[0001] The invention relates to a personal cleansing system and a personal cleansing kit,
and more specifically wherein an assembly of one or more of skin cleansing, aesthetic,
and skin moisturization and benefit bars are selected, and then combined in a customized
manner.
[0002] Toilet bar skin cleaning properties are well known. An ideal bar composition not
only cleans, but provides a large quantity of lather and leaves the skin feeling comfortable.
Consumers also desire to obtain toilet bars with good hardness, low mush, and that
contain appealing fragrances and one or more skin benefit agents and emollients for
moisturizing and treating the skin according to individual preferences and needs.
[0003] To accomplish this, a wide variety of additives have been suggested for inclusion
in toilet bars. Some additives enhance the physical properties of the bar such as
lather volume, hardness and wear rate. Other additives effect the aesthetic and sensory
properties of the bar. Still other additives enhance skin moisturization, residual
antibacterial properties, and treat skin conditions such as acne, etc. Unfortunately
not all potentially desirable additives may be compatible with each other. As a result,
a single toilet bar product is not suitable or desirable for every consumer. At the
same time, the bar manufacturer desires to reduce costs by minimizing the difference
in toilet bar compositions it produces.
[0004] The use of a porous or netted bag or pouch to carry soap is known. The prior art
includes
US 1,682,119 where a bag is provided with soap in a flake or fragment form. Similarly
US 2,607,940 discloses a mesh bag so that a soap can be easily inserted. Similar arrangements
are taught in e.g.
US Patent No. 3,167,805,
US Patent No. 4,190,550,
US Patent No. 4,228,834,
US Patent No. 4,480,939, and
US Patent No. 5,462,378.
US Patent No. 4,789,262 teaches a soap holding cleaning pad.
US Patent No. 5,839,842 discloses a cleansing system with a toilet bar and a sponge in a porous pouch.
US Patent No. 6,042,288 teaches the use of a synthetic detergent bar and a pouf for holding the bar.
JP Patent No. 10137152 also teaches a solid soap in an expansible net. However, the problem with prior art
toilet bar and pouch implements is the lack of a system and a kit to make available
a product with a wide range of sensory properties in a convenient format but with
excellent physical properties.
[0005] Surprisingly it has been found that when a single toilet bar is formulated with high
levels of moisturizing and aesthetic fragrance ingredients, the properties of the
bar such as lather, wear rate, etc. are substantially degraded compared to a system
of individual toilet bar ingredients formulated separately where a cleansing bar,
a moisturizing bar, and an aesthetic fragrance bar are separately produced. For the
purposes of this invention, a "bar" is herein defined as an individual toilet bar
or other geometrically or amorphous shaped body that may be selected from and combined
with other toilet bars or bodies in a porous holder according to the invention. According
to the present invention, these separate bars may be presented in a kit and combined
in a porous pouch to bring together all the cleansing and skin treatment attributes
desired by the consumer and at the same time form a useful cleansing implement with
superior lathering properties compared to a single toilet bar formed with the same
ingredients. Furthermore it has been found that production efficiency is enhanced
by making the bars separately, since such bars if made by the melt cast process have
a shorter solidification time. Moreover, the variability of solidification time in
melt cast bars may be minimized by separate manufacturing of the bars. With respect
to extrusion of such bars, the variability of processing parameters such as extrusion
rate and stampability may also be minimized by separate manufacture of the bars.
[0006] In a first aspect of the invention, there is provided a personal cleansing kit according
to claim 1.
[0007] As used herein, the aesthetic ingredient is defined as either fragrances, colorants,
pigments, cosmetics (without benefit ingredients as hereafter defined), suspended
bodies and blends thereof; and the benefit ingredient is defined as either emollients,
skin active materials (as defined below) and blends thereof.
[0008] In another aspect of the invention is a method for providing a personal customized
cleansing product to a user according to claim 4.
[0009] Preferred embodiments of the invention will now be described by way of example only
with reference to the accompanying drawings wherein like figures represent like features,
in which:
- Fig. 1 is a perspective view of a preferred embodiment of the inventive cleansing
kit.
[0010] The present invention consists of a kit comprising two or more solid/semi-solid bars
that may be combined in a porous closable pouch by the user and the system for fabricating
such a combination. The kit's parts, i.e. the cleansing, aesthetic and benefit bars
and porous holder advantageously contained in an outer container may also be purchased
separately by the consumer, who can use the inventive system to create a customized
cleansing article by selecting two or more of the compositions and inserting them
into the pouch prior to showering.
[0011] The bars may serve different functions such as cleansing, benefit delivery etc. They
may also have different ingredients that combine together to provide a unique benefit
or fragrance. The bars may also consist in whole or part of inert ingredients and
provide e.g. a massage or exfoliation type action and the like.
[0012] Advantageously, the cleansing kit further includes a set of instructions relating
to the use of the kit. Preferably the first and second compositions in the kit have
a rigidity index greater than about 0.2 Mpa at 25°C.
[0013] With respect to the cleansing composition, it advantageously includes an amphoteric
surfactant, and preferaly about 15 % to 80 % by wt. of a C8 to C24 acyl isethionate,
or about 15 % to 80 % by wt. of a soap. With respect to an emollient, the benefit
composition advantageously includes an emollient selected from silicone oils and gums,
fats, triglyceride oils, waxes, hydrophobic plant extracts, fatty esters, hydrocarbons
and blends thereof, as well as other useful emollients listed below. The benefit composition
advantageously includes a component selected from vitamins, antimicrobial agents,
acne medications, exfoliating agents, astringents, antioxidants, enzymes, sunscreens
and ultraviolet radiation absorbing compositions and the like.
