| (19) |
 |
|
(11) |
EP 1 638 715 B1 |
| (12) |
EUROPEAN PATENT SPECIFICATION |
| (45) |
Mention of the grant of the patent: |
|
19.12.2007 Bulletin 2007/51 |
| (22) |
Date of filing: 23.06.2004 |
|
| (51) |
International Patent Classification (IPC):
|
| (86) |
International application number: |
|
PCT/CA2004/000927 |
| (87) |
International publication number: |
|
WO 2004/112992 (29.12.2004 Gazette 2004/53) |
|
| (54) |
METHOD FOR CASTING COMPOSITE INGOT
VERFAHREN UND VORRICHTUNG ZUR HERSTELLUNG VON VERBUNDMETALLSTRÄNGEN
PROCEDE DE COULAGE D'UN LINGOT COMPOSITE
|
| (84) |
Designated Contracting States: |
|
AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IT LI LU MC NL PL PT RO SE SI SK TR
|
|
Designated Extension States: |
|
AL HR LT LV MK |
| (30) |
Priority: |
24.06.2003 US 482229 P
|
| (43) |
Date of publication of application: |
|
29.03.2006 Bulletin 2006/13 |
| (60) |
Divisional application: |
|
07117678.8 |
| (73) |
Proprietor: Novelis Inc. |
|
Toronto, ON M8Z 1J5 (CA) |
|
| (72) |
Inventors: |
|
- ANDERSON, Mark, Douglas
Green Acres, WA 99016 (US)
- KUBO, Kenneth, Takeo
Milwaukie, Oregon 97267 (US)
- BISCHOFF, Todd, F.
Veradale, WA 99037 (US)
- FENTON, Wayne, J.
Spokane, WA 99216 (US)
- REEVES, Eric, W.
Hayden, ID 83835 (US)
- SPENDLOVE, Brent
Spokane, WA 99216 (US)
- WAGSTAFF, Robert, Bruce
Green Acres, WA 99016 (US)
|
| (74) |
Representative: Boydell, John Christopher et al |
|
Stevens Hewlett & Perkins
Halton House
20/23 Holborn GB-London EC1N 2JD GB-London EC1N 2JD (GB) |
| (56) |
References cited: :
EP-A- 0 189 313 EP-A- 0 636 440 DE-A- 4 420 697 GB-A- 856 424 GB-A- 1 266 570 SU-A- 1 447 544 US-A- 3 421 569 US-A1- 2003 062 143
|
EP-A- 0 219 581 WO-A-03/035305 FR-A1- 2 835 455 GB-A- 1 174 764 GB-A- 2 003 556 US-A- 3 353 934 US-A- 4 449 568
|
|
| |
|
|
- PATENT ABSTRACTS OF JAPAN vol. 0041, no. 08 (M-024), 5 August 1980 (1980-08-05) -&
JP 55 068156 A (SUMITOMO METAL IND LTD), 22 May 1980 (1980-05-22)
- PATENT ABSTRACTS OF JAPAN vol. 008, no. 174 (M-316), 10 August 1984 (1984-08-10) &
JP 59 066962 A (MITSUBISHI JUKOGYO KK; others: 01), 16 April 1984 (1984-04-16)
- PATENT ABSTRACTS OF JAPAN vol. 1996, no. 10, 31 October 1996 (1996-10-31) & JP 08
164469 A (NIKKO KINZOKU KK; FUJI ELECTRIC CO LTD), 25 June 1996 (1996-06-25)
|
|
| |
|
| Note: Within nine months from the publication of the mention of the grant of the European
patent, any person may give notice to the European Patent Office of opposition to
the European patent
granted. Notice of opposition shall be filed in a written reasoned statement. It shall
not be deemed to
have been filed until the opposition fee has been paid. (Art. 99(1) European Patent
Convention).
|
Background of the Invention
1. Technical Field
[0001] This invention relates to a method and apparatus for casting composite metal ingots,
as well as novel composite metal ingots thus obtained.
2. Background Art
[0002] For many years metal ingots, particularly aluminum or aluminum alloy ingots, have
been produced by a semi-continuous casting process known as direct chill casting.
In this procedure molten metal has been poured into the top of an open ended mould
and a coolant, typically water, has been applied directly to the solidifying surface
of the metal as it emerges from the mould.
[0003] Such a system is commonly used to produce large rectangular-section ingots for the
production of rolled products, e.g. aluminum alloy sheet products. There is a large
market for composite ingots consisting of two or more layers of different alloys.
Such ingots are used to produce, after rolling, clad sheet for various applications
such as brazing sheet, aircraft plate and other applications where it is desired that
the properties of the surface be different from that of the core.
[0004] The conventional approach to such clad sheet has been to hot roll slabs of different
alloys together to "pin" the two together, then to continue rolling to produce the
finished product. This has a disadvantage in that the interface between the slabs
is generally not metallurgically clean and bonding of the layers can be a problem.
[0005] There has also been an interest in casting layered ingots to produce a composite
ingot ready for rolling. This has typically been carried out using direct chill (DC)
casting, either by simultaneous solidification of two alloy streams or sequential
solidification where one metal is solidified before being contacted by a second molten
metal. A number of such methods are described in the literature that have met with
varying degrees of success.
[0006] In
Binczewski, U.S. Patent 4,567,936, issued February 4, 1986, a method is described for producing a composite ingot by DC casting where an outer
layer of higher solidus temperature is cast about an inner layer with a lower solidus
temperature. The disclosure states that the outer layer must be "fully solid and sound"
by the time the lower solidus temperature alloy comes in contact with it.
[0008] In
Robinson, U.S. Patent 3,353,934, issued November 21, 1967 a casting system is described where an internal partition is placed within the mould
cavity to substantially separate areas of different alloy compositions. The end of
the baffle is designed so that it terminates in the "mushy zone" just above the solidified
portion of the ingot. Within the "mushy zone" alloy is free to mix under the end of
the baffle to form a bond between the layers. However, the method is not controllable
in the sense that the baffle used is "passive" and the casting depends on control
of the sump location - which is indirectly controlled by the cooling system.
[0009] In
Matzner, German patent DE 44 20 697, published December 21, 1995 a casting system is described using a similar internal partition to Robinson, in
which the baffle sump position is controlled to allow for liquid phase mixing of the
interface zone to create a continuous concentration gradient across the interface.
[0010] In
Robertson et al, British patent GB 1,174,764, filed 21 December 1965 published 17 Dec 1969, a moveable baffle is provided to divide up a common casting
sump and allow casting of two dissimilar metals. The baffle is moveable to allow in
one limit the metals to completely intermix and in the other limit to cast two separate
strands.
[0011] In
Kilmer et al., WO Publication 2003/035305, published May 1, 2003 a casting system is described using a barrier material in the form of a thin sheet
between two different alloy layers. The thin sheet has a sufficiently high melting
point that it remains intact during casting, and is incorporated into the final product.
[0012] Takeuchi et al., U.S. Patent 4,828,015, issued May 9, 1989 describes a method of casting two liquid alloys in a single mould by creating a partition
in the liquid zone by means of a magnetic field and feeding the two zones with separate
alloys. The alloy that is to the upper part of the zone thereby forms a shell around
the metal fed to the lower portion.
[0015] Takeda et al., U.S. Patent 4,498,521 describes a metal level control system using a float on the surface of the metal
to measure metal level and feedback to the metal flow control.
[0018] Binczewski, European Patent application no. EP 0 219 581 A1, describes a method and system for continuously casting a composite metal article
in a direct chill mould. The molten metal is fed to different sides of a divider in
the mold, and initial contact of the metals is between molten metal in a core and
fully solidified metal in a cladding component.
[0019] It is an object of the present invention to produce a composite metal ingot consisting
of two or more layers having an improved metallurgical bond between adjoining layers.
[0020] It is further object of the present invention to provide a means for controlling
the interface temperature where two or more layers join in a composite ingot to improve
the metallurgical bond between adjoining layers.
[0021] It is further object of the present invention to provide a means for controlling
the interface shape where two or more alloys are combined in a composite metal ingot.
[0022] It is a further object of the present invention to provide a sensitive method for
controlling the metal level in an ingot mould that is particularly useful in confined
spaces.
Disclosure of the Invention
[0023] One embodiment of the present invention is a method for the casting of a composite
metal ingot comprising at least two layers formed of one or more alloys compositions.
The method comprises providing an open ended annular mould having a feed end and an
exit end wherein molten metal is added at the feed end and a solidified ingot is extracted
from the exit end. Divider walls are used to divide the feed end into at least two
separate feed chambers, the divider walls terminating above the exit end of the mould,
and where each feed chamber is adjacent at least one other feed chamber. For each
pair of adjacent feed chambers a first stream of a first alloy is fed to one of the
pair of feed chambers to form a pool of metal in the first chamber and a second stream
of a second alloy is fed through the second of the pair of feed chambers to form a
pool of metal in the second chamber. The first metal pool contacts the divider wall
between the pair of chambers to cool the first pool so as to form a self-supporting
surface adjacent the divider wall. The second metal pool is then brought into contact
with the first pool so that the second pool first contacts the self-supporting surface
of the first pool at a point where the temperature of the self-supporting surface
is between the solidus and liquidus temperatures of the first alloy. The two alloy
pools are thereby joined as two layers and cooled to form a composite ingot.
[0024] Preferably the second alloy initially contacts the self-supporting surface of the
first alloy when the temperature of the second alloy is above the liquidus temperature
of the second alloy. The first and second alloys may have the same alloy composition
or may have different alloy compositions.
[0025] Preferably the upper surface of the second alloy contacts the self-supporting surface
of the first pool at a point where the temperature of the self-supporting surface
is between the solidus and liquidus temperatures of the first alloy.
[0026] In this embodiment of the invention the self-supporting surface may be generated
by cooling the first alloy pool such that the surface temperature at the point where
the second alloy first contacts the self-supporting surface is between the liquidus
and solidus temperature.
[0027] Another embodiment of the present invention comprises a method for the casting of
a composite metal ingot comprising at least two layers formed of one or more alloys
compositions. This method comprises providing an open ended annular mould having a
feed end and an exit end wherein molten metal is added at the feed end and a solidified
ingot is extracted from the exit end. Divider walls are used to divide the feed end
into at least two separate feed chambers, the divider walls terminating above the
exit end of the mould, and where each feed chamber is adjacent at least one other
feed chamber. For each pair of adjacent feed chambers a first stream of a first alloy
is fed to one of the pair of feed chambers to form a pool of metal in the first chamber
and a second stream of a second alloy is fed through the second of the pair of feed
chambers to form a pool of metal in the second chamber. The first metal pool contacts
the divider wall between the pair of chambers to cool the first pool so as to form
a self-supporting surface adjacent the divider wall. The second metal pool is then
brought into contact with the first pool so that the second pool first contacts the
self-supporting surface of the first pool at a point where the temperature of the
self-supporting surface is below the solidus temperature of the first alloy to form
an interface between the two alloys. The interface is then reheated to a temperature
between the solidus and liquidus temperature of the first alloy so that the two alloy
pools are thereby joined as two layers and cooled to form a composite ingot.
