[Technical Field]
[0001] The present invention relates to a method for manufacturing a tapered plate (also
called a tapered steel plate or a LP steel plate (Longitudinally Profiled Steel Plate))
whose plate thickness continuously changes in the longitudinal direction which can
be preferably used for shipbuilding or the architecture, for example, and relates
to a method for manufacturing a tapered plate having a tensile strength of 570 MPa
or more and a difference in thickness between a thicker portion and a thinner portion
(a difference of steel plate thickness) in the longitudinal direction of 10 mm or
more which has only a small difference in strength throughout the steel plate and
can be subjected to high-heat input welding with a welding heat input of more than
300 kJ/cm.
[Background Art]
[0002] Generally, a thick steel plate has a shape which is uniform in both the width and
longitudinal directions. However, in the case where the plate thickness continuously
changes in the longitudinal direction, there are cases where there is a great effect
of decreasing material weight and welding man-hours. This kind of thick steel plate
is called a tapered plate, a tapered steel plate, a LP steel plate or the like, and
there have been many proposals regarding the method for manufacturing a tapered plate
such as those disclose in Patent Literature 1, Patent Literature 2 and Patent Literature
3. These proposals are intended to show how to manufacture a tapered plate with high
dimensional accuracy. However, unless the material properties and material uniformity
of a steel plate are satisfactory in addition to dimensional accuracy, the steel plate
cannot be used in practice.
[0003] Nowadays, quality demands for thick steel plates are becoming stronger, and, in particular,
demands for increases in tensile strength and weldability are becoming stronger. In
order to meet these demands, a TMCP (Thermo-Mechanical Control Process) such as controlled
rolling and controlled cooling is adopted. In this method, heavy reduction in a no-recrystallization
temperature range in austenite or an (austenite + ferrite) dual phase temperature
range and subsequent transformation from austenite to ferrite (ferrite transformation)
are utilized in order to decrease a ferrite grain size, and, further, cooling is performed
as needed in order to further increase strength and toughness.
[0004] However, in the case where this method is used to manufacture a tapered plate, since
temperature control is very difficult, there is large variation of material properties.
[0005] In particular, in the case of controlled rolling in which heavy reduction is performed
in a low temperature range, such as a rolling in a no-recrystallization temperature
range in austenite or a rolling in a dual phase (austenite + ferrite) temperature
range, there is a remaining problem in that, since a plate thickness changes in the
longitudinal direction as is the case with a tapered plate, a difference in the steel
plate temperature between the thinner portion and the thicker portion becomes excessively
large, which results in a large difference in strength. There have been some proposals
for manufacturing a tapered plate having uniform material properties by reducing such
inhomogeneity of material.
[0006] For example, Patent Literature 4 discloses a method for cooling a tapered plate,
in order to achieve uniform material properties, the method including measuring a
temperature distribution in the longitudinal direction before cooling is performed,
calculating optimum cooling conditions at respective positions on the basis of the
measured temperature distribution and adjusting conveyance speed in cooling in accordance
with a plate thickness. Patent Literature 5 discloses a method for cooling a tapered
plate, the method including starting cooling the thinner portion and the thicker portion
of the steel plate at the same time and changing the time at which the portions leave
a cooling apparatus in accordance with their thicknesses, or the method including
starting cooling sequentially in order of distance in the longitudinal direction of
the steel plate and stopping cooling at the same time. Both of the proposals are intended
to decrease the variation of material properties in a steel plate when accelerated
cooling is performed.
[0007] On the other hand, an example of approaches to solve the problem described above,
which controls a chemical composition of the steel plate, is described in Patent Literature
6. In this technique, it is disclosed that the scatter of strength can be decreased
by increasing Nb content up to 0.015% to 0.06%.
[0008] In addition, Patent Literature 7 discloses that the scatter of strength can be decreased
by controlling the value of Hv
20-50 (difference in Hv hardness between steel plates respectively having plate thicknesses
of 20 mm and 50 mm after the steel plates have been cooled down to room temperature
at a cooling rate equivalent to that of air cooling in a temperature range from 800°C
to 500°C), which is expressed by the equation Hv
20-50 = -110 + 460C + 44Si + 39Mn - 31Cu - 9Ni + 11Cr + 22Mo + 180V + 9600B -23000MoxB,
to be 15 or less.
[0009] However, in the case of steel materials capable of being subjected to high-heat input
welding, the needs for which has been increasing recently, since there are various
limitations regarding alloy design in order to achieve toughness in a weld zone, it
is not easy to determine alloy design from the viewpoint of decreasing the scatter
of strength of a tapered plate, which results there being a problem in that there
is a markedly large scatter of strength due to the variation of plate thickness or
finishing temperature, in particular in the case of B containing steel materials which
are used for high-heat input welding.
