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EP 1 855 047 B1 |
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EUROPEAN PATENT SPECIFICATION |
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Mention of the grant of the patent: |
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01.07.2009 Bulletin 2009/27 |
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Date of filing: 12.05.2006 |
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International Patent Classification (IPC):
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A system and method for vaporizing cryogenic liquids using a naturally circulating
intermediate refrigerant
Vorrichtung und Verfahren zum Verdampfen kryogener Flüssigkeiten unter Zuhilfennahme
eines im Naturumlauf gefahrenen Wärmeübertragungsfluids
Appareil et méthode de vaporisation de liquides cryogènes à l'aide d'un fluide caloporteur
circulant naturellement
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Designated Contracting States: |
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AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU LV MC NL PL PT RO SE
SI SK TR |
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Date of publication of application: |
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14.11.2007 Bulletin 2007/46 |
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Proprietor: Black & Veatch Corporation |
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Overland Park, KS 66211 (US) |
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Inventors: |
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- Minton, Bill R.
Houston, Texas 77041 (US)
- Franklin, David A.
Katy, Texas 77494 (US)
- Rosetta, Martin J.
Pearland, , Texas 77584 (US)
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Representative: Duckett, Anthony Joseph et al |
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Mathys & Squire LLP
120 Holborn London
EC1N 2SQ London
EC1N 2SQ (GB) |
| (56) |
References cited: :
EP-A1- 0 048 316 FR-A- 2 124 635 GB-A- 2 018 967 US-A- 6 164 247
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WO-A-03/085317 FR-A1- 2 357 814 US-A- 3 986 340 US-A1- 2001 008 126
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| Note: Within nine months from the publication of the mention of the grant of the European
patent, any person may give notice to the European Patent Office of opposition to
the European patent
granted. Notice of opposition shall be filed in a written reasoned statement. It shall
not be deemed to
have been filed until the opposition fee has been paid. (Art. 99(1) European Patent
Convention).
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FIELD OF THE INVENTION
[0001] The present invention relates to a system and method for vaporizing cryogenic fluids
using a naturally circulating intermediate refrigerant in a thermal siphon type arrangement
wherein a first heat exchanger is positioned above a second heat exchanger so that
the intermediate refrigerant is vaporized in the second heat exchanger with the vapor
passing upwardly into the first exchanger for heat exchange with a cryogenic liquid
with a condensed intermediate refrigerant liquid being recovered and passed back to
the second heat exchanger by gravity flow.
BACKGROUND OF THE INVENTION
[0002] In many areas of the world, large natural gas deposits are found, which are remote
from any commercial market for the volumes of natural gas available. Accordingly,
methods have been considered for moving natural gas to commercial markets by pipeline
and by liquefaction of the natural gas followed by transport by ship and the like.
When the natural gas is liquefied and transported by ship or the like to a destination
it is necessary to revaporize the liquefied natural gas (LNG) for use as a natural
gas.
[0003] Many approaches have been used for such vaporization or revaporization. For instance,
seawater is frequently used as a heating medium to vaporize the LNG since seawater
is normally present at the unloading area. A continuing problem, however, is the large
surface area required in the heat exchangers for revaporization of the LNG by seawater
as a heating medium. Further, the use of seawater results in contamination of the
heat exchanger surfaces in many instances so that frequent cleaning is required. Further,
when lower flow rates of seawater or excessively high rates of cryogenic liquid are
used, the seawater can freeze in the seawater side of the heat exchange system used.
This can result in damage to the system as well as interrupting production of vaporized
cryogenic material. Accordingly, an improved method has been sought to accomplish
the desired heat exchange efficiently and in a smaller area, which is of tremendous
benefit when the regasification is accomplished offshore and the like.
[0004] FR-A-2357814, considered as closest prior art, discloses an apparatus for vaporizing liquefied
natural gas using estuarine water comprising as arranged in series a heat exchanger
of the indirectly heating, intermediate fluid type, a multitubular concurrent heat
exchanger and a multitubular countercurrent heat exchanger.