[0028] In this embodiment the reheating is preferably achieved by allowing the latent heat
within the first or second alloy pools to reheat the surface.
[0029] Preferably the second alloy initially contacts the self-supporting surface of the
first alloy when the temperature of the second alloy is above the liquidus temperature
of the second alloy. The first and second alloys may have the same alloy composition
or may have different alloy compositions.
[0030] Preferably the upper surface of the second alloy contacts the self-supporting surface
of the first pool at a point where the temperature of the, self-supporting surface
is between the solidus and liquidus temperatures of the first alloy.
[0031] The self-supporting surface may also have an oxide layer formed on it. It is sufficiently
strong to support the splaying forces normally causing the metal to spread out when
unconfined. These splaying forces include the forces created by the metallostatic
head of the first stream, and expansion of the surface in the case where cooling extends
below the solidus followed by re-heating the surface. By bringing the liquid second
alloy into first contact with the first alloy while the first alloy is still in the
semi-solid state or, and in the alternate embodiment, by ensuring that the interface
between the alloys is reheated to a semi-solid state, a distinct but joining interface
layer is formed between the two alloys. Furthermore, the fact that the interface between
the second alloy layer and the first alloy is thereby formed before the first alloy
layer has developed a rigid shell means that stresses created by the direct application
of coolant to the exterior surface of the ingot are better controlled in the finished
product, which is particularly advantageous when casting crack prone alloys.
[0032] The result of the present invention is that the interface between the first and second
alloy is maintained, over a short length of emerging ingot, at a temperature between
the solidus and liquidus temperature of the first alloy. In one particular embodiment,
the second alloy is fed into the mould so that the upper surface of the second alloy
in the mould is in contact with the surface of the first alloy where the surface temperature
is between the solidus and liquidus temperature and thus an interface having met this
requirement is formed. In an alternate embodiment, the interface is reheated to a
temperature between the solidus and liquidus temperature shortly after the upper surface
of the second alloy contacts the self-supporting surface of the first alloy. Preferably
the second alloy is above its liquidus temperature when it first contacts the surface
of the first alloy. When this is done, the interface integrity is maintained but at
the same time, certain alloy components are sufficiently mobile across the interface
that metallurgical bonding is facilitated.
[0033] If the second alloy is contacted where the temperature of the surface of the first
alloy is sufficiently below the solidus (for example after a significant solid shell
has formed), and there is insufficient latent heat to reheat the interface to a temperature
between the solidus and liquidus temperatures of the first alloy, then the mobility
of alloy components is very limited and a poor metallurgical bond is formed. This
can cause layer separation during subsequent processing.
[0034] If the self-supporting surface is not formed on the first alloy prior to the second
alloy contacting the first alloy, then the alloys are free to mix and a diffuse layer
or alloy concentration gradient is formed at the interface, making the interface less
distinct.
[0035] It is particularly preferred that the upper surface of the second alloy be maintained
a position below the bottom edge of the divider wall. If the upper surface of the
second alloy in the mould lies above the point of contact with the surface of the
first alloy, for example, above the bottom edge of the divider wall, then there is
a danger that the second alloy can disrupt the self supporting surface of the first
alloy or even completely re-melt the surface because of excess latent heat. If this
happens, there may be excessive mixing of alloys at the interface, or in some cases
runout and failure of the cast. If the second alloy contacts the divider wall particularly
far above the bottom edge, it may even be prematurely cooled to a point where the
contact with the self-supporting surface of the first alloy no longer forms a strong
metallurgical bond. In certain cases it may however be advantageous to maintain the
upper surface of the second alloy close to the bottom edge of the divider wall but
slightly above the bottom edge so that the divider wall can act as an oxide skimmer
to prevent oxides from the surface of the second layer from being incorporated in
the interface between the two layers. This is particularly advantageous where the
second alloy is prone to oxidation. In any case the upper surface position must be
carefully controlled to avoid the problems noted above, and should not lie more than
about 3 mm above the bottom end of the divider.
[0036] In all of the preceding embodiments it is particularly advantageous to contact the
second alloy to the first at a temperature between the solidus and coherency temperature
of the first alloy or to reheat the interface between the two to a temperature between
the solidus and coherency temperature of the first alloy. The coherency point, and
the temperature (between the solidus and liquidus temperature) at which it occurs
is an intermediate stage in the solidification of the molten metal. As dendrites grow
in size in a cooling molten metal and start to impinge upon one another, a continuous
solid network builds up throughout the alloy volume. The point at which there is a
sudden increase in the torque force needed to shear the solid network is known as
the "coherency point". The description of coherency point and its determination can
be found in Solidification Characteristics of Aluminum Alloys Volume 3 Dendrite Coherency
Pg 210.
[0037] In another embodiment of the invention, there is provided an apparatus for casting
metal comprising an open ended annular mould having a feed end and an exit end and
a bottom block that can fit within the exit end and is movable in a direction along
the axis of the annular mould. The feed end of the mould is divided into at least
two separate feed chambers, where each feed chamber is adjacent at least one other
feed chamber and where the adjacent feed chambers are separated by a temperature controlled
divider wall that can add or remove heat. The divider wall ends above the exit end
of the mould. Each chamber includes a metal level control apparatus such that in adjacent
pairs of chambers the metal level in one chamber can be maintained at a position above
the lower end of the divider wall between the chambers and in the other chamber can
be maintained at a different position from the level in the first chamber.
[0038] Preferably the level in the other chamber is maintained at a position below the lower
end of the divider wall.
[0039] The divider wall is designed so that the heat extracted or added is calibrated so
as to create a self-supporting surface on metal in the first chamber adjacent the
divider wall and to control the temperature of the self-supporting surface of the
metal in the first chamber to lie between the solidus and liquidus temperature at
a point where the upper surface of the metal in the second chamber can be maintained.
[0040] The temperature of the self-supporting layer can be carefully controlled by removing
heat from the divider wall by a temperature control fluid being passed through a portion
of the divider wall or being brought into contact with the divider wall at its upper
end to control the temperature of the self-supporting layer.
[0041] A further embodiment of the invention is a method for the casting of a composite
metal ingot comprising at least two different alloys, which comprises providing an
open ended annular mould having a feed end and an exit end and means for dividing
the feed end into at least two separate, feed chambers, where each feed chamber is
adjacent at least one other feed chamber. For each pair of adjacent feed chambers,
a first stream of a first alloy is fed through one of the adjacent feed chambers into
said mould, a second stream of a second alloy is fed through another of the adjacent
feed chambers. A temperature controlling divider wall is provided between the adjacent
feed chambers such that the point on the interface where the first and second alloy
initially contact each other is maintained at a temperature between the solidus and
liquidus temperatures of the first alloy by means of the temperature controlling divider
wall whereby the alloy streams are joined as two layers. The joined alloy layers are
cooled to form a composite ingot.
[0042] The second alloy is preferably brought into contact with the first alloy immediately
below the bottom of the divider wall without first contacting the divider wall. In
any event, the second alloy should contact the first alloy no less than about 2 mm
below the bottom edge of the divider wall but not greater than 20 mm and preferably
about 4 to 6 mm below the bottom edge of the divider wall.
[0043] If the second alloy contacts the divider wall before contacting the first alloy,
it may be prematurely cooled to a point where the contact with the self-supporting
surface of the first alloy no longer forms a strong metallurgical bond. Even if the
liquidus temperature of the second alloy is sufficiently low that this does not happen,
the metallostatic head that would exist may cause the second alloy to feed up into
the space between the first alloy and the divider wall and cause casting defects or
failure. When the upper surface of the second alloy is desired to be above the bottom
edge of the divider wall (e.g. to skim oxides) it must be carefully controlled and
positioned as close as practically possible to the bottom edge of the divider wall
to avoid these problems.
[0044] The divider wall between adjacent pairs of feed chambers may be tapered and the taper
may vary along the length of the divider wall. The divider wall may further have a
curvilinear shape. These features can be used to compensate for the different thermal
and solidification properties of the alloys used in the chambers separated by the
divider wall and thereby provide for control of the final interface geometry within
the emerging ingot. The curvilinear shaped wall may also serve to form ingots with
layers having specific geometries that can be rolled with less waste. The divider
wall between adjacent pairs of feed chambers may be made flexible and may be adjusted
to ensure that the interface between the two alloy layers in the final cast and rolled
product is straight regardless of the alloys used and is straight even in the start-up
section.
[0045] A further embodiment of the invention is an apparatus for casting of composite metal
ingots, comprising an open ended annular mould having a feed end and an exit end and
a bottom block that can fit inside the exit end and move along the axis of the mould.
The feed end of the mould is divided into at least two separate feed chambers, where
each feed chamber is adjacent at least one other feed chamber and where the adjacent
feed chambers are separated by a divider wall. The divider wall is flexible, and a
positioning device is attached to the divider wall so that the wall curvature in the
plane of the mould can be varied by a predetermined amount during operation.
[0046] A further embodiment of the invention is a method for the casting of a composite
metal ingot comprising at least two different alloys, which comprises providing an
open ended annular mould having a feed end and an exit end and means for dividing
the feed end into at least two separate, feed chambers, where each feed chamber is
adjacent at least one other feed chamber. For adjacent pairs of the feed chambers,
a first stream of a first alloy is fed through one of the adjacent feed chambers into
the mould, and a second stream of a second alloy is fed through another of the adjacent
feed chambers. A flexible divider wall is provided between adjacent feed chambers
and the curvature of the flexible divider wall is adjusted during casting to control
the shape of interface where the alloys are joined as two layers. The joined alloy
layers are then cooled to form a composite ingot.
[0047] The metal feed requires careful level control and one such method is to provide a
slow flow of gas, preferably inert, through a tube with an opening at a fixed point
with respect to the body of the annular mould. The opening is immersed in use below
the surface of the metal in the mould, the pressure of the gas is measured and the
metallostatic head above the tube opening is thereby determined. The measured pressure
can therefore be used-to directly control the metal flow into the mould so as to maintain
the upper surface of the metal at a constant level.
[0048] A further embodiment of the invention is a method of casting a metal ingot which
comprises providing an open ended annular mould having a feed end and an exit end,
and feeding a stream of molten metal into the feed end of said mould to create a metal
pool within said mould having a surface. The end of a gas delivery tube is immersed
into the metal pool from the feed end of mould tube at a predetermined position with
respect to the mould body and an inert gas is bubbled though the gas delivery tube
at a slow rate sufficient to keep the tube unfrozen. The pressure of the gas within
the said tube is measured to determine the position of the molten metal surface with
respect to the mould body.