[0014] Advantageously, the closable receptacle and plurality of cosmetic compositions are
contained in a container partitioned to separate the receptacle and the plurality
of cosmetic compositions for ease in selection by the consumer. Preferably the closable
receptacle is formed of a polymeric mesh material.
[0015] Preferred embodiments of the invention will now be described by way of example with
reference to the accompanying drawing.
[0016] A preferred embodiment of the inventive cleansing kit 60 is depicted in Fig. 1. The
customized cleansing implement may be supplied partially pre-assembled or preferably
in components as illustrated in Fig. 1 to be assembled by the user according to instructions
supplied with kit 60. In operation, the user will select and insert, as desired, one
or more of a cleansing bar 24, a fragrance bar 26, a conditioning bar 28, and an active
agent bar 30 into bag holder 40 all contained in container 64. When all of the bars
desired for the implement have been inserted in the bag holder 40, pull ties 56 may
be pulled so that together with cord locking device 58 will serve to keep the bars
inside the bag holder 40 during use until the bars are either exhausted or until such
time as the user desires to use a new selection of bars in the kit by either adding,
removing or replacing any of the bars in any combination desired.
[0017] Surfactants are an essential ingredient of at least one of the toilet bars of the
invention. They are compounds that have hydrophobic and hydrophilic portions that
act to reduce the surface tension of the aqueous solutions they are dissolved in.
Useful surfactants can include anionic, nonionic, amphoteric, and cationic surfactants,
and blends thereof.
[0018] At least one of the toilet bars such as the cleansing bar, may contain an anionic
surfactant which may preferably be a soap; preferably it contains at least 0.1 % by
wt. of soap. The term "soap" is used herein in its popular sense, i.e., the alkali
metal or alkanol ammonium salts of alkane- or alkene monocarboxylic acids. Sodium,
potassium, mono-, di- and triethanol ammonium cations, or combinations thereof, are
suitable for purposes of this invention. In general, sodium soaps are used in the
compositions of this invention, but from about 1 % to about 25 % of the soap may be
ammonium, potassium, magnesium, calcium or a mixture of these soaps. The soaps useful
herein are the well known alkali metal salts of alkanoic or alkenoic acids having
about 12 to 22 carbon atoms, preferably about 12 to about 18 carbon atoms. They may
also be described as alkali metal carboxylates of alkyl or alkene hydrocarbons having
about 12 to about 22 carbon atoms.
[0019] At least one of the toilet bars of the present invention may contain one or more
non-soap anionic detergents. The anionic detergent active which may be used may be
aliphatic sulfonates, such as a primary alkane (e.g., C
8-C
22) sulfonate, primary alkane (e.g., C
8-C
22) disulfonate, C
8-C
22 alkene sulfonate, C
8-C
22 hydroxyalkane sulfonate or alkyl glyceryl ether sulfonate (AGS); or aromatic sulfonates
such as alkyl benzene sulfonate.
[0020] The anionic may also be an alkyl sulfate (e.g., C
12-C
18 alkyl sulfate) or alkyl ether sulfate (including alkyl glyceryl ether sulfates).
Among the alkyl ether sulfates are those having the formula:
RO(CH
2CH
2O)
nSO
3M
wherein R is an alkyl or alkenyl having 8 to 18 carbons, preferably 12 to 18 carbons,
n has an average value of greater than 1.0, preferably greater than 3; and M is a
solubilizing cation such as sodium, potassium, ammonium or substituted ammonium. Ammonium
and sodium lauryl ether sulfates are preferred.
[0021] The anionic may also be alkyl sulfosuccinates (including mono- and dialkyl, e.g.,
C
6-C
22 sulfosuccinates); alkyl and acyl taurates, alkyl and acyl sarcosinates, sulfoacetates,
C
8-C
22 alkyl phosphates and phosphates, alkyl phosphate esters and alkoxyl alkyl phosphate
esters, acyl lactates, C
8-C
22 monoalkyl succinates and maleates, sulphoacetates, alkyl glucosides and acyl isethionates,
and the like.
[0022] Sulfosuccinates may be monoalkyl sulfosuccinates having the formula:
R
4O
2CCH
2CH(SO
3M)CO
2M;
and amide-MEA sulfosuccinates of the formula;
R
4CONHCH
2CH
2O
2CCH
2CH(SO
3M)CO
2M
wherein R
4 ranges from C
8-C
22 alkyl and M is a solubilizing cation.
[0023] Sarcosinates are generally indicated by the formula:
R
1CON(CH
3)CH
2CO
2M,
wherein R
1 ranges from C
8-C
20 alkyl and M is a solubilizing cation.
[0024] Taurates are generally identified by formula:
R
2CONR
3CH
2CH
2SO
3M
wherein R
2 ranges from C
8-C
20 alkyl, R
3 ranges from C
1-C
4 alkyl and M is a solubilizing cation.
[0025] At least one of the toilet bars preferably contains non-soap anionic surfactants,
preferably C
8-C
14 acyl isethionates. These esters are prepared by reaction between alkali metal isethionate
with mixed aliphatic fatty acids having from 6 to 12 carbon atoms and an iodine value
of less than 20.
[0026] The acyl isethionate may be an alkoxylated isethionate such as is described in
Ilardi et al., U.S. Patent No. 5,393,466, titled "Fatty Acid Esters of Polyalkoxylated isethonic acid; issued February 28,
1995; hereby incorporated by reference. This compound has the general formula:

wherein R is an alkyl group having 8 to 18 carbons, m is an integer from 1 to 4, X
and Y are hydrogen or an alkyl group having 1 to 4 carbons and M
+ is a monovalent cation such as, for example, sodium, potassium or ammonium.