SUMMARY OF THE INVENTION
[0005] According to the present invention, it has been found that cryogenic liquids are
readily revaporized by a method for vaporizing a cryogenic fluid using a naturally
circulating intermediate refrigerant, the method comprising: passing the cryogenic
liquid in heat exchange contact with a vaporous intermediate refrigerant in a first
heat exchanger having a vaporous intermediate refrigerant inlet and a liquid intermediate
refrigerant outlet to heat the cryogenic fluid to produce a gaseous cryogenic fluid
and a liquid intermediate refrigerant; passing the liquid intermediate refrigerant
in heat exchange contact with a heating fluid in a second heat exchanger having a
liquid intermediate refrigerant inlet and a vaporous intermediate refrigerant outlet
to heat the intermediate refrigerant to produce the vaporous intermediate refrigerant,
the first heat exchanger being above the second heat exchanger; allowing the vaporous
intermediate refrigerant to rise into the first heat exchanger; and, allowing the
liquid intermediate refrigerant to flow downwardly into the second heat exchanger;
wherein the first and second heat exchangers are plate type heat exchangers.
[0006] The invention further comprises a system for vaporizing a cryogenic liquid using
a naturally circulating intermediate refrigerant, the system comprising: a first heat
exchanger having a liquid cryogenic fluid inlet, a vaporized cryogenic fluid outlet,
a vaporized intermediate refrigerant inlet and a liquid intermediate refrigerant outlet;
and, a second heat exchanger having a liquid refrigerant inlet, a vaporized refrigerant
outlet, a heating fluid inlet and a heating fluid outlet, the first heat exchanger
being positioned above the second heat exchanger with the vaporized intermediate refrigerant
inlet to the first heat exchanger being in fluid communication with the vaporized
intermediate refrigerant outlet from the second heat exchanger and with the liquid
intermediate refrigerant outlet from the first heat exchanger being in fluid communication
with the liquid intermediate refrigerant inlet to the second heat exchanger; wherein
the first and second heat exchangers are plate type heat exchangers.
BRIEF DESCRIPTION OF THE DRAWINGS
[0007]
FIG 1. is a schematic diagram of a comparative system and comprises a heat exchanger
comprising two tube bundles in a vertical position inside a low pressure vessel with
a welded plate type heat exchanger as an intermediate refrigerant reboiler;
FIG 2. is a schematic diagram of an embodiment of the present invention using a plate
type heat exchanger for both the vaporization of the cryogenic liquid and for vaporizing
of the intermediate refrigerant;
FIG 3 is a schematic diagram of a further embodiment of the present invention wherein
a superheater is provided to superheat the refrigerant vapor;
In FIG 4. a superheater is used to superheat the vaporized natural gas; and,
In FIG 5 an intermediate separation vessel is used between the intermediate refrigerant
vapor outlet from the intermediate refrigerant heater and the liquid intermediate
refrigerant outlet from the cryogenic liquid vaporizing section.
DESCRIPTION OF PREFERRED EMBODIMENTS
[0008] In the description of the FIGs, the same numbers will be used throughout to refer
to the same or similar components.
[0009] In FIG 1 a comparative system is shown which uses a typical shell and tube heat exchanger
in a vertical configuration. Vaporization system 10 comprises a refrigerant condenser
and cryogenic liquid vaporizer having a top 11. The refrigerant condenser (first heat
exchanger) 12 includes a cryogenic liquid inlet 14 and a vaporized cryogenic fluid
outlet 16. As shown, line 14 passes liquid cryogenic material into a zone established
by a divider 21 and a header 20 and into an inlet of tube bundles 18. The vaporized
cryogenic material is recovered through an outlet from tubes 18 through a header 22
and passed to line 16. Two headers for the two tube bundles 18 are shown. The second
bundle of tubes is shown as receiving the cryogenic liquid through a header 24 into
the tube bundles 18 and recovering the vaporized cryogenic material through a header
26 from an outlet from tube bundles 18 in header 26. A variety of arrangements can
be used to pass the cryogenic material through headers into heat exchange tubes as
well known to those skilled in the art. The embodiment shown is illustrative only.
[0010] The first heat exchanger 12 also includes a refrigerant vapor inlet 38 through which
refrigerant vapor is introduced and passes upward through a riser 30 and outwardly
into a space for refrigerant vapor 28, as shown by arrows 50. The vapor then exchanges
heat with the cryogenic fluid in tube bundles 18 and condenses into a liquid intermediate
refrigerant material. A representative liquid level 32 is shown in a bottom 34 of
heat exchanger 12. The liquid intermediate refrigerant is passed through an outlet
36 through a line 45 and into an inlet 44 into a second heat exchanger 40. In second
heat exchanger 40, the intermediate refrigerant is heated by heat exchange contact
with a heat exchange fluid passed into heat exchanger 40 via an inlet 46 and a line
47. The intermediate refrigerant is vaporized in second heat exchanger 40 by heat
exchange with the heat exchange fluid which is then discharged through an outlet 48
and a line 49. Refrigerant vapor is discharged through a line 42 and passes upwardly
through a line 43 into a vaporous refrigerant inlet 38 into first heat exchanger 12.
