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(11) | EP 0 903 304 B1 |
| (12) | EUROPEAN PATENT SPECIFICATION |
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| (54) |
Protection of large above-ground storage tanks against corrosion Schutz grosser, oberirdisch aufgestellter Tankbehälter gegen Korrosion Protection de gros réservoirs non-enterrés contre la corrosion |
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| Note: Within nine months from the publication of the mention of the grant of the European patent, any person may give notice to the European Patent Office of opposition to the European patent granted. Notice of opposition shall be filed in a written reasoned statement. It shall not be deemed to have been filed until the opposition fee has been paid. (Art. 99(1) European Patent Convention). |
[0001] This invention relates to a method for protecting above-ground storage tanks against external corrosion.
[0002] The background and the invention are described with the help of the following Figures:
- Figure 1 represents the main features of large storage tanks;
- Figure 2 represents the undesired deformation of the ground caused by the weight of storage tanks and their contents;
- Figure 3 represents a waterproof skirt according to the present invention;
- Figure 4 represents a preferred embodiment of the present invention;
- Figure 5 represents an embodiment of a window useful with the preferred embodiment of Figure 4;
- Figure 6 represents an optional drainage trough dug around the foot of the storage tank in order to collect water.
- Figure 7 represents an inspection window.
Background.
[0003] Large storage tanks can have a diameter of up to about 88 m and the weight of their content can reach up to 100,000 tons. Referring to Figure 1, they comprise as bottom part an horizontal annular metal ring (1) which has a mean diameter of about 88 m, a width of 30 to 50 cm and a thickness of 10 to 13 mm. Upon this ring (1) are welded horizontal metal sheets (2) of a thickness ranging from 6 to 7 mm. This horizontal structure (1,2) is surmounted by the vertical metal walls (3) of the tank which are made of a series of cylindrical shells welded on top of one another, each having a height of 1.5 to 2.5 m and a thickness which decreases from about 32 mm for the lowermost shell to about 6 mm for the uppermost shell; the total height of the tank is about 21 metres. The lowermost cylindrical vertical wall is welded to the horizontal ring (1) by a welding seam (26).
[0004] These tanks are equipped with an internal floating roof (4) which is made of a metal sheet, about 5 mm thick, weighs about 350 tons and is equipped with up to 200 legs (5) which, under operating conditions, are set at a height under the roof of 1.5 m and, under maintenance conditions, at a height under the roof of 2 m. This roof (4) serves several purposes: it is used to prevent vapours and gases from escaping the tank, to protect the stored fluid from external contamination and to determine the fluid level in the tank. It is equipped with safety devices to allow prompt intervention in case of fire hazard. It also contains a system (6) for collecting and evacuating rain water which would otherwise accumulate on top of the roof (4) and cause it to sink; the water is evacuated through a pipe which is made of three or more segments (7) articulated with respect to one another (8) in order to adjust to the changing height of the roof.
[0005] The tanks are filled and emptied through a pipe (9) which has a diameter of about 90 cm and allows a flow rate of about 16000 m3 per hour. The input flow can automatically be interrupted when the roof has nearly risen to the top of the tank.
[0006] Because of their enormous weight, when filled, these large tanks are built upon a basement (10) constituted of sand and gravel. Such basement (10) typically has a diameter which is about 3 metres larger than the diameter of the storage tank and a height of about 1 metre above the ground. It is covered with a waterproof layer of bitumen which has a thickness of about 10 cm.
[0007] As the weight of the stored oil varies from 0 when empty to up to 100,000 tons when full, the platform undergoes deformations when the level of the fluid in the tank is modified. It flattens when the tank is filled and rebounds when the tank is emptied; this deformation can reach up to 3 cm. The tank itself undergoes an horizontal deformation of up to about 8 cm for a full tank of 88 m diameter. These changes can be considered as essentially reversible.