[0049] A further embodiment of the invention is an apparatus for casting a metal ingot that
comprises an open-ended annular mould having a feed end and an exit end and a bottom
block that fits in the exit end and is movable along the axis of the mould. A metal
flow control device is provided for controlling the rate at which metal can flow into
the mould from an external source, and a metal level sensor is also provided comprising
a gas delivery tube attached to a source of gas by means of a gas flow controller
and having an open end positioned at a predefined location below the feed end of the
mould, such that in use, the open end of the tube would normally lie below the metal
level in the mould. A means is also provided for measuring the pressure of the gas
in the gas delivery tube between the flow controller and the open end of the gas delivery
tube, the measured pressure of the gas being adapted to control the metal flow control
device so as to maintain the metal into which the open end of the gas delivery tube
is placed at a predetermined level.
[0050] This method and apparatus for measuring metal level is particularly useful in measuring
and controlling metal level in a confined space such as in some or all of the feed
chambers in a multi-chamber mould design. It may be used in conjunction with other
metal level control systems that use floats or similar surface position monitors,
where for example, a gas tube is used in smaller feed chambers and a feed control
system based on a float or similar device in the larger feed chambers.
[0051] In one preferred embodiment of the present invention there is provided a method for
casting a composite ingot having two layer of different alloys, where one alloy forms
a layer on the wider or "rolling" face of a rectangular cross-sectional ingot formed
from another alloy. For this procedure there is provided an open ended annular mould
having a feed end and an exit end and means for dividing the feed end into separate
adjacent feed chambers separated by a temperature controlled divider wall. The first
stream of a first alloy is fed though one of the feed chambers into the mould and
a second stream of a second alloy is fed through another of the feed chambers, this
second alloy having a lower liquidus temperature than the first alloy. The first alloy
is cooled by the temperature controlled divider wall to form a self-supporting surface
that extends below the lower end of the divider wall and the second alloy is contacted
with the self-supporting surface of the first alloy at a location where the temperature
of the self-supporting surface is maintained between the solidus and liquidus temperature
of the first alloy, whereby the two alloy streams are joined as two layers. The joined
alloy layers are then cooled to form a composite ingot.
[0052] In another preferred embodiment the two chambers are configured so that an outer
chamber completely surrounds the inner chamber whereby an ingot is formed having a
layer of one alloy completely surrounding a core of a second alloy.
[0053] A preferred embodiment includes two laterally spaced temperature controlled divider
walls forming three feed chambers. Thus, there is a central feed chamber with a divider
wall on each side and a pair of outer feed chambers on each side of the central feed
chamber. A stream of the first alloy may be fed through the central feed chamber,
with streams of the second alloy being fed into the two side chambers. Such an arrangement
is typically used for providing two cladding layers on a central core material.
[0054] It is also possible to reverse the procedure such that streams of the first alloy
are feed through the side chambers while a stream of the second alloy is fed through
the central chamber. With this arrangement, casting is started in the side feed chambers
with the second alloy being fed through the central chamber and contacting the pair
of first alloys immediately below the divider walls.
[0055] The ingot cross-sectional shape may be any convenient shape (for example circular,
square, rectangular or any other regular or irregular shape) and the cross-sectional
shapes of individual layers may also vary within the ingot.
[0056] Another embodiment of the invention is a cast ingot product consisting of an elongated
ingot comprising, in cross-section, two or more separate alloy layers of differing
composition, wherein the interface between adjacent alloys layers is in the form of
a substantially continuous metallurgical bond. This bond is characterized by the presence
of dispersed particles of one or more intermetallic compositions of the first alloy
in a region of the second alloy adjacent the interface. Generally in the present invention
the first alloy is the one on which a self-supporting surface is first formed and
the second alloy is brought into contact with this surface while the surface temperature
is between the soldidus and liquidus temperature of the first alloy, or the interface
is subsequently reheated to a temperature between the solidus and liquidus temperature
of the first alloy. The dispersed particles preferably are less than about 20 µm in
diameter and are found in,a region of up to about 200 µm from the interface.
[0057] The bond may be further characterized by the presence of plumes or exudates of one
or more intermetallic compositions of the first alloy extending from the interface
into the second alloy in the region adjacent the interface. This feature is particularly
formed when the temperature of the self-supporting surface has not been reduced below
the solidus temperature prior to contact with the second alloy.
[0058] The plumes or exudates preferably penetrate less than about 100 µm into the second
alloy from the interface.
[0059] Where the intermetallic compositions of the first alloy are dispersed or exuded into
the second alloy, there remains in the first alloy, adjacent to the interface between
the first and second alloys, a layer which contains a reduced quantity of the intermetallic
particles and which consequently can form a layer which is more noble than the first
alloy and may impart corrosion resistance to the clad material. This layer is typically
4 to 8 mm thick.
[0060] This bond may be further characterized by the presence of a diffuse layer of alloy
components of the first alloy in the second alloy layer adjacent the interface. This
feature is particularly formed in instances where the surface of the first alloy is
cooled below the solidus temperature of the first alloy and then the interface between
first and second alloy is reheated to between the solidus and liquidus temperatures.
[0061] Although not wishing to be bound by any theory, it is believed that the presence
of these features is caused by formation of segregates of intermetallic compounds
of the first alloy at the self supporting surface formed on it with their subsequent
dispersal or exudation into the second alloy after it contacts the surface. The exudation
of intermetallic compounds is assisted by splaying forces present at the interface.
[0062] A further feature of the interface between layers formed by the methods of this invention
is the presence of alloy components from the second alloy between the grain boundaries
of the first alloy immediately adjacent the interface between the two alloys. It is
believed that these arise when the second alloy (still generally above its liquidus
temperature) comes in contact with the self-supporting surface of the first alloy
(at a temperature between the solidus and liquidus temperature of the first alloy).
Under these specific conditions, alloy component of the second alloy can diffuse a
short distance (typically about 50 µm) along the still liquid grain boundaries, but
not into the grains already formed at the surface of the first alloy. If the interface
temperature in above the liquidus temperature of both alloys, general mixing of the
alloys will occur, and the second alloy components will be found within the grains
as well as grain boundaries. If the interface temperature is below the solidus temperature
of the first alloy, there will be not opportunity for grain boundary diffusion to
occur.
[0063] The specific interfacial features described are specific features caused by solid
state diffusion, or diffusion or movement of elements along restricted liquid paths
and do not affect the generally distinct nature of the overall interface.
[0064] Regardless how the interface is formed, the unique structure of the interface provides
for a strong metallurgical bond at the interface and therefore makes the structure
suitable for rolling to sheet without problems associated with delamination or interface
contamination.
[0065] In yet a further embodiment of the invention, there is a composite metal ingot, comprising
at least two layers of metal, wherein pairs of adjacent layers are formed by contacting
the second metal layer to the surface of the first metal layer such that the when
the second metal layer first contacts the surface of the first metal layer the surface
of the first metal layer is at a temperature between its liquidus and solidus temperature
and the temperature of the second metal layer is above its liquidus temperature. Preferably
the two metal layers are composed of different alloys.
[0066] Similarly in yet a further embodiment of the invention, there is a composite metal
ingot, comprising at least two layers of metal, wherein pairs of adjacent layers are
formed by contacting the second metal layer to the surface of the first metal layer
such that the when the second metal layer first contacts the surface of the first
metal layer the surface of the first metal layer is at a temperature below its solidus
temperature and the temperature of the second metal layer is above its liquidus temperature,
and the interface formed between the two metal layers is subsequently reheated to
a temperature between the solidus and liquidus temperature of the first alloy. Preferably
the two metal layers are composed of different alloys.
[0067] In one preferred embodiment, the ingot is rectangular in cross section and comprises
a core of the first alloy and at least one surface layer of the second alloy, the
surface layer being applied to the long side of the rectangular cross-section. This
composite metal ingot is preferably hot and cold rolled to form a composite metal
sheet.
[0068] In one particularly preferred embodiment, the alloy of the core is an aluminum-manganese
alloy and the surface alloy is an aluminum-silicon alloy. Such composite ingot when
hot and cold rolled to form a composite metal brazing sheet that may be subject to
a brazing operation to make a corrosion resistant brazed structure.
[0069] In another particularly preferred embodiment, the alloy core is a scrap aluminum
alloy and the surface alloy a pure aluminum alloy. Such composite ingots when hot
and cold rolled to form composite metal sheet provide for inexpensive recycled products
having improved properties of corrosion resistance, surface finishing capability,
etc. In the present context a pure aluminum alloy is an aluminum alloy having a thermal
conductivity greater than 190 watts/m/K and a solidification range of less than 50°C.
[0070] In yet another particularly preferred embodiment the alloy core is a high strength
non-heat treatable alloy (such as an Al-Mg alloy) and the surface alloy is a brazeable
alloy (such as an Al-Si alloy). Such composite ingots when hot and cold rolled to
form composite metal sheet may be subject to a forming operation and used for automotive
structures which can then be brazed or similarly joined.
[0071] In yet another particularly preferred embodiment the alloy core is a high strength
heat treatable alloy (such as an 2xxx alloy) and the surface alloy is a pure aluminum
alloy. Such composite ingots when hot and cold rolled form composite metal sheet suitable
for aircraft structures. The pure alloy may be selected for corrosion resistance or
surface finish and should preferably have a solidus temperature greater than the solidus
temperature of the core alloy.
[0072] In yet another particularly preferred embodiment the alloy core is a medium strength
heat treatable alloy (such as an Al-Mg-Si alloy) and the surface alloy is a pure aluminum
alloy. Such composite ingots when hot and cold rolled form composite metal sheet suitable
for automotive closures. The pure alloy may be selected for corrosion resistance or
surface finish and should preferably have a solidus temperature greater than the solidus
temperature of the core alloy.
[0073] In another preferred embodiment, the ingot is cylindrical in cross-section and comprises
a core of the first alloy and a concentric surface layer of the second alloy. In yet
another preferred embodiment, the ingot is rectangular or square in cross-section
and comprises a core of the second alloy and a annular surface layer of the first
alloy.