In the operation of the heat exchanger system, the liquid head in bottom 34 of first
heat exchanger 12 supplies the motive force to flow liquid intermediate refrigerant
back through line 45 into inlet 44 into second heat exchanger 40. The vaporized heat
exchange fluid is then passed upwardly into first heat exchanger 12 as a vapor. This
cycle is a repeating cycle and provides a supply of heat to first heat exchanger 12
from second heat exchanger 40 without the need for mechanical pumps or the like.
[0011] Plate type heat exchangers are marketed by many suitable suppliers. Printed circuit
heat exchanges are a type of plate heat exchanges and are marketed by HEATRIC. Printed
circuit heat exchangers are extremely compact, high efficiency heat exchangers which
readily tolerate high pressure and have extreme temperature capabilities. The printed
circuit heat exchangers basically are prepared by etching a flow path into a plate
with a matching flow path being etched into another plate with the two plates then
being joined, as known to those skilled in the art. The plates are stacked and may
be diffusion bonded and also welded if desired. These plates can have a wide variety
of heat exchange paths and are considered to be well known to those skilled in the
art. Because of their high efficiency and compact configuration, plate heat exchangers
are used in the process of the present invention. They are also configured to provide
certain advantages with respect to their cleaning and use generally when seawater
is used as a heat exchange material.
[0012] It should be noted that not only seawater but any other suitable liquid or vapor
which is warm relative to the cryogenic liquid and at a temperature sufficient to
vaporize the intermediate refrigerant can be used as a heat exchange fluid in the
second heat exchanger. Some such materials are freshwater, seawater, light hydrocarbons,
steam, air, quench water and refinery waste heat streams and the like.
[0013] Desirably the intermediate refrigerant is a material such as propane, mixed refrigerants,
fluorocarbon refrigerants, chlorofluorocarbon refrigerants, such as the family of
FREON refrigerants produced by DuPont and the like, which do not freeze at cryogenic
temperatures, i.e., below -100°F. A primary criterion in the intermediate refrigerant
is that it be readily vaporized by the heat exchange fluid available and that it be
effective to convey heat to the first heat exchanger and condense in heat exchange
contact with the cryogenic liquid. Since most intermediate refrigerants will readily
condense at the temperature of the cryogenic liquid, a primary consideration is the
ready vaporization of the intermediate refrigerant by the heat source available. It
is further desirable that the intermediate refrigerant remain liquid in contact with
the heat exchange surfaces in contact with the liquid cryogenic fluid in the first
heat exchanger. The refrigerants named are considered to meet these criteria. Certain
of the refrigerants may be more desirable than others for certain applications.
[0014] In accordance with the present invention, shown for instance in FIG 2, a plate type
heat exchanger is used for both the first heat exchanger 12 and the second heat exchanger
40. The flow through these plate type heat exchangers is as discussed previously.
For instance, the intermediate refrigerant vapor is produced from an intermediate
refrigerant vapor outlet 42 from the second heat exchanger and passed through a line
43 to an inlet 38 to first exchanger 12 where a cryogenic fluid is introduced through
a line 14 and recovered through line 16 in a revaporized or partially revaporized
form. The condensed intermediate refrigerant is recovered through an outlet 36 from
first heat exchanger 12 and passed via a line 45 to second heat exchanger 40.
[0015] As shown in FIG 2, a heating fluid is introduced through an inlet 46 and a line 47
and discharged via an outlet 48 through a line 49. The operation of the first and
second heat exchanger in combination is as discussed previously with the condensed
liquid intermediate refrigerant discharged through outlet 36 supplying the necessary
fluid head for movement of the intermediate refrigerant through line 45 to inlet 44
to second heat exchanger 40. The vapor is discharged through line 42 and line 43 to
inlet 38 with the operation of the refrigerant flow being completely by gravity by
a thermal siphon type process. This type process presents significant advantages in
that no pumps are necessary for the circulation of the intermediate refrigerant, although
a pump could be used if desired. Since the refrigerant is a material not readily frozen
in contact with the heat exchange surfaces containing the cryogenic liquid and is
readily vaporized in the second heat exchanger, an efficient heat transfer is accomplished
without exposing the heating fluid in line 47 to direct contact with heat exchange
surfaces containing the cryogenic liquid. This is a significant advantage with respect
to the freezing of the heat exchange fluid during periods of slow heat exchange fluid
flow or high flows of cryogenic fluid.
