[0001] The invention relates to an electron multiplying structure for use in a vacuum tube
using electron multiplying, the electron multiplying structure comprising an input
face intended to be oriented in a facing relationship with an entrance window of the
vacuum tube, an output face intended to be oriented in a facing relationship with
a detection surface of the vacuum tube, as well as an ion barrier membrane for shielding
off stray ions.
[0002] The invention also relates to an vacuum tube using electron multiplying having a
photocathode capable of releasing electrons into said vacuum chamber when exposed
to light, electric field means for accelerating said released electrons from said
photocathode towards an anode spaced apart from said photocathode in a facing relationship,
as well as an electron multiplying structure according to the invention disposed in
said vacuum chamber between said photocathode and said anode.
[0003] The invention also relates to an ion barrier membrane for use in a vacuum tube and/or
an electron multiplying structure according to the invention.
[0004] Please note that in this application vacuum tube structures using electron multiplying
comprise - amongst others - image intensifier tube devices, open faced electron multipliers,
channeltrons, microchannel plates and also sealed devices like image intensifiers
and photomultipliers that incorporate elements or subassemblies like discrete dynodes
and microchannel plates that use the phenomenon of secondary emission as a gain mechanism.
Such vacuum tubes are known in the art. They comprise a cathode which under the influence
of incident radiation, such as light or X-rays, emits so-called photo electrons which
under the influence of an electric field move towards an anode. The electrons striking
the anode constitute an information signal, which signal is further processed by suitable
processing means.
[0005] In modern image intensifier tubes an electron multiplying structure, mostly a microchannel
plate or MCP for short, is placed between the cathode and the anode to increase the
image intensification. In the case that the electron multiplying structure is constructed
as a channel plate, the channel plate comprises a stack of hollow tubes, e.g. hollow
glass fibres, extending between an input face and an output face. A (voltage) potential
difference is applied between the input face and the output face of the channel plate,
such that an electron entering a channel at the input face moves in the direction
of the output face, in which displacement the number of electrons is increased by
secondary emission effects. After leaving the channel plate at the output face these
electrons (primary electrons and secondary electrons) are accelerated in the usual
manner in the direction of the anode.
[0006] In each of these devices, there is an associated phenomenon that is commonly referred
to as 'ion feedback'. This phenomenon occurs when (negatively charged) electrons that
have acquired sufficient kinetic energy in the accelerating electric field strike
and ionise atoms or molecules still present in the vacuum chamber or adsorbed at the
surfaces stricken by the electrons.
[0007] Once the neutral gas atom or molecule has been positively charged by the electron
impact that knocked an electron from the outer region of the atom's electron cloud,
the ions are subjected to the same electric field but, due to their positive charge,
will move in the opposite direction, acquiring kinetic energy and striking surfaces
at the input side of the device.
[0008] These ion feedback impacts are quite often very noticeable and on most instances
disturb or reduce the signal outputted by the device by so-called after-pulses or
ion spots in the image of the device. In many of the prior art devices, special care
is given to the design, the construction or the limitation in operating pressure range
or operating voltages to avoid or reduce the effects of ion feedback.
[0009] As a solution, in particular in image intensifier tube devices having component surfaces
made from or contain vulnerable mono-atomic negative electron affinity layers, like
for example GaAs with a Cs-based surface layer, a so-called ion barrier membrane is
disposed in the vacuum chamber in order to shield off those component surfaces from
the stray ions. Such membrane will prevent that such stray ions will permanently damage
and reduce the photocathode's emissive quantum efficiency.
[0010] An essential drawback of such an ion barrier membrane is that it not only blocks
the feedback of stray ions, but it also considerably reduces the amount of primary
electrons that can be considered to carry the signal or image information in the device
towards the anode. Practical considerations of strength, desired permeability for
electrons and desired impermeability for ions have lead to most common thicknesses
of ion barrier membranes of several tens of nanometer using materials such as Al
2O
3 or SiO
2 or other compounds having a low atomic mass.
[0011] It is an object of the invention is to provide an electron multiplying structure
having an improved performance in term of shielding capabilities against stray ions
and reduced loss of emitted electrons. For this purpose, the electron multiplying
structure according to the invention is characterized in that said ion barrier membrane
is composed of at least one atomic layer containing graphene.
[0012] Graphene is a one-atom-thick planar sheet of carbon atoms having a hexagonal crystal
lattice and can be construed as a membrane shielding off the fragile or vulnerable
component surfaces of vacuum tubes using electron multiplying against stray ions.