[Citation List]
[Patent Literature]
[0010]
[PTL 1] Japanese Examined Patent Application Publication No. 50-36826
[PTL 2] Japanese Examined Patent Application Publication No. 60-124
[PTL 3] Japanese Examined Patent Application Publication No. 5-49361
[PTL 4] Japanese Unexamined Patent Application Publication No. 62-166013
[PTL 5] Japanese Unexamined Patent Application Publication No. 7-68309
[PTL 6] Japanese Patent No. 3180944
[PTL 7] Japanese Patent No. 3972553
[Summary of Invention]
[Technical Problem]
[0011] An object of the present invention is, by advantageously solving the problems described
above, to provide a method for manufacturing a tapered plate having a difference in
thickness (taper amount) between a thicker portion and a thinner portion in the longitudinal
direction of 10 mm or more, which has a tensile strength of 570 MPa or more and a
small scatter of strength, and which is excellent in terms of toughness in a weld
zone formed by performing high-heat input welding with a heat input of more than 300
kJ/cm.
[Solution to Problem]
[0012] The present inventors, in order to solve the problems described above, conducted
investigations regarding the influence of the contents of Ti and N on a difference
in strength between a thicker portion and a thinner portion of B containing tapered
plates having various contents of Ti and N, and found that, in the case where the
contents of Ti and N satisfy the relationship 0 ≤ N - Ti/3.42 ≤ 0.0025, since an appropriate
amount of solid solute B is stably achieved, there is a decrease in difference in
strength between a thicker portion and a thinner portion.
[0013] The present invention has been completed on the basis of the knowledge described
above and further investigations, and the present invention is as follows.
- 1. A method for manufacturing a tapered plate having a tensile strength of 570 MPa
or more and a difference in thickness between a thicker portion and a thinner portion
of 10 mm or more, the method including heating to a temperature of 1000°C or higher
and 1200°C or lower, a steel slab having a chemical composition containing, by mass%,
C: 0.03% or more and 0.12% or less
Si: 0.03% or more and 0.5% or less
Mn: 0.8% or more and 2.2% or less
P: 0.015% or less
S: 0.0005% or more and 0.0050% or less
Al: 0.005% or more and 0.1% or less
Nb: 0.003% or more and 0.014% or less
Ti: 0.003% or more and 0.02% or less
B: 0.0003% or more and 0.0025% or less
N: 0.0030% or more and 0.0070% or less
Ca: 0.0005% or more and 0.0050% or less, and
the balance being Fe and inevitable impurities, in which expression (1) is satisfied,
performing hot rolling on the heated slab in which plate thickness changes in the
longitudinal direction so as to form a tapered shape at a finishing rolling temperature
of 900°C or lower and equal to or higher than the Ar3 point and then performing accelerated cooling on the hot-rolled steel plate down
to a temperature of 500°C or lower:

where N and Ti respectively represent the contents (mass%) of N and Ti.
- 2. The method for manufacturing a tapered plate having a tensile strength of 570 MPa
or more and a difference in thickness between a thicker portion and a thinner portion
of 10 mm or more according to item 1, the steel slab having the chemical composition
further containing, by mass%, one, two or more selected from among
Cu: 0.05% or more and 1.0% or less
Ni: 0.05% or more and 1.0% or less
Cr: 0.05% or more and 0.5% or less
Mo: 0.05% or more and 0.5% or less, and
V: 0.02% or more and 0.1% or less.
- 3. The method for manufacturing a tapered plate having a tensile strength of 570 MPa
or more and a difference in thickness between a thicker portion and a thinner portion
of 10 mm or more according to item 1 or 2, the steel slab having the chemical composition
further containing, by mass%, one, two or more selected from among
Mg: 0.0005% or more and 0.005% or less
Zr: 0.003% or more and 0.02% or less, and
REM: 0.003% or more and 0.02% or less.
- 4. The method for manufacturing a tapered plate having a tensile strength of 570 MPa
or more and a difference in thickness between a thicker portion and a thinner portion
of 10 mm or more according to any one of items 1 to 3, the steel slab having the chemical
composition further containing, by mass%,
O: 0.0030% or less,
in which the contents of Ca, O and S satisfy expression (2) below:

where ACR = (Ca - (0.18 + 130×Ca)×O)/1.25/S, and where Ca, O and S respectively represent
the contents (mass%) of Ca, O and S.