[0016] Desirably outlet 36 is placed sufficiently above inlet 44 to provide the necessary
heat for the desired flow. The height is typically at least about two feet and is
preferably from about two to about ten feet. More preferably, the height is at least
about six feet and desirably from about six to about ten feet.
[0017] In FIG 3, another embodiment is shown. In this embodiment, a superheater 54 is used
with a second heating medium supplied through a line 56 and recovered through a line
58 to superheat the intermediate refrigerant vapor, which is then passed through an
outlet 42 from superheater 54 through a line 43 into an inlet 38 to first heater 12.
The liquid refrigerant is returned as discussed previously through line 44 to second
heater 40.
[0018] In FIG 4, a further embodiment is shown wherein a superheater 60, heated by heating
material supplied through line 56 and recovered through line 58, is used to superheat
the recovered cryogenic material which has been liquefied in heat exchanger 12 (downstream).
In other aspects the flow of material is as described previously.
[0019] In FIG 5, a further embodiment is shown where a separator 62, having a liquid level
64, is used to ensure the separation of liquid and vapor from the streams in lines
43 and 45. The liquid refrigerant passed from outlet 36 through line 45 to separator
62 is desirably all liquid. Accordingly, this stream is introduced into separator
62 below the liquid level 64 in separator 62. Similarly, the stream recovered via
outlet 42 and passed through line 43 to separator 62 is desirably all vapor. This
stream is introduced into separator 62 at a level above liquid level 64 and a vapor
stream is then passed onward through line 43' to inlet 38 to vessel 12. Similarly,
a liquid stream is recovered from separator 62 and passed through line 45' to inlet
44 to heat exchanger 40. This embodiment ensures that the vaporous intermediate refrigerant
is passed as a vapor to first exchanger 12 and that the liquid intermediate refrigerant
is passed to second heat exchanger 40 as a liquid.
[0020] It should be understood that liquid may be entrained with the vapor passed to first
heat exchanger 12 and that vapor may be absorbed or contained in the intermediate
refrigeration stream passed back to second heat exchanger 40. Such inclusion of liquid
or vapor does not affect the operation of either vessel significantly since the vessels
each act substantially as a separation vessel in their own right, as well as heat
exchangers.
[0021] Accordingly to the present invention, an intermediate refrigerant is used which is
not prone to freeze on heat exchange surfaces in contact with the cryogenic liquids.
Clearly when a material such as seawater is used as a heat exchange material, there
is always a risk that seawater in contact with heat exchange surfaces contacting cryogenic
materials may freeze, thus obstructing the passage of additional heat exchange material
and resulting in even greater freezing of the vessel. Since the freezing may be relatively
sudden considering the radical difference in temperature between the seawater and
the cryogenic materials, this can result in substantial damage to heat exchange surfaces
in a very short period of time. These problems are avoided by the present invention
wherein an intermediate refrigerant resistant to freezing in contact with surfaces
contacting cryogenic liquids is used.
[0022] Further the plate type heat exchangers used in the present invention are very readily
cleaned in the event that pollution of the heat exchange surfaces occurs as a result
of the passage of the seawater. The occurrence of pollution is minimized because the
differential temperature across the heat exchange surfaces is much less. Further the
environmental problems resulting from discharging seawater at a very low temperature
into the sea are avoided. By the present invention, the heat exchange can be a lower
temperature since the heat of vaporization is supplied by seawater which can be used
readily in larger volumes since the plate type heat exchangers are very efficient
and occupy a relatively small area. Since the heat of vaporization is transferred
to the cryogenic fluid, a greater heat transfer can be achieved than if only sensible
heat were available for transfer to the cryogenic liquid. Further, the present invention
reduces the need for pumping an intermediate refrigerant, thereby making the process
more energy efficient.
[0023] By positioning the heat exchangers so that the second heat exchanger is below the
first heat exchanger and so that the superheaters are above the first heater and the
second heater respectively, much less area is required for the installation of a revaporizing
system having sufficient capacity to handle large quantities of cryogenic liquid.
Further, systems of these types could readily be placed side by side so that the appropriate
number of systems could be used to vaporize a desired cryogenic fluid at a desired
rate. It is clear that the inlet and outlet from the second heat exchanger could be
positioned to draw seawater from a substantial distance from the platform and discharge
it a substantial distance from a platform or other facility.