In particular it has proven that a mono-atomic thickness graphene layer is impermeable
for stray ions and thus can serve as an efficient ion barrier membrane.
[0013] Furthermore due to the fact that a mono-atomic membrane of carbon atoms, such as
graphene, can be construed in a very thin membrane layer it has a significant low
loss of electrons. Therefore it will have the best detective quantum efficiency (DQE)
in devices where it will be used to block 'stray' ion feed back.
[0014] The shielding off capabilities of the ion barrier membrane according to the invention
can be further improved or otherwise influenced as according to the invention said
ion barrier membrane is composed of multiple atomic layers containing graphene.
[0015] More specifically said at least one atomic layer solely contains graphene.
[0016] In a specific embodiment of the invention said ion barrier membrane is placed at
the input face of the electron multiplying structure, whereas in another embodiment
said ion barrier membrane is placed at the output face of the electron multiplying
structure.
[0017] In yet another embodiment said electron multiplying structure is arranged to support
the entrance windows of said vacuum tube.
[0018] In a further embodiment said electron multiplying structure is constructed as a channel
plate, in particular a microchannel plate, whereas in another embodiment said electron
multiplying structure is constructed as an array of secondary electron emitting dynodes.
[0019] In a further aspect of the invention the vacuum tube using electron multiplying as
an image intensifier tube, whereas in another embodiment said vacuum tube is constructed
as a photo multiplier tube.
[0020] Also embodiments wherein said vacuum tube is constructed as a channeltron or as a
microchannel plate detector are advantageous over the prior art devices.
[0021] The invention will be explained in greater detail below with reference to the appended
drawing, which shows in:
Figure 1 a vacuum tube provided with an electron multiplying structure according to
the state of the art;
Figure 2 a first embodiment of a vacuum tube using electron multiplying with an electron
multiplying structure according to the invention;
Figure 3 a second embodiment of a vacuum tube using electron multiplying with an electron
multiplying structure according to the invention;
Figure 4 a third embodiment of a vacuum tube using electron multiplying with an electron
multiplying structure according to the invention;
Figure 5 a fourth embodiment of a vacuum tube using electron multiplying with an electron
multiplying structure according to the invention;
[0022] For the sake of clarity in the following detailed description all like parts are
denoted with the same reference numerals.
[0023] Figure 1 shows schematically, in cross section, an example of an vacuum tube, for
example an image intensifier. The image intensifier tube comprises a tubular housing
1 having an entrance or cathode window 2 and a detection or anode window 3. The housing
can be made of glass, as can the cathode window and the anode window. The detection
window 3 is, however, also often an optical fibre plate or constructed as a scintillating
screen or as a pixilated array of elements (such as a semiconductor active pixel array).
The housing can also be made of metal, in the event of the cathode and possibly the
anode being arranged in an insulated manner in the housing, for example by using a
separate carrier.
[0024] If the image intensifier is designed for receiving X-rays, the cathode window can
be made of a thin metal. The anode window can, however, be light-transmitting. The
cathode 4 can also be provided directly on the input face 7 of the channel plate 6.
All such variants are known per se and are therefore not shown in greater detail.
[0025] In the example shown the actual cathode 4 is on the inside of the entrance window
2 and emits electrons under the influence of incident light or x-rays (indicated in
Figures 1-5 with "h.v"). The emitted electrons are propelled in a known manner under
the influence of an electric field (not shown) in the direction of an anode 5 disposed
on the inside of the detection window 3.
[0026] An electron multiplying structure in this embodiment constructed as a channel plate
6 extending approximately parallel to cathode 4 and anode 5 is placed between cathode
and anode. A large number of tubular channels, which can have a diameter, e.g., of
the order of 8-12 µm, extend between the input face 7 of the channel plate facing
the entrance window 2 (cathode 4) and the output face 8 of the channel plate facing
the detection surface 3 (anode 5).
[0027] As mentioned in the introductionary part the phenomenon 'ion feedback' disturb or
reduce the signal outputted by the device by so-called after-pulses or ion spots in
the image of the device. In many of the prior art devices, special care is given to
the design, the construction or the limitation in operating pressure range or operating
voltages to avoid or reduce the effects of ion feedback.
[0028] This phenomenon occurs when (negatively charged) electrons that have acquired sufficient
kinetic energy in the accelerating electric field strike and ionise atoms or molecules
still present in the vacuum chamber or adsorbed at the surfaces stricken by the electrons,
here the anode 5 and the detection window 3.
[0029] According to the invention and as disclosed in Figures 2-5 the electron multiplying
structure 6 comprises an ion barrier membrane 10, which is composed of at least one
atomic layer containing graphene.
