted aryl groups, preferably with from about 6 to about 30
carbon atoms and more preferably with from about 6 to about 18 carbon atoms, arylalkyl
groups, preferably with from about 7 to about 31 carbon atoms and more preferably
with from about 7 to about 20 carbon atoms, substituted arylalkyl groups, preferably
with from about 7 to about 32 carbon atoms and more preferably with from about 7 to
about 21 carbon atoms, hydroxy groups, amine groups, imine groups, ammonium groups,
pyridine groups, pyridinium groups, ether groups, aldehyde groups, ketone groups,
ester groups, amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl
groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine
groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups, mercapto
groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl groups,
acid anhydride groups, azide groups, and the like, and wherein the curved portion
of the structure represents a hydrocarbon chain or a substituted hydrocarbon chain,
preferably of from about 1 to about 20 carbon atoms, wherein two or more substituents
can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, substituted arylalkyl groups, and substituted
hydrocarbon chain can be (but are not limited to) hydroxy groups, amine groups, imine
groups, ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde
groups, ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl
groups, thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide
groups, phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile
groups, mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups,
acyl groups, acid anhydride groups, azide groups, and the like, wherein two or more
substituents can be joined together to form a ring. Other variations are also possible,
such as a double bond between one of the ring carbon atoms and another atom, such
as carbon, oxygen, or the like. These compounds can also be in acid salt form, wherein
they are associated with a compound of the general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, l
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, lO
3-, ClO
3-, or the like, as well as mixtures thereof.
[0074] Examples of suitable imide compounds include (1) maleimide, (2) N-ethylmaleimide,
(3) N-butylmaleimide, (4) N-cyclohexylmaleimide, (5) N-phenylmaleimide, (6) N-benzylmaleimide,
(7) N-hydroxymaleimide, (8) succinimide, (9) N-methylsuccinimide, (10) (S)-(-)-2-hydroxy-N-methylsuccinimide,
(11) N-hydroxysuccinimide, (12) succinimidyl 2,2,2-trichloroethyl carbonate, (13)
2-dodecyl-N-(2,2,6,6-tetramethyl-4-ppiperidinyl) succinimide, (14) 2-dodecyl-N-(1,2,2,6,6-pentamethyl-4-piperdinyl)
succinimide, (15) N-(1-acetyl-2,2,6,6-tetramethyl-4-piperidinyl)-2-dodecyl succinimide,
(16) α-methyl-α-propylsuccinimide, (17) α-methyl-α-phenylsuccinimide, (18) N-vinylphthalimide,
(19) N-ethylphthalimide, (20) N-(trimethylsilylmethyl)phthalimide, (21) N-(2-bromoethyl)phthalimide,
(22) N-(3-bromopropyl)phthalimide, (23) N-(4-bromobutyl)phthalimide, (24) phthalimidoacetaldehyde
diethyl acetal, (25) diethyl (phthalimidomethyl)phosphonate, (26) N-benzylphthalimide,
(27) phthalimide, DBU (1,8-diazabicyclo [5.4.0]undec-7-ene) salt, (28) phthalimide,
DBN (1,5-diazabicyclo [4.3.0]non-5-ene), and the like;
[0075] II. Oxa-aza-cyclic compounds, including (A) oxazoles and oxazole derivatives, and
isoxazoles and isoxazole derivatives, including those of the general formulae

wherein R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
14, and R
15 each, independently of the others, can be (but are not limited to) hydrogen atoms,
alkyl groups, preferably with from 1 to about 6 carbon atoms and more preferably with
from 1 to about 3 carbon atoms, substituted alkyl groups, preferably with from 1 to
about 12 carbon atoms and more preferably with from 1 to about 6 carbon atoms, aryl
groups, preferably with from about 6 to about 24 carbon atoms and more preferably
with from about 6 to about 12 carbon atoms, substituted aryl groups, preferably with
from about 6 to about 30 carbon atoms and more preferably with from about 6 to about
18 carbon atoms, arylalkyl groups, preferably with from about 7 to about 31 carbon
atoms and more preferably with from about 7 to about 20 carbon atoms, substituted
arylalkyl groups, preferably with from about 7 to about 32 carbon atoms and more preferably
with from about 7 to about 21 carbon atoms, hydroxy groups, amine groups, imine groups,
ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde groups,
ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl groups,
thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups,
phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups,
mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl
groups, acid anhydride groups, azide groups, and the like, wherein two or more of
R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
14, and R
15 can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, l
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, lO
3-, ClO
3-, or the like, as well as mixtures thereof.
[0076] Examples of suitable oxazole and isoxazole compounds include (1) 3-amino-5-methyl
isoxazole, (2) 5-amino-3-methyl isoxazole, (3) 3,5-dimethyl-4-nitroisoxazole, (4)
1,2-benzisoxazole, (5) 2,1-benzisoxazole (Anthranil), (6) cycloserine [4-amino-3-isoxazolidinone],
(7) 4-benzyl-2-methyl-2-oxazoline, (8) 2-methyl-5-phenyl-2-oxazoline-4-methanol, (9)
benzoxazole, (10) 2-methylbenzoxazole, (11) 2-chlorobenzoxazole, (12) 2-chloro-3-ethylbenzeneoxazolium
tetrafluoroborate, (13) 2-oxazolidone, (14) 3-methyl-2-oxazolidinone, (15) 5-chloromethyl-2-oxazolidinone,
(16) 4-isopropyl-2-oxazolidinone, (17) 3-acetyl-2-oxazolidinone, (18) 5,5-dimethyl
oxazolidine-2,4-dione, (19) 3-ethyl-2-thioxo-4-oxazolidinone, (20) 4-methyl-5-phenyl-2-oxazolidinone,
(21) 4-benzyl-2-oxazolidinone, (22) 2-benzoisoxazolinone, (23) muscimol hydrate [5-(aminomethyl)-3-isoxazolol
hydrate], (24) 5-methyl-3-phenyl isoxazole-4-carboxylic acid, (25) 2-methyl-5-phenyl-2-oxazoline-4-methanol,
(26) sulfamethoxazole [4-amino-N-(5-methyl-3-isoxazolyl) benzene sulfonamide], (27)
sulfisoxazole [4-amino-N-(3,4-dimethyl-5-isoxazolyl) benzene sulfonamide], (28) N'-(4,5-dimethyloxazol-2-yl)
sulfanilamide, (29) cycloserine [4-amino-3-isoxazolidinone], (30) chlorzoxazone [5-chloro-2-benzoxazolone],
(31) 3,3'-dimethyl oxacarbocyanine iodide, (32) 2-ethyl-5-phenyl isoxazolium-3'-sulfonate,
(33) 2-chloro-3-ethylbenzoxazolium tetrafluoroborate, (34) 2-tert-butyl-5-methyl isoxazolium
perchlorate, (35) 5-phenyl-2-(4-pyridyl) oxazole hydrochloride hydrate, (36) 5-phenyl-2-(4-pyridyl)
oxazole methyl tosylate salt, and the like;
[0077] (B) morpholines and morpholine derivatives, including those of the general formula

wherein R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, and R
9 each, independently of the others, can be (but are not limited to) hydrogen atoms,
alkyl groups, preferably with from 1 to about 6 carbon atoms and more preferably with
from 1 to about 3 carbon atoms, substituted alkyl groups, preferably with from 1 to
about 12 carbon atoms and more preferably with from 1 to about 6 carbon atoms, aryl
groups, preferably with from about 6 to about 24 carbon atoms and more preferably
with from about 6 to about 12 carbon atoms, substituted aryl groups, preferably with
from about 6 to about 30 carbon atoms and more preferably with from about 6 to about
18 carbon atoms, arylalkyl groups, preferably with from about 7 to about 31 carbon
atoms and more preferably with from about 7 to about 20 carbon atoms, substituted
arylalkyl groups, preferably with from about 7 to about 32 carbon atoms and more preferably
with from about 7 to about 21 carbon atoms, hydroxy groups, amine groups, imine groups,
ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde groups,
ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl groups,
thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups,
phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups,
mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl
groups, acid anhydride groups, azide groups, and the like, wherein two or more of
R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, and R
9 can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, l
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, lO
3-, ClO
3-, or the like, as well as mixtures thereof.
[0078] Examples of suitable morpholines include (1) 4-aminomorpholine, (2) 4-morpholine
carbonitrile, (3) 4-morpholine propionitrile, (4) 4-formyl morpholine, (5) 4-acetylmorpholine,
(6) 4-(2-hydroxyethyl) morpholine, (7) 3-morpholino-1,2-propane diol, (8) 4-(3-amino
propyl) morpholine, (9) 1-morpholino-1-cyclopentene, (10) 1-morpholino-1-cyclohexene,
(11) 1-morpholino-1-cycloheptene, (12) 4-phenyl morpholine, (13) 4-morpholinoaniline,
(14) 2,2,2-tribromoethyl phosphoromorpholino chloridate, (15) 1-(morpholino carbonyl
methyl) piperazine, (16) 1,3-dimorpholine-2-nitropropane, (17) hemicholinium-3, (18)
hemicholinium-15, (19) 2-methoxy-4-morpholinobenzene diazoniumchloride, zinc chloride,
(20) fomocaine, (21) 4-morpholinobenzophenone, (22) 4,4'-ethylene-bis (2,6-morpholinedione),
(23) N,N'-dicylcohexyl-4-morpholine carboxamidine, (24) 1-cyclohexyl-3-(2-morpholino
ethyl)-2-thiourea, (25) 4-morpholinoacetophenone, (26) 4-(2-chloroethyl) morpholine
hydrochloride, (27) 4-morpholine ethane sulfonic acid, (28) 4-morpholine propane sulfonic
acid, (29) β-hydroxy morpholine propane sulfonic acid, (30) [N-(aminoiminomethyl)-4-morpholine
carboximidamide] hydrochloride, (31) 4-morpholine carbodithioic acid compound with
morpholine, (32) 2,5-dimethyl-4-(morpholinomethyl) phenol hydrochloride monohydrate,
(33) 1-cyclohexyl-3-(2-morpholinoethyl) carbodiimide metho-p-toluene sulfonate, (34)
hemicholinium-3[2,2'-(4,4'-biphenylene) bis(2-hydroxy-4,4-dimethyl morpholinium bromide),
(35) hemicholinium-15[4,4-dimethyl-2-hydroxy-2-phenyl morpholinium bromide], and the
like; (C) cyclic aza-ethers and diazaethers, such as (1) 1-aza-12-crown-4, (2) 1-aza-15-crown-5,
(3) 1-aza-18-crown-6, (4) 1,4,10-trioxa-7,13-diazacyclopentadecane, (5) 1,4,10,13-tetraoxa-7,16-diazacyclooctadecane,
(6) N,N'-dibenzyl-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane, (7) 4,7,13,18-tetraoxa-1,10-diazabicyclo
[8.5.5] eicosane, (8) 4,7,13,16,21-pentaoxa-1,10-diazabicyclo [8.5.5] tricosane, (9)
4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo [8.8.8] hexacosane, (10) 5,6-benzo-4,17,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]
hexacosane, and the like;
[0079] III. Oxacyclic compounds, including (A) cyclic compounds wherein the ring contains
one oxygen atom, such as (1) lactones and lactone derivatives, including those of
the general formula

wherein the curved portion of the structure represents a hydrocarbon chain or a substituted
hydrocarbon chain, preferably of from about 2 to about 20 carbon atoms, wherein two
or more substituents can be joined together to form a ring, and wherein the substituents
on the hydrocarbon chain can be (but are not limited to) alkyl groups, preferably
with from 1 to about 6 carbon atoms and more preferably with from 1 to about 3 carbon
atoms, substituted alkyl groups, preferably with from 1 to about 12 carbon atoms and
more preferably with from 1 to about 6 carbon atoms, aryl groups, preferably with
from about 6 to about 24 carbon atoms and more preferably with from about 6 to about
12 carbon atoms, substituted aryl groups, preferably with from about 6 to about 30
carbon atoms and more preferably with from about 6 to about 18 carbon atoms, arylalkyl
groups, preferably with from about 7 to about 31 carbon atoms and more preferably
with from about 7 to about 20 carbon atoms, substituted arylalkyl groups, preferably
with from about 7 to about 32 carbon atoms and more preferably with from about 7 to
about 21 carbon atoms, hydroxy groups, amine groups, imine groups, ammonium groups,
pyridine groups, pyridinium groups, ether groups, aldehyde groups, ketone groups,
ester groups, amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl
groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine
groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups, mercapto
groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl groups,
acid anhydride groups, azide groups, and the like, wherein two or more substituents
can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, I
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, lO
3-, ClO
3-, or the like, as well as mixtures thereof.
[0080] Examples of lactone compounds include (a) γ-butyrolactone, (b) γ-valerolactone, (c)
γ-caprolactone, (d) γ-octanoic lactone, (e) γ-nonanoic lactone, (f) γ-decanolactone,
(g) undecanoic γ-lactone, (h) γ-phenyl-γ-butyrolactone, (i) (±)-α-carbethoxy-γ-phenyl-butyrolactone,
(j) 2-coumaranone, (k) (±)-β,β-dimethyl-γ-(hydroxymethyl)-γ-butyrolactone, (I) (S)-(+)-γ-ethoxy
carbonyl-γ-butyrolactone, (m) (S)-(-)-5-(hydroxymethyl)-2(5H)-furanone, (n) dihydro-4,4-dimethyl-2,3-furandione,
(o) 2,5-dimethyl-4-hydroxy-3(2H)-furanone, (p) (±)-mevalonic (β-hydroxy β-methyl-δ-valero)
lactone, (q) (±)-δ-decanolactone, (r) (±)-undecanoic δ-lactone, (s) (±)-δ-dodecanolactone,
(t) undecanoic ω-lactone, (u) oxacyclotridecan-2-one, (v) ω-pentadecalactone, (w)
hydrindantin (2,2'-dihydroxy-2,2'-biindan-1,1'3,3'-tetrone, (x) hydrindantin dihydrate,
(y) 2-oxepanone, and the like;
(2) pyrans and pyran derivatives, including those of the general formulae

wherein R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
14, R
15, R
16, R
17, R
18, R
19, R
20, R
21, R
22, R
23, R
24, R
25, R
26, R
27, and R
28 each, independently of the others, can be (but are not limited to) hydrogen atoms,
alkyl groups, preferably with from 1 to about 6 carbon atoms and more preferably with
from 1 to about 3 carbon atoms, substituted alkyl groups, preferably with from 1 to
about 12 carbon atoms and more preferably with from 1 to about 6 carbon atoms, aryl
groups, preferably with from about 6 to about 24 carbon atoms and more preferably
with from about 6 to about 12 carbon atoms, substituted aryl groups, preferably with
from about 6 to about 30 carbon atoms and more preferably with from about 6 to about
18 carbon atoms, arylalkyl groups, preferably with from about 7 to about 31 carbon
atoms and more preferably with from about 7 to about 20 carbon atoms, substituted
arylalkyl groups, preferably with from about 7 to about 32 carbon atoms and more preferably
with from about 7 to about 21 carbon atoms, hydroxy groups, amine groups, imine groups,
ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde groups,
ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl groups,
thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups,
phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups,
mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl
groups, acid anhydride groups, azide groups, and the like, wherein two or more of
R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
14, R
15, R
16, R
17, R
18, R
19, R
20, R
21, R
22, R
23, R
24, R
25, R
26, R
27, and R
28 can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, l
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, lO
3-, ClO
3-, or the like, as well as mixtures thereof.
[0081] Examples of pyran compounds include (a) 4H-pyran-2-one, (b) methylcoumalate (methyl-2-oxo-2H-pyran-5-carboxylate,
(c) methyl 2-oxo-2H-pyran-3-carboxylate, (d) 4,6-dimethyl-α-pyrone, (e) 4-methoxy-6-methyl-2H-pyran-2-one,
(f) 2-oxo-6-pentyl-2H-pyran-3-carboxylic acid, (g) methylisodehydracetate, (h) ethylisodehydracetate,
(i) 5,6-dihydro-2H-pyran-2-one, (j) 3,6-dihydro-4,6,6-trimethyl-2H-pyran-2-one, (k)
3,4-dihydro-6-methyl-2H-pyran-2-one, (I) 3-acetyl coumarin, (m) 6-methyl coumarin,
(n) 7-ethoxy coumarin, (o) ethyl-3-coumarin carboxylate, (p) 7-diethylamino-4-methyl
coumarin, (q) dihydro coumarin, (r) 3-bromo-2-coumaranone, (s) patulin (4-hydroxy-4H-furo[3.2.c]pyran-2(6H)-one),
(t) 4H-pyran-4-one, (u) 2-ethyl-3-hydroxy-4H-pyran-4-one, (v) butopyronoxyl(butyl
3,4-dihydro-2,2-dimethyl-4-oxo-2H-pyran-6-carboxylate, (w) dehydroacetic acid, (x)
4-chromone (1-benzylpyran-4(4H)-one), (y) 4-chromanone, (z) 4-chromanol, (aa) 6,7-dimethoxy-2,2-dimethyl-4-chromanone,
(bb) 3-isochromanone, (cc) 6,7-dimethoxy-3-isochromanone, (dd) 6-ethyl-4-oxo-4H-1-benzopyran-3-carbonitrile,
(ee) 6-ethyl-4-oxo-4H-1-benzopyran-3-carboxaldehyde, (ff) 6-isopropyl-4-oxo-4H-1-benzopyran-3-carbonitrile,
(gg) 6-isopropyl-4-oxo-4H-1-benzopyran-3-carboxaldehyde, and the like;
(3) cyclic anhydrides and anhydride derivatives, including those of the general formulae

wherein the curved portion of the structure represents a hydrocarbon chain or a substituted
hydrocarbon chain, preferably of from about 1 to about 20 carbon atoms, wherein two
or more substituents can be joined together to form a ring, and wherein the substituents
on the hydrocarbon chain can be (but are not limited to) alkyl groups, preferably
with from 1 to about 6 carbon atoms and more preferably with from 1 to about 3 carbon
atoms, substituted alkyl groups, preferably with from 1 to about 12 carbon atoms and
more preferably with from 1 to about 6 carbon atoms, aryl groups, preferably with
from about 6 to about 24 carbon atoms and more preferably with from about 6 to about
12 carbon atoms, substituted aryl groups, preferably with from about 6 to about 30
carbon atoms and more preferably with from about 6 to about 18 carbon atoms, arylalkyl
groups, preferably with from about 7 to about 31 carbon atoms and more preferably
with from about 7 to about 20 carbon atoms, substituted arylalkyl groups, preferably
with from about 7 to about 32 carbon atoms and more preferably with from about 7 to
about 21 carbon atoms, hydroxy groups, amine groups, imine groups, ammonium groups,
pyridine groups, pyridinium groups, ether groups, aldehyde groups, ketone groups,
ester groups, amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl
groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine
groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups, mercapto
groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl groups,
acid anhydride groups, azide groups, and the like, wherein two or more substituents
can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, l
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, lO
3-, ClO
3-, or the like, as well as mixtures thereof.
[0082] Examples of cyclic anhydrides include (a) maleic anhydride, (b) bromomaleic anhydride,
(c) citraconic anhydride, (d) 2,3-dimethylmaleic anhydride, (e) dichloromaleic anhydride,
(f) cis-aconitic anhydride, (g) itaconic anhydride, (h) methylsuccinic anhydride,
(i) S-acetylmercaptosuccinic anhydride, (j) 2,2-dimethylsuccinic anhydride, (k) phenylsuccinic
anhydride, (l) (±)-2-octen-1-ylsuccinic anhydride, (m) 2-dodecen-1-ylsuccinic anhydride,
(n) 2-octadecen-1-ylsuccinic anhydride, (o) 3-oxabicyclo [3.1.0] hexane-2,4-dione,
(p) diglycolic anhydride, (q) glutaric anhydride, (r) 3-methylglutaric anhydride,
(s) 2,2-dimethylglutaric anhydride, (t) 3,3-tetramethyleneglutaric anhydride, (u)
1-cyclopentene-1,2-dicarboxylic anhydride, (v) 3,4,5,6-tetrahydrophthalic anhydride,
(w) cis-1,2-cyclohexanedicarboxylic anhydride, (x) (±)-hexahydro-4-methylphthalic
anhydride, (y) methyl-5-norbornene-2,3-dicarboxylic anhydride, (z) 2,3-pyridinecarboxylic
anhydride, (aa) 3,4-pyridinecarboxylic anhydride, and the like; (4) cyclic oxa-sulfur
compounds and their derivatives, including (a) furfurylmercaptan, (b) S-furfurylthioacetate,
(c) furfurylsulfide, (d) furfurylmethyldisulfide, (e) furfuryldisulfide, and the like;
(B) cyclic compounds wherein the ring contains at least two oxygen atoms, such as
(1) dioxanes and dioxane derivatives, and trioxanes and trioxand derivatives, including
those of the general formulae

wherein R
1, R
2, R
3, R
4, R
5, R
6, R
7, and R
8 each, independently of the others, can be (but are not limited to) hydrogen atoms,
alkyl groups, preferably with from 1 to about 6 carbon atoms and more preferably with
from 1 to about 3 carbon atoms, substituted alkyl groups, preferably with from 1 to
about 12 carbon atoms and more preferably with from 1 to about 6 carbon atoms, aryl
groups, preferably with from about 6 to about 24 carbon atoms and more preferably
with from about 6 to about 12 carbon atoms, substituted aryl groups, preferably with
from about 6 to about 30 carbon atoms and more preferably with from about 6 to about
18 carbon atoms, arylalkyl groups, preferably with from about 7 to about 31 carbon
atoms and more preferably with from about 7 to about 20 carbon atoms, substituted
arylalkyl groups, preferably with from about 7 to about 32 carbon atoms and more preferably
with from about 7 to about 21 carbon atoms, hydroxy groups, amine groups, imine groups,
ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde groups,
ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl groups,
thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups,
phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups,
mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl
groups, acid anhydride groups, azide groups, and the like, wherein two or more of
R
1, R
2, R
3, R
4, R
5, R
6, R
7, and R
8 can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, l
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, lO
3-, ClO
3-, or the like, as well as mixtures thereof.
[0083] Examples of suitable dioxanes and trioxanes include (a) glycolaldehyde dimer (2,5-dihydroxy-1,4-dioxane),
(b) 6,7-dihydrocyclopenta-1,3-dioxin-5(4H)-one, (c) (2R,6R)-tert-butyl-6-methyl-1,3-dioxan-4-one,
6-methyl-1,3-dioxan-4-one, (d) 2,2-dimethyl-1,3-dioxane-4,6-dione, (e) (f) 2,2,6-trimethyl-4H-1,3-dioxin-4-one,
(g) 2,2,5-trimethyl-1,3-dioxane-4,6-dione, (h) 5-bromo-2,2,5-trimethyl-1,3-dioxane-4,6-dione,
(i) 1,3-dioxane-5,5-dimethanol, (j) 1,3,5-trioxane, and the like; (2) oxaspiros and
oxaspiro derivatives, and ketals and ketal derivatives, including those of the general
formulae

wherein the curved portions of the structures represent a hydrocarbon chain or a
substituted hydrocarbon chain, preferably of from 1 to about 20 carbon atoms, wherein
two or more substituents can be joined together to form a ring, and wherein the substituents
on the hydrocarbon chains can be (but are not limited to) hydrogen atoms, alkyl groups,
preferably with from 1 to about 6 carbon atoms and more preferably with from 1 to
about 3 carbon atoms, substituted alkyl groups, preferably with from 1 to about 12
carbon atoms and more preferably with from 1 to about 6 carbon atoms, aryl groups,
preferably with from about 6 to about 24 carbon atoms and more preferably with from
about 6 to about 12 carbon atoms, substituted aryl groups, preferably with from about
6 to about 30 carbon atoms and more preferably with from about 6 to about 18 carbon
atoms, arylalkyl groups, preferably with from about 7 to about 31 carbon atoms and
more preferably with from about 7 to about 20 carbon atoms, substituted arylalkyl
groups, preferably with from about 7 to about 32 carbon atoms and more preferably
with from about 7 to about 21 carbon atoms, hydroxy groups, amine groups, imine groups,
ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde groups,
ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl groups,
thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups,
phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups,
mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl
groups, acid anhydride groups, azide groups, and the like, wherein two or more substituents
can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, l
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, lO
3-, ClO
3-, or the like, as well as mixtures thereof.
[0084] Examples of oxaspiros and ketals include (a) 1,6-dioxaspiro [4.4]nonane-2,7-dione,
(b) 1,4-dioxaspiro [4.5]decan-2-one, (c) 1,7-dioxaspiro [5.5]undecane, (d) 2,4,8,10-tetraoxaspiro[5.5]undecane,
(e) 3,9-divinyl-2,4,8-tetraoxaspiro[5.5]undecane, (f) 2,2-pentamethylene-1,3-dioxalane,(g)
2-phenyl-1,3-dioxalane, (h) 1,4-cyclohexanedione monoethylene ketal, (i) 1,4-cyclohexanedione
bis(ethylene ketal), (j) 1,4-cyclohexanedione mono-2,2-dimethyl trimethylene ketal,
and the like; (3) methylene dioxys and methylene dioxy derivatives, including those
of the general formula

wherein R
1, R
2, R
3, R
4, R
5, and R
6 each, independently of the others, can be (but are not limited to) hydrogen atoms,
alkyl groups, preferably with from 1 to about 6 carbon atoms and more preferably with
from 1 to about 3 carbon atoms, substituted alkyl groups, preferably with from 1 to
about 12 carbon atoms and more preferably with from 1 to about 6 carbon atoms, aryl
groups, preferably with from about 6 to about 24 carbon atoms and more preferably
with from about 6 to about 12 carbon atoms, substituted aryl groups, preferably with
from about 6 to about 30 carbon atoms and more preferably with from about 6 to about
18 carbon atoms, arylalkyl groups, preferably with from about 7 to about 31 carbon
atoms and more preferably with from about 7 to about 20 carbon atoms, substituted
arylalkyl groups, preferably with from about 7 to about 32 carbon atoms and more preferably
with from about 7 to about 21 carbon atoms, hydroxy groups, amine groups, imine groups,
ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde groups,
ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl groups,
thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups,
phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups,
mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl
groups, acid anhydride groups, azide groups, and the like, wherein two or more of
R
1, R
2, R
3, R
4, R
5, and R
6 can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, I
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, IO
3-, ClO
3-, or the like, as well as mixtures thereof.
[0085] Examples of suitable methylenedioxy compounds include (a) piperonal, (b) piperonyl
acetate, (c) piperonyl alcohol, (d) piperonylnitrile, (e) piperonyl amine, (f) 6-nitropiperonal,
(g) 6-nitropiperonyl alcohol, (h) 3',4'-(methylenedioxy)acetophenone, (i) 3,4-(methylenedioxy)aniline,
(j) 2,3-(methylenedioxy)benzaldehyde, (k) 3,4-(methylenedioxy)phenylacetonitrile,
(I) 3,4-(methylenedioxy)toluene, and the like;
(C) crown ethers, including (1) 1,4,7,10-tetraoxacyclododecane (12-crown-4), (2) 2-(hydroxyethyl)-12-crown-4,
(3) 2-(aminoethyl)-12-crown-4, (4) benzo-12-crown-4, (5) 1,4,7,10,13-pentaoxacyclododecane
(15-crown-5), (6) 2-(hydroxyethyl)-15-crown-5,(7) 2-(aminoethyl)-15-crown-5, (8) benzo-15-crown-5,
(9) 4'-aminobenzo-15-crown-5, (10) 4'-formylbenzo-15-crown-5, (11) 4'-nitrobenzo-15-crown-5,
(12) bis [(benzo-15-crown-5)-15-ylmethyl] pimelate, (13) 1,4,7,10,13,16-hexaoxacyclooctadecane
(18-crown-6), (14) 2-(aminoethyl)-18 crown-6, (15) benzo-18 crown-6, (16) 4'-bromobenzo-18-crown-6,
(17) dibenzo-18-crown-6 (2,3,11,12-dibenzo-1,4,7,10,13,16-hexaoxacyclooctadeca-2,11-diene),
(18) di-tert-butyldibenzo-18-crown-6, (19) cis-dicyclohexane-18 crown-6 (2,3,11,12-dicyclohexano-1,4,7,10,13,16-hexaoxacyclooctadecane),
(20) dibenzo-24-crown-8 [2,3,14,15-dibenzo,1,4,7,10,13,16,19,22-octaoxacyclotetracosa
2,14-diene], (21) dicyclohexano-24-crown-8, (22) dibenzo-30-crown-10,[2,3,17,18-dibenzo-1,4,7,10,13,16,19,22,25,28-decaoxacyclotriaconta-2,17-diene],
and the like;
[0086] III. Cyclic hydrocarbons (wherein the compound contains at least one ring with only
carbon atoms, although other rings present in the compound may contain atoms other
than carbon and substituents may be present on the ring(s)), including (A) norbornanes
and norbornane derivatives, and norbornenes and norbornene derivatives, including
those of the general formulae

wherein R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, and R
12 each, independently of the others, can be (but are not limited to) hydrogen atoms,
alkyl groups, preferably with from 1 to about 6 carbon atoms and more preferably with
from 1 to about 3 carbon atoms, substituted alkyl groups, preferably with from 1 to
about 12 carbon atoms and more preferably with from 1 to about 6 carbon atoms, aryl
groups, preferably with from about 6 to about 24 carbon atoms and more preferably
with from about 6 to about 12 carbon atoms, substituted aryl groups, preferably with
from about 6 to about 30 carbon atoms and more preferably with from about 6 to about
18 carbon atoms, arylalkyl groups, preferably with from about 7 to about 31 carbon
atoms and more preferably with from about 7 to about 20 carbon atoms, substituted
arylalkyl groups, preferably with from about 7 to about 32 carbon atoms and more preferably
with from about 7 to about 21 carbon atoms, hydroxy groups, amine groups, imine groups,
ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde groups,
ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl groups,
thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups,
phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups,
mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl
groups, acid anhydride groups, azide groups, and the like, wherein two or more of
R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, and R
12 can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, I
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, IO
3-, ClO
3-, or the like, as well as mixtures thereof.
[0087] Examples of norbornanes and norbornenes include (1) norbornane, (Aldrich N3,200-8),
(2) 2-norbornane carbonitrile, (3) 2-norbornane methanol, (4) 3-methyl-2-norbornane
methanol, (5) camphene, (6) fenchyl alcohol, (7) thiocamphor, (8) norbornene, (9)
5-norbornene-2-carbonitrile, (10) 5-norbornene-2-carboxaldehyde, (11) 5-norbornene-2-methanol,
(12) 5-norbornene-2,2-dimethanol, (13) 5-norbornene-2-benzoyl, (14) 2-norbornanone
(norcamphor), (15) 3-chloro-2-norbornanone, (16) fenchone (1,3,3-trimethyl-2-norbornanone,
(17) (+)-3-(trifluoroacetyl)camphor, (18) 3-heptafluorobutyryl camphor, (19) 3-bromocamphor,
(20) 9,10-dibromocamphor, (21) 3,9,10-tribromocamphor, (22) dicyclopentadiene, (23)
methylcyclopentadiene dimer, (24) tricyclo[5.2.1]decane, (25) 4,8-bis(hydroxymethyl)tricyclo[5.2.1.0
2.6]decane, (26) 8-ketotricyclo[5.2.1.0
2.6]decane, and the like; (B) cyclobutenes and cyclobutene derivatives, of the general
formula

wherein R
1, R
2, R
3, R
4, R
5, and R
6 each, independently of the others, can be (but are not limited to) hydrogen atoms,
alkyl groups, preferably with from 1 to about 6 carbon atoms and more preferably with
from 1 to about 3 carbon atoms, substituted alkyl groups, preferably with from 1 to
about 12 carbon atoms and more preferably with from 1 to about 6 carbon atoms, aryl
groups, preferably with from about 6 to about 24 carbon atoms and more preferably
with from about 6 to about 12 carbon atoms, substituted aryl groups, preferably with
from about 6 to about 30 carbon atoms and more preferably with from about 6 to about
18 carbon atoms, arylalkyl groups, preferably with from about 7 to about 31 carbon
atoms and more preferably with from about 7 to about 20 carbon atoms, substituted
arylalkyl groups, preferably with from about 7 to about 32 carbon atoms and more preferably
with from about 7 to about 21 carbon atoms, hydroxy groups, amine groups, imine groups,
ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde groups,
ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl groups,
thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups,
phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups,
mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl
groups, acid anhydride groups, azide groups, and the like, wherein two or more of
R
1, R
2, R
3, R
4, R
5, and R
6 can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, l
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, or the like, as well as mixtures thereof.
[0088] Examples of cyclobutenes and cyclobutene derivatives include (1) 3,4-dimethoxy-3-cyclobutene-1,2-dione,
(2) 3,4-diethoxy-3-cyclobutene-1,2-dione, (3) 3,4-diisopropoxy-3-cyclobutene-1,2-dione,
(4) 3,4-dibutoxy-3-cyclobutene-1,2-dione, and the like;
(C) cyclopentanes and cyclopentane derivatives, and cyclopentenes and cyclopentene
derivatives, of the formulae

wherein R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, and R
10 each, independently of the others, can be (but are not limited to) hydrogen atoms,
alkyl groups, preferably with from 1 to about 6 carbon atoms and more preferably with
from 1 to about 3 carbon atoms, substituted alkyl groups, preferably with from 1 to
about 12 carbon atoms and more preferably with from 1 to about 6 carbon atoms, aryl
groups, preferably with from about 6 to about 24 carbon atoms and more preferably
with from about 6 to about 12 carbon atoms, substituted aryl groups, preferably with
from about 6 to about 30 carbon atoms and more preferably with from about 6 to about
18 carbon atoms, arylalkyl groups, preferably with from about 7 to about 31 carbon
atoms and more preferably with from about 7 to about 20 carbon atoms, substituted
arylalkyl groups, preferably with from about 7 to about 32 carbon atoms and more preferably
with from about 7 to about 21 carbon atoms, hydroxy groups, amine groups, imine groups,
ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde groups,
ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl groups,
thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups,
phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups,
mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl
groups, acid anhydride groups, azide groups, and the like, wherein two or more of
R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, and R
10 can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, l
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, ClO
3-, ClO
3-, or the like, as well as mixtures thereof.
[0089] Examples of cyclopentanes and cyclopentenes include (1) 3-methyl-2-(nitromethyl)-5-oxocyclopentaneacetic
acid, (2) 3-ethyl-2-hydroxy-2-cyclopenten-1-one, (3) methyl-4-methoxy-2-oxo-3-cyclopentene-1-carboxylate,
(4) 3,3a,6,6a-tetrahydro-2H-cyclopenta[b]furan-2-one, (5) 3a,4,5,6a-hexahydro-5-hydroxy-4(hydroxymethyl)-2H-cydopenta[b]furan-2-one,
(6) 3-methyl-1,2-cyclopentanedione, (7) 4-hydroxy-5-methyl-4-cyclopentene-1,3-dione
monohydrate, and the like;
(D) cyclohexane, cyclohexene, and cyclohexadiene compounds and derivatives, of the
general formulae

wherein R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, and R
12 each, independently of the others, can be (but are not limited to) hydrogen atoms,
alkyl groups, preferably with from 1 to about 6 carbon atoms and more preferably with
from 1 to about 3 carbon atoms, substituted alkyl groups, preferably with from 1 to
about 12 carbon atoms and more preferably with from 1 to about 6 carbon atoms, aryl
groups, preferably with from about 6 to about 24 carbon atoms and more preferably
with from about 6 to about 12 carbon atoms, substituted aryl groups, preferably with
from about 6 to about 30 carbon atoms and more preferably with from about 6 to about
18 carbon atoms, arylalkyl groups, preferably with from about 7 to about 31 carbon
atoms and more preferably with from about 7 to about 20 carbon atoms, substituted
arylalkyl groups, preferably with from about 7 to about 32 carbon atoms and more preferably
with from about 7 to about 21 carbon atoms, hydroxy groups, amine groups, imine groups,
ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde groups,
ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl groups,
thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups,
phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups,
mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl
groups, acid anhydride groups, azide groups, and the like, wherein two or more of
R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, and R
12 can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, l
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, lO
3-, Cl0
3-, or the like, as well as mixtures thereof.
[0090] Examples of cyclohexanes, cyclohexenes, and cyclohexadienes include (1) 2,4,4-trimethylcyclohexen-1-one,
(2) ethyl-6-methyl-2-oxo-3-cyclohexene-1-carboxylate, (3) ethyl 4-hydroxy-6-methyl-2-oxo-3-cyclohexene-1-carboxylate,
(4) 5-(1-acetoxy-1-methylethyl)-2-methyl-2-cyclohexen-1-one, (5) thymoquinone, (6)
2,6,6-trimethyl-2-cyclohexene-1,4-dione, and the like;
(E) indans and indan derivatives, including those of the general formula

wherein R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, and R
10 each, independently of the others, can be (but are not limited to) hydrogen atoms,
alkyl groups, preferably with from 1 to about 6 carbon atoms and more preferably with
from 1 to about 3 carbon atoms, substituted alkyl groups, preferably with from 1 to
about 12 carbon atoms and more preferably with from 1 to about 6 carbon atoms, aryl
groups, preferably with from about 6 to about 24 carbon atoms and more preferably
with from about 6 to about 12 carbon atoms, substituted aryl groups, preferably with
from about 6 to about 30 carbon atoms and more preferably with from about 6 to about
18 carbon atoms, arylalkyl groups, preferably with from about 7 to about 31 carbon
atoms and more preferably with from about 7 to about 20 carbon atoms, substituted
arylalkyl groups, preferably with from about 7 to about 32 carbon atoms and more preferably
with from about 7 to about 21 carbon atoms, hydroxy groups, amine groups, imine groups,
ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde groups,
ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl groups,
thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups,
phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups,
mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl
groups, acid anhydride groups, azide groups, and the like, wherein two or more of
R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, and R
10 can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, l
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, lO
3-, ClO
3-, or the like, as well as mixtures thereof.
[0091] Examples of indans and indan derivatives include (1) indan, (2) 1-indanol, (3) 2-indanol,
(4) 1-indanone, (S) 2-indanone, and the like; (F) tetralones and tetralone derivatives,
including those of the general formulae

wherein R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, and R
10 each, independently of the others, can be (but are not limited to) hydrogen atoms,
alkyl groups, preferably with from 1 to about 6 carbon atoms and more preferably with
from 1 to about 3 carbon atoms, substituted alkyl groups, preferably with from 1 to
about 12 carbon atoms and more preferably with from 1 to about 6 carbon atoms, aryl
groups, preferably with from about 6 to about 24 carbon atoms and more preferably
with from about 6 to about 12 carbon atoms, substituted aryl groups, preferably with
from about 6 to about 30 carbon atoms and more preferably with from about 6 to about
18 carbon atoms, arylalkyl groups, preferably with from about 7 to about 31 carbon
atoms and more preferably with from about 7 to about 20 carbon atoms, substituted
arylalkyl groups, preferably with from about 7 to about 32 carbon atoms and more preferably
with from about 7 to about 21 carbon atoms, hydroxy groups, amine groups, imine groups,
ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde groups,
ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl groups,
thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups,
phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups,
mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl
groups, acid anhydride groups, azide groups, and the like, wherein two or more of
R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, and R
10 can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, l
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, lO
3-, ClO
3-, or the like, as well as mixtures thereof.
[0092] Examples of tetralones and tetralone derivatives include (1) 2-acetyl-1-tetralone,
(2) 4-methyl-1-tetralone, (3) 5,7-dimethyl-1-tetralone, (4) 6,7-dimethoxy-1-tetralone,
(5) 1-methyl-2-tetralone, (6) 6,7-dimethoxy-2-tetralone, and the like;
(G) cyclonones and cyclonone derivatives, of the general formula

wherein the curved portion of the structure represents a hydrocarbon chain or a substituted
hydrocarbon chain, preferably of from about 3 to about 1 1 carbon atoms, wherein two
or more substituents can be joined together to form a ring, and wherein the substituents
on the hydrocarbon chain can be (but are not limited to) alkyl groups, preferably
with from 1 to about 6 carbon atoms and more preferably with from 1 to about 3 carbon
atoms, substituted alkyl groups, preferably with from 1 to about 12 carbon atoms and
more preferably with from 1 to about 6 carbon atoms, aryl groups, preferably with
from about 6 to about 24 carbon atoms and more preferably with from about 6 to about
12 carbon atoms, substituted aryl groups, preferably with from about 6 to about 30
carbon atoms and more preferably with from about 6 to about 18 carbon atoms, arylalkyl
groups, preferably with from about 7 to about 31 carbon atoms and more preferably
with from about 7 to about 20 carbon atoms, substituted arylalkyl groups, preferably
with from about 7 to about 32 carbon atoms and more preferably with from about 7 to
about 21 carbon atoms, hydroxy groups, amine groups, imine groups, ammonium groups,
pyridine groups, pyridinium groups, ether groups, aldehyde groups, ketone groups,
ester groups, amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl
groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine
groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups, mercapto
groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl groups,
acid anhydride groups, azide groups, and the like, wherein two or more substituents
can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, l
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, lO
3-, ClO
3-, or the like, as well as mixtures thereof.
[0093] Examples of cyclonones and cyclonone derivatives include (1) cyclohexanone, (2) cycloheptanone,
(3) cyclooctanone, (4) cyclononanone, (5) cyclodecanone, (6) cycloundecanone, (7)
cyclododecanone, (8) cyclotridecanone, (9) cyclopentadecanone, (10) 2-acetylcyclohexanone,
(11) 2-allylcyclohexanone, (12) 2-phenylcyclohexanone, (13) cyclohexanedione, (14)
2-acetyl-1,3-cyclohexanedione, (15) 4,4-dimethyl-1,3-cyclohexanedione, (16) 2-acetyl-1,3-cyclopentanedione,
(17) 3,3,5,5-tetramethyl-1,2-cyclopentanedione, and the like; (H) bicyclo[3.2.1]octan-2-one,
(I) endo-dimethyl 7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylate, (J) cineole, (K) bicyclo[2.2.2]oct-5-ene-2,3-dimethanol,
(L) tropone, (M) tropolone, (N) cyclooctene oxide (9-oxabicyclo[6.1.0]nonane), (O)
1,2,5,6-diepoxycyclooctane, (P) 9-methyl-Δ
5(10)-octalin-1,6-dione, (Q) cis-bicyclo[3.3.0]octane-3.7-dione, (R) azulene, (S) 1-benzosuberone,
(T) 1,5,9-cyclododecatriene, (U) cyclododecane epoxide, (V) 2,3-cyclododeceno pyridine,
(W) 1,2,5,6,9,10-hexabromo cyclododecane, (X) 8-cyclohexadecen-1-one, (Y) bicyclo[10.3.0]pentadec-12(1)-en-13-one,
(Z) 1,4,4a,8a-tetrahydro-endo-1,4-methanonaphthalene-5,8-dione, and the like;
[0094] IV. Sulfur-containing compounds, including (A) thioureas and thiourea derivatives,
such as (1) 1-allyl-2-thiourea, (2) 1-methallyl-3-methyl-2-thiourea, (3) 4-allyl-3-thiosemicarbazide,
(4) 1,3-diethyl-2-thiourea, (5) 1,3-dibutyl-2-thiourea, (6) 1-benzyl-3-methyl-2-thiourea,
(7) 1,1,3,3-tetramethyl-2-thiourea, (8) 2-imino-4-thiobiuret, (9) 1-allyl-3-(2-hydroxyethyl)-2-thiourea,
(10) S-(2-aminoethyl)isothiouronium bromide hydrobromide, (11) S,S-diphenylsulfillimine
monohydrate, and the like; (B) sulfones and sulfone derivatives, such as (1) methylsulfone
(dimethylsulfone), (2) ethylsulfone (diethylsulfone), (3) butylsulfone (dibutylsulfone),
(4) butadiene sulfone, (5) tetramethylene sulfone, (6) 1,4-butane sulfone, (7) 1,4-butanediolcyclic
sulfate, (8) benzylsulfone, (9) phenylsulfone (diphenylsulfone), (10) phenylvinylsulfone,
(11) phenylstyrenesulfone, (12) phenyl-2-(trimethylsilyl)methyl sulfone, (13) phenyl
2-(trimethylsilyl)ethyl sulfone, (14) phenyl 2-(trimethylsilyl)ethynyl sulfone, (15)
4-(fluorophenyl)sulfone, (16) 4-(fluorophenyl)methyl sulfone, (17) chloromethylphenyl
sulfone, (18) chloromethyl-p-tolyl sulfone, (19) 2-chloroethylphenyl sulfone, (20)
methylthiomethylphenyl sulfone, (21) methylthiomethyl-p-tolyl sulfone, (22) 2-(phenylsulfonyl)
tetrahydropyran, (23) 1-(phenylsulfonyl)indole, (24) 1-(p-toluenesulfonyl)imidazole,
(25) 1-(p-tosyl)-3,4,4-trimethyl imidazolidine, (26) 4-(p-tosylsulfonyl)hexahydro
-1,4-thiazepine, and the like; (C) thiocyclic compounds, such as (1) thionaphthene,
(2) 4-keto-4,5,6,7-tetrahydrothianaphthene, (3) 2,2'-bithiophene, (4) 2,2':5',2"-terthiophene,
(5) D,L-N-acetylhomocysteine thiolactone, (6) tetrahydrothiopyran-4-one, (7) thiochroman-4-one,
(8) thiochroman-4-ol, (9) D,L-thioctic acid, (10) ethyl 1,3-dithiolane-2-carboxylate,
(11) 3H-1,2-benzodithiol-3-one, (12) 1,3-dithiane, (13) 2-phenyl-1,3-dithiane, (14)
ethyl-1,3-dithiane-2-carboxylate, (15) 5,6-dihydro-5-methyl-4H-1,3,5-dithiazine, (16)
1,4-dithiane, (17) 2,5-dihydroxy-2,5-dimethyl-1,4-dithiane, (18) 1,5-dithiacyclooactan-3-ol,
(19) 1,4-dithiaspiro [45] decan-8-ol, (20) 1,3,5-trithiane, (21) 1,4,7-trithiacyclononane,
(22) 1,4,7-trithiacyclodecane, (23) 1,4,7,10-tetrathiacyclododecane, (24) 3,6,9,14-tetrathiabicyclo
[9.2.1] tetradeca-11,13-diene, (25) 1,4,8,1-tetrathiacyclotetradecane, (26) 1,5,9,13-tetrathiocyclohexadecane,
(27) 1,5,9,13-tetrathiacyclohexadecane-3,11-diol, (28) 1,4,7,10,13-pentathiacyclopentadecane,
(29) 1,4,7,10,13,16-hexathiacyclooctadecane, (30) 1,5,9,13,17,21-hexathiacyclotetracosane-3,11,19-triol,
(31) 1,4,7,10,13,16,19,22-octathiacyclotetracosane, (32) 1,4,8,11,15,18,22,25-octathiacyclooctacosane,
(33) 1,4,7,10,13,16,19,22,25-nonathiacycloheptacosane, and the like; (D) sulfites
and sulfite derivatives, including (1) dimethylsulfite, (2) diethylsulfite, (3) sodium
sulfite, and the like; (E) sulfides and sulfide derivatives, including (1) allyldisulfide,
(2) aminophenyldisulfide, (3) benzyldisulfide, (4) benzylphenylsulfide, and the like;
(F) quaternary sulfur compounds and their derivatives, including (1) trimethylsulfonium
methylsulfate, (2) (2-chloroethyl)dimethylsulfonium iodide, (3) 3-(chloropropyl)diphenylsulfonium
tetrafluoroborate, (4) trimethyl sulfonium iodide, (5) trimethyl sulfoxonium iodide,
(6) trimethyl sulfoxonium chloride, (7) triphenyl methane sulfenyl chloride, (8) dimethyl
(2-methoxy-5-nitrobenzyl) sulfonium bromide, (9) thionin perchlorate, (10) p-xylylene
bis(tetrahydrothiopheneum chloride), (11) tris (dimethyl amino) sulfonium difluorotrimethyl
silicate, (12) tris (dimethyl amino) sulfonium trifluoromethoxide, (13) (3-amino-3-carboxypropyl)
dimethyl sulfonium chloride, and the like;
[0095] V. Thia-aza-cyclic compounds, including (A) thiazoles and thiazole derivatives, and
thiazolidines and thiazolidine derivatives, and thiadiazoles and thiadiazole derivatives,
including those of the general formulae

wherein R
1, R
2, R
3, R
4, R
5, R
6, and R
7 each, independently of the others, can be (but are not limited to) hydrogen atoms,
alkyl groups, preferably with from 1 to about 6 carbon atoms and more preferably with
from 1 to about 3 carbon atoms, substituted alkyl groups, preferably with from 1 to
about 12 carbon atoms and more preferably with from 1 to about 6 carbon atoms, aryl
groups, preferably with from about 6 to about 24 carbon atoms and more preferably
with from about 6 to about 12 carbon atoms, substituted aryl groups, preferably with
from about 6 to about 30 carbon atoms and more preferably with from about 6 to about
18 carbon atoms, arylalkyl groups, preferably with from about 7 to about 31 carbon
atoms and more preferably with from about 7 to about 20 carbon atoms, substituted
arylalkyl groups, preferably with from about 7 to about 32 carbon atoms and more preferably
with from about 7 to about 21 carbon atoms, hydroxy groups, amine groups, imine groups,
ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde groups,
ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl groups,
thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups,
phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups,
mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl
groups, acid anhydride groups, azide groups, and the like, wherein two or more of
R
1, R
2, R
3, R
4, R
5, R
6, and R
7 can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, l
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, lO
3-, ClO
3-, or the like, as well as mixtures thereof.
[0096] Examples of thiazoles include (1) 2-amino-2-thiazoline, (2) 2-amino thiazole, (3)
2-amino-4-methylthiazole, (4) 2-amino-4-methylthiazole, (S) 2-amino-4-thiazoleacetic
acid, (6) 2-acetamido-4-methylthiazole, (7)2-acetylthiazole, (8) 5-acetyl-2,4-dimethylthiazole,
(9) 4-methyl-5-vinylthiazole, (10) 2-amino-4-phenyl-5-tetradecylthiazole, (11) 2,4-thiazolidine
dione, (12) 3-aminorhodanine, (13) 3-methylrhodanine, (14) 3-ethylrhodanine, (15)
3-allylrhodanine, (16) 3-hydroxy-4-methyl-2(3H)-thiazolethione, (17) benzothiazole,
(18) 2-methylbenzothiazole, (19) 2-(methylthio)benzothiazole, (20) 2-amino-4-methylbenzothiazole,
(21) 3-methylbenzothiazole-2-thione, (22) 2,1,3-benzothiadiazole, (23) 4-amino-2,1,3-benzothiadiazole,
(24) 3,4-dimethyl-5-(2-hydroxyethyl)thiazolium iodide, (25) 3-ethyl-5-(2-hydroxyethyl)4-methylthiazolium
bromide, (26) 2-amino-5-nitrothiazole, (27) 2-amino-α-(methoxyimino)-4-thiazole acetic
acid, (28) ethyl 2-amino-α-(hydroxyimino)-4-thiazole acetate, (29) ethyl 2-amino-α-(methoxyimino)-4-thiazole
acetate, (30) ethyl 2-amino-4-thiazole acetate, (31) ethyl 2-amino-4-thiazole glyoxylate,
(32) 1-phenyl-3-(2-thiazolyl)-2-thiourea, (33) 2-amino-4-methoxy benzothiazole, (34)
2-amino-5,6-dimethylbenzothiazole, (35) N'-(2-thiazolyl) sulfanilamide, (36) 6-ethoxy-2-benzothiazole
sulfonamide, (37) ethyl-2-(formylamino)-4-thiazoleacetate, (38) ethyl-2-(formylamino)-4-thiazoleglyoxylate,
(39) 2-(formylamino)-α-(methoxyimino)-4-thiazole acetic acid, (40) 2-acetamido-4-methyl-5-thiazole
sulfonyl chloride, (41) (4R)-(-)-2-thioxo-4-thiazolidine carboxylic acid, (42) (R)-(-)-thiazolidine-4-carboxylic
acid, (43) pseudothiohydantoin, (44) 2-amino-1,3,4-thiadiazole, (45) 2-amino-5-trifluoromethyl-1,3,4-thiadiazole,
(46) 2-amno-5-methyl-1,3,4-thiadiazole, (47) 2-amino-5-ethyl-1,3,4-thiadiazole, (48)
2-amino-5-(ethylthio)-1,3,4-thiadiazole, (49) 5-amino-1,3,4-thiadiazole-2-thiol, (50)
2-acetamido-5-benzyl thio-1,3,4-thiadiazole, (51) 5-acetamido-1,3,4-thiadiazole-2-sulfonamide,
(52) 5-anilino-1,2,3,4-thiatriazole, (53) 2-amino-4,5-dimethyl thiazole hydrochloride,
(54) 2-amino 4-imino-2-thiazoline hydrochloride, (55) 2-amino-2-thiazoline hydrochloride,
(56) 2-amino-5-bromothiazole monohydrobromide, (57) 5-amino-3-methyl isothiazole hydrochloride,
(58) 3-methyl-2- benzothiazolinone hydrazone hydrochloride hydrate, (59) 5-amino-2-methylbenzothiazole
dihydrochloride, (60) 2,4-diamino-5-phenyl thiazole monohydrobromide, (61) 2-amino-4-phenyl
thiazole hydrobromide monohydrate, (62) 2-(tritylamino)-a-(methoxyimino)-4-thiazole
acetic acid hydrochloride, (63) (2,3,5,6-tetrahydro-6-phenylimidazo [2,1-b] thiazole
hydrochloride, (64) 3-ethyl-2-methyl-2-thiazolium iodide, (65) 3-benzyl-5-(2-hydroxyethyl)-4-methyl
thiazolium chloride, (66) thiamine hydrochloride, (67) 3-(carboxymethyl) benzothiazolium
bromide, (68) 2-azido-3-ethyl benzothiazolium tetrafluoroborate, (69) 3-ethyl-2-methyl
benzothiazolium iodide, (70) 2-methyl-3-propyl benzothiazolium iodide, (71) 3-ethyl-2-(2-hydroxy-1-propenyl)
benzothiazolium chloride, (72) 3,6-dimethyl-2-(4-dimethyl aminophenyl) benzothiazolium
bromide, and the like; (b) phenothiazines, including those of the general formula

