[0001] The present invention relates in general to a fuel composition and in particular
to an aviation gasoline (Avgas).
[0002] International Patent Publication
WO 02/40620 relates to an aviation gasoline fuel composition possessing a high motor octane number
and which contains reduced amounts of tetraethyl lead compound. The Avgas composition
is said to preferably contain about 20 to about 80 vol % iso-octane, about 5 to about
18 vol % toluene, about 1 to about 20 vol % C
4 to C
5 paraffins, about 0 to about 1 ml/gallon tetraethyl lead (TEL) and the balance light
alkylate. The motor octane number is said to be preferably greater than or equal to
about 100. The fuel is said to be preferably suitable as a substitute for Grade 100LL
aviation fuel. This patent publication illustrates only compositions with 0.9 ml/gallon
tetraethyl lead.
[0003] There is a need for an aviation fuel which can be used in moderately powered engines
(such as presently use leaded aviation gasoline with a MON of at least 91) as well
as in high performance engines (such as presently use leaded aviation gasoline with
a MON of at least 99.5 MON) which have been modified to use lower octane number fuels.
[0004] Thus, according to the present invention there is provided an aviation gasoline composition
comprising at least one tri-methyl pentane hydrocarbon and at least one C
4 or C
5 alkane wherein the amount of the at least one tri-methyl pentane in said composition
is 10 to 90 vol %, the composition is substantially free of any lead compounds and
the composition has a motor octane number of at least 92 and less than 98.
[0005] The composition of the present invention solves the technical problem defined above
by the presence of at least one tri-methyl pentane compound in an amount of 10 - 90
vol. % in the composition which, in the substantial absence of lead compounds, provides
a fuel with a motor octane number of at least 92 and less than 98.
[0006] The composition of the present invention can provide the same performance in full
size spark ignition aviation engines as known leaded 91/96 or 91/98 aviation gasoline,
the higher MON value compensating for the absence of lead compounds such as tetraethyl
lead.
[0007] The motor octane number is defined according to ASTM D2700 standard, which is known
in the art.
[0008] The composition of the present invention preferably has a MON of at least 93 and
more preferably of at least 94.
[0009] By substantially free of lead compounds is meant that the amount of lead compounds
in the composition according to the present invention is not greater than 0.003g of
lead per litre. Lead compounds in particular which should be absent include tetraethyl
lead.
[0010] The at least one tri-methyl pentane preferably comprises 2,2,4-trimethylpentane (herein
referred to as iso-octane). Iso-octane may be prepared as described in
WO 02/40620, the contents of which are incorporated by reference. Iso-octane may be prepared
by the hydrogenation of di-isobutylene, which in turn may be prepared by the dimerisation
of isobutenes. Such dimerisation may be performed using converted MTBE production
facilities.
[0011] The at least one tri-methyl pentane may be provided as a substantially pure component
and/or as a component in one or more alkylate process streams.
[0012] The composition of the present invention comprises at least one tri-methyl pentane
(from whatever source) in an amount of 10 - 90 vol %, preferably 40 - 90 vol %, more
preferably 60 - 90 vol %.
[0013] The composition of the present invention may comprise at least 0.01 vol % C
4 alkane. The composition of the present invention may comprise less than 5 vol %,
preferably less than 2 vol % C
4 alkane. The composition of the present invention may comprise at least 10 vol % C
5 alkane. The composition of the present invention may comprise less than 40 vol %,
preferably less than 20 vol % C
5 alkane. 2-methyl butane is preferred over n-pentane.
[0014] The composition of the present invention may optionally comprise alkylate in an amount
of up to 90 vol %, for example up to 70 vol %. Preferably, the alkylate if present
in the composition of the present invention, has been distilled such that it has a
boiling point not greater than 170 °C. The alkylate component may comprise at least
one tri-methyl pentane.
[0015] The composition of the present invention may comprise isomerate and/or isopentane
(2-methyl butane) in a combined total amount of up to 40 vol %, preferably in an amount
of less than 20 vol %. Isopentane used in the composition of the present invention
may be provided as a substantially pure component and/or as a component in a C
5 refinery stream, for example from an isomerisation unit.
[0016] The composition of the present invention may optionally comprise hydrocrackate. If
present in the composition of the present invention, the amount of hydrocrackate is
preferably up to 40 vol %, more preferably up to 20 vol %.
[0017] Aromatics may optionally be present in the composition of the present invention in
an amount of up to 30 vol %, preferably up to 25 vol %. Toluene is optionally present
in the composition of the present invention in an amount of up to 30 vol %. Preferably,
the amount of toluene, if present in the composition of the present invention, is
less than 20 vol %, more preferably not greater than 10 vol %. Other aromatic compounds,
for example ethylbenzene and xylene, may be present in the composition of the present
invention in place of or in addition to toluene. Such aromatic compounds may be obtained
by distillation of a process stream from a catalytic reformer.