[0027] In another embodiment of at least one of the toilet bars in the inventive cleansing
article, e.g. the fragrance bar, conditioning bar or active agent bar, there is less
than 25 % by wt. of anionic surfactants; preferably there is less than 20 %, and more
preferably less than 15, 10, 7, 5, 3 or 1 % by wt. of these surfactants.
[0028] Anionic surfactants may be usefully employed in the cleansing bar of the present
invention in the concentration range of about 5 % to 90 % by wt., preferably in the
concentration range of about 20 % to 60 % by wt.
[0029] One or more amphoteric surfactants may be used in at least one bar of this invention.
Such surfactants include at least one acid group. This may be a carboxylic or a sulphonic
acid group. They include quaternary nitrogen, and therefore are quaternary amido acids.
They should generally include an alkyl or alkenyl group of 7 to 18 carbon atoms. They
will usually comply with an overall structural formula:
where R1 is alkyl or alkenyl of 7 to 18 carbon atoms;
R2 and R3 are each independently alkyl, hydroxyalkyl or carboxyalkyl of 1 to 3 carbon atoms;
n is 2 to 4;
m is 0 to 1;
X is alkylene of 1 to 3 carbon atoms optionally substituted with hydroxyl; and
Y is -CO2- or -SO3-
[0030] Suitable amphoteric surfactants within the above general formula include simple betaines
of formula:

and amido betaines of formula:

where n is 2 or 3.
[0031] In both formulae, R
1, R
2 and R
3 are as defined previously. R
1 may in particular be a mixture of C
12 and C
14 alkyl groups derived from coconut oil so that at least half, preferably at least
three quarters of the groups R
1 have 10 to 14 carbon atoms. R
2 and R
3 are preferably methyl.
[0032] A further possibility is that the amphoteric detergent is a sulphobetaine of formula:

or

where m is 2 or 3, or variants of these in which -(CH
2)
3SO
3- is replaced by

[0033] In these formulae R
1, R
2 and R
3 are as discussed previously.
[0034] Amphoacetates and diamphoacetates are also intended to be covered in possible zwitterionic
and/or amphoteric compounds which may be used such as e.g., sodium lauroamphoacetate,
sodium cocoamphoacetate, and blends thereof, and the like.
[0035] Zwitterionic and/or amphoteric surfactants may be usefully employed in the cleansing
bar of the present invention in the concentration range of about 0 to 30 % by wt.,
preferably in the concentration range of about 1 % to 20 % by wt.
[0036] One or more nonionic surfactants may also be used in at least one of the cleansing
bars of the present invention.
[0037] The nonionics which may be used include in particular the reaction products of compounds
having a hydrophobic group and a reactive hydrogen atom, for example aliphatic alcohols,
acids, amides or alkylphenols with alkylene oxides, especially ethylene oxide either
alone or with propylene oxide. Specific nonionic detergent compounds are alkyl (C
6-C
22) phenols ethylene oxide condensates, the condensation products of aliphatic (C
8-C
18) primary or secondary linear or branched alcohols with ethylene oxide, and products
made by condensation of ethylene oxide with the reaction products of propylene oxide
and ethylenediamine. Other so-called nonionic detergent compounds include long chain
tertiary amine oxides, long chain tertiary phosphine oxides and dialkyl sulphoxide,
and the like.
[0038] The nonionic may also be a sugar amide, such as a polysaccharide amide. Specifically,
the surfactant may be one of the lactobionamides described in
U.S. Patent No. 5,389,279 to Au et al. titled "Compositions Comprising Nonionic Glycolipid Surfactants issued February
14, 1995; which is hereby incorporated by reference or it may be one of the sugar
amides described in
US Patent No. 5,009,814 to Kelkenberg, titled "Use of N-Poly Hydroxyalkyl Fatty Acid Amides as Thickening Agents for Liquid
Aqueous Surfactant Systems" issued April 23, 1991; hereby incorporated into the subject
application by reference.
[0039] Nonionic surfactants may be usefully employed in the cleansing bar of the present
invention in the concentration range of about 0 to 30 % by wt., preferably in the
concentration range of about 1 % to 20 % by wt.
[0040] One or more cationic surfactants may also be used in the inventive toilet bar composition.
[0041] Examples of cationic detergents are the quaternary ammonium compounds such as alkyldimethylammonium
halogenides.
[0042] Cationic surfactants may be usefully employed in the cleansing bar of the present
invention in the concentration range of about 0 to 30 % by wt., preferably in the
concentration range of about 1 % to 20 % by wt.
[0043] Other suitable surfactants which may be used are described in
U.S. Patent No. 3,723,325 to Parran Jr. titled "Detergent Compositions Containing Particle Deposition Enhancing Agents" issued
March, 27, 1973; and "Surface Active Agents and Detergents" (Vol. I & II) by Schwartz,
Perry & Berch, both of which are also incorporated into the subject application by
reference.
[0044] In addition, at least one of the bar compositions may be an aesthetic agent bar and
may include fragrances, colorants, pigments, particles, suspended materials, blends
thereof, and the like. When they are employed, fragrances are advantageously used
in the range of about 0.1 % to 10 % by wt., colorants in the range of about 0.000001
% to 1 % by wt., and particles/suspended materials in the range of about 0.01 % to
10 % by wt.
[0045] Preferably the bars employed in the inventive article may be differentiated from
each other by different colorants, where the color signifies a specific attribute
to be conferred by the bar or where color is used as a descriptor of the bar.
[0046] The personal cleansing article of the present invention may contain toilet bar compositions
that contain a safe and effective amount of a benefit agent. This benefit agent may
be selected from water-soluble active agents, oil soluble active agents, pharmaceutically
acceptable salts and mixtures thereof. The term "benefit agent" as used herein means
personal care actives that can be used to deliver a benefit to the skin and/or hair.