Brief Description of the Drawings
[0074] In the drawings which illustrate certain preferred embodiments of this invention:
Fig. 1 is an elevation view in partial section showing a single divider wall;
Fig. 2 is a schematic illustration of the contact between the alloys;
Fig. 3 is an elevation view in partial section similar to Fig. 1, but showing a pair
of divider walls;
Fig. 4 is an elevation view in partial section similar to Fig. 3, but with the second
alloy having a lower liquidus temperature than the first alloy being fed into the
central chamber;
Figs. 5a, 5b and 5c are plan views showing some alternative arrangements of feed chamber
that may be used with the present invention;
Fig. 6 is an enlarged view in partial section of a portion of Fig. 1 showing a curvature
control system;
Fig. 7 is a plan view of a mould showing the effects of variable curvature of the
divider wall;
Fig. 8 is an enlarged view of a portion of Fig. 1 illustrating a tapered divider wall
between alloys;
Fig. 9 is a plan view of a mould showing a particularly preferred configuration of
a divider wall;
Fig. 10 is a schematic view showing the metal level control system of the present
invention;
Fig. 11 is a perspective view of a feed system for one of the feed chambers of the
present invention;
Fig. 12 is a plan view of a mould showing another preferred configuration of the divider
wall;
Fig. 13 is a microphotograph of a section through the joining face between a pair
of adjacent alloys using the method of the present invention showing the formation
of intermetallic particles in the opposite alloy;
Fig. 14 is a microphotograph of a section through the same joining face as in Fig.
13 showing the formation of intermetallic plumes or exudates;
Fig. 15 is a microphotograph of a section through the joining face between a pair
of adjacent alloys processed under conditions outside the scope of the present invention;
Fig. 16 is a microphotograph of a section through the joining face between a cladding
alloy layer and a cast core alloy using the method of the present invention;
Fig. 17 is a microphotograph of a section through the joining face between a cladding
alloy layer and a cast core alloy using the method of the present invention, and illustrating
the presence of components of core alloy solely along grain boundaries of the cladding
alloy at the joining face;
Fig. 18 a microphotograph of a section through the joining face between a cladding
alloy layer and a cast core alloy using the method of the present invention, and illustrating
the presence of diffused alloy components as in Figure 17; and
Fig. 19 a microphotograph of a section through the joining face between a cladding
alloy layer and a cast core alloy using the method of the present invention, and also
illustrating the presence of diffused alloy components as in Figure 17.
Best Modes for Carrying Out the Invention
[0075] With reference to Fig. 1, rectangular casting mould assembly 10 has mould walls 11
forming part of a water jacket 12 from which a stream of cooling water 13 is dispensed.
[0076] The feed portion of the mould is divided by a divider wall 14 into two feed chambers.
A molten metal delivery trough 30 and delivery nozzle 15 equipped with an adjustable
throttle 32 feeds a first alloy into one feed chamber and a second metal delivery
trough 24 equipped with a side channel, delivery nozzle 16 and adjustable throttle
31 feeds a second alloy into a second feed chamber. The adjustable throttles 31, 32
are adjusted either manually or responsive to some control signal to adjust the flow
of metal into the respective feed chambers. A vertically movable bottom block unit
17 supports the embryonic composite ingot being formed and fits into the outlet end
of the mould prior to starting a cast and thereafter is lowered to-allow the ingot
to form.
[0077] As more clearly shown with reference to Figure 2, in the first feed chamber, the
body of molten metal 18 gradually cools so as to form a self-supporting surface 27
adjacent the lower end of the divider wall and then forms a zone 19 that is between
liquid and solid and is often referred as a mushy zone. Below this mushy or semi-solid
zone is a solid metal alloy 20. Into the second feed chamber is fed a second alloy
liquid flow 21 having a lower liquidus temperature than the first alloy 18. This metal
also forms a mushy zone 22 and eventually a solid portion 23.
[0078] The self-supporting surface 27 typically undergoes a slight contraction as the metal
detaches from the divider wall 14 then a slight expansion as the splaying forces caused,
for example, by the metallostatic head of the metal 18 coming to bear. The self-supporting
surface has sufficient strength to restrain such forces even though the temperature
of the surface may be above the solidus temperature of the metal 18. An oxide layer
on the surface can contribute to this balance of forces.
[0079] The temperature of the divider wall 14 is maintained at a predetermined target temperature
by means of a temperature control fluid passing through a closed channel 33 having
an inlet 36 and outlet 37 for delivery and removal of temperature control fluid that
extracts heat from the divider wall so as to create a chilled interface which serves
to control the temperature of the self supporting surface 27 below the lower end of
the divider wall 35. The upper surface 34 of the metal 21 in the second chamber is
then maintained at a position below the lower edge 35 of the divider wall 14 and at
the same time the temperature of the self supporting surface 27 is maintained such
that the surface 34 of the metal 21 contacts this self supporting surface 27 at a
point where the temperature of the surface 27 lies between the solidus and liquidus
temperature of the metal 18. Typically the surface 34 is controlled at a point slightly
below the lower edge 35 of the divider wall 14, generally within about 2 to 20 mm
from the lower edge. The interface layer thus formed between the two alloy streams
at this point forms a very strong metallurgical bond between the two layers without
excessive mixing of the alloys.
[0080] The coolant flow (and temperature) required to establish the temperature of the self-supporting
surface 27 of metal 18 within the desired range is generally determined empirically
by use of small thermocouples that are embedded in the surface 27 of the metal ingot
as it forms and once established for a given composition and casting temperature for
metal 18 (casting temperature being the temperature at which the metal 18 is delivered
to the inlet end of the feed chamber) forms, part of the casting practice for such
an alloy. It has been found in particular that at a fixed coolant flow through the
channel 33, the temperature of the coolant exiting the divider wall coolant channel
measured at the outlet 37 correlates well with the temperature of the self supporting
surface of the metal at predetermined locations below the bottom edge of the divider
wall, and hence provides for a simple and effective means of controlling this critical
temperature by providing a temperature measuring device such as a thermocouple or
thermistor 40 in the outlet of the coolant channel.
[0081] Fig. 3 is essentially the same mould as in Fig. 1, but in this case a pair of divider
walls 14 and 14a are used dividing the mouth of the mould into three feed chambers.
There is a central chamber for the first metal alloy and a pair of outer feed chambers
for a second metal alloy. The outer feed chambers may be adapted for a second and
third metal alloy, in which case the lower ends of the divider walls 14 and 14a may
be positioned differently and the temperature control may differ for the two divider
walls depending on the particular requirements for casting and creating strongly bonded
interfaces between the first and second alloys and between the first and third alloys.
[0082] As shown in Fig. 4, it is also possible to reverse the alloys so that the first alloy
streams are fed into the outer feed chambers and a second alloy stream is fed into
the central feed chamber.
[0083] Figure 5 shows several more complex chamber arrangements in plan view. In each of
these arrangements there is an outer wall 11 shown for the mould and the inner divider
walls 14 separating the individual chambers. Each divider wall 14 between adjacent
chambers must be positioned and thermally controlled such that the conditions for
casting described herein are maintained. This means that the divider walls may extend
downwards from the inlet of the mould and terminate at different positions and may
be controlled at different temperatures and the metal levels in each chamber may be
controlled at different levels in accordance with the requirements of the casting
practice.
[0084] It is advantageous to make the divider wall 14 flexible or capable of having a variable
curvature in the plane of the mould as shown in Figures 6 and 7. The curvature is
normally changed between the start-up position 14' and steady state position 14 so
as to maintain a constant interface throughout the cast. This is achieved by means
of an arm 25 attached at one end to the top of the divider wall 14 and driven in a
horizontal direction by a linear actuator 26. If necessary the actuator is protected
by a heat shield 42.
[0085] The thermal properties of alloys vary considerably and the amount and degree of variation
in the curvature is predetermined based on the alloys selected for the various layers
in the ingot. Generally these are determined empirically as part of a casting practice
for a particular product.
[0086] As shown in Figure 8 the divider wall 14 may also be tapered 43 in the vertical direction
on the side of the metal 18. This taper may vary along the length of the divider wall
14 to further control the shape of the interface between adjacent alloy layer. The
taper may also be used on the outer wall 11 of the mould. This taper or shape can
be established using principals, for example, as described in
U.S. 6,260,602 (Wagstaff) and will again depend on the alloys selected for the adjacent layers.
[0087] The divider wall 14 is manufactured from metal (steel or aluminum for example) and
may in part be manufactured from graphite, for example by using a graphite insert
46 on the tapered surface. Oil delivery channels 48 and grooves 47 may also be used
to provide lubricants or parting substances. Of course inserts and oil delivery configurations
may be used on the outer walls in manner known in the art.
[0088] A particular preferred embodiment of divider wall is shown in Figure 9. The divider
wall 14 extends substantially parallel to the mould sidewall 11 along one or both
long (rolling) faces of a rectangular cross section ingot. Near the ends of the long
sides of the mould, the divider wall 14 has 90° curves 45 and is terminated at locations
50 on the long side wall 11, rather than extending fully to the short side walls.
The clad ingot cast with such a divider wall can be rolled to better maintain the
shape of the cladding over the width of the sheet than occurs in more conventional
roll-cladding processes. The taper described in Figure 8 may also be applied to this
design, where for example, a high degree of taper may be used at curved surface 45
and a medium degree of taper on straight section 44.
[0089] Figure 10 shows a method of controlling the metal level in a casting mould which
can be used in any casting mould, whether or not for casting layered ingots, but is
particularly useful for controlling the metal level in confined spaces as may be encountered
in some metal chambers in moulds for casting multiple layer ingots. A gas supply 51
(typically a cylinder of inert gas) is attached to a flow controller 52 that delivers
a small flow of gas to a gas delivery tube with an open end.53 that is positioned
at a reference location 54 within the mould. The inside diameter of the gas delivery
tube at its exit is typically between 3 to 5 mm. The reference location is selected
so as to be below the top surface of the metal 55 during a casting operation, and
this reference location may vary depending on the requirements of the casting practice.
[0090] A pressure transducer 56 is attached to the gas delivery tube at a point between
the flow controller and the open end so as to measure the backpressure of gas in the
tube. This pressure transducer 56 in turn produces a signal that can be compared to
a reference signal to control the flow of metal entering the chamber by means known
to those skilled in the art. For example an adjustable refractory stopper 57 in a
refractory tube 58 fed in turn from a metal delivery trough 59 may be used. In use,
the gas flow is adjusted to a low level just sufficient to maintain the end of the
gas delivery tube open. A piece of refractory fibre inserted in the open end of the
gas delivery tube is used to dampen the pressure fluctuations caused by bubble formation.
The measured pressure then determines the degree of immersion of the open end of the
gas delivery tube below the surface of the metal in the chamber and hence the level
of the metal surface with respect to the reference location and the flow rate of metal
into the chamber is therefore controlled to maintain the metal surface at a predetermined
position with respect to the reference location.
[0091] The flow controller and pressure transducer are devices that are commonly available
devices. It is particularly preferred however that the flow controller be capable
of reliable flow control in the range of 5 to 10 cc/minute of gas flow. A pressure
transducer able to measure pressures to about 0.1 psi (0.689 kPa) provides a good
measure of metal level control (to within 1 mm) in the present invention and the combination
provides for good control even in view of slight fluctuations in the pressure causes
by the slow bubbling through the open end of the gas delivery tube.