[0008] Referring to Figure 2, it is observed, however, that in addition to the predicted flattening of the platform and expansion of the tank, an undesired local deformation also occurs at the edge (11) of the metal annular ring (1) of the storage tank. A bulge (12) is formed and it increases with each successive deformation upon loading and downloading of the tank. This bulge allows water to seep and infiltrate (13) between the bitumen covered platform (10) and the metal bottom (1,2) of the tank, thereby allowing corrosion of the metal sheets (2) forming the bottom (1,2) of the storage tank. As air is also allowed to penetrate at the same time as water, at least under the outer part of the tank, corrosion is observed in the outer part of the tank floor over a distance of about 3 m. Because corrosion of the tank's bottom may lead to leaks and therefore pollution of the underground, the welding seams and metal sheets forming the floor of the large storage tanks must be inspected at regular intervals (e.g. every 10 years). The tank's floor can only be accessed through the tank interior; this therefore requires that the tank be completely emptied and gas-free for inspection.
[0009] The problem of corrosion has been addressed in prior art document JP-58099380 that discloses the use of a fitted waterproof membrane to protect the base of the tanks.
[0010] It is an object of the present invention to solve the problem of corrosion of the metal floor of above-ground large storage tanks.
[0011] It is another object of the present invention to increase the time between two consecutive inspections of the welding seams and bottom of the tanks.
Summary of the invention.
[0012] The present invention discloses a method for protecting against external corrosion the lower part of storage tanks which have a diameter larger than 20 metres and preferably larger than 40 m.
[0013] It is now found that corrosion can be prevented from seeping underneath the floor of large storage tanks by placing a downwardly extending waterproof skirt around the bottom part of the tank, said skirt being designed to create a ventilated space limited by the vertical wall of the tank, the horizontal floor of the platform and the skirt.
Detailed description of the invention.
[0014] The invention is best described by way of specific embodiments, without wanting however to limit its scope to these embodiments alone.
[0015] According to a preferred embodiment of the present invention, the waterproof skirt (14) fitted around the exterior bottom part of the tank is a flexible membrane made of polypropylene sheets. Referring to Figure 4, the upper end of the skirt (14) is glued to the vertical wall of the tank at a height of about 60 cm (15) and the inferior end of the skirt is glued to the bitumen of the tank basement (10) at an horizontal distance of about 60 cm from the bottom of the tank (20). The skirt (14) is allowed a small amount of curvature between these two fixed points (15,20) in order to accomodate for the lateral motions of the tank's wall and the vertical motion of the tank basement when the tank is filled or emptied.
[0016] Ventilation is obtained through "windows" or openings (21). Referring to Figure 5, these openings are properly screened by a fine flexible mesh (22) in order to avoid the undesired entrance of vermin (rodents or insects) or waste, and covered by an awning in order to avoid water infiltration (23). Such windows are typically spaced between 10 and 15 m.
[0017] Referring to Figure 6, a prior art embodiment was designed to solve the problem of corrosion by digging a drainage trough (24) around the edge of the metal ring (1) supporting the bottom of the tank (2), in order to collect rain water. It was observed however that the upward and downward motion of the tank at unloadindg or loading did create a small additional bulge (25), thereby reducing but not suppressing the problem of corrosion. A waterproof skirt (not represented) must therefore also be fitted around the bottom of the storage tank, but in addition to the above-described embodiment of the present invention, it is necessary to dig narrow evacuation troughs (not represented), about perpendicular to the drainage trough, at regular intervals (e.g. every 25m) in order to drain any water collected in the drainage trough. These evacuation troughs are each screened by a stainless steel mesh which is tightly fitted to the bottom of the trough at the lower end and glued to the bottom of the waterproof skirt at the upper end.
[0018] It is preferably desired that the important welding seam(26) between the vertical walls (3) of the tank and the horizontal metal ring (1), be easily accessed for inspection. For this purpose, refastenable openings can be carved in the skirt (14) where necessary.
[0019] According to a preferred embodiment of the present invention, the awning (23) is mobile and can be opened and fastened with refastenable closing means; it is opened when inspection is desired (see Figure 7) and, under operating conditions, it remains in a semi-open position thereby allowing moisture out and no water in.