[Advantageous Effects of Invention]
[0014] According to the present invention, it is possible to manufacture a tapered plate
having a difference in thickness (taper amount) between a thicker portion and a thinner
portion of 10 mm or more, which has a tensile strength of 570 MPa or more and small
difference in strength between a thicker portion and a thinner portion, and which
can be subjected to high-heat input welding such as submerged arc welding, electrogas
arc welding and electroslag welding, which results in a great advantage in industry.
[Description of Embodiments]
[0015] In the present invention, a chemical composition and manufacturing conditions are
specified. In the description, % represents mass%.
[Chemical Composition]
C: 0.03% or more and 0.12% or less
[0016] C is added in an amount of 0.03% or more in order to achieve strength required for
structural steel. On the other hand, in the case where the C content is more than
0.12%, since there is a decrease in the toughness of a welded heat affected zone,
the C content is set to be 0.03% or more and 0.12% or less, preferably 0.04% to 0.09%.
Si: 0.03% or more and 0.5% or less
[0017] Si is added in an amount of 0.03% or more for the purpose of deoxidation and achieving
strength. In the case where the Si content is more than 0.5%, since there is a decrease
in toughness due to island martensite (M-A constituent) formed in a welded heat affected
zone in the case where high-heat input welding is performed, the Si content is set
to be 0.5% or less, preferably 0.4% or less.
Mn: 0.8% or more and 2.2% or less
[0018] Mn is added in an amount of 0.8% or more in order to achieve strength of a base metal.
On the other hand, in the case where the Mn content is more than 2.2%, since there
is a significant decrease in the toughness of a heat affected zone, the Mn content
is set to be 0.8% or more and 2.2% or less, preferably 1.2% to 2.0%.
P: 0.015% or less
[0019] P is an inevitable impurity in the present invention. In the case where the P content
is more than 0.015%, since there is a decrease in toughness, in particular in a CTOD
(Crack Tip Opening Displacement) property, due to formation of island martensite (M-A
constituent) in a heat affected zone formed as a result of performing high-heat input
welding, the P content is set to be 0.015% or less, preferably 0.012% or less.
S: 0.0005% or more and 0.0050% or less
[0020] S content is 0.0005% or more in order to form CaS and MnS. On the other hand, in
the case where the S content is more than 0.0050%, since there is a decrease in the
toughness of a base metal, the S content is set to be 0.0005% or more and 0.0050 or
less.
Al: 0.005% or more and 0.1% or less
[0021] Al content is 0.005% or more for the purpose of deoxidation of steel. On the other
hand, in the case where the Al content is more than 0.1%, since there is a decrease
in the toughness of a base metal and there also is a decrease in the toughness of
a weld metal, the Al content is set to be 0.005% or more and 0.1% or less, preferably
0.01% to 0.06%.
Nb: 0.003% or more and 0.014% or less
[0022] Although Nb is effective for achieving strength and toughness of a base metal and
strength of a weld joint and it is necessary that the Nb content be 0.003% or more
in order to realize these effects, since there is a decrease in the toughness of a
welded heat affected zone formed as a result of performing high-heat input welding
in the case where the Nb content is more than 0.014%, the Nb content is set to be
0.003% or more and 0.014% or less, preferably 0.005% to 0.013%.
Ti: 0.003% or more and 0.02% or less
[0023] Ti is added in an amount of 0.003% or more, since Ti increases toughness of a base
metal by precipitating in a form of TiN at a time of solidification so as to prevent
an increase in an austenite grain size in a welded heat affected zone and by providing
the nuclei of ferrite transformation so as to precipitate ferrite grains. On the other
hand, in the case where the Ti content is more than 0.02%, since there is an increase
in TiN grain size, which results in a decrease in toughness, the Ti content is set
to be 0.003% or more and 0.02% or less, preferably 0.005% to 0.018%.
B: 0.0003% or more and 0.0025% or less
[0024] Since, when a steel plate is manufactured, B increases the strength of a base metal
by forming solid solute B so as to increase hardenability, and when high-heat input
welding is performed, B increases the toughness of a base metal by forming BN in a
welded heat affected zone so as to decrease the amount of solid solute N and by providing
nuclei of ferrite transformation so as to form ferrite grains, B is added in an amount
of 0.0003% or more.
[0025] On the other hand, in the case where the B content is more than 0.0025%, since there
is a decrease in toughness due to an excessive increase in hardenability, the B content
is set to be 0.0003% or more and 0.0025% or less, preferably 0.0005% to 0.0022%.
N: 0.0030% or more and 0.0070% or less
[0026] Since N forms TiN which is effective for increasing toughness, the N content is set
to be 0.0030% or more. On the other hand, in the case where the N content is more
than 0.0070%, since there is a case where it is impossible to achieve a sufficient
amount of solid solute B which increases hardenability when a steel plate is manufactured,
and since there is a decrease in toughness due to an increase in the amount of solid
solute N in a weld metal as a result of TiN in the vicinity of a weld bond being dissolved
when high-heat input welding is performed, the N content is set to be 0.0030% or more
and 0.0070% or less.