[0092] Figure 11 shows a perspective view of a portion of the top of the mould of the present
invention. A feed system for one of the metal chambers is shown, particularly suitable
for feeding metal into a narrow feed chamber as may be used to produce a clad surface
on an ingot. In this feed system, a channel 60 is provided adjacent the feed chamber
having several small down spouts 61 connected to it which end below the surface of
the metal. Distribution bags 62 made from refractory fabric by means known in the
art are installed around the outlet of each down spout 61 to improve the uniformity
of metal distribution and temperature. The channel in turn is fed from a trough 68
in which a single down spout 69 extends into the metal in the channel and in which
is inserted a flow control stopper (not shown) of conventional design. The channel
is positioned and leveled so that metal flows uniformly to all locations.
[0093] Figure 12 shows a further preferred arrangement of divider walls 14 for casting a
rectangular cross-section ingot clad on two faces. The divider walls have a straight
section 44 substantially parallel to the mould sidewall 11 along one or both long
(rolling) faces of a rectangular cross section ingot. However, in this case each divider
wall has curved end portions 49 which intersect the shorter end wall of the mould
at locations 41. This is again useful in maintaining the shape of the cladding over
the width of the sheet than occurs in more conventional roll-cladding processes. Whilst
illustrated for cladding on two faces, it can equally well be used for cladding on
a single face of the ingot.
[0094] Figure 13 is a microphotograph at 15X magnification showing the interface 80 between
an A1-Mn alloy 81 (X-904 containing 0.74% by weight Mn, 0.55% by weight Mg, 0.3% by
weight Cu, 0.17 % by weight, 0.07% by weight Si and the balance Al and inevitable
impurities) and an Al-Si alloy 82(AA4147 containing 12% by weight Si, 0.19% by weight
Mg and the balance Al and inevitable impurities) cast under the conditions of the
present invention. The Al-Mn alloy had a solidus temperature of 1190°F (643°C) and
a liquidus temperature of 1215°F (657°C). The Al-Si alloy had a solidus temperature
of 1070°F (576°C) and a liquidus temperature of 1080°F (582°C). The Al-Si alloy was
fed into the casting mould such that the upper surface of the metal was maintained
so that it contacted the Al-Mn alloy at a location where a self-supporting surface
has been established on the Al-Mn alloy, but its temperature was between the solidus
and liquidus temperatures of the Al-Mn alloy.
[0095] A clear interface is present on the sample indicating no general mixing of alloys,
but in addition, particles of intermetallic compounds containing Mn 85 are visible
in an approximately 200 µm band within the A1-Si alloy 82 adjacent the interface 80
between the Al-Mn and Al-Si alloys. The intermetallic compounds are mainly MnAl
6 and alpha-AlMn.
[0096] Figure 14 is a microphotograph at 200X magnification showing the interface 80 of
the same alloy combination as in Figure 13 where the self-surface temperature was
not allowed to fall below the solidus temperature of the Al-Mn alloy prior to the
Al-Si alloy contacting it. A plume or exudate 88 is observed extending from the interface
80 into the Al-Si alloy 82 from the A1-Mn alloy 81 and the plume or exudate has a
intermetallic composition containing Mn that is similar to the particles in Figure
13. The plumes or exudates typically extend up to 100 µm into the neighbouring metal.
The resulting bond between the alloys is a strong metallurgical bond. Particles of
intermetallic compounds containing Mn 85 are also visible in this microphotograph
and have a size typically up to 20 µm.
[0097] Figure 15 is a microphotograph (at 300X magnification) showing the interface between
an Al-Mn alloy (AA3003) and an Al-Si alloy (AA4147) but where the Al-Mn self-supporting
surface was cooled more than about 5°C below the solidus temperature of the Al-Mn
alloy, at which point the upper surface of the Al-Si alloy contacted the self-supporting
surface of the Al-Mn alloy. The bond line 90 between the alloys is clearly visible
indicating that a poor metallurgical bond was thereby formed. There is also an absence
of exudates or dispersed intermetallic compositions of the first alloy in the second
alloy.
[0098] A variety of alloy combinations were cast in accordance with the process of the present
invention. The conditions were adjusted so that the first alloy surface temperature
was between its solidus and liquidus temperature at the the upper surface of the second
alloy. In all cases, the alloys were cast into ingots 690mm x 1590mm and 3 metres
long and then processed by conventional preheating, hot rolling and cold rolling.
The alloy combinations cast are given in Table 1 below. Using convention terminology,
the "core" is the thicker supporting layer in a two alloy composite and the "cladding"
is the surface functional layer. In the table, the First Alloy is the alloy cast first
and the second alloy is the alloy brought into contact with the self-supporting surface
of the first alloy.
TABLE 1
| |
First Alloy |
Second Alloy |
| Cast |
Location and alloy |
L-S range (° C) |
Casting temperature (°C) |
Location and alloy |
L-S range (° C) |
Casting temperature (°C) |
| 051804 |
Clad 0303 |
660-659 |
664-665 |
Core 3104 |
654-629 |
675-678 |
| 030826 |
Clad 1200 |
657-646 |
685-690 |
Core 2124 |
638-502 |
688-690 |
| 031013 |
Clad 0505 |
660-659 |
692-690 |
Core 6082 |
645-563 |
680-684 |
| 030827 |
Clad 1050 |
657-646 |
695-697 |
Core 6111 |
650-560 |
686-684 |
[0099] In each of these examples, the cladding was the first alloy to solidify and the core
alloy was applied to the cladding alloy at a point where a self-supporting surface
had formed, but where the surface temperature was still within the L-S range given
above. This may be compared to the example above for brazing sheet where the cladding
alloy had a lower melting range than the core alloy, in which case the cladding alloy
(the "second alloy") was applied to the self supporting surface of the core alloy
(the "first alloy"). Micrographs were taken of the interface between the cladding
and the core in the above four casts. The micrographs were taken at 50X magnification.
In each image the "cladding" layer appears to the left and the "core" layer to the
right.
[0100] Figure 16 shows the interface of Cast #051804 between cladding alloy 0303 and core
alloy 3104. The interface is clear from the change in grain structure in passing from
the cladding material to the relatively more alloyed core layer
[0101] Figure 17 shows the interface of Cast #030826 between cladding alloy 1200 and core
alloy 2124. The interface between the layers is shown by the dotted line 94 in the
Figure. In this figure, the presence of alloy components of the 2124 alloy are present
in the grain boundaries of the 1200 alloy within a short distance of the interface.
These appear as spaced "fingers" of material in the Figure, one of which is illustrated
by the numeral 95.' It can be seen that the 2124 alloy components extend for a distance
of about 50 µm, which typically corresponds to a single grain of the 1200 alloy under
these conditions.
[0102] Figure 18 shows the interface of Cast #031013 between cladding alloy 0505 and core
alloy 6082 and Figure 19 shows the interface of Cast #030827 between cladding alloy
1050 and core alloy 6111. In each of these Figures the presence of alloy components
of the core alloy are gain visible in the grain boundaries of the cladding alloy immediately
adjacent the interface.
1. A method for the casting of a composite metal ingot comprising at least two layers
formed of one or more alloys compositions, which comprises providing an open ended
annular mould (10) having a feed end and an exit end wherein molten metal (18, 21)
is added at the feed end and a solidified ingot is extracted from the exit end, and
divider walls (14, 14a, 14') for dividing the feed end into at least two separate
feed chambers, the divider walls terminating at bottom ends (35) thereof positioned
above the exit end of said mould, with each feed chamber adjacent at least one other
feed chamber, wherein for each pair of the adjacent feed chambers a first stream of
a first alloy (18) is fed to one of the pair of feed chambers to form a pool of metal
in the first chamber and a second stream of a second alloy (21) is fed through the
second of the pair of feed chambers to form a pool of metal in the second chamber,
the pools of metal each having an upper surface, contacting the first alloy pool with
the divider wall between the pair chambers to thereby cool the first alloy pool to
form a self-supporting surface (27) and allowing the second alloy pool to contact
the first alloy pool such that the upper surface (34) of the second alloy pool contacts
the divider wall at a position no more than 3 mm above the bottom end of the divider
wall or contacts the self-supporting surface of the first alloy pool at a point where
the temperature of the self-supporting surface is between the solidus and liquidus
temperatures of the first alloy, whereby the two alloy pools are joined as two layers
(20, 23), and cooling the joined alloy layers to form a composite ingot.
2. A method according to claim 1 wherein the first and second alloys have the same composition.
3. A method according to claim 1 wherein the first alloy and second alloys have different
compositions.
4. A method according to claim 1 wherein the upper surface (34) of the second alloy contacts
the self-supporting surface (27) of the first alloy at a position where the temperature
of the self-supporting surface of the first alloy is between the solidus and liquidus
temperatures thereof.
5. A method according to claim 4 wherein the upper surface (34) of the second alloy contacts
the self-supporting surface (27) of the first alloy at a position where the temperature
of the self-supporting surface of the first alloy is between the solidus and coherency
temperatures thereof.
6. A method according to claim 1 wherein the temperature of the second alloy when it
first contacts the self-supporting surface (27) of the first alloy is greater than
or equal to the liquidus temperature of the second alloy.
7. A method according to any one of claims 1-6 wherein the divider walls (14, 14a, 14')
for dividing the feed end consists of temperature controlled divider walls between
each of the pair of chambers.
8. A method according to claim 7 wherein the temperature controlled divider walls (14,
14a, 14') serve to control the temperature of the self-supporting surface (27) of
the first alloy (18) at the position where the upper surface (34) of the second alloy
(21) contacts the self-supporting surface.
9. A method according to claim 7 wherein a temperature control fluid is contacted with
the temperature controlled divider wall (14, 14a, 14') to control the heat removed
or added via the divider wall.
10. A method according to claim 9 wherein the temperature control fluid flows through
a closed channel (33) and the temperature of the self-supporting surface (27) is controlled
by measuring the exit temperature of the fluid leaving the channel.
11. A method according to any one of claims 1-10 wherein the upper surface (34) of the
second alloy pool is maintained at a level below the lower end of the divider wall
(14, 14a, 14').
12. A method according to claim 11 where the upper surface (34) of the second alloy pool
is maintained within 2 mm of the bottom edge of the divider wall (14, 14a, 14').
13. A method according to any one of claims 1-12 wherein the curvature of the divider
wall 14, 14') is varied during casting.
14. A method according to any one of claims 1-12 wherein the divider wall (14, 14a, 14')
is provided with an outward taper on the face in contact with the first alloy (18)
.
15. A method according to claim 14 wherein the taper varies along the length of the divider
wall (14, 14a, 14').
16. A method according to claim 1 wherein the position of one or more of the metal pool
upper surfaces is controlled by providing a source of gas (51), delivering the gas
by means of an open ended tube wherein the open end (53) is position at a reference
point (54) within a chamber such that in use the open end will lie below the upper
surface (55) in that chamber, controlling the flow rate of the gas to maintain a slow
flow rate of gas through the tube at a rate sufficient to keep the tube open, measuring
the pressure of the gas in the tube, comparing the measured pressure to a predetermined
target and adjusting the flow of metal into the chamber to maintain the upper surface
at a desired position.