[0020] Referring to Figure 3, in yet another embodiment of the present invention, the skirt (14) is fitted to the vertical wall of the metal tank by a watertight seal (15) at a height ranging from 30 to 100 cm from the ground, downwardly extends, without touching the ground, to a lateral distance which goes beyond the edge (17) of the platform (10), defined here as the point where the platform floor starts sloping down, and makes an angle (16) with the vertical wall of the tank defined as tan-1(L/H) where L is the horizontal distance between the vertical wall of the tank and the edge of the platform increased by at most 15 cm, and H is the height above the tank's floor at which the skirt is attached to the vertical wall of the tank. The above-described set up creates a dry and ventilated space (18) limited by the vertical wall (3) of the tank, the horizontal floor (27) of the platform and the skirt (14); this space is screened (19) to avoid entrance of vermin or waste. The skirt is manufactured either by using a rigid material or by using a semi-flexible material maintained in an open position by means of rigid elements placed at regular intervals.
[0021] For large storage tanks equipped with the waterproof skirt of this invention, the timespan between two consecutive inspections of the welding seams and floor is now brought up to 20 years.
Example.
[0022] The waterproof skirt fitted around the exterior bottom part of the tank was a flexible membrane made of polypropylene sheets. The upper end of the skirt has been glued to the vertical wall of the tank at a height of about 60 cm and the inferior end of the skirt has been glued to the horizontal floor of the platform at an horizontal distance of about 60 cm from the bottom of the tank. The propylene sheets which have a surface of 1m by 3m, and a thickness of 2mm were sealed together. They were made of thermoplastic rubber extruded from a compound based on polypropylene; they offered an improved resistance to biodegradation, chemical reactions and UV light. Their properties were quantified as follows.
| Temperature range | -40° C (DIN 53361) to +80° C (DIN 53377) |
| Density | 0.9 g/cm3 |
| Modulus | 100 N/mm2 at 23° C |
| Maximum elongation, multiaxial | > 150% |
| Coefficient of linear expansion | 0.07 mm per m/° C |
| Thickness | 0.5 to 2 mm |
| Flame resistance | DIN 4102 B2 |
[0023] After periodic exposures to rain water and UV light according to ASTM G26, for a total duration of 4000 hour, at a temperature of 80° C, the strength and the extension to breaking point have been evaluated according to ASTM D638.
| Sample n° 1 | 0 hour | 2000 hours | 4000 hours |
| Stretching strength | 100 | 100 | 96 |
| Break by stretching | 100 | 94 | 78 |
[0024] In another method according to ASTM G90, the alteration of the material is measured in terms of Langleys. In the Netherlands, 100,000 Langleys correspond to the corrosion observed after one year of exposure to external conditions whereas in tropical situation, 150,000 to 180,000 Langleys correspond to the corrosion observed after the same length of time. In the present Example, carried out in the Netherlands, only minor alterations have been observed in the mechanical and physical properties of the propylene after 2 millions Langleys. This is summarised in the following table.
| Sample n° 2 | 0 hour | 1000 kLangleys | 2000 kLangleys |
| Stretching strength | 100 | 112 | 112 |
| Break by stretching | 100 | 104 | 98 |
[0025] The resistance to cracking of the propylene used in the present invention has been tested according to ASTM 1693.
[0026] For the membranes of the present invention, no cracking has been observed to start and spread after 3000 hour of exposure to a soap solution of Igepal concentrate, when measured in the temperature range of 20 to 100° C.
[0027] Ventilation was obtained by cutting rectangular openings about 30 cm high and 20 cm wide in the skirt; these openings were screened by a fine flexible mesh and covered by an awning which was attached to the upper edge of the opening and refastened to a half-closed position with Velcro®, under operating conditions. The openings were placed every 10 m.
1. Method for protecting against external corrosion the bottom part of storage tanks
(1,2) which have a diameter larger than 20 metres, by placing a waterproof skirt (14)
around the bottom part of the tank,
characterised in that the waterproof skirt is a downwardly extending skirt designed to create a ventilated space (18) limited by the vertical wall of the tank (3), the horizontal floor of the basement (10) and the skirt.
characterised in that the waterproof skirt is a downwardly extending skirt designed to create a ventilated space (18) limited by the vertical wall of the tank (3), the horizontal floor of the basement (10) and the skirt.
2. The method of claim 1 for protecting against external corrosion the bottom part of
storage tanks which have a diameter larger than 40 metres.