[0024] In summary, the present invention has provided a highly efficient and high effective
method and system for revaporizing a cryogenic liquid by the use of an intermediate
refrigerant, which is not prone to the problems associated with the use of most commonly
used heat exchange materials used to revaporize cryogenic liquids.
[0025] While the present invention has been described by reference to certain of its preferred
embodiments, it is pointed out that the embodiments described are illustrative rather
than limiting in nature and that many variations and modifications are possible within
the scope of the present invention. Many such variations and modifications may be
considered obvious and desirable by those skilled in the art based upon a review of
the foregoing description of preferred embodiments.
1. A method for vaporizing a cryogenic fluid using a naturally circulating intermediate
refrigerant, the method comprising:
a) passing the cryogenic liquid in heat exchange contact with a vaporous intermediate
refrigerant in a first heat exchanger having a vaporous intermediate refrigerant inlet
and a liquid intermediate refrigerant outlet to heat the cryogenic fluid to produce
a gaseous cryogenic fluid and a liquid intermediate refrigerant;
b) passing the liquid intermediate refrigerant in heat exchange contact with a heating
fluid in a second heat exchanger haying a liquid intermediate refrigerant inlet and
a vaporous intermediate refrigerant outlet to heat the intermediate refrigerant to
produce the vaporous intermediate refrigerant, the first heat exchanger being above
the second heat exchanger;
c) allowing the vaporous intermediate refrigerant to rise into the first heat exchanger;
and,
d) allowing the liquid intermediate refrigerant to flow downwardly into the second
heat exchanger;
wherein the first and second heat exchangers are plate type heat exchangers.
2. The method of claim 1 wherein the cryogenic fluid is liquefied natural gas.
3. The method of claim wherein the first heat exchanger is a printed circuit heat exchanger.
4. The method of claim 1 wherein the heating fluid is seawater.
5. The method of claim 1 wherein the refrigerant comprises at least one of propane, a
mixed refrigerant, a fluorocarbon refrigerant and a chlorofluorocarbon refrigerant.
6. The method of claim 1 wherein the cryogenic fluid is further heated in a third heat
exchanger downstream from the first heat exchanger.
7. The method of claim 1 wherein the intermediate refrigerant is further heated in a
fourth heat exchanger between the second heat exchanger and the first heat exchanger.
8. The method of claim 1 wherein the liquid intermediate refrigerant outlet from the
first heat exchanger is placed sufficiently above the liquid intermediate refrigerant
inlet to the second heat exchanger to assure natural circulation of the refrigerant.
9. The method of claim 1 wherein the liquid intermediate refrigerant outlet from the
first heat exchanger is at least about two feet above the liquid intermediate refrigerant
to the second heat exchanger.
10. A system for vaporizing a cryogenic liquid using a naturally circulating intermediate
refrigerant, the system comprising:
a) a first heat exchanger having a liquid cryogenic fluid inlet, a vaporized cryogenic
fluid outlet, a vaporized intermediate refrigerant inlet and a liquid refrigerant
outlet;
b) a second heat exchanger having a liquid refrigerant inlet, a vaporized refrigerant
outlet, a heating fluid inlet and a heating fluide outlet, the first heat exchanger
being positioned above the second heat exchanger with the vaporized intermediate refrigerant
inlet to the first heat exchanger being in fluid communication with the vaporized
intermediate refrigerant outlet from the second heat exchanger and with the liquid
intermediate refrigerant outlet from the first heat exchanger being in fluid communication
with the liquid intermediate refrigerant inlet to the second heat exchanger;
wherein the first and second heat exchangers are plate type heat exchangers.
11. The system of claim 10 wherein the liquid intermediate refrigerant outlet from the
first heat exchanger is placed sufficiently above the liquid intermediate refrigerant
inlet to the second heat exchanger to assure natural circulation of the refrigerant.
12. The system of claim 10 wherein the liquid refrigerant outlet of the first heat exchanger
is at least about two feet above the liquid refrigerant inlet into the second heat
exchanger.
13. The system of claim 10 wherein a third heat exchanger is positioned in fluid communication
with the vaporized cryogenic fluid outlet to heat the vaporized cryogenic fluid.
14. The system of claim 10 wherein a fourth heat exchanger is positioned in fluid communication
with the vaporized intermediate refrigerant outlet to heat the vaporized intermediate
refrigerant.