The term "safe and effective amount" as used herein, means an amount of benefit agent
high enough to modify the condition to be treated or to deliver the desired skin care
benefit, but low enough to avoid serious side effects.
[0047] The term "benefit," as used herein, means the therapeutic, prophylactic, and/or chronic
benefits associated with treating a particular condition with one or more of the benefit
agents described herein. What is a safe and effective amount of the active agent ingredient
will vary with the specific active agent, the ability of the active to penetrate through
the skin, the age, health condition, and skin condition of the user, and other like
factors. Preferably the benefit agent containing toilet bars of the present invention
comprise from about 0.01 % to about 50 %, more preferably from about 0.05 % to about
25 %, even more preferably 0.1 % to about 10 %, and most preferably 0.1 % to about
5 % by weight of the benefit agent component.
[0048] A wide variety of benefit agent ingredients are useful herein and include those selected
from emollients, anti-acne actives, anti-wrinkle and anti-skin atrophy actives, skin
barrier repair aids, cosmetic soothing aids, topical anesthetics, artificial tanning
agents and accelerators, skin lightening actives, antimicrobial and antifungal actives,
sunscreen actives, sebum stimulators, sebum inhibitors, anti-glycation actives and
mixtures thereof and the like.
[0049] Anti-acne actives can be effective in treating acne vulgaris, a chronic disorder
of the pilosebaceous follicles. Non-limiting examples of useful anti-acne actives
include the keratolytics such as salicylic acid (o-hydroxybenzoic acid), derivatives
thereof, and the like. Antimicrobial and antifungal actives can be effective to prevent
the proliferation and growth of bacteria and fungi. Non-limiting examples of antimicrobial
and antifungal actives include antibiotic drugs, quaternary ammonium compounds such
as benzalkonium chloride; benzethonium chloride; triclosan; triclocarban; and mixtures
thereof and the like.
[0050] Anti-wrinkle, anti-skin atrophy and skin repair actives can be effective in replenishing
or rejuvenating the epidermal layer. These actives generally provide these desirable
skin care benefits by promoting or maintaining the natural process of desquamation.
Non-limiting examples of anti-wrinkle and anti-skin atrophy actives include retinoic
acid and its derivatives, and the like. Skin barrier repair actives are those skin
care actives which can help repair and replenish the natural moisture barrier function
of the epidermis. Non-limiting examples of skin barrier repair actives include ceramide
derivatives, mixtures thereof, and the like.
[0051] Non-steroidal cosmetic soothing actives can be effective in preventing or treating
inflammation of the skin. The soothing active enhances the skin appearance benefits
of the present invention, e.g., such agents contribute to a more uniform and acceptable
skin tone or color. Non-limiting examples of cosmetic soothing agents include diphenhydramine
and the like. Artificial tanning actives can help in simulating a natural suntan by
increasing melanin in the skin or by producing the appearance of increased melanin
in the skin. Non-limiting examples of artificial tanning agents and accelerators include
dihydroxyacetone and the like.
[0052] Skin lightening actives can actually decrease the amount of melanin in the skin or
provide an effect by other mechanisms. Non-limiting examples of skin lightening actives
useful herein include phenolic and resourcinol derivatives, hydroquinone, and the
like. Also useful herein are sunscreen actives. Non-limiting examples of sunscreens
which are useful in the compositions of the present invention are those selected from
the group consisting of 2-ethylhexyl p- methoxycinnamate, 2-ethylhexyl N,N-dimethyl-p-aminobenzoate,
p- aminobenzoic acid, oxybenzone, and the like.
[0053] Sebum stimulators can increase the production of sebum by the sebaceous glands. Non-limiting
examples of sebum stimulating actives include dehydroetiandrosterone (DHEA) and the
like. Sebum inhibitors can decrease the production of sebum by the sebaceous glands.
Non-limiting examples of useful sebum inhibiting actives include aluminium hydroxy
chloride salts and the like. Also useful as actives in the present invention are protease
inhibitors. The protease inhibitors suitable for use in the present invention include,
but are not limited to, proteinases such as serine proteases and peptidases, such
as carboxypepidases, and the like.
[0054] Other useful benefit ingredients in the present invention are skin tightening agents.
Non-limiting examples of skin tightening agents which are useful in the compositions
of the present invention include monomers which can bind a polymer to the skin such
as terpolymers of vinylpyrrolidone, (meth)acrylic acid, and the like. Benefit agents
in the present invention may also include anti-itch ingredients. Suitable examples
of anti-itch ingredients which are useful in the compositions of the present invention
include hydrocortisone, and the like. Suitable benefit agents may also include hair
growth inhibitors, desquamating enzyme enhancers, and the like.
[0055] In addition, the inventive cleansing article includes toilet bar compositions that
may include 0 to 15% by wt. optional ingredients which may be as follows:
- sequestering agents, such as tetrasodium ethylenediaminetetraacetate (EDTA), EHDP
or mixtures in an amount of 0.01 % to 1 %, preferably 0.01 % to 0.05 %; opacifiers
and pearlizers such as zinc stearate, magnesium stearate, TiO2, EGMS (ethylene glycol monostearate) or Lytron 621 (Styrene/Acrylate copolymer) and
the like; all of which are useful in enhancing the appearance or cosmetic properties
of the product.
[0056] The compositions may further comprise preservatives such as dimethyloldimethylhydantoin
(Glydant XL1000), parabens, sorbic acid etc., and the like.
[0057] The compositions may also comprise coconut acyl mono- or diethanol amides as suds
boosters, and strongly ionizing salts such as sodium chloride and sodium sulfate may
also be used to advantage.
[0058] Antioxidants such as, for example, butylated hydroxytoluene (BHT) and the like may
be used advantageously in amounts of about 0.01 % or higher if appropriate.