[0030] Please note that for solely illustrative purposes the atomic layer graphene ion barrier
mebrane is depicted as a thick line.
[0031] Graphene is a one-atom-thick planar sheet of carbon atoms having a hexagonal crystal
lattice and can be construed as a membrane shielding off the fragile or vulnerable
component surfaces of vacuum tubes using electron multiplying against stray ions.
In particular it has proven that a mono-atomic thickness graphene layer is impermeable
for stray ions moving from the detection windows 3 (5) in the direction of the electron
multiplying structure 8 and the entrance window 2 (4) due to the applied electric
field. A graphene mono-atomic layer thus can serve as an efficient ion barrier membrane.
[0032] Furthermore due to the fact that a mono-atomic membrane of carbon atoms, such as
graphene, can be construed in a very thin membrane layer it has a significant low
loss of electrons moving from the entrance windows 2 (4) and the electron multiplying
structure 8 towards the entrance window 3 (5) due to the applied electric field. Therefore
it will have the best detective quantum efficiency (DQE) in devices where it will
be used to block 'stray' ion feed back.
[0033] The shielding off capabilities of the graphene ion barrier membrane 10 can be further
improved or otherwise influenced by composing said ion barrier membrane 10 from multiple
atomic layers containing graphene.
[0034] In one embodiment said graphene ion barrier membrane 10 can be positioned between
the anode 5/detection window 3 and said output face 8 of the electron multiplying
means 6 (Figure 2).
[0035] In another embodiment (Figure 3) said graphene ion barrier membrane 10 is applied
on said output face 8 of the electron multiplying means 6.
[0036] In yet another embodiment (Figure 4) said graphene ion barrier membrane 10 is applied
on said input face 7 of the electron multiplying means 6, whereas in yet another embodiment
(Figure 5) said graphene ion barrier membrane 10 is applied on (or supports) the inner
side of the entrance window 2 and more in particular on the cathode 4.
1. An electron multiplying structure for use in a vacuum tube using electron multiplying,
the electron multiplying structure comprising
an input face intended to be oriented in a facing relationship with an entrance window
of the vacuum tube,
an output face intended to be oriented in a facing relationship with a detection surface
of the vacuum tube, as well as
an ion barrier membrane for shielding off stray ions, characterized in that, said ion barrier membrane is composed of at least one atomic layer containing graphene.
2. Electron multiplying structure according to claim 1, characterized in that, said ion barrier membrane is composed of multiple atomic layers containing graphene.
3. Electron multiplying structure according to claim 1 or 2, characterized in that, said at least one atomic layer solely contains graphene.
4. Electron multiplying structure according to anyone of the claims 1-3, characterized in that, said ion barrier membrane is placed at the input face of the electron multiplying
structure.
5. Electron multiplying structure according to anyone of the claims 1-4, characterized in that, said ion barrier membrane is placed at the output face of the electron multiplying
structure.
6. Electron multiplying structure according to anyone of the preceding claims, characterized in that, said electron multiplying structure is arranged to support the entrance window of
the vacuum tube.
7. Electron multiplying structure according to anyone of the claims 1-6, characterized in that, said electron multiplying structure is constructed as a channel plate, in particular
a microchannel plate.
8. Electron multiplying structure according to anyone of the claims 1-6, characterized in that, said electron multiplying structure is constructed as an array of secondary electron
emitting dynodes.
9. An vacuum tube using electron multiplying having a photocathode capable of releasing
electrons into said vacuum chamber when exposed to light, electric field means for
accelerating said released electrons from said photocathode towards an anode spaced
apart from said photocathode in a facing relationship, as well as an electron multiplying
structure according to one or more of the preceding claims disposed in said vacuum
chamber between said photocathode and said anode.
10. An vacuum tube using electron multiplying according to claim 9, characterized in that, said photocathode is composed from one or more materials contained in columns III
and/or V of the periodic table of elements.
11. An vacuum tube using electron multiplying according to claim 9 or 10, characterized in that, said vacuum tube is constructed as an image intensifier tube.
12. An vacuum tube using electron multiplying according to claim 9 or 10, characterized in that, said vacuum tube is constructed as a photo multiplier tube.
13. An vacuum tube using electron multiplying according to claim 9 or 10, characterized in that, said vacuum tube is constructed as a channeltron.
14. An vacuum tube using electron multiplying according to claim 9 or 10, characterized in that, said vacuum tube is constructed as a microchannel plate detector.
15. An ion barrier membrane as described in one or more of the preceeding claims.