15. The system of claim 10 wherein a vessel is positioned in fluid communication with
the liquid intermediate refrigerant outlet, the vaporized intermediate refrigerant
outlet, the liquid intermediate refrigerant inlet, and the vaporized intermediate
refrigerant inlet to separate vaporized and liquid intermediate refrigerant for passage
to the vaporized intermediate refrigerant inlet and to the liquid intermediate refrigerant
inlet respectively.
1. Verfahren zum Verdampfen einer kryogenischen Flüssigkeit mittels eines natürlich zirkulierenden
intermediären Kältemittels, wobei das Verfahren umfasst:
a) Führen der kryogenischen Flüssigkeit in Wärmeaustauschkontakt mit einem dampfförmigen
intermediären Kältemittel in einen ersten Wärmetauscher, der einen Eingang für das
dampfförmige intermediäre Kältemittel und einen Ausgang für das flüssige intermediäre
Kältemittel aufweist, um die kryogenische Flüssigkeit zu erwärmen, um eine gasförmige
kryogenische Flüssigkeit und ein flüssiges intermediäres Kältemittel zu erzeugen;
b) Führen des flüssigen intermediären Kältemittels in Wärmeaustauschkontakt mit einer
Wärmeflüssigkeit in einen zweiten Wärmetauscher, der einen Eingang für das flüssige
intermediäre Kältemittel und einen Ausgang für das dampfförmige intermediäre Kältemittel
aufweist, um das intermediäre Kältemittel zu erwärmen, um das dampfförmige intermediäre
Kältemittel zu erzeugen, wobei sich der erste Wärmetauscher oberhalb des zweiten Wärmetauschers
befindet;
c) Ermöglichen, dass das dampfförmige intermediäre Kältemittel in den ersten Wärmetauscher
aufsteigt; und
d) Ermöglichen, dass das flüssige intermediäre Kältemittel nach unten in den zweiten
Wärmetauscher fließt;
wobei der erste und der zweite Wärmetauscher Wärmetauscher des Plattentyps sind.
2. Verfahren nach Anspruch 1, wobei die kryogenische Flüssigkeit ein verflüssigtes Naturgas
ist.
3. Verfahren nach Anspruch 1, wobei der erste Wärmetauscher ein Platinen-Wärmetauscher
ist.
4. Verfahren nach Anspruch 1, wobei die Wärmeflüssigkeit Meerwasser ist.
5. Verfahren nach Anspruch 1, wobei das Kältemittel wenigstens eines von Propan, einem
gemischten Kältemittel, einem Fluorkohlenwasserstoff-Kältemittel und einem Fluorchlorkohlenwasserstoff-Kältemittel
aufweist.
6. Verfahren nach Anspruch 1, wobei die kryogenische Flüssigkeit des Weiteren in einem
dritten Wärmetauscher, der dem ersten Wärmetauscher nachgeschaltet ist, erwärmt wird.
7. Verfahren nach Anspruch 1, wobei das intermediäre Kältemittel des Weiteren in einem
vierten Wärmetauscher zwischen dem zweiten Wärmetauscher und dem ersten Wärmetauscher
erwärmt wird.
8. Verfahren nach Anspruch 1, wobei der Ausgang für das flüssige intermediäre Kältemittel
aus dem ersten Wärmetauscher ausreichend oberhalb des Eingangs für das flüssige intermediäre
Kältemittel in den zweiten Wärmetauscher platziert ist, um die natürliche Zirkulation
des Kältemittels sicherzustellen.
9. Verfahren nach Anspruch 1, wobei der Ausgang für das flüssige intermediäre Kältemittel
aus dem ersten Wärmetauscher sich wenigstens ca. 0,61 m (zwei Fuß) oberhalb des Eingangs
für das flüssige intermediäre Kältemittel in den zweiten Wärmetauscher befindet.
10. System zum Verdampfen einer kryogenischen Flüssigkeit mittels eines natürlich zirkulierenden
intermediären Kältemittels, wobei das System aufweist:
a) einen ersten Wärmetauscher mit einem Eingang für die flüssige kryogenische Flüssigkeit,
einem Ausgang für die verdampfte kryogenische Flüssigkeit, einem Eingang für das verdampfte
intermediäre Kältemittel und einem Ausgang für das flüssige Kältemittel;
b) einen zweiten Wärmetauscher mit einem Eingang für das flüssige Kältemittel, einem
Ausgang für das verdampfte Kältemittel, einem Eingang für die Wärmeflüssigkeit und
einem Ausgang für die Wärmeflüssigkeit, wobei sich der erste Wärmetauscher oberhalb
des zweiten Wärmetauschers befindet, wobei der Eingang für das verdampfte intermediäre
Kältemittel in den ersten Wärmetauscher in flüssiger Verbindung mit dem Ausgang für
das verdampfte intermediäre Kältemittel aus dem zweiten Wärmetauscher steht, und wobei
der Ausgang für das flüssige intermediäre Kätemittel aus dem ersten Wärmetauscher
in flüssiger Verbindung mit dem Eingang des flüssigen intermediären Kältemittels in
den zweiten Wärmetauscher steht;
wobei der erste und der zweite Wärmetauscher Wärmetauscher des Plattentyps sind.