3. The method according to claim 1 or claim 2, wherein the skirt is made of a waterproof
flexible membrane which is fitted to the vertical wall of the tank and to the horizontal
floor of the platform through waterproof seals (15 and 20) and presents screened ventilation
openings (21) which are protected from water infiltration by semi-open (22) awnings
(23) and which are spaced at regular intervals.
4. The method according to claim 3 which simultaneously allows for inspection of the
seal (26) joining the vertical metal walls of the storage tank to its horizontal metal
floor through the ventilation openings.
5. The method according to claim 3 or claim 4 wherein the waterproof skirt is made up
of propylene sheets sealed together.
6. The method according to claim 1 or claim 2 wherein the skirt is fitted to the vertical
wall of the metal tank by a watertight seal (15) at a height ranging from 30 to 100
cm from the ground, downwardly extends to a lateral distance which goes beyond the
edge of the platform without touching the ground, creating a dry and ventilated space
(18) limited by the vertical wall of the tank, the horizontal floor of the platform
and the skirt and which is screened (19) to avoid entrance of vermin or waste.
7. The method of claim 6 wherein the skirt is made of rigid material.
8. The method of claim 6 wherein the skirt is made of semi-flexible material held in
open position by means of rigid elements placed at regular intervals.
9. The method according to any one of claims 3 to 5 wherein the water collected in the
optional drainage trough surrounding the bottom part of the large storage tank is
evacuated outside of the area sheltered by the waterproof skirt through drainage troughs
about perpendicular to said main drainage trough.
10. Use of the method according to any one of claims 1 to 9 for increasing the time separating
two consecutive inspections of the seals and floor of large storage tanks
1. Verfahren zum Schützen gegen äußere Korrosion den Bodenteil von Lagertanks (1,2),
die einen Durchmesser größer als 20 m haben, durch Anordnen eines wasserdichten Randes
(14) um das Bodenteil des Tanks,
dadurch gekennzeichnet, daß der wasserdichte Rand ein sich nach unten erstreckender Rand ist, entworfen, einen belüfteten Raum (18), begrenzt durch die vertikale Tankwand (3), den horizontalen Boden des Fundaments (10) und den Rand, zu erzeugen.
dadurch gekennzeichnet, daß der wasserdichte Rand ein sich nach unten erstreckender Rand ist, entworfen, einen belüfteten Raum (18), begrenzt durch die vertikale Tankwand (3), den horizontalen Boden des Fundaments (10) und den Rand, zu erzeugen.
2. Verfahren nach Anspruch 1 zum Schützen gegen äußere Korrosion das Bodenteil von Lagertanks,
die einen Durchmesser größer als 40 Meter haben.
3. Verfahren nach Anspruch 1 oder Anspruch 2, wobei der Rand hergestellt wird aus einer
wasserdichten flexiblen Membran, die angepaßt wird an die vertikale Tankwand und an
den horizontalen Boden der Plattform durch wasserdichte Abdichtungen (15 und 20) und
abgeschirmte Belüftungsöffnungen (21) zeigt, die vor Wassereindringung durch semi-offene
(22) Zeltstoffplanen (23) geschützt sind, und die in regelmäßigen Intervallen angeordnet
sind.
4. Verfahren nach Anspruch 3, welches gleichzeitig Prüfung der Abdichtung (26) erlaubt,
die die vertikalen Metallwände des Lagertanks an seinen horizontalen Metallboden verbindet,
durch die Belüftungsöffnungen.
5. Verfahren nach Anspruch 3 oder Anspruch 4, wobei der wasserdichte Rand aus Propylenlagen,
aneindergesiegelt, gebildet ist.
6. Verfahren nach Anspruch 1 oder Anspruch 2, wobei der Rand an die vertikale Wand des
Metalltanks durch eine wasserdichte Abdichtung (15) in einer Höhe angepaßt wird, die
von 30 bis 100 cm von dem Boden reicht, sich nach unten zu einem seitlichen Abstand
erstreckt, der über die Ecke der Plattform geht, ohne den Boden zu berühren, einen
trockenen und belüfteten Raum (18) erzeugend, begrenzt durch die vertikale Tankwand,
den horizontalen Boden der Plattform und den Rand, und welcher abgeschirmt (19) ist
zum Vermeiden von Eintritt von Ungeziefer oder Abfall.