[0018] Naphtha may be present in the composition of the present invention. If present in
the composition of the present invention, the amount of naphtha is preferably not
greater than 30 vol %, and more preferably is less than 10 vol %.
[0019] Olefins are preferably not present in the composition of the present invention, but
their presence is not excluded.
[0020] The composition of the present invention may comprise a dye, or may be undyed. The
composition of the present invention may comprise one or more anti-oxidants such as
hindered phenols.
[0021] The composition of the present invention may comprise one or more lubricity improvers
such as acids, esters and/or amides. Biofuel may also be present in the composition
of the present invention. The composition of the present invention may comprise one
or more additives to reduce valve seat recession, such as phosphorus, potassium or
sodium based valve seat recession additives.
[0022] The composition of the present invention may independently have one or more of the
features listed in Table 1 below and preferably all of the features.
TABLE 1
Feature |
Range/value |
Vapour pressure |
38 to 49 kPa |
Distillation properties : |
|
10 % evaporation |
by 75 °C max |
40 % evaporation |
by 75 °C min |
50 % evaporation |
by 105 °C max |
90 % evaporation |
by 135 °C max |
Final boiling point |
< 170 °C |
Supercharge |
Not specified, or > 96 or > 98 ON |
Calorific value |
> 43.5 Mj/kg |
Freezing point |
Less than or equal to - 58 °C |
[0023] Preferably, the composition of the present invention meets the Def Stan 91-90 standard
and/or ASTM D910 standards with the provisos (i) that the MON value is at least 92
and less than 98 (ii) the supercharge is unspecified or at least 96 and (iii) the
composition is substantially free of any lead compounds.
[0024] The composition of the present invention may be made by blending together one or
more process streams selected from the group consisting of iso-octane, alkylate, isopentane,
isomerate, hydrocrackate, aromatics and naphtha streams. Preferably, the composition
of the present invention is made by adding to one or more of these process streams
or a blend thereof, one or more aviation gasoline additives selected from the group
consisting of dye, anti-oxidants, lubricity improvers and additives to reduce valve
seat recession.
[0025] The composition of the present invention may further comprise at least one fuel system
icing inhibitor. Such icing inhibitors are preferably added at the point of use of
the composition. Suitable fuel system icing inhibitors comprise alcohols or ethers
for example diethylene glycol monomethyl ether and isopropanol. The icing inhibitor
may be used in an amount of up to 5 % by volume in the fuel composition.
[0026] The composition of the present invention may be used in spark ignition aviation engines.
The aviation engines may be capable of operating at 30 metres or more above sea level.
The aviation engines may be used to propel heavier than air craft such as light aircraft.
The aviation engines may be used to propel lighter than air craft such as airships.
Thus, according to a further embodiment of the present invention there is provided
a method of operating a spark ignition aviation engine which comprises providing said
engine with an aviation gasoline composition comprising at least one tri-methyl pentane
hydrocarbon and at least one C
4 or C
5 alkane wherein the amount of the at least one tri-methyl pentane in said composition
is 10 to 90 vol %, the composition is substantially free of any lead compounds and
the composition has a motor octane number of at least 92 and less than 98.
[0027] The present invention will now be illustrated by reference only to the following
examples. Compositions were prepared by blending amounts of components as listed in
Table 2 below.
TABLE 2
Component |
Example 1 (W02/421) |
Example 2 (W02/579) |
|
Amount |
Amount |
Alkylate, initial boiling point to 170 °C fraction * |
24 vol % |
24 vol % |
Naphtha |
2.4 vol % |
- |
Toluene |
8 vol % |
8 vol % |
Isopentane |
16 vol % |
16 vol % |
Iso-octane |
49.6 vol % |
52 vol % |
* the alkylate fraction comprised approximately 30 vol % iso-octane such that the
total amount of iso-octane in the composition was about 60 vol %. |
[0028] The properties of the compositions were determined and these are listed in Table
3 below.