11. System nach Anspruch 10, wobei der Ausgang für das flüssige intermediäre Kältemittel
aus dem ersten Wärmetauscher ausreichend oberhalb des Eingangs für das flüssige intermediäre
Kältemittel in den zweiten Wärmetauscher platziert ist, um die natürliche Zirkulation
des Kältemittels sicherzustellen.
12. System nach Anspruch 10, wobei der Ausgang für das flüssige Kältemittel aus dem ersten
Wärmetauscher sich wenigstens ca. 0,61 m (zwei Fuß) oberhalb des Eingangs für das
flüssige Kältemittel in den zweiten Wärmetauscher befindet.
13. System nach Anspruch 10, wobei ein dritter Wärmetauscher in flüssiger Verbindung mit
dem Ausgang für die verdampfte kryogenische Flüssigkeit steht, um die verdampfte kryogenische
Flüssigkeit zu erwärmen.
14. System nach Anspruch 10, wobei ein vierter Wärmetauscher in flüssiger Verbindung mit
dem Ausgang für das verdampfte intermediäre Kältemittel steht, um das verdampfte intermediäre
Kältemittel zu erwärmen.
15. System nach Anspruch 10, wobei sich ein Gefäß in flüssiger Verbindung mit dem Ausgang
für das flüssige intermediäre Kältemittel, dem Ausgang für das verdampfte intermediäre
Kältemittel, dem Eingang für das flüssige intermediäre Kältemittel und dem Eingang
für das verdampfte intermediäre Kältemittel befindet, um das verdampfte und das flüssige
intermediäre Kältemittel zum Führen in den Eingang für das verdampfte intermediäre
Kältemittel bzw. in den Eingang für das flüssige intermediäre Kältemittel voneinander
zu trennen.
1. Méthode de vaporisation d'un fluide cryogène par utilisation d'un réfrigérant intermédiaire
circulant naturellement, la méthode comprenant les étapes consistant suivantes :
a) faire passer le fluide cryogène en contact d'échange thermique avec un réfrigérant
intermédiaire à l'état de vapeur dans un premier échangeur de chaleur ayant un orifice
d'admission de réfrigérant intermédiaire à l'état de vapeur et un orifice de sortie
de réfrigérant intermédiaire liquide, afin de chauffer le fluide cryogène pour produire
un fluide cryogène gazeux et un réfrigérant intermédiaire liquide ;
b) faire passer le réfrigérant intermédiaire liquide en contact d'échange thermique
avec un fluide chauffant dans un deuxième échangeur de chaleur ayant un orifice d'admission
de réfrigérant intermédiaire liquide et un orifice de sortie de réfrigérant intermédiaire
à l'état de vapeur, afin de chauffer le réfrigérant intermédiaire pour produire un
réfrigérant intermédiaire à l'état de vapeur, le premier échangeur de chaleur étant
situé au-dessus du deuxième échangeur de chaleur ;
c) permettre au réfrigérant intermédiaire à l'état de vapeur de monter dans le premier
échangeur de chaleur ; et,
d) permettre au réfrigérant intermédiaire liquide de s'écouler vers le bas dans le
deuxième échangeur de chaleur ;
dans laquelle le premier et le deuxième échangeur de chaleur sont des échangeurs de
chaleur du type à plaques.
2. Méthode selon la revendication 1, dans laquelle le fluide cryogène est du gaz naturel
liquéfié.
3. Méthode selon la revendication 1, dans laquelle le premier échangeur de chaleur est
un échangeur de chaleur à circuit imprimé.
4. Méthode selon la revendication 1, dans laquelle le fluide chauffant est de l'eau de
mer.
5. Méthode selon la revendication 1, dans laquelle le réfrigérant comprend au moins un
élément parmi le propane, un réfrigérant mixte, un réfrigérant fluorocarboné et un
réfrigérant chlorofluorocarboné.