[0059] As discussed above emollients may be advantageously used in the present invention
as benefit agents. The emollient "composition" may be a single benefit agent compound,
or it may be a mixture of two or more compounds one or all of which may have a beneficial
aspect. In addition, the benefit agent itself may act as a carrier for other compounds
one may wish to add to one or more of the inventive toilet bars.
[0060] Humectants such as polyhydric alcohols, e.g. glycerine and propylene glycol, and
the like, and polyols such as the polyethylene glycols listed below, and the like
may be used as emollients or moisturizers.
| Polyox WSR-205 |
PEG 14M, |
| Polyox WSR-N-60K |
PEG 45M, or |
| Polyox WSR-N-750 |
PEG 7M. |
[0061] Humectants may be usefully employed in at least one bar of the present invention
in the concentration range of about 1 % to 40 % by wt., preferably in the concentration
range of about 5 % to 30 % by wt.
[0062] Hydrophobic emollients, hydrophilic emollients, or a blend thereof may be used. Preferably,
hydrophobic emollients are used in excess of hydrophilic emollients in at least one
of the toilet bars. Most preferably one or more hydrophobic emollients are used alone.
Hydrophobic emollients are preferably present in a concentration greater than about
0.5 % by weight, more preferably about 4 % by weight in at least one of the bars.
The term "emollient" is defined as a substance which softens or improves the elasticity,
appearance, and youthfulness of the skin (stratum corneum) by either increasing its
water content, adding, or replacing lipids and other skin nutrients; or both, and
keeps it soft by retarding the decrease of its water content.
[0063] Useful emollients include the following:
(a) silicone oils and modifications thereof such as linear and cyclic polydimethylsiloxanes;
amino, alkyl, alkylaryl, and aryl silicone oils;
(b) fats and oils including natural fats and oils such as jojoba, soybean, sunflower,
rice bran, avocado, almond, olive, sesame, persic, castor, coconut, mink oils; cacao
fat; beef tallow, lard; hardened oils obtained by hydrogenating the aforementioned
oils; and synthetic mono, di and triglycerides such as myristic acid glyceride and
2-ethylhexanoic acid glyceride;
(c) waxes such as carnuba, spermaceti, beeswax, lanolin, and derivatives thereof;
(d) hydrophobic and hydrophillic plant extracts;
(e) hydrocarbons such as liquid paraffins, Vaseline®, microcrystalline wax, ceresin,
squalene, pristan and mineral oil;
(f) higher fatty acids such as lauric, myristic, palmitic, stearic, behenic, oleic,
linoleic, linolenic, lanolic, isostearic, arachidonic and poly unsaturated fatty acids
(PUFA);
(g) higher alcohols such as lauryl, cetyl, stearyl, oleyl, behenyl, cholesterol and
2-hexydecanol alcohol;
(h) esters such as cetyl octanoate, myristyl lactate, cetyl lactate, isopropyl myristate,
myristyl myristate, isopropyl palmitate, isopropyl adipate, butyl stearate, decyl
oleate, cholesterol isostearate, glycerol monostearate, glycerol distearate, glycerol
tristearate, alkyl lactate, alkyl citrate and alkyl tartrate;
(i) essential oils and extracts thereof such as mentha, jasmine, camphor, white cedar,
bitter orange peel, ryu, turpentine, cinnamon, bergamot, citrus unshiu, calamus, pine,
lavender, bay, clove, hiba, eucalyptus, lemon, starflower, thyme, peppermint, rose,
sage, sesame, ginger, basil, juniper, lemon grass, rosemary, rosewood, avocado, grape,
grapeseed, myrrh, cucumber, watercress, calendula, elder flower, geranium, linden
blossom, amaranth, seaweed, ginko, ginseng, carrot, guarana, tea tree, jojoba, comfrey,
oatmeal; cocoa, neroli, vanilla, green tea, penny royal, aloe vera, menthol, cineole,
eugenol, citral, citronelle, borneol, linalool, geraniol, evening primrose, camphor,
thymol, spirantol, penene, limonene and terpenoid oils;
(j) lipids such as cholesterol, ceramides, sucrose esters and pseudo-ceramides as
described in European Patent Specification No. 556,957;
(k) vitamins, minerals, and skin nutrients such as milk, vitamins A, E, and K; vitamin
alkyl esters, including vitamin C alkyl esters; magnesium, calcium, copper, zinc and
other metallic components;
(l) phospholipids;
(m) antiaging compounds such as alpha hydroxy acids, beta hydroxy acids; and
(o) mixtures of any of the foregoing components, and the like.
[0064] Preferred emollient benefit agents are selected from C12 to C18 fatty acids, triglyceride
oils, mineral oils, petrolatum, and mixtures thereof.
[0065] Emollients may be usefully employed in at least one bar of the present invention
in the concentration range of about 1 % to 90 % by wt., preferably in the concentration
range of about 10 % to 60 % by wt.
[0066] Struturants such as solid structuring aids and fillers are advantageously used to
maintain bar structural integrity. Examples of structuring aids include, but are not
limited to polyalkylene glycols having MW of 2,500 to 10,000 and a melting point of
about 40°C to 65°C; C8 to C20 alkanols, preferably straight chain, and saturated C14
to C18 alkanols; C8 to C25 fatty acids; preferably straight chain, and saturated C14
to C22 fatty acids; and water soluble starches, such as maltodextrin and the like.
The structuring aids and fillers generally comprise about 0 to 35 % by weight of the
bar composition, preferably about 10 % to 25 % by weight.