wherein R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, and R
9 each, independently of the others, can be (but are not limited to) hydrogen atoms,
alkyl groups, preferably with from 1 to about 6 carbon atoms and more preferably with
from 1 to about 3 carbon atoms, substituted alkyl groups, preferably with from 1 to
about 12 carbon atoms and more preferably with from 1 to about 6 carbon atoms, aryl
groups, preferably with from about 6 to about 24 carbon atoms and more preferably
with from about 6 to about 12 carbon atoms, substituted aryl groups, preferably with
from about 6 to about 30 carbon atoms and more preferably with from about 6 to about
18 carbon atoms, arylalkyl groups, preferably with from about 7 to about 31 carbon
atoms and more preferably with from about 7 to about 20 carbon atoms, substituted
arylalkyl groups, preferably with from about 7 to about 32 carbon atoms and more preferably
with from about 7 to about 21 carbon atoms, hydroxy groups, amine groups, imine groups,
ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde groups,
ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl groups,
thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide groups,
phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile groups,
mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups, acyl
groups, acid anhydride groups, azide groups, and the like, wherein two or more of
R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, and R
9 can be joined together to form a ring, and wherein the substituents on the substituted
alkyl groups, substituted aryl groups, and substituted arylalkyl groups can be (but
are not limited to) hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, azide
groups, and the like, wherein two or more substituents can be joined together to form
a ring. Other variations are also possible, such as a double bond between one of the
ring carbon atoms and another atom, such as carbon, oxygen, or the like. These compounds
can also be in acid salt form, wherein they are associated with a compound of the
general formula xH
nY
n-, wherein n is an integer of 1, 2, or 3, x is a number indicating the relative ratio
between compound and acid (and may be a fraction), and Y is an anion, such as Cl
-, Br
-, L
-, HSO
4-, SO
42-, NO
3-, HCOO
-, CH
3COO
-, HCO
3-, CO
32-, H
2PO
4-, HPO
42-, PO
43-, SCN
-, BF
4-, ClO
4-, SSO
3-, CH
3SO
3-, CH
3C
6H
4SO
3-, SO
32-, BrO
3-, IO
3-, ClO
3-, or the like, as well as mixtures thereof.
[0097] Examples of phenothiazines include (1) trifluoroperazine dihydrochloride, (2) thioridazine
hydrochloride, (3) (±)-promethazine hydrochloride, (4) ethopropazine hydrochloride,
(5) chlorpromazine hydrochloride, and the like;
[0098] VI. Phosphorus compounds and their derivatives, including (A) phosphines, such as
(1) trialkyl, triaryl, and heterocyclic phosphines and their derivatives, including
(a) triphenylphosphine, (b) tri-m-tolyl phosphine, (c) tris(3-methoxyphenyl)phosphine,
(d) tris(4-chlorophenyl)phosphine, (e) tris(pentafluorophenyl)phosphine, (f) tricyclohexylphosphine,
(g) tribenzylphosphine, (h) tri-2-furylphosphine, (i) bis (pyrrolidino)methoxy phosphone,
(j) compounds of the general formula (C
6H
5)
2P(CH
2)nP(C
6H
5)
2 where n is an integer of from 0 to about 10, such as (1) n=0: tetraphenylbiphosphine,
(2) n = 3: 1,3-bis(diphenylphosphino)propane, (3) n = 5: 1,5-bis(diphenylphosphino)pentane,
(4) n = 6: 1,6-bis(diphenylphosphino)hexane, and the like; (k) alkyldiphenyl or dialkylphenyl
compounds, including (1) isopropyl diphenyl phosphine, (2) diphenyl (p-tolyl) phosphine,
(3) (4-bromophenyl) diphenyl phosphine, (4) diphenyl-2-pyridylphosphine, (5) dicyclohexylphenyl
phosphine, and the like; (B) phosphites and phosphite derivatives, including (1) trialkyl
and triaryl phosphites and their complexes, such as (a) trimethyl phosphite, (b) triethyl
phosphite, (c) tris(2-chloroethyl) phosphite, (d) tributyl phosphite, (e) triphenyl
phosphite,(f) trimethyl phosphite copper iodide, (g) triethyl phosphite copper iodide,
and the like; (2) dialkyl and diaryl phosphites, such as (a) dipropyl phosphite, (b)
bis(2-ethylhexyl) phosphite, (c) bis(4-nitrobenzyl) phosphite, (d) 2,2'-ethylidene
bis(4,6-di-tert-butylphenyl) fluorophosphite, (e) pentaerythritol diphenyl diphosphite,
and the like; (C) cyclic phosphorus compounds, including (1) 2-furyltetramethyl phosphorodiamidate,
(2) diethyl(pyrrolidinomethyl)phosphonate, (3) cyclophosphamide monohydrate, (4) 2-chloro-1,3,2-dioxaphospholane-2-oxide,
(5) N,N-diethyl-1,5-dihydro-2,4,3-benzodioxaphosphepin-3-amine, (6) 1,2-phenylene
phosphochloridite, (7) 1,2-phenylene phosphochloridate, (8) 2-chloro-4H-1,3,2-benzodioxaphosphorin-4-one,
(9) 2,4-bis(methylthio)-1,3-dithia-2,4-diphosphetane-2,4-disulfide, and the like;
(D) phosphine oxide compounds, including (1) trisubstituted phosphine oxides, such
as (a) triphenyl phosphine oxide, (b) tris(hydroxymethyl) phosphine oxide, (c) trimethoxy
phosphine oxide, (d) triethoxy phosphine oxide, (e) triphenoxy phosphine oxide, (f)
tris (2-butoxy ethoxy) phosphine oxide, and the like; (2) disubstituted phosphine
oxides, such as (a) diphenyl phosphine oxide, (b) diphenyl (2,4,6-trimethylbenzoyl)
phosphine oxide, and the like; (3) hydroxy phosphine oxide compounds, such as (a)
phenyl phosphinic acid, (b) diphenyl phosphate, (c) vinyl phosphonic acid, (d) propyl
phosphonic acid, (e) pyrophosphoric acid, (f) triphenylphosphate, and the like; (E)
quaternary phosphonium salts, including (1) tetrabutylphosphonium chloride, (2) tetrabutylphosphonium
bromide, (3) hexadecyltributylphosphonium bromide, (4) stearyltributylphosphonium
bromide, (5) azidotris(diethylamino)phosphonium bromide, (6) phosphonitrilic chloride
trimer, (7) tetramethyl phosphonium bromide, (8) tetramethyl phosphonium chloride,
(9) tetraethyl phosphonium bromide, (10) tetraethyl phosphonium chloride, (11) tetraethyl
phosphonium iodide, (12) tetraphenyl phosphonium bromide, (13) tetraphenyl phosphonium
chloride, (14) tetraphenyl phosphonium Iodide, (15) methyl triphenyl phosphonium bromide,
(16) methyl triphenyl phosphonium iodide, (17) ethyl triphenyl phosphonium bromide,
(18) n-propyl triphenyl phosphonium bromide, (19) isopropyl triphenyl phosphonium
iodide, (20) cyclopropyl triphenyl phosphonium bromide, (21) n-butyl triphenyl phosphonium
bromide, (22) isobutyl triphenyl phosphonium bromide, (23) hexyl triphenyl phosphonium
bromide, (24) benzyl triphenyl phosphonium chloride, (25) bromomethyl triphenyl phosphonium
bromide, (26) chloromethyl triphenyl phosphonium chloride, (27) 3-bromopropyl triphenyl
phosphonium bromide, (28) 3-bromobutyl triphenyl phosphonium bromide, (29) 4-bromobutyl
triphenyl phosphonium bromide, (30) 2-dimethyl aminoethyl triphenyl phosphonium bromide,
(31) [(3-dimethyl amino) propyl] triphenyl phosphonium bromide, (32) 2-hydroxyethyl
triphenyl phosphonium bromide (33) (2-hydroxyethyl) triphenyl phosphonium chloride,
(34) [(R)-(+)-3-hydroxy-2-methyl propyl] triphenyl phosphonium bromide, (35) [(S)-(-)-3-hydroxy-2-methyl
propyl] triphenyl phosphonium bromide, (36) (2-hydroxybenzyl triphenyl phosphonium
bromide, (37) (formyl methyl) triphenyl phosphonium chloride, (38) (methoxymethyl)
triphenyl phosphonium chloride, (39) acetonyl triphenyl phosphonium chloride, (40)
carbomethoxymethyl triphenyl phosphonium bromide, (41) (ethoxy carbonyl methyl) triphenyl
phosphonium chloride, (42) carbethoxymethyl triphenyl phosphonium bromide, (43) (tert-butoxy
carbonyl methyl) triphenyl phosphonium bromide, (44) phenacyl triphenyl phosphonium
bromide, (45) (4-ethoxybenzyl) triphenyl phosphonium bromide, (46) 4-butoxybenzyl
triphenyl phosphonium bromide, (47) 2-(1,3-dioxan-2-yl) ethyl] triphenyl phosphonium
bromide, (48) (1,3-dioxolan-2-ylmethyl) triphenyl phosphonium bromide, (49) vinyl
triphenyl phosphonium bromide, (50) allyl triphenyl phosphonium bromide, (51) allyl
triphenyl phosphonium chloride, (52) propargyl triphenyl phosphonium bromide, (53)
(3-trimethyl silyl-2-propynyl) triphenyl phosphonium bromide, (54) p-xylylene bis
(triphenyl phosphonium bromide), and the like;
[0099] VII. Nitrile compounds and their derivatives, including (1) cyanoacetohydrazide,
(2) 4,4-dimethyl-3-oxopentanenitrile, (3) 1-cyano-N-methylthioformamide, (4) cyanomethyl
N,N-dimethyl dithiocarbamate, (5) 4-hydroxy-3-methoxy-phenyl acetonitrile, (6) tosyl
cyanide, (7) tosylmethyl isocyanide, (8) 5-fluoro-2-methyl benzonitrile, (9) 2-fluoro-5-methyl
benzonitrile, (10) 4-(methylthio) benzonitrile, (11) 4-(dimethylamino) benzonitrile,
(12) 3,4-dimethoxy benzonitrile, (13) 4-hydroxy-3-methoxy benzonitrile, (14) 4-(trans-4-pentyl
cyclohexyl)benzonitrile, (15) 4'-pentyl-4'-biphenyl carbonitrile, (16) 4'-(pentyloxy)-4-biphenylcarbonitrile,
(17) 4'-hexyl-4-biphenyl carbonitrile, (18) 4'-(hexyloxy)-4-biphenyl carbonitrile,
(19) 4'-heptyl-4-biphenyl carbonitrile, (20) 4'-heptyloxy-4-biphenyl carbonitrile,
(21) 4'-octyl-4-biphenyl carbonitrile, (22) 4'-(octyloxy)-4-biphenyl carbonitrile,
(23) succinonitrile, (24) fumaronitrile, (25) 1,4-dicyano-2-butene, (26) (dimethyl
aminomethylene)malononitrile, (27) (1-ethoxyethylidene)malononitrile, (28) α-chlorobenzylidenemalononitrile,
(29) benzylidenemalononitrile, (30) 2-benzoyloxy-2-phenyl malononitrile, (31) O-(p-tosyl)isonitrosomalononitrile,
(32) tetrafluorophthalonitrile, (33) iminodiacetonitrile, (34) phenylene diacetonitrile,
(35) 3,3'-(4-formyl phenylimino) dipropionitrile, (36) tris (2-cyanoethyl) nitromethane,
(37) 1,1,3,3-propanetetracarbonitrile, (38) tetracyanoethylene oxide, and the like;
[0100] VIII. Isothiocyanate compounds and isocyanate compounds and their derivatives, including
(A) 4-azidophenyl isothiocyanate, (B) 1-naphthyl isothiocyanate, (C) 4-dimethyl amino-1-naphthyl
isothiocyanate, (D) 1-isothiocyanato-4-(trans-4-propyl cyclohexyl) benzene, (E) 1-(trans-4-hexyl
cyclohexyl)-4-isothiocyanato benzene, (F) 1-(4-trans-hexyl cyclohexyl)-4-[2-(4-isothio
cyanatophenyl)] benzene, (G) 1-isothiocyanato-4-(trans-4-octylcyclohexyl) benzene,
(H) 4-isothiocyanatophenyl-4-pentabicyclo [2.2.2] octane-1-carboxylate, (I) benzylthiocyanate,
(J) guanidinethiocyanate, (K) methylene dithiocyanate, (L) 4,4'-methylene bis (phenyl
isocyanate), (M) 4,4'-methylene bis(2,6-diethyl isocyanate), and the like;
[0101] IX. Oxime compounds and their derivatives, including (A) formamidoxime, (B) acetaldoxime,
(C) pyruvic aldehyde-1-oxime, (D) acetone oxime, (E) ethylchlorooximido acetate, (F)
2,3-butane dione monoxime, (G) 5-hydroxy pentenal oxime, (H) cyclopentanone oxime,
(I) cyclohexanone oxime, (J) cyclooctanone oxime, (K) benzaldehyde oxime, (L) 2-nitrobenzaldehyde
oxime, (M) salicyl aldoxime, (N) 2-isonitroso acetphenone, (O) 1-phenyl-1,2-propanedione
2-oxime, (P) 2-pyridine aldoxime, (Q) nifuroximeand the like;
[0102] X. Hydroxamic acid derivatives, including (A) acetohydroxamic acid, (B) suberohydroxamic
acid, (C) mandelohydroxamic acid, (D) benzohydroxamic acid, (E) N-phenylbenzohydroxamic
acid, and the like;
[0103] XI. Halide compounds, including (A) tetraalkyl ammonium salts, such as (1) tetramethylammonium
fluoride tetrahydrate, (2) tetraethylammonium acetate tetrahydrate, (3) tetrabutylammonium
chloride, (4) tetrabutylammonium chloride hydrate, (5) tetrabutylammonium bromide,
(6) tetrabutylammonium tribromide, (7) tetrabutylammonium acetate, (8) tetrabutylammonium
thiocyanate, (9) tetrapentylammonium bromide, (10) tetrahexylammonium bromide, (11)
tetrahexylammonium chloride, (12) tetrahexylammonium hydrogensulfate, (13) tetraheptylammonium
chloride, (14) tetraheptylammonium bromide, (15) tetraoctylammonium bromide, (16)
tetrakisdecylammonium bromide, (17) tetrahexadecylammonium bromide, (18) tetramethyl
ammonium bromide, (19) tetramethyl ammonium chloride, (20) tetramethyl ammonium iodide,
(21) tetraethyl ammonium bromide, (22) tetraethyl ammonium chloride, (23) tetraethyl
ammonium iodide, (24) tetrapropyl ammonium bromide, (25) tetrapropyl ammonium iodide,
(26) tetrabutyl ammonium iodide, (27) tetrapentyl ammonium chloride, (28) tetrahexyl
ammonium bromide, (29) tetrahexyl ammonium iodide, (30) tetradecyl ammonium bromide,
(31) tetradodecyl ammonium bromide, (32) tetraoctadecyl ammonium bromide, and the
like; (B) alkyl trialkyl ammonium salts, aryl trialkyl ammonium salts, alkyl triaryl
ammonium salts, and aryl triaryl ammonium salts, such as (1) methyltrioctylammonium
bromide, (2) tridodecylmethylammonium chloride, (3) tridodeylmethylammonium iodide,
(4) (-)-N-dodecyl-N-methylephedrinium bromide, (5) phenyltrimethylammonium tribromide,
(6) tricapryl methyl ammonium chloride, (7) tridodecyl methyl ammonium chloride, (8)
tridecyloxypropyl dihydroxy ethyl methyl ammonium chloride, (9) N-tetradecyl dimethyl-naphthyl
methyl ammonium chloride, (10) octadecyl diethanol methyl ammonium chloride, (11)
octadecyl dihydroxyethyl methyl ammonium chloride, (12) dihydrogenated tallow benzyl
methyl ammonium chloride, (13) 2-aminoethyl trimethyl ammonium chloride hydrochloride,
(14) 2-bromoethyl trimethyl ammonium bromide, (15) 2-chloroethyl trimethyl ammonium
chloride, (16) 3-carboxypropyl trimethyl ammonium chloride, (17) [3-(methacryloyl
amino) propyl] trimethyl ammonium chloride, (18) phenyl trimethyl ammonium bromide,
(19) phenyl trimethyl ammonium chloride, (20) phenyl trimethyl ammonium iodide, (21)
benzyl trimethyl ammonium chloride, (22) benzyl trimethyl ammonium bromide, (23) 4-nitrobenzyl
trimethyl ammonium chloride, (24) [2-(4-nitrophenyl) allyl] trimethyl ammonium iodide,
(25) coco trimethyl ammonium chloride, (26) palmityl trimethyl ammonium chloride,
(27) myristyl trimethyl ammonium bromide, (28) oleyl trimethyl ammonium chloride,
(29) soya trimethyl ammonium chloride, (30) tallow trimethyl ammonium chloride, (31)
hydrogenated tallow trimethyl ammonium chloride, (32) stearyl trimethyl ammonium chloride,
(33) behenyl trimethyl ammonium chloride, (34) guar hydroxypropyl trimethyl ammonium
chloride, (35) benzyl triethyl ammonium chloride, (36) benzyl triethyl ammonium bromide,
(37) butyl tripropyl ammonium bromide, (38) methyl tributyl ammonium chloride, (39)
methyl tributyl ammonium bromide, (40) methyl tributyl ammonium iodide, (41) benzyl
tributyl ammonium chloride, (42) benzyl tributyl ammonium bromide, (43) benzyl tributyl
ammonium iodide, (44) heptyl tributyl ammonium bromide, and the like; (C) dialkyl
dialkyl ammonium salts, such as (1) benzyldodecyldimethylammonium bromide, (2) benzyltetradecyldimethylammonium
chloride dihydrate, (3) benzylcetyldimethylammonium chloride monohydrate, (4) benzylstearyldimethylammonium
chloride monohydrate, (5) N,N-dimethyl methylene ammonium chloride, (6) N,N-dimethyl
methylene ammonium iodide, (7) chloromethylene dimethyl ammonium chloride, (8) dichloromethylene
dimethyl ammonium chloride, (9) dimethyl amino methylene amino methylene dimethyl
ammonium chloride, (10) benzethonium chloride, (11) methyl benzethoniumchloride, (12)
1-propanaminium 2,3-dihydroxy-N-dimethyl-N-[3(oxococoyl) amino]propyl]-chloride, (13)
cetyl dimethyl ethyl ammonium bromide, (14) octyl dodecyl dimethyl ammonium chloride,
(15) dodecyl (2-hydroxy1-methyl-2-phenyl-ethyl) dimethyl ammonium bromide, (16) dodecyl
dimethyl 2-phenoxyethyl ammonium bromide, (17) dodecanoyl-N-methylamino ethyl-(phenyl
carbamyl methyl) dimethyl ammonium chloride, (18) 3-chloro-2-hydroxypropyl N,N,N-dimethyl
dodecyl ammonium chloride, (19) 3-chloro-2-hydroxypropyl N,N,N-dimethyl octadecyl
ammonium chloride, (20) dodecyl benzyl dimethyl ammonium bromide, (21) dodecyl benzyl
dimethyl ammonium chloride, (22) coco benzyl dimethyl ammonium chloride, (23) benzyl
tetradecyl dimethyl ammonium chloride, (24) benzyl cetyl dimethyl ammonium chloride,
(25) benzyl octadecyl dimethyl ammonium chloride, (26) benzyl tallow dimethyl ammonium
chloride, (27) benzyl hydrogenated tallow dimethyl ammonium chloride, (28) benzyl
behenyl dimethyl ammonium chloride, (29) dioctyl dimethyl ammonium chloride, (30)
didecyl dimethyl ammonium chloride, (31) didecyl dimethyl ammonium bromide, (32) dicoco
dimethyl ammonium chloride, (33) dicetyl dimethyl ammonium chloride, (34) disoya dimethyl
ammonium chloride, (35) ditallow dimethyl ammonium chloride, (36) dihydrogenated tallow
dimethyl ammonium chloride, (37) dibehenyl/diarachidyl dimethyl ammonium chloride,
(38) soya amido propyl benzyl dimethyl ammonium chloride, (39) soya dicoco quaternary
ammonium chloride, (40) gluconamidopropyl dimethyl-2-hydroxyethyl ammonium chloride,
(41) N-alkyl-N-N-dimethyl-N(dodecyl acetate) ammonium chloride, wherein alkyl has
from 14 to 20 carbon atoms, (42) mink amidopropyl dimethyl-2-hydroxyethyl ammonium
chloride, (43) N-rapeseed-(3-amidopropyl)-N-N-dimethyl-N-(2,3 epoxy propyl) ammonium
chloride, (44) N-stearyl-(3-amido propyl)-N-benzyl dimethyl ammonium chloride, (45)
rapeseed amido propyl benzyl dimethyl ammonium chloride, (46) rapeseed amido propyl
ethyl dimethyl ammonium chloride, (47) cocamidopropyl polyethylene glycol dimethyl
ammonium chloride phosphate, and the like; (D) choline salts, such as butyrylcholine
chloride, and the like.
[0104] Any other transparentizing agent suitable for the selected migration marking material(s)
can also be employed, as well as mixtures thereof.
EXAMPLE I
[0105] Migration imaging members were prepared as follows. A solution for the softenable
layer was prepared by dissolving about 84 parts by weight of a terpolymer of styrene/ethylacrylate/acrylic
acid (prepared as disclosed in U.S. Patent 4,853,307, and about 16 parts by weight
of N,N'-diphenyl-N,N'-bis(3"-methylphenyl)-(1,1'-biphenyl)-4,4'-diamine (prepared
as disclosed in U.S. Patent 4,265,990, in about 450 parts by weight of toluene. N,N'-diphenyl-N,N'-bis(3''-methylphenyl)-(1,1'-biphenyl)-4,4'-diamine
is a charge transport material capable of transporting positive charges (holes). The
resulting solution was coated by a solvent extrusion technique onto 3 mil thick polyester
substrates (Melinex 442), aluminized to 50 percent light transmission), and the deposited
softenable layers were allowed to dry at about 115°C for about 2 minutes, resulting
in dried softenable layers with thicknesses of about 4 microns. The temperature of
the softenable layers was then raised to about 115°C to lower the viscosity of the
exposed surfaces of the softenable layers to about 5×10
3 poises in preparation for the deposition of marking material. Thin layers of particulate
vitreous selenium were then applied by vacuum deposition in a vacuum chamber maintained
at a vacuum of about 4×10
-4 Torr. The imaging members were then rapidly chilled to room temperature. Reddish
monolayers of selenium particles having an average diameter of about 0.3 micron embedded
about 0.05 to 0.1 micron below the surfaces of the copolymer layers were formed.
[0106] Separate sheets of polyester 100 microns thick were solvent coated from solutions
of toluene containing about 10 percent by weight solids with blends of various transparentizing
agents as indicated in the tables below with a styrene/ethyl acrylate/acrylic acid
binder (obtained from Scientific Polymer Products, #815) to form coating layers about
4 microns thick. The weight ratio of transparentizing agent to binder was 1:4 in each
instance. The coated sheets were dried at 25°C for 1 hour. Thereafter, the coated
surfaces of the polyester sheets were placed in intimate contact with the surfaces
of the migration imaging members coated with the softenable material and the migration
marking material, and the "sandwiches" thus formed were subjected to temperatures
of 100°C for 1 minute, at which temperature the softenable layer was softened sufficiently
to enable contact between the embedded selenium particles and the transparentizing
agents while the softenable material was in a molten state. The polyester sheets coated
with the transparentizing agents were then separated from the migration imaging members
and the UV absorption spectra at 685 nm of the migration imaging members were measured
to determine the extent of migration marking material transparentization. UV absorption
spectra were measured with a Shimadzu UV-160 spectrometer; all spectra were recorded
by using 50% transmission aluminized ICI 442 polyester as a reference. The optical
densities of the migration imaging members were also measured with a Macbeth TR927
densitometer in the visible, ultraviolet, and infrared range, using a Wratten No.
47 filter for the blue measurements, a Wratten No. 18A filter for the UV measurements,
and a Wratten No. 25 filter for the IR measurements. For comparison purposes, the
UV absorption spectrum at 685 nm and the optical density of the migration imaging
members prior to contact with the sheet coated with transparentizing agent were also
measured. The results were as follows:
| Agent |
UV absorption |
Optical Density |
| |
|
vis. |
UV |
IR |
| none |
1.50 |
1.82 |
2.65 |
0.89 |
| piperidine thiocyanate |
0.00 |
0.40 |
1.30 |
0.70 |
| 2-piperidine methanol |
0.50 |
0.65 |
0.50 |
0.36 |
| bis(pentamethylene) urea |
0.00 |
0.27 |
0.60 |
0.35 |
| 4,4'-trimethylene bis(1-piperidine propionitrile) |
0.00 |
0.25 |
0.60 |
0.50 |
| tripiperidino phosphine oxide |
0.00 |
0.24 |
0.55 |
0.35 |
| homopiperazine |
0.00 |
0.30 |
0.55 |
0.32 |
| 1-piperonyl piperazine |
0.00 |
0.28 |
1.09 |
0.30 |
| hexacyclentrisulfate |
0.50 |
0.60 |
1.20 |
0.70 |
| 5,10,15,20-tetraphenyl-21H ,23H porphine |
0.40 |
1.00 |
1.50 |
0.80 |
| 5,10,15,20-tetrakis(4-methoxyphenyl)-2H ,23H -porphine |
0.70 |
1.00 |
1.50 |
1.10 |
| pyrrole-2-carboxaldehyde |
0.00 |
0.28 |
0.76 |
0.35 |
| 3-pyrrolidino-1,2-propanediol |
0.00 |
0.25 |
0.95 |
0.31 |
| pyrazole |
0.50 |
0.38 |
0.79 |
0.45 |
| 3-aminopyrazole |
0.10 |
0.41 |
1.00 |
0.50 |
| imidazole |
1.00 |
0.60 |
1.10 |
0.60 |
| 2-ethylimidazole |
0.00 |
0.35 |
0.55 |
0.38 |
| 2-(2-piperidinoethyl) pyridine |
0.00 |
0.25 |
0.75 |
0.28 |
| 1-dodecyl pyridinium chloride |
0.00 |
0.32 |
0.83 |
0.27 |
| pyridinium bromide perbromide |
0.00 |
0.11 |
0.90 |
0.19 |
| 3-aminoquinoline |
0.20 |
0.45 |
0.97 |
0.48 |
| 8-hydroxyquinoline |
0.40 |
0.40 |
0.85 |
0.50 |
| 8-hydroxyquinaldine |
0.10 |
0.40 |
0.72 |
0.55 |
| quinoxaline |
0.00 |
0.30 |
0.57 |
0.37 |
| 4,5-dihydro-6-methyl-3(2H )-pyridazinone monohydrate |
1.00 |
0.80 |
1.50 |
0.70 |
| phthalazine |
0.50 |
0.45 |
0.97 |
0.48 |
| 1,10-phenanthroline |
0.20 |
0.41 |
1.30 |
0.45 |
| 1,3,5-triazine |
0.00 |
0.50 |
0.97 |
0.52 |
| trichloromelamine |
0.00 |
0.15 |
0.57 |
0.09 |
| trichloroisocyanouric acid |
0.00 |
0.11 |
0.55 |
0.08 |
| norbornane |
0.05 |
0.34 |
0.85 |
0.44 |
| tricyclo[5.2.1.0] decane |
0.00 |
0.26 |
0.53 |
0.35 |
| norcamphor |
0.00 |
0.37 |
0.51 |
0.39 |
| tropolone |
0.00 |
0.28 |
3.55 |
0.08 |
| 1-indanol |
0.00 |
0.20 |
0.40 |
0.33 |
| trans,trans,cis- 1,5,9-cyclododecatriene |
0.00 |
0.23 |
0.80 |
0.30 |
| cyclodecane epoxide |
0.00 |
0.26 |
0.50 |
0.33 |
| 2,3-cyclododecane pyridine |
0.50 |
0.71 |
0.50 |
0.33 |
| 1,2,5,6,9,10-hexabromo-cyclododecane |
0.00 |
0.35 |
0.85 |
0.35 |
| 1,4,4a,8a-tetrahydro-endo-1,4-methanonaphthalene-5,8-dione |
0.10 |
0.39 |
1.41 |
0.43 |
| γ-butyrolactone |
0.00 |
0.62 |
0.94 |
0.63 |
| β,β-dimethyl-γ-(hydroxymethyl)-γ-butyrolactone |
0.30 |
0.42 |
1.20 |
0.50 |
| 2,5-dimethyl-4-hydroxy-3(2 H )-furanone |
0.00 |
0.28 |
0.65 |
0.35 |
| hydrindantin dihydrate |
0.33 |
0.60 |
1.00 |
0.65 |
| 2,4,8,10-tetraoxaspiro [5.5]undecane |
0.00 |
0.27 |
0.65 |
0.35 |
| 1,3,5-trioxane |
0.00 |
0.26 |
0.50 |
0.35 |
| cyclooctanone |
0.00 |
0.27 |
0.48 |
0.33 |
| piperonal |
0.00 |
0.25 |
0.90 |
0.28 |
| piperonylalcohol |
0.00 |
0.31 |
0.88 |
0.40 |
| piperonyl nitrile |
0.00 |
0.25 |
0.40 |
0.35 |
| 3,4(methylenedioxy) phenylacetonitrile |
0.10 |
0.40 |
0.75 |
0.40 |
| maleic anhydride |
0.00 |
0.27 |
0.65 |
0.35 |
| s-acetylmercapto succinic anhydride |
0.00 |
0.30 |
0.48 |
0.38 |
| 2-octadecen-1-yl succinic anhydride |
0.00 |
0.28 |
0.55 |
0.35 |
| 18-crown-6 |
0.00 |
0.30 |
0.60 |
0.35 |
| benzo-18 crown-6 |
0.16 |
0.41 |
1.00 |
0.60 |
| dibenzo-18 crown-6 |
0.60 |
0.60 |
1.20 |
0.65 |
| dibenzo-24 crown-8 |
0.00 |
0.30 |
1.00 |
0.50 |
| 5-amino-3-methyl isooxazole |
0.00 |
0.32 |
0.55 |
0.45 |
| 2-oxazolidone |
0.50 |
0.71 |
0.95 |
0.75 |
| 5,5-dimethyl oxazolidine-2,4-dione |
0.15 |
0.37 |
0.90 |
0.44 |
| 3-ethyl-2-thioxo-4-oxazolidinone |
0.00 |
0.22 |
0.45 |
0.35 |
| 3-morpholino-1,2-propandiol |
0.20 |
0.35 |
0.73 |
0.55 |
| 4-phenyl morpholine |
0.00 |
0.30 |
0.55 |
0.32 |
| N,N' -dibenzyl-1,4,10,13-tetraoxa-7,16 diazacycloocta-decane |
0.00 |
0.26 |
0.70 |
0.30 |
| 4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo [8.8.8] hexacosane |
0.00 |
0.30 |
0.70 |
0.60 |
| γ-valerolactam |
0.20 |
0.46 |
1.15 |
0.51 |
| ε-caprolactam |
0.00 |
0.26 |
0.50 |
0.35 |
| 2-azacyclooctanone |
0.00 |
0.30 |
0.45 |
0.40 |
| 2-azacyclononanone |
0.00 |
0.30 |
0.41 |
0.40 |
| maleimide |
0.00 |
0.35 |
0.70 |
0.35 |
| n-methylsuccinimide |
0.00 |
0.32 |
0.70 |
0.42 |
| phthalimide DBU salt |
0.00 |
1.20 |
0.20 |
0.80 |
| 1-allyl-2-thiourea |
0.00 |
0.52 |
1.00 |
0.55 |
| 1-benzyl-3-methyl-2-thiourea |
0.00 |
0.22 |
1.12 |
0.33 |
| 2-imino-4-thiobiuret |
0.00 |
0.60 |
1.25 |
0.67 |
| butyl sulfone |
0.00 |
0.25 |
0.72 |
0.40 |
| 2,2'-bithiophene |
0.00 |
0.58 |
1.45 |
0.58 |
| 2-phenyl-1,3-dithiane |
0.00 |
0.30 |
0.50 |
0.41 |
| 3,6,9,14-tetrathiabicyclo [9.2.1] tetradeca-11,13-diene |
0.25 |
0.50 |
1.10 |
0.65 |
| 1,5,9,13-tetra-thiacyclohexadecane-3,11-diol |
0.00 |
0.30 |
0.60 |
0.45 |
| 1,4,7,10,13-penta-thiacyclopentadecane |
0.60 |
0.70 |
1.50 |
0.70 |
| 2-aminothiazole |
0.10 |
0.30 |
1.60 |
0.45 |
| 2-amino-2-thiazoline |
0.00 |
0.23 |
0.65 |
0.30 |
| 3-methyl rhodanine |
0.20 |
0.50 |
1.85 |
0.33 |
| 3-ethyl-5-(2-hydroxy-ethyl)-4- methylthiazolium bromide |
0.00 |
0.29 |
1.04 |
0.32 |
| triphenylphosphine |
0.00 |
0.28 |
0.55 |
0.32 |
| tricyclohexylphosphine |
0.20 |
0.25 |
0.68 |
0.35 |
| 1,3-bis (diphenylphosphino) propane |
0.00 |
0.22 |
0.76 |
0.31 |
| 1,5-his(diphenyl phosphino) pentane |
0.00 |
0.23 |
0.48 |
0.30 |
| isopropyldiphenyl phosphine |
0.10 |
0.23 |
0.55 |
0.30 |
| triethyl phosphite |
0.00 |
0.25 |
0.70 |
0.33 |
| triphenyl phosphite |
0.00 |
0.05 |
0.30 |
0.05 |
| triethyl phosphite copper iodide |
0.20 |
0.28 |
0.46 |
0.25 |
| dipropyl phosphite |
0.00 |
0.05 |
0.12 |
0.05 |
| bis(2-ethylhexyl) phosphite |
0.00 |
0.15 |
0.70 |
0.12 |
| bis(4-nitrobenzyl) phosphite |
0.10 |
0.20 |
1.15 |
0.15 |
| diphenyl phosphine oxide |
0.00 |
0.23 |
0.66 |
0.31 |
| diphenyl(2,4,6-trimethylbenzoyl) phosphine oxide |
0.00 |
0.26 |
3.45 |
0.31 |
| vinyl phosphonic acid |
0.00 |
0.24 |
0.65 |
0.30 |
| cyanoaceto-hydrazide |
0.10 |
0.35 |
0.95 |
0.45 |
| cyanomethyl N,N-dimethyl dithiocarbamate |
0.00 |
0.56 |
1.00 |
0.40 |
| 4'-pentyl-4'-biphenyl carbonitrile |
0.00 |
0.22 |
1.15 |
0.30 |
| 4'-(octyloxy)-4-biphenyl carbonitrile |
0.00 |
0.30 |
0.70 |
0.39 |
| 1,4-dicyano-2-butene |
0.00 |
0.30 |
0.68 |
0.40 |
| benzylidene malononitrile |
0.00 |
0.30 |
1.00 |
0.35 |
| 1-isothiocyanato-4-(trans-4-propylcyclohexyl)benzene |
0.00 |
0.33 |
0.70 |
0.35 |
| formamidoxime |
0.00 |
0.28 |
1.00 |
0.35 |
| ethyl chlorooximido acetate |
0.00 |
0.09 |
0.15 |
0.07 |
| acetohydroxamic acid |
0.00 |
0.25 |
0.50 |
0.35 |
| tetraheptylammonium chloride |
0.00 |
0.25 |
0.80 |
0.32 |
| tetraheptylammonium bromide |
0.00 |
0.30 |
0.75 |
0.30 |
[0107] As the data indicate, contact between the migration marking material and the indicated
transparentizing agents while the softenable material was in a molten state resulted
in transparentization of the migration marking material. The process was repeated
except that poly (2-hydroxyethyl methacrylate) (obtained from Scientific Polymer Products,
#414) was substituted for the styrene/ethyl acrylate/acrylic acid terpolymer as the
binder. Substantially similar results were obtained.
EXAMPLE II
[0108] Migration imaging members were prepared as described in Example I. The surfaces of
the members thus formed were uniformly negatively charged to a surface potential of
-142 Volts with a corona charging device and were subsequently optically exposed by
placing test pattern masks comprising silver halide images in contact with the imaging
members and exposing the members to blue light of 480 nanometers through the mask
for a period of 5 seconds. The imaging members were then developed by heating them
with an aluminum heating block in contact with the polyester substrates at temperatures
of from about 85 to about 100°C for about 5 seconds. Images corresponding to the images
on the test pattern masks were subsequently visible in the developed imaging members.
[0109] The developed migration imaging members were then cut into pieces and pieces containing
only Dmin areas (i.e., areas wherein the selenium particles had migrated in depth
through the softenable layer) were placed in intimate contact with polyester sheets
coated with a binder and a transparentizing agent and prepared as described in Example
I. The UV absorption spectra at 685 nm of the D
min areas of the migration imaging members were measured to determine the extent of migration
marking material transparentization. UV absorption spectra were measured with a Shimadzu
UV-160 spectrometer; all spectra were recorded by using 50% transmission aluminized
ICI 442 polyester as a reference. The optical densities of the D
min areas of the migration imaging members were also measured with a Macbeth TR927 densitometer
in the visible, ultraviolet, and infrared range, using a Wratten No. 47 filter for
the blue measurements, a Wratten No. 18A filter for the UV measurements, and a Wratten
No. 25 filter for the IR measurements. For comparison purposes, the UV absorption
spectrum at 685 nm and the optical density of the D
min areas of the migration imaging members prior to contact with the sheet coated with
transparentizing agent were also measured. The results were as follows:
| Agent |
UV absorption |
Optical Density |
| |
|
vis. |
UV |
IR |
| none |
1.45 |
0.74 |
1.63 |
0.79 |
| piperidine |
0.00 |
0.25 |
0.85 |
0.35 |
| 2-piperidine methanol |
0.50 |
0.50 |
0.40 |
0.28 |
| bis(pentamethylene) urea |
0.00 |
0.25 |
0.50 |
0.30 |
| 4,4'-trimethylene bis(1-piperidine propionitrile) |
0.00 |
0.20 |
0.50 |
0.40 |
| homopiperazine |
0.00 |
0.25 |
0.50 |
0.28 |
| hexacyclentrisulfate |
0.25 |
0.40 |
0.80 |
0.50 |
| 5,10,15,20-tetraphenyl-21H,23Hporphine |
0.25 |
0.50 |
0.78 |
0.50 |
| 3-pyrrolidino-1,2-propanediol |
0.00 |
0.24 |
0.75 |
0.28 |
| 1-dodecyl pyridinium chloride |
0.00 |
0.29 |
0.80 |
0.30 |
| 7,8-benzoquinoline |
0.15 |
0.28 |
0.61 |
0.33 |
| 8-hydroxyquinaldine |
0.05 |
0.26 |
0.74 |
0.35 |
| phthalazine |
0.25 |
0.30 |
0.85 |
0.36 |
| 1,10-phenanthroline |
0.10 |
0.36 |
0.80 |
0.42 |
| 1,3,5-triazine |
0.00 |
0.42 |
0.83 |
0.40 |
| norbornane |
0.05 |
0.30 |
0.80 |
0.45 |
| γ-butyrolactone |
0.00 |
0.45 |
1.01 |
0.52 |
| 1,3,5-trioxane |
0.00 |
0.28 |
0.66 |
0.31 |
| piperonal |
0.00 |
0.29 |
0.65 |
0.35 |
| piperonylalcohol |
0.00 |
0.23 |
0.55 |
0.37 |
| maleic anhydride |
0.00 |
0.28 |
0.73 |
0.34 |
| benzo-18-crown-6 |
0.10 |
0.35 |
0.77 |
0.33 |
| 5-amino-3-methyl isooxazole |
0.00 |
0.28 |
0.57 |
0.40 |
| 3-ethyl-2-thioxo-4-oxazolidinone |
0.00 |
0.26 |
0.85 |
0.31 |
| 3-morpholino-1,2-propandiol |
0.10 |
0.37 |
0.88 |
0.42 |
| 4-phenyl morpholine |
0.00 |
0.26 |
0.65 |
0.32 |
| N,N'-dibenzyl-1,4,10,13-tetraoxa-7,16 diazacyclooctadecane |
0.00 |
0.24 |
0.65 |
0.30 |
| γ-valerolactam |
0.10 |
0.29 |
0.83 |
0.31 |
| 2-azacyclooctanone |
0.00 |
0.26 |
0.74 |
0.38 |
| 1-allyl-2-thiourea |
0.00 |
0.30 |
0.95 |
0.35 |
| 1,3-dithiane |
0.15 |
0.34 |
0.54 |
0.35 |
| 2-amino-2-thiazoline |
0.00 |
0.23 |
0.90 |
0.30 |
| 3-ethyl-5-(2-hydroxy-ethyl)-4-methylthiazolium bromide |
0.00 |
0.31 |
1.09 |
0.27 |
| triphenylphosphine |
0.00 |
0.31 |
0.87 |
0.29 |
| tricyclohexylphosphine |
0.10 |
0.30 |
0.75 |
0.40 |
| 1,3-bis(diphenyl-phosphino) propane |
0.00 |
0.25 |
0.80 |
0.35 |
| 1,5-bis(diphenyl phosphino) pentane |
0.00 |
0.26 |
0.60 |
0.30 |
| triethyl phosphite copper iodide |
0.10 |
0.35 |
0.50 |
0.33 |
| bis(4-nitrobenzyl) phosphite |
0.10 |
0.25 |
0.80 |
0.30 |
| diphenyl phosphine oxide |
0.00 |
0.24 |
0.71 |
0.35 |
| vinyl phosphonic acid |
0.00 |
0.30 |
0.75 |
0.25 |
| triphenyl phosphate |
0.20 |
0.35 |
0.80 |
0.45 |
| cyanoaceto-hydrazide |
0.10 |
0.30 |
0.92 |
0.42 |
| 1-isothiocyanato-4-(trans-4-propylcyclohexyl)benzene |
0.00 |
0.41 |
0.72 |
0.41 |
| formamidoxime |
0.00 |
0.28 |
1.30 |
0.38 |
| acetohydroxamic acid |
0.00 |
0.23 |
0.77 |
0.30 |
| tetrahexylammonium chloride |
0.40 |
0.34 |
0.90 |
0.41 |
| tetraheptylammonium bromide |
0.00 |
0.27 |
0.75 |
0.30 |
As the data indicate, contact between the migration marking material in the D
min areas and the indicated transparentizing agents while the softenable material was
in a molten state resulted in transparentization of the migration marking material
in the D
min areas. The process was repeated except that poly (2-hydroxyethyl methacrylate) (obtained
from Scientific Polymer Products, #414) was substituted for the styrene/ethyl acrylate/acrylic
acid terpolymer as the binder. Substantially similar results were obtained.
EXAMPLE III
[0110] Migration imaging members are prepared as described in Example I with the exception
that prior to coating the softenable layer onto the polyester substrate, the polyester
substrate is first coated as follows. A solution is prepared of toluene containing
about 10 percent solids, wherein the solids comprise about 10 percent by weight of
a transparentizing agent and about 90 percent by weight of a styrene/ethyl acrylate/acrylic
acid terpolymer. The resulting solution is coated by a solvent extrusion technique
onto the polyester substrates. The layer thus deposited is allowed to dry at about
25°C for about 1 hour, resulting in a dried transparentizing layer with a thickness
of about 2 microns. Thereafter, the softenable layer is coated onto the transparentizing
layer by the method described in Example I. The transparentizing agents used are those
set forth in Examples I and II. During the selenium vacuum deposition process, the
transparentizing layer and the softenable layer fuse to form a single softenable layer
with the transparentizing agent concentrated in the bottom area thereof. The imaging
members thus formed are imaged as described in Example II. It is believed that the
optical contrast density of these imaging members will be greater than that of an
imaging member of identical composition except that it contains no transparentizing
agent, and that the optical density of the D
min areas of these imaging members will be less than that of an imaging member of identical
composition except that it contains no transparentizing agent.
EXAMPLE IV
[0111] Migration imaging members are prepared as described in Example I with the exception
that the solution for the softenable layer is prepared by dissolving about 76 parts
by weight of the styrene/ethyl acrylate/acrylic acid terpolymer, about 14 parts by
weight of the charge transporting compound, and about 10 parts by weight of a transparentizing
agent. The transparentizing agents used are those set forth in Examples I and II.
The imaging members thus formed are imaged as described in Example II. It is believed
that the optical contrast density of these imaging members will be greater than that
of an imaging member of identical composition except that it contains no transparentizing
agent, and that the optical density of the D
min areas of these imaging members will be less than that of an imaging member of identical
composition except that it contains no transparentizing agent.
EXAMPLE V
[0112] Migration imaging members are prepared as described in Example I with the exception
that prior to coating the softenable layer onto the polyester substrate, the polyester
substrate is first coated as follows. A solution is prepared of methanol containing
about 10 percent solids, wherein the solids comprise about 10 percent by weight of
a transparentizing agent and about 90 percent by weight of a poly (2-hydroxyethyl
methacrylate) binder (available from Scientific Polymer Products). The resulting solution
is coated by a solvent extrusion technique onto the polyester substrates. The layer
thus deposited is allowed to dry at about 25°C for about 1 hour, resulting in a dried
transparentizing layer with a thickness of about 2 microns. Thereafter, the softenable
layer is coated onto the transparentizing layer by the method described in Example
I. The transparentizing agents used are those set forth in Examples I and II. The
imaging members thus formed are imaged as described in Example II. It is believed
that the optical contrast density of these imaging members will be greater than that
of an imaging member of identical composition except that it contains no transparentizing
agent, and that the optical density of the D
min areas of these imaging members will be less than that of an imaging member of identical
composition except that it contains no transparentizing agent.
EXAMPLE VI
[0113] Migration imaging members are prepared as described in Example I with the exception
that subsequent to vacuum deposition of the selenium migration marking material, the
softenable layer is coated as follows. A solution is prepared of methanol containing
10 percent by weight solids, wherein the solids comprise about 10 percent by weight
of a transparentizing agent and about 90 percent by weight of a poly (2-hydroxyethyl
methacrylate) binder. The resulting solution is coated by a solvent extrusion technique
onto the softenable layers containing migration marking material. The layer thus deposited
is allowed to dry at about 25°C for about 1 hour, resulting in a dried transparentizing
layer with a thickness of about 2 microns. The transparentizing agents used are those
set forth in Examples I and II. The imaging members thus formed are imaged as described
in Example II. It is believed that the optical contrast density of these imaging members
will be greater than that of an imaging member of identical composition except that
it contains no transparentizing agent, and that the optical density of the D
min areas of these imaging members will be less than that of an imaging member of identical
composition except that it contains no transparentizing agent.
1. A migration imaging member (1) comprising (a) a substrate (2), (b) a softenable layer
(6) comprising a softenable material (7) and a photosensitive migration marking material
(8), and (c) a transparentizing agent which transparentizes the migration marking
material in contact therewith contained in at least one layer of the migration imaging
member, wherein the transparentizing agent affects the migration marking material
which comes into contact therewith by reducing the optical density of the softenable
layer containing the migration marking material.
2. A migration imaging member according to claim 1, wherein the migration marking material
(8) is selected from the group consisting of (a) selenium, (b) tellurium, (c) alloys
of selenium and a material selected from the group consisting of tellurium, arsenic,
antimony, thallium, bismuth, or mixtures thereof, (d) alloys of tellurium and a material
selected from the group consisting of arsenic, antimony, thallium, bismuth, or mixtures
thereof, (e) halogen doped selenium, (f) halogen doped tellurium, (g) halogen doped
alloys of selenium and a material selected from the group consisting of tellurium,
arsenic, antimony, thallium, bismuth, or mixtures thereof, (h) halogen doped alloys
of tellurium and a material selected from the group consisting of arsenic, antimony,
thallium, bismuth, or mixtures thereof, and (i) mixtures thereof.
3. A migration imaging member according to claim 1 or claim 2, wherein the transparentizing
agent is contained in the softenable layer.
4. A migration imaging member according to claim 1 or claim 2, wherein the transparentizing
agent is contained in a layer situated between the softenable layer and the substrate.
5. The migration imaging member according to claim 1 or 2, wherein the softenable layer
is situated between the substrate and a layer containing the transparentizing agent.
6. A migration imaging member according to claim 1 or claim 2, wherein the migration
imaging member comprises a substrate, a first softenable layer comprising a first
softenable material and a first migration marking material, and a second softenable
layer comprising a second softenable material and a second migration marking material,
wherein the transparentizing agent is contained in a layer situated between the first
softenable layer and the second softenable layer.
7. A migration imaging member according to any of claims 1 to 6, wherein the transparentizing
agent is present in an amount of from about 1 to about 50 percent by weight of the
material comprising the layer in which it is contained.
8. A migration imaging member according to claim 1 wherein the transparentizing agent
is an azacyclic compound; or wherein the transparentizing agent is selected from the
group consisting of: (A) materials of the general formulae:

wherein R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
14, R
is, R
16, R
17, R
18, R
19, R
20, R
21, R
22, R
23, R
24, R
25, R
26, R
27, R
28, R
29, R
30, R
31, R
32, R
33, R
34, R
35, R
36, R
37, R
38, and R
39 each, independently of the others, are selected from the group consisting of hydrogen
atoms, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups,
arylalkyl groups, substituted arylalkyl groups, hydroxy groups, amine groups, imine
groups, ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde
groups, ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl
groups, thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide
groups, phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile
groups, mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups,
acyl groups, acid anhydride groups, and azide groups, wherein two or more of R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
14, R
15, R
16, R
17, R
18, R
19, R
20, R
21, R
22, R
23, R
24, R
25, R
26, R
27, R
28, R
29, R
30, R
31, R
32, R
33, R
34, R
35, R
36, R
37, R
38, and R
39 can be joined together to form a ring; (B) materials of the general formulae:

wherein R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
14, R
15, R
16, R
17, R
18, R
19, R
20, R
21, and R
22 each, independently of the others, are selected from the group consisting of hydrogen
atoms, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups,
arylalkyl groups, substituted arylalkyl groups, hydroxy groups, amine groups, imine
groups, ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde
groups, ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl
groups, thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide
groups, phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile
groups, mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups,
acyl groups, acid anhydride groups, and azide groups, wherein two or more of R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
14, R
15, R
16, R
17, R
18, R
19, R
20, R
21, and R
22 can be joined together to form a ring; (C) materials of the general formulae:

wherein R
1, R
2, and R
3 each, independently of the others, are selected from the group consisting of hydrogen
atoms, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups,
arylalkyl groups, substituted arylalkyl groups, hydroxy groups, amine groups, imine
groups, ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde
groups, ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl
groups, thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide
groups, phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile
groups, mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups,
acyl groups, acid anhydride groups, and azide groups, wherein two or more of R
1, R
2, and R
3 can be joined together to form a ring; (D) materials of the general formulae:

wherein R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, and R
12 each, independently of the others, are selected from the group consisting of hydrogen
atoms, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups,
arylalkyl groups, substituted arylalkyl groups, hydroxy groups, amine groups, imine
groups, ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde
groups, ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl
groups, thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide
groups, phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile
groups, mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups,
acyl groups, acid anhydride groups, and azide groups, wherein two or more of R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, and R
12 can be joined together to form a ring; (E) materials of the general formulae:

wherein R
1, R
2, R
3, and R
4 each, independently of the others, are selected from the group consisting of hydrogen
atoms, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups,
arylalkyl groups, substituted arylalkyl groups, hydroxy groups, amine groups, imine
groups, ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde
groups, ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl
groups, thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide
groups, phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile
groups, mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups,
acyl groups, acid anhydride groups, and azide groups, wherein two or more of R
1, R
2, R
3, and R
4 can be joined together to form a ring; (F) materials of the general formula:

R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, and R
14 each, independently of the others, are selected from the group consisting of hydrogen
atoms, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups,
arylalkyl groups, substituted arylalkyl groups, hydroxy groups, amine groups, imine
groups, ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde
groups, ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl
groups, thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide
groups, phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile
groups, mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups,
acyl groups, acid anhydride groups, and azide groups, wherein two or more of R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, and R
14 can be joined together to form a ring; (G) materials of the general formula:

wherein R
1 and R
2 each, independently of the other, are selected from the group consisting of hydrogen
atoms, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups,
arylalkyl groups, substituted arylalkyl groups, hydroxy groups, amine groups, imine
groups, ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde
groups, ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl
groups, thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide
groups, phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile
groups, mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups,
acyl groups, acid anhydride groups, and azide groups, wherein R
1 and R
2 can be joined together to form a ring; (H) materials of the general formula:

wherein R
1, R
2, R
3, R
4, and R
5 each, independently of the others, are selected from the group consisting of hydrogen
atoms, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups,
arylalkyl groups, substituted arylalkyl groups, hydroxy groups, amine groups, imine
groups, ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde
groups, ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl
groups, thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide
groups, phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile
groups, mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups,
acyl groups, acid anhydride groups, and azide groups, wherein two or more of R
1, R
2, R
3, R
4, and R
5 can be joined together to form a ring; (I) materials of the general formula:

wherein R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, and R
9 each, independently of the others, are selected from the group consisting of hydrogen
atoms, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups,
arylalkyl groups, substituted arylalkyl groups, hydroxy groups, amine groups, imine
groups, ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde
groups, ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl
groups, thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide
groups, phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile
groups, mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups,
acyl groups, acid anhydride groups, and azide groups, wherein two or more of R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, and R
9 can be joined together to form a ring; (J) materials of the general formula:

wherein R
1, R
2, R
3, and R
4 each, independently of the others, are selected from the group consisting of hydrogen
atoms, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups,
arylalkyl groups, substituted arylalkyl groups, hydroxy groups, amine groups, imine
groups, ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde
groups, ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl
groups, thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide
groups, phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile
groups, mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups,
acyl groups, acid anhydride groups, and azide groups, wherein two or more of R
1, R
2, R
3, and R
4 can be joined together to form a ring; (K) materials of the general formula:

wherein R
1, R
2, R
3, and R
4 each, independently of the others, are selected from the group consisting of hydrogen
atoms, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups,
arylalkyl groups, substituted arylalkyl groups, hydroxy groups, amine groups, imine
groups, ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde
groups, ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl
groups, thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide
groups, phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile
groups, mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups,
acyl groups, acid anhydride groups, and azide groups, wherein two or more of R
1, R
2, R
3, and R
4 can be joined together to form a ring; (L) materials of the general formula:

wherein R
1, R
2, R
3, R
4, and R
5 each, independently of the others, are selected from the group consisting of hydrogen
atoms, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups,
arylalkyl groups, substituted arylalkyl groups, hydroxy groups, amine groups, imine
groups, ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde
groups, ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl
groups, thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide
groups, phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile
groups, mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups,
acyl groups, acid anhydride groups, and azide groups, wherein two or more of R
1, R
2, R
3, R
4, and R
5 can be joined together to form a ring; (M) materials of the general formulae:

wherein R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, and R
14 each, independently of the others, are selected from the group consisting of hydrogen
atoms, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups,
arylalkyl groups, substituted arylalkyl groups, hydroxy groups, amine groups, imine
groups, ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde
groups, ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl
groups, thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide
groups, phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile
groups, mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups,
acyl groups, acid anhydride groups, and azide groups, wherein two or more of R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, and R
14 can be joined together to form a ring; (N) materials of the general formula:

wherein R
1, R
2, R
3, and R
4 each, independently of the others, are selected from the group consisting of hydrogen
atoms, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups,
arylalkyl groups, substituted arylalkyl groups, hydroxy groups, amine groups, imine
groups, ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde
groups, ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl
groups, thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide
groups, phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile
groups, mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups,
acyl groups, acid anhydride groups, and azide groups, wherein two or more of R
1, R
2, R
3, and R
4 can be joined together to form a ring; (O) materials of the general formula:

wherein R
1, R
2, R
3, and R
4 each, independently of the others, are selected from the group consisting of hydrogen
atoms, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups,
arylalkyl groups, substituted arylalkyl groups, hydroxy groups, amine groups, imine
groups, ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde
groups, ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl
groups, thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide
groups, phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile
groups, mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups,
acyl groups, acid anhydride groups, and azide groups, wherein two or more of R
1, R
2, R
3, and R
4 can be joined together to form a ring; (P) materials of the general formula:

wherein R
1, R
2, R
3, and R
4 each, independently of the others, are selected from the group consisting of hydrogen
atoms, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups,
arylalkyl groups, substituted arylalkyl groups, hydroxy groups, amine groups, imine
groups, ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde
groups, ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl
groups, thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide
groups, phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile
groups, mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups,
acyl groups, acid anhydride groups, and azide groups, wherein two or more of R
1, R
2, R
3, and R
4 can be joined together to form a ring; (Q) materials of the general formula:

wherein R
1, R
2, R
3, and R
4 each, independently of the others, are selected from the group consisting of hydrogen
atoms, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups,
arylalkyl groups, substituted arylalkyl groups, hydroxy groups, amine groups, imine
groups, ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde
groups, ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl
groups, thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide
groups, phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile
groups, mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups,
acyl groups, acid anhydride groups, and azide groups, wherein two or more of R
1, R
2, R
3, and R
4 can be joined together to form a ring; (R) materials of the general formulae:

wherein R
1 is selected from the group consisting of hydrogen atoms, alkyl groups, substituted
alkyl groups, aryl groups, substituted aryl groups, arylalkyl groups, substituted
arylalkyl groups, hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, and
azide groups, and wherein the curved portion of the structure represents a hydrocarbon
chain or a substituted hydrocarbon chain, wherein two or more substituents can be
joined together to form a ring; (S) materials of the general formula:

wherein R
1 is selected from the group consisting of hydrogen atoms, alkyl groups, substituted
alkyl groups, aryl groups, substituted aryl groups, arylalkyl groups, substituted
arylalkyl groups, hydroxy groups, amine groups, imine groups, ammonium groups, pyridine
groups, pyridinium groups, ether groups, aldehyde groups, ketone groups, ester groups,
amide groups, carboxylic acid groups, carbonyl groups, thiocarbonyl groups, sulfate
groups, sulfonate groups, sulfide groups, sulfoxide groups, phosphine groups, phosphonium
groups, phosphate groups, cyano groups, nitrile groups, mercapto groups, nitroso groups,
halogen atoms, nitro groups, sulfone groups, acyl groups, acid anhydride groups, and
azide groups, and wherein the curved portion of the structure represents a hydrocarbon
chain or a substituted hydrocarbon chain, wherein two or more substituents can be
joined together to form a ring; and (T) mixtures thereof; or wherein the transparentizing
agent is selected from the group consisting of (1) homopiperidine, (2) piperidinethiocyanate,
(3) -2-piperidinemethanol, (4) 3-piperidinemethanol, (5) 2-piperidineethanol, (6)
4-piperidineethanol, (7) 4-piperidine monohydrate hydrochloride, (8) 1-aminopiperidine,
(9) 1-(2-aminoethyl)piperidine, (10) 4-(aminomethyl)piperidine, (11) 3-piperidino-1,2-propanediol
(Aldrich 21,849-9), (12) 1-piperidine propionic acid, (13) 1-methyl-4-(methylamino)piperidine,
(14) 1-acetyl-3-methylpiperidine, (15) 4'-piperidinoacetophenone, (16) 4-phenylpiperidine,
(17) 4-piperidinopiperidine, (18) 4-benzylpiperidine, (19) 4-(4-methylpiperidino)pyridine,
(20) 4-piperidone ethylene ketal, (21) bis(pentamethylene)urea, (22) 1-benzyl-4-hydroxypiperidine,
(23) 1-benzoyl-4-piperidone, (24) 1,1'-methylenebis(3-methylpiperidine), (25) 4,4'-trimethylenedipiperidine,
(26) 4,4'-trimethylenebis(1-menthylpiperidine), (27) 4,4'-trimethylenebis(1-piperidinepropionitrile),
(28) 4,4'-trimethylenebis(1-piperidineethanol), (29) 2,2,6,6-tetramethylpiperidine,
(30) 4-amino-2,2,6,6-tetramethylpiperidine, (31) 4-(dimethylamino)-1,2,2,6,6-pentamethylpiperidine,
(32) N,N'-bis(2,2,6,6-tetramethyl-4-piperidinyl)-1,6-hexanediamine, (33) tripiperidinophosphine
oxide, (34) tropane, (35) tropinehydrate, (36) tropinone, (37) 8-hydroxytropinone,
(38) 2-piperidine carboxylic acid, (39) 2-piperidone, (40) 4,4'-trimethylene bis (1-piperidine
carboxamide), (41) 4-methyl-2-(piperidinomethyl) phenol, (42) 1-methyl-4-piperidinyl
bis (chlorophenoxy) acetate, (43) 2-(hexamethylene imino) ethyl chloride monohydrochloride,
(44) 3-(hexahydro-1H-azepin-1-yl)-3'-nitropropiophenone hydrochloride, (45) imipramine
hydrochloride, (46) carbamezepine, (47) 5,6,11,12-tetrahydro dibenz [b,f] azocine
hydrochloride, (48) quinuclidine hydrochloride, (49) 3-quinuclidinol hydrochloride,
(50) 3-quinuclidinone hydrochloride, (51) 2-methylene-3-quinuclidinone dihydrate hydrochloride,
(52) 3-amino quinuclidine dihydrochloride, (53) 3-chloro quinuclidine hydrochloride,
(54) quinidine sulfate dihydrate, (55) quinine monohydrochloride dihydrate, (56) quinine
sulfate monohydrate, (57) hydroquinidine hydrochloride, (58) hydroquinine hydrobromide
dihydrate, (59) piperazine, (60) homopiperazine, (61) 1-methylpiperazine, (62) 2-methylpiperazine,
(63) 1-acetylpiperazine, (64) 1-(2-hydroxyethyl)piperazine, (65) 1-(2-aminoethyl)piperazine,
(66) tert-butyl 1-piperazinecarboxylate, (67) N-isopropyl-1-piperazineacetamide, (68)
1-(2-methoxyphenyl)piperazine, (69) 1-(2-pyridyl)piperazine, (70) 1-benzylpiperazine,
(71) 1-cinnamylpiperazine, (72) 1-(4-chlorobenzhydryl)piperazine, (73) 2,6-dimethylpiperazine,
(74) 1-amino-4-methylpiperazine, (75) 1-amino-4-(2-hydroxyethyl)piperazine, (76) 1,4-bis(2-hydroxyethyl)piperazine,
(77) 1,4-bis(3-aminopropyl)piperazine, (78) tert-butyl-4-benzyl-1-piperazinecarboxylate,
(79) 1-piperonyl piperazine, (80) bis(4-methyl-1-homopiperazinylthiocarbonyl)disulfide,
(81) 1-amino-4-methyl piperazine dihydrochloride monohydrate, (82) 1-(3-chloropropyl)-piperazine
dihydrochloride monohydrate, (83) 1-(2,3-xylyl) piperazine monohydrochloride, (84)
1,1-dimethyl-4-phenyl piperazineium iodide, (85) 1,4,7-triazacyclononane, (86) 1,5,9-triazacyclododecane,
(87) 1,2,3-triazole, (88) 4-amino-1,2,4-triazole, (89) 3-amino-5-methylthio-lH-1,2,4-triazole,
(90) benzotriazole, (91) 1-aminobenzotriazole, (92) 1-cyanobenzotriazole, (93) 5-methyl-1H-benzotriazole,
(94) 1H-benzotriazole-1-ylmethyl isocyanide, (95) 2-[3-(2H-benzotriazole-2-yl)-4-hydroxyphenyl]ethyl
methacrylate, (96) 1,2,4-triazole, (97) 1,2,4-triazole sodium derivative, (98) 3-amino-1,2,4-triazole,
(99) 3,5-diamino-1,2,4-triazole, (100) 3-amino-5-mercapto-1,2,4-triazole, (101) 3-amino-1,2,4-triazole-5-carboxylic
acid hemihydrate, (102) 4-amino-3-hydrazino-5-mercapto-1,2,4-triazole, (103) 1,2,3-triazole-4,5-dicarboxylic
acid monohydrate, (104) nitron, (105) 1-hydroxybenzotriazole hydrate, (106) 1,3,5-triazine,
(107) cyanuric acid, (108) trithiocyanuric acid, (109) 2,4-bis (methylthio)-6-chloro-1,3,5-triazine,
(110) 2-chloro-4,6-dimethoxy-1,3,5-triazine, (111) 2-chloro-4,6-diamino-1,3,5-triazine,
(112) trichloromelamine, (113) cyanuric chloride, (114) 2,4,6-tris(perfluoroheptyl)-1,3,5-triazine,
(115) hexahydro-2,4,6-trimethyl-1,3,5-triazine trihydrate, (116) 1,3,5-trimethylhexahydro-1,3,5-triazine,
(117) 1,3,5-triethylhexahydro-1,3,5-triazine, (118) 1,3,5-triclohexylhexahydro-1,3,5-triazine,
(119) 1,3,5-tribenzylhexahydro-1,3,5-triazine, (120) trichloroisocyanuric acid, (121)
tris (2,3-dibromopropylisocyanurate), (122) cyanuric acid compound with melamine,
(123) urazole, (124) 1-methyl urazole, (125) 4-phenyl urazole, (126) 5-(4-hydroxyphenyl)-5-phenyl
hydantoin, (127) β-tetralone hydantoin, (128) cyclen (1,4,7,10-tetraazacyclododecane),
(129) 1,4,8,11-tetraazacyclotetradecane, (130) 1,4,8,11-tetramethyl-1,4,8,11-tetraazacydotetradecane,
(131) 1,4,8,11-tetraazacyclotetradecane-5,7-dione, -dione, (132) 1,4,8,12-tetraazacyclopentadecane,
(133) 2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphine, (134) dimethyl 3,7,12,17-tetramethyl-21H,23H-porphine-2,18-dipropionate,
(135) dimethyl 7,12-diacetyl-3,8,13,17-tetramethyl-21H,23H-porphine-2,18-dipropionate,
(136) 8,3-divinyl-3,7,12,17-tetramethyl-21H,23H-porphine-2,18-dipropionic acid, disodium
salt, (137) 5,10,1 5,20-tetraphenyl-21 H,23H-porphine, (138) 5,10,15,20-tetrakis(4-methoxyphenyl)-21H,23H-porphine,
(139) 5,10,15-20-tetrakis[4-(trimethylamino)phenyl]-21H,23H-porphine tetra-p-tosylate
salt, (140) 5,10,15,20-tetra(4-pyridyl)-21H,23H-porphine, (141) 5,10,15,20-tetrakis(1-methyl-4-pyridyl)-21H,23H-porphine,
tetra-p-tosylate salt), (142) 1,5-pentamethylenetetrazole, (143) 1-H-tetrazole, (144)
5-amino tetrazole monohydrate, (145) 2,3,5-triphenyl-2H-tetrazolium chloride, (146)
2-(4-iodophenyl)-5-(4-nitrophenyl)-3-phenyltetrazolium chloride, (147) 1,2,3,3-tetramethyl-3H-indolinium
iodide, (148) hexacyclen trisulfate, (149) hexamethylhexacyclen, (150) pyrrole-2-carboxaldehyde,
(151) proline amide, (152) 3-pyrrolidino-1,2-propane diol, (153) 1-(pyrrolidino carbonylmethyl)
piperazine, (154) 4-pyrrolidinopyridine, (155) 3-indolylacetonitrile, (156) 6-nitroindoline,
(157) 7-azaindole, (158) indazole, (159) 2-acetyl-pyrrole, (160) 2-acetyl-1-methylpyrrole,
(161) 3-acetyl-1-methylpyrrole, (162) 3-acetyl-2,4-dimethylpyrrole, (163) pyrrole-2-carboxylic
acid, (164) 3-carboxy-1,4-dimethyl-2-pyrroleacetic acid, (165) proline, (166) 2-pyrrolidone-5-carboxylic
acid, (167) 4-hydroxyproline, (168) 1,1'-ethylene bis (5-oxo-3-pyrrolidine carboxylic
acid), (169) kainic acid monohydrate, (170) 1-amino pyrrolidine hydrochloride, (171)
2-(2-chloroethyl)-1-methyl pyrrolidine hydrochloride, (172) 1-(2-chloroethyl) pyrrolidine
hydrochloride, (173) tremorine dihydrochloride, (174) L-proline methyl ester hydrochloride,
(175) ammonium pyrrolidine dithiocarbamate, (176) pyrrolidone hydrotribromide, (177)
1-(4-chlorobenzyl)-2-(1-pyrrolidinyl methyl) benzimidazole hydrochloride, (178) billverdin
dihydrochloride, (179) indole, (180) 4,5,6,7-tetrahydroindole, (181) 3-indolemethanol
hydrate, (182) 3-indole ethanol, (183) indole-3-carboxaldehyde, (184) 3-indolylacetate,
(185) indole-3-acetamide, (186) indole-3-carboxylic acid, (187) indole-3-acetic acid,
(188) 3-indole propionic acid, (189) 3-indole acrylic acid, (190) 3-indole glyoxylic
acid, (191) indole-3-pyruvic acid, (192) 3-indolelactic acid, (193) 3-indole butyric
acid, (194) N-acetyltryptophanamide, (195) N-(3-indolylacetyl)alanine, (196) N-(3-indolyl
acetyl)valine, (197) N-(3-indolyl acetyl)isoleucine, (198) N-(3-indolyl acetyl)leucine,
(199) N-(3-indolyl acetyl)aspartic acid, (200) N-(3-indolyl acetyl)-L-phenylalanine,
(201) 4-hydroxyindole, (202) indole-4-carboxylic acid, (203) 4-indolyl acetate, (204)
4-methyl indole, (205) 5-hydroxy indole, (206) 5-hydroxy indole-3-acetic acid, (207)
5-hydroxy-2-indole carboxylic acid, (208) N-acetyl-5-hydroxytryptamine, (209) indole-5-carboxylic
acid, (210) 5-methyl indole, (211) 5-methoxy indole, (212) indole-2-carboxylic acid,
(213) indolene-2-carboxylic acid, (214) indole-2,3-dione, (215) 2-methyl indole, (216)
2,3,3-trimethyl indolenine, (217) tryptamine hydrochloride, (218) 5-methyl tryptamine
hydrochloride (219) serotonin hydrochloride hemihydrate, (220) norharman hydrochloride
monohydrate, (221) harmane hydrochloride monohydrate, (222) harmine hydrochloride
hydrate, (223) harmaline hydrochloride dihydrate, (224) harmol hydrochloride dihydrate,
(225) harmalol hydrochloride dihydrate, (226) 3,6-diamino acridine hydrochloride,
(227) (3-indolyl) isothiuronium iodide, (228) yohimbine hydrochloride, 229) pyrazole,
(230) 3-amino pyrazole, (231) 5-amino-1-ethylpyrazole, (232) 3-amino-4-carbethoxypyrazole,
(233) 3-amino-5-methylpyrazole, (234) 3-amino-5-phenylpyrazole, (235) ethyl 4-pyrazole
carboxylate, (236) diethyl 3,5-pyrazolecarboxylate, (237) 1,1'-(1-ethylpropylidene)bis
1H-pyrazole, (238) 4-bromopyrazole, (239) 4-bromo-3-methyl pyrazole, (240) 3,5-dimethyl
pyrazole, (241) 4-bromo-3,5-dimethyl pyrazole, (242) 3,5-dimethyl pyrazole-1-carboxamide,
(243) 3,5-dimethylpyrazole-1-methanol, (244) 3-methyl-1-vinylpyrazole, (245) 4-benzoyl-3-methyl-1-phenyl-2-pyrazolin-5-one,
(246) 1-nitropyrazole, (247) 4-pyrazole carboxylic acid, (248) 3,5-pyrazole dicarboxylic
acid monohydrate, (249) 3-amino-5-hydroxypyrazole, (250) 3-amino-4-pyrazole carbonitrile,
(251) 3-amino-4-pyrzaolecarboxylic acid, (252) 4-methyl pyrazole hydrochloride, (253)
3,4-diamino-5-hydroxy pyrazole sulfate, (254) (3,5-dimethyl pyrazole-1-carboxamidine
nitrate), (255) 3-amino-4-pyrazole carboxamide hemisulfate, (256) acid salt of 6-amino
indazole hydrochloride, (257) 4-hydroxypyrazolo [3,4-d] pyrimidine, (258) 4-mercapto-1H-pyrazolo-[3,4-d]-pyrimidine,
(259) indazole, (260) 5-aminoindazole, (261) 6-aminoindazole, (262) 3-indazolinone,
(263) N'-(6-indazolyl) sulfanilamide, (264) 4,5-dihydro-3-(4-pyridinyl)-2H-benz[g]
indazole methane sulfonate, (265) imidazole, (266) 4-methylimidazole, (267) 2-ethylimidazole,
(268) 2-propylimidazole, (269) 1-butylimidazole, (270) 2-undecylimidazole, (271) histamine,
(272) 1-(3-aminopropyl) imidazole, (273) 1-acetylimidazole, (274) 2-methyl-1-vinylimidazole,
(275) 2-ethyl-4-methylimidazole, (276) 1-benzyl-2-methylimidazole, (277) 1-methylbenzimidazole,
(278) 1-ethyl-3-methyl-1,H-imidazolinium chloride, (279) 2-(aminomethyl) benzimidazole
dihydrochloride hydrate, (280) 2,6-diamino-8-purinol hemisulfate monohydrate, (281)
purin-6-yl-trimethyl ammonium chloride, (282) 4-methyl-5-imidazole methanol hydrochloride,
(283) N,N'-bis[3-(4,5-dihydro-1H-imidazol-2-yl)phenyl]urea dipropanoate, (284) 1-(p-tosyl)-3,4,4-trimethyl-2-imidazolinium
iodide, (285) 1-ethyl-3-methyl-1H-imidazolinium chloride, (286) 2-amino imidazole
sulfate, (287) 4-amino-5-imidazole carboxamide hydrochloride, (288) 2-hydrazino-2-imidazoline
hydrobromide, (289) imidazole hydrochloride, (290) 4-imidazole acetic acid hydrochloride,
(291) 2-benzyl-2-imidazoline hydrochloride, (292) propyl-1-(1-phenyl ethyl imidazole-5-carboxylate
hydrochloride, (293) 2,6-diamino purine sulfate hydrate, (294) 1-tallow amido ethyl-3-methyl-2-heptadecyl
imidazolinium methyl sulfate, (295) isostearyl ethyl imidonium ethyl sulfate, (296)
methyl-1-tallow amido ethyl-2-tallow imidazolinium methyl sulfate, (297) isostearyl
benzyl imidonium chloride, (298) methyl-1-hydrogenated tallow amido ethyl (299) hydrogenated
tallow imidazolinium methyl sulfate, (300) 1-methyl-1-oleyl amido ethyl-2-oleyl-imidazolinium
methyl sulfate, (301) cocohydroxyethyl polyethyleneglycol imidazolinium chloride phosphate,
(302) guanine, (303) guanosine hydrate, (304) xanthine, (305) 1-methylxanthine, (306)
3-methyl xanthine, (307) 3-isobutyl-1-methyl xanthine, (308) hypoxanthin, (309) xanthosine
dihydrate, (310) 6-thioxanthene, (311) purine, (312) 6-amino purine, (313) 6-methoxy
purine hemihydrate, (314) 6-mercaptopurine monohydrate, (315) 2-amino-6-chloropurine,
(316) 2-amino-6,8-dihydroxy purine, (317) theophylline (3,7 dihydro-1,3-dimethyl-1H-purine-2,6-dione),
(318) kinetin, (319) 1-methyl adenine, (320) 3-methyl adenine, (321) adenosine, (322)
inosine, (323) 6-mercaptopurine riboside, (324) 6-amino purine hydrochloride hemihydrate,
(325) 6-amino purine sulfate, (326) 2,6-diamino-8-purinol hemisulfate monohydrate,
(327) benzimidazole, (328) 2-aminobenzimidazole, (329) 2-amino-5,6-dimethlybenzimidazole,
(330) 5-benzimidazole carboxylic acid, (331) 2,4,5-trimethyl benzimidazole, (332)
2-guanidinobenzimidazole, (333) 2-hydroxybenzimidazole, (334) 4-(2-keto-1-benzimidazolinyl)
piperidine, (335) 2-imidazolidine thione, (336) 2-imidazolidone, (337) hydantoin,
(338) 1-methyl hydantoin, (339) creatinine, (340) 2-thiohydrantoin, (341) 5-hydantoin
acetic acid, (342) 5-ureidohydantoin, (343) 5,5-dimethyl hydantoin, (344) 2-imidazolidone-4-carboxylic
acid, (345) N,N-bis (2-hydroxyethyl) isonicotinamide, (346) 1,2-bis(4-pyridyl) ethylene,
(347) 2-(2-piperidinoethyl) pyridine, (348) 1,2-bis (4-pyridyl)ethane, (349) 4,4'-trimethylene
pyridine, (350) aldrithiol-2, (351) aldrithiol-4, (352) 1,3-bis (3-pyridylmethyl)-2-thiourea,
(353) 2,2':6',2"-terpyridine, (354) 2-[N,N-bis(triflouromethylsulfonyl)amino]pyridine,
(355) 2,3-pyridine dicarboxylic acid, (356) 2,4-pyridine dicarboxylic acid monohydrate,
(357) 2,5-pyridine dicarboxylic acid, (358) 2,6-pyridine dicarboxylic acid, (359)
3,4-pyridine dicarboxylic acid, (360) 3,5-pyridine dicarboxylic acid, (361) 2,6-pyridine
dicarboxaldehyde, (362) 3,4-pyridine carboxamide, (363) 3,4-pyridine carboximide,
(364) 2,3-pyridine carboxylic anhydride, (365) 3,4-pyridine carboxylic anhydride,
(366) 2,6-pyridine methanol, (367) 2-pyridine ethane sulfonic acid, (368) 4-pyridine
ethane sulfonic acid, (369) 3-pyridine sulfonic acid, (370) pyridoxic acid, (371)
trans-3-(3-pyridyl) acrylic acid, (372) 2-pyridyl hydroxymethane sulfonic acid, (373)
3-pyridyl hydroxymethane sulfonic acid, (374) 6-methyl-2,3-pyridine dicarboxylic acid,
(375) isonicotinic acid, (376) pyridine hydrobromide, (377) pyridine hydrochloride,
(378) 2-(chloromethyl) pyridine hydrochloride, (379) 2-pyridylacetic acid hydrochloride,
(380) nicotinoyl chloride hydrochloride, (381) 2-hydrazinopyridine dihydrochloride,
(382) 2-(2-methyl aminoethyl) pyridine dihydrochloride, (383) 1-methyl-1,2,3,6-tetrahydropyridine
hydrochloride, (384) 2,6-dihydroxypyridine hydrochloride, (385) 3-hydroxy-2(hydroxymethyl)
pyridine hydrochloride, (386) pyridoxine hydrochloride, (387) pyridoxal hydrochloride,
(388) pyridoxal 5-phosphate monohydrate, (389) 3-amino-2,6-dimethoxy pyridine hydrochloride,
(390) pyridoxamine dihydrochloride monohydrate, (391) iproniazid phosphate, (392)
tripelennamine hydrochloride, (393) pyridinium bromide perbromide, (394) pyridinium
3-nitrobenzenesulfonate, (395) 1-ethyl-3-hydroxy pyridinium bromide, (396) 1-ethyl-4-(methoxy
carbonyl) pyridinium iodide, (397) 1-heptyl-4-(4-pyridyl) pyridinium bromide, (398)
1-dodecyl pyridinium chloride, (399) 1-hexadecyl pyridinium chloride monohydrate,
(400) 1-hexadecyl pyridinium bromide monohydrate, (401) 1-(carboxymethyl) pyridinium
chloride, (402) 1-(carboxymethyl) pyridinium chloride hydrazide, (403) 1-(3-nitrobenzyloxymethyl)
pyridinium chloride, (404) 1-(3-sulfopropyl) pyridinium hydroxide, (405) N-(lauroyl
colamino formyl methyl) pyridinium chloride, (406) N-(stearoyl colamine formyl methyl)
pyridinium chloride, (407) 2-chloro-1-methyl pyridinium iodide, (408) 2-pyridine aldoxime-1-methyl
methane sulfonate, 2-pyridine aldoxime-1-methyl chloride, (409) 2-[4-(dimethyl amino)
styryl]1-ethylpyridinium iodide, (410) 1-benzyl-3-hydroxy pyridinium chloride, (411)
1,4 dimethyl pyridinium iodide, (412) 1-ethyl-4-phenyl pyridinium iodide, (413) 4-phenyl-1-propyl
pyridinium iodide, (414) 1-docosyl-4-(4 hydroxystyryl) pyridinium bromide, (415) 1,1'-dimethyl-4-4'-bipyridinium
dichloride, (416) 1,1'-diethyl-4-4'-bipyridinium dibromide, (417) 1,1'-dibenzyl-4,4'-bipyridinium
dichloride, (418) 1,1'-diheptyl-4,4'-bipyridinium dibromide, (419) 1,7-phenanthroline,
(420) 1,10-phenanthroline, (421) 5-chloro-1,10-phenanthroline, (422) 4,5-dihydro-3-(4-pyridinyl)-2H-benz[g]
indazole methane sulfonate, (423) 1,2,3,4-tetrahydro quinoline, (424) 6-ethoxy-1,2,3,4-tetrahydro-2,2,4-trimethyl
quinoline, (425) 2-cyanoquinoline, (426) 1-cyanoisoquinoline, (427) 3-cyanoisoquinoline,
(428) 3-amino quinoline, (429) 8-aminoquinoline, (430) 7,8-benzoquinoline, (431) 8-hydroxy
quinoline, (432) 8-hydroxyquinoline, aluminium salt, (433) 8-hydroxyquinaldine, (434)
3,4,5,6,7,8-hexahydro 2 (1H)-quinolinone, (435) julolidine, (436) quinoxaline, (437)
ethyl-2-quinoxalinecarboxylate, (438) quinoline, (439) 2-hydroxyquinoline, (440) 4-hydroxy
quinoline, (441) 5-hydroxy quinoline, (442) 5-amino quinoline, (443) 6-amino quinoline,
(444) 2-quinoline carboxylic acid, (445) 3-quinoline carboxylic acid, (446) 4-quinoline
carboxylic acid, (447) 4-quinoline carboxaldehyde, (448) 2-quinoline thiol, (449)
2,4-quinoline diol, (450) quinaldine, (451) 4-aminoquinaldine, (452) 2,6-dimethyl
quinoline, (453) 2,7-dimethyl quinoline, (454) 4-methoxy-2-quinoline carboxylic acid,
(455) methyl-2-phenyl-4-quinoline carboxylate, (456) 2-(N-butyl carbamoyl)-1,2,3,4-tetrahydro-isoquinoline,
(457) 1-hydroxyisoquinoline, (458) 1-isoquinoline carboxylic acid, (459) 3-isoquinoline
carboxylic acid, (460) 1,5-isoquinoline diol, (461) 8-hydroxyquinoline hemisulfate
hemihydrate, (462) 5-amino-8-hydroxy quinoline dihydrochloride, (463) 2-(chloromethyl)
quinoline monohydrochloride, (464) 8-hydroxyquinoline-5-sulfonic acid monohydrate,
(465) 8-ethoxy-5-quinoline sulfonic acid sodium salt hydrate, (466) 1,2,3,4-tetrahydroisoquinoline
hydrochloride, (467) 1,2,3,4-tetrahydro-3-isoquinoline carboxylic acid hydrochloride,
(468) 6,7-dimethoxy-1,2,3,4-tetrahydro isoquinoline hydrochloride, (469) 1-methyl-6,7-dihydroxy-1,2,3,4-tetrahydro
isoquinoline hydrobromide, (470) primaquine diphosphate, (471) pentaquine phosphate,
(472) dibucaine hydrochloride, (473) 9-aminoacridine hydrochloride hemihydrate, (474)
3, 6-diamino acridine hemisulfate, (475) 2-quinoline thiol hydrochloride, (476) sparteine
sulfate pentahydrate, (477) papaverine hydrochloride, (478) emetine dihydrochloride
hydrate, (479) 1,10-phenanthroline monohydrochloride monohydrate, (480) neocuproine
hydrochloride trihydrate, (481) pyrimidine, (482) 2 chloropyrimidine, (483) 4-phenylpyrimidine,
(484) 5-bromopyrimidine, (485) 2,4-dichloropyrimidine, (486) 4,6-dichloropyrimidine,
(487) 2,4-dichloro-6-methylpyrimidine, (488) 6-chloro-2,4-dimethoxypyrimidine, (489)
2-amino-4,6-dimethoxypyrimidine, (490) 2,4,6-trichloropyrimidine, (491) 2,4,5,6-tetrachloropyrimidine,
(492) 1,3,4,6,7,8-hexahydro-1-methyl-2H-pyrimido [1,2-a] pyrimidine, (493) 1,3,4,6,7,8-hexahydro-2H-pyrimido
[1,2-a] pyrimidine, (494) hexetidine, (495) tert-butyl S-(4,6-dimethylpyrimidin-2-yl)
thiocarbonate, (496) 4-methoxybenzyl-S(4,6-dimethylpyrimidin-2-yl) thiocarbonate,
(497) 2-amino pyrimidine, (498) 2-amino-4-methyl pyrimidine, (499) 2-amino-5-nitropyrimidine,
(500) 2-amino-5-bromopyrimidine, (501) 2-amino-4-chloro-6-methyl pyrimidine, (502)
2-amino-4,6-dimethyl pyrimidine, (503) 2-amino-4-hydroxy-6-methyl pyrimidine, (504)
2-amino-4,6-dichloropyrimidine, (505) 2-amino-5-bromo-6-methyl-4-pyrimidinol, (506)
4-aminopyrimidine, (507) 4,5-diamino pyrimidine, (508) 4-amino-2,6-dimethyl pyrimidine,
(509) 2,4-diamino-6-hydroxypyrimidine, (510) 2,6-diamino-4-chloro pyrimidine, (511)
4,6-diamino-2-mercaptopyrimidine hemihydrate, (512) 2,4,6-triamino pyrimidine, (513)
5-nitroso-2,4,6-triamino pyrimidine, (514) 4,6-dihydroxy pyrimidine, (515) 4,6-dihydroxy-2-amino
pyrimidine, (516) 4,6-dihydroxy-2-methyl pyrimidine, (517) 4,6-dihydroxy-5-nitropyrimidine,
(518) 2,4-dihydroxy-5-methyl pyrimidine, (519) 2,4-dihydroxy-6-methyl pyrimidine,
(520) 2,4-dihydroxy-5,6-dimethyl pyrimidine, (521) 2,6-dihydroxy pyrimidine-5-carboxylic
acid hydrate, (522) 2,6-dihydroxy-4-amino pyrimidine, (523) 2,4,5-trihydroxy pyrimidine,
(524) 2-thiouracil, (525) 6-amino-5-nitroso-2-thiouracil, (526) folic acid dihydrate,
(527) folinic acid, calcium salt hydrate, (528) 2-hydroxypyrimidine hydrochloride,
(529) 2-hydroxy-4-methyl pyrimidine hydrochloride, (530) 4,6-dimethyl-2-hydroxypyrimidine
hydrochloride, (531) 2-mercapto-4-methyl pyrimidine hydrochloride, (532) 4,6-diamino
pyrimidine hemisulfate monohydrate, (533) 4,5,6-triamino pyrimidine sulfate hydrate,
(534) 4,5-diamino-6-hydroxy pyrimidine sulfate, (535) 2,4-diamino-6-mercapto pyrimidine
hemisulfate, (536) 2,4-diamino-6-hydroxy pyrimidine hemisulfate hydrate, (537) 6-hydroxy-2,4,5-triamino
pyrimidine sulfate, (538) 5,6-diamino-2,4-dihydroxy pyrimidine sulfate, (539) N4-(2-amino-4-pyrimidinyl)
sulfanilamide monohydrochloride, (540) 2,4,5,6-tetraamino pyrimidine sulfate, (541)
2,4 (1H,3H)-pyrimidine dione, (542) 5-amino uracil, (543) 5-nitrouracil, (544) 5-iodouracil,
(545) 5-(hydroxymethyl) uracil hydrate, (546) 5,6-dihydrouracil, (547) 6-amino-1-methyl
uracil, (548) 5,6-diamino-1,3-dimethyl uracil hydrate, (549) uridine, (550) 5-methyl
uridine, (551) 5-iodouridine, (552) thimidine, (553) 5-methyl-2-thiouracil, (554)
4-thiouridine, (555) 2-thiocytidine dihydrate, (556) orotic acid monohydrate, (557)
hydroorotic acid, (558) 5-aminoorotic acid, (559) methylorotate, (560) barbituric
acid, (561) 5-nitrobarbituric acid trihydraet, (562) violuric acid monohydrate, (563)
alloxan monohydrate, (564) 4,5,6-triamino-2(1H)-pyrimidinethione sulfate, (565) cyclocytidine
hydrochloride, (566) cytosine arabinoside hydrochloride, (567) pyridazine, (568) phthalazine,
(569) 4,5-dihydro-6-methyl-3(2H)-pyridazinone monohydrate, (570) 3,6-dichloropyridazine,
(571) 3,4,5-trichloropyridazine, (572) 3,6-dichloro-4-methylpyridazine, (573) 3-chloro-6-methoxypyridazine,
(574) pyrazine, (575) acetylpyrazine, (576) aminopyrazine, (577) 2,6-dichloropyrazine,
(578) 2,3,5-trimethylpyrazine, (579) tetramethylpyrazine, (580) 5-methyl-2-pyrazine
carboxylic acid, (581) pyrazine amide, (582) 2,3-pyrazine dicarboxamide, (583) 4-pyridazine
carboxylic acid, (584) 2,3-pyrazine dicarboxylic acid, (585) lumazine monohydrate,
(586) xanthopterin monohydrate, (587) 2-quinoxazoline carboxylic acid, (588) 2-quinoxalinol,
(589) 2,3-dihydroxy quinoxaline, (590) phenazine methosulfate, (591) 2-azetidinone,
(592) 2-pyrrolidinone, (593) pyrrolidone hydrotribromide, (594) δ-valerolactam, (595)
ε-caprolactam, (596) amino-ε-caprolactam, (597) N-methyl caprolactam, (598) 2-azacyclooctanone,
(599) 2-azacyclononanone, (600) ω-thiocaprolactam, (601) N-vinylcaprolactam, (602)
2-azabicyclo[2.2.1]hept-5-en-3-one, (603) maleimide, (604) N-ethylmaleimide, (605)
N-butylmaleimide, (606) N-cyclohexylmaleimide, (607) N-phenylmaleimide, (608) N-benzylmaleimide,
(609) N-hydroxymaleimide, (610) succinimide, (611) N-methylsuccinimide, (612) 2-hydroxy-N-methylsuccinimide,
(613) N-hydroxysuccinimide, (614) succinimidyl 2,2,2-trichloroethyl carbonate, (615)
2-dodecyl-N-(2,2,6,6-tetramethyl-4-ppiperidinyl) succinimide, (616) 2-dodecyl-N-(1,2,2,6,6-pentamethyl-4-piperdinyl)
succinimide, (617) N-(1-acetyl-2,2,6,6-tetramethyl-4-piperidinyl)-2-dodecyl succinimide,
(618) α-methyl-α-propylsuccinimide, (619) α-methyl-α-phenylsuccinimide, (620) N-vinylphthalimide,
(621) N-ethylphthalimide, (622) N-(trimethylsilylmethyl)phthalimide, (623) N-(2-bromoethyl)phthalimide,
(624) N-(3-bromopropyl)phthalimide, (625) N-(4-bromobutyl)phthalimide, (626) phthalimidoacetaldehyde
diethyl acetal, (627) diethyl (phthalimidomethyl)phosphonate, (628) N-benzylphthalimide,
(629) phthalimide, DBU (1,8-diazabicyclo [5.4.0]undec-7-ene) salt, (630) phthalimide,
DBN (1,5-diazabicyclo [4.3.0]non-5-ene), and (631) mixtures thereof; or wherein the
transparentizing agent is an oxa-aza-cyclic compound; or wherein the transparentizing
agent is selected from the group consisting of: (A) materials of the general formulae:

wherein R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
14, and R
15 each, independently of the others, are selected from the group consisting of hydrogen
atoms, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups,
arylalkyl groups, substituted arylalkyl groups, hydroxy groups, amine groups, imine
groups, ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde
groups, ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl
groups, thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide
groups, phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile
groups, mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups,
acyl groups, acid anhydride groups, and azide groups, wherein two or more of R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
14, and R
15 can be joined together to form a ring; (B) materials of the general formula:

wherein R
1, R
2, R
3, R
4, R
5, and R
6 each, independently of the others, are selected from the group consisting of hydrogen
atoms, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups,
arylalkyl groups, substituted arylalkyl groups, hydroxy groups, amine groups, imine
groups, ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde
groups, ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl
groups, thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide
groups, phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile
groups, mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups,
acyl groups, acid anhydride groups, and azide groups, wherein two or more of R
1, R
2, R
3, R
4, R
5, and R
6 can be joined together to form a ring; (C) mixtures thereof; or wherein the transparentizing
agent is selected from the group consisting of (1) 3-amino-5-methyl isoxazole, (2)
5-amino-3-methyl isoxazole, (3) 3,5-dimethyl-4-nitroisoxazole, (4) 1,2-benzisoxazole,
(5) 2,1-benzisoxazole, (6) cycloserine, (7) 4-benzyl-2-methyl-2-oxazoline, (8) 2-methyl-5-phenyl-2-oxazoline-4-methanol,
(9) benzoxazole, (10) 2-methylbenzoxazole, (11) 2-chlorobenzoxazole, (12) 2-chloro-3-ethylbenzeneoxazolium
tetrafluoroborate, (13) 2-oxazolidone, (14) 3-methyl-2-oxazolidinone, (15) 5-chloromethyl-2-oxazolidinone,
(16) 4-isopropyl-2-oxazolidinone, (17) 3-acetyl-2-oxazolidinone, (18) 5,5-dimethyl
oxazolidine-2,4-dione, (19) 3-ethyl-2-thioxo-4-oxazolidinone, (20) 4-methyl-5-phenyl-2-oxazolidinone,
(21) 4-benzyl-2-oxazolidinone, (22) 2-benzoisoxazolinone, (23) muscimol hydrate, (24)
5-methyl-3-phenyl isoxazole-4-carboxylic acid, (25) 2-methyl-5-phenyl-2-oxazoline-4-methanol,
(26) sulfamethoxazole, (27) sulfisoxazole, (28) N'-(4,5-dimethyloxazol-2-yl) sulfanilamide,
(29) chlorzoxazone, (30) 3,3'-dimethyl oxacarbocyanine iodide, (31) 2-ethyl-5-phenyl
isoxazolium-3'-sulfonate, (32) 2-tert-butyl-5-methyl isoxazolium perchlorate, (33)
5-phenyl-2-(4-pyridyl) oxazole hydrochloride hydrate, (34) 5-phenyl-2-(4-pyridyl)
oxazole methyl tosylate salt, (35) 4-aminomorpholine, (36) 4-morpholine carbonitrile,
(37) 4-morpholine propionitrile, (38) 4-formyl morpholine, (39) 4-acetylmorpholine,
(40) 4-(2-hydroxyethyl) morpholine, (41) 3-morpholino-1,2-propane diol, (42) 4-(3-amino
propyl) morpholine, (43) 1-morpholino-1-cyclopentene, (44) 1-morpholino-1-cyclohexene,
(45) 1-morpholino-1-cycloheptene, (46) 4-phenyl morpholine, (47) 4-morpholinoaniline,
(48) 2,2,2-tribromoethyl phosphoromorpholino chloridate, (49) 1-(morpholino carbonyl
methyl) piperazine, (50) 1,3-dimorpholine-2-nitropropane, (51) hemicholinium-3, (52)
hemicholinium-15, (53) 2-methoxy-4-morpholinobenzene diazoniumchloride, zinc chloride,
(54) fomocaine, (55) 4-morpholinobenzophenone, (56) 4,4'-ethylene-bis (2,6-morpholinedione),
(57) N,N'-dicylcohexyl-4-morpholine carboxamidine, (58) 1-cyclohexyl-3-(2-morpholino
ethyl)-2-thiourea, (59) 4-morpholinoacetophenone, (60) 4-(2-chloroethyl) morpholine
hydrochloride, (61) 4-morpholine ethane sulfonic acid, (62) 4-morpholine propane sulfonic
acid, (63) β-hydroxy morpholine propane sulfonic acid, (64) [N-(aminoiminomethyl)-4-morpholine
carboximidamide] hydrochloride, (65) 4-morpholine carbodithioic acid compound with
morpholine, (66) 2,5-dimethyl-4-(morpholinomethyl) phenol hydrochloride monohydrate,
(67) 1-cyclohexyl-3-(2-morpholinoethyl) carbodiimide metho-p-toluene sulfonate, (68)
hemicholinium-3[2,2'-(4,4'-biphenylene) bis(2-hydroxy-4,4-dimethyl morpholinium bromide),
(69) hemicholinium-15[4,4-dimethyl-2-hydroxy-2-phenyl morpholinium bromide], (70)
1-aza-12-crown-4, (71) 1-aza-15-crown-5, (72) 1-aza-18-crown-6, (73) 1,4,10-trioxa-7,13-diazacyclopentadecane,
(74) 1,4,10,1 3-tetraoxa-7,16-diazacyclooctadecane, (75) N,N'-dibenzyl-1,4,10,13-tetraoxa-7,16-diazacyclooctadecane,
(76) 4,7,13,18-tetraoxa-1,10-diazabicyclo [8.5.5] eicosane, (77) 4,7,13,16,21-pentaoxa-1,10-diazabicyclo
[8.5.5] tricosane, (78) 4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo [8.8.8] hexacosane,
(79) 5,6-benzo-4,17,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8] hexacosane, and (80)
mixtures thereof; or wherein the transparentizing agent is an oxacyclic compound;
or wherein the transparentizing agent is selected from the group consisting of: (A)
materials of the general formula:

wherein the curved portion of the structure represents a hydrocarbon chain or a substituted
hydrocarbon chain, wherein two or more substituents can be joined together to form
a ring; (B) materials of the general formulae:

wherein R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
14, R
15, R
16, R
17, R
18, R
19, R
20, R
21, R
22, R
23, R
24, R
25, R
26, R
27, and R
28 each, independently of the others, are selected from the group consisting of hydrogen
atoms, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups,
arylalkyl groups, substituted arylalkyl groups, hydroxy groups, amine groups, imine
groups, ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde
groups, ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl
groups, thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide
groups, phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile
groups, mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups,
acyl groups, acid anhydride groups, and azide groups, wherein two or more of R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
14, R
15, R
16, R
17, R
18, R
19, R
20, R
21, R
22, R
23, R
24, R
25, R
26, R
27, and R
28 can be joined together to form a ring; (C) materials of the general formula:

wherein the curved portion of the structure represents a hydrocarbon chain or a substituted
hydrocarbon chain, wherein two or more substituents can be joined together to form
a ring; (D) materials of the general formulae:

wherein R
1, R
2, R
3, R
4, R
5, R
6, R
7, and R
8 each, independently of the others, are selected from the group consisting of hydrogen
atoms, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups,
arylalkyl groups, substituted arylalkyl groups, hydroxy groups, amine groups, imine
groups, ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde
groups, ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl
groups, thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide
groups, phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile
groups, mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups,
acyl groups, acid anhydride groups, and azide groups, wherein two or more of R
1, R
2, R
3, R
4, R
5, R
6, R
7, and R
8 can be joined together to form a ring; (E) materials of the general formulae:

wherein the curved portions of the structures represent a hydrocarbon chain or a
substituted hydrocarbon chain, wherein two or more substituents can be joined together
to form a ring; (F) materials of the general formula:

wherein R
1, R
2, R
3, R
4, R
5, and R
6 each, independently of the others, are selected from the group consisting of hydrogen
atoms, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups,
arylalkyl groups, substituted arylalkyl groups, hydroxy groups, amine groups, imine
groups, ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde
groups, ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl
groups, thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide
groups, phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile
groups, mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups,
acyl groups, acid anhydride groups, and azide groups, wherein two or more of R
1, R
2, R
3, R
4, R
5, and R
6 can be joined together to form a ring; and (G) mixtures thereof; or wherein the transparentizing
agent is selected from the group consisting of (1) γ-butyrolactone, (2) γ-valerolactone,
(3) γ-caprolactone, (4) γ-octanoic lactone, (5) γ-nonanoic lactone, (6) γ-decanolactone,
(7) undecanoic γ-lactone, (8) γ-phenyl-γ-butyrolactone, (9) α-carbethoxy-γ-phenyl-butyrolactone,
(10) 2-coumaranone, (11) β,β-dimethyl-γ-(hydroxymethyl)-γ-butyrolactone, (12) γ-ethoxy
carbonyl-γ-butyrolactone, (13) 5-(hydroxymethyl)-2(5H)-furanone, (14) dihydro-4,4-dimethyl-2,3-furandione,
(15) 2,5-dimethyl-4-hydroxy-3(2H)-furanone, (16) mevalonic (β-hydroxy β-methyl-δ-valero)
lactone, (17) δ-decanolactone, (18) undecanoic δ-lactone, (19) δ-dodecanolactone,
(20) undecanoic ω-lactone, (21) oxacyclotridecan-2-one, (22) ω-pentadecalactone, (23)
hydrindantin (2,2'-dihydroxy-2,2'-biindan-1,1'3,3'-tetrone, (24) hydrindantin dihydrate,
(25) 2-oxepanone, (26) 4H-pyran-2-one, (27) methylcoumalate, (28) methyl 2-oxo-2H-pyran-3-carboxylate,
(29) 4,6-dimethyl-α-pyrone, (30) 4-methoxy-6-methyl-2H-pyran-2-one, (31) 3,6-dihydro-4,6,6-trimethyl-2H-pyran-2-one,
(32) 3,4-dihydro-6-methyl-2H-pyran-2-one, (33) 3-acetyl coumarin, (34) 6-methyl coumarin,
(35) 7-ethoxy coumarin, (36) ethyl-3-coumarin carboxylate, (37) 7-diethylamino-4-methyl
coumarin, (38) dihydro coumarin, (39) 3-bromo-2-coumaranone, (40) patulin, (41) 4H-pyran-4-one,
(42) 2-ethyl-3-hydroxy-4H-pyran-4-one, 43v) butopyronoxyl(butyl 3,4-dihydro-2,2-dimethyl-4-oxo-2H-pyran-6-carboxylate,
(44) dehydroacetic acid, (45) 4-chromone, (46) 4-chromanone, (47) 4-chromanol, (48)
6,7-dimethoxy-2,2-dimethyl-4-chromanone, (49) 3-isochromanone, (50) 6,7-dimethoxy-3-isochromanone,
(51) 6-ethyl-4-oxo-4H-1-benzopyran-3-carbonitrile, (52) 6-ethyl-4-oxo-4H-1-benzopyran-3-carboxaldehyde,
(53) 6-isopropyl-4-oxo-4H-1-benzopyran-3-carbonitrile, (54) 6-isopropyl-4-oxo-4H-1-benzopyran-3-carboxaldehyde,
(55) maleic anhydride, (56) bromomaleic anhydride, (57) citraconic anhydride, (58)
2,3-dimethylmaleic anhydride, (59) dichloromaleic anhydride, (60) cis-aconitic anhydride,
(61) itaconic anhydride, (62) methylsuccinic anhydride, (63) acetylmercaptosuccinic
anhydride, (64) 2,2-dimethylsuccinic anhydride, (65) phenylsuccinic anhydride, (66)
2-octen-1-ylsuccinic anhydride, (67) 2-dodecen-1-ylsuccinic anhydride, (68) 2-octadecen-1-ylsuccinic
anhydride, (69) 3-oxabicyclo [3.1.0] hexane-2,4-dione, (70) diglycolic anhydride,
(71) glutaric anhydride, (72) 3-methylglutaric anhydride, (73) 2,2-dimethylglutaric
anhydride, (74) 3,3-tetramethyleneglutaric anhydride, (75) 1-cyclopentene-1,2-dicarboxylic
anhydride, (76) 3,4,5,6-tetrahydrophthalic anhydride, (77) cis-1,2-cyclohexanedicarboxylic
anhydride, (78) hexahydro-4-methylphthalic anhydride, (79) methyl-5-norbornene-2,3-dicarboxylic
anhydride, (80) 2,3-pyridinecarboxylic anhydride, (81) 3,4-pyridinecarboxylic anhydride,
(82) furfurylmercaptan, (83) S-furfurylthioacetate, (84) furfurylsulfide, (85) furfurylmethyldisulfide,
(86) furfuryldisulfide, (87) glycolaldehyde dimer, (88) 6,7-dihydrocyclopenta-1,3-dioxin-5(4H)-one,
(89) (2R,6R)-tert-butyl-6-methyl-1,3-dioxan-4-one, (90) 2,2-dimethyl-1,3-dioxane-4,6-dione,
(91) 3,6-dimethyl-1,4-dioxane-2,5-dione, (92) 2,2,6-trimethyl-4H-1,3-dioxin-4-one,
(93) 2,2,5-trimethyl-1,3-dioxane-4,6-dione, (94) 5-bromo-2,2,5-trimethyl-1,3-dioxane-4,6-dione,
(95) 1,3-dioxane-5,5-dimethanol, (96) 1,3,5-trioxane, (97) 1,6-dioxaspiro [4.4]nonane-2,7-dione,
(98) 1,4-dioxaspiro [4.5]decan-2-one, (99) 1,7-dioxaspiro [5.5]undecane, (100) 2,4,8,10-tetraoxaspiro[5.5]undecane,
(101) 3,9-divinyl-2,4,8-tetraoxaspiro[5.5]undecane, (102) 2,2-pentamethylene-1,3-dioxalane,
(103) 2-phenyl-1,3-dioxalane, (104) 1,4-cyclohexanedione monoethylene ketal, (105)
1,4-cyclohexanedione bis(ethylene ketal), (106) 1,4-cyclohexanedione mono-2,2-dimethyl
trimethylene ketal, (107) piperonal, (108) piperonyl acetate, (109) piperonyl alcohol,
(110) piperonylnitrile, (111) piperonyl amine, (112) 6-nitropiperonal, (113) 6-nitropiperonyl
alcohol, (114) 3',4'-(methylenedioxy)acetophenone, (115) 3,4-(methylenedioxy)aniline,
(116) 2,3-(methylenedioxy)benzaldehyde, (117) 3,4-(methylenedioxy)phenylacetonitrile,
(118) 3,4-(methylenedioxy)toluene, and (119) mixtures thereof; or wherein the transparentizing
agent is a crown ether; or wherein the transparentizing agent is selected from the
group consisting of (1) 1,4,7,10-tetraoxacyclododecane (12-crown-4), (2) 2-(hydroxyethyl)-12-crown-4,
(3) 2-(aminoethyl)-12-crown-4, (4) benzo-12-crown-4, (5) 1,4,7,10,13-pentaoxacyclododecane
(15-crown-5), (6) 2-(hydroxyethyl)-15-crown-5, (7) 2-(aminoethyl)-15-crown-5, (8)
benzo-15-crown-5, (9) 4'-aminobenzo-15-crown-5, (10) 4'-formylbenzo-15-crown-5, (11)
4'-nitrobenzo-15-crown-5, (12) bis [(benzo-15-crown-5)-15-ylmethyl] pimelate, (13)
1,4,7,10,13,16-hexaoxacyclooctadecane (18-crown-6), (14) 2-(aminoethyl)-18 crown-6,
(15) benzo-18 crown-6, (16) 4'-bromobenzo-18-crown-6, (17) dibenzo-18-crown-6, (18)
di-tert-butyldibenzo-18-crown-6, (19) cis-dicyclohexane-18 crown-6, (20) dibenzo-24-crown-8,
(21) dicyclohexano-24-crown-8, (22) dibenzo-30-crown-10, and (23) mixtures thereof;
or wherein the transparentizing agent is a cyclic hydrocarbon; or wherein the transparentizing
agent is selected from the group consisting of: (A) materials of the general formulae:

wherein R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, and R
12 each, independently of the others, are selected from the group consisting of hydrogen
atoms, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups,
arylalkyl groups, substituted arylalkyl groups, hydroxy groups, amine groups, imine
groups, ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde
groups, ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl
groups, thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide
groups, phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile
groups, mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups,
acyl groups, acid anhydride groups, and azide groups, wherein two or more of R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, and R
12 can be joined together to form a ring; (B) materials of the general formula:

wherein R
1, R
2, R
3, R
4, R
5, and R
6 each, independently of the others, are selected from the group consisting of hydrogen
atoms, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups,
arylalkyl groups, substituted arylalkyl groups, hydroxy groups, amine groups, imine
groups, ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde
groups, ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl
groups, thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide
groups, phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile
groups, mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups,
acyl groups, acid anhydride groups, and azide groups, wherein two or more of R
1, R
2, R
3, R
4, R
5, and R
6 can be joined together to form a ring; (C) materials of the general formula:

wherein R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, and R
10 each, independently of the others, are selected from the group consisting of hydrogen
atoms, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups,
arylalkyl groups, substituted arylalkyl groups, hydroxy groups, amine groups, imine
groups, ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde
groups, ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl
groups, thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide
groups, phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile
groups, mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups,
acyl groups, acid anhydride groups, and azide groups, wherein two or more of R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, and R
10 can be joined together to form a ring; (D) materials of the general formulae:

wherein R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, and R
12 each, independently of the others, are selected from the group consisting of hydrogen
atoms, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups,
arylalkyl groups, substituted arylalkyl groups, hydroxy groups, amine groups, imine
groups, ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde
groups, ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl
groups, thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide
groups, phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile
groups, mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups,
acyl groups, acid anhydride groups, and azide groups, wherein two or more of R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, and R
12 can be joined together to form a ring; (E) materials of the general formula:

wherein R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, and R
10 each, independently of the others, are selected from the group consisting of hydrogen
atoms, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups,
arylalkyl groups, substituted arylalkyl groups, hydroxy groups, amine groups, imine
groups, ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde
groups, ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl
groups, thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide
groups, phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile
groups, mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups,
acyl groups, acid anhydride groups, and azide groups, wherein two or more of R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, and R
10 can be joined together to form a ring; (F) materials of the general formulae:

wherein R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, and R
10 each, independently of the others, are selected from the group consisting of hydrogen
atoms, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups,
arylalkyl groups, substituted arylalkyl groups, hydroxy groups, amine groups, imine
groups, ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde
groups, ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl
groups, thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide
groups, phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile
groups, mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups,
acyl groups, acid anhydride groups, and azide groups, wherein two or more of R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, and R
10 can be joined together to form a ring; (G) materials of the general formula:

wherein the curved portion of the structure represents a hydrocarbon chain or a substituted
hydrocarbon chain, wherein two or more substituents can be joined together to form
a ring; and (H) mixtures thereof; or wherein the transparentizing agent is selected
from the group consisting of (1) norbornane, (2) 2-norbornane carbonitrile, (3) 2-norbornane
methanol, (4) 3-methyl-2-norbornane methanol, (5) camphene, (6) fenchyl alcohol, (7)
thiocamphor, (8) norbornene, (9) 5-norbornene-2-carbonitrile, (10) 5-norbornene-2-carboxaldehyde,
(11) 5-norbornene-2-methanol, (12) 5-norbornene-2,2-dimethanol, (13) 5-norbornene-2-benzoyl,
(14) 2-norbornanone, (15) 3-chloro-2-norbornanone, (16) fenchone, (17) 3-(trifluoroacetyl)camphor,
(18) 3-heptafluorobutyryl camphor, (19) 3-bromocamphor, (20) 9,10-dibromocamphor,
(21) 3,9,10-tribromocamphor, (22) dicyclopentadiene, (23) methylcyclopentadiene dimer,
(24) tricyclo[5.2.1]decane, (25) 4,8-bis(hydroxymethyl)tricyclo[5.2.1.0
2.6]decane, (26) 8-ketotricyclo[5.2.1.0
2.6]decane, (27) 3,4-dimethoxy-3-cyclobutene-1,2-dione, (28) 3,4-diethoxy-3-cyclobutene-1,2-dione,
(29) 3,4-diisopropoxy-3-cyclobutene-1,2-dione, (30) 3,4-dibutoxy-3-cyclobutene-1,2-dione,
(31) 3-methyl-2-(nitromethyl)-5-oxocyclopentaneacetic acid, (32) 3-ethyl-2-hydroxy-2-cyclopenten-1-one,
(33) methyl-4-methoxy-2-oxo-3-cyclopentene-1-carboxylate, (34) 3,3a,6,6a-tetrahydro-2H-cyclopenta[b]furan-2-one,
(35) 3a,4,5,6a-hexahydro-5-hydroxy-4(hydroxymethyl)-2H-cyclopenta[b]furan-2-one, (36)
3-methyl-1,2-cyclopentanedione, (37) 4-hydroxy-5-methyl-4-cyclopentene-1,3-dione monohydrate,
(38) 2,4,4-trimethylcyclohexen-1-one, (39) ethyl-6-methyl-2-oxo-3-cyclohexene-1-carboxylate,
(40) ethyl 4-hydroxy-6-methyl-2-oxo-3-cyclohexene-1-carboxylate, (41) 5-(1-acetoxy-1-methylethyl)-2-methyl-2-cyclohexen-1-one,
(42) thymoquinone, (43) 2,6,6-trimethyl-2-cyclohexene-1,4-dione, (44) indan, (45)
1-indanol, (46) 2-indanol, (47) 1-indanone, (48) 2-indanone, (49) 2-acetyl-1-tetralone,
(50) 4-methyl-1-tetralone, 513) 5,7-dimethyl-1-tetralone, (52) 6,7-dimethoxy-1-tetralone,
(53) 1-methyl-2-tetralone, (54) 6,7-dimethoxy-2-tetralone, (55) cyclohexanone, (56)
cycloheptanone, (57) cyclooctanone, (58) cyclononanone, (59) cyclodecanone, (60) cycloundecanone,
(61) cyclododecanone, (62) cyclotridecanone, (63) cyclopentadecanone, (64) 2-acetylcyclohexanone,
(65) 2-allylcyclohexanone, (66) 2-phenylcyclohexanone, (67) cyclohexanedione, (68)
2-acetyl-1,3-cyclohexanedione, (69) 4,4-dimethyl-1,3-cyclohexanedione, (70) 2-acetyl-1,3-cyclopentanedione,
(71) 3,3,5,5-tetramethyl-1,2-cyclopentanedione, (72) bicyclo[3.2.1]octan-2-one, (73)
endo-dimethyl 7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylate, (74) cineole, (75) bicyclo[2.2.2]oct-5-ene-2,3-dimethanol,
(76) tropone, (77) tropolone, (78) cyclooctene oxide, (79) 1,2,5,6-diepoxycyclooctane,
(80) 9-methyl-Δ
5(10)-octalin-1,6-dione, (81) cis-bicyclo[3.3.0]octane-3.7-dione, (82) azulene, (83) 1-benzosuberone,
(84) 1,5,9-cyclododecatriene, (85) cyclododecane epoxide, (86) 2,3-cyclododeceno pyridine,
(87) 1,2,5,6,9,10-hexabromo cyclododecane, (88) 8-cyclohexadecen-1-one, (89) bicyclo[10.3.0]pentadec-12(1)-en-13-one,
(90) 1,4,4a,8a-tetrahydro-endo-1,4-methanonaphthalene-5,8-dione, and (19) mixtures
thereof; or wherein the transparentizing agent is a thiourea; or wherein the transparentizing
agent is a sulfone; or wherein the transparentizing agent is a thiocyclic compound;
or wherein the transparentizing agent is selected from the group consisting of sulfites,
sulfite derivatives, sulfides, sulfide derivatives, quaternary sulfur compounds, quaternary
sulfur derivatives, and mixtures thereof; or wherein the transparentizing agent is
a thia-aza-cyclic compound; or wherein the transparentizing agent is selected from
the group consisting of (1) 1-allyl-2-thioure, (2) 1-methallyl-3-methyl-2-thiourea,
(3) 4-allyl-3-thiosemicarbazide, (4) 1,3-diethyl-2-thiourea, (5) 1,3-dibutyl-2-thiourea,
(6) 1-benzyl-3-methyl-2-thiourea, (7) 1,1,3,3-tetramethyl-2-thiourea, (8) 2-imino-4-thiobiuret,
(9) 1-allyl-3-(2-hydroxyethyl)-2-thiourea, (10) S-(2-aminoethyl)isothiouronium bromide
hydrobromide, (11) S,S-diphenylsulfillimine monohydrate, (12) methylsulfon), (13)
ethylsulfone, (14) butylsulfone, (15) butadiene sulfone, (16) tetramethylene sulfone,
(17) 1,4-butane sulfone, (18) 1,4-butanediolcyclic sulfate, (19) benzylsulfone, (20)
phenylsulfone, (21) phenylvinylsulfone, (22) phenylstyrenesulfone, (23) phenyl-2-(trimethylsilyl)methyl
sulfone, (24) phenyl 2-(trimethylsilyl)ethyl sulfone, (25) phenyl 2-(trimethylsilyl)ethynyl
sulfone, (26) 4-(fluorophenyl)sulfone, (27) 4-(fluorophenyl)methyl sulfone, (28) chloromethylphenyl
sulfone, (29) chloromethyl-p-tolyl sulfone, (30) 2-chloroethylphenyl sulfone, (31)
methylthiomethylphenyl sulfone, (32) methylthiomethyl-p-tolyl sulfone, (33) 2-(phenylsulfonyl)
tetrahydropyran, (34) 1-(phenylsulfonyl)indole, (35) 1-(p-toluenesulfonyl)imidazole,
(36) 1-(p-tosyl)-3,4,4-trimethyl imidazolidine, (37) 4-(p-tosylsulfonyl)hexahydro
-1,4-thiazepine, (38) thionaphthene, (39) 4-keto-4,5,6,7-tetrahydrothianaphthene,
(40) 2,2'-bithiophene, (41) 2,2':5',2"-terthiophene, (42) N-acetylhomocysteine thiolactone,
(43) tetrahydrothiopyran-4-one, (44) thiochroman-4-one, (45) thiochroman-4-ol, (46)
thioctic acid, (47) ethyl 1,3-dithiolane-2-carboxylate, (48) 3H-1,2-benzodithiol-3-one,
(49) 1,3-dithiane, (50) 2-phenyl-1,3-dithiane, (51) ethyl-1,3-dithiane-2-carboxylate,
(52) 5,6-dihydro-5-methyl-4H-1,3,5-dithiazine, (53) 1,4-dithiane, (54) 2,5-dihydroxy-2,5-dimethyl-1,4-dithiane,
(55) 1,5-dithiacyclooactan-3-ol, (56) 1,4-dithiaspiro [45] decan-8-ol, (57) 1,3,5-trithiane,
(58) 1,4,7-trithiacyclononane, (59) 1,4,7-trithiacyclodecane, (60) 1,4,7,10-tetrathiacyclododecane,
(61) 3,6,9,14-tetrathiabicyclo [9.2.1] tetradeca-11,13-diene, (62) 1,4,8,1-tetrathiacyclotetradecane,
(63) 1,5,9,13-tetrathiocyclohexadecane, (64) 1,5,9,13-tetrathiacyclohexadecane-3,11-diol,
(65) 1,4,7,10,13-pentathiacyclopentadecane, (66) 1,4,7,10,13,16-hexathiacyclooctadecane,
(67) 1,5,9,13,17,21-hexathiacyclotetracosane-3,1 1,19-triol, (68) 1,4,7,10,13,16,19,22-octathiacyclotetracosane,
(69) 1,4,8,11,15,18,22,25-octathiacyclooctacosane, (70) 1,4,7,10,13,16,19,22,25-nonathiacycloheptacosane,
(71) dimethylsulfite, (72) diethylsulfite, (73) sodium sulfite, (74) allyldisulfide,
(75) aminophenyldisulfide, (76) benzyldisulfide, (77) benzylphenylsulfide, (78) trimethylsulfonium
methylsulfate, (79) (2-chloroethyl)dimethylsulfonium iodide, (80) 3-(chloropropyl)diphenylsulfonium
tetrafluoroborate, (81) trimethyl sulfonium iodide, (82) trimethyl sulfoxonium iodide,
(83) trimethyl sulfoxonium chloride, (84) triphenyl methane sulfenyl chloride, (85)
dimethyl (2-methoxy-5-nitrobenzyl) sulfonium bromide, (86) thionin perchlorate, (87)
p-xylylene bis(tetrahydrothiopheneum chloride), (88) tris (dimethyl amino) sulfonium
difluorotrimethyl silicate, (89) tris (dimethyl amino) sulfonium trifluoromethoxide,
(90) (3-amino-3-carboxypropyl) dimethyl sulfonium chloride, and (91) mixtures thereof;
or wherein the transparentizing agent is of one of the general formulae:

wherein R
1, R
2, R
3, R
4, R
5, R
6, and R
7 each, independently of the others, are selected from the group consisting of hydrogen
atoms, alkyl groups, substituted alkyl groups, aryl groups, substituted aryl groups,
arylalkyl groups, substituted arylalkyl groups, hydroxy groups, amine groups, imine
groups, ammonium groups, pyridine groups, pyridinium groups, ether groups, aldehyde
groups, ketone groups, ester groups, amide groups, carboxylic acid groups, carbonyl
groups, thiocarbonyl groups, sulfate groups, sulfonate groups, sulfide groups, sulfoxide
groups, phosphine groups, phosphonium groups, phosphate groups, cyano groups, nitrile
groups, mercapto groups, nitroso groups, halogen atoms, nitro groups, sulfone groups,
acyl groups, acid anhydride groups, and azide groups, wherein two or more of R
1, R2, R3, R4, R
5, R6, and R7 can be joined together to form a ring; or wherein the transparentizing
agent is selected from the group consisting of (1) 2-amino-2-thiazoline, (2) 2-amino
thiazole, (3) 2-amino-4-methylthiazole, (4) 2-amino-4-methylthiazole, (5) 2-amino-4-thiazoleacetic
acid, (6) 2-acetamido-4-methylthiazole, (7) 2-acetylthiazole, (8) 5-acetyl-2,4-dimethylthiazole,
(9) 4-methyl-5-vinylthiazole, (10) 2-amino-4-phenyl-5-tetradecylthiazole, (11) 2,4-thiazolidine
dione, (12) 3-aminorhodanine, (13) 3-methylrhodanine, (14) 3-ethylrhodanine, (15)
3-allylrhodanine, (16) 3-hydroxy-4-methyl-2(3H)-thiazolethione, (17) benzothiazole,
(18) 2-methylbenzothiazole, (19) 2-(methylthio)benzothiazole, (20) 2-amino-4-methylbenzothiazole,
(21) 3-methylbenzothiazole-2-thione, (22) 2,1,3-benzothiadiazole, (23) 4-amino-2,1,3-benzothiadiazole,
(24) 3,4-dimethyl-5-(2-hydroxyethyl)thiazolium iodide, (25) 3-ethyl-5-(2-hydroxyethyl)4-methylthiazolium
bromide, (26) 2-amino-5-nitrothiazole, (27) 2-amino-α-(methoxyimino)-4-thiazole acetic
acid, (28) ethyl 2-amino-a-(hydroxyimino)-4-thiazole acetate, (29) ethyl 2-amino-a-(methoxyimino)-4-thiazole
acetate, (30) ethyl 2-amino-4-thiazole acetate, (31) ethyl 2-amino-4-thiazole glyoxylate,
(32) 1-phenyl-3-(2-thiazolyl)-2-thiourea, (33) 2-amino-4-methoxy benzothiazole, (34)
2-amino-5,6-dimethylbenzothiazole, (35) N'-(2-thiazolyl) sulfanilamide, 6-ethoxy-2-benzothiazole
sulfonamide, (37) ethyl-2-(formylamino)-4-thiazoleacetate, (38) ethyl-2-(formylamino)-4-thiazoleglyoxylate,
(39) 2-(formylamino)-α-(methoxyimino)-4-thiazole acetic acid, (40) 2-acetamido-4-methyl-5-thiazole
sulfonyl chloride, (41) 2-thioxo-4-thiazolidine carboxylic acid, (42) thiazolidine-4-carboxylic
acid, (43) pseudothiohydantoin, (44) 2-amino-1,3,4-thiadiazole, (45) 2-amino-5-trifluoromethyl-1,3,4-thiadiazole,
(46) 2-amno-5-methyl-1,3,4-thiadiazole, (47) 2-amino-5-ethyl-1,3,4-thiadiazole, (48)
2-amino-5-(ethylthio)-1,3,4-thiadiazole, (49) 5-amino-1,3,4-thiadiazole-2-thiol, (50)
2-acetamido-5-benzyl thio-1,3,4-thiadiazole, (51) 5-acetamido-1,3,4-thiadiazole-2-sulfonamide,
(52) 5-anilino-1,2,3,4-thiatriazole, (53) 2-amino-4,5-dimethyl thiazole hydrochloride,
(54) 2-amino 4-imino-2-thiazoline hydrochloride, (55) 2-amino-2-thiazoline hydrochloride,
(56) 2-amino-5-bromothiazole monohydrobromide, (57) 5-amino-3-methyl isothiazole hydrochloride,
(58) 3-methyl-2-benzothiazolinone hydrazone hydrochloride hydrate, (59) 5-amino-2-methylbenzothiazole
dihydrochloride, (60) 2,4-diamino-5-phenyl thiazole monohydrobromide, (61) 2-amino-4-phenyl
thiazole hydrobromide monohydrate, (62) 2-(tritylamino)-α-(methoxyimino)-4-thiazole
acetic acid hydrochloride, (63) (2,3,5,6-tetrahydro-6-phenylimidazo [2,1-b] thiazole
hydrochloride, (64) 3-ethyl-2-methyl-2-thiazolium iodide, (65) 3-benzyl-5-(2-hydroxyethyl)-4-methyl
thiazolium chloride, (66) thiamine hydrochloride, (67) 3-(carboxymethyl) benzothiazolium
bromide, (68) 2-azido-3-ethyl benzothiazolium tetrafluoroborate, (69) 3-ethyl-2-methyl
benzothiazolium iodide, (70) 2-methyl-3-propyl benzothiazolium iodide, (71) 3-ethyl-2-(2-hydroxy-1-propenyl)
benzothiazolium chloride, (72) 3,6-dimethyl-2-(4-dimethyl aminophenyl) benzothiazolium
bromide, (73) trifluoroperazine dihydrochloride, (74) thioridazine hydrochloride,
(75) promethazine hydrochloride, (76) ethopropazine hydrochloride, (77) chlorpromazine
hydrochloride, and (78) mixtures thereof; or wherein the transparentizing agent is
selected from the group consisting of phosphines, phosphites, cyclic phosphorus compounds,
phosphine oxides, quaternary phosphonium salts, and mixtures thereof; or wherein the
transparentizing agent is selected from the group consisting of (1) triphenylphosphine,
(2) tri-m-tolyl phosphine, (3) tris(3-methoxyphenyl)phosphine, (4) tris(4-chlorophenyl)phosphine,
(5) tris(pentafluorophenyl)phosphine, (6) tricyclohexylphosphine, (7) tribenzylphosphine,
(8) tri-2-furylphosphine, (9) bis (pyrrolidino)methoxy phosphone, (10) tetraphenylbiphosphine,
(11) 1,3-bis(diphenylphosphino)propane, (12) 1,5-bis(diphenylphosphino)pentane, (13)
1,6-bis(diphenylphosphino)hexane, (14) isopropyl diphenyl phosphine, (15) diphenyl
(p-tolyl) phosphine, (16) (4-bromophenyl) diphenyl phosphine, (17) diphenyl-2-pyridylphosphine,
(18) dicyclohexylphenyl phosphine, (19) trimethyl phosphite, (20) triethyl phosphite,
(21) tris(2-chloroethyl) phosphite, (22) tributyl phosphite, (23) triphenyl phosphite,
(24) trimethyl phosphite copper iodide, (25) triethyl phosphite copper iodide, (26)
dipropyl phosphite, (27) bis(2-ethylhexyl) phosphite, (28) bis(4-nitrobenzyl) phosphite,
(29) 2,2'-ethylidene bis(4,6-di-tert-butylphenyl) fluorophosphite, (30) pentaerythritol
diphenyl diphosphite, (31) 2-furyltetramethyl phosphorodiamidate, (32) diethyl(pyrrolidinomethyl)phosphonate,
(33) cyclophosphamide monohydrate, (34) 2-chloro-1,3,2-dioxaphospholane-2-oxide, (35)
N,N-diethyl-1,5-dihydro-2,4,3-benzodioxaphosphepin-3-amine, (36) 1,2-phenylene phosphochloridite,
(37) 1,2-phenylene phosphochloridate, (38) 2-chloro-4H-1,3,2-benzodioxaphosphorin-4-one,
(39) 2,4-bis(methylthio)-1,3-dithia-2,4-diphosphetane-2,4-disulfide, (40) triphenyl
phosphine oxide, (41) tris(hydroxymethyl) phosphine oxide, (42) trimethoxy phosphine
oxide, (43) triethoxy phosphine oxide, (44) triphenoxy phosphine oxide), (45) tris
(2-butoxy ethoxy) phosphine oxide, (46) diphenyl phosphine oxide, (47) diphenyl (2,4,6-trimethylbenzoyl)
phosphine oxide, (48) phenyl phosphinic acid, (49) diphenyl phosphate, (50) vinyl
phosphonic acid, (51) propyl phosphonic acid, (52) pyrophosphoric acid, (53) triphenylphosphate,
(54) tetrabutylphosphonium chloride, (55) tetrabutylphosphonium bromide, (56) hexadecyltributylphosphonium
bromide, (57) stearyltributylphosphonium bromide, (58) azidotris(diethylamino)phosphonium
bromide, (59) phosphonitrilic chloride trimer, (60) tetramethyl phosphonium bromide,
(61) tetramethyl phosphonium chloride, (62) tetraethyl phosphonium bromide, (63) tetraethyl
phosphonium chloride, (64) tetraethyl phosphonium iodide, (65) tetraphenyl phosphonium
bromide, (66) tetraphenyl phosphonium chloride, (67) tetraphenyl phosphonium Iodide,
(68) methyl triphenyl phosphonium bromide, (69) methyl triphenyl phosphonium iodide,
(70) ethyl triphenyl phosphonium bromide, (71) n-propyl triphenyl phosphonium bromide,
(72) isopropyl triphenyl phosphonium iodide, (73) cyclopropyl triphenyl phosphonium
bromide, (74) n-butyl triphenyl phosphonium bromide, (75) isobutyl triphenyl phosphonium
bromide, (76) hexyl triphenyl phosphonium bromide, (77) benzyl triphenyl phosphonium
chloride, (78) bromomethyl triphenyl phosphonium bromide, (79) chloromethyl triphenyl
phosphonium chloride, (80) 3-bromopropyl triphenyl phosphonium bromide, (81) 3-bromobutyl
triphenyl phosphonium bromide, (82) 4-bromobutyl triphenyl phosphonium bromide, (83)
2-dimethyl aminoethyl triphenyl phosphonium bromide, (84) [(3-dimethyl amino) propyl]
triphenyl phosphonium bromide, (85) 2-hydroxyethyl triphenyl phosphonium bromide,
(86) (2-hydroxyethyl) triphenyl phosphonium chloride, (87) [3-hydroxy-2-methyl propyl]
triphenyl phosphonium bromide, (88) [3-hydroxy-2-methyl propyl] triphenyl phosphonium
bromide, (89) (2-hydroxybenzyl triphenyl phosphonium bromide, (90) (formyl methyl)
triphenyl phosphonium chloride, (91) (methoxymethyl) triphenyl phosphonium chloride,
(92) acetonyl triphenyl phosphonium chloride, (93) carbomethoxymethyl triphenyl phosphonium
bromide, (94) (ethoxy carbonyl methyl) triphenyl phosphonium chloride, (95) carbethoxymethyl
triphenyl phosphonium bromide, (96) (tert-butoxy carbonyl methyl) triphenyl phosphonium
bromide, (97) phenacyl triphenyl phosphonium bromide, (98) (4-ethoxybenzyl) triphenyl
phosphonium bromide, (99) 4-butoxybenzyl triphenyl phosphonium bromide, (100) 2-(1,3-dioxan-2-yl)
ethyl] triphenyl phosphonium bromide, (101) (1,3-dioxolan-2-ylmethyl) triphenyl phosphonium
bromide, (102) vinyl triphenyl phosphonium bromide, (103) allyl triphenyl phosphonium
bromide, (104) allyl triphenyl phosphonium chloride, (105) propargyl triphenyl phosphonium
bromide, (106) (3-trimethyl silyl-2-propynyl) triphenyl phosphonium bromide, (107)
p-xylylene bis (triphenyl phosphonium bromide), and (108) mixtures thereof; or wherein
the transparentizing agent is a nitrile; or wherein the transparentizing agent is
selected from the group consisting of (1) cyanoacetohydrazide, (2) 4,4-dimethyl-3-oxopentanenitrile,
(3) 1-cyano-N-methylthioformamide, (4) cyanomethyl N,N-dimethyl dithiocarbamate, (5)
4-hydroxy-3-methoxy-phenyl acetonitrile, (6) tosyl cyanide, (7) tosylmethyl isocyanide,
(8) 5-fluoro-2-methyl benzonitrile, (9) 2-fluoro-5-methyl benzonitrile, (10) 4-(methylthio)
benzonitrile, (11) 4-(dimethylamino) benzonitrile, (12) 3,4-dimethoxy benzonitrile,
(13) 4-hydroxy-3-methoxy benzonitrile, (14) 4-(trans-4-pentyl cyclohexyl)benzonitrile,
(15) 4'-pentyl-4'-biphenyl carbonitrile, (16) 4'-(pentyloxy)-4-biphenylcarbonitrile,
(17) 4'-hexyl-4-biphenyl carbonitrile, (18) 4'-(hexyloxy)-4-biphenyl carbonitrile,
(19) 4'-heptyl-4-biphenyl carbonitrile, (20) 4'-heptyloxy-4-biphenyl carbonitrile,
(21) 4'-octyl-4-biphenyl carbonitrile, (22) 4'-(octyloxy)-4-biphenyl carbonitrile,
(23) succinonitrile, (24) fumaronitrile, (25) 1,4-dicyano-2-butene, (26) (dimethyl
aminomethylene)malononitrile, (27) (1-ethoxyethylidene)malononitrile, (28) α-chlorobenzylidenemalononitrile,
(29) benzylidenemalononitrile, (30) 2-benzoyloxy-2-phenyl malononitrile, (31) O-(p-tosyl)isonitrosomalononitrile,
(32) tetrafluorophthalonitrile, (33) iminodiacetonitrile, (34) phenylene diacetonitrile,
(35) 3,3'-(4-formyl phenylimino) dipropionitrile, (36) tris (2-cyanoethyl) nitromethane,
(37) 1,1,3,3-propanetetracarbonitrile, (38) tetracyanoethylene oxide, and (39) mixtures
thereof; or wherein the transparentizing agent is selected from the group consisting
of isothiocyanates, isocyanates, and mixtures thereof; or wherein the transparentizing
agent is selected from the group consisting of (1) 4-azidophenyl isothiocyanate, (2)
1-naphthyl isothiocyanate, (3) 4-dimethyl amino-1-naphthyl isothiocyanate, (4) 1-isothiocyanato-4-(trans-4-propyl
cyclohexyl) benzene, (5) 1-(trans-4-hexyl cyclohexyl)-4-isothiocyanato benzene, (6)
1-(4-trans-hexyl cyclohexyl)-4-[2-(4-isothio cyanatophenyl)] benzene, (7) 1-isothiocyanato-4-(trans-4-octylcyclohexyl)
benzene, (8) 4-isothiocyanatophenyl-4-pentabicyclo [2.2.2] octane-1-carboxylate, (9)
benzylthiocyanate, (10) guanidinethiocyanate, (11) methylene dithiocyanate, (12) 4,4'-methylene
bis (phenyl isocyanate), (13) 4,4'-methylene bis (2,6-diethyl isocyanate), and (14)
mixtures thereof; or wherein the transparentizing agent is selected from the group
consisting of oxime compound, hydroxamic acid compounds, and mixtures thereof; or
wherein the transparentizing agent is selected from the group consisting of (1) formamidoxime
(2) acetaldoxime, (3) pyruvic aldehyde-1-oxime, (4) acetone oxime, (5) ethylchlorooximido
acetate, (6) 2,3-butane dione monoxime, (7) 5-hydroxy pentenal oxime, (8) cyclopentanone
oxime, (9) cyclohexanone oxime, (10) cyclooctanone oxime, (11) benzaldehyde oxime,
(12) 2-nitrobenzaldehyde oxime, (13) salicyl aldoxime, (14) 2-isonitroso acetphenone,
(15) 1-phenyl-1,2-propanedione 2-oxime, (16) 2-pyridine aldoxime, (17) nifuroxime,
and (18) mixtures thereof; or wherein the transparentizing agent is a hydroxamic acid
derivative; or wherein the transparentizing agent is selected from the group consisting
of (1) acetohydroxamic acid, (2) suberohydroxamic acid, (3) mandelohydroxamic acid,
(4) benzohydroxamic acid, (5) N-phenylbenzohydroxamic acid, and (6) mixtures thereof;
or wherein the transparentizing agent is selected from the group consisting of alkyl
ammonium salts, aryl ammonium salts, arylalkyl ammonium salts, and mixtures thereof;
or wherein the transparentizing agent is selected from the group consisting of (1)
tetramethylammonium fluoride tetrahydrate, (2) tetraethylammonium acetate tetrahydrate,
(3) tetrabutylammonium chloride, (4) tetrabutylammonium chloride hydrate, (5) tetrabutylammonium
bromide, (6) tetrabutylammonium tribromide, (7) tetrabutylammonium acetate, (8) tetrabutylammonium
thiocyanate, (9) tetrapentylammonium bromide, (10) tetrahexylammonium bromide, (11)
tetrahexylammonium chloride, (12) tetrahexylammonium hydrogensulfate, (13) tetraheptylammonium
chloride, (14) tetraheptylammonium bromide, (15) tetraoctylammonium bromide, (16)
tetrakisdecylammonium bromide, (17) tetrahexadecylammonium bromide, (18) tetramethyl
ammonium bromide, (19) tetramethyl ammonium chloride, (20) tetramethyl ammonium iodide,
(21) tetraethyl ammonium bromide, (22) tetraethyl ammonium chloride, (23) tetraethyl
ammonium iodide, (24) tetrapropyl ammonium bromide, (25) tetrapropyl ammonium iodide,
(26) tetrabutyl ammonium iodide, (27) tetrapentyl ammonium chloride, (28) tetrahexyl
ammonium bromide, (29) tetrahexyl ammonium iodide, (30) tetradecyl ammonium bromide,
(31) tetradodecyl ammonium bromide, (32) tetraoctadecyl ammonium bromide, (33) methyltrioctylammonium
bromide, (34) tridodecylmethylammonium chloride, (35) tridodeylmethylammonium iodide,
(36) N-dodecyl-N-methylephedrinium bromide, (37) phenyltrimethylammonium tribromide,
(38) tricapryl methyl ammonium chloride, (39) tridodecyl methyl ammonium chloride,
(40) tridecyloxypropyl dihydroxy ethyl methyl ammonium chloride, (41) N-tetradecyl
dimethyl-naphthyl methyl ammonium chloride, (42) octadecyl diethanol methyl ammonium
chloride, (43) octadecyl dihydroxyethyl methyl ammonium chloride, (44) dihydrogenated
tallow benzyl methyl ammonium chloride, (45) 2-aminoethyl trimethyl ammonium chloride
hydrochloride, (46) 2-bromoethyl trimethyl ammonium bromide, (47) 2-chloroethyl trimethyl
ammonium chloride, (48) 3-carboxypropyl trimethyl ammonium chloride, (49) [3-(methacryloyl
amino) propyl] trimethyl ammonium chloride, (50) phenyl trimethyl ammonium bromide,
(51) phenyl trimethyl ammonium chloride, (52) phenyl trimethyl ammonium iodide, (53)
benzyl trimethyl ammonium chloride, (54) benzyl trimethyl ammonium bromide, (55) 4-nitrobenzyl
trimethyl ammonium chloride, (56) [2-(4-nitrophenyl) allyl] trimethyl ammonium iodide,
(57) coco trimethyl ammonium chloride, (58) palmityl trimethyl ammonium chloride,
(59) myristyl trimethyl ammonium bromide, (60) oleyl trimethyl ammonium chloride,
(61) soya trimethyl ammonium chloride, (62) tallow trimethyl ammonium chloride, (63)
hydrogenated tallow trimethyl ammonium chloride, (64) stearyl trimethyl ammonium chloride,
(365) behenyl trimethyl ammonium chloride, (66) guar hydroxypropyl trimethyl ammonium
chloride, (67) benzyl triethyl ammonium bromide, (68) butyl tripropyl ammonium bromide,
(69) methyl tributyl ammonium chloride, (70) methyl tributyl ammonium bromide, (71)
methyl tributyl ammonium iodide, (72) benzyl tributyl ammonium chloride, (73) benzyl
tributyl ammonium bromide, (74) benzyl tributyl ammonium iodide, (75) heptyl tributyl
ammonium bromide, (76) benzyldodecyldimethylammonium bromide, (77) benzyltetradecyldimethylammonium
chloride dihydrate, (78) benzylcetyldimethylammonium chloride monohydrate, (79) benzylstearyldimethylammonium
chloride monohydrate, (80) N,N-dimethyl methylene ammonium chloride, (81) N,N-dimethyl
methylene ammonium iodide, (82) chloromethylene dimethyl ammonium chloride, (83) dichloromethylene
dimethyl ammonium chloride, (84) dimethyl amino methylene amino methylene dimethyl
ammonium chloride, (85) benzethonium chloride, (86) methyl benzethoniumchloride, (87)
1-propanaminium 2,3-dihydroxy-N-dimethyl-N-[3(oxococoyl) amino]propyl]-chloride, (88)
cetyl dimethyl ethyl ammonium bromide, (89) octyl dodecyl dimethyl ammonium chloride,
(90) dodecyl (2-hydroxy-1-methyl-2-phenyl-ethyl) dimethyl ammonium bromide, (91) dodecyl
dimethyl 2-phenoxyethyl ammonium bromide, (92) dodecanoyl-N-methylamino ethyl-(phenyl
carbamyl methyl) dimethyl ammonium chloride, (93) 3-chloro-2-hydroxypropyl N,N,N-dimethyl
dodecyl ammonium chloride, (94) 3-chloro-2-hydroxypropyl N,N,N-dimethyl octadecyl
ammonium chloride, (95) dodecyl benzyl dimethyl ammonium bromide, (96) dodecyl benzyl
dimethyl ammonium chloride, (97) coco benzyl dimethyl ammonium chloride, (98) benzyl
tetradecyl dimethyl ammonium chloride, (99) benzyl cetyl dimethyl ammonium chloride,
(100) benzyl octadecyl dimethyl ammonium chloride, (101) benzyl tallow dimethyl ammonium
chloride, (102) benzyl hydrogenated tallow dimethyl ammonium chloride, (103) benzyl
behenyl dimethyl ammonium chloride, (104) dioctyl dimethyl ammonium chloride, (105)
didecyl dimethyl ammonium chloride, (106) didecyl dimethyl ammonium bromide, (107)
dicoco dimethyl ammonium chloride, (108) dicetyl dimethyl ammonium chloride, (109)
disoya dimethyl ammonium chloride, (110) ditallow dimethyl ammonium chloride, (111)
dihydrogenated tallow dimethyl ammonium chloride, (112) dibehenyl/diarachidyl dimethyl
ammonium chloride, (113) soya amido propyl benzyl dimethyl ammonium chloride, (114)
soya dicoco quaternary ammonium chloride, (115) gluconamidopropyl dimethyl-2-hydroxyethyl
ammonium chloride, (116) N-alkyl-N-N-dimethyl-N(dodecyl acetate) ammonium chloride,
wherein alkyl has from 14 to 20 carbon atoms, (117) mink amidopropyl dimethyl-2-hydroxyethyl
ammonium chloride, (118) N-rapeseed-(3-amidopropyl)-N-N-dimethyl-N-(2,3 epoxy propyl)
ammonium chloride, (119) N-stearyl-(3-amido propyl)-N-benzyl dimethyl ammonium chloride,
(120) rapeseed amido propyl benzyl dimethyl ammonium chloride, (121) rapeseed amido
propyl ethyl dimethyl ammonium chloride, (122) cocamidopropyl polyethylene glycol
dimethyl ammonium chloride phosphate, (123) butyrylcholine chloride, and (124) mixtures
thereof; or wherein the transparentizing agent is selected from the group consisting
of piperidine thiocyanate, 2-piperidine methanol, bis(pentamethylene) urea, 4,4'-trimethylene
bis(1-piperidine propionitrile), tripiperidino phosphine oxide, homopiperazine, 1-piperonyl
piperazine, hexacyclentrisulfate, 5,10,15,20-tetraphenyl-21H,23Hporphine, 5,10,15,20-tetrakis(4-methoxyphenyl)-2H,23H-porphine,
pyrrole-2-carboxaldehyde, 3-pyrrolidino-1,2-propanediol, pyrazole, 3-aminopyrazole,
imidazole, 2-ethylimidazole, 2-(2-piperidinoethyl) pyridine, 1-dodecyl pyridinium
chloride, pyridinium bromide perbromide, 3-aminoquinoline, 8-hydroxyquinoline, 7,8-benzoquinoline,
8-hydroxyquinaldine, quinoxaline, 4,5-dihydro-6-methyl-3(2H)-pyridazinone monohydrate,
phthalazine, 1,10-phenanthroline, 1,3,5-triazine, trichloromelamine, trichloroisocyanouric
acid, norbornane, tricyclo[5.2.1.0] decane, norcamphor, tropolone, 1-indanol, trans,trans,cis-1,5,9-cyclododecatriene,
cyclodecane epoxide, 2,3-cyclododecane pyridine, 1,2,5,6,9,10-hexabromo-cyclododecane,
1,4,4a,8a-tetrahydro-endo-1,4-methano-naphthalene-5,8-dione, γ-butyrolactone, β,β-dimethyl-γ-(hydroxymethyl)-γ-butyrolactone,
2,5-dimethyl-4-hydroxy-3(2H)-furanone, hydrindantin dihydrate, 2,4,8,10-tetraoxaspiro
[5.5]undecane, 1,3,5-trioxane, cyclooctanone, piperonal, piperonylalcohol, piperonyl
nitrile, 3,4(methylenedioxy) phenylacetonitrile, maleic anhydride, s-acetylmercapto
succinic anhydride, 2-octadecen-1-yl succinic anhydride, 18-crown-6, benzo-18 crown-6,
dibenzo-18 crown-6, dibenzo-24 crown-8, 5-amino-3-methyl isooxazole, 2-oxazolidone,
5,5-dimethyl oxazolidine-2,4-dione, 3-ethyl-2-thioxo-4-oxazolidinone, 3-morpholino-1,2-propandiol,
4-phenyl morpholine, N,N'-dibenzyl-1,4,10,13- tetraoxa-7,16 diazacycloocta-decane,
4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo [8.8.8] hexacosane, γ-valerolactam, ε-caprolactam,
2-azacyclooctanone, 2-azacyclononanone, maleimide, n-methylsuccinimide, phthalimide
DBU salt, 1-allyl-2-thiourea, 1,3-dithiane, 1-benzyl-3-methyl-2-2-imino-4-thiobiuret,
butyl sulfone, 2,2'-bithiophene, 2-phenyl-1,3-dithiane, 3,6,9,14-tetrathiabicyclo
[9.2.1] tetradeca-11,13-diene, 1,5,9,13-tetra-thiacyclohexadecane-3,11-diol, 1,4,7,10,13-penta-thiacyclopentadecane,
2-aminothiazole, 2-amino-2-thiazoline, 3-methyl rhodanine, 3-ethyl-5-(2-hydroxy-ethyl)-4-methylthiazolium
bromide, triphenylphosphine, tricyclohexylphosphine, 1,3-bis (diphenylphosphino) propane,
1,5-bis(diphenyl phosphino) pentane, isopropyldiphenyl phosphine, triethyl phosphite,
triphenyl phosphite, triethyl phosphite copper iodide, dipropyl phosphite, bis(2-ethylhexyl)
phosphite, bis(4-nitrobenzyl) phosphite, diphenyl phosphine oxide, diphenyl(2,4,6-trimethylbenzoyl)
phosphine oxide, vinyl phosphonic acid, cyanoaceto-hydrazide, cyanomethyl N,N-dimethyl
dithiocarbamate, 4'-pentyl-4'-biphenyl carbonitrile, 4'-(octyloxy)-4-biphenyl carbonitrile,
1,4-dicyano-2-butene, benzylidene malononitrile, 1-isothiocyanato-4-(trans-4-propylcyclohexyl)benzene,
formamidoxime, ethyl chlorooximido acetate, acetohydroxamic acid, tetrahexylammonium
chloride, tetraheptylammonium chloride, tetraheptylammonium bromide, and mixtures
thereof.
9. A process which comprises (1) providing the migration imaging member according to
claim 1, comprising (a) a substrate, (b) a softenable layer comprising a softenable
material and a photosensitive migration marking material, and (c) a transparentizing
agent which transparentizes migration marking material in contact therewith contained
in at least one layer of the migration imaging member; (2) uniformly charging the
imaging member; (3) subsequent to step (2), exposing the charged imaging member to
activating radiation at a wavelength to which the migration marking material is sensitive;
(4) subsequent to step (3), causing the softenable material to soften and enabling
a first portion of the migration marking material to migrate through the softenable
material toward the substrate in an imagewise pattern while a second portion of the
migration marking material remains substantially unmigrated within the softenable
layer, wherein subsequent to migration of the first portion of migration marking material,
either (a) the first portion of migration marking material contacts the transparentizing
agent and the second portion of migration marking material does not contact the transparentizing
agent; or (b) the second portion of migration marking material contacts the transparentizing
agent and the first portion of migration marking material does not contact the transparentizing
agent.
10. A process according to claim 9 wherein the first portion of migration marking material
contacts the transparentizing agent and the second portion of migration marking material
does not contact the transparentizing agent; or wherein the second portion of migration
marking material contacts the transparentizing agent and the first portion of migration
marking material does not contact the transparentizing agent.
1. Ein Migrationsbilderzeugungselement (1) umfassend (a) ein Substrat (2), (b) eine erweichbare
Schicht (6) umfassend ein erweichbares Material (7) und ein photo-empfindliches Migrationsmarkierungsmaterial
(8), und (c) ein transparentmachendes Mittel, welches das damit in Kontakt befindliche
Migrationsmarkierungsmaterial transparent macht, enthaltend in mindestens einer Schicht
des Migrationsbilderzeugungselementes, worin das transparentmachende Mittel das damit
in Kontakt kommende Migrationsmarkierungsmaterial beeinflußt durch Verringern der
optischen Dichte der erweichbaren Schicht, welche das Migrationsmarkierungsmaterial
enthält.
2. Ein Migrationsbilderzeugungselement gemäß Anspruch 1, worin das Migrationsmarkierungsmaterial
(8) ausgewählt ist aus der Gruppe bestehend aus (a) Selen, (b) Tellur, (c) Legierungen
von Selen und einem Material, ausgewählt aus der Gruppe bestehend aus Tellur, Arsen,
Antimon, Thallium, Wismut oder Mischungen davon, (d) Legierungen von Tellur und einem
Material ausgewählt aus der Gruppe bestehend aus Arsen, Antimon, Thallium, Wismut
oder Mischungen davon, (e) Halogen-dotiertem Selen, (f) Halogen-dotiertem Tellur,
(g) Halogen-dotierten Legierungen von Selen und einem Material ausgewählt aus der
Gruppe bestehend aus Tellur, Arsen, Antimon, Thallium, Wismut oder Mischungen davon,
(h) Halogen-dotierten Legierungen von Tellur und einem Material ausgewählt aus der
Gruppe bestehend aus Arsen, Antimon, Thallium, Wismut oder Mischungen davon und (i)
Mischungen davon.
3. Ein Migrationsbilderzeugungselement gemäß Anspruch 1 oder Anspruch 2, worin das transparentmachende
Mittel in der erweichbaren Schicht enthalten ist.
4. Ein Migrationsbilderzeugungselement gemäß Anspruch 1 oder Anspruch 2, worin das transparentmachende
Mittel in einer Schicht enthalten ist, die zwischen der erweichbaren Schicht und dem
Substrat angeordnet ist.
5. Das Migrationsbilderzeugungselement gemäß Anspruch 1 oder 2, worin die erweichbare
Schicht zwischen dem Substrat und einer Schicht angeordnet ist, welche das transparentmachende
Mittel enthält.
6. Ein Migrationsbilderzeugungselement gemäß Anspruch 1 oder Anspruch 2, worin das Migrationsbilderzeugungselement
umfaßt ein Substrat, eine erste erweichbare Schicht umfassend ein erstes erweichbares
Material und ein erstes Migrationsmarkierungsmaterial, und eine zweite erweichbare
Schicht umfassend ein zweites erweichbares Material und ein zweites Migrationsmarkierungsmaterial,
worin das transparentmachende Mittel in einer Schicht enthalten ist, die zwischen
der ersten erweichbaren Schicht und der zweiten erweichbaren Schicht angeordnet ist.
7. Ein Migrationsbilderzeugungselement gemäß einem der Ansprüche 1 bis 6, worin das transparentmachende
Mittel in einer Menge von etwa 1 bis etwa 50 Gew.-% des Materials umfassend die Schicht,
in welcher es enthalten ist, vorhanden ist.
8. Ein Migrationsbilderzeugungselement gemäß Anspruch 1, worin das transparentmachende
Mittel eine azacyclische Verbindung ist; oder worin das transparentmachende Mittel
ausgewählt ist aus der Gruppe bestehend aus: (A) Materialien der allgemeinen Formeln:

worin R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
14, R
15, R
16, R
17, R
18, R
19, R
20, R
21, R
22, R
23, R
24, R
25, R
26, R
27, R
28, R
29, R
30, R
31, R
32, R
33, R
34, R
35, R
36, R
37, R
38 und R
39 jeweils unabhängig voneinander ausgewählt sind aus der Gruppe bestehend aus Wasserstoffatomen,
Alkylgruppen, substituierten Alkylgruppen, Arylgruppen, substituierten Arylgruppen,
Arylalkylgruppen, substituierten Arylalkylgruppen, Hydroxygruppen, Amingruppen, Imingruppen,
Ammoniumgruppen, Pyridingruppen, Pyridiniumgruppen, Ethergruppen, Aldehydgruppen,
Ketongruppen, Estergruppen, Amidgruppen, Carbonsäuregruppen, Carbonylgruppen, Thiocarbonylgruppen,
Sulfatgruppen, Sulfonatgruppen, Sulfidgruppen, Sulfoxidgruppen, Phosphingruppen, Phosphoniumgruppen,
Phosphatgruppen, Cyangruppen, Nitrilgruppen, Mercaptogruppen, Nitrosogruppen, Halogenatomen,
Nitrogruppen, Sulfongnuppen, Acylgruppen, Säureanhydridgruppen und Azidgruppen, worin
zwei oder mehr von R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
14, R
15, R
16, R
17, R
18, R
19, R
20, R
21, R
22, R
23, R
24, R
25, R
26, R
27, R
28, R
29, R
30, R
31, R
32, R
33, R
34, R
35, R
36, R
37, R
38 und R
39 miteinander verbunden sein können, um einen Ring zu bilden; (B) Materialien der allgemeinen
Formeln:

worin R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
14, R
15, R
16, R
17, R
18, R
19, R
20, R
21 und R
22 jeweils unabhängig voneinander ausgewählt sind aus der Gruppe bestehend aus Wasserstoffatomen,
Alkylgruppen, substituierten Alkylgruppen, Arylgruppen, substituierten Arylgruppen,
Arylalkylgruppen, substituierten Arylalkylgruppen, Hydroxygruppen, Amingruppen, Imingruppen,
Ammoniumgruppen, Pyridingruppen, Pyridiniumgruppen, Ethergruppen, Aldehydgruppen,
Ketongruppen, Estergruppen, Amidgruppen, Carbonsäuregruppen, Carbonylgruppen, Thiocarbonylgruppen,
Sulfatgruppen, Sulfonatgruppen, Sulfidgruppen, Sulfoxidgruppen, Phosphingruppen, Phosphoniumgruppen,
Phosphatgruppen, Cyangruppen, Nitrilgruppen, Mercaptogruppen, Nitrosogruppen, Halogenatomen,
Nitrogruppen, Sulfongruppen, Acylgruppen, Säureanhydridgruppen und Azidgruppen, worin
zwei oder mehr von R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
14, R
15, R
16, R
17, R
18, R
19, R
20, R
21 und R
22 miteinander verbunden sein können, um einen Ring zu bilden; (C) Materialien der allgemeinen
Formeln:

worin R
1, R
2 und R
3 jeweils unabhängig voneinander ausgewählt sind aus der Gruppe bestehend aus Wasserstoffatomen,
Alkylgruppen, substituierten Alkylgruppen, Arylgruppen, substituierten Arylgruppen,
Arylalkylgruppen, substituierten Arylalkylgruppen, Hydroxygruppen, Amingruppen, Imingruppen,
Ammoniumgruppen, Pyridingruppen, Pyridiniumgruppen, Ethergruppen, Aldehydgruppen,
Ketongruppen, Estergruppen, Amidgruppen, Carbonsäuregruppen, Carbonylgruppen, Thiocarbonylgruppen,
Sulfatgruppen, Sulfonatgruppen, Sulfidgruppen, Sulfoxidgruppen, Phosphingruppen, Phosphoniumgruppen,
Phosphatgruppen, Cyangruppen, Nitrilgruppen, Mercaptogruppen, Nitrosogruppen, Halogenatomen,
Nitrogruppen, Sulfongruppen, Acylgruppen, Säureanhydridgruppen und Azidgruppen, worin
zwei oder mehr von R
1, R
2 und R
3 miteinander verbunden sein können, um einen Ring zu bilden; (D) Materialien der allgemeinen
Formeln:

worin R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11 und R
12 jeweils unabhängig voneinander ausgewählt sind aus der Gruppe bestehend aus Wasserstoffatomen,
Alkylgruppen, substituierten Alkylgruppen, Arylgruppen, substituierten Arylgruppen,
Arylalkylgruppen, substituierten Arylalkylgruppen, Hydroxygruppen, Amingruppen, imingruppen,
Ammoniumgruppen, Pyridingruppen, Pyridiniumgruppen, Ethergruppen, Aldehydgruppen,
Ketongruppen, Estergruppen, Amidgruppen, Carbonsäuregruppen, Carbonylgruppen, Thiocarbonylgruppen,
Sulfatgruppen, Sulfonatgruppen, Sulfidgruppen, Sulfoxidgruppen, Phosphingruppen, Phosphoniumgruppen,
Phosphatgruppen, Cyangruppen, Nitrilgruppen, Mercaptogruppen, Nitrosogruppen, Halogenatomen,
Nitrogruppen, Sulfongruppen, Acylgruppen, Säureanhydridgruppen und Azidgruppen, worin
zwei oder mehr von R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11 und R
12 miteinander verbunden sein können, um einen Ring zu bilden; (E) Materialien der allgemeinen
Formeln:

worin R
1, R
2, R
3 und R
4 jeweils unabhängig voneinander ausgewählt sind aus der Gruppe bestehend aus Wasserstoffatomen,
Alkylgruppen, substituierten Alkylgruppen, Arylgruppen, substituierten Arylgruppen,
Arylalkylgruppen, substituierten Arylalkylgruppen, Hydroxygruppen, Amingruppen, Imingruppen,
Ammoniumgruppen, Pyridingruppen, Pyridiniumgruppen, Ethergruppen, Aldehydgruppen,
Ketongruppen, Estergruppen, Amidgruppen, Carbonsäuregruppen, Carbonylgruppen, Thiocarbonylgruppen,
Sulfatgruppen, Sulfonatgruppen, Sulfidgruppen, Sulfoxidgruppen, Phosphingruppen, Phosphoniumgruppen,
Phosphatgruppen, Cyangruppen, Nitrilgruppen, Mercaptogruppen, Nitrosogruppen, Halogenatomen,
Nitrogruppen, Sulfongruppen, Acylgruppen, Säureanhydridgruppen und Azidgruppen, worin
zwei oder mehr von R
1, R
2, R
3 und R
4 miteinander verbunden sein können, um einen Ring zu bilden; (F) Materialien der allgemeinen
Formel:

worin R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13 und R
14 jeweils unabhängig voneinander ausgewählt sind aus der Gruppe bestehend aus Wasserstoffatomen,
Alkylgruppen, substituierten Alkylgruppen, Arylgruppen, substituierten Arylgruppen,
Arylalkylgruppen, substituierten Arylalkylgruppen, Hydroxygruppen, Amingruppen, Imingruppen,
Ammoniumgruppen, Pyridingruppen, Pyridiniumgruppen, Ethergruppen, Aldehydgruppen,
Ketongruppen, Estergruppen, Amidgruppen, Carbonsäuregruppen, Carbonylgruppen, Thiocarbonylgruppen,
Sulfatgruppen, Sulfonatgruppen, Sulfidgruppen, Sulfoxidgruppen, Phosphingruppen, Phosphoniumgruppen,
Phosphatgruppen, Cyangruppen, Nitrilgruppen, Mercaptogruppen, Nitrosogruppen, Halogenatomen,
Nitrogruppen, Sulfongruppen, Acylgruppen, Säureanhydridgruppen und Azidgruppen, worin
zwei oder mehr von R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13 und R
14 miteinander verbunden sein können, um einen Ring zu bilden; (G) Materialien der allgemeinen
Formel:

worin R
1 und R
2 jeweils unabhängig voneinander ausgewählt sind aus der Gruppe bestehend aus Wasserstoffatomen,
Alkylgruppen, substituierten Alkylgruppen, Arylgruppen, substituierten Arylgruppen,
Arylalkylgruppen, substituierten Arylalkylgruppen, Hydroxygruppen, Amingruppen, Imingruppen,
Ammoniumgruppen, Pyridingruppen, Pyridiniumgruppen, Ethergruppen, Aldehydgruppen,
Ketongruppen, Estergruppen, Amidgruppen, Carbonsäuregruppen, Carbonylgruppen, Thiocarbonylgruppen,
Sulfatgruppen, Sulfonatgruppen, Sulfidgruppen, Sulfoxidgruppen, Phosphingruppen, Phosphoniumgruppen,
Phosphatgruppen, Cyangruppen, Nitrilgruppen, Mercaptogruppen, Nitrosogruppen, Halogenatomen,
Nitrogruppen, Sulfongruppen, Acylgruppen, Säureanhydridgruppen und Azidgruppen, worin
R
1 und R
2 miteinander verbunden sein können, um einen Ring zu bilden; (H) Materialien der allgemeinen
Formel:

worin R
1, R
2, R
3, R
4 und R
5 jeweils unabhängig voneinander ausgewählt sind aus der Gruppe bestehend aus Wasserstoffatomen,
Alkylgruppen, substituierten Alkylgruppen, Arylgruppen, substituierten Arylgruppen,
Arylalkylgruppen, substituierten Arylalkylgruppen, Hydroxygruppen, Amingruppen, Imingruppen,
Ammoniumgruppen, Pyridingruppen, Pyridiniumgruppen, Ethergruppen, Aldehydgruppen,
Ketongruppen, Estergruppen, Amidgruppen, Carbonsäuregruppen, Carbonylgruppen, Thiocarbonylgruppen,
Sulfatgruppen, Sulfonatgruppen, Sulfidgruppen, Sulfoxidgruppen, Phosphingruppen, Phosphoniumgruppen,
Phosphatgruppen, Cyangruppen, Nitrilgruppen, Mercaptogruppen, Nitrosogruppen, Halogenatomen,
Nitrogruppen, Sulfongruppen, Acylgruppen, Säureanhydridgruppen und Azidgruppen, worin
zwei oder mehr von R
1, R
2, R
3, R
4 und R
5 miteinander verbunden sein können, um einen Ring zu bilden; (1) Materialien der allgemeinen
Formel:

worin R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8 und R
9 jeweils unabhängig voneinander ausgewählt sind aus der Gruppe bestehend aus Wasserstoffatomen,
Alkylgruppen, substituierten Alkylgruppen, Arylgruppen, substituierten Arylgruppen,
Arylalkylgruppen, substituierten Arylalkylgruppen, Hydroxygruppen, Amingruppen, Imingruppen,
Ammoniumgruppen, Pyridingruppen, Pyridiniumgruppen, Ethergruppen, Aldehydgruppen,
Ketongruppen, Estergruppen, Amidgruppen, Carbonsäuregruppen, Carbonylgruppen, Thiocarbonylgruppen,
Sulfatgruppen, Sulfonatgruppen, Sulfidgruppen, Sulfoxidgruppen, Phosphingruppen, Phosphoniumgruppen,
Phosphatgruppen, Cyangruppen, Nitrilgruppen, Mercaptogruppen, Nitrosogruppen, Halogenatomen,
Nitrogruppen, Sulfongruppen, Acylgruppen, Säureanhydridgruppen und Azidgruppen, worin
zwei oder mehr von R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8 und R
9 miteinander verbunden sein können, um einen Ring zu bilden; (J) Materialien der allgemeinen
Formel:

worin R
1, R
2, R
3 und R
4 jeweils unabhängig voneinander ausgewählt sind aus der Gruppe bestehend aus Wasserstoffatomen,
Alkylgruppen, substituierten Alkylgruppen, Arylgruppen, substituierten Arylgruppen,
Arylalkylgruppen, substituierten Arylalkylgruppen, Hydroxygruppen, Amingruppen, Imingruppen,
Ammoniumgruppen, Pyridingruppen, Pyridiniumgruppen, Ethergruppen, Aldehydgruppen,
Ketongruppen, Estergruppen, Amidgruppen, Carbonsäuregruppen, Carbonylgruppen, Thiocarbonylgruppen,
Sulfatgruppen, Sulfonatgruppen, Sulfidgruppen, Sulfoxidgruppen, Phosphingruppen, Phosphoniumgruppen,
Phosphatgruppen, Cyangruppen, Nitrilgruppen, Mercaptogruppen, Nitrosogruppen, Halogenatomen,
Nitrogruppen, Sulfongruppen, Acylgruppen, Säureanhydridgruppen und Azidgruppen, worin
zwei oder mehr von R
1, R
2, R
3 und R
4 miteinander verbunden sein können, um einen Ring zu bilden; (K) Materialien der allgemeinen
Formel:

worin R
1, R
2, R
3 und R
4 jeweils unabhängig voneinander ausgewählt sind aus der Gruppe bestehend aus Wasserstoffatomen,
Alkylgruppen, substituierten Alkylgruppen, Arylgruppen, substituierten Arylgruppen,
Arylalkylgruppen, substituierten Arylalkylgruppen, Hydroxygruppen, Amingruppen, Imingruppen,
Ammoniumgruppen, Pyridingruppen, Pyridiniumgruppen, Ethergruppen, Aldehydgruppen,
Ketongruppen, Estergruppen, Amidgruppen, Carbonsäuregruppen, Carbonylgruppen, Thiocarbonylgruppen,
Sulfatgruppen, Sulfonatgruppen, Sulfidgruppen, Sulfoxidgruppen, Phosphingruppen, Phosphoniumgruppen,
Phosphatgruppen, Cyangruppen, Nitrilgruppen, Mercaptogruppen, Nitrosogruppen, Halogenatomen,
Nitrogruppen, Sulfongruppen, Acylgruppen, Säureanhydridgruppen und Azidgruppen, worin
zwei oder mehr von R
1, R
2, R
3 und R
4 miteinander verbunden sein können, um einen Ring zu bilden; (L) Materialien der allgemeinen
Formel:

worin R
1, R
2, R
3, R
4 und R
5 jeweils unabhängig voneinander ausgewählt sind aus der Gruppe bestehend aus Wasserstoffatomen,
Alkylgruppen, substituierten Alkylgruppen, Arylgruppen, substituierten Arylgruppen,
Arylalkylgruppen, substituierten Arylalkylgruppen, Hydroxygruppen, Amingruppen, Imingruppen,
Ammoniumgruppen, Pyridingruppen, Pyridiniumgruppen, Ethergruppen, Aldehydgruppen,
Ketongruppen, Estergruppen, Amidgruppen, Carbonsäuregruppen, Carbonylgruppen, Thiocarbonylgruppen,
Sulfatgruppen, Sulfonatgruppen, Sulfidgruppen, Sulfoxidgruppen, Phosphingruppen, Phosphoniumgruppen,
Phosphatgruppen, Cyangruppen, Nitrilgruppen, Mercaptogruppen, Nitrosogruppen, Halogenatomen,
Nitrogruppen, Sulfongruppen, Acylgruppen, Säureanhydridgruppen und Azidgruppen, worin
zwei oder mehr von R
1, R
2, R
3, R
4 und R
5 miteinander verbunden sein können, um einen Ring zu bilden; (M) Materialien der allgemeinen
Formeln:

worin R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13 und R
14 jeweils unabhängig voneinander ausgewählt sind aus der Gruppe bestehend aus Wasserstoffatomen,
Alkylgruppen, substituierten Alkylgruppen, Arylgruppen, substituierten Arylgruppen,
Arylalkylgruppen, substituierten Arylalkylgruppen, Hydroxygruppen, Amingruppen, Imingruppen,
Ammoniumgruppen, Pyridingruppen, Pyridiniumgruppen, Ethergruppen, Aldehydgruppen,
Ketongruppen, Estergruppen, Amidgruppen, Carbonsäuregruppen, Carbonylgruppen, Thiocarbonylgruppen,
Sulfatgruppen, Sulfonatgruppen, Sulfidgruppen, Sulfoxidgruppen, Phosphingruppen, Phosphoniumgruppen,
Phosphatgruppen, Cyangruppen, Nitrilgruppen, Mercaptogruppen, Nitrosogruppen, Halogenatomen,
Nitrogruppen, Sulfongruppen, Acylgruppen, Säureanhydridgruppen und Azidgruppen, worin
zwei oder mehr von R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13 und R
14 miteinander verbunden sein können, um einen Ring zu bilden; (N) Materialien der allgemeinen
Formel:

worin R
1, R
2, R
3 und R
4 jeweils unabhängig voneinander ausgewählt sind aus der Gruppe bestehend aus Wasserstoffatomen,
Alkylgruppen, substituierten Alkylgruppen, Arylgruppen, substituierten Arylgruppen,
Arylalkylgruppen, substituierten Arylalkylgruppen, Hydroxygruppen, Amingruppen, Imingruppen,
Ammoniumgruppen, Pyridingruppen, Pyridiniumgruppen, Ethergruppen, Aldehydgruppen,
Ketongruppen, Estergruppen, Amidgruppen, Carbonsäuregruppen, Carbonylgruppen, Thiocarbonylgruppen,
Sulfatgruppen, Sulfonatgruppen, Sulfidgruppen, Sulfoxidgruppen, Phosphingruppen, Phosphoniumgruppen,
Phosphatgruppen, Cyangruppen, Nitrilgruppen, Mercaptogruppen, Nitrosogruppen, Halogenatomen,
Nitrogruppen, Sulfongruppen, Acylgruppen, Säureanhydridgruppen und Azidgruppen, worin
zwei oder mehr von R
1, R
2, R
3 und R
4 miteinander verbunden sein können, um einen Ring zu bilden; (O) Materialien der allgemeinen
Formel:

worin R
1, R
2, R
3 und R
4 jeweils unabhängig voneinander ausgewählt sind aus der Gruppe bestehend aus Wasserstoffatomen,
Alkylgruppen, substituierten Alkylgruppen, Arylgruppen, substituierten Arylgruppen,
Arylalkylgruppen, substituierten Arylalkylgruppen, Hydroxygruppen, Amingruppen, Imingruppen,
Ammoniumgruppen, Pyridingruppen, Pyridiniumgruppen, Ethergruppen, Aldehydgruppen,
Ketongruppen, Estergruppen, Amidgruppen, Carbonsäuregruppen, Carbonylgruppen, Thiocarbonylgruppen,
Sulfatgruppen, Sulfonatgruppen, Sulfidgruppen, Sulfoxidgruppen, Phosphingruppen, Phosphoniumgruppen,
Phosphatgruppen, Cyangruppen, Nitrilgruppen, Mercaptogruppen, Nitrosogruppen, Halogenatomen,
Nitrogruppen, Sulfongruppen, Acylgruppen, Säureanhydridgruppen und Azidgruppen, worin
zwei oder mehr von R
1, R
2, R
3 und R
4 miteinander verbunden sein können, um einen Ring zu bilden; (P) Materialien der allgemeinen
Formel:

worin R
1, R
2, R
3 und R
4 jeweils unabhängig voneinander ausgewählt sind aus der Gruppe bestehend aus Wasserstoffatomen,
Alkylgruppen, substituierten Alkylgruppen, Arylgruppen, substituierten Arylgruppen,
Arylalkylgruppen, substituierten Arylalkylgruppen, Hydroxygruppen, Amingruppen, Imingruppen,
Ammoniumgruppen, Pyridingruppen, Pyridiniumgruppen, Ethergruppen, Aldehydgruppen,
Ketongruppen, Estergruppen, Amidgruppen, Carbonsäuregruppen, Carbonylgruppen, Thiocarbonylgruppen,
Sulfatgruppen, Sulfonatgruppen, Sulfidgruppen, Sulfoxidgruppen, Phosphingruppen, Phosphoniumgruppen,
Phosphatgruppen, Cyangruppen, Nitrilgruppen, Mercaptogruppen, Nitrosogruppen, Halogenatomen,
Nitrogruppen, Sulfongruppen, Acylgruppen, Säureanhydridgruppen und Azidgruppen, worin
zwei oder mehr von R
1, R
2, R
3 und R
4 miteinander verbunden sein können, um einen Ring zu bilden; (Q) Materialien der allgemeinen
Formel:

worin R
1, R
2, R
3 und R
4 jeweils unabhängig voneinander ausgewählt sind aus der Gruppe bestehend aus Wasserstoffatomen,
Alkylgruppen, substituierten Alkylgruppen, Arylgruppen, substituierten Arylgruppen,
Arylalkylgruppen, substituierten Arylalkylgruppen, Hydroxygruppen, Amingruppen, Imingruppen,
Ammoniumgruppen, Pyridingruppen, Pyridiniumgruppen, Ethergruppen, Aldehydgruppen,
Ketongruppen, Estergruppen, Amidgruppen, Carbonsäuregruppen, Carbonylgruppen, Thiocarbonylgruppen,
Sulfatgruppen, Sulfonatgruppen, Sulfidgruppen, Sulfoxidgruppen, Phosphingruppen, Phosphoniumgruppen,
Phosphatgruppen, Cyangnuppen, Nitrilgruppen, Mercaptogruppen, Nitrosogruppen, Halogenatomen,
Nitrogruppen, Sulfongruppen, Acylgruppen, Säureanhydridgruppen und Azidgruppen, worin
zwei oder mehr von R
1, R
2, R
3 und R
4 miteinander verbunden sein können, um einen Ring zu bilden; (R) Materialien der allgemeinen
Formeln:

worin R
1 ausgewählt ist aus der Gruppe bestehend aus Wasserstoffatomen, Alkylgruppen, substituierten
Alkylgruppen, Arylgruppen, substituierten Arylgruppen, Arylalkylgruppen, substituierten
Arylalkylgruppen, Hydroxygruppen, Amingruppen, Imingruppen, Ammoniumgruppen, Pyridingruppen,
Pyridiniumgruppen, Ethergruppen, Aldehydgruppen, Ketongruppen, Estergruppen, Amidgruppen,
Carbonsäuregruppen, Carbonylgruppen, Thiocarbonylgruppen, Sulfatgruppen, Sulfonatgruppen,
Sulfidgruppen, Sulfoxidgruppen, Phosphingruppen, Phosphoniumgruppen, Phosphatgruppen,
Cyangruppen, Nitrilgruppen, Mercaptogruppen, Nitrosogruppen, Halogenatomen, Nitrogruppen,
Sulfongruppen, Acylgruppen, Säureanhydridgruppen und Azidgruppen, und worin der gekrümmte
Teil der Struktur eine Kohlenwasserstoffkette oder eine substituierte Kohlenwasserstoffkette
bedeutet, worin zwei oder mehr Substituenten miteinander verbunden sein können, um
einen Ring zu bilden; (S) Materialien der allgemeinen Formel:

worin R
1 ausgewählt ist aus der Gruppe bestehend aus Wasserstoffatomen, Alkylgruppen, substituierten
Alkylgruppen, Arylgruppen, substituierten Arylgruppen, Arylalkylgruppen, substituierten
Arylalkylgruppen, Hydroxygruppen, Amingruppen, Imingruppen, Ammoniumgruppen, Pyridingruppen,
Pyridiniumgruppen, Ethergruppen, Aldehydgruppen, Ketongruppen, Estergruppen, Amidgruppen,
Carbonsäuregruppen, Carbonylgruppen, Thiocarbonylgruppen, Sulfatgruppen, Sulfonatgruppen,
Sulfidgruppen, Sulfoxidgruppen, Phosphingruppen, Phosphoniumgruppen, Phosphatgruppen,
Cyangruppen, Nitrilgruppen, Mercaptogruppen, Nitrosogruppen, Halogenatomen, Nitrogruppen,
Sulfongruppen, Acylgruppen, Säureanhydridgruppen und Azidgruppen, und worin der gekrümmte
Teil der Struktur eine Kohlenwasserstoffkette oder eine substituierte Kohlenwasserstoffkette
bedeutet, worin zwei oder mehr Substituenten miteinander verbunden sein können, um
einen Ring zu bilden; und (T) Mischungen davon; oder worin das transparentmachende
Mittel ausgewählt ist aus der Gruppe bestehend aus (1) Homopiperidin, (2) Piperidinthiocyanat,
(3) 2-Piperidinmethanol, (4) 3-Piperidinmethanol, (5) 2-Piperidinethanol, (6) 4-Piperidinethanol,
(7) 4-Piperidin-Monohydrat-Hydrochlorid, (8) 1-Aminopiperidin, (9) 1-(2-Aminoethyl)piperidin,
(10) 4-(Aminomethyl)piperidin, (11) 3-Piperidino-1,2-propandiol, (12) 1-Piperidinpropionsäure,
(13) 1-Methyl-4-(methylamino)piperidin, (14) 1-Acetyl-3-methylpiperidin, (15) 4'-Piperidinoacetophenon,
(16) 4-Phenylpiperidin, (17) 4-Piperidinopiperidin, (18) 4-Benzylpiperidin, (19) 4-(4-Methylpiperidino)pyridin,
(20) 4-Piperidonethylenketal, (21) Bis(pentamethylen)harnstoff, (22) 1-Benzyl-4-hydroxypiperidin,
(23) 1-Benzoyl-4-piperidon, (24)1,1'-Methylenbis(3-methylpiperidin), (25) 4,4'-Trimethylendipiperidin,
(26) 4,4'-Trimethylenbis(1-menthylpiperidin), (27) 4,4'-Trimethylenbis(1-piperidinpropionitril),
(28) 4,4'-Trimethylenbis(1-piperidinethanol), (29) 2,2,6,6-Tetramethylpiperidin, (30)
4-Amino-2,2,6,6-tetramethylpiperidin, (31) 4-(Dimethylamino)-1,2,2,6,6-pentamethylpiperidin,
(32) N,N'-Bis(2,2,6,6-tetramethyl-4-piperidinyl)-1,6-hexandiamin, (33) Tripiperidinophosphinoxid,
(34) Tropan, (35) Tropinhydrat, (36) Tropinon, (37) 8-Hydroxytropinon, (38) 2-Piperidincarbonsäure,
(39) 2-Piperidon, (40) 4,4'-Trimethylenbis(1-piperidincarboxamid), (41) 4-Methyl-2-(piperidinomethyl)phenol,
(42) 1-Methyl-4-piperidinylbis(chlorphenoxy)acetat, (43) 2-(Hexamethylenimino)ethylchlorid-Monohydrochlorid,
(44) 3-(Hexahydro-1H-azepin-1-yl)-3'-nitropropiophenon-Hydrochlorid, (45) lmipramin-Hydrochlorid,
(46) Carbamezepin, (47) 5,6,11,12-Tetrahydrodibenz[b,f]azocin-Hydrochlorid, (48) Chinuclidin-Hydrochlorid,
(49) 3-Chinuclidinol-Hydrochlorid, (50) 3-Chinuclidinon-Hydrochlorid, (51) 2-Methylen-3-chinuclidinon-Dihydrat-Hydrochlorid,
(52) 3-Aminochinuclidin-Dihydrochlorid, (53) 3-Chlorchinuclidin-Hydrochlorid, (54)
Chinidinsulfat-Dihydrat, (55) Chinin-Monohydrochlorid-Dihydrat, (56) Chininsulfat-Monohydrat,
(57) Hydrochinidin-Hydrochlorid, (58) Hydrochinin-Hydrobromid-Dihydrat, (59) Piperazin,
(60) Homopiperazin, (61) 1-Methylpiperazin, (62) 2-Methylpiperazin, (63) 1-Acetylpiperazin,
(64) 1-(2-Hydroxyethyl)piperazin, (65) 1-(2-Aminoethyl)piperazin, (66) tert-Butyl-1-piperazincarboxylat,
(67) N-lsopropyl-1-piperazinacetamid, (68) 1-(2-Methoxyphenyl)piperazin, (69) 1-(2-Pyridyl)piperazin,
(70) 1-Benzylpiperazin, (71) 1-Cinnamylpiperazin, (72) 1-(4-Chlorbenzhydryl)piperazin,
(73) 2,6-Dimethylpiperazin, (74) 1-Amino-4-methylpiperazin, (75) 1-Amino-4-(2-hydroxyethyl)piperazin,
(76) 1,4-Bis(2-hydroxyethyl)piperazin, (77) 1,4-Bis(3-aminopropyl)piperazin, (78)
tert-Butyl-4-benzyl-1-piperazincarboxylat, (79) 1-Piperonylpiperazin, (80) Bis(4-methyl-1-homopiperazinylthiocarbonyl)disulfid,
(81) 1-Amino-4-methylpiperazin-Dihydrochlorid-Monohydrat, (82) 1-(3-Chlorpropyl)piperazin-Dihydrochlorid-Monohydrat,
(83) 1-(2,3-Xylyl)piperazin-Monohydrochlorid, (84) 1,1-Dimethyl-4-phenylpiperaziniumiodid,
(85) 1,4,7-Triazacyclononan, (86) 1,5,9-Triazacyclododecan, (87) 1,2,3-Triazol, (88)
4-Amino-1,2,4-triazol, (89) 3-Amino-5-methylthio-1H-1,2,4-triazol, (90) Benzotriazol,
(91) 1-Aminobenzotriazol, (92) 1-Cyanbenzotriazol, (93) 5-Methyl-1 H-benzotriazol,
(94) 1 H-Benzotriazol-1-ylmethylisocyanid, (95) 2-[3-(2H-Benzotriazol-2-yl)-4-hydroxyphenyl]
ethylmethacrylat, (96) 1,2,4-Triazol, (97) 1,2,4-Triazol-Natriumderivat, (98) 3-Amino-1,2,4-triazol,
(99) 3,5-Diamino-1,2,4-triazol, (100) 3-Amino-5-mercapto-1,2,4-triazol, (101) 3-Amino-1,2,4-triazol-5-carbonsäure-Hemihydrat,
(102) 4-Amino-3-hydrazino-5-mercapto-1,2,4-triazol, (103) 1,2,3-Triazol-4,5-dicarbonsäure-Monohydrat,
(104) Nitron, (105) 1-Hydroxybenzotriazol-Hydrat, (106) 1,3,5-Triazin, (107) Cyanursäure,
(108) Trithiocyanursäure, (109) 2,4-Bis(methylthio)-6-chlor-1,3,5-triazin, (110) 2-Chlor-4,6-dimethoxy-1,3,5-triazin,
(111) 2-Chlor-4,6-diamino-1,3,5-triazin, (112) Trichlormelamin, (113) Cyanurchlorid,
(114) 2,4,6-Tris(perfluorheptyl)-1,3,5-triazin, (115) Hexahydro-2,4,6-trimethyl-1,3,5-triazin-Trihydrat,
(116) 1,3,5-Trimethylhexahydro-1,3,5-triazin, (117) 1,3,5-Triethylhexahydro-1,3,5-triazin,
(118) 1,3,5-Triclohexylhexahydro-1,3,5-triazin, (119) 1,3,5-Tribenzylhexahydro-1,3,5-triazin,
(120) Trichlorisocyanursäure, (121) Tris(2,3-dibrompropylisocyanurat), (122) Cyanursäureverbindung
mit Melamin, (123) Urazol, (124) 1-Methylurazol, (125) 4-Phenylurazol, (126) 5-(4-Hydroxyphenyl)-5-phenylhydantoin,
(127) β-Tetralonhydantoin, (128) Cyclen (1,4,7,10-Tetraazacyclododecan), (129)1,4,8,11-Tetraazacyclotetradecan,
(130)1,4,8,11-Tetramethyl-1,4,8,11-tetraazacyclotetradecan, (131) 1,4,8,11-Tetraazacyclotetradecan-5,7-dion,
(132) 1,4,8,12-Tetraazacyclopentadecan, (133) 2,3,7,8,12,13,17,18-Octaethyl-21H,23H-porphin,
(134) Dimethyl-3,7,12,17-tetramethyl-21H,23H-porphin-2,18-dipropionat, (135) Dimethyl-7,12-diacetyl-3,8,13,17-tetramethyl-21
H,23H-porphin-2,18-dipropionat, (136) 8,3-Divinyl-3,7,12,17-tetramethyl-21 H,23H-porphin-2,18-dipropionsäure,
Dinatriumsalz, (137) 5,10,15,20-Tetraphenyl-21H,23H-porphin, (138) 5,10,15,20-Tetrakis(4-methoxyphenyl)-21H,23H-porphin,
(139) 5,10,15,20-Tetrakis[4-(trimethylamino)phenyl]-21H,23H-porphin, Tetra-p-tosylatsalz
, (140) 5,10,15,20-Tetra(4-pyridyl)-21H,23H-porphin, (141) 5,10,15,20-Tetrakis(1-methyl-4-pyridyl)-21H,23H-porphin,
Tetra-p-tosylatsalz, (142) 1,5-Pentamethylentetrazol, (143)1-H-Tetrazol, (144) 5-Aminotetrazol-Monohydrat,
(145) 2,3,5-Triphenyl-2H-tetrazoliumchlorid, (146) 2-(4-lodphenyl)-5-(4-nitrophenyl)-3-phenyltetrazoliumchlorid,
(147) 1,2,3,3-Tetramethyl-3H-indoliniumiodid, (148) Hexacyclentrisulfat, (149) Hexamethylhexacyclen,
(150) Pyrrol-2-carboxaldehyd, (151) Prolinamid, (152) 3-Pyrrolidino-1,2-propandiol,
(153) 1-(Pyrrolidinocarbonylmethyl)piperazin, (154) 4-Pyrrolidinopyridin, (155) 3-lndolylacetonitril,
(156) 6-Nitroindolin, (157) 7-Azaindol, (158) Indazol, (159) 2-Acetylpyrrol, (160)
2-Acetyl-1-methylpyrrol, (161) 3-Acetyl-1-methylpyrrol, (162) 3-Acetyl-2,4-dimethylpyrrol,
(163) Pyrrol-2-carbonsäure, (164) 3-Carboxy-1,4-dimethyl-2-pyrrolessigsäure, (165)
Prolin, (166) 2-Pyrrolidon-5-carbonsäure, (167) 4-Hydroxyprolin, (168) 1,1'-Ethylenbis(5-oxo-3-pyrrolidincarbonsäure),
(169) Kainsäure-Monohydrat, (170) 1-Aminopyrrolidin-Hydrochlorid, (171) 2-(2-Chlorethyl)-1-methylpyrrolidin-Hydrochlorid,
(172) 1-(2-Chlorethyl)pyrrolidin-Hydrochlorid, (173) Tremorin-Dihydrochlorid, (174)
L-Prolinmethylester-Hydrochlorid, (175) Ammoniumpyrrolidindithiocarbamat, (176) Pyrrolidon-Hydrotribromid,
(177) 1-(4-Chlorbenzyl)-2-(1-pyrrolidinylmethyl)benzimidazol-Hydrochlorid, (178) Billverdin-Dihydrochlorid,
(179) Indol, (180) 4,5,6,7-Tetrahydroindol, (181) 3-lndolmethanol-Hydrat, (182) 3-lndolethanol,
(183) Indol-3-carboxaldehyd, (184) 3-lndolylacetat, (185) Indol-3-acetamid, (186)
Indol-3-carbonsäure, (187) Indol-3-essigsäure, (188) 3-lndolpropionsäure, (189) 3-Indolacrylsäure,
(190) 3-lndolglyoxylsäure, (191) Indol-3-pyruvinsäure, (192) 3-Indolmilchsäure, (193)
3-Indolbuttersäure, (194) N-Acetyltryptophanamid, (195) N-(3-lndolylacetyl)alanin,
(196) N-(3-lndolylacetyl)valin, (197) N-(3-lndolylacetyl)isoleucin, (198) N-(3-lndolylacetyl)leucin,
(199) N-(3-lndolylacetyl)asparaginsäure, (200) N-(3-lndolylacetyl)-L-phenylalanin,
(201) 4-Hydroxyindol, (202) Indol-4-carbonsäure, (203) 4-lndolylacetat, (204) 4-Methylindol,
(205) 5-Hydroxyindol, (206) 5-Hydroxyindol-3-essigsäure, (207) 5-Hydroxy-2-indolcarbonsäure,
(208) N-Acetyl-5-hydroxytryptamin, (209) Indol-5-carbonsäure, (210) 5-Methylindol,
(211) 5-Methoxyindol, (212) Indol-2-carbonsäure, (213) lndolen-2-carbonsäure, (214)
Indol-2,3-dion, (215) 2-Methylindol, (216) 2,3,3-Trimethylindolenin, (217) Tryptamin-Hydrochlorid,
(218) 5-Methyltryptamin-Hydrochlorid, (219) Serotonin-Hydrochlorid-Hemihydrat, (220)
Norharman-Hydrochlorid-Monohydrat, (221) Harman-Hydrochlorid-Monohydrat, (222) Harmin-Hydrochlorid-Hydrat,
(223) Harmalin-Hydrochlorid-Dihydrat, (224) Harmol-Hydrochlorid-Dihydrat, (225) Harmalol-Hydrochlorid-Dihydrat,
(226) 3,6-Diaminoacridin-Hydrochlorid, (227) (3-lndolyl)isothiuroniumiodid, (228)
Yohimbin-Hydrochlorid, (229) Pyrazol, (230) 3-Aminopyrazol, (231) 5-Amino-1-ethylpyrazol,
(232) 3-Amino-4-carbethoxypyrazol, (233) 3-Amino-5-methylpyrazol, (234) 3-Amino-5-phenylpyrazol,
(235) Ethyl-4-pyrazolcarboxylat, (236) Diethyl-3,5-pyrazolcarboxylat, (237) 1,1'-(1-Ethylpropyliden)bis-1H-pyrazol,
(238) 4-Brompyrazol, (239) 4-Brom-3-methylpyrazol, (240) 3,5-Dimethylpyrazol, (241)
4-Brom-3,5-dimethylpyrazol, (242) 3,5-Dimethylpyrazol-1-carboxamid, (243) 3,5-Dimethylpyrazol-1-methanol,
(244) 3-Methyl-1-vinylpyrazol, (245) 4-Benzoyl-3-methyl-1-phenyl-2-pyrazolin-5-on,
(246) 1-Nitropyrazol, (247) 4-Pyrazolcarbonsäure, (248) 3,5-Pyrazoldicarbonsäure-Monohydrat,
(249) 3-Amino-5-hydroxypyrazol, (250) 3-Amino-4-pyrazolcarbonitril, (251) 3-Amino-4-pyrazolcarbonsäure,
(252) 4-Methylpyrazol-Hydrochlorid, (253) 3,4-Diamino-5-hydroxypyrazolsulfat, (254)
3,5-Dimethylpyrazol-1-carboxamidinnitrat, (255) 3-Amino-4-pyrazolcarboxamid-Hemisulfat,
(256) Säuresalz von 6-Aminoindazol-Hydrochlorid, (257) 4-Hydroxypyrazolo-[3,4-d]-pyrimidin,
(258) 4-Mercapto-1 H-pyrazolo-[3,4-d]-pyrimidin, (259) Indazol, (260) 5-Aminoindazol,
(261) 6-Aminoindazol, (262) 3-Indazolinon, (263) N'-(6-Indazolyl)sulfanilamid, (264)
4,5-Dihydro-3-(4-pyridinyl)-2H-benz[g]indazol-Methansulfonat, (265) Imidazol, (266)
4-Methylimidazol, (267) 2-Ethylimidazol, (268) 2-Propylimidazol, (269) 1-Butylimidazol,
(270) 2-Undecylimidazol, (271) Histamin, (272) 1-(3-Aminopropyl)imidazol, (273) 1-Acetylimidazol,
(274) 2-Methyl-1-vinylimidazol, (275) 2-Ethyl-4-methylimidazol, (276) 1-Benzyl-2-methylimidazol,
(277) 1-Methylbenzimidazol, (278) 1-Ethyl-3-methyl-1,H-imidazoliniumchlorid, (279)
2-(Aminomethyl)benzimidazol-Dihydrochlorid-Hydrat, (280) 2,6-Diamino-8-purinol-Hemisulfat-Monohydrat,
(281) Purin-6-yl-trimethylammoniumchlorid, (282) 4-Methyl-5-imidazolmethanol-Hydrochlorid,
(283) N,N'-Bis[3-(4,5-dihydro-1H-imidazol-2-yl)phenyl]harnstoffdipropanoat, (284)
1-(p-Tosyl)-3,4,4-trimethyl-2-imidazoliniumiodid, (285) 1-Ethyl-3-methyl-1 H-imidazoliniumchlorid,
(286) 2-Aminoimidazolsulfat, (287) 4-Amino-5-imidazolcarboxamid-Hydrochlorid, (288)
2-Hydrazino-2-imidazolin-Hydrobromid, (289) Imidazol-Hydrochlorid, (290) 4-lmidazolessigsäure-Hydrochlorid,
(291) 2-Benzyl-2-imidazolin-Hydrochlorid, (292) Propyl-1-(1-phenylethylimidazol-5-carboxylat-Hydrochlorid,
(293) 2,6-Diaminopurinsulfat-Hydrat, (294) 1-Talgamidoethyl-3-methyl-2-heptadecylimidazolinium-Methylsulfat,
(295) Isostearylethylimidonium-Ethylsulfat, (296) Methyl-(1)-talgamidoethyl-2-talgimidazolinium-Methylsulfat,
(297) Isostearylbenzylimidoniumchlorid, (298) Methyl-(1)-hydriertes Talgamidoethyl,
(299) hydriertes Talgimidazolinium-Methylsulfat, (300) 1-Methyl-1-oleylamidoethyl-2-oleylimidazolinium-Methylsulfat,
(301) Kokoshydroxyethylpolyethylenglycolimidazoliniumchloridphosphat, (302) Guanin,
(303) Guanosin-Hydrat, (304) Xanthin, (305) 1-Methylxanthin, (306) 3-Methylxanthin,
(307) 3-lsobutyl-1-methylxanthin, (308) Hypoxanthin, (309) Xanthosin-Dihydrat, (310)
6-Thioxanthen, (311) Purin, (312) 6-Aminopurin, (313) 6-Methoxypurin-Hemihydrat, (314)
6-Mercaptopurin-Monohydrat, (315) 2-Amino-6-chlorpurin, (316) 2-Amino-6,8-dihydroxypurin,
(317) Theophyllin (3,7-Dihydro-1,3-dimethyl-1H-purin-2,6-dion), (318) Kinetin (6-Furfurylaminopurin),
(319) 1-Methyladenin, (320) 3-Methyladenin, (321) Adenosin, (322) Inosin, (323) 6-Mercaptopurinribosid,
(324) 6-Aminopurin-Hydrochlorid-Hemihydrat, (325) 6-Aminopurinsulfat, (326) 2,6-Diamino-8-purinol-Hemisulfat-Monohydrat,
(327) Benzimidazol, (328) 2-Aminobenzimidazol, (329) 2-Amino-5,6-dimethylbenzimidazol,
(330) 5-Benzimidazolcarbonsäure, (331) 2,4,5-Trimethylbenzimidazol, (332) 2-Guanidinobenzimidazol,
(333) 2-Hydroxybenzimidazol, (334) 4-(2-Keto-1-benzimidazolinyl)piperidin, (335) 2-lmidazolidinthion,
(336) 2-lmidazolidon, (337) Hydantoin, (338) 1-Methylhydantoin, (339) Kreatinin, (340)
2-Thiohydrantoin, (341) 5-Hydantoinessigsäure, (342) 5-Ureidohydantoin, (343) 5,5-Dimethylhydantoin,
(344) 2-lmidazolidon-4-carbonsäure, (345) N,N-Bis(2-hydroxyethyl)isonicotinamid, (346)
1,2-Bis(4-pyridyl)ethylen, (347) 2-(2-Piperidinoethyl)pyridin, (348) 1,2-Bis(4-pyridyl)ethan,
(349) 4,4'-Trimethylenpyridin, (350) Aldrithiol-2, (351) Aldrithiol-4, (352) 1,3-Bis(3-pyridylmethyl)-2-thioharnstoff,
(353) 2,2':6',2"-Terpyridin, (354) 2-[N,N-Bis(trifluormethylsulfonyl)amino]pyridin,
(355) 2,3-Pyridindicarbonsäure, (356) 2,4-Pyridindicarbonsäure-Monohydrat, (357) 2,5-Pyridindicarbonsäure,
(358) 2,6-Pyridindicarbonsäure, (359) 3,4-Pyridindicarbonsäure, (360) 3,5-Pyridindicarbonsäure,
(361) 2,6-Pyridindicarboxaldehyd, (362) 3,4-Pyridincarboxamid, (363) 3,4-Pyridincarboximid,
(364) 2,3-Pyridincarbonsäureanhydrid, (365) 3,4-Pyridincarbonsäureanhydrid, (366)
2,6-Pyridinmethanol, (367) 2-Pyridinethansulfonsäure, (368) 4-Pyridinethansulfonsäure,
(369) 3-Pyridinsulfonsäure, (370) Pyridoxsäure, (371) trans-3-(3-Pyridyl)acrylsäure,
(372) 2-Pyridylhydroxymethansulfonsäure, (373) 3-Pyridylhydroxymethansulfonsäure,
(374) 6-Methyl-2,3-pyridindicarbonsäure, (375) Isonicotinsäure, (376) Pyridin-Hydrobromid,
(377) Pyridin-Hydrochlorid, (378) 2-(Chlormethyl)pyridin-Hydrochlorid, (379) 2-PyridylessigsäureHydrochlorid,
(380) Nicotinoylchlorid-Hydrochlorid, (381) 2-Hydrazinopyridin-Dihydrochlorid, (382)
2-(2-Methylaminoethyl)pyridin-Dihydrochlorid, (383) 1-Methyl-1,2,3,6-tetrahydropyridin-Hydrochlorid,
(384) 2,6-Dihydroxypyridin-Hydrochlorid, (385) 3-Hydroxy-2-(hydroxymethyl)pyridin-Hydrochlorid,
(386) Pyridoxin-Hydrochlorid, (387) Pyridoxal-Hydrochlorid, (388) Pyridoxal-5-phosphat-Monohydrat,
(389) 3-Amino-2,6-dimethoxypyridin-Hydrochlorid, (390) Pyridoxamin-Dihydrochlorid-Monohydrat,
(391) Iproniazidphosphat, (392) Tripelennamin-Hydrochlorid, (393) Pyridiniumbromidperbromid,
(394) Pyridinium-3-nitrobenzolsulfonat, (395) 1-Ethyl-3-hydroxypyridiniumbromid, (396)
1-Ethyl-4-(methoxycarbonyl)pyridiniumiodid, (397) 1-Heptyl-4-(4-pyridyl)pyridiniumbromid,
(398) 1-Dodecylpyridiniumchlorid, (399) 1-Hexadecylpyridiniumchlorid-Monohydrat, (400)
1-Hexadecylpyridiniumbromid-Monohydrat, (401) 1-(Carboxymethyl)pyridiniumchlorid,
(402) 1-(Carboxymethyl)pyridiniumchloridhydrazid, (403) 1-(3-Nitrobenzyloxymethyl)pyridiniumchlorid,
(404) 1-(3-Sulfopropyl)pyridiniumhydroxid, (405) N-(Lauroylcolaminoformylmethyl)pyridiniumchlorid,
(406) N-(Stearoylcolaminformylmethyl)pyridiniumchlorid, (407) 2-Chlor-1-methylpyridiniumiodid,
(408) 2-Pyridinaldoxim-1-methylmethansulfonat, 2-Pyridinaldoxim-1-methylchlorid, (409)
2-[4-(Dimethylamino)styryl]-1-ethylpyridiniumiodid, (410) 1-Benzyl-3-hydroxypyridiniumchlorid,
(411) 1,4-Dimethylpyridiniumiodid, (412) 1-Ethyl-4-phenylpyridiniumiodid, (413) 4-Phenyl-1-propylpyridiniumiodid,
(414) 1-Docosyl-4-(4-hydroxystyryl)pyridiniumbromid, (415) 1,1'-Dimethyl-4-4'-bipyridiniumdichlorid,
(416)1,1'-Diethyl-4-4'-bipyridiniumdibromid, (417) 1,1'-Dibenzyl-4,4'-bipyridiniumdichlorid,
(418) 1,1'-Diheptyl-4,4'-bipyridiniumdibromid, (419) 1,7-Phenanthrolin, (420) 1,10-Phenanthrolin,
(421) 5-Chlor-1,10-phenanthrolin, (422) 4,5-Dihydro-3-(4-pyridinyl)-2H-benz[g]indazol-Methansulfonat,
(423) 1,2,3,4-Tetrahydrochinolin, (424) 6-Ethoxy-1,2,3,4-tetrahydro-2,2,4-trimethylchinolin,
(425) 2-Cyanchinolin, (426) 1-Cyanisochinolin, (427) 3-Cyanisochinolin, (428) 3-Aminochinolin,
(429) 8-Aminochinolin, (430) 7,8-Benzochinolin, (431) 8-Hydroxychinolin, (432) 8-Hydroxychinolin-Aluminiumsalz,
(433) 8-Hydroxychinaldin, (434) 3,4,5,6,7,8-Hexahydro-2-(1H)-chinolinon, (435) Julolidin,
(436) Chinoxalin, (437) Ethyl-2-chinoxalincarboxylat, (438) Chinolin, (439) 2-Hydroxychinolin,
(440) 4-Hydroxychinolin, (441) 5-Hydroxychinolin, (442) 5-Aminochinolin, (443) 6-Aminochinolin,
(444) 2-Chinolincarbonsäure, (445) 3-Chinolincarbonsäure, (446) 4-Chinolincarbonsäure,
(447) 4-Chinolincarboxaldehyd, (448) 2-Chinolinthiol, (449) 2,4-Chinolindiol, (450)
Chinaldin, (451) 4-Aminochinaldin, (452) 2,6-Dimethylchinolin, (453) 2,7-Dimethylchinolin,
(454) 4-Methoxy-2-chinolincarbonsäure, (455) Methyl-2-phenyl-4-chinolincarboxylat,
(456) 2-(N-Butylcarbamoyl)-1,2,3,4-tetrahydroisochinolin, (457) 1-Hydroxyisochinolin,
(458) 1-lsochinolincarbonsäure, (459) 3-lsochinolincarbonsäure, (460) 1,5-lsochinolindiol,
(461) 8-Hydroxychinolin-Hemisulfat-Hemihydrat, (462) 5-Amino-8-hydroxychinolin-Dihydrochlorid,
(463) 2-(Chlormethyl)chinolin-Monohydrochlorid, (464) 8-Hydroxychinolin-5-sulfonsäure-Monohydrat,
(465) 8-Ethoxy-5-chinolinsulfonsäure-Natriumsalz-Hydrat. (466) 1,2,3,4-Tetrahydroisochinolin-Hydrochlorid,
(467) 1,2,3,4-Tetrahydro-3-isochinolincarbonsäure-Hydrochlorid, (468) 6,7-Dimethoxy-1,2,3,4-tetrahydroisochinolin-Hydrochlorid,
(469) 1-Methyl-6,7-dihydroxy-1,2,3,4-tetrahydroisochinolin-Hydrobromid, (470) Primachindiphosphat,
(471) Pentachinphosphat, (472) Dibucain-Hydrochlorid, (473) 9-Aminoacridin-Hydrochlorid-Hemihydrat,
(474) 3,6-Diaminoacridin-Hemisulfat, (475) 2-Chinolinthiol-Hydrochlorid, (476) Sparteinsulfat-Pentahydrat,
(477) Papaverin-Hydrochlorid, (478) Emetin-Dihydrochlorid-Hydrat, (479) 1,10-Phenanthrolin-Monohydrochlorid-Monohydrat,
(480) Neocuproin-Hydrochlorid-Trihydrat, (481) Pyrimidin, (482) 2-Chlorpyrimidin,
(483) 4-Phenylpyrimidin, (484) 5-Brompyrimidin, (485) 2,4-Dichlorpyrimidin, (486)
4,6-Dichlorpyrimidin, (487) 2,4-Dichlor-6-methylpyrimidin, (488) 6-Chlor-2,4-dimethoxypyrimidin,
(489) 2-Amino-4,6-dimethoxypyrimidin, (490) 2,4,6-Trichlorpyrimidin, (491) 2,4,5,6-Tetrachlorpyrimidin,
(492) 1,3,4,6,7,8-Hexahydro-1-methyl-2H-pyrimido-[1,2-a]-pyrimidin, (493) 1,3,4,6,7,8-Hexahydro-2H-pyrimido-[1,2-a]-pyrimidin,
(494) Hexetidin, (495) tert-Butyl-S-(4,6-dimethylpyrimidin-2-yl)thiocarbonat, (496)
4-MethoxybenzylS(4,6-dimethylpyrimidin-2-yl)thiocarbonat, (497) 2-Aminopyrimidin,
(498) 2-Amino-4-methylpyrimidin, (499) 2-Amino-5-nitropyrimidin, (500) 2-Amino-5-brompyrimidin,
(501) 2-Amino-4-chlor-6-methylpyrimidin, (502) 2-Amino-4,6-dimethylpyrimidin, (503)
2-Amino-4-hydroxy-6-methylpyrimidin, (504) 2-Amino-4,6-dichlorpyrimidin, (505) 2-Amino-5-brom-6-methyl-4-pyrimidinol,
(506) 4-Aminopyrimidin, (507) 4,5-Diaminopyrimidin, (508) 4-Amino-2,6-dimethylpyrimidin,
(509) 2,4-Diamino-6-hydroxypyrimidin, (510) 2,6-Diamino-4-chlorpyrimidin, (511) 4,6-Diamino-2-mercaptopyrimidin-Hemihydrat,
(512) 2,4,6-Triaminopyrimidin, (513) 5-Nitroso-2,4,6-triaminopyrimidin, (514) 4,6-Dihydroxypyrimidin,
(515) 4,6-Dihydroxy-2-aminopyrimidin, (516) 4,6-Dihydroxy-2-methylpyrimidin, (517)
4,6-Dihydroxy-5-nitropyrimidin, (518) 2,4-Dihydroxy-5-methylpyrimidin, (519) 2,4-Dihydroxy-6-methylpyridimin,
(520) 2,4-Dihydroxy-5,6-dimethylpyrimidin, (521) 2,6-Dihydroxypyrimidin-5-carbonsäure-Hydrat,
(522) 2,6-Dihydroxy-4-aminopyrimidin, (523) 2,4,5-Trihydroxypyrimidin, (524) 2-Thiouracil,
(525) 6-Amino-5-nitroso-2-thiouracil, (526) Folsäure-Dihydrat, (527) Folinsäure-Calciumsalz-Hydrat,
(528) 2-Hydroxypyrimidin-Hydrochlorid, (529) 2-Hydroxy-4-methylpyrimidin-Hydrochlorid,
(530) 4,6-Dimethyl-2-hydroxypyrimidin-Hydrochlorid, (531) 2-Mercapto-4-methylpyrimidin-Hydrochlorid,
(532) 4,6-Diaminopyrimidin-Hemisulfat-Monohydrat, (533) 4,5,6-Triaminopyrimidinsulfat-Hydrat,
(534) 4,5-Diamino-6-hydroxypyrimidinsulfat, (535) 2,4-Diamino-6-mercaptopyrimidin-Hemisulfat,
(536) 2,4-Diamino-6-hydroxypyrimidin-Hemisulfat-Hydrat, (537) 6-Hydroxy-2,4,5-triaminopyrimidinsulfat,
(538) 5,6-Diamino-2,4-dihydroxypyrimidinsulfat, (539) N4-(2-Amino-4-pyrimidinyl)sulfanilamid-Monohydrochlorid,
(540) 2,4,5,6-Tetraaminopyrimidinsulfat, (541) 2,4-(1H,3H)-Pyrimidindion, (542) 5-Aminouracil,
(543) 5-Nitrouracil, (544) 5-loduracil, (545) 5-(Hydroxymethyl)uracil-Hydrat, (546)
5,6-Dihydrouracil, (547) 6-Amino-1-methyluracil, (548) 5,6-Diamino-1,3-dimethyluracil-Hydrat,
(549) Uridin, (550) 5-Methyluridin, (551) 5-loduridin, (552) Thimidin, (553) 5-Methyl-2-thiouracil,
(554) 4-Thiouridin, (555) 2-Thiocytidin-Dihydrat, (556) Orotsäure-Monohydrat, (557)
Hydroorotsäure, (558) 5-Aminoorotsäure, (559) Methylorotat (560) Barbitursäure, (561)
5-Nitrobarbitursäure-Trihydrat, (562) Violursäure-Monohydrat, (563) Alloxan-Monohydrat,
(564) 4,5,6-Triamino-2(1H)-pyrimidinthionsulfat, (565) Cyclocytidin-Hydrochlorid,
(566) Cytosinarabinosid-Hydrochlorid, (567) Pyridazin, (568) Phthalazin, (569) 4,5-Dihydro-6-methyl-3(2H)-pyridazinon-Monohydrat,
(570) 3,6-Dichlorpyridazin, (571) 3,4,5-Trichlorpyridazin, (572) 3,6-Dichlor-4-methylpyridazin,
(573) 3-Chlor-6-methoxypyridazin, (574) Pyrazin, (575) Acetylpyrazin, (576) Aminopyrazin,
(577) 2,6-Dichlorpyrazin, (578) 2,3,5-Trimethylpyrazin, (579) Tetramethylpyrazin,
(580) 5-Methyl-2-pyrazincarbonsäure, (581) Pyrazinamid, (582) 2,3-Pyrazindicarboxamid,
(583) 4-Pyridazincarbonsäure, (584) 2,3-Pyrazindicarbonsäure, (585) Lumazin-Monohydrat,
(586) Xanthopterin-Monohydrat, (587) 2-Chinoxazolincarbonsäure, (588) 2-Chinoxalinol,
(589) 2,3-Dihydroxychinoxalin, (590) Phenazinmethosulfat, (591) 2-Azetidinon, (592)
2-Pyrrolidinon, (593) Pyrrolidon-Hydrotribromid, (594) δ-Valerolactam, (595) ε-Caprolactam,
(596) Amino-ε-caprolactam, (597) N-Methylcaprolactam, (598) 2-Azacyclooctanon, (599)
2-Azacyclononanon, (600) ω-Thiocaprolactam, (601) N-Vinylcaprolactam, (602) 2-Azabicyclo[2.2.1]hept-5-en-3-on,
(603) Maleimid, (604) N-Ethylmaleimid, (605) N-Butylmaleimid, (606) N-Cyclohexylmaleimid,
(607) N-Phenylmaleimid, (608) N-Benzylmaleimid, (609) N-Hydroxymaleimid, (610) Succinimid,
(611) N-Methylsuccinimid, (612) 2-Hydroxy-N-methylsuccinimid, (613) N-Hydroxysuccinimid,
(614) Succinimidyl-2,2,2-trichlorethylcarbonat, (615) 2-Dodecyl-N-(2,2,6,6-tetramethyl-4-piperidinyl)succinimid,
(616) 2-Dodecy-N-(1,2,2,6,6-pentamethyl-4-piperidinyl)succinimid, (617) N-(1-Acetyl-2,2,6,6-tetramethyl-4-piperidinyl)-2-dodecylsuccinimid,
(618) α-Methyl-α-propylsuccinimid, (619) α-Methyl-α-phenylsuccinimid, (620) N-Vinylphthalimid,
(621) N-Ethylphthalimid, (622) N-(Trimethylsilylmethyl)phthalimid, (623) N-(2-Bromethyl)phthalimid,
(624) N-(3-Brompropyl)phthalimid, (625) N-(4-Brombutyl)phthalimid, (626) Phthalimidoacetaldehyddiethylacetal,
(627) Diethyl(phthalimidomethyl)phosphonat, (628) N-Benzylphthalimid, (629) Phthalimid,
DBU (1,8-Diazabicyclo[5.4.0]undec-7-en)-Salz, (630) Phthalimid, DBN (1,5-Diazabicyclo[4.3.0]non-5-en),
und (631) Mischungen davon; oder worin das transparentmachende Mittel eine Oxaaza-cyclische
Verbindung ist, oder worin das transparentmachende Mittel ausgewählt ist aus der Gruppe
bestehend aus: (A) Materialien der allgemeinen Formeln:

worin R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
14 und R
15 jeweils unabhängig voneinander ausgewählt sind aus der Gruppe bestehend aus Wasserstoffatomen,
Alkylgruppen, substituierten Alkylgruppen, Arylgruppen, substituierten Arylgruppen,
Arylalkylgruppen, substituierten Arylalkylgruppen, Hydroxygruppen, Amingruppen, Imingruppen,
Ammoniumgruppen, Pyridingruppen, Pyridiniumgruppen, Ethergruppen, Aldehydgruppen,
Ketongruppen, Estergruppen, Amidgruppen, Carbonsäuregruppen, Carbonylgruppen, Thiocarbonylgruppen,
Sulfatgruppen, Sulfonatgruppen, Sulfidgruppen, Sulfoxidgruppen, Phosphingruppen, Phosphoniumgruppen,
Phosphatgruppen, Cyangruppen, Nitrilgruppen, Mercaptogruppen, Nitrosogruppen, Halogenatomen,
Nitrogruppen, Sulfongruppen, Acylgruppen, Säureanhydridgruppen und Azidgruppen, worin
zwei oder mehr von R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
14 und R
15 miteinander verbunden sein können, um einen Ring zu bilden; (B) Materialien der allgemeinen
Formel:

worin R
1, R
2, R
2, R
4, R
5, R
6, R
7, R
8 und R
9 jeweils unabhängig voneinander ausgewählt sind aus der Gruppe bestehend aus Wasserstoffatomen,
Alkylgruppen, substituierten Alkylgruppen, Arylgruppen, substituierten Arylgruppen,
Arylalkylgruppen, substituierten Arylalkylgruppen, Hydroxygruppen, Amingruppen, Imingruppen,
Ammoniumgruppen, Pyridingruppen, Pyridiniumgruppen, Ethergruppen, Aldehydgruppen,
Ketongruppen, Estergruppen, Amidgruppen, Carbonsäuregruppen, Carbonylgruppen, Thiocarbonylgruppen,
Sulfatgruppen, Sulfonatgruppen, Sulfidgruppen, Sulfoxidgruppen, Phosphingruppen, Phosphoniumgruppen,
Phosphatgruppen, Cyangruppen, Nitrilgruppen, Mercaptogruppen, Nitrosogruppen, Halogenatomen,
Nitrogruppen, Sulfongruppen, Acylgruppen, Säureanhydridgruppen und Azidgruppen, worin
zwei oder mehr von R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8 und R
9 miteinander verbunden sein können, um einen Ring zu bilden; (C) Mischungen davon;
oder worin das transparentmachende Mittel ausgewählt ist aus der Gruppe bestehend
aus (1) 3-Amino-5-methylisoxazol, (2) 5-Amino-3-methylisoxazol, (3) 3,5-Dimethyl-4-nitroisoxazol,
(4) 1,2-Benzisoxazol, (5) 2,1-Benzisoxazol, (6) Cycloserin, (7) 4-Benzyl-2-methyl-2-oxazolin,
(8) 2-Methyl-5-phenyl-2-oxazolin-4-methanol, (9) Benzoxazol, (10) 2-Methylbenzoxazol,
(11) 2-Chlorbenzoxazol, (12) 2-Chlor-3-ethylbenzoloxazoliumtetrafluorborat, (13) 2-Oxazolidon,
(14) 3-Methyl-2-oxazolidinon, (15) 5-Chlormethyl-2-oxazolidinon, (16) 4-lsopropyl-2-oxazolidinon,
(17) 3-Acetyl-2-oxazolidinon, (18) 5,5-Dimethyloxazolidin-2,4-dion, (19) 3-Ethyl-2-thioxo-4-oxazolidinon,
(20) 4-Methyl-5-phenyl-2-oxazolidinon, (21) 4-Benzyl-2-oxazolidinon, (22) 2-Benzoisoxazolinon,
(23) Muscimol-Hydrat, (24) 5-Methyl-3-phenylisoxazol-4-carbonsäure, (25) 2-Methyl-5-phenyl-2-oxazolin-4-methanol,
(26) Sulfamethoxazol, (27) Sulfisoxazol, (28) N'-(4,5-Dimethyloxazol-2-yl)sulfanilamid,
(29) Cloroxazon, (30) 3,3'-Dimethyloxacarbocyaniniodid, (31) 2-Ethyl-5-phenylisoxazolium-3'-sulfonat,
(32) 2-tert-Butyl-5-methylisoxazoliumperchlorat, (33) 5-Phenyl-2-(4-pyridyl)oxazol-Hydrochlorid-Hydrat,
(34) 5-Phenyl-2-(4-pyridyl)oxazolmethyl-Tosylatsalz, (35) 4-Aminomorpholin, (36) 4-Morpholincarbonitril,
(37) 4-Morpholinpropionitril, (38) 4-Formylmorpholin, (39) 4-Acetylmorpholin, (40)
4-(2-Hydroxyethyl)morpholin, (41) 3-Morpholino-1,2-propandiol, (42) 4-(3-Aminopropyl)morpholin,
(43) 1-Morpholino-1-cyclopenten, (44) 1-Morpholino-1-cyclohexen, (45) 1-Morpholino-1-cyclohepten,
(46) 4-Phenylmorpholin, (47) 4-Morpholinoanilin, (48) 2,2,2-Tribromethylphosphoromorpholinochloridat,
(49) 1-(Morpholinocarbonylmethyl)piperazin, (50) 1,3-Dimorpholin-2-nitropropan, (51)
Hemicholinium-3, (52) Hemicholinium-15, (53) 2-Methoxy-4-morpholinobenzoldiazoniumchlorid,
Zinkchlorid, (54) Fomocain, (55) 4-Morpholinobenzophenon, (56) 4,4'-Ethylen-bis(2,6-morpholindion),
(57) N,N'-Dicyclohexyl-4-morpholincarboxamidin, (58) Cyclohexyl-3-(2-morpholinoethyl)-2-thioharnstoff,
(59) 4-Morpholinoacetophenon, (60) 4-(2-Chlorethyl)morpholin-Hydrochlorid, (61) 4-Morpholinethansulfonsäure,
(62) 4-Morpholinpropansulfonsäure, (63) β-Hydroxymorpholinpropansufonsäure, (64) [N-(Aminoiminomethyl)-4-morpholincarboximidamid]-Hydrochlorid,
(65) 4-Morpholincarbodithionsäureverbindung mit Morpholin, (66) 2,5-Dimethyl-4-(morpholinomethyl)phenol-Hydrochlorid-Monohydrat,
(67) 1-Cyclohexyl-3-(2-morpholinoethyl)carbodiimidmetho-p-toluolsulfonat, (68) Hemicholinium-3[2,2'-(4,4'-biphenylen)bis(2-hydroxy-4,4-dimethylmorpholiniumbromid),
(69) Hemicholinium-15[4,4-dimethyl-2-hydroxy-2-phenylmorpholiniumbromid], (70) 1-Aza-12-krone-4,
(71) 1-Aza-15-krone-5, (72) 1-Aza-18-krone-6, (73) 1,4,10-Trioxa-7,13-diazacyclopentadecan,
(74) 1,4,10,13-Tetraoxa-7,16-diazacyclooctadecan, (75) N,N'-Dibenzyl-1,4,10,13-tetraoxa-7,16-diazacyclioctadecan,
(76) 4,7,13,18-Tetraoxa-1,10-diazabicyclo[8.5.5]eicosan, (77) 4,7,13,16,21-Pentaoxa-1,10-diazabicyclo[8.5.5]tricosan,
(78) 4,7,13,16,21,24-Hexaoxa-1,10-diazabicyclo[8.8.8]hexacosan, (79) 5,6-Benzo-4,17,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosan
und (80) Mischungen davon; oder worin das transparentmachende Mittel eine Oxacyclische
Verbindung ist; oder worin das transparentmachende Mittel ausgewählt ist aus der Gruppe
bestehend aus: (A) Materialien der allgemeinen Formel:

worin der gekrümmte Teil der Struktur eine Kohlenwasserstoffkette oder eine substituierte
Kohlenwasserstoffkette bedeutet, worin zwei oder mehr Substituenten miteinander verbunden
sein können, um einen Ring zu bilden; (B) Materialien der allgemeinen Formeln:

worin R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
14, R
15, R
16, R
17, R
18, R
19, R
20, R
21 R
22, R
23, R
24, R
25, R
26, R
27 und R
28 jeweils unabhängig voneinander ausgewählt sind aus der Gruppe bestehend aus Wasserstoffatomen,
Alkylgruppen, substituierten Alkylgruppen, Arylgruppen, substituierten Arylgruppen,
Arylalkylgruppen, substituierten Arylalkylgruppen, Hydroxygruppen, Amingruppen, Imingruppen,
Ammoniumgruppen, Pyridingruppen, Pyridiniumgruppen, Ethergruppen, Aldehydgruppen,
Ketongruppen, Estergruppen, Amidgruppen, Carbonsäuregruppen, Carbonylgruppen, Thiocarbonylgruppen,
Sulfatgruppen, Sulfonatgruppen, Sulfidgruppen, Sulfoxidgruppen, Phosphingruppen, Phosphoniumgruppen,
Phosphatgruppen, Cyangruppen, Nitrilgruppen, Mercaptogruppen, Nitrosogruppen, Halogenatomen,
Nitrogruppen, Sulfongruppen, Acylgruppen, Säureanhydridgruppen und Azidgruppen, worin
zwei oder mehr von R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
14, R
15, R
16, R
17, R
18, R
19, R
20, R
21, R
22, R
23, R
24, R
25, R
26, R
27 und R
28 miteinander verbunden sein können, um einen Ring zu bilden; (C) Materialien der allgemeinen
Formel:

worin der gekrümmte Teil der Struktur eine Kohlenwasserstoffkette oder eine substituierte
Kohlenwasserstoffkette bedeutet, worin zwei oder mehr Substituenten miteinander verbunden
sein können, um einen Ring zu bilden; (D) Materialien der allgemeinen Formeln:

worin R
1, R
2, R
3, R
4, R
5, R
6, R
7 und R
8 jeweils unabhängig voneinander ausgewählt sind aus der Gruppe bestehend aus Wasserstoffatomen,
Alkylgruppen, substituierten Alkylgruppen, Arylgruppen, substituierten Arylgruppen,
Arylalkylgruppen, substituierten Arylalkylgruppen, Hydroxygruppen, Amingruppen, Imingruppen,
Ammoniumgruppen, Pyridingruppen, Pyridiniumgruppen, Ethergruppen, Aldehydgruppen,
Ketongruppen, Estergruppen, Amidgruppen, Carbonsäuregruppen, Carbonylgruppen, Thiocarbonylgruppen,
Sulfatgruppen, Sulfonatgruppen, Sulfidgruppen, Sulfoxidgruppen, Phosphingruppen, Phosphoniumgruppen,
Phosphatgruppen, Cyangruppen, Nitrilgruppen, Mercaptogruppen, Nitrosogruppen, Halogenatomen,
Nitrogruppen, Sulfongruppen, Acylgruppen, Säureanhydridgruppen und Azidgruppen, worin
zwei oder mehr von R
1, R
2, R
3, R
4, R
5, R
6, R
7 und R
8 miteinander verbunden sein können, um einen Ring zu bilden; (E) Materialien der allgemeinen
Formeln:

worin die gekrümmten Teile der Strukturen eine Kohlenwasserstoffkette oder eine substituierte
Kohlenwasserstoffkette bedeuten, worin zwei oder mehr Substituenten miteinander verbunden
sein können, um einen Ring zu bilden; (F) Materialien der allgemeinen Formel:

worin R
1, R
2, R
3, R
4, R
5 und R
6 jeweils unabhängig voneinander ausgewählt sind aus der Gruppe bestehend aus Wasserstoffatomen,
Alkylgruppen, substituierten Alkylgruppen, Arylgruppen, substituierten Arylgruppen,
Arylalkylgruppen, substituierten Arylalkylgruppen, Hydroxygruppen, Amingruppen, Imingruppen,
Ammoniumgruppen, Pyridingruppen, Pyridiniumgruppen, Ethergruppen, Aldehydgruppen,
Ketongruppen, Estergruppen, Amidgruppen, Carbonsäuregruppen, Carbonylgruppen, Thiocarbonylgruppen,
Sulfatgruppen, Sulfonatgruppen, Sulfidgruppen, Sulfoxidgruppen, Phosphingruppen, Phosphoniumgruppen,
Phosphatgruppen, Cyangruppen, Nitrilgruppen, Mercaptogruppen, Nitrosogruppen, Halogenatomen,
Nitrogruppen, Sulfongruppen, Acylgruppen, Säureanhydridgruppen und Azidgruppen, worin
zwei oder mehr von R
1, R
2, R
3, R
4, R
5 und R
6 miteinander verbunden sein können, um einen Ring zu bilden; und (G) Mischungen davon;
oder worin das transparentmachende Mittel ausgewählt ist aus der Gruppe bestehend
aus (1) γ-Butyrolacton, (2) γ-Valerolacton, (3) γ-Caprolacton, (4) γ-Octanlacton,
(5) γ-Nonanlacton, (6) γ-Decanolacton, (7) Undecan-γ-lacton, (8) γ-Phenyl-γ-butyrolacton,
(9) α-Carbethoxy-γ-phenylbutyrolacton, (10) 2-Cumaranon, (11) β,β-Dimethyl-γ-(hydroxymethyl)-γ-butyrolacton,
(12) γ-Ethoxycarbonyl-γ-butyrolacton, (13) 5-(Hydroxymethyl)-2(5H)-furanon, (14) Dihydro-4-4-dimethyl-2,3-furandion,
(15) 2,5-Dimethyl-4-hydroxy-3(2H)-furanon, (16) Mevalon-(β-hydroxy-β-methyl-δ-valero)-lacton,
(17) δ-Decanolacton, (18) Undecan-δ-lacton, (19) δ-Dodecanolacton, (20) Undecan-ω-lacton,
(21) Oxacyclotridecan-2-on, (22) ω-Pentadecalacton, (23) Hydrindantin (2,2'-Dihydroxy-2,2'-biindan-1,1'3,3'-tetron,
(24) Hydrindantin-Dihydrat, (25) 2-Oxepanon, (26) 4H-Pyran-2-on, (27) Methylcumalat,
(28) Methyl-2-oxo-2H-pyran-3-carboxylat, (29) 4,6-Dimethyl-α-pyron, (30) 4-Methoxy-6-methyl-2H-pyran-2-on,
(31) 3,6-Dihydro-4,6,6-trimethyl-2H-pyran-2-on, (32) 3,4-Dihydro-6-methyl-2H-pyran-2-on,
(33) 3-Acetylcumarin, (34) 6-Methylcumarin, (35) 7-Ethoxycumarin, (36) Ethyl-3-cumarincarboxylat,
(37) 7-Diethylamino-4-methylcumarin, (38) Dihydrocumarin, (39) 3-Brom-2-cumaranon,
(40) Patulin, (41) 4H-Pyran-4-on, (42) 2-Ethyl-3-hydroxy-4H-pyran-4-on, (43) Butopyronoxyl(butyl-3,4-dihydro-2,2-dimethyl-4-oxo-2H-pyran-6-carboxylat,
(44) Dehydroessigsäure, (45) 4-Chromon, (46) 4-Chromanon, (47) 4-Chromanol, (48) 6,7-Dimethoxy-2,2-dimethyl-4-chromanon,
(49) 3-Isochromanon, (50) 6,7-Dimethoxy-3-isochromanon, (51) 6-Ethyl-4-oxo-4H-1-benzopyran-3-carbonitril,
(52) 6-Ethyl-4-oxo-4H-1-benzopyran-3-carboxaldehyd, (53) 6-Isopropyl-4-oxo-4H-1-benzopyran-3-carbonitril,
(54) 6-Isopropyl-4-oxo-4H-1-benzopyran-3-carboxaldehyd, (55) Maleinsäureanhydrid,
(56) Brommaleinsäureanhydrid, (57) Citraconsäureanhydrid, (58) 2,3-Dimethylmaleinsäureanhydrid,
(59) Dichlormaleinsäureanhydrid, (60) cis-Aconitsäureanhydrid, (61) Itaconsäureanhydrid,
(62) Methylbemsteinsäureanhydrid, (63) Acetylmercaptobernsteinsäureanhydrid, (64)
2,2-Dimethylbemsteinsäureanhydrid (65) Phenylbemsteinsäureanhydrid, (66) 2-Octen-1-ylbemsteinsäureanhydrid,
(67) 2-Dodecen-1-ylbernsteinsäureanhydrid, (68) 2-Octadecen-1-ylbernsteinsäureanhydrid,
(69) 3-Oxabicyclo[3.1.0]hexan-2,4-dion, (70) Diglycolsäureanhydrid, (71) Glutarsäureanhydrid,
(72) 3-Methylglutarsäureanhydrid, (73) 2,2-Dimethylglutarsäureanhydrid, (74) 3,3-Tetramethylenglutarsäureanhydrid,
(75) 1-Cyclopenten-1,2-dicarbonsäureanhydrid, (76) 3,4,5,6-Tetrahydrophthalsäureanhydrid,
(77) cis-1,2-Cyclohexandicarbonsäureanhydrid, (78) Hexahydro-4-methylphthalsäureanhydrid,
(79) Methyl-5-norbomen-2,3-dicarbonsäureanhydrid, (80) 2,3-Pyridincarbonsäureanhydrid,
(81) 3,4-Pyridincarbonsäureanhydrid, (82) Furfurylmercaptan, (83) S-Furfurylthioacetat,
(84) Furfurylsulfid, (85) Furfurylmethyldisulfid, (86) Furfuryldisulfid, (87) Glycolaldehyddimer,
(88) 6,7-Dihydrocyclopenta-1,3-dioxin-5(4H)-on, (89) (2R,6R)-tert-Butyl-6-methyl-1,3-dioxan-4-on,
(90) 2,2-Dimethyl-1,3-dioxan-4,6-dion, (91) 3,6-Dimethyl-1,4-dioxan-2,5-dion, (92)
2,2,6-Trimethyl-4H-1,3-dioxin-4-on, (93) 2,2,5-Trimethyl-1,3-dioxan-4,6-dion, (94)
5-Brom-2,2,5-trimethyl-1,3-dioxan-4,6-dion, (95) 1,3-Dioxan-5,5-dimethanol, (96) 1,3,5-Trioxan,
(97) 1,6-Dioxaspiro[4.4]nonan-2,7-dion, (98) 1,4-Dioxaspiro[4.5]decan-2-on, (99) 1,7-Dioxaspiro[5.5]undecan,
(100) 2,4,8,10-Tetraoxaspiro[5.5]undecan, (101) 3,9-Divinyl-2,4,8-tetraoxaspiro[5.5]undecan,
(102) 2,2-Pentamethylen-1,3-dioxalan, (103) 2-Phenyl-1,3-dioxalan, (104) 1,4-Cyclohexandionmonoethylenketal,
(105) 1,4-Cyclohexandionbis(ethylenketal), (106) 1,4-Cyclohexandionmono-2,2-dimethyltrimethylenketal,
(107) Piperonal, (108) Piperonylacetat, (109) Piperonylalkohol, (110) Piperonylnitril,
(111) Piperonylamin, (112) 6-Nitropiperonal, (113) 6-Nitropiperonylalkohol, (114)
3',4'-(Methylendioxy)acetophenon, (115) 3,4-(Methylendioxy)anilin, (116) 2,3-(Methylendioxy)benzaldehyd,
(117) 3,4-(Methylendioxy)phenylacetonitril, (118) 3,4-(Methylendioxy)toluol und (119)
Mischungen davon; oder worin das transparentmachende Mittel ein Kronenether ist; oder
worin das transparentmachende Mittel ausgewählt ist aus der Gruppe bestehend aus (1)
1,4,7,10-Tetraoxacyclododecan (12-Krone-4), (2) 2-(Hydroxyethyl)-12-krone-4, (3) 2-(Aminoethyl)-12-krone-4,
(4) Benzo-12-krone-4, (5) 1,4,7,10,13-Pentaoxacyclododecan (15-Krone-5), (6) 2-(Hydroxyethyl)-15-krone-5,
(7) 2-(Aminoethyl)-15-krone-5, (8) Benzo-15-krone-5, (9) 4'-Aminobenzo-15-krone-5,
(10) 4'-Formylbenzo-15-krone-5, (11) 4'-Nitrobenzo-15-krone-5, (12) Bis[(benzo-15-krone-5)-15-ylmethyl]pimelat,
(13) 1,4,7,10,13,16-Hexaoxacyclooctadecan (18-Krone-6), (14) 2-(Aminoethyl)-18-krone-6,
(15) Benzo-18-krone-6, (16) 4'-Brombenzo-18-krone-6, (17) Dibenzo-18-krone-6, (18)
Di-tert-butyldibenzo-18-krone-6, (19) cis-Dicyclohexan-18-krone-6, (20) Dibenzo-24-krone-8,
(21) Dicyclohexano-24-krone-8, (22) Dibenzo-30-krone-10 und (23) Mischungen davon;
oder worin das transparentmachende Mittel ein cyclischer Kohlenwasserstoff ist; oder
worin das transparentmachende Mittel ausgewählt ist aus der Gruppe bestehend aus:
(A) Materialien der allgemeinen Formeln:

worin R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
6, R
9, R
10, R
11 und R
12 jeweils unabhängig voneinander ausgewählt sind aus der Gruppe bestehend aus Wasserstoffatomen,
Alkylgruppen, substituierten Alkylgruppen, Arylgruppen, substituierten Arylgruppen,
Arylalkylgruppen, substituierten Arylalkylgruppen, Hydroxygruppen, Amingruppen, Imingruppen,
Ammoniumgruppen, Pyridingruppen, Pyridiniumgruppen, Ethergruppen, Aldehydgruppen,
Ketongruppen, Estergruppen, Amidgruppen, Carbonsäuregruppen, Carbonylgruppen, Thiocarbonylgruppen,
Sulfatgruppen, Sulfonatgruppen, Sulfidgruppen, Sulfoxidgruppen, Phosphingruppen, Phosphoniumgruppen,
Phosphatgruppen, Cyangruppen, Nitrilgruppen, Mercaptogruppen, Nitrosogruppen, Halogenatomen,
Nitrogruppen, Sulfongruppen, Acylgruppen, Säureanhydridgruppen und Azidgruppen, worin
zwei oder mehr von R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11 und R
12 miteinander verbunden sein können, um einen Ring zu bilden; (B) Materialien der allgemeinen
Formel:

worin R
1, R
2, R
3, R
4, R
5 und R
6 jeweils unabhängig voneinander ausgewählt sind aus der Gruppe bestehend aus Wasserstoffatomen,
Alkylgruppen, substituierten Alkylgruppen, Arylgruppen, substituierten Arylgruppen,
Arylalkylgruppen, substituierten Arylalkylgruppen, Hydroxygruppen, Amingruppen, Imingruppen,
Ammoniumgruppen, Pyridingruppen, Pyridiniumgruppen, Ethergruppen, Aldehydgruppen,
Ketongruppen, Estergruppen, Amidgruppen, Carbonsäuregruppen, Carbonylgruppen, Thiocarbonylgruppen,
Sulfatgruppen, Sulfonatgruppen, Sulfidgruppen, Sulfoxidgruppen, Phosphingruppen, Phosphoniumgruppen,
Phosphatgruppen, Cyangruppen, Nitrilgruppen, Mercaptogruppen, Nitrosogruppen, Halogenatomen,
Nitrogruppen, Sulfongruppen, Acylgruppen, Säureanhydridgruppen und Azidgruppen, worin
zwei oder mehr von R
1, R
2, R
3, R
4, R
5 und R
6 miteinander verbunden sein können, um einen Ring zu bilden; (C) Materialien der allgemeinen
Formel:

worin R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9 und R
10 jeweils unabhängig voneinander ausgewählt sind aus der Gruppe bestehend aus Wasserstoffatomen,
Alkylgruppen, substituierten Alkylgruppen, Arylgruppen, substituierten Arylgruppen,
Arylalkylgruppen, substituierten Arylalkylgruppen, Hydroxygruppen, Amingruppen, Imingruppen,
Ammoniumgruppen, Pyridingruppen, Pyridiniumgruppen, Ethergruppen, Aldehydgruppen,
Ketongruppen, Estergruppen, Amidgruppen, Carbonsäuregruppen, Carbonylgruppen, Thiocarbonylgruppen,
Sulfatgruppen, Sulfonatgruppen, Sulfidgruppen, Sulfoxidgruppen, Phosphingruppen, Phosphoniumgruppen,
Phosphatgruppen, Cyangruppen, Nitrilgruppen, Mercaptogruppen, Nitrosogruppen, Halogenatomen,
Nitrogruppen, Sulfongruppen, Acylgruppen, Säureanhydridgruppen und Azidgruppen, worin
zwei oder mehr von R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9 und R
10 miteinander verbunden sein können, um einen Ring zu bilden; (D) Materialien der allgemeinen
Formeln:

worin R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11 und R
12 jeweils unabhängig voneinander ausgewählt sind aus der Gruppe bestehend aus Wasserstoffatomen,
Alkylgruppen, substituierten Alkylgruppen, Arylgruppen, substituierten Arylgruppen,
Arylalkylgruppen, substituierten Arylalkylgruppen, Hydroxygruppen, Amingruppen, Imingruppen,
Ammoniumgruppen, Pyridingruppen, Pyridiniumgruppen, Ethergruppen, Aldehydgruppen,
Ketongruppen, Estergruppen, Amidgruppen, Carbonsäuregruppen, Carbonylgruppen, Thiocarbonylgruppen,
Sulfatgruppen, Sulfonatgruppen, Sulfidgruppen, Sulfoxidgruppen, Phosphingruppen, Phosphoniumgruppen,
Phosphatgruppen, Cyangruppen, Nitrilgruppen, Mercaptogruppen, Nitrosogruppen, Halogenatomen,
Nitrogruppen, Sulfongruppen, Acylgruppen, Säureanhydridgruppen und Azidgruppen, worin
zwei oder mehr von R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11 und R
12 miteinander verbunden sein können, um einen Ring zu bilden; (E) Materialien der allgemeinen
Formel:

worin R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9 und R
10 jeweils unabhängig voneinander ausgewählt sind aus der Gruppe bestehend aus Wasserstoffatomen,
Alkylgruppen, substituierten Alkylgruppen, Arylgruppen, substituierten Arylgruppen,
Arylalkylgruppen, substituierten Arylalkylgruppen, Hydroxygruppen, Amingruppen, Imingruppen,
Ammoniumgruppen, Pyridingruppen, Pyridiniumgruppen, Ethergruppen, Aldehydgruppen,
Ketongruppen, Estergruppen, Amidgruppen, Carbonsäuregruppen, Carbonylgruppen, Thiocarbonylgruppen,
Sulfatgruppen, Sulfonatgruppen, Sulfidgruppen, Sulfoxidgruppen, Phosphingruppen, Phosphoniumgruppen,
Phosphatgruppen, Cyangruppen, Nitrilgruppen, Mercaptogruppen, Nitrosogruppen, Halogenatomen,
Nitrogruppen, Sulfongruppen, Acylgruppen, Säureanhydridgruppen und Azidgruppen, worin
zwei oder mehr von R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9 und R
10 miteinander verbunden sein können, um einen Ring zu bilden; (F) Materialien der allgemeinen
Formeln:

worin R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9 und R
10 jeweils unabhängig voneinander ausgewählt sind aus der Gruppe bestehend aus Wasserstoffatomen,
Alkylgruppen, substituierten Alkylgruppen, Arylgruppen, substituierten Arylgruppen,
Arylalkylgruppen, substituierten Arylalkylgruppen, Hydroxygruppen, Amingruppen, Imingruppen,
Ammoniumgruppen, Pyridingruppen, Pyridiniumgruppen, Ethergruppen, Aldehydgruppen,
Ketongruppen, Estergruppen, Amidgruppen, Carbonsäuregruppen, Carbonylgruppen, Thiocarbonylgruppen,
Sulfatgruppen, Sulfonatgruppen, Sulfidgruppen, Sulfoxidgruppen, Phosphingruppen, Phosphoniumgruppen,
Phosphatgruppen, Cyangruppen, Nitrilgruppen, Mercaptogruppen, Nitrosogruppen, Halogenatomen,
Nitrogruppen, Sulfongruppen, Acylgruppen, Säureanhydridgruppen und Azidgruppen, worin
zwei oder mehr von R
1, R
2, R
3, R
4, R
5, R
6 R
7, R
8, R
9 und R
10 miteinander verbunden sein können, um einen Ring zu bilden; (G) Materialien der allgemeinen
Formel:

worin der gekrümmte Teil der Struktur eine Kohlenwasserstoffkette oder eine substituierte
Kohlenwasserstoffkette bedeutet, worin zwei oder mehr Substituenten miteinander verbunden
sein können, um einen Ring zu bilden; und (H) Mischungen davon; oder worin das transparentmachende
Mittel ausgewählt ist aus der Gruppe bestehend aus (1) Norbornan, (2) 2-Norbomancarbonitril,
(3) 2-Norbomanmethanol, (4) 3-Methyl-2-norbornanmethanol, (5) Camphen, (6) Fenchylalkohol,
(7) Thiocampher, (8) Norbornen, (9) 5-Norbomen-2-carbonitril, (10) 5-Norbornen-2-carboxaldehyd,
(11) 5-Norbornen-2-methanol, (12) 5-Norbomen-2,2-dimethanol, (13) 5-Norbornen-2-benzoyl,
(14) 2-Norbornanon, (15) 3-Chlor-2-norbomanon, (16) Fenchon, (17) 3-(Trifluoracetyl)campher,
(18) 3-Heptafluorbutyrylcampher, (19) 3-Bromcampher, (20) 9,10-Dibromcampher, (21)
3,9,10-Tribromcampher, (22) Dicyclopentadien, (23) Methylcyclopentadiendimer, (24)
Tricyclo[5.2.1]decan, (25) 4,8-Bis(hydroxymethyl)tricyclo[5.2.1.0
2.6]decan, (26) 8-Ketotricyclo[5.2.1.0
2.6]decan, (27) 3,4-Dimethoxy-3-cyclobuten-1,2-dion, (28) 3,4-Diethoxy-3-cyclobuten-1,2-dion,
(29) 3,4-Diisopropoxy-3-cyclobuten-1,2-dion, (30) 3,4-Dibutoxy-3-cyclobuten-3-cyclobuten-1,2-dion,
(31) 3-Methyl-2-(nitromethyl)-5-oxocyclopentanessigsäure, (32) 3-Ethyl-2-hydroxy-2-cyclopenten-1-on,
(33) Methyl-4-methoxy-2-oxo-3-cyclopenten-1-carboxylat, (34) 3,3a,6,6a-Tetrahydro-2H-cyclopenta[b]furan-2-on,
(35) 3a,4,5,6a-Hexahydro-5-hydroxy-4(hydroxymethyl)-2H-cyclopenta[b]furan-2-on, (36)
3-Methyl-1,2-cyclopentandion, (37) 4-Hydroxy-5-methyl-4-cyclopenten-1,3-dion-Monohydrat,
(38) 2,4,4-Trimethylcyclohexen-1-on, (39) Ethyl-6-methyl-2-oxo-3-cyclohexen-1-carboxylat,
(40) Ethyl-4-Hydroxy-6-methyl-2-oxo-3-cyclohexen-1 -carboxylat, (41) 5-(1-Acetoxy-1-methylethyl)-2-methyl-2-cyclohexen-1-on,
(42) Thymochinon, (43) 2,6,6-Trimethyl-2-cyclohexen-1,4-dion, (44) Indan, (45) 1-Indanol,
(46) 2-Indanol, (47) 1-Indanon, (48) 2-Indanon, (49) 2-Acetyl-1-tetralon, (50) 4-Methyl-1-tetralon,
(51) 5,7-Dimethyl-1-tetralon, (52) 6,7-Dimethoxy-1-tetralon, (53) 1-Methyl-2-tetralon,
(54) 6,7-Dimethoxy-2-tetralon, (55) Cyclohexanon, (56 Cycloheptanon, (57) Cyclooctanon,
(58) Cyclononanon, (59) Cyclodecanon, (60) Cycloundecanon, (61) Cyclododecanon, (62)
Cyclotridecanon, (63) Cyclopentadecanon, (64) 2-Acetylcyclohexanon, (65) 2-Allylcyclohexanon,
(66) 2-Phenylcyclohexanon, (67) Cyclohexandion, (68) 2-Acetyl-1,3-cyclohexandion,
(69) 4,4-Dimethyl-1,3-cyclohexandion, (70) 2-Acetyl-1,3-cyclopentandion, (71) 3,3,5,5-Tetramethyl-1,2-cyclopentandion,
(72) Bicyclo[3.2.1]octan-2-on, (73) Endo-dimethyl-7-oxabicyclo[2.2.1]heptan-2,3-dicarboxylat,
(74) Cineol, (75) Bicyclo[2.2.2]oct-5-en-2,3-dimethanol, (76) Tropon, (77) Tropolon,
(78) Cyclooctenoxid, (79) 1,2,5,6-Diepoxycyclooctan, (80) 9-Methyl-Δ
5(10)-octalin-1,6-dion, (81) cis-Bicyclo[3.3.0]octan-3.7-dion, (82) Azulen, (83) 1-Benzosuberon,
(84) 1,5,9-Cyclododecatrien, (85) Cyclododecanepoxid, (86) 2,3-Cyclododecenopyridin,
(87) 1,2,5,6,9,10-Hexabromcyclododecan, (88) 8-Cyclohexadecen-1-on, (89) Bicyclo[10.3.0]pentadec-12(1)-en-13-on,
(90) 1,4,4a,8a-Tetrahydro-endo-1,4-methannaphthalin-5,8-dion, und (91) Mischungen
davon; oder worin das transparentmachende Mittel ein Thioharnstoff ist; oder worin
das transparentmachende Mittel ein Sulfon ist; oder worin das transparentmachende
Mittel eine thiocyclische Verbindung ist; oder worin das transparentmachende Mittel
ausgewählt ist aus der Gruppe bestehend aus Sulfiten, Sulfitderivaten, Sulfiden, Sulfidderivaten,
quaternären Schwefelverbindungen, quaternären Schwefelderivaten und Mischungen davon;
oder worin das transparentmachende Mittel eine Thiaaza-cyclische Verbindung ist; oder
worin das transparentmachende Mittel ausgewählt ist aus der Gruppe bestehend aus (1)
1-Allyl-2-thiohamstoff, (2) 1-Methallyl-3-methyl-2-thioharnstoff, (3) 4-Allyl-3-thiosemicarbazid,
(4) 1,3-Diethyl-2-thioharnstoff, (5) 1,3-Dibutyl-2-thioharnstoff, (6) 1-Benzyl-3-methyl-2-thiohamstoff,
(7) 1,1,3,3-Tetramethyl-2-thiohamstoff, (8) 2-Imino-4-thiobiuret, (9) 1-Allyl-3-(2-hydroxyethyl)-2-thioharnstoff,
(10) S-(2-Aminoethyl)isothiouroniumbromid-Hydrobromid, (11) S,S-Diphenylsulfillimin-Monohydrat,
(12) Methylsulfon, (13) Ethylsulfon, (14) Butylsulfon, (15) Butadiensulfon, (16) Tetramethylensulfon,
(17) 1,4-Butansulfon, (18) 1,4-Butandiol-cyclisches Sulfat, (19) Benzylsulfon, (20)
Phenylsulfon, (21) Phenylvinylsulfon, (22) Phenylstyrolsulfon, (23) Phenyl-2-(trimethylsilyl)methylsulfon,
(24) Phenyl-2-(trimethylsilyl)ethylsulfon, (25) Phenyl-2-(trimethylsilyl)ethinylsulfon,
(26) 4-(Fluorphenyl)sulfon, (27) 4-(Fluorphenyl)methylsulfon, (28) Chlormethylphenylsulfon,
(29) Chlormethyl-p-tolylsulfon, (30) 2-Chlorethylphenylsulfon, (31) Methylthiomethylphenylsulfon,
(32) Methylthiomethyl-p-tolylsulfon, (33) 2-(Phenylsulfonyl)tetrahydropyran, (34)
1-(Phenylsulfonyl)indol, (35) 1-(p-Toluolsulfonyl)imidazol, (36) 1-(p-Tosyl)-3,4,4-trimethylimidazolidin,
(37) 4-(p-Tosylsulfonyl)hexahydro-1,4-thiazepin, (38) Thionaphthen, (39) 4-Keto-4,5,6,7-tetrahydrothianaphthen,
(40) 2,2'-Bithiophen, (41) 2,2':5',2"-Terthiophen, (42) N-Acetylhomocystein-Thiolacton,
(43) Tetrahydrothiopyran-4-on, (44) Thiochroman-4-on, (45) Thiochroman-4-ol, (46)
Thioctansäure, (47) Ethyl-1,3-dithiolan-2-carboxylat, (48) 3H-1,2-Benzodithiol-3-on,
(49) 1,3-Dithian, (50) 2-Phenyl-1,3-dithian, (51) Ethyl-1,3-dithian-2-carboxylat,
(52) 5,6-Dihydro-5-methyl-4H-1,3,5-dithiazin, (53) 1,4-Dithian, (54) 2,5-Dihydroxy-2,5-dimethyl-1,4-dithian,
(55) 1,5-Dithiacyclooctan-3-ol, (56) 1,4-Dithiaspiro[45]decan-8-ol, (57) 1,3,5-Tithian,
(58) 1,4,7-Trithiacyclononan, (59) 1,4,7-Trithiacyclodecan, (60) 1,4,7,10-Tetrathiacyclododecan,
(61) 3,6,9,14-Tetrathiabicyclo[9.2.1]tetradeca-11,13-dien, (62) 1,4,8,1-Tetrathiacyclotetradecan,
(63) 1,5,9,13-Tetrathiocyclohexadecan, (64)1,5,9,13-Tetrathiacyclohexadecan-3,11-diol,
(65)1,4,7,10,13-Pentathiacyclopentadecan, (66)1,4,7,10,13,16-Hexathiacyclooctadecan,
(67) 1,5,9,13,17,21-Hexathiacyclotetracosan-3,11,19-triol, (68)1,4,7,10,13,16,19,22-Octathiacyclotetracosan,
(69) 1,4,8,11,15,18,22,25-Octathiacyclooctacosan, (70) 1,4,7,10,13,16,19,22,25-Nonathiacycloheptacosan,
(71) Dimethylsulfit, (72) Diethylsulfit, (73) Natriumsulfit, (74) Allyldisulfid, (75)
Aminophenyldisulfid, (76) Benzyldisulfid, (77) Benzylphenylsulfid, (78) Trimethylsulfoniummethylsulfat,
(79) (2-Chlorethyl)dimethylsulfoniumiodid, (80) 3-(Chlorpropyl)diphenylsulfoniumtetrafluorborat,
(81) Trimethylsulfoniumiodid, (82) Trimethylsulfoxoniumiodid, (83) Trimethylsulfoxoniumchlorid,
(84) Triphenylmethansulfenylchlorid, (85) Dimethyl(2-methoxy-5-nitrobenzyl)sulfoniumbromid,
(86) Thioninperchlorat, (87) p-Xylylenbis(tetrahydrothiopheneumchlorid), (88) Tris(dimethylamino)sulfoniumdifluortrimethylsilicat,
(89) Tris(dimethylamino)sulfoniumtrifluormethoxid, (90) (3-Amino-3-carboxypropyl)dimethylsulfoniumchlorid
und (91) Mischungen davon; oder worin das transparentmachende Mittel eines der folgenden
allgemeinen Formeln ist:

worin R
1, R
2, R
3, R
4, R
5, R
6 und R
7, jeweils unabhängig voneinander ausgewählt sind aus der Gruppe bestehend aus Wasserstoffatomen,
Alkylgruppen, substituierten Alkylgruppen, Arylgruppen, substituierten Arylgruppen,
Arylalkylgruppen, substituierten Arylalkylgruppen, Hydroxygruppen, Amingruppen, Imingruppen,
Ammoniumgruppen, Pyridingruppen, Pyridiniumgruppen, Ethergruppen, Aldehydgruppen,
Ketongruppen, Estergruppen, Amidgruppen, Carbonsäuregruppen, Carbonylgruppen, Thiocarbonylgruppen,
Sulfatgruppen, Sulfonatgruppen, Sulfidgruppen, Sulfoxidgruppen, Phosphingruppen, Phosphoniumgruppen,
Phosphatgruppen, Cyangruppen, Nitrilgruppen, Mercaptogruppen, Nitrosogruppen, Halogenatomen,
Nitrogruppen, Sulfongruppen, Acylgruppen, Säureanhydridgruppen und Azidgruppen, worin
zwei oder mehr von R
1, R
2, R
3, R
4, R
5, R
6 und R
7 miteinander verbunden sein können, um einen Ring zu bilden; oder worin das transparentmachende
Mittel ausgewählt ist aus der Gruppe bestehend aus (1) 2-Amino-2-thiazolin, (2) 2-Aminothiazol,
(3) 2-Amino-4-methylthiazol, (4) 2-Amino-4-methylthiazol, (5) 2-Amino-4-thiazolessigsäure,
(6) 2-Acetamido-4-methylthiazol, (7) 2-Acetylthiazol, (8) 5-Acetyl-2,4-dimethylthiazol,
(9) 4-Methyl-5-vinylthiazol, (10) 2-Amino-4-phenyl-5-tetradecylthiazol, (11) 2,4-Thiazolidindion,
(12) 3-Aminorhodanin, (13) 3-Methylrhodanin, (14) 3-Ethylrhodanin, (15) 3-Allylrhodanin,
(16) 3-Hydroxy-4-methyl-2(3H)-thiazolethion, (17) Benzothiazol, (18) 2-Methylbenzothiazol,
(19) 2-(Methylthio)benzothiazol, (20) 2-Amino-4-methylbenzothiazol, (21) 3-Methylbenzothiazol-2-thion,
(22) 2,1,3-Benzothiadiazol, (23) 4-Amino-2,1,3-benzothiadiazol, (24) 3,4-Dimethyl-5-(2-hydroxyethyl)thiazoliumiodid,
(25) 3-Ethyl-5-(2-hydroxyethyl)4-methylthiazoliumbromid, (26) 2-Amino-5-nitrothiazol,
(27) 2-Amino-a-(methoxyimino)-4-thiazolessigsäure, (28) Ethyl-2-amino-α-(hydroxyimino)-4-thiazolacetat,
(29) Ethyl-2-amino-a-(methoxyimino)-4-thiazolacetat, (30) Ethyl-2-amino-4-thiazolacetat,
(31) Ethyl-2-amino-4-thiazolglyoxylat, (32) 1-Phenyl-3-(2-thiazolyl)-2-thioharnstoff,
(33) 2-Amino-4-methoxybenzothiazol, (34) 2-Amino-5,6-dimethylbenzothiazol, (35) N'-(2-Thiazolyl)sulfanilamid,
(36) 6-Ethoxy-2-benzothiazolsulfonamid, (37) Ethyl-2-(formylamino)-4-thiazolacetat,
(38) Ethyl-2-(formylamino)-4-thiazolglyoxylat, (39) 2-(Formylamino)-a-(methoxyimino)-4-thiazolessigsäure,
(40) 2-Acetamido-4-methyl-5-thiazolsulfonylchlorid, (41) 2-Thioxo-4-thiazolidincarbonsäure,
(42) Thiazolidin-4-carbonsäure, (43) Pseudothiohydantoin, (44) 2-Amino-1,3,4-thiadiazol,
(45) 2-Amino-5-trifluormethyl-1,3,4-thiadiazol, (46) 2-Amino-5-methyl-1,3,4-thiadiazol,
(47) 2-Amino-5-ethyl-1,3,4-thiadiazol, (48) 2-Amino-5-(ethylthio)-1,3,4-thiadiazol,
(49) 5-Amino-1,3,4-thiadiazol-2-thiol, (50) 2-Acetamido-5-benzylthio-1,3,4-thiadiazol,
(51) 5-Acetamido-1,3,4-thiadiazol-2-sulfonamid, (52) 5-Anilino-1,2,3,4-thiatriazol,
(53) 2-Amino-4,5-dimethylthiazol-Hydrochlorid, (54) 2-Amino-4-imino-2-thiazolin-Hydrochlorid,
(55) 2-Amino-2-thiazolin-Hydrochlorid, (56) 2-Amino-5-bromthiazol-Monohydrobromid,
(57) 5-Amino-3-methylisothiazol-Hydrochlorid, (58) 3-Methyl-2-benzothiazolinonhydrazon-Hydrochlorid-Hydrat,
(59) 5-Amino-2-methylbenzothiazol-Dihydrochlorid, (60) 2,4-Diamino-5-phenylthiazol-Monohydrobromid,
(61) 2-Amino-4-phenylthiazol-Hydrobromid-Monohydrat, (62) 2-(Tritylamino)-α-(methoxyimino)-4-thiazolessigsäure-Hydrochlorid,
(63) (2,3,5,6-Tetrahydro-6-phenylimidazo[2,1-b]thiazol-Hydrochlorid, (64) 3-Ethyl-2-methyl-2-thiazoliumiodid,
(65) 3-Benzyl-5-(2-hydroxyethyl)-4-methylthiazoliumchlorid, (66) Thiamin-Hydrochlorid,
(67) 3-(Carboxymethyl)benzothiazoliumbromid, (68) 2-Azido-3-ethylbenzothiazoliumtetrafluorborat,
(69) 3-Ethyl-2-methylbenzothiazoliumiodid, (70) 2-Methyl-3-propylbenzothiazoliumiodid,
(71) 3-Ethyl-2-(2-hydroxy-1-propenyl)benzothiazoliumchlorid, (72) 3,6-Dimethyl-2-(4-dimethylaminophenyl)benzothiazoliumbromid,
(73) Trifluorperazin-Dihydrochlorid, (74) Thioridazin-Hydrochlorid, (75) Promethazin-Hydrochlorid,
(76) Ethopropazin-Hydrochlorid, (77) Chlorpromazin-Hydrochlorid und (78) Mischungen
davon; oder worin das transparentmachende Mittel ausgewählt ist aus der Gruppe bestehend
aus Phosphinen, Phosphiten, cyclischen Phosphorverbindungen, Phosphinoxiden, quatemären
Phosphoniumsalzen und Mischungen davon; oder worin das transparentmachende Mittel
ausgewählt ist aus der Gruppe bestehend aus (1) Triphenylphosphin, (2) Tri-m-tolylphosphin,
(3) Tris(3-methoxyphenyl)phosphin, (4) Tris(4-chlorphenyl)phosphin, (5) Tris(pentafluorphenyl)phosphin,
(6) Tricyclohexylphosphin, (7) Tribenzylphosphin, (8) Tri-2-furylphosphin, (9) Bis(pyrrolidino)methoxyphosphon,
(10) Tetraphenylbiphosphin, (11) 1,3-Bis(diphenylphosphino)propan, (12) 1,5-Bis(diphenylphosphino)pentan,
(13) 1,6-Bis(diphenylphosphino)hexan, (14) lsopropyldiphenylphosphin, (15) Diphenyl(p-tolyl)phosphin,
(16) (4-Bromphenyl)diphenylphosphin, (17) Diphenyl-2-pyridylphosphin, (18) Dicyclohexylphenylphosphin,
(19) Trimethylphosphit, (20) Triethylphosphit, (21) Tris(2-chlorethyl)phosphit, (22)
Tributylphosphit, (23) Triphenylphosphit, (24) Trimethylphosphit-Kupferiodid, (25)
Triethylphosphit-Kupferiodid, (26) Dipropylphosphit, (27) Bis(2-ethylhexyl)phosphit,
(28) Bis(4-Nitrobenzyl)phosphit, (29) 2,2'-Ethylidenbis(4,6-di-tert-butylphenyl)fluorphosphit,
(30) Pentaerythritdiphenyldiphosphit, (31) 2-Furyltetramethylphosphorodiamidat, (32)
Diethyl(pyrrolidinomethyl)phosphonat, (33) Cyclophosphamid-Monohydrat, (34) 2-Chlor-1,3,2-dioxaphospholan-2-oxid,
(35) N,N-Diethyl-1,5-dihydro-2,4,3-benzodioxaphosphepin-3-amin, (36) 1,2-Phenylenphosphochloridit,
(37) 1,2-Phenylenphosphochloridat, (38) 2-Chlor-4H-1,3,2-benzodioxaphosphorin-4-on,
(39) 2,4-Bis(methylthio)-1,3-dithia-2,4-diphosphetan-2,4-disulfid, (40) Triphenylphosphinoxid,
(41) Tris(hydroxymethyl)phosphinoxid, (42) Trimethoxyphosphinoxid, (43) Triethoxyphosphinoxid,
(44) Triphenoxyphosphinoxid, (45) Tris(2-butoxyethoxy)phosphinoxid, (46) Diphenylphosphinoxid,
(47) Diphenyl(2,4,6-trimethylbenzoyl)phosphinoxid, (48) Phenylphosphinsäure, (49)
Diphenylphosphat, (50) Vinylphosphonsäure, (51) Propylphosphonsäure, (52) Pyrophosphorsäure,
(53) Triphenylphosphat, (54) Tetrabutylphosphoniumchlorid, (55) Tetrabutylphosphoniumbromid,
(56) Hexadecyltributylphosphoniumbromid, (57) Stearyltributylphosphoniumbromid, (58)
Azidotris(diethylamino)phosphoniumbromid, (59) Phosphonitrilchloridtrimer, (60) Tetramethylphosphoniumbromid,
(61) Tetramethylphosphoniumchlorid, (62) Tetraethylphosphoniumbromid, (63) Tetraethylphosphoniumchlorid,
(64) Tetraethylphosphoniumiodid, (65) Tetraphenylphosphoniumbromid, (66) Tetraphenylphosphoniumchlorid,
(67) Tetraphenylphosphoniumiodid, (68) Methyltriphenylphosphoniumbromid, (69) Methyltriphenylphosphoniumiodid,
(70) Ethyltriphenylphosphoniumbromid, (71) n-Propyltriphenylphosphoniumbromid, (72)
lsopropyltriphenylphosphoniumiodid, (73) Cyclopropyltriphenylphosphoniumbromid, (74)
n-Butyltriphenylphosphoniumbromid, (75) Isobutyltriphenylphosphoniumbromid, (76) Hexyltriphenylphosphoniumbromid,
(77) Benzyltriphenylphosphoniumchlorid, (78) Brommethyltriphenylphosphoniumbromid,
(79) Chlormethyltriphenylphosphoniumchlorid, (80) 3-Brompropyltriphenylphosphoniumbromid,
(81) 3-Brombutyltriphenylphosphoniumbromid, (82) 4-Brombutyltriphenylphosphoniumbromid,
(83) 2-Dimethylaminoethyltriphenylphosphoniumbromid, (84) [(3-Dimethylamino)propyl]triphenylphosphoniumbromid,
(85) 2-Hydroxyethyltriphenylphosphoniumbromid, (86) (2-Hydroxyethyl)triphenylphosphoniumchlorid,
(87) [3-Hydroxy-2-methylpropyl]triphenylphosphoniumbromid, (88) [3-Hydroxy-2-methylpropyl]triphenylphosphoniumbromid,
(89) (2-Hydroxybenzyltriphenylphosphoniumbromid, (90) (Formylmethyl)triphenylphosphoniumchlorid,
(91) (Methoxymethyl)triphenylphosphoniumchlorid, (92) Acetonyltriphenylphosphoniumchlorid,
(93) Carbomethoxymethyltriphenylphosphoniumbromid, (94) (Ethoxycarbonylmethyl)triphenylphosphoniumchlorid,
(95) Carbethoxymethyltriphenylphosphoniumbromid, (96) (tert-Butoxycarbonylmethyl)triphenylphosphoniumbromid,
(97) Phenacyltriphenylphosphoniumbromid, (98) (4-Ethoxybenzyl)triphenylphosphoniumbromid,
(99) 4-Butoxybenzyltriphenylphosphoniumbromid, (100) 2-(1,3-Dioxan-2-yl)ethyl]triphenylphosphoniumbromid,
(101) (1,3-Dioxolan,2-ylmethyl)triphenylphosphoniumbromid, (102) Vinyltriphenylphosphoniumbromid,
(103) Allyltriphenylphosphoniumbromid, (104) Allyltriphenylphosphoniumchlorid, (105)
Propargyltriphenylphosphoniumbromid, (106) (3-Trimethylsilyl-2-propinyl)triphenylphosphoniumbromid,
(107) p-Xylylenbis(triphenylphosphoniumbromid) und (108) Mischungen davon; oder worin
das transparentmachende Mittel ein Nitril ist; oder worin das transparentmachende
Mittel ausgewählt ist aus der Gruppe bestehend aus (1) Cyanacetohydrazid, (2) 4,4-Dimethyl-3-oxopentannitril,
(3) 1-Cyan-N-methylthioformamid, (4) Cyanmethyl-N,N-dimethyldithiocarbamat, (5) 4-Hydroxy-3-methoxy-phenylacetonitril,
(6) Tosylcyanid, (7) Tosylmethylisocyanid, (8) 5-Fluor-2-methylbenzonitril, (9) 2-Fluor-5-methylbenzonitril,
(10) 4-(Methylthio)benzonitril, (11) 4-(Dimethylamino)benzonitril, (12) 3,4-Dimethoxybenzonitril,
(13) 4-Hydroxy-3-methoxybenzonitril, (14) 4-(trans-4-Pentylcyclohexyl)benzonitril,
(15) 4'-Pentyl-4'-biphenylcarbonitril, (16) 4'-(Pentyloxy)-4-biphenylcarbonitril,
(17) 4'-Hexyl-4-biphenylcarbonitril, (18) 4'-(Hexyloxy)-4-biphenylcarbonitril, (19)
4'-Heptyl-4-biphenylcarbonitril, (20) 4'-Heptyloxy-4-biphenylcarbonitril, (21) 4'-Octyl-4-biphenylcarbonitril,
(22) 4'-(Octyloxy)-4-biphenylcarbonitril, (23) Succinonitril, (24) Fumaronitril, (25)
1,4-Dicyan-2-buten, (26) (Dimethylaminomethylen)malononitril, (27) (1-Ethoxyethyliden)malononitril,
(28) a-Chlorbenzylidenmalononitril, (29) Benzylidenmalononitril, (30) 2-Benzoyloxy-2-phenylmalononitril,
(31) O-(p-Tosyl)isonitrosomalononitril, (32) Tetrafluorphthalonitril, (33) Iminodiacetonitril,
(34) Phenylendiacetonitril, (35) 3,3'-(4-Formylphenylimino)dipropionitril, (36) Tris(2-cyanethyl)nitromethan,
(37) 1,1,3,3-Propantetracarbonitril, (38) Tetracyanethylenoxid und (39) Mischungen
davon; oder worin das transparentmachende Mittel ausgewählt ist aus der Gruppe bestehend
aus Isothiocyanaten, Isocyanaten und Mischungen davon; oder worin das transparentmachende
Mittel ausgewählt ist aus der Gruppe bestehend aus (1) 4-Azidophenylisothiocyanat,
(2) 1-Naphthylisothiocyanat, (3) 4-Dimethylamino-1-naphthylisothiocyanat, (4) 1-lsothiocyanato-4-(trans-4-propylcyclohexyl)benzol,
(5) 1-(trans-4-Hexylcyclohexyl)-4-isothiocyanatobenzol, (6) 1-(4-trans-Hexylcyclohexyl)-4-[2-(4-isothiocyanatophenyl)]benzol,
(7) 1-lsothiocyanato-4-(trans-4-octylcyclohexyl)benzol, (8) 4-lsothiocyanatophenyl-4-pentabicyclo[2.2.2]octan-1-carboxylat,
(9) Benzylthiocyanat, (10) Guanidinthiocyanat, (11) Methylendithiocyanat, (12) 4,4'-Methylenbis(phenylisocyanat),
(13) 4,4'-Methylenbis(2,6-diethylisocyanat) und (14) Mischungen davon; oder worin
das transparentmachende Mittel ausgewählt ist aus der Gruppe bestehend aus Oximverbindung,
Hydroxamsäureverbindungen und Mischungen davon; oder worin das transparentmachende
Mittel ausgewählt ist aus der Gruppe bestehend aus (1) Formamidoxim, (2) Acetaldoxim,
(3) Pyruvinaldehyd-1-oxim, (4) Acetonoxim, (5) Ethylchloroximidoacetat, (6) 2,3-Butandionmonoxim,
(7) 5-Hydroxypentenaloxim, (8) Cyclopentanonoxim, (9) Cyclohexanonoxim, (10) Cyclooctanonoxim,
(11) Benzaldehydoxim, (12) 2-Nitrobenzaldehydoxim, (13) Salicylaldoxim, (14) 2-lsonitrosoacetphenon,
(15) 1-Phenyl-1,2-Propandion-2-oxim, (16) 2-Pyridinaldoxim, (17) Nifuroxim und (18)
Mischungen davon; oder worin das transparentmachende Mittel ein Hydroxamsäurederivat
ist; oder worin das transparentmachende Mittel ausgewählt ist aus der Gruppe bestehend
aus (1) Acetohydroxamsäure, (2) Suberohydroxamsäure, (3) Mandelohydroxamsäure, (4)
Benzohydroxamsäure, (5) N-Phenylbenzohydroxamsäure und (6) Mischungen davon; oder
worin das transparentmachende Mittel ausgewählt ist aus der Gruppe bestehend aus Alkylammoniumsalzen,
Arylammoniumsalzen, Arylalkylammoniumsalzen oder Mischungen davon; oder worin das
transparentmachende Mittel ausgewählt ist aus der Gruppe bestehend aus (1) Tetramethylammoniumfluorid-Tetrahydrat,
(2) Tetraethylammoniumacetat-Tetrahydrat, (3) Tetrabutylammoniumchlorid, (4) Tetrabutylammoniumchlorid-Hydrat,
(5) Tetrabutylammoniumbromid, (6) Tetrabutylammoniumtribromid, (7) Tetrabutylammoniumacetat,
(8) Tetrabutylammoniumthiocyanat, (9) Tetrapentylammoniumbromid, (10) Tetrahexylammoniumbromid,
(11) Tetrahexylammoniumchlorid, (12) Tetrahexylammoniumhydrogensulfat, (13) Tetraheptylammoniumchlorid,
(14) Tetraheptylammoniumbromid, (15) Tetraoctylammoniumbromid, (16) Tetrakisdecylammoniumbromid,
(17) Tetrahexadecylammoniumbromid, (18) Tetramethylammoniumbromid, (19) Tetramethylammoniumchlorid,
(20) Tetramethylammoniumiodid, (21) Tetraethylammoniumbromid, (22) Tetraethylammoniumchlorid,
(23) Tetraethylammoniumiodid, (24) Tetrapropylammoniumbromid, (25) Tetrapropylammoniumiodid,
(26) Tetrabutylammoniumiodid, (27) Tetrapentylammoniumchlorid, (28) Tetrahexylammoniumbromid,
(29) Tetrahexylammoniumiodid, (30) Tetradecylammoniumbromid, (31) Tetradodecylammoniumbromid,
(32) Tetraoctadecylammoniumbromid, (33) Methyltrioctylammoniumbromid, (34) Tridodecylmethylammoniumchlorid,
(35) Tridodecylammoniumiodid, (36) N-Dodecyl-N-methylephedriniumbromid, (37) Phenyltrimethylammoniumtribromid,
(38) Tricaprylmethylammoniumchlorid, (39) Tridodecylmethylammoniumchlorid, (40) Tridecyloxypropyldihydroxyethylmethylammoniumchlorid,
(41) N-Tetradecyldimethylnaphthylmethylammoniumchlorid, (42) Octadecyldiethanolmethylammoniumchlorid,
(43) Octadecyldihydroxyethylmethylammoniumchlorid, (44) dihydriertes Talgbenzylmethylammoniumchlorid,
(45) 2-Aminoethyltrimethylammoniumchlorid-Hydrochlorid, (46) 2-Bromethyltrimethylammoniumbromid,
(47) 2-Chlorethyltrimethylammoniumchlorid (48) 3-Carboxypropyltrimethylammoniumchlorid,
(49) [3-(Methacryloylamino)propyl]trimethylammoniumchlorid, (50) Phenyltrimethylammoniumbromid,
(51) Phenyltrimethylammoniumchlorid, (52) Phenyltrimethylammoniumiodid, (53) Benzyltrimethylammoniumchlorid,
(54) Benzyltrimethylammoniumbromid, (55) 4-Nitrobenzyltrimethylammoniumchlorid, (56)
[2-(4-Nitrophenyl)allyl]trimethylammoniumiodid, (57) Kokostrimethylammoniumchlorid,
(58) Palmityltrimethylammoniumchlorid, (59) Myristyltrimethylammoniumbromid, (60)
Oleyltrimethylammoniumchlorid, (61) Soyatrimethylammoniumchlorid, (62) Talgtrimethylammoniumchlorid,
(63) hydriertes Talgtrimethylammoniumchlorid, (64) Stearyltrimethylammoniumchlorid,
(65) Behenyltrimethylammoniumchlorid, (66) Guarhydroxypropyltrimethylammoniumchlorid,
(67) Benzyltriethylammoniumbromid, (68) Butyltripropylammoniumbromid, (69) Methyltributylammoniumchlorid,
(70) Methyltributylammoniumbromid, (71) Methyltributylammoniumiodid, (72) Benzyltributylammoniumchlorid,
(73) Benzyltributylammoniumbromid, (74) Benzyltributylammoniumiodid, (75) Heptyltributylammoniumbromid,
(76) Benzyldodecyldimethylammoniumbromid, (77) Benzyltetradecyldimethylammoniumchlorid-Dihydrat,
(78) Benzylcetyldimethylammoniumchlorid-Monohydrat, (79) Benzylstearyldimethylammoniumchlorid-Monohydrat,
(80) N,N-Dimethylmethylenammoniumchlorid, (81) N,N-Dimethylmethylenammoniumiodid,
(82) Chlormethylendimethylammoniumchlorid, (83) Dichlormethylendimethylammoniumchlorid,
(84) Dimethylaminomethylenaminomethylendimethylammoniumchlorid, (85) Benzethoniumchlorid,
(86) Methylbenzethoniumchlorid, (87) 1-Propanaminium-2,3-dihydroxy-N-dimethyl-N-[3(oxococoyl)amino]propyl]-chlorid,
(88) Cetyldimethylethylammoniumbromid, (89) Octyldodecyldimethylammoniumchlorid, (90)
Dodecyl(2-hydroxy-1-methyl-2-phenyl-ethyl)dimethylammoniumbromid, (91) Dodecyldimethyl-2-phenoxyethylammoniumbromid,
(92) Dodecanoyl-N-methylaminoethyl(phenylcarbamylmethyl)dimethylammoniumchlorid, (93)
3-Chlor-2-hydroxypropyl-N,N,N-dimethyldodecylammoniumchlorid, (94) 3-Chlor-2-hydroxypropyl-N,N,N-dimethyloctadecylammoniumchlorid,
(95) Dodecylbenzyldimethylammoniumbromid, (96) Dodecylbenzyldimethylammoniumchlorid,
(97) Kokosbenzyldimethylammoniumchlorid, (98) Benzyltetradecyldimethylammoniumchlorid,
(99) Benzylcetyldimethylammoniumchlorid, (100) Benzyloctadecyldimethylammoniumchlorid,
(101) Benzyltalgdimethylammoniumchlorid, (102) Benzyl-hydriertes-talgdimethylammoniumchlorid,
(103) Benzylbehenyldimethylammoniumchlorid, (104) Dioctyldimethylammoniumchlorid,
(105) Didecyldimethylammoniumchlorid, (106) Didecyldimethylammoniumbromid, (107) Dikokosdimethylammoniumchlorid,
(108) Dicetyldimethylammoniumchlorid, (109) Disoyadimethylammoniumchlorid, (110) Ditalgdimethylammoniumchlorid,
(111) dihydriertes Talgdimethylammoniumchlorid, (112) Dibehenyl/Diarachidyldimethylammoniumchlorid,
(113) Soyaamidopropylbenzyldimethylammoniumchlorid, (114) Soyadikokos-quatemäres-ammoniumchlorid,
(115) Gluconamidopropyldimethyl-2-hydroxyethylammoniumchlorid, (116) N-Alkyl-N-N-dimethyl-N(dodecylacetat)ammoniumchlorid,
worin Alkyl 14 bis 20 Kohlenstoffatome hat, (117) Nerzamidopropyldimethyl-2-hydroxyethylammoniumchlorid,
(118) N-Raps-(3-amidopropyl)-N-N-dimethyl-N-(2,3-epoxypropyl)ammoniumchlorid, (119)
N-Stearyl-(3-amidopropyl)-N-benzyldimethylammoniumchlorid, (120) Rapsamidopropylbenzyldimethylammoniumchlorid,
(121) Rapsamidopropylethyldimethylammoniumchlorid, (122) Kokamidopropylpolyethylenglycoldimethylammoniumchloridphosphat,
(123) Butyrylcholinchlorid und (124) Mischungen davon; oder worin das transparentmachende
Mittel ausgewählt ist aus der Gruppe bestehend aus Piperidinthiocyanat, 2-Piperidinmethanol,
Bis(pentamethylenharnstoff, 4,4'-Trimethylen-bis(1-piperidinpropionitril), Tripiperidinphosphinoxid,
Homopiperazin, 1-Piperonylpiperazin, Hexacyclentrisulfat, 5,10,15,20-Tetraphenyl-21H,23H-porphin,
5,10,15,20-Tetrakis(4-methoxyphenyl)-2H,23H-porphin, Pyrrol-2-carboxaldehyd, 3-Pyrrolidino-1,2-propandiol,
Pyrazol, 3-Aminopyrazol, Imidazol, 2-Ethylimidazol, 2-(2-Piperidinoethyl)pyridin,
1-Dodecylpyridiniumchlorid, Pyridiniumbromidperbromid, 3-Aminochinolin, 8-Hydroxychinolin,
7,8-Benzochinolin, 8-Hydroxychinaldin, Chinoxalin, 4,5-Dihydro-6-methyl-3(2H)-pyridazinon-Monohydrat,
Phthalazin, 1,10-Phenanthrolin, 1,3,5-Triazin, Trichlormelamin, Trichlorisocyanursäure,
Norboman, Tricyclo[5.2.1.0]decan, Norcampher, Tropolon, 1-Indanol, trans,trans,cis-1,5,9-Cyclododecatrien,
Cyclodecanepoxid, 2,3-Cyclododecanpyridin, 1,2,5,6,9,10-Hexabromcyclododecan, 1,4,4a,8a-Tetrahydro-endo-1,4-methano-naphthalin-5,8-dion,
γ-Butyrolacton, β,β-Dimethyl-γ-(hydroxymethyl)-γ-butyrolacton, 2,5-Dimethyl-4-hydroxy-3(2H)-furanon,
Hydrindantin-Dihydrat, 2,4,8,10-Tetraoxaspiro[5.5]undecan, 1,3,5-Trioxan, Cyclooctanon,
Piperonal, Piperonylalkohol, Piperonylnitril, 3,4(Methylendioxy)phenylacetonitril,
Maleinsäureanhydrid, S-Acetylmercaptobemsteinsäureanhydrid, 2-Octadecen-1-ylbernsteinsäureanhydrid,
18-Krone-6, Benzo-18-krone-6, Dibenzo-18-krone-6, Dibenzo-24-krone-8, 5-Amino-3-methylisooxazol,
2-Oxazolidon, 5,5-Dimethyloxazolidin-2,4-dion, 3-Ethyl-2-thioxo-4-oxazolidinon, 3-Morpholino-1,2-propandiol,
4-Phenylmorpholin, N, N'-Dibenzyl-1,4,10,13-tetraoxa-7,16-diazacyclooctadecan, 4,7,13,16,21,24-Hexaoxa-1,10-diazabicyclo[8.8.8]hexacosan,
γ-Valerolactam, ε-Caprolactam, 2-Azacyclooctanon, 2-Azacyclononanon, Maleimid, N-Methylsuccinimid,
Phthalimid-DBU-Salz, 1-Allyl-2-thioharnstoff, 1,3-Dithian, 1-Benzyl-3-methyl-2-thioharnstoff,
2-lmino-4-thiobiuret, Butylsulfon, 2,2'-Bithiophen, 2-Phenyl-1,3-dithian, 3,6,9,14-Tetrathiabicyclo[9.2.1]tetradeca-11,13-dien,
1,5,9,13-Tetrathiacyclohexadecan-3,11-diol, 1,4,7,10,13-Penta-thiacyclopentadecan,
2-Aminothiazol, 2-Amino-2-thiazolin, 3-Methylrhodanin, 3-Ethyl-5-(2-hydroxyethyl)-4-methylthiazoliumbromid,
Triphenylphosphin, Tricyclohexylphosphin, 1,3-Bis(diphenylphosphino)propan, 1,5-Bis(diphenylphosphino)pentan,
Isopropyldiphenylphosphin, Triethylphosphit, Triphenylphosphit, Triethylphosphit-Kupferiodid,
Dipropylphosphit, Bis(2-ethylhexyl)phosphit, Bis(4-nitrobenzyl)phosphit, Diphenylphosphinoxid,
Diphenyl(2,4,6-trimethylbenzoyl)phosphinoxid, Vinylphosphonsäure, Cyanacetohydrazid,
Cyanmethyl-N,N-dimethyldithiocarbamat, 4'-Pentyl-4'-biphenylcarbonitril, 4'-(Octyloxy)-4-biphenylcarbonitril,
1,4-Dicyan-2-buten, Benzylidenmalononitril, 1-lsothiocyanato-4-(trans-4-propylcyclohexyl)benzol,
Formamidoxim, Ethylchloroximidoacetat, Acetohydroxamsäure, Tetrahexylammoniumchlorid,
Tetraheptylammoniumchlorid, Tetraheptylammoniumbromid und Mischungen davon.
9. Ein Verfahren welches umfaßt (1) das Migrationsbilderzeugungselementes gemäß Anspruch
1 umfassend (a) ein Substrat, (b) eine erweichbare Schicht umfassend ein erweichbares
Material und ein photoempfindliches Migrationsmarkierungsmaterial und (c) ein transparentmachendes
Mittel, welches das damit in Kontakt befindliche Migrationsmarkierungsmaterial transparent
macht, enthalten in mindestens einer Schicht des Migrationsbilderzeugungselementes;
(2) gleichmäßiges Laden des Bilderzeugungselementes; (3) nach der Stufe (2), Aussetzen
des geladenen Bilderzeugungselementes aktivierender Strahlung bei einer Wellenlänge,
für welche das Migrationsmarkierungsmaterial empfindlich ist; (4) nach Stufe (3),
Bewirken der Erweichung des erweichbaren Materials und Befähigen eines ersten Teiles
des Migrationsmarkierungsmaterials, durch das erweichbare Material zu dem Substrat
in einem bildweisen Muster zu migrieren, während ein zweiter Teil des Migrationsmarkierungsmaterials
im wesentlichen nicht migriert in der erweichbaren Schicht zurückbleibt; worin nach
der Migration des ersten Teiles des Migrationsmarkierungsmaterials entweder (a) der
erste Teil des Migrationsmarkierungsmaterials das transparentmachende Mittel kontaktiert
und der zweite Teil des Migrationsmarkierungsmaterials das transparentmachende Mittel
nicht kontaktiert; oder (b) der zweite Teil des Migrationsmarkierungsmaterials das
transparentmachende Mittel kontaktiert und der erste Teil des Migrationsmarkierungsmaterials
das transparentmachende Mittel nicht kontaktiert.
10. Ein Verfahren nach Anspruch 9, worin der erste Teil des Migrationsmarkierungsmaterials
das transparentmachende Mittel kontaktiert und der zweite Teil des Migrationsmarkierungsmaterials
das transparentmachende Mittel nicht kontaktiert; oder worin der zweite Teil des Migrationsmarkierungsmaterials
das transparentmachende Mittel kontaktiert und der erste Teil des Migrationsmarkierungsmaterials
das transparentmachende Mittel nicht kontaktiert.
1. Elément de formation d'images par migration (1) comprenant (a) un substrat (2), (b)
une couche ramollissable (6) comprenant un matériau ramollissable (7) et un matériau
de marquage par migration photosensible (8), et (c) un agent de transparence qui rend
transparent le matériau de marquage par migration en contact avec lui, contenu dans
au moins une couche de l'élément de formation d'images par migration, dans lequel
l'agent de transparence agit sur le matériau de marquage par migration qui entre en
contact avec lui en réduisant la densité optique de la couche ramollissable contenant
le matériau de marquage par migration.
2. Elément de formation d'images par migration selon la revendication 1, dans lequel
le matériau de marquage par migration (8) est choisi dans le groupe constitué par
(a) le sélénium, (b) le tellure, (c) des alliages de sélénium et d'un matériau choisi
dans le groupe constitué par le tellure, l'arsenic, l'antimoine, le thallium, le bismuth,
ou des mélanges de ceux-ci, (d) des alliages de tellure et d'un matériau choisi dans
le groupe constitué par l'arsenic, l'antimoine, le thallium, le bismuth ou des mélanges
de ceux-ci, (e) du sélénium dopé par un halogène, (f) du tellure dopé par un halogène,
(g) des alliages dopés par un halogène de sélénium et d'un matériau choisi dans le
groupe constitué par le tellure, l'arsenic, l'antimoine, le thallium, le bismuth ou
des mélanges de ceux-ci, (h) des alliages dopés par un halogène de tellure et d'un
matériau choisi dans le groupe constitué par l'arsenic, l'antimoine, le thallium,
le bismuth ou des mélanges de ceux-ci, et (i) des mélanges de ceux-ci.
3. Elément de formation d'images par migration selon la revendication 1 ou la revendication
2, dans lequel l'agent de transparence est contenu dans la couche ramollissable.
4. Elément de formation d'images par migration selon la revendication 1 ou la revendication
2, dans lequel l'agent de transparence est contenu dans une couche située entre la
couche ramollissable et le substrat.
5. Elément de formation d'images par migration selon la revendication 1 ou 2, dans lequel
la couche ramollissable est située entre le substrat et une couche contenant l'agent
de transparence.
6. Elément de formation d'images par migration selon la revendication 1 ou la revendication
2, dans lequel l'élément de formation d'images par migration comprend un substrat,
une première couche ramollissable comprenant un premier matériau ramollissable et
un premier matériau de marquage par migration, et une seconde couche ramollissable
comprenant un second matériau ramollissable et un second matériau de marquage par
migration, dans lequel l'agent de transparence est contenu dans une couche située
entre la première couche ramollissable et la seconde couche ramollissable.
7. Elément de formation d'images par migration selon l'une quelconque des revendications
1 à 6, dans lequel l'agent de transparence est présent en une quantité d'environ 1
à environ 50 % en poids du matériau constituant la couche dans laquelle il est contenu.
8. Elément de formation d'images par migration selon la revendication 1, dans lequel
l'agent de transparence est un composé azacyclique ; ou dans lequel l'agent de transparence
est choisi dans le groupe constitué par : (A) des matériaux répondant aux formules
générales :

dans lesquelles R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
14, R
15, R
16, R
17, R
18, R
19, R
20, R
21, R
22, R
23, R
24, R
25, R
26, R
27, R
28, R
29, R
30, R
31, R
32, R
33, R
34, R
35, R
36, R
37, R
38 et R
39 sont choisis chacun, indépendamment des autres, dans le groupe constitué par des
atomes d'hydrogène, des groupes alkyle, des groupes alkyle substitué, des groupes
aryle, des groupes aryle substitué, des groupes arylalkyle, des groupes arylalkyle
substitué, des groupes hydroxy, des groupes amine, des groupes imine, des groupes
ammonium, des groupes pyridine, des groupes pyridinium, des groupes éther, des groupes
aldéhyde, des groupes cétone, des groupes ester, des groupes amide, des groupes acide
carboxylique, des groupes carbonyle, des groupes thiocarbonyle, des groupes sulfate,
des groupes sulfonate, des groupes sulfure, des groupes sulfoxyde, des groupes phosphine,
des groupes phosphonium, des groupes phosphate, des groupes cyano, des groupes nitrile,
des groupes mercapto, des groupes nitroso, des atomes d'halogène, des groupes nitro,
des groupes sulfone, des groupes acyle, des groupes anhydride d'acide, et des groupes
azide, dans lesquelles deux ou plus de deux des symboles R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
14, R
15, R
16, R
17, R
18, R
19, R
20, R
21, R
22, R
23, R
24, R
25, R
26, R
27, R
28, R
29, R
30, R
31, R
32, R
33, R
34, R
35, R
36, R
37, R
38 et R
39 peuvent être liés ensemble pour former un cycle ; (B) des matériaux répondant aux
formules générales :

dans lesquelles R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
14, R
15, R
16, R
17, R
18, R
19, R
20, R
21 et R
22 sont choisis chacun, indépendamment des autres, dans le groupe constitué par des
atomes d'hydrogène, des groupes alkyle, des groupes alkyle substitué, des groupes
aryle, des groupes aryle substitué, des groupes arylalkyle, des groupes arylalkyle
substitué, des groupes hydroxy, des groupes amine, des groupes imine, des groupes
ammonium, des groupes pyridine, des groupes pyridinium, des groupes éther, des groupes
aldéhyde, des groupes cétone, des groupes ester, des groupes amide, des groupes acide
carboxylique, des groupes carbonyle, des groupes thiocarbonyle, des groupes sulfate,
des groupes sulfonate, des groupes sulfure, des groupes sulfoxyde, des groupes phosphine,
des groupes phosphonium, des groupes phosphate, des groupes cyano, des groupes nitrile,
des groupes mercapto, des groupes nitroso, des atomes d'halogène, des groupes nitro,
des groupes sulfone, des groupes acyle, des groupes anhydride d'acide, et des groupes
azide, dans lesquelles deux ou plus de deux des symboles R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
14, R
15, R
16, R
17, R
18, R
19, R
20, R
21 et R
22 peuvent être liés ensemble pour former un cycle ; (C) des matériaux répondant aux
formules générales :

dans lesquelles R
1, R
2, et R
3 sont choisis chacun, indépendamment des autres, dans le groupe constitué par des
atomes d'hydrogène, des groupes alkyle, des groupes alkyle substitué, des groupes
aryle, des groupes aryle substitué, des groupes arylalkyle, des groupes arylalkyle
substitué, des groupes hydroxy, des groupes amine, des groupes imine, des groupes
ammonium, des groupes pyridine, des groupes pyridinium, des groupes éther, des groupes
aldéhyde, des groupes cétone, des groupes ester, des groupes amide, des groupes acide
carboxylique, des groupes carbonyle, des groupes thiocarbonyle, des groupes sulfate,
des groupes sulfonate, des groupes sulfure, des groupes sulfoxyde, des groupes phosphine,
des groupes phosphonium, des groupes phosphate, des groupes cyano, des groupes nitrile,
des groupes mercapto, des groupes nitroso, des atomes d'halogène, des groupes nitro,
des groupes sulfone, des groupes acyle, des groupes anhydride d'acide, et des groupes
azide, dans lesquelles deux ou plus de deux des symboles R
1, R
2 et R
3 peuvent être liés ensemble pour former un cycle ; (D) des matériaux répondant aux
formules générales :

dans lesquelles R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, sont choisis chacun, indépendamment des autres, dans le groupe constitué par des
atomes d'hydrogène, des groupes alkyle, des groupes alkyle substitué, des groupes
aryle, des groupes aryle substitué, des groupes arylalkyle, des groupes arylalkyle
substitué, des groupes hydroxy, des groupes amine, des groupes imine, des groupes
ammonium, des groupes pyridine, des groupes pyridinium, des groupes éther, des groupes
aldéhyde, des groupes cétone, des groupes ester, des groupes amide, des groupes acide
carboxylique, des groupes carbonyle, des groupes thiocarbonyle, des groupes sulfate,
des groupes sulfonate, des groupes sulfure, des groupes sulfoxyde, des groupes phosphine,
des groupes phosphonium, des groupes phosphate, des groupes cyano, des groupes nitrile,
des groupes mercapto, des groupes nitroso, des atomes d'halogène, des groupes nitro,
des groupes sulfone, des groupes acyle, des groupes anhydride d'acide, et des groupes
azide, dans lesquelles deux ou plus de deux des symboles R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11 et R
12 peuvent être liés ensemble pour former un cycle ; (E) des matériaux répondant aux
formules générales :

dans lesquelles R
1, R
2, R
3, et R
4 sont choisis chacun, indépendamment des autres, dans le groupe constitué par des
atomes d'hydrogène, des groupes alkyle, des groupes alkyle substitué, des groupes
aryle, des groupes aryle substitué, des groupes arylalkyle, des groupes arylalkyle
substitué, des groupes hydroxy, des groupes amine, des groupes imine, des groupes
ammonium, des groupes pyridine, des groupes pyridinium, des groupes éther, des groupes
aldéhyde, des groupes cétone, des groupes ester, des groupes amide, des groupes acide
carboxylique, des groupes carbonyle, des groupes thiocarbonyle, des groupes sulfate,
des groupes sulfonate, des groupes sulfure, des groupes sulfoxyde, des groupes phosphine,
des groupes phosphonium, des groupes phosphate, des groupes cyano, des groupes nitrile,
des groupes mercapto, des groupes nitroso, des atomes d'halogène, des groupes nitro,
des groupes sulfone, des groupes acyle, des groupes anhydride d'acide, et des groupes
azide, dans lesquelles deux ou plus de deux des symboles R
1, R
2, R
3, et R
4 peuvent être liés ensemble pour former un cycle ; (F) des matériaux répondant à la
formule générale

dans laquelle R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13 et R
14 sont choisis chacun, indépendamment des autres, dans le groupe constitué par des
atomes d'hydrogène, des groupes alkyle, des groupes alkyle substitué, des groupes
aryle, des groupes aryle substitué, des groupes arylalkyle, des groupes arylalkyle
substitué, des groupes hydroxy, des groupes amine, des groupes imine, des groupes
ammonium, des groupes pyridine, des groupes pyridinium, des groupes éther, des groupes
aldéhyde, des groupes cétone, des groupes ester, des groupes amide, des groupes acide
carboxylique, des groupes carbonyle, des groupes thiocarbonyle, des groupes sulfate,
des groupes sulfonate, des groupes sulfure, des groupes sulfoxyde, des groupes phosphine,
des groupes phosphonium, des groupes phosphate, des groupes cyano, des groupes nitrile,
des groupes mercapto, des groupes nitroso, des atomes d'halogène, des groupes nitro,
des groupes sulfone, des groupes acyle, des groupes anhydride d'acide, et des groupes
azide, dans laquelle deux ou plus de deux des symboles R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13 et R
14 peuvent être liés ensemble pour former un cycle ; (G) des matériaux répondant à la
formule générale :

dans laquelle R
1 et R
2 sont choisis chacun, indépendamment des autres, dans le groupe constitué par des
atomes d'hydrogène, des groupes alkyle, des groupes alkyle substitué, des groupes
aryle, des groupes aryle substitué, des groupes arylalkyle, des groupes arylalkyle
substitué, des groupes hydroxy, des groupes amine, des groupes imine, des groupes
ammonium, des groupes pyridine, des groupes pyridinium, des groupes éther, des groupes
aldéhyde, des groupes cétone, des groupes ester, des groupes amide, des groupes acide
carboxylique, des groupes carbonyle, des groupes thiocarbonyle, des groupes sulfate,
des groupes sulfonate, des groupes sulfure, des groupes sulfoxyde, des groupes phosphine,
des groupes phosphonium, des groupes phosphate, des groupes cyano, des groupes nitrile,
des groupes mercapto, des groupes nitroso, des atomes d'halogène, des groupes nitro,
des groupes sulfone, des groupes acyle, des groupes anhydride d'acide, et des groupes
azide, dans lesquels deux ou plus de deux des symboles R
1, et R
2 peuvent être liés ensemble pour former un cycle ; (H) des matériaux répondant à la
formule générale :

dans laquelle R
1, R
2, R
3, R
4, et R
6 sont choisis chacun, indépendamment des autres, dans le groupe constitué par des
atomes d'hydrogène, des groupes alkyle, des groupes alkyle substitué, des groupes
aryle, des groupes aryle substitué, des groupes arylalkyle, des groupes arylalkyle
substitué, des groupes hydroxy, des groupes amine, des groupes imine, des groupes
ammonium, des groupes pyridine, des groupes pyridinium, des groupes éther, des groupes
aldéhyde, des groupes cétone, des groupes ester, des groupes amide, des groupes acide
carboxylique, des groupes carbonyle, des groupes thiocarbonyle, des groupes sulfate,
des groupes sulfonate, des groupes sulfure, des groupes sulfoxyde, des groupes phosphine,
des groupes phosphonium, des groupes phosphate, des groupes cyano, des groupes nitrile,
des groupes mercapto, des groupes nitroso, des atomes d'halogène, des groupes nitro,
des groupes sulfone, des groupes acyle, des groupes anhydride d'acide, et des groupes
azide, dans laquelle deux ou plus de deux des symboles R
1, R
2, R
3, R
4, et R
5 peuvent être liés ensemble pour former un cycle ; (I) des matériaux répondant à la
formule générale :

dans laquelle R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8 et R
9 sont choisis chacun, indépendamment des autres, dans le groupe constitué par des
atomes d'hydrogène, des groupes alkyle, des groupes alkyle substitué, des groupes
aryle, des groupes aryle substitué, des groupes arylalkyle, des groupes arylalkyle
substitué, des groupes hydroxy, des groupes amine, des groupes imine, des groupes
ammonium, des groupes pyridine, des groupes pyridinium, des groupes éther, des groupes
aldéhyde, des groupes cétone, des groupes ester, des groupes amide, des groupes acide
carboxylique, des groupes carbonyle, des groupes thiocarbonyle, des groupes sulfate,
des groupes sulfonate, des groupes sulfure, des groupes sulfoxyde, des groupes phosphine,
des groupes phosphonium, des groupes phosphate, des groupes cyano, des groupes nitrile,
des groupes mercapto, des groupes nitroso, des atomes d'halogène, des groupes nitro,
des groupes sulfone, des groupes acyle, des groupes anhydride d'acide, et des groupes
azide, dans laquelle deux ou plus de deux des symboles R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8 et R
9 peuvent être liés ensemble pour former un cycle ; (J) des matériaux répondant à la
formule générale :

dans laquelle R
1, R
2, R
3, et R
4 sont choisis chacun, indépendamment des autres, dans le groupe constitué par des
atomes d'hydrogène, des groupes alkyle, des groupes alkyle substitué, des groupes
aryle, des groupes aryle substitué, des groupes arylalkyle, des groupes arylalkyle
substitué, des groupes hydroxy, des groupes amine, des groupes imine, des groupes
ammonium, des groupes pyridine, des groupes pyridinium, des groupes éther, des groupes
aldéhyde, des groupes cétone, des groupes ester, des groupes amide, des groupes acide
carboxylique, des groupes carbonyle, des groupes thiocarbonyle, des groupes sulfate,
des groupes sulfonate, des groupes sulfure, des groupes sulfoxyde, des groupes phosphine,
des groupes phosphonium, des groupes phosphate, des groupes cyano, des groupes nitrile,
des groupes mercapto, des groupes nitroso, des atomes d'halogène, des groupes nitro,
des groupes sulfone, des groupes acyle, des groupes anhydride d'acide, et des groupes
azide, dans laquelle deux ou plus de deux des symboles R
1, R
2, R
3, et R
4 peuvent être liés ensemble pour former un cycle ; (K) des matériaux répondant à la
formule générale :

dans laquelle R
1, R
2, R
3, et R
4, sont choisis, chacun indépendamment des autres, dans le groupe constitué par des
atomes d'hydrogène, des groupes alkyle, des groupes alkyle substitué, des groupes
aryle, des groupes aryle substitué, des groupes arylalkyle, des groupes arylalkyle
substitué, des groupes hydroxy, des groupes amine, des groupes imine, des groupes
ammonium, des groupes pyridine, des groupes pyridinium, des groupes éther, des groupes
aldéhyde, des groupes cétone, des groupes ester, des groupes amide, des groupes acide
carboxylique, des groupes carbonyle, des groupes thiocarbonyle, des groupes sulfate,
des groupes sulfonate, des groupes sulfure, des groupes sulfoxyde, des groupes phosphine,
des groupes phosphonium, des groupes phosphate, des groupes cyano, des groupes nitrile,
des groupes mercapto, des groupes nitroso, des atomes d'halogène, des groupes nitro,
des groupes sulfone, des groupes acyle, des groupes anhydride d'acide, et des groupes
azide, dans laquelle deux ou plus de deux des symboles R
1, R
2, R
3, et R
4 peuvent être liés ensemble pour former un cycle ; (L) des matériaux répondant à la
formule générale :