TABLE 3
Property |
Units |
W02/421 |
W02/579 |
MON |
|
93.2 |
95.0 |
Supercharge |
|
99 |
99 |
Lead |
gPb/litre |
0.00 |
0.00 |
D 1319 FIA Aromatics |
% v/v |
6.5 |
7.4 |
D 1319 FIA Olefins |
% v/v |
0.6 |
0 |
D1319 FIA Saturates |
% v/v |
92.9 |
92.6 |
D3338 Specific Energy |
MJ/kg |
44.086 |
44.071 |
D381 Existent Gum (Air) |
Mg/100ml |
1 |
<1 |
IP365 Composite Density |
kg/m3 |
700.9 |
698.8 |
D86 Initial Boiling Point |
°C |
39.7 |
32.5 |
D86 Final Boiling Point |
°C |
123.4 |
119.5 |
D86 Loss |
% v/v |
0.6 |
0.5 |
D86 Recovery |
% v/v |
98.3 |
99.0 |
D86 Residue |
% v/v |
1.1 |
0.5 |
D86 10% Evaporated |
°C |
67.1 |
69.5 |
D86 40% Evaporated |
°C |
96.2 |
96.0 |
D86 50% Evaporated |
°C |
99.3 |
98.5 |
D86 90% Evaporated |
°C |
104.0 |
101.0 |
D86 Sum of 10% and 50% Evaporated temps |
°C |
166.4 |
168.0 |
D873 16Hr Accelerated Gum |
Mg/100ml |
3 |
1 |
D873 Lead Precipitate |
Mg/100ml |
0 |
0 |
IP 16 Freeze point |
°C |
<-80 |
<-60 |
IP154 Copper Corrosion 2Hrs @ 100 °C |
- |
1a |
1 |
IP289 Water Reaction Interface Rating |
- |
1 |
1b |
IP289 Water Reaction Volume change |
- |
0 |
0 |
Vapour Pressure |
KPa |
45.1 |
41.1 |
Sulphur (D2622mod) |
% w/w |
0.0011 |
0.0010 |
Anti-oxidant |
mg/L |
12 |
12 |
[0029] The properties of the compositions show that these are suitable for use as aviation
gasolines, in particular, the compositions of the present invention meet the Def Stan
91-90 standard and/or ASTM D910 standards with the provisos (i) that the MON value
is at least 92 and less than 98 (ii) the supercharge is unspecified or at least 96
and (iii) the composition is substantially free of any lead compounds.
1. An aviation gasoline composition comprising at least one tri-methyl pentane hydrocarbon
and at least one C4 or C5 alkane wherein the amount of the at least one tri-methyl pentane in said composition
is 10 to 90 vol. % and the composition has a motor octane number of at least 92 and
less than 98 in which: the amount of lead compounds in the composition is not greater
than 0.003g of lead per litre; the composition comprises at least 10 vol.% and less
than 40 vol.% C5 alkane; and the composition comprises aromatics in an amount of up to 30 vol.%.
2. A composition as claimed in claim 1 in which the composition has a MON of at least
93.
3. A composition as claimed in any one of the preceding claims in which the tri-methyl
pentane is provided as a component in one or more alkylate process streams
4. A composition as claimed in any one of the preceding claims in which the amount of
the at least one tri-methyl pentane in said composition is 40 - 90 vol. %.
5. A composition as claimed in any one of the preceding claims in which the amount of
the at least one tri-methyl pentane in said composition is 60 - 90 vol. %.
6. A composition as claimed in any one of the preceding claims in which the composition
comprises alkylate in an amount of up to 90 vol. %.
7. A composition as claimed in claim 6 in which the alkylate has been distilled such
that it has a boiling point not greater than 170 °C.
8. A composition as claimed in any one of the preceding claims in which the composition
comprises isomerate and/or isopentane (2-methyl butane) in a combined total amount
of up to 40 vol. %.
9. A composition as claimed in any one of the preceding claims in which the composition
comprises hydrocrackate in an amount of up to 40 vol. %.
10. A composition as claimed in any one of the preceding claims in which the composition
comprises aromatics in an amount of up to 25 vol. %.
11. A composition as claimed in any one of the preceding claims in which the composition
comprises toluene in an amount of up to 30 vol. %.
12. A composition as claimed in any one of the preceding claims in which the composition
meets the Def Stan 91-90 standard with the provisos (i) that the MON value is at least
92 and less than 98 (ii) the supercharge is unspecified or at least 96 and (iii) the
composition is substantially free of any lead compounds.
13. A composition as claimed in any one of the preceding claims in which the composition
meets the ASTM D910 standard with the provisos (i) that the MON value is at least
92 and less than 98 (ii) the supercharge is unspecified or at least 96 and (iii) the
composition is substantially free of any lead compounds.
14. A method of making an aviation gasoline composition which comprises blending together
one or more process streams selected from the group consisting of iso-octane, alkylate,
isopentane, isomerate, hydrocrackate, aromatics and naphtha streams to make a composition
as claimed in any one of claims 1 to 13.
15. A method as claimed in claim 14 which further comprises adding to one or more of said
process streams or a blend thereof, one or more aviation gasoline additives selected
from the group consisting of dye, anti-oxidants, lubricity improvers and additives
to reduce valve seat recession.
16. A method of operating a spark ignition aviation engine which comprises providing said
engine with an aviation gasoline composition as claimed in any one of claims 1 to
13 or made by a method as claimed in claim 14 or claim 15.