6. Méthode selon la revendication 1, dans laquelle le fluide cryogène est en davantage
chauffé dans un troisième échangeur de chaleur situé en aval du premier échangeur
de chaleur.
7. Méthode selon la revendication 1, dans laquelle le réfrigérant intermédiaire est davantage
chauffé dans un quatrième échangeur de chaleur situé entre le deuxième échangeur de
chaleur et le premier échangeur de chaleur.
8. Méthode selon la revendication 1, dans laquelle l'orifice de sortie de réfrigérant
intermédiaire liquide depuis le premier échangeur de chaleur est positionné suffisamment
au-dessus de l'orifice d'admission de réfrigérant intermédiaire liquide vers le deuxième
échangeur de chaleur pour assurer une circulation naturelle du réfrigérant intermédiaire.
9. Méthode selon la revendication 1, dans laquelle l'orifice de sortie de réfrigérant
intermédiaire liquide depuis le premier échangeur de chaleur est situé au moins à
environ 61 cm (deux pieds) au-dessus de l'orifice d'admission de réfrigérant intermédiaire
liquide vers le deuxième échangeur de chaleur.
10. Système de vaporisation d'un fluide cryogène utilisant un réfrigérant intermédiaire
circulant naturellement, le système comprenant :
a) un premier échangeur de chaleur comprenant un orifice d'admission de fluide cryogène
liquide, un orifice de sortie de fluide cryogène vaporisé, un orifice d'admission
de réfrigérant intermédiaire vaporisé et un orifice de sortie de réfrigérant intermédiaire
liquide ;
b) un deuxième échangeur de chaleur comprenant un orifice d'admission de réfrigérant
intermédiaire liquide, un orifice de sortie de réfrigérant intermédiaire vaporisé,
un orifice d'admission de fluide chauffant et un orifice de sortie de fluide chauffant,
le premier échangeur de chaleur étant positionné au-dessus du deuxième échangeur de
chaleur et l'orifice d'admission de réfrigérant intermédiaire vaporisé vers le premier
échangeur de chaleur étant en communication fluidique avec l'orifice de sortie de
réfrigérant intermédiaire vaporisé depuis le deuxième échangeur de chaleur et l'orifice
de sortie de réfrigérant intermédiaire liquide depuis le premier échangeur de chaleur
étant en communication fluidique avec l'orifice d'admission de réfrigérant intermédiaire
liquide vers le deuxième échangeur de chaleur ;
dans lequel le premier et le deuxième échangeur de chaleur sont des échangeurs de
chaleur du type à plaques.
11. Système selon la revendication 10, dans lequel l'orifice de sortie de réfrigérant
intermédiaire liquide depuis le premier échangeur de chaleur est positionné suffisamment
au-dessus de l'orifice d'admission de réfrigérant intermédiaire liquide vers le deuxième
échangeur de chaleur pour assurer une circulation naturelle du réfrigérant intermédiaire.
12. Système selon la revendication 10, dans lequel l'orifice de sortie de réfrigérant
intermédiaire liquide depuis le premier échangeur de chaleur est situé au moins à
environ 61 cm (deux pieds) au-dessus de l'orifice d'admission de réfrigérant intermédiaire
liquide vers le deuxième échangeur de chaleur.
13. Système selon la revendication 10, dans lequel un troisième échangeur de chaleur est
monté en communication fluidique avec l'orifice de sortie de fluide cryogène vaporisé
pour chauffer le fluide cryogène vaporisé.
14. Système selon la revendication 10, dans lequel un quatrième échangeur de chaleur est
monté en communication fluidique avec l'orifice de sortie de réfrigérant intermédiaire
vaporisé pour chauffer le réfrigérant intermédiaire vaporisé.
15. Système selon la revendication 10, dans lequel une cuve est montée en communication
fluidique avec l'orifice de sortie de réfrigérant intermédiaire liquide, l'orifice
de sortie de réfrigérant intermédiaire vaporisé, l'orifice d'admission de réfrigérant
intermédiaire liquide et l'orifice d'admission de réfrigérant intermédiaire liquide
pour un passage vers l'orifice d'admission de réfrigérant intermédiaire vaporisé et
vers l'orifice d'admission de réfrigérant intermédiaire liquide, respectivement.


REFERENCES CITED IN THE DESCRIPTION
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It does not form part of the European patent document. Even though great care has
been taken in compiling the references, errors or omissions cannot be excluded and
the EPO disclaims all liability in this regard.
Patent documents cited in the description