dans laquelle R
1, R
2, R
3, R
4 et R
5 sont choisis chacun, indépendamment des autres, dans le groupe constitué par des
atomes d'hydrogène, des groupes alkyle, des groupes alkyle substitué, des groupes
aryle, des groupes aryle substitué, des groupes arylalkyle, des groupes arylalkyle
substitué, des groupes hydroxy, des groupes amine, des groupes imine, des groupes
ammonium, des groupes pyridine, des groupes pyridinium, des groupes éther, des groupes
aldéhyde, des groupes cétone, des groupes ester, des groupes amide, des groupes acide
carboxylique, des groupes carbonyle, des groupes thiocarbonyle, des groupes sulfate,
des groupes sulfonate, des groupes sulfure, des groupes sulfoxyde, des groupes phosphine,
des groupes phosphonium, des groupes phosphate, des groupes cyano, des groupes nitrile,
des groupes mercapto, des groupes nitroso, des atomes d'halogène, des groupes nitro,
des groupes sulfone, des groupes acyle, des groupes anhydride d'acide, et des groupes
azide, dans laquelle deux ou plus de deux des symboles R
1, R
2, R
3, R
4 et R
5 peuvent être liés ensemble pour former un cycle ; (M) des matériaux répondant aux
formules générales :

dans lesquelles R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13 et R
14 sont choisis chacun, indépendamment des autres, dans le groupe constitué par des
atomes d'hydrogène, des groupes alkyle, des groupes alkyle substitué, des groupes
aryle, des groupes aryle substitué, des groupes arylalkyle, des groupes arylalkyle
substitué, des groupes hydroxy, des groupes amine, des groupes imine, des groupes
ammonium, des groupes pyridine, des groupes pyridinium, des groupes éther, des groupes
aldéhyde, des groupes cétone, des groupes ester, des groupes amide, des groupes acide
carboxylique, des groupes carbonyle, des groupes thiocarbonyle, des groupes sulfate,
des groupes sulfonate, des groupes sulfure, des groupes sulfoxyde, des groupes phosphine,
des groupes phosphonium, des groupes phosphate, des groupes cyano, des groupes nitrile,
des groupes mercapto, des groupes nitroso, des atomes d'halogène, des groupes nitro,
des groupes sulfone, des groupes acyle, des groupes anhydride d'acide, et des groupes
azide, dans lesquelles deux ou plus de deux des symboles R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13 et R
14 peuvent être liés ensemble pour former un cycle ; (N) des matériaux répondant à la
formule générale :

dans laquelle R
1, R
2, R
3, et R
4 sont choisis chacun, indépendamment des autres, dans le groupe constitué par des
atomes d'hydrogène, des groupes alkyle, des groupes alkyle substitué, des groupes
aryle, des groupes aryle substitué, des groupes arylalkyle, des groupes arylalkyle
substitué, des groupes hydroxy, des groupes amine, des groupes imine, des groupes
ammonium, des groupes pyridine, des groupes pyridinium, des groupes éther, des groupes
aldéhyde, des groupes cétone, des groupes ester, des groupes amide, des groupes acide
carboxylique, des groupes carbonyle, des groupes thiocarbonyle, des groupes sulfate,
des groupes sulfonate, des groupes sulfure, des groupes sulfoxyde, des groupes phosphine,
des groupes phosphonium, des groupes phosphate, des groupes cyano, des groupes nitrile,
des groupes mercapto, des groupes nitroso, des atomes d'halogène, des groupes nitro,
des groupes sulfone, des groupes acyle, des groupes anhydride d'acide, et des groupes
azide, dans laquelle deux ou plus de deux des symboles R
1, R
2, R
3, et R
4 peuvent être liés ensemble pour former un cycle ; (O) des matériaux répondant à la
formule générale :

dans laquelle R
1, R
2, R
3, et R
4 sont choisis chacun, indépendamment des autres, dans le groupe constitué par des
atomes d'hydrogène, des groupes alkyle, des groupes alkyle substitué, des groupes
aryle, des groupes aryle substitué, des groupes arylalkyle, des groupes arylalkyle
substitué, des groupes hydroxy, des groupes amine, des groupes imine, des groupes
ammonium, des groupes pyridine, des groupes pyridinium, des groupes éther, des groupes
aldéhyde, des groupes cétone, des groupes ester, des groupes amide, des groupes acide
carboxylique, des groupes carbonyle, des groupes thiocarbonyle, des groupes sulfate,
des groupes sulfonate, des groupes sulfure, des groupes sulfoxyde, des groupes phosphine,
des groupes phosphonium, des groupes phosphate, des groupes cyano, des groupes nitrile,
des groupes mercapto, des groupes nitroso, des atomes d'halogène, des groupes nitro,
des groupes sulfone, des groupes acyle, des groupes anhydride d'acide, et des groupes
azide, dans laquelle deux ou plus de deux des symboles R
1, R
2, R
3, et R
4 peuvent être liés ensemble pour former un cycle ; (P) des matériaux répondant à la
formule générale :

dans laquelle R
1, R
2, R
3, et R
4 sont choisis chacun, indépendamment des autres, dans le groupe constitué par des
atomes d'hydrogène, des groupes alkyle, des groupes alkyle substitué, des groupes
aryle, des groupes aryle substitué, des groupes arylalkyle, des groupes arylalkyle
substitué, des groupes hydroxy, des groupes amine, des groupes imine, des groupes
ammonium, des groupes pyridine, des groupes pyridinium, des groupes éther, des groupes
aldéhyde, des groupes cétone, des groupes ester, des groupes amide, des groupes acide
carboxylique, des groupes carbonyle, des groupes thiocarbonyle, des groupes sulfate,
des groupes sulfonate, des groupes sulfure, des groupes sulfoxyde, des groupes phosphine,
des groupes phosphonium, des groupes phosphate, des groupes cyano, des groupes nitrile,
des groupes mercapto, des groupes nitroso, des atomes d'halogène, des groupes nitro,
des groupes sulfone, des groupes acyle, des groupes anhydride d'acide, et des groupes
azide, dans laquelle deux ou plus de deux des symboles R
1, R
2, R
3, et R
4 peuvent être liés ensemble pour former un cycle ; (Q) des matériaux répondant à la
formule générale :

dans laquelle R
1, R
2, R
3 et R
4 sont choisis chacun, indépendamment des autres, dans le groupe constitué par des
atomes d'hydrogène, des groupes alkyle, des groupes aklyle substitué, des groupes
aryle, des groupes aryle substitué, des groupes arylalkyle, des groupes arylalkyle
substitué, des groupes hydroxy, des groupes amine, des groupes imine, des groupes
ammonium, des groupes pyridine, des groupes pyridinium, des groupes éther, des groupes
aldéhyde, des groupes cétone, des groupes ester, des groupes amide, des groupes acide
carboxylique, des groupes carbonyle, des groupes thiocarbonyle, des groupes sulfate,
des groupes sulfonate, des groupes sulfure, des groupes sulfoxyde, des groupes phosphine,
des groupes phosphonium, des groupes phosphate, des groupes cyano, des groupes nitrile,
des groupes mercapto, des groupes nitroso, des atomes d'halogène, des groupes nitro,
des groupes sulfone, des groupes acyle, des groupes anhydride d'acide, et des groupes
azide, dans laquelle deux ou plus de deux des symboles R
1, R
2, R
3 et R
4 peuvent être liés ensemble pour former un cycle ; (R) des matériaux répondant aux
formules générales :

dans laquelle R
1 est choisi dans le groupe constitué par des atomes d'hydrogène, des groupes alkyle,
des groupes alkyle substitué, des groupes aryle, des groupes aryle substitué, des
groupes arylalkyle, des groupes arylalkyle substitué, des groupes hydroxy, des groupes
amine, des groupes imine, des groupes ammonium, des groupes pyridine, des groupes
pyridinium, des groupes éther, des groupes aldéhyde, des groupes cétone, des groupes
ester, des groupes amide, des groupes acide carboxylique, des groupes carbonyle, des
groupes thiocarbonyle, des groupes sulfate, des groupes sulfonate, des groupes sulfure,
des groupes sulfoxyde, des groupes phosphine, des groupes phosphonium, des groupes
phosphate, des groupes cyano, des groupes nitrile, des groupes mercapto, des groupes
nitroso, des atomes d'halogène, des groupes nitro, des groupes sulfone, des groupes
acyle, des groupes anhydride d'acide, et des groupes azide et dans lesquelles la partie
courbe de la structure représente une chaîne hydrocarbonée ou une chaîne hydrocarbonée
substituée, dans lesquelles deux ou plus de deux substituants peuvent être liés ensemble
pour former un cycle ; (S) des matériaux répondant à la formule générale :

dans laquelle R
1 est choisi dans le groupe constitué par des atomes d'hydrogène, des groupes alkyle,
des groupes alkyle substitué, des groupes aryle, des groupes aryle substitué, des
groupes arylalkyle, des groupes arylalkyle substitué, des groupes hydroxy, des groupes
amine, des groupes imine, des groupes ammonium, des groupes pyridine, des groupes
pyridinium, des groupes éther, des groupes aldéhyde, des groupes cétone, des groupes
ester, des groupes amide, des groupes acide carboxylique, des groupes carbonyle, des
groupes thiocarbonyle, des groupes sulfate, des groupes sulfonate, des groupes sulfure,
des groupes sulfoxyde, des groupes phosphine, des groupes phosphonium, des groupes
phosphate, des groupes cyano, des groupes nitrile, des groupes mercapto, des groupes
nitroso, des atomes d'halogène, des groupes nitro, des groupes sulfone, des groupes
acyle, des groupes anhydride d'acide, et des groupes azide, et dans laquelle la partie
courbe de la structure représente une chaîne hydrocarbonée ou une chaîne hydrocarbonée
substituée, dans laquelle deux ou plus de deux substituants peuvent être liés ensemble
pour former un cycle ; (T) des mélanges de ceux-ci ; ou dans lequel l'agent de transparence
est choisi dans le groupe constitué par l'homopipéridine, (2) le thiocyanate de pipéridine,
(3) le 2-pipéridineméthanol, (4) le 3-pipéridineméthanol, (5) le 2-pipéridineéthanol,
(6) le 4-pipéridineéthanol, (7) le monohydrate de chlorhydrate de 4-pipéridine, (8)
la 1-aminopipéridine, (9) la 1-(2-aminoéthyl)pipéridine, (10) la 4-(aminométhyl)pipéridine,
(11) le 3-pipéridino-1,2-propanediol (Aldrich 21,849-9), (12) l'acide 1-pipéridinepropionique,
(13) la 1-méthyl-4(méthylamino)pipéridine, (14) la 1-acétyl-3-méthylpipéridine, (15)
la 4'-pipéridinoacétophénone, (16) la 4-phénylpipéridine, (17) la 4-pipéridinopipéridine,
(18) la 4-benzylpipéridine, (19) la 4-(4-méthylpipéridino)pyridine, (20) le 4-pipéridoneéthylèneacétal,
(21) la bis(pentaméthylène)urée, (22) la 1- benzyl-4-hydroxypipéridine, (23) la 1-benzoyl-4-pipéridone,
(24) la 1,1'-méthylènebis (3-méthylpipéridine), (25) la 4,4'-triméthylènedi-pipéridine,
(26) la 4,4'-triméthylènebis(1-menthylpipéridine), (27) le 4-4'-triméthylènebis(1-pipéridinepropionitrile),
(28) le 4,4'-triméthylènebis-(1-pipéridineéthanol), (29) la 2,2,6,6-tétraméthylpipé-ridine,
(30) la 4-amino-2,2,6,6-tétraméthylpipéridine, (31) la 4-(diméthylamino)-1,2,2,6,6-pentaméthyl-pipéridine,
(32) la N,N'-bis-(2,2,6,6-tétraméthyl-4-pipéridinyl)-1,6-hexanediamine, (33) l'oxyde
de tripipéridinophosphine, (34) le tropane, (35) l'hydrate de tropine, (36) la tropinone,
(37) la 8-hydroxytropinone, (38) l'acide 2-pipéridinecarboxylique, (39) la 2-pipéridone,
(40) le 4,4'-triméthylènebis(1-pipéridinecarboxamide), (41) le 4-méthyl-2-(pipéridinométhyl)phénol,
(42) le bis-(chlorophénoxy)acétate de 1-méthyl-4-pipéridinyle, (43) le monochlorhydrate
de chlorure de 2-(hexaméthylène-imino)éthyle, (44) le chlorhydrate de 3-(hexahydro-1H-azépin-1-yl)-3'-nitropropiophénone,
(45) le chlorhydrate d'imipramine, (46) la carbamézépine, (47) le chlorhydrate de
5,6,11,12-tétrahydrodibenz[b,f]azocine, (48) le chlorhydrate de quinuclidine, (49)
le chlorhydrate de 3-quinuclidinol, (50) le chlorhydrate de 3-quinuclidinone, (51)
le dihydrate de chlorhydrate de 2-méthylène-3-quinuclidinone, (52) le dichlorhydrate
de 3-aminoquinuclidine, (53) le chlorhydrate de 3-chloro-quinuclidine, (54) le dihydrate
de sulfate de quinidine, (55) le dihydrate de monochlorhydrate de quinine, (56) le
monohydrate de sulfate de quinine, (57) le chlorhydrate d'hydroquinidine, (58) le
dihydrate de bromhydrate d'hydroquinine, (59) la pipérazine, (60) l'homopipérazine,
(61) la 1-méthylpipérazine, (62) la 2-méthylpipérazine, (63) la 1-acétylpipérazine,
(64) la 1-(2-hydroxyéthyl)pipérazine, (65) la 1-(2-aminoéthyl)pipérazine, (66) le
1-pipérazinecarboxylate de tert-butyle, (67) le N-isopropyl-1-pipérazineacétamide,
(68) la 1-(2-méthoxyphényl)pipérazine, (69) la 1-(2-pyridyl)pipérazine, (70) la 1-benzylpipérazine,
(71) la 1-cinnamylpipérazine, (72) la 1-(4-chlorobenzhy-dryl)pipérazine, (73) la 2,6-diméthylpipérazine,
(74) la 1-amino-4-méthylpipérazine, (75) la 1-amino-4-(2-hydroxyéthyl)-pipérazine,
(76) la 1,4-bis(2-hydroxyéthyl)pipérazine, (77) la 1,4-bis(3-aminopropyl)-pipérazine,
(78) le carboxylate de tert-butyl-4-benzyl-1-pipérazine, (79) la 1-pipéronylpipérazine,
(80) le disulfure de bis(4-méthyl-1-homopipérazinyl-thiocarbonyle), (81) le monohydrate
de dichlorhydrate de 1-amino-4-méthylpipérazine, (82) le monohydrate de dichlorhydrate
de 1-(3-chloropropyl)-pipérazine, (83) le monochlorhydrate de 1-(2,3-xylyl)-pipérazine,
(84) l'iodure de 1,1-diméthyl-4-phénylpipérazinium, (85) le 1,4,7-triazacyclononane,
(86) le 1,5,9-triazacyclododécane, (87) le 1,2,3-triazole, (88) le 4-amino-1,2,4-triazole,
(89) le 3-amino-5-méthylthio-1H-1,2,4-triazole, (90) le benzotriazole, (91) le 1-aminobenzotriazole,
(92) le 1-cyanobenzotriazole, (93) le 5-méthyl-1H-benzotriazole, (94) l'isocyanure
de 1H-benzotriazole-1-ylméthyle, (95) le méthacrylate de 2-[3-(2H-benzotriazole-2-yl)-4-hydroxyphényl]éthyle,
(96) le 1,2,4-triazole, (97) le dérivé de sodium de 1,2,4-triazole, (98) le 3-amino-1,2,4-triazole,
(99) le 3,5-diamino-1,2,4-triazole, (100) le 3-amino-5-mercapto-1,2,4-triazole, (101)
l'hémihydrate de l'acide 3-amino-1,2,4-triazole-5-carboxylique, (102) le 4-amino-3-hydrazino-5-mercapto-1,2,4-triazole,
(103) le monohydrate de l'acide 1,2,3-triazole-4,5-dicarboxylique, (104) le nitron,
(105) l'hydrate de 1-hydroxybenzotriazole, (106) la 1,3,5-triazine, (107) l'acide
cyanurique, (108) l'acide trithiocyanurique, (109) la 2,4-bis(méthylthio)-6-chloro-1,3,5-triazine,
(110) la 2-chloro-4,6-diméthoxy-1,3,5-triazine, (111) la 2-chloro-4,6-diamino-1,3,5-triazine,
(112) la trichloromélamine, (113) le chlorure cyanurique, (114) la 2,4,6-tris(perfluoroheptyl)-1,3,5-triazine,
(115) le trihydrate d'hexahydro-2,4,6-triméthyl-1,3,5-triazine, (116) la 1,3,5-triméthylhexahydro-1,3,5-triazine,
(117) la 1,3,5-triéthylhexahydro-1,3,5-triazine, (118) la 1,3,5-trichlohexylhexahydro-1,3,5-triazine,
(119) la 1,3,5-tribenzylhexahydro-1,3,5-triazine, (120) l'acide trichloroisocyanurique,
(121) le tris(isocyanurate de 2,3-dibromopropyle), (122) un composé d'acide cyanurique
et de mélamine (123) l'urazole, (124) le 1-méthylurazole, (125) le 4-phénylurazole,
(126) la 5-(4-hydroxyphényl)-5-phénylhydantoïne, (127) la β-tétralonehydantoïne, (128)
le cyclène (1,4,7,10-tétraazacyclododécane), (129) le 1,4,8,11-tétraazacyclotétradécane,
(130) le 1,4,8,11-tétraméthyl-1,4,8,11-tétraazacyclotétradécane, (131) la 1,4,8,11-tétraazacyclotétradécane-5,7-dione,
(132) le 1,4,8,12-tétraazacyclopentadécane, (133) la 2,3,7,8,12,13,17,18-octaéthyl-21H,23H-porphine,
(134) le 3,7,12,17-tétraméthyl-21H,23H-porphine-2,18-dipropionate de diméthyle, (135)
le 7,12-diacétyl-3,8,13,17-tétraméthyl-21H,23H-porphine-2,18-dipropionate de diméthyle,
(136) le sel disodique de l'acide 8,3-divinyl-3,7,12,17-tétraméthyl-21H,23H-porphine-2,18-dipropionique,
(137) la 5,10,15,20-tétraphényl-21H,23H-porphine, (138) la 5,10,15,20-tétrakis(4-méthoxyphényl)-21H,23H-porphine,
(139) le sel tétra-p-tosylate de 5,10,15-20-tétrakis[4-(triméthylamino)phényl]-21H,23H-porphine,
(140) la 5,10,15,20-tétra(4-pyridyl)-21H,23H-porphine, (141) le sel tétra-p-tosylate
de 5,10,15,20-tétrakis(1-méthyl-4-pyridyl)-21H,23H-porphine, (142) le 1,5-pentaméthylènetétrazole,
(143) le 1-H-tétrazole, (144) le monohydrate de 5-aminotétrazole, (145) le chlorure
de 2,3,5-triphényl-2H-tétrazolium, (146) le chlorure de 2-(4-iodophényl)-5-(4-nitrophényl)-3-phényltétrazolium,
(147) l'iodure de 1,2,3,3-tétraméthyl-3H-indolinium, (148) le trisulfate d'hexacyclène,
(149) l'hexaméthylhexacyclène, (150) le pyrrole-2-carboxaldéhyde, (151) le prolineamide,
(152) le 3-pyrrolidino-1,2-propanediol, (153) la 1-(pyrrolidinocarbonylméthyl)pipérazine,
(154) la 4-pyrrolidinopyridine, (155) le 3-indolylacétonitrile, (156) la 6-nitroindoline,
(157) le 7-azaindole, (158) l'indazole, (159) le 2-acétylpyrrole, (160) le 2-acétyl-1-méthylpyrrole,
(161) le 3-acétyl-1-méthylpyrrole, (162) le 3-acétyl-2,4-diméthylpyrrole, (163) l'acide
pyrrole-2-carboxylique, (164) l'acide 3-carboxy-1,4-diméthyl-2-pyrroleacétique, (165)
la proline, (166) l'acide 2-pyrrolidone-5-carboxylique, (167) la 4-hydroxyproline,
(168) l'acide 1,1'-éthylènebis(5-oxo-3-pyrrolidinecarboxylique, (169) le monohydrate
de l'acide kaïnique, (170) le chlorohydrate de 1-aminopyrrolidine, (171) le chlorhydrate
de 2-(2-chloroéthyl)-1-méthylpyrrolidine, (172) le chlorhydrate de 1-(2-chloroéthyl)pyrrolidine,
(173) le dichlorhydrate de trémorine, (174) le chlorhydrate de l'ester méthylique
de la L-proline, (175) le pyrrolidinedithiocarbamate d'ammonium, (176) le tribromhydrate
de pyrrolidone, (177) le chlorhydrate de 1-(4-chlorobenzyl)-2-(1-pyrrolidinylméthyl)benzimidazole,
(178) le dichlorhydrate de billiverdine, (179) l'indole, (180) le 4,5,6,7-tétrahydroindole,
(181) l'hydrate de 3-indoleméthanol, (182) le 3-indoleéthanol, (183) l'indole-3-carboxaldéhyde,
(184) l'acétate de 3-indolyle, (185) l'indole-3-acétamide, (186) l'acide indole-3-carboxylique,
(187) l'acide indole-3-acétique, (188) l'acide 3-indolepropionique, (189) l'acide
3-indoleacrylique, (190) l'acide 3-indoleglyoxylique, (191) l'acide indole-3-pyruvique,
(192) l'acide 3-indolelactique, (193) l'acide 3-indolebutyrique, (194) le N-acétyltryptophanamide,
(195) la N-(3-indolylacétyl)alanine, (196) la N-(3-indolylacétyl)valine, (197) la
N-(3-indolylacétyl)isoleucine, (198) la N-(3-indolylacétyl)leucine, (199) l'acide
N-(3-indolyl-acétyl)aspartique, (200) la N-(3-indolylacétyl)-L-phénylalanine, (201)
le 4-hydroxyindole, (202) l'acide indole-4-carboxylique, (203) l'acétate de 4-indolyle,
(204) le 4-méthylindole, (205) le 5-hydroxyindole, (206) l'acide 5-hydroxyindole-3-acétique,
(207) l'acide 5-hydroxy-2-indolecarboxylique, (208) la N-acétyl-5-hydroxytryptamine,
(209) l'acide indole-5-carboxylique, (210) le 5-méthylindole, (211) le 5-méthoxyindole,
(212) l'acide indole-2-carboxylique, (213) l'acide indolène-2-carboxylique, (214)
l'indole-2,3-dione, (215) le 2-méthylindole, (216) la 2,3,3-triméthylindolénine, (217)
le chlorhydrate de tryptamine, (218) le chlorhydrate de 5-méthyltryptamine, (219)
l'hémihydrate de chlorhydrate de sérotonine, (220) le monohydrate de chlorhydrate
de norharmane, (221) le monohydrate de chlorhydrate d'harmane, (222) l'hydrate de
chlorhydrate d'harmine, (223) l'hydrate de chorhydrate d'harmaline, (224) le dihydrate
de chlorhydrate d'harmol, (225) le dihydrate de chlorhydrate d'harmalol, (226) le
chlorhydrate de 3,6-diaminoacridine, (227) l'iodure de (3-indolyl)isothiuronium, (228)
le chlorhydrate de yohimbine, (229) le pyrazole, (230) le 3-aminopyrazole, (231) le
5-amino-1-éthylpyrazole, (232) le 3-amino-4-carbéthoxypyrazole, (233) le 3-amino-5-méthylpyrazole,
(234) le 3-amino-5-phénylpyrazole, (235) le 4-pyrazolecarboxylate d'éthyle, (236)
le 3,5-pyrazolecarboxylate de diéthyle, (237) le 1,1'-(1-éthylpropylidène)bis-lH-pyrazole,
(238) le 4-bromopyrazole, (239) le 4-bromo-3-méthylpyrazole, (240) le 3,5-diméthylpyrazole,
(241) le 4-bromo-3,5-diméthylpyrazole, (242) le 3,5-diméthylpyrazole-1-carboxamide,
(243) le 3,5-diméthylpyrazole-1-méthanol, (244) le 3-méthyl-1-vinylpyrazole, (245)
la 4-benzoyl-3-méthyl-1-phényl-2-pyrazolin-5-one, (246) le 1-nitropyrazole, (247)
l'acide 4-pyrazolecarboxylique, (248) le monohydrate de l'acide 3,5-pyrazoledicarboxylique,
(249) le 3-amino-5-hydroxypyrazole, (250) le 3-amino-4-pyrazolecarbonitrile, (251)
l'acide 3-amino-4-pyrazolecarboxylique, (252) le chlorhydrate de 4-méthylpyrazole,
(253) le sulfate de 3,4-diamino-5-hydroxypyrazole, (254) le nitrate de 3,5-diméthylpyrazole-1-carboxamidine,
(255) l'hémisulfate de 3-amino-4-pyrazolecarboxamide, (256) un sel d'acide du chlorhydrate
de 6-aminoindazole, (257) la 4-hydroxypyrazolo[3, 4-d]pyrimidine, (258) la 4-mercapto-lH-pyrazolo-[3,4-d]-pyrimidine,
(259) l'indazole, (260) le 5-aminoindazole, (261) le 6-aminoindazole, (262) la 3-indazolinone,
(263) le N'-(6-indazolyl)sulfanilamide, (264) le méthanesulfonate de 4,5-dihydro-3-(4-pyridinyl)-2H-benz[g]indazole,
(265) l'imidazole, (266) le 4-méthylimidazole, (267) le 2-éthylimidazole, (268) le
2-propylimidazole, (269) le 1-butylimidazole, (270) le 2-undécylimidazole, (271) l'histamine,
(272) le 1-(3-aminopropyl)imidazole, (273) le 1-acétylimidazole, (274) le 2-méthyl-1-vinylimidazole,
(275) le 2-éthyl-4-méthylimidazole, (276) le 1-benzyl-2-méthylimidazole, (277) le
1-méthylbenzimidazole, (278) le chlorure de 1-éthyl-3-méthyl-1,H-imidazolinium, (279)
l'hydrate de dichlorhydrate de 2-(aminométhyl)benzimidazole, (280) le monohydrate
d'hémisulfate de 2,6-diamino-8-purinol, (281) le chlorure de purin-6-yl-triméthylammonium,
(282) le chlorhydrate de 4-méthyl-5-imidazoleméthanol, (283) le dipropanoate de N,N'-bis[3-(4,5-dihydro-1H-imidazol-2-yl)phényl]urée,
(284) l'iodure de 1-(p-tosyl)-3,4,4-triméthyl-2-imidazolinium, (285) le chlorure de
1-éthyl-3-méthyl-1H-imidazolinium, (286) le sulfate de 2-aminoimidazole, (287) le
chlorhydrate de 4-amino-5-imidazolecarboxamide, (288) le bromhydrate de 2-hydrazino-2-imidazoline,
(289) le chlorhydrate d'imidazole, (290) le chlorhydrate d'acide 4-imidazole-acétique,
(291) le chlorhydrate de 2-benzyl-2-imidazoline, (292) le chlorhydrate de 1-(1-phényl-éthyl)imidazole-5-carboxylate
de propyle, (293) l'hydrate de sulfate de 2,6-diaminopurine, (294) le méthylsulfate
de 1-suif-amidoéthyl-3-méthyl-2-heptadécylimidazolinium, (295) l'éthylsulfate d'isostéaryléthylimidonium,
(296) le méthylsulfate de méthyl-1-suif-amidoéthyl-2-suif-imidazolinium, (297) le
chlorure d'isostéarylbenzylimidonium, (298) le méthyl-1-suif hydrogéné-amidoéthyle,
(299) le méthylsulfate de suif hydrogéné-imidazolinium, (300) le méthylsulfate de
1-méthyl-1-oléylamidoéthyl-2-oléylimidazolinium, (301) le chlorure de phosphate de
cocohydroxyéthylpolyéthylèneglycolimidazolinium, (302) la guanine, (303) l'hydrate
de guanosine, (304) la xanthine, (305) la 1-méthylxanthine, (306) la 3-méthylxanthine,
(307) la 3-isobutyl-1-méthylxanthine, (308) l'hypoxanthine, (309) le dihydrate de
xanthosine, (310) le 6-thioxanthène, (311) la purine, (312) la 6-aminopurine, (313)
l'hémihydrate de 6-méthoxypurine, (314) le monohydrate de 6-mercaptopurine, (315)
la 2-amino-6-chloropurine, (316) la 2-amino-6,8- dihydroxypurine, (317) la théophylline
(3,7-dihydro-1,3-diméthyl-1H-purine-2,6-dione), (318) la kinétine, (319) la 1-méthyladénine,
(320) la 3-méthyladénine, (321) l'adénosine, (322) l'inosine, (323) le 6-mercaptopurineriboside,
(324) l'hémihydrate de chlorhydrate de 6-aminopurine, (325) le sulfate de 6-aminopurine,
(326) le monohohydrate d'hémisulfate de 2,6-diamino-8-purinol, (327) le benzimidazole,
(328) le 2-aminobenzimidazole, (329) le 2-amino-5,6-diméthylbenzimidazole, (330) l'acide
5-benzimidazolecarboxylique, (331) le 2,4,5-triméthylbenzimidazole, (332) le 2-guanidinobenzimidazole,
(333) le 2-hydroxybenzimidazole, (334) la 4-(2-céto-1-benzimidazolinyl)pipéridine,
(335) la 2-imidazolidinethione, (336) la 2-imidazolidone, (337) l'hydantoïne, (338)
la 1-méthylhydantoïne, (339) la créatinine, (340) la 2-thiohydantoïne, (341) l'acide
5-hydantoïneacétique, (342) la 5-uréidohydantoïne, (343) la 5,5-diméthylhydantoïne,
(344) l'acide 2-imidazolidone-4-carboxylique, (345) le N,N-bis(2-hydroxyéthyl)isonicotinamide,
(346) le 1,2-bis(4-pyridyl)éthylène, (347) la 2-(2-pipéridinoéthyl)pyridine, (348)
le 1,2-bis(4-pyridyl)éthane, (349) la 4,4'-triméthylènepyridine, (350) l'aldrithiol-2,
(351) l'aldrithiol-4, (352) la 1,3-bis(3-pyridylméthyl)-2-thiourée, (353) la 2,2'
: 6',2" -terpyridine, (354) la 2-[N,N-bis(trifluorométhylsulfonyl)amino]pyridine,
(355) l'acide 2,3-pyridinedicarboxylique, (356) le monohydrate d'acide 2,4-pyridinedicarboxylique,
(357) l'acide 2,5-pyridinedicarboxylique, (358) l'acide 2,6-pyridinedicarboxylique,
(359) l'acide 3,4-pyridinedicarboxylique, (360) l'acide 3,5-pyridinedicarboxylique,
(361) le 2,6-pyridinedicarboxaldéhyde, (362) le 3,4-pyridinecarboxamide, (363) le
3,4-pyridinecarboximide, (364) l'anhydride 2,3-pyridinecarboxylique, (365) l'anhydride
3,4-pyridinecarboxylique, (366) le 2,6-pyridineméthanol, (367) l'acide 2-pyridineéthanesulfonique,
(368) l'acide 4-pyridineéthanesulfonique, (369) l'acide 3-pyridinesulfonique, (370)
l'acide pyridoxique, (371) l'acide trans-3-(3-pyridyl)acrylique, (372) l'acide 2-pyridylhydroxyméthanesulfonique,
(373) l'acide 3-pyridylhydroxyméthanesulfonique, (374) l'acide 6-méthyl-2,3-pyridinedicarboxylique,
(375) l'acide isonicotinique, (376) le bromhydrate de pyridine, (377) le chlorhydrate
de pyridine, (378) le chlorhydrate de 2-(chlorométhyl)pyridine, (379) le chlorhydrate
d'acide 2-pyridylacétique, (380) le chlorhydrate de chlorure de nicotinoyle, (381)
le dichlorhydrate de 2-hydrazinopyridine, (382) le dichlorhydrate de 2-(2-méthylaminoéthyl)pyridine,
(383) le chlorhydrate de 1-méthyl-1,2,3,6-tétrahydropyridine, (384) le chlorhydrate
de 2,6-dihydroxypyridine, (385) le chlorhydrate de 3-hydroxy-2(hydroxyméthyl)pyridine,
(386) le chlorhydrate de pyridoxine, (387) le chlorhydrate de pyridoxal, (388) le
monohydrate de 5-phosphate de pyridoxal, (389) le chlorhydrate de 3-amino-2,6-diméthoxypyridine,
(390) le monohydrate de dichlorhydrate de pyridoxamine, (391) le phosphate d'iproniazide,
(392) le chlorhydrate de tripélennamine, (393) le perbromure de bromure de pyridinium,
(394) le 3-nitrobenzènesulfonate de pyridinium, (395) le bromure de 1-éthyl-3-hydroxy-pyridinium,
(396) l'iodure de 1-éthyl-4-(méthoxy-carbonyl)pyridinium, (397) le bromure de 1-heptyl-4-(4-pyridyl)pyridinium,
(398) le chlorure de 1-dodécylpyridinium, (399) le monohydrate de chlorure de 1-hexadécylpyridinium,
(400) le monohydrate de bromure de 1-hexadécylpyridinium, (401) le chlorure de 1-(carboxyméthyl)pyridinium,
(402) l'hydrazide de chlorure de 1-(carboxyméthyl)pyridinium, (403) le chlorure de
1-(3-nitrobenzyloxyméthyl)pyridinium, (404) l'hydroxyde de 1-(3-sulfopropyl)pyridinium,
(405) le chlorure de N-(lauroylcolaminoformylméthyl)pyridinium, (406) le chlorure
de N-(stéaroylcolamineformylméthyl)pyridinium, (407) l'iodure de 2-chloro-1-méthylpyridinium,
(408) le méthanesulfonate de 2-pyridinealdoxime-l-méthyle, le chlorure de 2-pyridinealdoxime-1-méthyle,
(409) l'iodure de 2-[4-(diméthylamino)styryl]-1-éthylpyridinium, (410) le chlorure
de 1-benzyl-3-hydroxypyridinium, (411) l'iodure de 1,4-diméthylpyridinium, (412) l'iodoure
de 1-éthyl-4-phénylpyridinium, (413) l'iodure de 4-phényl-1-propylpyridinium, (414)
le bromure de 1-docosyl-4-(4-hydroxystyryl)pyridinium, (415) le dichlorure de 1,1'-diméthyl-4-4'-bipyridinium,
(416) le dibromure de 1,1'-diéthyl-4-4'-bipyridinium, (417) le dichlorure de 1,1'-dibenzyl-4,4'-bipyridinium,
(418) le dibromure de 1,1'-diheptyl-4,4'-bipyridinium, (419) la 1,7-phénanthroline,
(420) la 1,10-phénanthroline, (421) la 5-chloro-1,10-phénanthroline, (422) le méthanesulfonate
de 4,5-dihydro-3-(4-pyridinyl)-2H-benz[g]indazole, (423) la 1,2,3,4-tétrahydroquinoléine,
(424) la 6-éthoxy-1,2,3,4-tétrahydro-2,2,4-triméthylquinoléine, (425) la 2-cyanoquinoléine,
(426) la 1-cyanoisoquinoléine, (427) la 3-cyanoisoquinoléine, (428) la 3-aminoquinoléine,
(429) la 8-aminoquinoléine, (430) la 7,8-benzoquinoléine, (431) la 8-hydroxyquinoléine,
(432) le sel d'aluminium de la 8-hydroxyquinoléine, (433) la 8-hydroxyquinaldine,
(434) la 3,4,5,6,7,8-hexahydro-2-(1H)-quinolinone, (435) la julolidine, (436) la quinoxaline,
(437) le 2-quinoxalinecarboxylate d'éthyle, (438) la quinoléine, (439) la 2-hydroxyquinoléine,
(440) la 4-hydroxyquinoléine, (441) la 5-hydroxyquinoléine, (442) la 5-aminoquinoléine,
(443) la 6-aminoquinoléine, (444) l'acide 2-quinoléinecarboxylique, (445) l'acide
3-quinoléinecarboxylique, (446) l'acide 4-quinoléinecarboxylique, (447) le 4-quinoléinecarboxaldéhyde,
(448) le 2-quinoléinethiol, (449) le 2,4-quinoléinediol, (450) la quinaldine, (451)
la 4-aminoquinaldine, (452) la 2,6-diméthylquinoléine, (453) la 2,7-diméthylquinoléine,
(454) l'acide 4-méthoxy-2-quinoléinecarboxylique, (455) le 2-phényl-4-quinoléinecarboxylate
de méthyle, (456) la 2-(N-butyl-carbamoyl)-1,2,3,4-tétrahydraisoquinoléine, (457)
la 1-hydroxyisoquinoléine, (458) l'acide 1-isoquinoléinecarboxylique, (459) l'acide
3-isoquinoléinecarboxylique, (460) le 1,5-isoquinoléinediol, (461) l'hémihydrate d'hémisulfate
de 8-hydroxyquinoléine, (462) le dichlorhydrate de 5-amino-8-hydroxyquinoléine, (463)
le monochlorhydrate de 2-(chlorométhyl)quinoléïne, (464) le monohydrate d'acide 8-hydroxyquinoléine-5-sulfonique,
(465) l'hydrate du sel de sodium de l'acide 8-éthoxy-5-quinoléinesulfonique, (466)
le chlorhydrate de 1,2,3,4-tétrahydroisoquinoléine, (467) le chlorhydrate de l'acide
1,2,3,4-tétrahydro-3-isoquinoléinecarboxylique acide, (468) le chlorhydrate de 6,7-diméthoxy-1,2,3,4-tétrahydroisoquinoléine,
(469) le bromhydrate de 1-méthyl-6,7-dihydroxy-1,2,3,4-tétrahydroisoquinoléine, (470)
le diphosphate de primaquine, (471) le phosphate de pentaquine, (472) le chlorhydrate
de dibucaïne, (473) l'hémihydrate de chlorhydrate de 9-aminoacridine, (474) l'hémisulfate
de 3,6-diaminoacridine, (475) le chlorhydrate de 2-quinoléinethiol, (476) le pentahydrate
de sulfate de spartéine, (477) le chlorhydrate de papavérine, (478) l'hydrate de dichlorhydrate
d'émétine, (479) le monohydrate de monochlorhydrate de 1,10-phénanthroline, (480)
le trihydrate de chlorhydrate de néocuproïne, (481) la pyrimidine, (482) la 2-chloropyrimidine,
(483) la 4-phénylpyrimidine, (484) la 5-bromopyrimidine, (485) la 2,4-dichloropyrimidine,
(486) la 4,6-dichloropyrimidine, (487) la 2,4-dichloro-6-méthylpyrimidine, (488) la
6-chloro-2,4-diméthoxypyrimidine, (489) la 2-amino-4,6-diméthoxypyrimidine, (490)
la 2,4,6-trichloropyrimidine, (491) la 2,4,5,6-tétrachloropyrimidine, (492) la 1,3,4,6,7,8-hexahydro-1-méthyl-2H-pyrimido[1,2-a]pyrimidine,
(493) la 1,3,4,6,7,8-hexahydro-2H-pyrimido-[1,2-a]pyrimidine, (494) l'hexétidine,
(495) le S-(4,6-diméthylpyrimidin-2-yl)thiocarbonate de tert-butyle, (496) le S-(4,6-diméthylpyrimidin-2-yl)thiocarbonate
de 4-méthoxybenzyle, (497) la 2-aminopyrimidine, (498) la 2-amino-4-méthylpyrimidine,
(499) la 2-amino-5-nitropyrimidine, (500) la 2-amino-5-bromopyrimidine, (501) la 2-amino-4-chloro-6-méthylpyrimidine,
(502) la 2-amino-4,6-diméthylpyrimidine, (503) la 2-amino-4-hydroxy-6-méthylpyrimidine,
(504) la 2-amino-4,6-dichloropyrimidine, (505) le 2-amino-5-bromo-6-méthyl-4-pyrimidinol,
(506) la 4-aminopyrimidine, (507) la 4,5-diaminopyrimidine, (508) la 4-amino-2,6-diméthylpyrimidine,
(509) la 2,4-diamino-6-hydroxypyrimidine, (510) la 2,6-diamino-4-chloropyrimidine,
(511) l'hémihydrate de 4,6-diamino-2-mercaptopyrimidine, (512) la 2,4,6-triaminopyridine,
(513) la 5-nitroso-2,4,6-triaminopyrimidine, (514) la 4,6-dihydroxypyrimidine, (515)
la 4,6-dihydroxy-2-aminopyrimidine, (516) la 4,6-dihydroxy-2-méthylpyrimidine, (517)
la 4,6-dihydroxy-5-nitropyrimidine, (518) la 2,4-hihydroxy-5-méthylpyrimidine, (519)
2,4-dihydroxy-6-méthylpyrimidine, (520) la 2,4-dihydroxy-5,6-diméthylpyrimidine, (521)
l'hydrate d'acide 2,6-dihydroxypyrimidine-5-carboxylique, (522) la 2,6-dihydroxy-4-aminopyrimidine,
(523) la 2,4,5-trihydroxypyrimidine, (524) le 2-thiouracile, (525) le 6-amino-5-nitroso-2-thiouracile,
(526) le dihydrate d'acide folique, (527) l'hydrate de sel de calcium d'acide folinique,
(528) le chlorhydrate de 2-hydroxypyrimidine, (529) le chlorhydrate de 2-hydroxy-4-méthylpyrimidine,
(530) le chlorhydrate de 4,6-diméthyl-2-hydroxypyrimidine, (531) le chlorhydrate de
2-mercapto-4-méthylpyrimidine, (532) le monohydrate d'hémisulfate de 4,6-diaminopyrimidine,
(533) l'hydrate de sulfate de 4,5,6-triaminopyrimidine, (534) le sulfate de 4,5-diamino-6-hydroxypyrimidine,
(535) l'hémisulfate de 2,4-diamino-6-mercaptopyrimidine, (536) l'hydrate d'hémisulfate
de 2,4-diamino-6-hydroxypyrimidine, (537) le sulfate de 6-hydroxy-2,4,5-triaminopyrimidine,
(538) le sulfate de 5,6-diamino-2,4-dihydroxypyrimidine, (539) le monochlorhydrate
de N
4-(2-amino-4-pyrimidinyl)sulfanilamide, (540) le sulfate de 2,4,5,6-tétraaminopyrimidine,
(541) la 2,4-(1H,3H)-pyrimidinedione, (542) le 5-aminouracile, (543) le 5-nitrouracile,
(544) le 5-iodouracile, (545) l'hydrate de 5-(hydroxyméthyl)uracile, (546) le 5,6-dihydrouracile,
(547) le 6-amino-1-méthyluracile, (548) l'hydrate de 5,6-diamino-1,3-diméthyluracile,
(549) l'uridine, (550) la 5-méthyluridine, (551) la 5-iodouridine, (552) la thimidine,
(553) le 5-méthyl-2-thiouracile, (554) la 4-thiouridine, (555) le dihydrate de 2-thiocytidine,
(556) le monohydrate d'acide orotique, (557) l'acide hydroorotique, (558) l'acide
5-aminoorotique, (559) l'orotate de méthyle, (560) l'acide barbiturique, (561) le
trihydrate de l'acide 5-nitrobarbiturique, (562) le monohydrate de l'acide violurique,
(563) le monohydrate d'alloxane, (564) le sulfate de 4,5,6-triamino-2(1H)-pyrimidinéthione,
(565) le chlorhydrate de cyclocytidine, (566) le chlorhydrate de cytosinearabinoside,
(567) la pyridazine, (568) la phtalazine, (569) le monohydrate de 4,5-dihydro-6-méthyl-3(2H)-pyridazinone,
(570) la 3,6-dichloropyridazine, (571) la 3,4,5-trichloropyridazine, (572) la 3,6-dichloro-4-méthylpyridazine,
(573) la 3-chloro-6-méthoxypyridazine, (574) la pyrazine, (575) l'acétylpyrazine,
(576) l'aminopyrazine, (577) la 2,6-dichloropyrazine, (578) la 2,3,5-triméthylpyrazine,
(579) la tétraméthylpyrazine, (580) l'acide 5-méthyl-2-pyrazinecarboxylique, (581)
le pyrazineamide, (582) le 2,3-pyrazinedicarboxamide, (583) l'acide 4-pyridazinecarboxylique,
(584) l'acide 2,3-pyrazinedicarboxylique, (585) le monohydrate de lumazine, (586)
le monohydrate de xanthoptérine, (587) l'acide 2-quinoxazolinecarboxylique, (588)
le 2-quinoxalinol, (589) la 2,3-dihydroxyquinoxaline, (590) le méthosulfate de phénazine,
(591) la 2-azétidinone, (592) la 2-pyrrolidinone, (593) le tribromhydrate de pyrrolidone,
(594) le δ-valérolactame, (595) l'ε-caprolactame, (596) l'amino-ε-caprolactame, (597)
le N-méthylcaprolactame, (598) la 2-azacyclooctanone, (599) la 2-azacyclononanone,
(600) l'ω-thiocaprolactame, (601) le N-vinylcaprolactame, (602) la 2-azabicyclo[2.2.1]hept-5-èn-3-one,
(603) le maléimide, (604) le N-éthylmaléimide, (605) le N-butylmaléimide, (606) le
N-cyclohexylmaléimide, (607) le N-phénylmaléimide, (608) le N-benzylmaléimide, (609)
le N-hydroxymaléimide, (610) le succinimide, (611) le N-méthylsuccinimide, (612) le
2-hydroxy-N-méthylsuccinimide, (613) le N-hydroxysuccinimide, (614) le carbonate de
succinimidyle et de 2,2,2-trichloroéthyle, (615) le 2-dodécyl-N-(2,2,6,6-tétraméthyl-4-pipéridinyl)succinimide,
(616) le 2-dodécyl-N-(1,2,2,6,6-pentaméthyl-4-pipéridinyl)succinimide, (617) le N-(1-acétyl-2,2,6,6-tétraméthyl-4-pipéridinyl)-2-dodécylsuccinimide,
(618) l'α-méthyl-α-propylsuccinimide, (619) l'α-méthyl-α-phénylsuccinimide, (620)
le N-vinylphtalimide, (621) le N-éthylphtalimide, (622) le N-(triméthylsilylméthyl)phtalimide,
(623) le N-(2-bromoéthyl)phtalimide, (624) le N-(3-bromopropyl)phtalimide, (625) le
N-(4-bromobutyl)phtalimide, (626) le phtalimidoacétaldéhydediéthylacétal, (627) le
(phtalimidométhyl)phosphonate de diéthyle, (628) le N-benzylphtalimide, (629) un sel
de DBU (1,8-diazabicyclo[5.4.0]undéc-7-ène)-phtalimide (630) le DBN (1,5-diazabicyclo[4.3.0)]non-5-ène)-phtalimide
et (631) des mélanges de ceux-ci ; ou dans lequel l'agent de transparence est un composé
oxa-aza-cyclique ; ou dans lequel l'agent de transparence est choisi dans le groupe
constitué par : (A) des matériaux répondant aux formules générales :

dans lesquelles R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
14 et R
15 sont choisis chacun, indépendamment des autres, dans le groupe constitué par des
atomes d'hydrogène, des groupes alkyle, des groupes alkyle substitué, des groupes
aryle, des groupes aryle substitué, des groupes arylalkyle, des groupes arylalkyle
substitué, des groupes hydroxy, des groupes amine, des groupes imine, des groupes
ammonium, des groupes pyridine, des groupes pyridinium, des groupes éther, des groupes
aldéhyde, des groupes cétone, des groupes ester, des groupes amide, des groupes acide
carboxylique, des groupes carbonyle, des groupes thiocarbonyle, des groupes sulfate,
des groupes sulfonate, des groupes sulfure, des groupes sulfoxyde, des groupes phosphine,
des groupes phosphonium, des groupes phosphate, des groupes cyano, des groupes nitrile,
des groupes mercapto, des groupes nitroso, des atomes d'halogène, des groupes nitro,
des groupes sulfone, des groupes acyle, des groupes anhydride d'acide et des groupes
azide, dans lesquelles deux ou plus de deux des symboles R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
14 et R
15 peuvent être liés ensemble pour former un cycle ; (B) des matériaux répondant à la
formule générale :

dans laquelle R
1, R
2, R
3, R
4, R
5, et R
6 sont choisis chacun, indépendamment des autres dans le groupe constitué par des atomes
d'hydrogène, des groupes alkyle, des groupes alkyle substitué, des groupes aryle,
des groupes aryle substitué, des groupes arylalkyle, des groupes arylalkyle substitué,
des groupes hydroxy, des groupes amine, des groupes imine, des groupes ammonium, des
groupes pyridine, des groupes pyridinium, des groupes éther, des groupes aldéhyde,
des groupes cétone, des groupes ester, des groupes amide, des groupes acide carboxylique,
des groupes carbonyle, des groupes thiocarbonyle, des groupes sulfate, des groupes
sulfonate, des groupes sulfure, des groupes sulfoxyde, des groupes phosphine, des
groupes phosphonium, des groupes phosphate, des groupes cyano, des groupes nitrile,
des groupes mercapto, des groupes nitroso, des atomes d'halogène, des groupes nitro,
des groupes sulfone, des groupes acyle, des groupes anhydride d'acide et des groupes
azide, dans lesquels deux ou plus de deux des symboles R
1, R
2, R
3, R
4, R
5, et R
6 peuvent être liés ensemble pour former un cycle ; (C) des mélanges de ceux-ci ; ou
dans lequel l'agent de transparence est choisi dans le groupe constitué par (1) le
3-amino-5-méthylisoxazole, (2) le 5-amino-3-méthylisoxazole, (3) le 3,5-diméthyl-4-nitroisoxazole,
(4) le 1,2-benzisoxazole, (5) le 2,1-benzisoxazole, (6) la cyclosérine, (7) la 4-benzyl-2-méthyl-2-oxazoline,
(8) le 2-méthyl-5-phényl-2-oxazoline-4-méthanol, (9) le benzoxazole, (10) le 2-méthylbenzoxazole,
(11) le 2-chlorobenzoxazole, (12) le tétrafluoroborate de 2-chloro-3-éthylbenzeneoxazolium,
(13) la 2-oxazolidone, (14) la 3-méthyl-2-oxazolidinone, (15) la 5-chlorométhyl-2-oxazolidinone,
(16) la 4-isopropyl-2-oxazolidinone, (17) la 3-acétyl-2-oxazolidinone, (18) la 5,5-diméthyloxazolidine-2,4-dione,
(19) la 3-éthyl-2-thioxo-4-oxazolidinone, (20) la 4-méthyl-5-phényl-2-oxazolidinone,
(21) la 4-benzyl-2-oxazolidinone, (22) la 2-benzoisoxazolinone, (23) l'hydrate de
muscimol, (24) l'acide 5-méthyl-3-phényl-isoxazole-4-çarboxylique, (25) le 2-méthyl-5-phényl-2-oxazoline-4-méthanol,
(26) le sulfaméthoxazole, (27) le sulfisoxazole, (28) le N'-(4,5-diméthyloxazol-2-yl)sulfanilamide,
(29) la chlorzoxazone, (30) l'iodure de 3,3'-diméthyloxacarbocyanine, (31) le 3'-sulfonate
de 2-éthyl-5-phénylisoxazolium, (32) le perchlorate de 2-tert-butyl-5-méthylisoxazolium,
(33) l'hydrate de chlorhydrate de 5-phényl-2-(4-pyridyl)oxazole, (34) le sel tosylate
de méthyle de 5-phényl-2-(4-pyridyl)oxazole, (35) la 4-aminomorpholine, (36) le 4-morpholinecarbonitrile,
(37) le 4-morpholinepropionitrile, (38) la 4-formylmorpholine, (39) la 4-acétylmorpholine,
(40) la 4-(2-hydroxyéthyl)morpholine, (41) le 3-morpholino-1,2-propanediol, (42) la
4-(3-aminopropyl)morpholine, (43) le 1-morpholino-1-cyclopentène, (44) le 1-morpholino-1-cyclohexène,
(45) le 1-morpholino-1-cycloheptène, (46) la 4-phénylmorpholine, (47) la 4-morpholinoaniline,
(48) le phosphoromorpholinochloridate de 2,2,2-tribromoéthyle, (49) la 1-(morpholinocarbonylméthyl)pipérazine,
(50) le 1,3-dimorpholine-2-nitropropane, (51) l'hémicholinium-3, (52) l'hémicholinium-15,
(53) le chlorure de 2-méthoxy-4-morpholinobenzènediazonium, le chlorure de zinc, (54)
la fomocaïne, (55) la 4-morpholinobenzophénone, (56) la 4,4'-éthylène-bis(2,6-morpholinedione),
(57) la N,N'-dicyclohexyl-4-morpholinecarboxamidine, (58) la 1-cyclohexyl-3-(2-morpholinoéthyl)-2-thiourée,
(59) la 4-morpholinoacétophénone, (60) le chlorhydrate de 4-(2-chloroéthyl)morpholine,
(61) l'acide 4-morpholineéthanesulfonique, (62) l'acide 4-morpholinepropanesulfonique,
(63) l'acide β-hydroxymorpholinepropanesulfonique, (64) le chlorhydrate de [N-(aminoiminométhyl)-4-morpholinecarboximidamide],
(65) un composé d'acide 4-morpholinecarbodithioique et de morpholine, (66) le monohydrate
du chlorhydrate de 2,5-diméthyl-4-(morpholinométhyl)phénol, (67) le méthop-toluènesulfonate
de 1-cyclohexyl-3-(2-morpholinoéthyl)carbodiimide, (68) l'hémicholinium-3-[2,2'-(4,4'-biphènylène)bis(bromure
de 2-hydroxy-4,4-diméthylmorpholinium]), (69) l'hémicholinium-15-[bromure de 4,4-diméthyl-2-hydroxy-2-phényl-morpholinium],
(70) le 1-aza-12-couronne-4, (71) le 1-aza-15-couronne-5, (72) le 1-aza-18 couronne-6,
(73) le 1,4,10-trioxa-7,13-diazacyclopentadécane, (74) le 1,4,10,13-tétraoxa-7,16-diazacyclooctadécane,
(75) le N,N'-dibenzyl-1,4,10,13-tétraoxa-7,16-diazacyclooctadécane, (76) le 4,7,13,18-tétraoxa-1,10-diazabicyclo[8.5.5]éicosane,
(77) le 4,7,13,16,21-pentaoxa-1,10-diazabicyclo[8.5.5]tricosane, (78) le 4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane,
(79) le 5,6-benzo-4,17,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane, et
(80) des mélanges de ceux-ci ; ou dans lequel l'agent de transparence est un composé
oxacyclique ; ou dans lequel l'agent de transparence est choisi dans le groupe constitué
par : (A) des matériaux répondant à la formule générale :

dans laquelle la partie courbe de la structure représente une chaîne hydrocarbonée
ou une chaîne hydrocarbonée substituée, dans laquelle deux ou plus de deux substituants
peuvent être liés ensemble pour former un cycle ; (B) des matériaux répondant aux
formules générales :

dans lesquelles R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
14, R
15, R
16, R
17, R
18, R
19, R
20, R
21, R
22, R
23, R
24, R
25, R
26, R
27, et R
28 sont choisis chacun, indépendamment des autres, dans le groupe constitué par des
atomes d'hydrogène, des groupes alkyle, des groupes alkyle substitué, des groupes
aryle, des groupes aryle substitué, des groupes arylalkyle, des groupes arylalkyle
substitué, des groupes hydroxy, des groupes amine, des groupes imine, des groupes
ammonium, des groupes pyridine, des groupes pyridinium, des groupes éther, des groupes
aldéhyde, des groupes cétone, des groupes ester, des groupes amide, des groupes acide
carboxylique, des groupes carbonyle, des groupes thiocarbonyle, des groupes sulfate,
des groupes sulfonate, des groupes sulfure, des groupes sulfoxyde, des groupes phosphine,
des groupes phosphonium, des groupes phosphate, des groupes cyano, des groupes nitrile,
des groupes mercapto, des groupes nitroso, des atomes d'halogène, des groupes nitro,
des groupes sulfone, des groupes acyle, des groupes anhydride d'acide et des groupes
azide, dans lesquelles deux ou plus de deux des symboles R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, R
12, R
13, R
14, R
15, R
16, R
17, R
18, R
19, R
20, R
21, R
22, R
23, R
24, R
25, R
26, R
27, et R
28 peuvent être liés ensemble pour former un cycle ; (C) des matériaux répondant à la
formule générale :

dans laquelle la partie courbe de la structure représente une chaîne hydrocarbonée
ou une chaîne hydrocarbonée substituée, dans laquelle deux ou plus de deux substituants
peuvent être liés ensemble pour former un cycle ; (D) des matériaux répondant aux
formules générales :

dans lesquelles R
1, R
2, R
3, R
4, R
5, R
6, R
7, et R
8 sont choisis chacun, indépendamment des autres, dans le groupe constitué par des
atomes d'hydrogène, des groupes alkyle, des groupes alkyle substitué, des groupes
aryle, des groupes aryle substitué, des groupes arylalkyle, des groupes arylalkyle
substitué, des groupes hydroxy, des groupes amine, des groupes imine, des groupes
ammonium, des groupes pyridine, des groupes pyridinium, des groupes éther, des groupes
aldéhyde, des groupes cétone, des groupes ester, des groupes amide, des groupes acide
carboxylique, des groupes carbonyle, des groupes thiocarbonyle, des groupes sulfate,
des groupes sulfonate, des groupes sulfure, des groupes sulfoxyde, des groupes phosphine,
des groupes phosphonium, des groupes phosphate, des groupes cyano, des groupes nitrile,
des groupes mercapto, des groupes nitroso, des atomes d'halogène, des groupes nitro,
des groupes sulfone, des groupes acyle, des groupes anhydride d'acide et des groupes
azide, dans lesquelles deux ou plus de deux des symboles R
1, R
2, R
3, R
4, R
5, R
6, R
7, et R
8 peuvent être liés ensemble pour former un cycle ; (E) des matériaux répondant aux
formules générales :

dans lesquelles les parties courbes des structures représentent une chaîne hydrocarbonée
ou une chaîne hydrocarbonée substituée, dans lesquelles deux ou plus de deux substituants
peuvent être liés ensemble pour former un cycle ; (F) des matériaux répondant à la
formule générale :