17. A method according to claim 1 wherein the mould (10) has a rectangular cross-section
and comprises two feed chambers of differing sizes oriented parallel to the long face
(11) of the rectangular mould so as to form a rectangular ingot with cladding on one
face.
18. A method according to claim 17 wherein the first alloy (18) is fed into the larger
of the two feed chambers.
19. A method according to claim 17 wherein the second alloy (21) is fed into the larger
of the two feed chambers.
20. A method according to claim 17, 18 or 19 wherein the divider wall (14, 14') is substantially
parallel (44) to the long face (11) of the mould with curved end portions (45) that
terminate (50) at the long walls of the mould.
21. A method according to claim 17, 18 or 19 wherein the divider wall (14, 14') is substantially
parallel to the long face (11) of the mould with curved end portions that terminate
at the short end walls of the mould.
22. A method according to claim 1 wherein the mould (10) has a rectangular cross-section
and comprises three feed chambers oriented parallel to the long face (11) of the rectangular
mould, wherein the central chamber is larger than either of the two side chambers
so as to form a rectangular ingot with cladding (23) on two faces.
23. A method according to claim 22 wherein the first alloy (18) is fed to the central
chamber.
24. A method according to claim 22 wherein the second alloy (21) is fed to the central
chamber.
25. A method according to claim 22, 23 or 24 wherein the divider wall (14, 14') is substantially
parallel (44) to the long face (11) of the mould with curved end portions (45) that
terminate (50) at the long walls of the mould.
26. A method according to claim 22, 23 or 24 wherein the divider wall (14, 14') is substantially
parallel to the long face (11) of the mould with curved end portions that terminate
at the short end walls of the mould.
27. Casting apparatus for the production of composite metal ingots, comprising an open
ended annular mould (10) having a feed end and an exit end and a moveable bottom block
(17) adapted to fit within the exit end and movable in a direction along the axis
of the annular mould, wherein the feed end of the mould is divided into at least two
separate feed chambers, each feed chamber being adjacent at least one other feed chamber,
and where adjacent pairs of feed chambers are separated by a temperature controlled
divider wall (14, 14a, 14') terminating above the exit end of the mould, a means (15,
16) for delivering metal (18, 21) to each feed chamber, a means (31, 32) to control
the flow of metal to each feed chamber, and a metal level control apparatus (51, 52,
53, 56) for each chamber such that in adjacent pairs of chambers the metal level in
the first chamber can be maintained at a position above the lower end (35) of the
said temperature controlled divider wall and in the second chamber can be maintained
at a different position relative to the metal level in the first chamber.
28. A casting apparatus according to claim 27 wherein the metal level (34) in the second
chamber can be maintained at a position below the lower end (35) of the divider wall.
29. A casting apparatus according to claim 27 wherein a closed channel (33) for temperature
control fluid having an inlet (36) and an outlet (37) is connected with the temperature
controlled divider wall (14, 14a, 14').
30. A casting apparatus according to claim 29 wherein a temperature measuring device (40)
is provided at the fluid outlet (37).
31. A casting apparatus according to any one of claims 27-30 comprising a linear actuator
(26) and control arm (25) attached to the temperature controlled divider wall (14)
so that the curvature of the divider wall can be varied.
32. A casting apparatus according to any one of claims 27-30 wherein the temperature controlled
divider wall (14) is tapered outwardly on the surface facing the first chamber.
33. A casting apparatus according to claim 32 wherein the taper is varied along the length
of the divider wall.
34. A casting apparatus according to claim 27 comprising a graphite insert (46) on the
surface of the temperature control divider wall (14) facing the first chamber.
35. A casting apparatus according to claim 27 comprising a fluid delivery channel (48)
for providing a lubricant or separating layer to the surface of the divider wall.
36. A casting apparatus according to claim 34 wherein the graphite insert (46) is porous
and one or more fluid delivery channels (48) in the temperature controlled divider
wall (14) are adapted to deliver fluid via the porous graphite insert to the surface
of the divider wall facing the first chamber.
37. A casting apparatus according to claim 27 wherein the metal level control apparatus
comprises a source of gas 51), a flow controller (52) for controlling the flow of
gas from the source, a tube connected to the flow controller at one end and open at
the other end (53), and a pressure gauge (56) attached to the tube for measuring the
pressure of gas in the tube, the open end of the tube being positioned within the
chamber at a predetermined position (54) with respect to the body (10) of the mould,
such that in use the open end of the tube is immersed in the metal in the chamber,
wherein the means to control the flow of metal to the chamber is controlled in response
to the measured pressure from the pressure gauge to maintain the metal level (55)
at a predetermined position.
38. A casting apparatus according to claim 27 wherein the means to deliver metal to the
chamber comprises a metal delivery trough (59) and one or more open ended metal delivery
tubes (58) connected to the trough.
39. A casting apparatus according to claim 38 wherein the one or more open ended tubes
is positioned within the chamber so that in use the open end is immersed in metal.
1. Verfahren zum Gießen eines Verbundmetall-Gussblocks, umfassend zumindest zwei Schichten,
die aus einer oder mehreren Legierungszusammensetzungen ausgebildet sind, welches
das Bereitstellen einer ringförmigen Gussform (10) mit offenem Ende mit einem Zufuhrende
und einem Austrittsende umfasst, wobei geschmolzenes Metall (18, 21) am Zufuhrende
zugeben wird und ein erstarrter Gussblock aus dem Austrittsende herausgezogen wird,
sowie Teilerwände (14, 14a, 14') zur Unterteilung des Zufuhrendes in zumindest zwei
unterschiedliche Zufuhrkammern, wobei die Teilerwände an deren Bodenenden (35), die
oberhalb des Austrittsendes der Gussform positioniert sind, enden, wobei jede Zufuhrkammer
zumindest zu einer anderen Zufuhrkammer benachbart ist und wobei für jedes Paar benachbarter
Zufuhrkammern ein erster Strom einer ersten Legierung (18) zu einem von dem Paar von
Zufuhrkammern zugeführt wird, um einen Pool aus Metall in der ersten Kammer auszubilden,
und ein zweiter Strom einer zweiten Legierung (21) durch die zweite des Paars von
Zufuhrkammern zugeführt wird, um einen Pool aus Metall in der zweiten Kammer auszubilden,
die Pools aus Metall jeweils eine obere Oberfläche aufweisen, die den ersten Legierungspool
mit der Teilerwand zwischen dem Paar von Kammern berührt, um hierdurch den ersten
Legierungspool abzukühlen, um eine sich selbst tragende Oberfläche (27) auszubilden
und es dem zweiten Legierungspool zu ermöglichen, den ersten Legierungspool derart
zu berühren, dass die obere Oberfläche (34) des zweiten Legierungspools die Teilerwand
an einer Position nicht mehr als 3 mm oberhalb des Bodenendes der Teilerwand berührt
oder die selbsttragende Oberfläche des ersten Legierungspools an einem Punkt berührt,
wo die Temperatur der selbsttragenden Oberfläche zwischen den Solidus- und Liquidus-Temperaturen
der ersten Legierung liegt, wodurch die zwei Legierungspools als zwei Schichten (20,
23) miteinander verbunden werden, und Abkühlen der verbundenen Legierungsschichten,
um einen Verbund-Gussblock auszubilden.
2. Verfahren gemäß Anspruch 1, wobei die ersten und zweiten Legierungen die gleiche Zusammensetzung
aufweisen.
3. Verfahren gemäß Anspruch 1, wobei die erste Legierung und die zweite Legierung unterschiedliche
Zusammensetzungen aufweisen.
4. Verfahren gemäß Anspruch 1, wobei die obere Oberfläche (34) der zweiten Legierung
die selbsttragende Oberfläche (27) der ersten Legierung an einer Position berührt,
wo die Temperatur der selbsttragenden Oberfläche der ersten Legierung zwischen deren
Solidus- und Liquidus-Temperatur liegt.
5. Verfahren gemäß Anspruch 4, wobei die obere Oberfläche (34) der zweiten Legierung
die selbsttragende Oberfläche (27) der ersten Legierung an einer Position berührt,
wo die Temperatur der selbsttragenden Oberfläche der ersten Legierung zwischen der
Solidus- und der Kohärenz-Temperatur hiervon liegt.
6. Verfahren gemäß Anspruch 1, wobei die Temperatur der zweiten Legierung dann, wenn
sie zuerst die selbsttragende Oberfläche (27), der ersten Legierung berührt, größer
als oder gleich der Liquidus-Temperatur der zweiten Legierung ist.
7. Verfahren gemäß einen der Ansprüche 1 bis 6, wobei die Teilerwände (14, 14a, 14')
zur Unterteilung des Zufuhrendes aus temperaturgeregelten Teilerwänden zwischen jedem
der Paare von Kammern bestehen.
8. Verfahren gemäß Anspruch 7, wobei die temperaturgeregelten Teilerwände (14, 14a, 14')
dazu dienen, die Temperatur der selbsttragenden Oberfläche (27) der ersten Legierung
(18) an einer Position zu regeln, wo die obere Oberfläche (34) der zweiten Legierung
(21) die selbsttragende Oberfläche berührt.
9. Verfahren gemäß Anspruch 7, wobei ein Temperaturregelungsfluid mit der temperaturgeregelten
Teilerwand (14, 14a, 14') in Kontakt tritt, um die über die Teilerwand abgeführte
oder zugegebene Wärme zu regeln.
10. Verfahren gemäß Anspruch 9, wobei das Temperaturregelungsfluid durch einen geschlossenen
Kanal (33) hindurchströmt und die Temperatur der selbsttragenden Oberfläche (27) durch
Messen der Austrittstemperatur des den Kanal verlassenden Fluids geregelt wird.
11. Verfahren gemäß einem der Ansprüche 1 bis 10, wobei die obere Oberfläche (34) des
zweiten Legierungspools an einem Niveau unterhalb des unteren Endes der Teilerwand
(14, 14a, 14') beibehalten wird.
12. Verfahren gemäß Anspruch 11, wobei die obere Oberfläche (34) des zweiten Legierungspools
innerhalb von 2 mm von der Bodenkante der Teilerwand (14, 14a, 14') beibehalten wird.
13. Verfahren gemäß einem der Ansprüche 1 bis 12, wobei die Krümmung der Teilerwand (14,
14') während des Gießens variiert wird.
14. Verfahren gemäß einem der Ansprüche 1 bis 12, wobei die Teilerwand (14, 14a, 14')
mit einer nach außen gerichteten Abschrägung an der Fläche versehen ist, die in Kontakt
mit der ersten Legierung (18) steht.