[0067] The pouch may be formed of any porous or water permeable material sufficiently permeable
to let water pass through the pouch and transfer the contents of the toilet bars that
are either dissolved, dispersed, or suspended in the water to the user. Preferably
the pouch material is sufficiently water insoluble so that maintains its integrity
until the toilet bars are substantially used up. Useful materials include polymeric
mesh, woven or nonwoven fabric, paper, tissue, sponge or laminate of foam and fabric.
[0068] Advantageously, a light-weight polymeric meshed substrate may be used. A useful material
is an extruded tubular netting mesh, particularly prepared from polyolefins such as
polyethylene and the like, and other materials such as polyamides or polyesters and
the like. They may be single or multiple ply netting such as in a pouf. The mesh structure
may be polygonal, such as diamond shaped, or the like. Also suitable are irregular
shapes. Advantageously the pouch cells are open and that preferably the contents within
the pouch are observable from the exterior.
[0069] Optionally sponge like materials may also be included in the pouch. Useful sponge
materials are closed cell materials either of synthetic or natural origin. Synthetic
sponges are advantageously formed of foamed polyurethane and the like. Optionally
the sponge material may be shaped to resemble an aesthetic form or be adapted to hold
one or more of the toilet bars.
[0070] Examples of suitable non-woven substrates useful as pouch materials would be wet-laid,
dry-laid, spun bonded, hydroentangled, air-laid, and the like comprising either singly
or in admixture fibers such as cellulose, rayon, polyester, polypropylene, polyethylene,
polyamide, and the like. The term substrate also includes naturally occurring materials
such as animal skin e.g. chamois leathers and the like. Preferred embodiments employ
non-woven substrates since they are economical and readily available in a variety
of materials. By non-woven is meant that the layer is comprised of fibers which are
not woven into a fabric but rather are formed into a sheet, particularly a tissue.
The fibers can either be random (i.e., randomly aligned) or they can be carded (i.e.
combed to be oriented in primarily one direction). Furthermore, the non-woven substrate
can be composed of a combination of layers of random and carded fibers.
[0071] Non-woven substrates may be comprised of a variety of materials both natural and
synthetic. By "natural" is meant that the materials are derived from plants, animals,
insects or byproducts. By "synthetic" is meant that the materials are obtained primarily
from various man-made materials or from material that is usually a fibrous web comprising
any of the common synthetic or natural textile-length fibers, or mixtures thereof.
[0072] Non-limiting examples of natural materials useful as a pouch material in the present
invention are silk fibers, keratin fibers and cellulosic fibers. Non-limiting examples
of keratin fibers include those selected from wool fibers, camel hair fibers, and
the like. Non-limiting examples of cellulosic fibers include those selected from wood
pulp fibers, cotton fibers, hemp fibers, jute fibers, flax fibers, and mixtures thereof.
[0073] Non-limiting examples of synthetic materials useful as components in the present
invention include those selected from acetate fibers, acrylic fibers, cellulose ester
fibers, modacrylic fibers, polyamide fibers, polyester fibers, polyolefin fibers,
polyvinyl alcohol fibers, rayon fibers and mixtures thereof. Examples of some of these
synthetic materials include acrylics such as Acrilan®, Creslan®, and the acrylonitrile-based
fiber, Orlon®; cellulose ester fibers such as cellulose acetate, Arnel®, and Acele®;
polyamides such as Nylons (e.g., Nylon 6, Nylon 66, Nylon 610 and the like; polyesters
such as Fortrel®, Kodel®, and the polyethylene terephthalate fibers, Dacron®; polyolefins
such as polypropylene, polyethylene; polyvinyl acetate fibers and mixtures thereof.
[0074] Non-woven substrates made from natural materials consist of webs or sheets most commonly
formed on a fine wire screen from a liquid suspension of the fibers. Substrates made
from natural materials useful in the present invention can be obtained from a wide
variety of commercial sources.
[0075] Suitable pouch materials may include at least one apertured fabric, where a pattern
is created by a network of bundled fiber segments surrounding apertures or holes;
or in a contiguous nonwoven web which has been apertured or provided with slits or
other openings. In one preferred embodiment, the water insoluble matterial is a substantially
contiguous network of water insoluble fibers having a plurality of macroscopic openings.
A macroscopic opening is defined as an opening that is large relative to the intrinsic
pore size of the water insoluble material.
[0076] In a typical spunbond or bonded carded web, for example, a macroscopic opening would
appear to the eye to be a deliberately introduced hole or void in the web, rather
than a characteristic pore between adjacent fibers, and specifically could have a
characteristic width or major axis diameter of about 0.1 mm to about 10 mm, or larger;
preferably about 1 mm to about 5 mm. A useful characteristic width may be defined
as 4 times the area of the aperture divided by the perimeter. Useful fabric aperture
densities are about 10 to 700 per square inch, preferably about 20 to 500 per square
inch.
[0077] As discussed above, the nonwoven web may be made from synthetic fibers, as is known
in the art, and may be a spunbond web, a meltblown web, a bonded carded web, or other
fibrous nonwoven structures known in the art.
[0078] For example, a polyester nonwoven web such as a low basis weight spunbond material
could be provided with apertures through pin aperturing; perf embossing and mechanical
stretching of the web; die punching or stamping to provide apertures or holes in the
web; hydroentangling to impart apertures by rearrangement of the fibers due to the
interaction of water jets with the fibrous web as it resides on a patterned, textured
or three-dimensional substrate that imparts a pattern to the web; water knives that
cut out desired apertures or holes in the web; laser cutters that cut out portions
of the web; patterned forming techniques, such as air laying of synthetic fibers on
a patterned substrate to impart macroscopic openings; needle punching with sets of
barbed needles to engage and displace fibers; and other methods known in the art.
Preferably, the openings are provided in a regular pattern over at least a portion
of the pouch.