dans laquelle R
1, R
2, R
3, R
4, R
5, et R
6 sont choisis chacun, indépendamment des autres, dans le groupe constitué par des
atomes d'hydrogène, des groupes alkyle, des groupes alkyle substitué, des groupes
aryle, des groupes aryle substitué, des groupes arylalkyle, des groupes arylalkyle
substitué, des groupes hydroxy, des groupes amine, des groupes imine, des groupes
ammonium, des groupes pyridine, des groupes pyridinium, des groupes éther, des groupes
aldéhyde, des groupes cétone, des groupes ester, des groupes amide, des groupes acide
carboxylique, des groupes carbonyle, des groupes thiocarbonyle, des groupes sulfate,
des groupes sulfonate, des groupes sulfure, des groupes sulfoxyde, des groupes phosphine,
des groupes phosphonium, des groupes phosphate, des groupes cyano, des groupes nitrile,
des groupes mercapto, des groupes nitroso, des atomes d'halogène, des groupes nitro,
des groupes sulfone, des groupes acyle, des groupes anhydride d'acide et des groupes
azide, dans laquelle deux ou plus de deux des symboles R
1, R
2, R
3, R
4, R
5, et R
6 peuvent être liés ensemble pour former un cycle ; et (G) des mélanges de ceux-ci
; ou dans lequel l'agent de transparence est choisi dans le groupe constitué par (1)
la γ-butyrolactone, (2) la γ-valérolactone, (3) la γ-caprolactone, (4) la lactone
γ-octanoïque, (5) la lactone γ-nonanoique, (6) la γ-décanolactone, (7) la γ-lactone
undécanoïque, (8) la γ-phényl-γ-butyrolactone, (9) l'α-carbéthoxy-γ-phénylbutyrolactone,
(10) la 2-coumaranone, (11) la β,β-diméthyl-γ-(hydroxyméthyl) -γ-butyrolactone, (12)
la γ-éthoxycarbonyl-γ-butyrolactone, (13) la 5-(hydroxyméthyl)-2(5H)-furanone, (14)
la dihydro-4,4-diméthyl-2,3-furandione, (15) la 2,5-diméthyl-4-hydroxy-3(2H)-furanone,
(16) la (β-hydroxy-β-méthyl-δ-valéro)lactone mévalonique, (17) la δ-décanolactone,
(18) la δ-lactone undécanoïque, (129) la δ-dodécanolactone, (20) la ω-lactone undécanoïque,
(21) la oxacyclotridécan-2-one, (22) la ω-pentadécalactone, (23) l'hydrindantine (2,2'-dihydroxy-2,2'-biindan-1,1'3,3'-tétrone),
(24) le dihydrate d'hydrindantine, (25) la 2-oxépanone, (26) la 4H-pyran-2-one, (27)
le coumalate de méthyle, (28) le 2-oxo-2H-pyran-3-carboxylate de méthyle, (29) la
4,6-diméthyl-a-pyrone, (30) la 4-méthoxy-6-méthyl-2H-pyran-2-one, (31) la 3,6-dihydro-4,6,6-triméthyl-2H-pyran-2-one,
(32) la 3,4-dihydro-6-méthyl-2H-pyran-2-one, (33) la 3-acétylcoumarine, (34) la 6-méthylcoumarine,
(35) la 7-éthoxycoumarine, (36) le 3-coumarinecarboxylate d'éthyle, (37) la 7-diéthylamino-4-méthylcoumarine,
(38) la dihydrocoumarine, (39) la 3-bromo-2-coumaranone, (40) la patuline, (41) la
4H-pyran-4-one, (42) la 2-éthyl-3-hydroxy-4H-pyran-4-one, (43) le butopyronoxyle (3,4-dihydro-2,2-diméthyl-4-oxo-2H-pyran-6-carboxylate
de butyle, (44) l'acide déshydroacétique, (45) la 4-chromone, (46) la 4-chromanone,
(47) le 4-chromanol, (48) la 6,7-diméthoxy-2,2-diméthyl-4-chromanone, (49) la 3-isochromanone,
(50) la 6,7-diméthoxy-3-isochromanone, (51) le 6-éthyl-4-oxo-4H-1-benzopyran-3-carbonitrile,
(52) le 6-éthyl-4-oxo-4H-1-benzopyran-3-carboxaldéhyde, (53) le 6-isopropyl-4-oxo-4H-1-benzopyran-3-carbonitrile,
(54) le 6-isopropyl-4-oxo-4H-1-benzopyran-3-carboxaldéhyde, (55) l'anhydride maléique,
(56) l'anhydride bromomaléique, (57) l'anhydride citraconique, (58) l'anhydride 2,3-diméthylmaléique,
(59) l'anhydride dichloromaléique, (60) l'anhydride cis-aconitique, (61) l'anhydride
itaconique, (62) l'anhydride méthylsuccinique, (63) l'anhydride acétylmercaptosuccinique,
(64) l'anhydride 2,2-diméthylsuccinique, (65) l'anhydride phénylsuccinique, (66) l'anhydride
2-octèn-1-ylsuccinique, (67) l'anhydride 2-dodécèn-1-ylsuccinique, (68) l'anhydride
2-octadécèn-1-yl-succinique, (69) la 3-oxabicyclo[3.1.0]-hexane-2,4-dione, (70) l'anhydride
diglycolique, (71) l'anhydride glutarique, (72) l'anhydride 3-méthylglutarique, (73)
l'anhydride 2,2-diméthylglutarique, (74) l'anhydride 3,3-tétraméthylèneglutarique,
(75) l'anhydride 1-cyclopentène-1,2-dicarboxylique, (76) l'anhydride 3,4,5,6-tétrahydrophtalique,
(77) l'anhydride cis-1,2-cyclohexanedicarboxylique, (78) l'anhydride hexahydro-4-méthylphtalique,
(79) l'anhydride méthyl-5-norbornène-2,3-dicarboxylique, (80) l'anhydride 2,3-pyridinecarboxylique,
(81) l'anhydride 3,4-pyridinecarboxylique, (82) le furfurylmercaptan, (83) le thioacétate
de S-furfuryle, (84) le sulfure de furfuryle, (85) le disulfure de furfuryle et de
méthyle, (86) le disulfure de furfuryle, (87) le dimère de glycolaldéhyde, (88) la
6,7-dihydrocyclopenta1,3-dioxin-5(4H)-one, (89) la (2R,6R)-ter-butyl-6-méthyl-1,3-dioxan-4-one,
(90) la 2,2-diméthyl-1,3-dioxane-4,6-dione, (91) la 3,6-diméthyl-1,4-dioxane-2,5-dione,
(92) la 2,2,6-triméthyl-4H-1,3-dioxin-4-one, (93) la 2,2,5-triméthyl-1,3-dioxane-4,6-dione,
(94) la 5-bromo-2,2,5-triméthyl-1,3-dioxane-4,6-dione, (95) le 1,3-dioxane-5,5-diméthanol,
(96) le 1,3,5-trioxane, (97) la 1,6-dioxaspiro[4.4]nonane-2,7-dione, (98) la 1,4-dioxaspiro[4.5]décan-2-one,
(99) le 1,7-dioxaspiro[5.5]undécane, (100) le 2,4,8,10-tétraoxaspiro[5.5]undécane,
(101) le 3,9-divinyl-2,4,8-tétraoxaspiro[5.5]undécane, (102) le 2,2-pentaméthylène-1,3-dioxalane,
(103) le 2-phényl-1,3-dioxalane, (104) le 1,4-cyclohexanedionemonoéthylèneacétal,
(105) le 1,4-cyclohexanedionebis(éthylèneacétal), (106) le 1,4-cyclohexanedionemono-2,2-diméthyltriméthylèneacétal,
(107) le pipéronal, (108) l'acétate de pipéronyle, (109) l'alcool pipéronylique, (110)
le pipéronylnitrile, (111) la pipéronylamine, (112) le 6-nitropipéronal, (113) l'alcool
6-nitropipéronylique, (114) la 3',4'-(méthylènedioxy)acétophénone, (115) la 3,4-(méthylènedioxy)aniline,
(116) le 2,3-(méthylènedioxy)benzaldéhyde, (117) le 3,4-(méthylènedioxy)phénylacétonitrile,
(118) le 3,4-(méthylènedioxy)toluène et (119) des mélanges de ceux-ci ; ou dans lequel
l'agent de transparence est un éther couronne ; ou dans lequel l'agent de transparence
est choisi dans le groupe constitué par le 1,4,7,10-tétraoxacyclododécane (12-couronne-4),
(2) le 2-(hydroxyéthyl)-12-couronne-4, (3) le 2-(aminoéthyl)-12-couronne-4, (4) le
benzo-12-couronne-4, (5) le 1,4,7,10,13-pentaoxacyclododécane (15-couronne-5), (6)
le 2-(hydroxyéthyl)-15-couronne-5, (7) le 2-(aminoéthyl)-15-couronne-5, (8) le benzo-15-couronne
5, (9) le 4'-aminobenzo-15-couronne-5, (10) le 4'-formylbenzo-15-couronne-5, (11)
le 4'-nitrobenzo-15-couronne-5, (12) le pimélate de bis[(benzo-15-couronne-5)-15-ylméthyle],
(13) le 1,4,7,10,13,16-hexaoxacyclooctadécane (18-couronne-6), (14) le 2-(aminoéthyl)-18-couronne-6,
(15) le benzo-18-couronne-6, (16) le 4'-bromobenzo-18-couronne-6, (17) le dibenzo-18-couronne-6,
(18) le di-tert-butyldibenzo-18-couronne-6, (19) le cis-dicyclohexane-18-couronne-6,
(20) le dibenzo-24-couronne-8, (21) le dicyclohexano-24-couronne-8, (22) le dibenzo-30-couronne-10,
et (23) des mélanges de ceux-ci ; ou dans lequel l'agent de transparence est un hydrocarbure
cyclique ; ou dans lequel l'agent de transparence est choisi dans le groupe constitué
par : (A) des matériaux répondant aux formules générales :

dans lesquelles R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, et R
12 sont choisis, chacun indépendamment des autres, dans le groupe constitué par des
atomes d'hydrogène, des groupes alkyle, des groupes alkyle substitué, des groupes
aryle, des groupes aryle substitué, des groupes arylalkyle, des groupes arylalkyle
substitué, des groupes hydroxy, des groupes amine, des groupes imine, des groupes
ammonium, des groupes pyridine, des groupes pyridinium, des groupes éther, des groupes
aldéhyde, des groupes cétone, des groupes ester, des groupes amide, des groupes acide
carboxylique, des groupes carbonyle, des groupes thiocarbonyle, des groupes sulfate,
des groupes sulfonate, des groupes sulfure, des groupes sulfoxyde, des groupes phosphine,
des groupes phosphonium, des groupes phosphate, des groupes cyano, des groupes nitrile,
des groupes mercapto, des groupes nitroso, des atomes d'halogène, des groupes nitro,
des groupes sulfone, des groupes acyle, des groupes anhydride d'acide et des groupes
azide, dans lesquelles deux ou plus de deux des symboles R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11 et R
12 peuvent être liés ensemble pour former un cycle ; (B) des matériaux répondant à la
formule générale :

dans laquelle R
1, R
2, R
3, R
4, R
5 et R
6 sont choisis, chacun indépendamment des autres, dans le groupe constitué par des
atomes d'hydrogène, des groupes alkyle, des groupes alkyle substitué, des groupes
aryle, des groupes aryle substitué, des groupes arylalkyle, des groupes arylalkyle
substitué, des groupes hydroxy, des groupes amine, des groupes imine, des groupes
ammonium, des groupes pyridine, des groupes pyridinium, des groupes éther, des groupes
aldéhyde, des groupes cétone, des groupes ester, des groupes amide, des groupes acide
carboxylique, des groupes carbonyle, des groupes thiocarbonyle, des groupes sulfate,
des groupes sulfonate, des groupes sulfure, des groupes sulfoxyde, des groupes phosphine,
des groupes phosphonium, des groupes phosphate, des groupes cyano, des groupes nitrile,
des groupes mercapto, des groupes nitroso, des atomes d'halogène, des groupes nitro,
des groupes sulfone, des groupes acyle, des groupes anhydride d'acide et des groupes
azide, dans laquelle deux ou plus de deux des symboles R
1, R
2, R
3, R
4, R
6 et R
6 peuvent être liés ensemble pour former un cycle ; (C) des matériaux répondant à la
formule générale :

dans lesquelles R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, et R
10, sont choisis, chacun indépendamment des autres, dans le groupe constitué par des
atomes d'hydrogène, des groupes alkyle, des groupes alkyle substitué, des groupes
aryle, des groupes aryle substitué, des groupes arylalkyle, des groupes arylalkyle
substitué, des groupes hydroxy, des groupes amine, des groupes imine, des groupes
ammonium, des groupes pyridine, des groupes pyridinium, des groupes éther, des groupes
aldéhyde, des groupes cétone, des groupes ester, des groupes amide, des groupes acide
carboxylique, des groupes carbonyle, des groupes thiocarbonyle, des groupes sulfate,
des groupes sulfonate, des groupes sulfure, des groupes sulfoxyde, des groupes phosphine,
des groupes phosphonium, des groupes phosphate, des groupes cyano, des groupes nitrile,
des groupes mercapto, des groupes nitroso, des atomes d'halogène, des groupes nitro,
des groupes sulfone, des groupes acyle, des groupes anhydride d'acide et des groupes
azide, dans lesquelles deux ou plus de deux des symboles R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, et R
10 peuvent être liés ensemble pour former un cycle ; (D) des matériaux répondant aux
formules générales :

dans lesquelles R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11, et R
12, sont choisis, chacun indépendamment des autres, dans le groupe constitué par des
atomes d'hydrogène, des groupes alkyle, des groupes alkyle substitué, des groupes
aryle, des groupes aryle substitué, des groupes arylalkyle, des groupes arylalkyle
substitué, des groupes hydroxy, des groupes amine, des groupes imine, des groupes
ammonium, des groupes pyridine, des groupes pyridinium, des groupes éther, des groupes
aldéhyde, des groupes cétone, des groupes ester, des groupes amide, des groupes acide
carboxylique, des groupes carbonyle, des groupes thiocarbonyle, des groupes sulfate,
des groupes sulfonate, des groupes sulfure, des groupes sulfoxyde, des groupes phosphine,
des groupes phosphonium, des groupes phosphate, des groupes cyano, des groupes nitrile,
des groupes mercapto, des groupes nitroso, des atomes d'halogène, des groupes nitro,
des groupes sulfone, des groupes acyle, des groupes anhydride d'acide et des groupes
azide, dans lesquelles deux ou plus de deux des symboles R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, R
11,et R
12 peuvent être liés ensemble pour former un cycle ; (E) des matériaux répondant à la
formule générale :

dans laquelle R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, R
10, sont choisis chacun, indépendamment des autres, dans le groupe constitué par des
atomes d'hydrogène, des groupes alkyle, des groupes alkyle substitué, des groupes
aryle, des groupes aryle substitué, des groupes arylalkyle, des groupes arylalkyle
substitué, des groupes hydroxy, des groupes amine, des groupes imine, des groupes
ammonium, des groupes pyridine, des groupes pyridinium, des groupes éther, des groupes
aldéhyde, des groupes cétone, des groupes ester, des groupes amide, des groupes acide
carboxylique, des groupes carbonyle, des groupes thiocarbonyle, des groupes sulfate,
des groupes sulfonate, des groupes sulfure, des groupes sulfoxyde, des groupes phosphine,
des groupes phosphonium, des groupes phosphate, des groupes cyano, des groupes nitrile,
des groupes mercapto, des groupes nitroso, des atomes d'halogène, des groupes nitro,
des groupes sulfone, des groupes acyle, des groupes anhydride d'acide et des groupes
azide, dans laquelle deux ou plus de deux des symboles R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, et R
10, peuvent être liés ensemble pour former un cycle ; (F) des matériaux répondant aux
formules générales :

dans laquelle R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9 et R
10, sont choisis chacun, indépendamment des autres, dans le groupe constitué par des
atomes d'hydrogène, des groupes alkyle, des groupes alkyle substitué, des groupes
aryle, des groupes aryle substitué, des groupes arylalkyle, des groupes arylalkyle
substitué, des groupes hydroxy, des groupes amine, des groupes imine, des groupes
ammonium, des groupes pyridine, des groupes pyridinium, des groupes éther, des groupes
aldéhyde, des groupes cétone, des groupes ester, des groupes amide, des groupes acide
carboxylique, des groupes carbonyle, des groupes thiocarbonyle, des groupes sulfate,
des groupes sulfonate, des groupes sulfure, des groupes sulfoxyde, des groupes phosphine,
des groupes phosphonium, des groupes phosphate, des groupes cyano, des groupes nitrile,
des groupes mercapto, des groupes nitroso, des atomes d'halogène, des groupes nitro,
des groupes sulfone, des groupes acyle, des groupes anhydride d'acide et des groupes
azide, dans lesquelles deux ou plus de deux des symboles R
1, R
2, R
3, R
4, R
5, R
6, R
7, R
8, R
9, et R
10 peuvent être liés ensemble pour former un cycle ; (G) des matériaux répondant à la
formule générale :

dans laquelle la partie courbe de la structure représente une chaîne hydrocarbonée
ou une chaîne hydrocarbonée substituée, dans laquelle deux ou plus de deux substituants
peuvent être liés ensemble pour former un cycle ; et (H) des mélanges de ceux-ci ;
ou dans lequel l'agent de transparence est choisi dans le groupe constitué par (1)
le norbornane, (2) le 2-norbornanecarbonitrile, (3) le 2-norbornaneméthanol, (4) le
3-méthyl-2-norbornaneméthanol, (5) le camphène, (6) l'alcool fenchylique, (7) le thiocamphre,
(8) le norbornène, (9) le 5-norbornène-2-carbonitrile, (10) le 5-norbornène-2-carboxaldéhyde,
(11) le 5-norbornène-2-méthanol, (12) le 5-norbornène-2,2-diméthanol, (13) le 2-benzoyl-5-norbornène,
(14) la 2-norbornanone, (15) la 3-chloro-2-norbornanone, (16) la fenchone, (17) le
3-(trifluoroacétyl)camphre, (18) le 3-heptafluorobutyrylcamphre, (19) le 3-bromocamphre,
(20) le 9,10-dibromocamphre, (21) le 3,9,10-tribromocamphre, (22) le dicyclopentadiène,
(23) le dimère de méthylcyclopentadiène, (24) le tricyclo[5.2.1]décane, (25) le 4,8-bis(hydroxyméthyl)tricyclo[5.2.1.0
2,6]décane, (26) le 8-cétotricyclo[5.2.1.0
2,6]décane, (27) la 3,4-diméthoxy-3-cyclobutène-1,2-dione, (28) la 3,4-diéthoxy-3-cyclobutène-1,2-dione,
(29) la 3,4-diisopropoxy-3-cyclobutène-1,2-dione, (30) la 3,4-dibutoxy-3-cyclobutène-1,2-dione,
(31) l'acide 3-méthyl-2-(nitrométhyl)-5-oxocyclopentaneacétique, (32) la 3-éthyl-2-hydroxy-2-cyclopentène-1-one,
(33) le 4-méthoxy-2-oxo-3-cyclopentène-1-carboxylate de méthyle, (34) la 3,3a,6,6a-tétrahydro-2H-cyclopenta[b]furan-2-one,
(35) la 3a,4,5,6a-hexahydro-5-hydroxy-4(hydroxyméthyl)-2H-cyclopenta[b]furan-2-one,
(36) la 3-méthyl-1,2-cyclopentanedione, (37) le monohydrate de 4-hydroxy-5-méthyl-4-cyclopentène-1,3-dione,
(38) la 2,4,4-triméthylcyclohexèn-1-one, (39) le 6-méthyl-2-oxo-3-cyclohexène-1-carboxylate
d'éthyle, (40) le 4-hydroxy-6-méthyl-2-oxo-3-cyclohexène-1-carboxylate d'éthyle, (41)
la 5-(1-acétoxy-1-méthyléthyl)-2-méthyl-2-cyclohéxène-1-one, (42) la thymoquinone,
(43) la 2,6,6-triméthyl-2-cyclohexène-1,4-dione, (44) l'indane, (45) le 1-indanol,
(46) le 2-indanol, (47) la 1-indanone, (48) la 2-indanone, (49) la 2-acétyl-1-tétralone,
(50) la 4-méthyl-1-tétralone, (51) la 5,7-diméthyl-1-tétralone, (52) la 6,7-diméthoxy-1-tétralone,
(53) la 1-méthyl-2-tétralone, (54) la 6,7-diméthoxy-2-tétralone, (55) la cyclohexanone,
(56) la cycloheptanone, (57) la cyclooctanone, (58) la cyclononanone, (59) la cyclodécanone,
(60) la cycloundécanone, (61) la cyclododécanone, (62) la cyclotridécanone, (63) la
cyclopentadécanone, (64) la 2-acétylcyclohexanone, (65) la 2-allylcyclohexanone, (66)
la 2-phénylcyclohexanone, (67) la cyclohexanedione, (68) la 2-acétyl-1,3-cyclohexanedione,
(69) la 4,4-diméthyl-1,3-cyclohexanedione, (70) la 2-acétyl-1,3-cyclopentanedione,
(71) la 3,3,5,5-tétraméthyl-1,2-cyclopentanedione, (72) la bicyclo[3.2.1]octan-2-one,
(73) le 7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylate d'endo-diméthyle, (74) le cinéole,
(75) le bicyclo[2.2.2]oct-5-ène-2,3-diméthanol, (76) la tropone, (77) la tropolone,
(78) l'oxyde de cyclooctène, (79) le 1,2,5,6-diépoxycyclooctane, (80) la 9-méthyl-Δ
5(10)-octalin-1,6-dione, (81) la cis-bicyclo[3.3.0]octane-3,7-dione, (82)l'azulène, (83)
la 1-benzosubérone, (84) le 1,5,9-cyclododécatriène, (85) l'époxyde de cyclododécane,
(86) la 2,3-cyclododécénopyridine, (87) le 1,2,5,6,9,10-hexabromocyclododécane, (88)
la 8-cyclohexadécène-1-one, (89) la bicyclo[10.3.0]pentadéc-12(1)-èn-13-one, (90)
la 1,4,4a,8a-tétrahydro-endo-1,4-méthanonaphtalène-5,8-dione, et (91) des mélanges
de ceux-ci ; ou dans lequel l'agent de transparence est une thiourée ; ou dans lequel
l'agent de transparence est une sulfone ; ou dans lequel l'agent de transparence est
un composé thiocyclique ; ou dans lequel l'agent de transparence est choisi dans le
groupe constitué par des sulfites, des dérivés de sulfites, des sulfures, des dérivés
de sulfures, des composés de soufre quaternaire, des dérivés de soufre quaternaire,
et des mélanges de ceux-ci ; ou dans lequel l'agent de transparence est un composé
thia-aza-cyclique ; ou dans lequel l'agent de transparence est choisi dans le groupe
constitué par (1) la 1-allyl-2-thiourée, (2) la 1-méthallyl-3-méthyl-2-thiourée, (3)
le 4-allyl-3-thiosemicarbazide, (4) la 1,3-diéthyl-2-thiourée, (5) la 1,3-dibutyl-2-thiourée,
(6) la 1-benzyl-3-méthyl-2-thiourée, (7) la 1,1,3,3-tétraméthyl-2-thiourée, (8) le
2-imino-4-thiobiuret, (9) la 1-allyl-3-(2-hydroxyéthyl)-2-thiourée, (10) le bromhydrate
de bromure de S-(2-aminoéthyl)isothiouronium, (11) le monohydrate de S,S-diphénylsulfillimine,
(12) la méthylsulfone, (13) l'éthylsulfone, (14) la butylsulfone, (15) la butadiènesulfone,
(16) la tétraméthylènesulfone, (17) la 1,4-butanesulfone, (18) le sulfate cyclique
de 1,4-butanediol, (19) la benzylsulfone, (20) la phénylsulfone, (21) la phénylvinylsulfone,
(22) la phénylstyrènesulfone, (23) la phényl-2-(triméthylsilyl)méthylsulfone, (24)
la phényl-2-(triméthylsilyl)éthylsulfone, (25) la phényl-2-(triméthylsilyl)éthynylsulfone,
(26) la 4-(fluorophényl)sulfone, (27) la 4-(fluorophényl)méthyl-sulfone, (28) la chlorométhylphénylsulfone,
(29) la chlorométhyl-p-tolylsulfone, (30) la 2-chloroéthylphénylsulfone, (31) la méthylthiométhylphénylsulfone,
(32) la méthylthiométhyl-p-tolylsulfone, (33) le 2-(phénylsulfonyl)tétrahydropyrane,
(34) le 1-(phénylsulfonyl)indole, (35) le 1- (p-toluènesulfonyl)imidazole, (36) la
1-(p-tosyl)-3,4,4-triméthylimidazolidine, (37) la 4-(p-tosylsulfonyl)hexahydro-1,4-thiazépine,
(38) le thionaphtène, (39) le 4-céto-4,5,6,7-tétrahydrothianaphtène, (40) le 2,2'-bithiophène,
(41) le 2,2':5',2"-terthiophène, (42) la N-acétylhomocystéinethiolactone, (43) la
tétrahydrothiopyran-4-one, (44) la thiochroman-4-one, (45) le thiochroman-4-ol, (46)
l'acide thioctique, (47) le 1,3-dithiolane-2-carboxylate d'éthyle, (48) la 3H-1,2-benzodithiol-3-one,
(49) le 1,3-dithiane, (50) le 2-phényl-1,3-dithiane, (51) le 1,3-dithiane-2-carboxylate
d'éthyle, (52) la 5,6-dihydro-5-méthyl-4H-1,3,5-dithiazine, (53) le 1,4-dithiane,
(54) le 2,5-dihydroxy-2,5-diméthyl-1,4-dithiane, (55) le 1,5-dithiacyclooactan-3-ol,
(56) le 1,4-dithiaspiro-[45]-décan-8-ol, (57) le 1,3,5-trithiane, (58) le 1,4,7-trithiacyclononane,
(59) le 1,4,7-trithiacyclodécane, (60) le 1,4,7,10-tétrathiacyclododécane, (61) le
3,6,9,14-tétrathiabicyclo[9.2.1]tétradéca-11,13-diène, (62) le 1,4,8,1-tétrathiacyclotétradécane,
(63) le 1,5,9,13-tétrathiocyclohexadécane, (64) le 1,5,9,13-tétrathiacyclohexadécane-3,11-diol,
(65) le 1,4,7,10,13-pentathiacyclopentadécane, (66) le 1,4,7,10,13,16-hexathiacyclooctadécane,
(67) le 1,5,9,13,17,21-hexathiacyclotétracosane-3,11,19-triol, (68) le 1,4,7,10,13,16,19,22-octathiacyclotétracosane,
(69) le 1,4,8,11,15,18,22,25-octathiacyclooctacosane, (70) le 1,4,7,10,13,16,19,22,25-nonathiacycloheptacosane,
(71) le sulfite de diméthyle, (72) le sulfite de diéthyle, (73) le sulfite de sodium,
(74) le disulfure d'allyle, (75) le disulfure d'aminophényle, (76) le disulfure de
benzyle, (77) le sulfure de benzyle et de phényle, (78) le méthylsulfate de triméthylsulfonium,
(79) l'iodure de (2-chloroéthyl)diméthylsulfonium, (80) le tétrafluoroborate de 3-(chloropropyl)diphénylsulfonium,
(81) l'iodure de trimethylsulfonium, (82) l'iodure de triméthylsulfoxonium, (83) le
chlorure de triméthyl- sulfoxonium, (84) le chlorure de triphénylméthane-sulfényle,
(85) le bromure de diméthyl- (2-méthoxy-5-nitrobenzyl) sulfonium, (86) le perchlorate
de thionine, (87) le p-xylylènebis(chlorure de tétrahydrothiophéneum), (88) le difluorotriméthylsilicate
de tris(diméthylamino)sulfonium, (89) le trifluorométhylate de tris(diméthylamino)sulfonium,
(90) le chlorure de (3-amino-3-carboxypropyl)diméthylsulfonium, et (91) des mélanges
de ceux-ci ; ou dans lequel l'agent de transparence est un agent répondant à l'une
des formules générales suivantes :

dans lesquelles R
1, R
2, R
3, R
4, R
5, R
6 et R
7 sont choisis chacun, indépendamment des autres, dans le groupe constitué par des
atomes d'hydrogène, des groupes alkyle, des groupes alkyle substitué, des groupes
aryle, des groupes aryle substitué, des groupes arylalkyle, des groupes arylalkyle
substitué, des groupes hydroxy, des groupes amine, des groupes imine, des groupes
ammonium, des groupes pyridine, des groupes pyridinium, des groupes éther, des groupes
aldéhyde, des groupes cétone, des groupes ester, des groupes amide, des groupes acide
carboxylique, des groupes carbonyle, des groupes thiocarbonyle, des groupes sulfate,
des groupes sulfonate, des groupes sulfure, des groupes sulfoxyde, des groupes phosphine,
des groupes phosphonium, des groupes phosphate, des groupes cyano, des groupes nitrile,
des groupes mercapto, des groupes nitroso, des atomes d'halogène, des groupes nitro,
des groupes sulfone, des groupes acyle, des groupes anhydride d'acide et des groupes
azide, dans lesquelles deux ou plus de deux des symboles R
1, R
2, R
3, R
4, R
5, R
6, et R
7, peuvent être liés ensemble pour former un cycle ; ou dans lequel l'agent de transparence
est choisi dans le groupe constitué par (1) la 2-amino-2-thiazoline, (2) le 2-aminothiazole,
(3) le 2-amino-4-méthylthiazole, (4) le 2-amino-4-méthylthiazole, (5) l'acide 2-amino-4-thiazolacétique,
(6) le 2-acétamido-4-méthylthiazole, (7) le 2-acétylthiazole, (8) le 5-acétyl-2,4-diméthylthiazole,
(9) le 4-méthyl-5-vinylthiazole, (10) le 2-amino-4-phényl-5-tétradécylthiazole, (11)
la 2,4-thiazolidinedione, (12) la 3-aminorhodanine, (13) la 3-méthylrhodanine, (14)
la 3-éthylrhodanine, (15) la 3-allylrhodanine, (16) la 3-hydroxy-4-méthyl-2(3H)-thiazoléthione,
(17) le benzothiazole, (18) le 2-méthylbenzothiazole, (19) le 2-(méthylthio)benzothiazole,
(20) le 2-amino-4-méthylbenzothiazole, (21) la 3-méthylbenzothiazole-2-thione, (22)
le 2,1,3-benzothiadiazole, (23) le 4-amino-2,1,3-benzothiadiazole, (24) l'iodure de
3,4-diméthyl-5-(2-hydroxyéthyl)thiazolium , (25) le bromure de 3-éthyl-5-(2-hydroxyéthyl)4-méthylthiazolium,
(26) le 2-amino-5-nitrothiazole, (27) l'acide 2-amino-α-(méthoxyimino)-4-thiazoleacétique,
(28) le 2-amino-α-(hydroxyimino)-4-thiazoleacétate d'éthyle, (29) le 2-amino-α-(méthoxyimino)-4-thiazoleacétate
d'éthyle, (30) le 2-amino-4-thiazoleacétate d'éthyle, (31) le 2-amino-4-thiazoleglyoxylate
d'éthyle, (32) la 1-phényl-3-(2-thiazolyl)-2-thiourée, (33) le 2-amino-4-méthoxybenzothiazole,
(34) le 2-amino-5,6-diméthylbenzothiazole, (35) le N'-(2-thiazolyl)sulfanilamide,
le 6-éthoxy-2-benzothiazolesulfonamide, (37) le 2-(formylamino)-4-thiazoleacétate
d'éthyle, (38) le 2-(formylamino)-4-thiazoleglyoxylate d'éthyle, (39) l'acide 2-(formylamino)-α-(méthoxyimino)-4-thiazoleacétique,
(40) le chlorure de 2-acétamido-4-méthyl-5-thiazolesulfonyle, (41) l'acide 2-thioxo-4-thiazolidinecarboxylique,
(42) l'acide thiazolidine-4-carboxylique, (43) la pseudothiohydantoïne, (44) le 2-amino-1,3,4-thiadiazole,
(45) le 2-amino-5-trifluorométhyl-1,3,4-thiadiazole, (46) le 2-amino-5-méthyl-1,3,4-thiadiazole,
(47) le 2-amino-5-éthyl-1,3,4-thiadiazole, (48), le 2-amino-5-(éthylthio)-1,3,4-thiadiazole,
(49) le 5-amino-1,3,4-thiadiazole-2-thiol, (50) le 2-acétamido-5-benzylthio-1,3,4-thiadiazole,
(51) le 5-acétamido-1,3,4-thiadiazole-2-sulfonamide, (52) le 5-anilino-1,2,3,4-thiatriazole,
(53) le chlorhydrate de 2-amino-4,5-diméthylthiazole, (54) le chlorhydrate de 2-amino-4-imino-2-thiazoline,
(55) le chlorhydrate de 2-amino-2-thiazoline, (56) le monohydrobromhydrate de 2-amino-5-bromothiazole,
(57) le chlorhydrate de 5-amino-3-méthylisothiazole, (58) l'hydrate de chlorhydrate
de 3-méthyl-2-benzothiazolinonehydrazone, (59) le dichlorhydrate de 5-amino-2-méthylbenzothiazole,
(60) le monobromhydrate de 2,4-diamino-5-phénylthiazole, (61) le monohydrate de bromhydrate
de 2-amino-4-phényl- thiazole, (62) le chlorhydrate de l'acide 2-(tritylamino)-α-(méthoxyimino)-4-thiazolacétique,
(63) le chlorhydrate de 2,3,5,6-tétrahydro-6-phénylimidazo-[2,1-b]thiazole, (64) l'iodure
de 3-éthyl-2-méthyl-2-thiazolium, (65) le chlorure de 3-benzyl-5-(2-hydroxyétyl)-4-méthylthiazolium,
(66) le chlorhydrate de thiamine, (67) le bromure de 3-(carboxyméthyl)-benzothiazolium,
(68) le tétrafluoroborate de 2-azido-3-éthylbenzothiazolium, (69) l'iodure de 3-éthyl-2-méthylbenzothiazolium,
(70) l'iodure de 2-méthyl-3-propylbenzothiazolium, (71) le chlorure de 3-éthyl-2-(2-hydroxy-1-propényl)benzothiazolium,
(72) le bromure de 3,6-diméthyl-2- (4-diméthylaminophényl)benzothiazolium, (73) le
dichlorhydrate de trifluoropérazine, (74) le chlorhydrate de thioridazine, (75) le
chlorhydrate de prométhazine, (76) le chlorhydrate d'éthopropazine, (77) le chlorhydrate
de chlorpromazine, et (78) des mélanges de ceux-ci ; ou dans lequel l'agent de transparence
est choisi dans le groupe constitué par des phospines, des phosphites, des composés
de phosphore cycliques, des oxydes de phosphine, des sels de phosphonium quaternaire,
et des mélanges de ceux-ci ; ou dans lequel l'agent de transparence est choisi dans
le groupe constitué par (1) la triphénylphosphine, (2) la tri-m-tolylphosphine, (3)
la tris(3-méthoxyphényl)phosphine, (4) la tris(4-chlorophényl)phosphine, (5) la tris(pentafluorophényl)phosphine,
(6) la tricyclohexylphosphine, (7) la tribenzylphosphine, (8) la tri-2-furylphosphine,
(9) la bis(pyrrolidino)méthoxyphosphine, (10) la tétraphénylbiphosphine, (11) le 1,3-bis(diphénylphosphino)propane,
(12) le 1,5-bis(diphénylphosphino)pentane, (13) le 1,6-bis(diphénylphosphino)hexane,
(14) l'isopropyldiphénylphosphine, (15) la diphényl(p-tolyl)-phosphine, (16) la (4-bromophényl)diphénylphosphine,
(17) la diphényl-2-pyridylphosphine, (18) la dicyclohexylphénylphosphine, (19) le
phosphite de triméthyle, (20) le phosphite de triéthyle, (21) le phosphite de tris(2-chloroéthyle),
(22) le phosphite de tributyle, (23) le phosphite de triphényle, (24) le phosphite
de triméthyle-iodure de cuivre, (25) le phosphite de triéthyle-iodure de cuivre, (26)
le phosphite de dipropyle, (27) le phosphite de bis(2-éthylhexyle), (28) le phosphite
de bis(4-nitrobenzyle), (29) le fluorophosphite de 2,2'-éthylidènebis(4,6-di-tert-butylphényle),
(30) le diphosphite de pentaérythrol et de diphényle, (31) le phosphorodiamidate de
2-furyle et de tétraméthyle, (32) le (pyrrolidinométhyle)phosphonate de diéthyle,
(33) le monohydrate de cyclophosphamide, (34) le 2-oxyde de 2-chloro-1,3,2-dioxaphospholane,
(35) la N,N-diéthyl-1,5-dihydro-2,4,3-benzodioxaphosphépin-3-amine, (36) le 1,2-phénylènephosphochloridite,
(37) le phosphochloridate de 1,2-phénylène, (38) la 2-chloro-4H-1,3,2-benzodioxaphosphorin-4-one,
(39) le 2,4-disulfure de 2,4-bis(méthylthio)-1,3-dithia-2,4-diphosphétane, (40) l'oxyde
de triphénylphosphine, (41) l'oxyde de tris(hydroxyméthyl)phosphine, (42) l'oxyde
de triméthoxyphosphine, (43) l'oxyde de triéthoxyphosphine, (44) l'oxyde de triphénoxyphosphine,
(45) l'oxyde de tris (2-butoxyéthoxy)phosphine, (46) l'oxyde de diphénylphosphine,
(47) l'oxyde de diphényl(2,4,6-triméthylbenzoyl)phosphine, (48) l'acide phénylphosphinique,
(49) le phosphate de diphényle, (50) l'acide vinylphosphonique, (51) l'acide propylphosphonique,
(52) l'acide pyrophosphorique, (53) le phosphate de triphényle, (54) le chlorure de
tétrabutylphosphonium, (55) le bromure de tétrabutylphosphonium, (56) le bromure d'hexadécyltributylphosphonium,
(57) le bromure de stéaryltributylphosphonium, (58) le bromure d'azidotris(diéthylamino)phosphonium,
(59) le trimère de chlorure phosphonitrilique, (60) le bromure de tétraméthylphosphonium,
(61) le chlorure de tétraméthylphosphonium, (62), le bromure de tétraéthylphosphonium,
(63) le chlorure de tétraéthylphosphonium, (64) l'iodure de tétraéthylphosphonium,
(65) le bromure de tétraphénylphosphonium, (66) le chlorure de tétraphénylphosphonium
(67) l'iodure de tétraphénylphosphonium, (68) le bromure de méthyltriphénylphosphonium,
(69) l'iodure de méthyltriphénylphosphonium, (70) le bromure d'éthyltriphénylphosphonium,
(71) le bromure de n-propyltriphénylphosphonium, (72) l'iodure d'isopropyltriphénylphosphonium,
(73) le bromure de cyclopropyltriphénylphosphonium, (74) le bromure de n-butyltriphénylphosphonium,
(75) le bromure d'isobutyltriphénylphosphonium, (76) le bromure d'hexyltriphénylphosphonium,
(77) le chlorure de benzyltriphénylphosphonium, (78) le bromure de bromométhyltriphénylphosphonium,
(79) le chlorure de chlorométhyltriphénylephosphonium, (80) le bromure de 3-bromopropyltriphénylphosphonium,
(81) le bromure de 3-bromobutyltriphénylphosphonium, (82) le bromure de 4-bromobutyltriphénylphosphonium,
(83) le bromure de 2-diméthylaminoéthyltriphénylphosphonium, (84) le bromure de [(3-diméthylamino)propyl]triphénylphosphonium,
(85) le bromure de 2-hydroxyéthyltriphénylphosphonium, (86) le chlorure de (2-hydroxyéthyl)triphénylphosphonium,
(87) le bromure de [3-hydroxy-2-méthylpropyl]-triphénylphosphonium, (88) le bromure
de [3-hydroxy-2-méthylpropyl]triphénylphosphonium, (89) le bromure de (2-hydroxybenzyltriphénylphosphonium,
(90) le chlorure de (formylméthyl)triphénylphosphonium, (91) le chlorure de (méthoxyméthyl)triphénylphosphonium,
(92) le chlorure d'acétonyltriphénylphosphonium, (93) le bromure de carbométhoxyméthyltriphénylphosphonium,
(94) le chlorure d' (éthoxycarbonylméthyl)triphénylphosphonium, (95) le bromure de
carbéthoxyméthyltriphénylphosphonium, (96) le bromure de (tert-butoxycarbonylméthyl)triphénylphosphonium,
(97) le bromure de phénacyltriphénylphosphonium, (98) le bromure de 4-éthoxybenzyl)triphénylphosphonium,
(99) le bromure de 4-butoxybenzyltriphénylphosphonium, (100) le bromure de 2-(1,3-dioxan-2-yl)éthyl]triphénylphosphonium,
(101) le bromure de (1,3-dioxolan-2-ylméthyl)triphénylphosphonium, (102) le bromure
de vinyltriphénylphosphonium, (103) le bromure d'allyltriphénylphosphonium, (104)
le chlorure d'allyltriphénylphosphonium, (105) le bromure de propargyltriphénylphosphonium,
(106) le bromure de (3-triméthylsilyl-2-propynyl)triphénylphosphonium, (107) le p-xylylènebis(bromure
de triphénylphosphonium), et (108) des mélanges de ceux-ci ; ou dans lequel l'agent
de transparence est un nitrile ; ou dans lequel l'agent de transparence est choisi
dans le groupe constitué par le cyanoacétohydrazide, (2) le 4,4-diméthyl-3-oxopentanenitrile,
(3) le 1-cyano-N-méthylthioformamide, (4) le N,N-diméthyldithiocarbamate de cyanométhyle,
(5) le 4-hydroxy-3-méthoxyphénylacétonitrile, (6) le cyanure de tosyle, (7) l'isocyanure
de tosylméthyle, (8) le 5-fluoro-2-méthylbenzonitrile, (9) le 2-fluoro-5-méthylbenzonitrile,
(10) le 4-(méthylthio)benzonitrile, (11) le 4-(diméthylamino)benzonitrile, (12) le
3,4-diméthoxybenzonitrile, (13) le 4-hydroxy-3-méthoxybenzonitrile, (14) le 4-(trans-4-pentyl-cyclohexyl)benzonitrile,
(15) le 4'-pentyl-4'-biphénylcarbonitrile, (16) le 4'-(pentyloxy)-4-biphénylcarbonitrile,
(17) le 4'-hexyl-4-biphénylcarbonitrile, (18) le 4'-(hexyloxy)-4-biphényl-carbonitrile,
(19) le 4'-heptyl-4-biphénylcarbonitrile, (20) le 4'-heptyloxy-4-biphénylcarbonitrile,
(21) le 4'-octyl-4-biphénylcarbonitrile, (22) le 4'-(octyloxy)-4-biphénylcarbonitrile,
(23) le succinonitrile, (24) le fumaronitrile, (25) le 1,4-dicyano-2-butène, (26)
le (diméthylaminométhylène)malononitrile, (27) le (1-éthoxyéthylidène)malononitrile,
(28) l'α-chlorobenzylidènemalononitrile, (29) le benzylidènemalononitrile, (30) le
2-benzoyloxy-2-phényl-malononitrile, (31) l'O-(p-tosyl)isonitrosomalononitrile, (32)
le tétrafluorophtalonitrile, (33) l'iminodiacétonitrile, (34) le phénylènediacétonitrile,
(35) le 3,3' - (4-formylphénylimino)dipropionitrile, (36) le tris(2-cyanoéthyl)nitrométhane,
(37) le 1,1,3,3-propanetétracarbonitrile, (38) l'oxyde de tétracyanoéthylène, et (39)
des mélanges de ceux-ci, ou dans lequel l'agent de transparence est choisi dans le
groupe constitué par des isothiocyanates, des isocyanates, et des mélanges de ceux-ci
; ou dans lequel l'agent de transparence est choisi dans le groupe constitué par (1)
l'isothiocyanate de 4-azidophényle, (2) l'isothiocyanate de 1-naphtyle, (3) l'isothiocyanate
de 4-diméthylamino-1-naphtyle, (4) le 1-isothiocyanato-4-(trans-4-propylcyclohexyl)benzène,
(5) le 1-(trans-4-hexyl-cyclohexyl)-4-isothiocyanatobenzène, (6) le 1-(4-trans-hexylcyclohexyl)
-4-[2- (4-isothiocyanatophényl)]benzène, (7) le 1-isothiocyanato-4(trans-4-octylcyclohexyl)benzène,
(8) le 4-pentabicyclo[2.2.2]octane-1-carboxylate de 4-isothiocyanatophényle, (9) le
thiocyanate de benzyle, (10) le thiocyanate de guanidine, (11) le dithiocyanate de
méthylène, (12) le 4,4'-méthylènebis(isocyanate de phényle), (13) le 4,4'-méthylènebis
(isocyanate de 2,6-diéthyle), et (14) des mélanges de ceux-ci ; ou dans lequel l'agent
de transparence est choisi dans le groupe constitué par des composés d'oxime, des
composés d'acide hydroxamique, et des mélanges de ceux-ci ; ou dans lequel l'agent
de transparence est choisi dans le groupe constitué par (1) le formamidoxime, (2)
l'acétaldoxime, (3) le pyruvaldéhyde-1-oxime, (4) l'acétoneoxime, (5) le chlorooximidoacétate
d'éthyle, (6) le 2,3-butanedionemonooxime, (7) le 5-hydroxypenténaloxime, (8) le cyclopentanoneoxime,
(9) le cyclohexanoneoxime, (10) le cyclooctanoneoxime, (11) le benzaldéhydeoxime,
(12) le 2-nitrobenzaldéhydeoxime, (13) le salicylaldoxime, (14) la 2-isonitrosoacétophénone,
(15) le 1-phényl-1,2-propanedione-2-oxime, (16) le 2-pyridinealdoxime, (17) le nifuroxime,
et (18) des mélanges de ceux-ci ; ou dans lequel l'agent de transparence est un dérivé
d'acide hydroxamique ; ou dans lequel l'agent de transparence est choisi dans le groupe
constitué par (1) l'acide acétohydroxamique, (2) l'acide subérohydroxamique, (3) l'acide
mandélohydroxamique, (4) l'acide benzohydroxamique, (5) l'acide N-phénylbenzohydroxamique,
et (6) des mélanges de ceux-ci ; ou dans lequel l'agent de transparence est choisi
dans le groupe constitué par des sels d'alkylammonium, des sels d'arylammonium, des
sels d'arylalkylammonium, et des mélanges de ceux-ci ; ou dans lequel l'agent de transparence
est choisi dans le groupe constitué par (1) le tétrahydrate de fluorure de tétraméthylammonium,
(2) le tétrahydrate d'acétate de tétraéthylammonium, (3) le chlorure de tétrabutylammonium,
(4) l'hydrate de chlorure de tétrabutylammonium, (5) le bromure de tétrabutylammonium,
(6) le tribromure de tétrabutylammonium, (7) l'acétate de tétrabutylammonium, (8)
le thiocyanate de tétrabutylammonium, (9) le bromure de tétrapentylammonium, (10)
le bromure de tétrahexylammonium, (11) le chlorure de tétrahexylammonium, (12) le
sulfate acide de tétrahexylammonium, (13) le chlorure de tétraheptylammonium, (14)
le bromure de tétraheptylammonium, (15) le bromure de tétraoctylammonium, (16) le
bromure de tétrakisdécylammonium, (17) le bromure de tétrahexadécylammonium, (18)
le bromure de tétraméthylammonium, (19) le chlorure de tétraméthylammonium, (20) l'iodure
de tétraméthylammonium, (21) le bromure de tétraéthylammonium, (22) le chlorure de
tétraéthylammonium, (23) l'iodure de tétraéthylammonium, (24) le bromure de tétrapropylammonium,
(25) l'iodure de tétrapropylammonium, (26) l'iodure de tétrabutylammonium, (27) le
chlorure de tétrapentylammonium, (28) le bromure de tétrahexylammonium, (29) l'iodure
de tétrahexylammonium, (30) le bromure de tétradécylammonium, (31) le bromure de tétradodécylammonium,
(32) le bromure de tétraoctadécylammonium, (33) le bromure de méthyltrioctylammonium,
(34) le chlorure de' tridodécylméthylammonium, (35) l'iodure de tridodécylméthylammonium,
(36) le bromure de N-dodécyl-N-méthyléphédrinium, (37) le tribromure de phényltriméthylammonium,
(38) le chlorure de tricaprylméthylammonium, (39) le chlorure de tridodécylméthylammonium,
(40) le chlorure de tridécyloxypropyldihydroxyéthylméthylammonium, (41) le chlorure
de N-tétradécyldiméthylnaphtylméthylammonium, (42) le chlorure de d'octadécyldiéthanolméthylammonium,
(43) le chlorure d'octadécyldihydroxyéthylméthylammonium, (44) le chlorure de suif
dihydrogéné-benzylméthylammonium, (45) le chlorhydrate de chlorure de 2-aminoéthyltriméthylammonium,
(46) le bromure de 2-bromoéthyltriméthylammonium, (47) le chlorure de 2-chloroéthyltriméthylammonium,
(48) le chlorure de 3-carboxypropyltriméthylammonium, (49) le chlorure de [3-(méthacryloylamino)propyl]triméthylammonium,
(50) le bromure de phényltriméthylammonium, (51) le chlorure de phényltriméthylammonium,
(52) l'iodure de phényltriméthylammonium, (53) le chlorure de benzyltriméthylammonium,
(54) le bromure de benzyltriméthylammonium, (55) le chlorure de 4-nitrobenzyltriméthylammonium,
(56) l'iodure de [2-(4-nitrophényl)allyl]triméthylammonium, (57) le chlorure de coco-triméthylammonium,
(58) le chlorure de palmityltriméthylammonium, (59) le bromure de myristyltriméthylammonium,
(60) le chlorure d'oléyltriméthylammonium, (61) le chlorure de soya-triméthylammonium,
(62) le chlorure de suif-triméthylammonium, (63) le chlorure de suif hydrogéné-triméthylammonium,
(64) le chlorure de stéaryltriméthylammonium, (65) le chlorure de béhényltriméthylammonium,
(66) le chlorure de guar-hydroxypropyltriméthylammonium, (67) le bromure de benzyltriéthylammonium,
(68) le bromure de butyltripropylammonium, (69) le chlorure de méthyltributylammonium,
(70) le bromure de méthyltributylammonium, (71) l'iodure de méthyltributylammonium,
(72) le chlorure de benzyltributylammonium, (73) le bromure de benzyltributylammonium,
(74) l'iodure de benzyltributylammonium, (75) le bromure d'heptyltributylammonium,
(76) le bromure de benzyldodécyldiméthylammonium, (77) le dihydrate de chlorure de
benzyltétradécylediméthylammonium, (78) le monohydrate de chlorure de benzylcétyldiméthylammonium,
(79) le monohydrate de chlorure de benzylstéaryldiméthylammonium, (80) le chlorure
de N,N-diméthylméthylèneammonium, (81) l'iodure de N,N-diméthylméthylèneammonium,
(82) le chlorure de chlorométhylènediméthylammonium, (83) le chlorure de dichlorométhylènediméthylammonium,
(84) le chlorure de diméthylaminométhylèneaminométhylènediméthylammonium, (85) le
chlorure de benzéthonium, (86) le chlorure de méthylbenzéthonium, (87) le chlorure
de 1-propanaminium-2,3-dihydroxy-N-diméthyl-N-[3 (oxococoyl) aminopropyle], (88) le
bromure de cétyldiméthyléthylammonium, (89) le chlorure d'octyldodécyldiméthylammonium,
(90) le bromure de dodécyl-(2-hydroxy-1-méthyl-2-phényléthyl)diméthylammonium, (91)
le bromure de dodécyldiméthyl-2-phénoxyéthylammonium, (92) le chlorure de dodécanoyl-N-méthylaminoéthyl(phénylcarbamylméthyl)diméthylammonium,
(93) le chlorure de 3-chloro-2-hydroxypropyl-N,N,N-diméthyldodécylammonium, (94) le
chlorure de 3-chloro-2-hydroxypropyl-N,N,N-diméthyloctadécylammonnium, (95) le bromure
de dodécylbenzyldiméthylammonium, (96) le chlorure de dodécylbenzyldiméthylammonium,
(97) le chlorure de coco-benzyldiméthylammonium, (98) le chlorure de benzyltétradécyldiméthylammonium,
(99) le chlorure de benzylcétyldiméthylammonium, (100) le chlorure de benzyloctadécyldiméthylammonium,
(101) le chlorure de benzyl-suif-diméthylammonium, (102) le chlorure de benzyl-suif
hydrogéné-diméthylammonium, (103) le chlorure de benzyl-béhényldiméthylammonium, (104)
le chlorure de dioctyldiméthylammonium, (105) le chlorure de didécyldiméthylammonium,
(106) le bromure de didécyldiméthylammonium, (107) le chlorure de dicoco-diméthylammonium,
(108) le chlorure de dicétyldiméthylammonium, '(109) le chlorure de disoya-diméthylammonium,
(110) le chlorure de disuif-diméthylammonium, (111) le chlorure de suif dihydrogénédiméthylammonium,
(112) le chlorure de dibéhényl/diarachidyldiméthylammonium, (113) le chlorure de soya-amidopropylbenzyldiméthylammonium,
(114) le chlorure de soja-di-coco-ammonium quaternaire, (115) le chlorure de gluco-namidopropyldiméthyl-2-hydroxyéthylammonium,
(116) un chlorure de N-alkyl-N-N-diméthyl-N-(acétate de dodécylammonium), dans lequel
le groupe alkyle comporte de 14 à 20 atomes de carbone, (117) le chlorure de visonamidopropyldiméthyl-2-hydroxyéthylammonium,
(118) le chlorure de N-colza-(3-amidopropyl)-N-N-diméthyl-N-(2,3-époxypropyl)ammonium,
(119) le chlorure de N-stéaryl-(3-amidopropyl)-N-benzyldiméthylammonium, (120) le
chlorure de colza-amidopropylbenzyldiméthylammonium, (121) le chlorure de colza-amidopropyléthyldiméthylammonium,
(122) le phosphate de chlorure de coco-amidopropylpolyéthylèneglycoldiméthylammonium,
(123) le chlorure de butyrylcholine, et (124) des mélanges de ceux-ci ; ou dans lequel
l'agent de transparence est choisi dans le groupe constitué par le thiocyanate de
pipéridine, le 2-pipéridineméthanol, la bis(pentaméthylène)urée, le 4,4'-triméthylènebis(1-pipéridinepropionitrile),
l'oxyde de tripipéridinophosphine, l'homopipérazine, la 1-pipéronylpipérazine, le
trisulfate d'hexacylène, la 5,10,15,20-tétraphényl-21H,23H-porphine, la 5,10,15,20-tétrakis(4-méthoxyphényl)-2H,23H-porphine,
le pyrrole-2-carboxaldéhyde, le 3-pyrrolidino-1,2-propanediol, le pyrazole, le 3-aminopyrazole,
l'imidazole, le 2-éthylimidazole, la 2-(2-pipéridinoéthyl)pyridine, le chlorure de
1-dodécylpyridinium, le perbromure de bromure de pyridinium, la 3-aminoquinoléine,
la 8-hydroxyquinoléine, la 7,8-benzoquinoléine, la 8-hydroxyquinaldine, la quinoxaline,
le monohydrate de 4,5-dihydro-6-méthyl-3(2H)-pyridazinone, la phtalazine, la 1,10-phénanthroline,
la 1,3,5-triazine, la trichloromélamine, l'acide trichloroisocyanurique, le norbornane,
le tricyclo-[5.2.1.0]décape, le norcamphre, la tropolone, le 1-indanol, le trans,trans,cis-1,5,9-cyclododécatriène,
l'époxyde de cyclodécane, la 2,3-cyclododécanepyridine, le 1,2,5,6,9,10-hexabromocyclododécane,
la 1,4,4a,8a-tétrahydro-endo-1,4-méthanonaphtalène-5,8-dione, la γ-butyrolactone,
la β,β-diméthyl-γ-(hydroxyméthyl)-γ-buty-rolactone, la 2,5-diméthyl-4-hydroxy-3(2H)-furanone,
le dihydrate d'hydrindantine, le 2,4,8,10-tétraoxaspiro-[5.5]undécane, le 1,3,5-trioxane,
la cyclooctanone, le pipéronal, l'alcool pipéronylique, le pipéronylnitrile, le 3,4(méthylènedioxy)phénylacétonitrile,
l'anhydride maléique, l'anhydride s-acétylmercaptosuccinique, l'anhydride 2-octadécèn-1-ylsuccinique,
le 18-couronne-6, le benzo-18-couronne-6, le dibenzo-18-couronne-6, le dibenzo-24-couronne-8,
le 5-amino-3-méthylisooxazole, la 2-oxazolidone, la 5,5-diméthyloxazolidine-2,4-dione,
la 3-éthyl-2-thioxo-4-oxazolidinone, le 3-morpholino-1,2-propanediol, la 4-phénylmorpholine,
le N,N'-dibenzyl-1,4,10,13-tétraoxa-7,16-diazacyclooctadécane, le 4,7,13,16,21,24-hexaoxa-1,10-diazabicyclo[8.8.8]hexacosane,
le γ-valérolactame, l'ε-caprolactame, la 2-azacyclooctanone, la 2-azacyclononanone,
le maléimide, le n-méthylsuccinimide, un sel de DBU-phtalimide, la 1-allyl-2-thiourée,
le 1,3-dithiane, la 1-benzyl-3-méthyl-2thiourée, le 2-imino-4-thiobiuret, la butylsulfone,
le 2,2'-bithiophène, le 2-phényl-1,3-dithiane, le 3,6,9,14-tétrathiabicyclo[9.2.1]tétradéca-11,13-diène,
le 1,5,9,13-tétrathiacyclohexadécane-3,11-diol, le 1,4,7,10,13-pentathiacyclopentadécane,
le 2-aminothiazole, la 2-amino-2-thiazoline, la 3-méthylrhodanine, le bromure de 3-éthyl-5-(2-hydroxyéthyl)-4-méthylthiazolium,
la triphénylphosphine, la tricyclohexylphosphine, le 1,3-bis(diphénylphosphino)propane,
le 1,5-bis(diphénylphosphino)pentane, l'isopropyldiphénylphosphine, le phosphite de
triéthyle, le phosphite de triphényle, le phosphite de triéthyle-iodure de cuivre,
le phosphite de dipropyle, le phosphite de bis(2-éthylhexyle), le phosphite de bis(4-nitrobenzyle),
l'oxyde de diphénylphosphine, l'oxyde de diphényl-(2,4,6-triméthylbenzoyl)phosphine,
l'acide vinylphosphonique, le cyanoacétohydrazide, le N,N-diméthyldithiocarbamate
de cyanométhyle, le 4'-pentyl-4'-biphénylcarbonitrile, le 4'-(octyloxy)-4-biphénylcarbonitrile,
le 1,4-dicyano-2-butène, le benzylidènemalononitrile, le 1-isothiocyanato-4-(trans-4-propylcyclohexyl)benzène,
le formamidoxime, le chlorooximidoacétate d'éthyle, l'acide acétohydroxamique, le
chlorure de tétrahexylammonium, le chlorure de tétraheptylammonium, le bromure de
tétraheptylammonium et des mélanges de ceux-ci.
9. Procédé qui comprend les étapes consistant à (1) fournir l'élément de formation d'images
par migration selon la revendication 1, comprenant (a) un substrat, (b) une couche
ramollissable comprenant un matériau ramollisable et un matériau de marquage par migration
photosensible, et (c) un agent de transparence qui rend transparent le matériau de
marquage par migration en contact avec lui, contenu dans au moins une couche de l'élément
de formation d'images par migration ; (2) charger uniformément l'élément de formation
d'images ; (3) à la suite de l'étape (2), exposer l'élément de formation d'images
chargé à un rayonnement activant à une longueur d'onde à laquelle le matériau de marquage
par migration est sensible ; (4) à la suite de l'étape (3), provoquer le ramollissement
du matériau ramollissable et permettre à une première partie du matériau de marquage
par migration de migrer à travers le matériau ramollissable vers le substrat selon
un motif formant une image tandis qu'une seconde partie du matériau de marquage par
migration reste essentiellement sans avoir migré à l'intérieur de la couche ramollissable,
dans lequel à la suite de la migration de la première partie du matériau de marquage
par migration, (a) la première partie du matériau de marquage par migration entre
en contact avec l'agent de transparence et la seconde partie du matériau de marquage
par migration n'entre pas en contact avec l'agent de transparence ; ou (b) la seconde
partie du matériau de marquage par migration entre en contact avec l'agent de transparence
et la première partie du matériau de marquage par migration n'entre pas en contact
avec l'agent de transparence
10. Procédé selon la revendication 9, dans lequel la première partie du matériau de marquage
par migration entre en contact avec l'agent de transparence et la seconde partie du
matériau de marquage par migration n'entre pas en contact avec l'agent de transparence
; ou dans lequel la seconde partie du matériau de marquage par migration entre en
contact avec l'agent de transparence et la première partie du matériau de marquage
par migration n'entre pas en contact avec l'agent de transparence.