7. Verfahren nach Anspruch 6, wobei der Rand aus starrem Material gebildet ist.
8. Verfahren nach Anspruch 6, wobei der Rand aus semiflexiblem Material gebildet ist,
gehalten in offener Position durch starre Elemente, angeordnet in regelmäßigen Intervallen.
9. Verfahren nach einem von Ansprüchen 3 bis 5, wobei das Wasser, gesammelt in der wahlfreien
Entwässerungsmulde, die das Bodenteil des großen Lagertanks umgibt, außerhalb des
Bereichs, der abgeschirmt ist durch den wasserdichten Rand, durch Entwässerungsmulden
etwa senkrecht zu der Hauptentwässerungsmulde evakuiert wird.
10. Verwendung des Verfahrens nach einem von Ansprüchen 1 bis 9 zum Erhöhen der Zeit,
trennend zwei aufeinanderfolgende Inspektionen der Abdichtungen und des Bodens großer
Lagertanks.
1. Procédé pour conférer une protection contre la corrosion externe à la partie inférieure
de réservoirs de stockage (1, 2) dont le diamètre est supérieur à 20 m, en plaçant
une jupe imperméable à l'eau (14) autour de la partie inférieure du réservoir, caractérisé en ce que la jupe imperméable à l'eau est une jupe s'étendant vers le bas conçue pour créer
un espace ventilé (18) limité par la paroi verticale du réservoir (3), par la base
horizontale du soubassement (10) et par la jupe.
2. Procédé selon la revendication 1, pour conférer une protection contre la corrosion
externe à la partie inférieure de réservoir de stockage dont le diamètre est supérieur
à 40 m.
3. Procédé selon la revendication 1 ou 2, dans lequel la jupe est réalisée en une membrane
inflexible imperméable à l'eau qui vient s'appliquer contre la paroi verticale du
réservoir et contre la base horizontale de la plate-forme via des joints étanches
imperméables à l'eau (15 et 20) et qui présente des ouvertures de ventilation munies
de treillis (21) qui sont protégées contre l'infiltration de l'eau par des bâches
(23) semi-ouvertes (22) et qui sont espacées par intervalles réguliers.
4. Procédé selon la revendication 3, qui permet simultanément l'inspection du joint (26)
qui joint les parois métalliques verticales du réservoir de stockage à sa base métallique
horizontale à travers les ouvertures de ventilation.
5. Procédé selon la revendication 3 ou 4, dans lequel la jupe imperméable à l'eau est
constituée par des feuilles de propylène jointes l'une à l'autre de manière étanche.
6. Procédé selon la revendication 1 ou 2, dans lequel la jupe est appliquée contre la
paroi verticale du réservoir métallique via un joint étanche imperméable à l'eau (15)
à une hauteur qui se situe dans le domaine de 30 à 100 cm par rapport au sol, s'étend
vers le bas jusqu'à une distance latérale qui dépasse le bord de la plate-forme sans
toucher le sol en créant un espace sec et ventilé (18) limité par la paroi verticale
du réservoir, la base horizontale de la plate-forme et la jupe et qui est munie d'un
treillis (19) pour éviter la pénétration de la vermine ou de déchets.
7. Procédé selon la revendication 6, dans lequel la jupe est constituée d'une matière
rigide.
8. Procédé selon la revendication 6, dans lequel la jupe est constituée d'une matière
semi-flexible maintenue dans une position ouverte à l'aide d'éléments rigides placés
à des intervalles réguliers.
9. Procédé selon l'une quelconque des revendications 3 à 5, dans lequel l'eau récoltée
dans la rigole de drainage facultative entourant la partie inférieure du réservoir
de stockage de grande dimension est évacuée à l'extérieur de la zone protégée par
la jupe imperméable à l'eau via une rigole de drainage disposée approximativement
en position perpendiculaire à ladite rigole de drainage principale.
10. Utilisation du procédé selon l'une quelconque des revendications 1 à 9 pour augmenter
l'intervalle de temps séparant deux inspections successives des joints étanches et
de la base de réservoirs de stockage de grandes dimensions.