[0079] The pouch of the present invention can comprise two or more portions, each having
a different texture and abrasiveness. The differing textures can result from the use
of different combinations of materials or from the use of a substrate having a more
abrasive side for exfoliation and a softer, absorbent side for gentle cleansing. In
addition, separate portions of the pouch can be manufactured to have different permanent
colors thereby helping the user to further distinguish the surfaces.
Examples
[0080] Except in the operating and comparative examples, or where otherwise explicitly indicated,
all numbers in this description indicating amounts of material ought to be understood
as modified by the word "about".
[0081] The following examples will more fully illustrate the embodiments of this invention.
All parts, percentages and proportions referred to herein and in the appended claims
are by weight unless otherwise illustrated.
[0082] The example illustrated in table 1 represents an inventive three part kit divided
into cleansing, benefits, and fragrances type bars as major categories, and a closable
porous pouch to contain a user selection of the bars. Each major bar category in Table
1 is further divided into subcategories representing different specific functions,
benefits, or aesthetic attributes. Examples of specific ingredients present in the
subcategory compositions are also illustrated, e.g. where the Benefits bar includes
separate subcategories identified as Nourishing, Anti-aging, Moisturizing, Smoothing,
Silkening, and Hydrating; and wherein e.g. the Nourishing Benefits bar contains vitamins
E, A, C and Jojoba and Macademia Nut oil as their specific benefit ingredients.
[0083] The kit could contain bars from one or more of the categories. A set of instructions
is also preferably provided with the kit instructing the user of the kit in how to
assemble the cleansing article that meets the users ) needs.
Table 1. Three part kit.
| Cleansing |
Benefits |
Fragrances |
| Natural |
Nourishing |
Rejuvenating |
| Gentle |
Vitamin E,A,C |
Cucumber Essence |
| |
Jojoba Oil |
Berry Blossom |
| |
Macadamia Nut Oil |
Ginger |
| Sensitive |
|
|
| |
Anti-aging |
Calming |
| Purifying |
AHA's |
Lavender |
| |
Retinal |
Vanilla |
| |
|
Aloe |
| |
|
|
| |
Moisturizing |
Romantic |
| |
Shea Butter |
Champagne |
| |
Cocoa Butter |
Plumeria |
| |
Sunflower Seed Oil |
Pomegranate |
| |
Smoothing |
Cooling |
| |
Safflower Oil |
Citrus |
| |
|
Melon |
| |
|
|
| |
|
|
| |
Silkening |
Sensual Fruits |
| |
Honey Silk Protein |
Strawberry Raspberry |
| |
Milk |
Apricot |
| |
|
|
| |
Hydrating |
Floral |
| |
Chamomile |
Roses |
| |
Glycerin |
Jasmin |
| |
|
Lilac |
| |
|
|
Examples of Use:
[0084]
1. One bar from each category.
2. Combine bars with various fragrances to make your own custom fragrance.
- a. Blend Cucumber & Melon Bars to obtain a Cucumber-Melon fragrance
- b. Combine Strawberry & Champagne Bars to obtain a Strawberry-Champagne fragrance
- c. Combine Vanilla & Rose Bars to obtain a Vanilla-Rose fragrance
3. The bars can also be sold separately, to complete or replenish a Kit.
Rigidity Index
Equipment used: Instron
Basic Method:
[0085]
- 1. Load Cell with the solid/semi-solid bar that is equilibrated and maintained at
a constant temperature of 25°C using a water bath.
- 2. Apply force from the top so that the solid/semi-solid bar is displaced at a rate
of 10 mm/min through an orifice at the bottom of cell and measure the force applied
in kN. The orifice has a diameter of .2 mm and a length of 60 mm.
[0086] The Pressure drop across the capillary length defines how rigid the material is.
This rigidity index is defined as:

Where the

Diam= diameter of the rod applying the force, in this case 31.4 mm.
1. Persönliches Reinigungs-Kit (60), umfassend:
a. einen Behälter (64);
b. ein verschließbares Behältnis (40), das geöffnet und geschlossen werden kann und
das aus einem porösen Material geformt ist;
c. eine Vielzahl von festen oder halbfesten Stücken (24, 26, 28, 30), die außerhalb
des Behältnisses (40) in dem Behälter (64) gehalten werden, umfassend ein erstes Stück
mit einer Reinigungszusammensetzung und ein zweites Stück mit einer zweiten Zusammensetzung,
ausgewählt aus einer ästhetischen Zusammensetzung, einer Zusammensetzung mit günstigen
Eigenschaften für die Haut und/oder einer kombinierten ästhetischen Zusammensetzung
mit günstigen Eigenschaften; wobei die Reinigungszusammensetzung und die zweite Zusammensetzung
sich voneinander unterscheiden;
wobei die Reinigungszusammensetzung ein oberflächenaktives Mittel, ausgewählt aus
einem synthetischen anionischen oberflächenaktiven Mittel, einer Seife und einer Mischung
davon, in einer Konzentration von höher als etwa 5 Gew.-% enthält und die zweite Zusammensetzung
ein ästhetisches Ingrediens, ein Ingrediens mit günstigen Eigenschaften für die Haut
oder eine Mischung davon enthält; wobei das ästhetische Ingrediens oder das Ingrediens
mit günstigen Eigenschaften in einer Konzentration vorliegt, die höher ist als die
Konzentration desselben Ingrediens in der Reinigungszusammensetzung und
wobei das schließbare Behältnis (40) und die Vielzahl von festen oder halbfesten Stücken
(24, 2, 28, 30) in dem Behälter (64) enthalten sind, der unterteilt ist, um das Behältnis
(40) und die Vielzahl von festen oder halbfesten Stücken (24, 26, 28, 30) zur einfachen
Auswahl durch den Verbraucher zu trennen, was dem Verbraucher ermöglicht, die ersten
und zweiten Stücke (24, 26, 28, 30) im Inneren des verschließbaren Behältnisses (40)
auszuwählen und einzusetzen, um ein persönliches, individuell gestaltetes Reinigungsprodukt
zu bilden, und
d. gegebenenfalls einen Satz von Instruktionen, die sich auf die Verwendung des Kits
beziehen.