15. Verfahren gemäß Anspruch 14, wobei die Abschrägung entlang der Länge der Teilerwand
(14, 14a, 14') variiert.
16. Verfahren gemäß Anspruch 1, wobei die Position einer oder mehrerer der oberen Oberflächen
des Metallpools durch Bereitstellen einer Gasquelle (51) geregelt wird, die das Gas
mittels eines Rohrs mit offenem Ende zuführt, wobei das offene Ende (53) die Position
an einem Bezugspunkt (54) innerhalb einer Kammer ist, so dass das offene Ende im Gebrauch
unterhalb der oberen Oberfläche (55) in dieser Kammer liegt, die Strömungsrate des
Gases geregelt wird, um eine langsame Strömungsrate des Gases durch das Rohr beizubehalten,
die ausreicht, das Rohr offen zu halten, des Messens des Drucks des Gases in dem Rohr,
der gemessene Druck mit einem vorab festgelegten Zieldruck verglichen wird und die
Strömung des Metalls in die Kammer hinein eingestellt wird, um die obere Oberfläche
bei einer gewünschten Position beizubehalten.
17. Verfahren gemäß Anspruch 1, wobei die Gussform (10) einen rechteckigen Querschnitt
aufweist und zwei Zufuhrkammern unterschiedlicher Größe umfasst, die parallel zur
langen Fläche (11) der rechteckigen Gussform ausgerichtet sind, um einen rechteckigen
Gussblock mit einer Plattierung auf einer Fläche auszubilden.
18. Verfahren gemäß Anspruch 17, wobei die erste Legierung (18) in die größere der zweiten
Zufuhrkammern zugeführt wird.
19. Verfahren gemäß Anspruch 17, wobei die zweite Legierung (21) in die größere der zwei
Zufuhrkammern zugeführt wird.
20. Verfahren gemäß Anspruch 17, 18 oder 19, wobei die Teilerwand (14, 14') im Wesentlichen
parallel (44) zur langen Fläche (11) der Gussform mit gekrümmten Endabschnitten (45),
die an den langen Wänden der Gussform enden (50), steht.
21. Verfahren gemäß Anspruch 17, 18 oder 19, wobei die Teilerwand (14, 14') im Wesentlichen
parallel zur langen Fläche (11) der Gussform mit gekrümmten Endabschnitten, die an
den kurzen Endwänden der Gussform enden, steht.
22. Verfahren gemäß Anspruch 1, wobei die Gussform (10) einen rechteckigen Querschnitt
aufweist und drei Zufuhrkammern umfasst, die parallel zur langen Fläche (11) der rechteckigen
Gussform ausgerichtet sind, wobei die zentrale Kammer größer als beide Seitenkammern
ist, um so einen rechteckigen Gussblock mit Plattierungen (23) an zwei Flächen auszubilden.
23. Verfahren gemäß Anspruch 22, wobei die erste Legierung (18) zur zentralen Kammer zugeführt
wird.
24. Verfahren gemäß Anspruch 22, wobei die zweite Legierung (21) zur zentralen Kammer
zugeführt wird.
25. Verfahren gemäß Anspruch 22, 23 oder 24, wobei die Teilerwand (14, 14') im Wesentlichen
parallel (44) zur langen Fläche (11) der Gussform mit gekrümmten Endabschnitten (45),
die an den langen Wänden der Gussform enden (50), steht.
26. Verfahren gemäß Anspruch 22, 23 oder 24, wobei die Teilerwand (14, 14') im Wesentlichen
parallel zur langen Fläche (11) der Gussform mit gekrümmten Endabschnitten, die an
den kurzen Endwänden der Gussform enden, steht.
27. Gießvorrichtung für die Herstellung von Verbundmetall-Gussblöcken, umfassend eine
ringförmige Gussform (10) mit offenem Ende, welche ein Zufuhrende sowie ein Austrittsende
sowie einen beweglichen Bodenblock (17) aufweist, der so angepasst ist, dass er in
das Austrittsende einpasst und in einer Richtung entlang der Achse der ringförmigen
Gussform beweglich ist, wobei das Zufuhrende der Gussform in zumindest zwei unterschiedliche
Zufuhrkammern unterteilt ist, jede Zufuhrkammer zumindest zu einer anderen Zufuhrkammer
benachbart ist, und wobei benachbarte Paare von Zufuhrkammern durch eine temperaturgeregelte
Teilerwand (14, 14a, 14') unterteilt ist, die oberhalb des Austrittsendes der Gussform
enden, ein Mittel (15, 16) zur Zufuhr von Metall (18, 21) zu jeder Zufuhr, ein Mittel
(31, 32) zur Steuerung des Stroms von Metall zu jeder Zufuhrkammer, sowie eine Regelungsvorrichtung
für das Metallniveau (51, 52, 53, 56) für jede Kammer, so dass das Metallniveau in
benachbarten Paaren von Kammern in der ersten Kammer bei einer Position oberhalb des
unteren Endes (35) der temperaturgeregelten Teilerwand beibehalten werden kann und
in der zweiten Kammer bei einer anderen Position in Bezug auf das Metallniveau in
der ersten Kammer beibehalten werden kann.
28. Gießvorrichtung gemäß Anspruch 27, wobei das Metallniveau (34) in der zweiten Kammer
bei einer Position unterhalb des unteren Endes (35) der Teilerwand beibehalten werden
kann.
29. Gießvorrichtung gemäß Anspruch 27, wobei ein geschlossener Kanal (33) für ein Temperaturregelungsfluid
mit einem Einlass (36) und einem Auslass (37) mit der temperaturgeregelten Teilerwand
(14, 14a, 14') verbunden ist.
30. Gießvorrichtung gemäß Anspruch 29, wobei eine Temperaturmessvorrichtung (40) am Fluidauslass
(37) vorgesehen ist.
31. Gießvorrichtung gemäß einem der Ansprüche 27 bis 30, umfassend einen linearen Betätiger
(26) und einen Regelungsarm (25), der an der temperaturgeregelten Teilerwand (14)
so angebracht ist, dass die Krümmung der Teilerwand variiert werden kann.
32. Gießvorrichtung gemäß einem der Ansprüche 27 bis 30, wobei die temperaturgeregelte
Teilerwand (14) nach außen an der Oberfläche, die der ersten Kammer gegenübersteht,
abgeschrägt ist.
33. Gießvorrichtung gemäß Anspruch 32, wobei die Abschrägung entlang der Länge der Teilerwand
variiert ist.
34. Gießvorrichtung gemäß Anspruch 27, umfassend einen Graphiteinsatz (46) an der Oberfläche
der temperaturgeregelten Teilerwand (14), die der ersten Kammer gegenübersteht.
35. Gießvorrichtung gemäß Anspruch 27, umfassend einen Fluidzufuhrkanal (48) zur Bereitstellung
eines Schmiermittels oder einer Trennschicht auf der Oberfläche der Teilerwand.
36. Gießvorrichtung gemäß Anspruch 34, wobei der Graphiteinsatz (46) porös ist und ein
oder mehrere Fluid-Zufuhrkanäle (48) in der temperaturgeregelten Teilerwand (14) so
angepasst sind, dass sie ein Fluid über den porösen Graphiteinsatz zur Oberfläche
der Teilerwand, die der ersten Kammer gegenübersteht, zuführen.
37. Gießvorrichtung gemäß Anspruch 27, wobei die Regelungsvorrichtung für das Metallniveau
eine Gasquelle (51), einen Strömungsregler (52) zur Regelung des Gasstroms von der
Quelle, ein mit dem Strömungsregler an einem Ende verbundenes und zum anderen Ende
(53) offenes Rohr, sowie eine Druckanzeige in dem Rohr umfasst, wobei das offene Ende
des Rohrs innerhalb der Kammer an einer vorab festgelegten Position (54) in Bezug
auf den Körper (10) der Gussform derart positioniert ist, dass das offene Ende des
Rohrs bei der Verwendung in das Metall in der Kammer eingetaucht ist, wodurch das
Mittel zur Regelung des Metallstroms zur Kammer als Reaktion auf den gemessenen Druck
von der Druckanzeige geregelt wird, um das Metallniveau (55) bei einer vorab festgelegten
Position beizubehalten.
38. Gießvorrichtung gemäß Anspruch 27, wobei das Mittel zur Zufuhr von Metall zur Kammer
eine Metallzufuhrrinne (59) an einer oder mehreren Zufuhrrohren (58) mit offenem Ende,
die mit der Rinne verbunden sind, umfasst.
39. Gießvorrichtung gemäß Anspruch 38, wobei das eine oder die mehreren Rohre mit offenem
Ende innerhalb der Kammer so positioniert sind, dass das offene Ende im Gebrauch in
das Metall eingetaucht ist.
1. Procédé de coulage d'un lingot de métal composite comprenant au moins deux couches
formées d'une ou plusieurs compositions d'alliages, qui comprend la fourniture d'un
moule annulaire (10) aux extrémités ouvertes, ayant une extrémité d'alimentation et
une extrémité de sortie, dans lequel on ajoute du métal fondu (18, 21) à l'extrémité
d'alimentation et on extrait un lingot solidifié de l'extrémité de sortie, et des
parois séparatrices (14, 14a, 14') pour diviser l'extrémité d'alimentation en au moins
deux chambres d'alimentation séparées, les parois séparatrices se terminant à leurs
extrémités inférieures (35) positionnées au-dessus de l'extrémité de sortie dudit
moule, chaque chambre d'alimentation étant adjacente à au moins une autre chambre
d'alimentation, dans lequel, pour chaque paire des chambres d'alimentation adjacentes,
un premier courant d'un premier alliage (18) est acheminé à une première paire des
chambres d'alimentation en vue de former un bain de métal dans la première chambre
et un second courant d'un second alliage (21) est acheminé à travers la seconde paire
des chambres d'alimentation en vue de former un bain de métal dans la seconde chambre,
les bains de métal ayant chacun une surface supérieure, la mise en contact du premier
bain d'alliage avec la paroi séparatrice entre les deux chambres pour refroidir de
la sorte le premier bain d'alliage afin de former une surface autoportante (27), et
le fait de laisser le second bain d'alliage venir en contact avec le premier bain
d'alliage de sorte que la surface supérieure (34) du second bain d'alliage vienne
en contact avec la paroi séparatrice dans une position ne dépassant pas plus de 3
mm au-dessus de l'extrémité inférieure de la paroi séparatrice ou vienne en contact
avec la surface autoportante du premier bain d'alliage en un point où la température
de la surface autoportante se situe entre les températures de solidus et de liquidus
du premier alliage, de sorte que les deux bains d'alliage soient joints en deux couches
(20,23), et le refroidissement des couches d'alliage jointes pour former un lingot
composite.
2. Procédé selon la revendication 1, dans lequel le premier et le second alliage ont
la même composition.