2. Reinigungs-Kit nach Anspruch 1, wobei die erste und die zweite Zusammensetzung einen
Festigkeits-Index bei 25 °C von größer als 0,2 MPa haben.
3. Reinigungs-Kit nach einem vorangehenden Anspruch, wobei das ästhetische Ingrediens
aus Duftstoffen, Färbemitteln, Pigmenten, Kosmetika, suspendierten Körpern und Mischungen
davon ausgewählt ist, und das Ingrediens mit günstigen Eigenschaften aus Weichmachern,
Wirkstoffen für die Haut und Mischungen davon; ausgewählt ist
wobei die Reinigungszusammensetzung 15 bis 80 Gew.-% eines C8- bis C24-Acylisethionats
oder 15 bis 80 Gew.-% einer Seife umfasst;
wobei die Zusammensetzung mit günstigen Eigenschaften ein Weichmacher, ausgewählt
aus Silikonölen und Gummen, Fetten, Triglyceridölen, Wachsen, hydrophoben Pflanzenextrakten,
Fettsäureestern, Kohlenwasserstoffen oder einer Komponente, ausgewählt aus Vitaminen,
antimikrobiellen Mitteln, Akne-Medikationen, Peelingmitteln, Adstringentien, Antioxidantien,
Enzymen, Sonnenschutzmitteln und ultraviolette Strahlung absorbierenden Zusammensetzungen,
und Mischungen davon umfasst.
4. Verfahren zur Bereitstellung eines persönlichen, individuell gestalteten Reinigungsprodukts
für einen Verbraucher, umfassend die Schritte:
a. Bereitstellen einer Auswahl einer Vielzahl von festen oder halbfesten Stücken (24,
26, 28, 30), umfassend ein erstes Stück mit einer Reinigungszusammensetzung und ein
zweites Stück mit einer zweiten Zusammensetzung, ausgewählt aus einer ästhetischen
Zusammensetzung, einer Zusammensetzung mit günstigen Eigenschaften für die Haut und
einer kombinierten ästhetischen Zusammensetzung mit günstigen Eigenschaften; wobei
die Reinigungszusammensetzung und die zweite Zusammensetzung sich voneinander unterscheiden;
b. wobei die Reinigungszusammensetzung ein oberflächenaktives Mittel, ausgewählt aus
einem synthetischen anionischen oberflächenaktiven Mittel, einer Seife und einer Mischung
davon, in einer kombinierten Konzentration von größer als etwa 5 Gew.-% enthält und
die zweite Zusammensetzung ein ästhetisches Ingrediens, ein Ingrediens mit günstigen
Eigenschaften für die Haut und eine Mischung davon enthält; wobei das ästhetische
Ingrediens oder das Ingrediens mit günstigen Eigenschaften in einer Konzentration
vorliegt, die höher als die Konzentration desselben Ingrediens in der Reinigungszusammensetzung
ist;
c. Bereitstellen eines schließbaren Behältnisses (40), das aus einem porösen Material
geformt ist, um die Vielzahl von festen oder halbfesten kosmetischen Stücken aufzunehmen,
und wobei das verschließbare Behältnis (40) und die Vielzahl von festen oder halbfesten
Stücken (24, 26, 28, 30) in einem Behälter (64) enthalten sind, der unterteilt ist,
um das Behältnis (40) und die Vielzahl von festen oder halbfesten Stücken zu trennen,
für eine Vereinfachung der Auswahl durch den Verbraucher; und
d. dem Verbraucher erlauben, die ersten und zweiten Stücke (24, 26, 28, 30) auszuwählen
und in das verschließbare Behältnis (40) einzusetzen, um ein persönliches, individuell
gestaltetes Reinigungsprodukt zu bilden; und
e. dem Verbraucher erlauben, die ersten und zweiten Stücke in einer beliebigen gewünschten
Kombination zuzufügen, zu entfernen oder zu ersetzen.
5. Verfahren nach Anspruch 4, wobei das ästhetische Ingrediens ausgewählt wird aus Duftstoffen,
Färbemitteln, Pigmenten, Kosmetika, suspendierten Körpern und Mischungen davon und
das Ingrediens mit günstigen Eigenschaften ausgewählt wird aus Weichmachern, Wirkstoffen
für die Haut und Mischungen davon;
wobei die Reinigungszusammensetzung etwa 15 Gew.-% bis 80 Gew.-% eines C8- bis C24-Acylisethionats
oder etwa 15 Gew.-% bis 80 Gew.-% einer Seife umfasst;
wobei die Zusammensetzung mit günstigen Eigenschaften ein Weichmacher, ausgewählt
aus Silikonölen und Gummen, Fetten, Triglyceridölen, Wachsen, hydrophoben Pflanzenextrakten,
Fettsäureestern, Kohlenwasserstoffen oder eine Komponente, ausgewählt aus Vitaminen,
antimikrobiellen Mitteln, Akne-Medikationen, Exfoliationsmitteln, Adstringentien,
Antioxidantien, Enzymen, Sonnenschutzmitteln und ultraviolette Strahlung absorbierenden
Zusammensetzungen und Mischungen davon umfasst.
6. Verfahren nach Anspruch 4 oder 5, wobei das verschließbare Behältnis (40) aus einem
polymeren Maschenmaterial gebildet ist.