3. Procédé selon la revendication 1, dans lequel le premier et le second alliage ont
des compositions différentes.
4. Procédé selon la revendication 1, dans lequel la surface supérieure (34) du second
alliage est en contact avec la surface autoportante (27) du premier alliage dans une
position où la température de la surface autoportante du premier alliage se situe
entre ses températures de solidus et de liquidus.
5. Procédé selon la revendication 4, dans lequel la surface supérieure (34) du second
alliage est en contact avec la surface autoportante (27) du premier alliage dans une
position où la température de la surface autoportante du premier alliage se situe
entre ses températures de solidus et de cohérence.
6. Procédé selon la revendication 1, dans lequel la température du second alliage lorsqu'il
est la première fois en contact avec la surface autoportante (27) du premier alliage
est supérieure ou égale à la température de liquidus du second alliage.
7. Procédé selon l'une quelconque des revendications 1 à 6, dans lequel les parois séparatrices
(14, 14a, 14') pour diviser l'extrémité d'alimentation sont constituées de parois
séparatrices commandées en température, entre chacune des deux chambres.
8. Procédé selon la revendication 7, dans lequel les parois séparatrices commandées en
température (14, 14a, 14') servent à commander la température de la surface autoportante
(27) du premier alliage (18) dans la position où la surface supérieure (34) du second
alliage (21) vient en contact avec la surface autoportante.
9. Procédé selon la revendication 7, dans lequel on met en contact un fluide de commande
de température avec la paroi séparatrice commandée en température (14, 14a, 14') pour
commander la chaleur éliminée ou ajoutée via la paroi séparatrice.
10. Procédé selon la revendication 9, dans lequel le fluide de commande de la température
s'écoule à travers un canal fermé (33) et la température de la surface autoportante
(27) est commandée par mesure de la température de sortie du fluide quittant le canal.
11. Procédé selon l'une quelconque des revendications 1 à 10, dans lequel on maintient
la surface supérieure (34) du second bain d'alliage à un niveau situé au-dessous de
l'extrémité inférieure de la paroi séparatrice (14, 14a, 14').
12. Procédé selon la revendication 11, dans lequel on maintient la surface supérieure
(34) du second bain d'alliage dans les 2 mm du bord inférieur de la paroi séparatrice
(14, 14a, 14').
13. Procédé selon l'une quelconque des revendications 1 à 12, dans lequel la courbure
de la paroi séparatrice (14, 14') est modifiée au cours du coulage.
14. Procédé selon l'une quelconque des revendications 1 à 12, dans lequel la paroi séparatrice
(14, 14a, 14') présente une conicité vers l'extérieur sur la face en contact avec
le premier alliage (18).
15. Procédé selon la revendication 14, dans lequel la conicité varie sur la longueur de
la paroi séparatrice (14, 14a, 14').
16. Procédé selon la revendication 1, dans lequel on commande la position d'une ou plusieurs
surfaces supérieures de bain de métal par la mise en oeuvre d'une source gazeuse (51),
la délivrance du gaz au moyen d'un tube à extrémité ouverte, dans lequel l'extrémité
ouverte (53) est positionnée en un point de référence (54) à l'intérieur de la chambre
de sorte que, en service, l'extrémité ouverte se trouve au-dessous de la surface supérieure
(55) dans cette chambre, la commande du débit du gaz pour maintenir un débit de gaz
lent à travers le tube suffisamment pour maintenir le tube ouvert, la mesure de la
pression du gaz dans le tube, la comparaison de la pression mesurée à une cible prédéterminée,
et l'ajustement de l'écoulement de métal dans la chambre afin de maintenir la surface
supérieure dans une position souhaitée.
17. Procédé selon la revendication 1, dans lequel le moule (10) a une coupe transversale
rectangulaire et comprend deux chambres d'alimentation de dimensions différentes orientées
parallèlement à la longue face (11) du moule rectangulaire afin de former un lingot
rectangulaire avec un gainage sur une face.
18. Procédé selon la revendication 17, dans lequel le premier alliage (18) est acheminé
dans la plus grande des deux chambres d'alimentation.
19. Procédé selon la revendication 17, dans lequel le second alliage (21) est acheminé
dans la plus grande des deux chambres d'alimentation.
20. Procédé selon la revendication 17, 18 ou 19, dans lequel la paroi séparatrice (14,
14') est sensiblement parallèle (44) à la longue face (11) du moule avec des parties
d'extrémité incurvées (45) qui se terminent (50) sur les longues parois du moule.
21. Procédé selon la revendication 17, 18 ou 19, dans lequel la paroi séparatrice (14,
14') est sensiblement parallèle à la longue face (11) du moule avec des parties d'extrémité
incurvées qui se terminent sur les courtes parois d'extrémité du moule.
22. Procédé selon la revendication 1, dans lequel le moule (10) a une coupe transversale
rectangulaire et comprend trois chambres d'alimentation orientées parallèlement à
la longue face (11) du moule rectangulaire, dans lequel la chambre centrale est plus
grande que l'une et l'autre des deux chambres latérales afin de former un lingot rectangulaire
avec un gainage (23) sur les deux faces.
23. Procédé selon la revendication 22, dans lequel le premier alliage (18) est acheminé
à la chambre centrale.
24. Procédé selon la revendication 22, dans lequel le second alliage (21) est acheminé
à la chambre centrale.
25. Procédé selon la revendication 22, 23 ou 24, dans lequel la paroi séparatrice (14,
14') est sensiblement parallèle (44) à la longue face (11) du moule avec des parties
d'extrémité incurvées (45) qui se terminent (50) sur les longues parois du moule.
26. Procédé selon la revendication 22, 23 ou 24, dans lequel la paroi séparatrice (14,
14') est sensiblement parallèle à la longue face (11) du moule avec des parties d'extrémité
incurvées qui se terminent sur les courtes parois d'extrémité du moule.
27. Appareil de coulage destiné à la production de lingots de métaux composites, comprenant
un moule annulaire (10) aux extrémités ouvertes ayant une extrémité d'alimentation
et une extrémité de sortie et un bloc inférieur mobile (17) à même de s'ajuster dans
l'extrémité de sortie et déplaçable dans une direction le long de l'axe du moule annulaire,
dans lequel l'extrémité d'alimentation du moule est divisé en au moins deux chambres
d'alimentation séparées, chaque chambre d'alimentation étant adjacente à au moins
une autre chambre d'alimentation, et où des paires adjacentes de chambres d'alimentation
sont séparées par une paroi séparatrice commandée en température (14, 14a, 14') se
terminant au-dessus de l'extrémité de sortie du moule, un moyen (15, 16) servant à
acheminer du métal (18, 21) à chaque chambre d'alimentation, un moyen (31, 32) pour
commander l'écoulement de métal à chaque chambre d'alimentation, et un appareil de
commande de niveau de métal (51, 52, 53, 56) pour chaque chambre de sorte que, dans
des paires adjacentes de chambres, on puisse maintenir le niveau de métal, dans la
première chambre, dans une position au-dessous de l'extrémité inférieure (35) de ladite
paroi séparatrice commandée en température et, dans la seconde chambre, dans une position
différente par rapport au niveau de métal dans la première chambre.
28. Appareil de coulage selon la revendication 27, dans lequel on peut maintenir le niveau
de métal (34) dans la seconde chambre dans une position au-dessous de l'extrémité
inférieure (35) de la paroi séparatrice.
29. Appareil de coulage selon la revendication 27, dans lequel un canal fermé (33) pour
un fluide de commande de température, ayant une entrée (36) et une sortie (37), est
raccordé à la paroi séparatrice commandée en température (14, 14a, 14').
30. Appareil de coulage selon la revendication 29, dans lequel un dispositif de mesure
de température (40) est prévu à la sortie de fluide (37).
31. Appareil de coulage selon l'une quelconque des revendications 27 à 30, comprenant
un dispositif d'actionnement linéaire (26) et un bras de commande (25) fixé à la paroi
séparatrice commandée en température (14) de sorte que la courbure de la paroi séparatrice
puisse être modifiée.
32. Appareil de coulage selon l'une quelconque des revendications 27 à 30, dans lequel
la paroi séparatrice commandée en température (14) est conformée en cône vers l'extérieur
sur la surface en regard de la première chambre.
33. Appareil de coulage selon la revendication 32, dans lequel on fait varier la conicité
sur la longueur de la paroi séparatrice.
34. Appareil de coulage selon la revendication 27, comprenant une pièce rapportée de graphite
(46) sur la surface de la paroi séparatrice commandée en température (14) en regard
de la première chambre.
35. Appareil de coulage selon la revendication 27, comprenant un canal d'acheminement
de fluide (48) pour fournir une couche lubrifiante ou séparatrice à la surface de
la paroi séparatrice.
36. Appareil de coulage selon la revendication 34, dans lequel la pièce rapportée de graphite
(46) est poreuse et un ou plusieurs canaux d'acheminement de fluide (48) dans la paroi
séparatrice commandée en température (14) sont adaptés pour acheminer du fluide via
la pièce rapportée en graphite poreux à la surface de la paroi séparatrice en regard
de la première chambre.
37. Appareil de coulage selon la revendication 27, dans lequel l'appareil de commande
de niveau de métal comprend une source gazeuse (51), un dispositif de commande d'écoulement
(52) pour commander l'écoulement de gaz depuis la source, un tube raccordé au dispositif
de commande d'écoulement à une extrémité et ouvert à l'autre extrémité (53), et une
jauge de pression (56) fixée au tube pour mesurer la pression du gaz dans le tube,
l'extrémité ouverte du tube étant positionnée à l'intérieur de la chambre dans une
position prédéterminée (54) par rapport au corps (10) du moule, de sorte que, en service,
l'extrémité ouverte du tube soit immergée dans le métal dans la chambre, dans lequel
le moyen de commande de l'écoulement de métal à la chambre est commandé en réponse
à la pression mesurée depuis la jauge de pression pour maintenir le niveau de métal
(55) dans une position prédéterminée.
38. Appareil de coulage selon la revendication 27, dans lequel le moyen permettant d'acheminer
du métal à la chambre comprend une gouttière d'acheminement de métal (59) et un ou
plusieurs tubes d'acheminement de métal (58) à extrémités ouvertes, raccordés à la
gouttière.
39. Appareil de coulage selon la revendication 38, dans lequel le ou les tubes à extrémités
ouvertes sont positionnés à l'intérieur de la chambre, de sorte qu'en service, l'extrémité
ouverte soit immergée dans le métal.
REFERENCES CITED IN THE DESCRIPTION
This list of references cited by the applicant is for the reader's convenience only.
It does not form part of the European patent document. Even though great care has
been taken in compiling the references, errors or omissions cannot be excluded and
the EPO disclaims all liability in this regard.
Patent documents cited in the description