0 ≤ N - Ti/3.42 ≤ 0.0025
[0027] In the present invention, since a steel plate is required to have a tensile strength
of 570 MPa or more and a small scatter of strength, and be excellent in terms of toughness
in a weld zone formed by performing high-heat input welding with a heat input of more
than 300 kJ/cm, this formula is specified in the chemical composition described above
in order to meet this requirement. In the case where the relationship between the
contents of Ti and N is expressed by N - Ti/3.42 > 0.0025, since it is impossible
to stably achieve an appropriate amount of solid solute B, there is a large scatter
of strength with respect to changes in plate thickness and rolling conditions. On
the other hand, in the case where the relationship is expressed by N-Ti/3.42 < 0,
there is a significant decrease in the toughness of a welded heat affected zone when
high-heat input welding is performed. Therefore, the relationship 0 ≤ N - Ti/3.42
≤ 0.0025 shall be satisfied.
Ca: 0.0005% or more and 0.0050% or less
[0028] Ca increases the toughness of a welded heat affected zone when high-heat input welding
is performed, since there is an increase in frequency of nuclei formation of ferrite
grains as a result of formation of MnS, TiN and BN on CaS. The Ca content is set to
be 0.0005% or more in order to realize this effect. On the other hand, in the case
where the Ca content is more than 0.0050%, since the effect becomes saturated, the
Ca content is set to be 0.0005% or more and 0.0050% or less, preferably 0.0005% to
0.0030%, more preferably 0.0007% to 0.0030%.
[0029] Although the chemical composition described above is the base chemical composition
of the present invention and a sufficient effect can be realized with this chemical
composition, in order to further improve the properties, one, two or more of Cu, Ni,
Cr, Mo, V, Mg, Zr and REM may be added.
Cu: 0.05% or more and 1.0% or less
[0030] Cu is effective for increasing the strength of a base metal, and it is preferable
that the Cu content be 0.05% or more in order to realize this effect, but, in the
case where the Cu content is more than 1.0%, there is deterioration of the surface
quality of a steel plate due to occurrence of hot shortness. Therefore, in the case
where Cu is added, it is preferable that the Cu content be 1.0% or less, more preferably
0.1% to 0.8%.
Ni: 0.05% or more and 1.0% or less
[0031] Since Ni increases the strength of a base metal while maintaining high toughness
of the base metal, it is preferable that the Ni content be 0.05% or more in order
to realize this effect. On the other hand, in the case where the Ni content is more
than 1.0%, since the effect becomes saturated, in the case where Ni is added, it is
preferable that the Ni content be 0.05% or more and 1.0% or less, more preferably
0.1% to 0.9%.
Cr: 0.05% or more and 0.5% or less
[0032] Cr is effective for increasing the strength of a base metal and it is preferable
that the Cr content be 0.05% or more in order to realize this effect, but, in the
case where the Cr content is excessively large, there is a decrease in toughness.
Therefore, in the case where Cr is added, it is preferable that the Cr content be
0.5% or less, more preferably 0.1% to 0.4%.
Mo: 0.05% or more and 0.5% or less
[0033] Mo is effective for increasing the strength of a base metal and it is preferable
that the Mo content be 0.05% or more in order to realize this effect, but there is
a decrease in toughness in the case where the Mo content is excessively large. Therefore,
in the case where Mo is added, it is preferable that the Mo content be 0.5% or less,
more preferably 0.07% to 0.4%.
V: 0.02% or more and 0.1% or less
[0034] V is effective for increasing the strength of a base metal and it is preferable that
the V content be 0.02% or more in order to realize this effect, but there is a decrease
in toughness in the case where the V content is more than 0.1%. Therefore, in the
case where V is added, it is preferable that the V content be 0.1% or less, more preferably
0.04% to 0.08%.
Mg: 0.0005% or more and 0.005% or less
[0035] Mg is a chemical element which is effective for improving toughness as a result of
dispersion of oxides. It is preferable that the Mg content be at least 0.0005% or
more in order to realize this effect, but the effect becomes saturated in the case
where the Mg content is more than 0.005%. Therefore, in the case where Mg is added,
it is preferable that the Mg content be 0.005% or less.
Zr: 0.003% or more and 0.02% or less
[0036] Zr is a chemical element which is effective for improving toughness as a result of
dispersion of oxides. It is preferable that the Zr content be at least 0.003% or more
in order to realize this effect, but the effect becomes saturated in the case where
the Zr content is more than 0.02%. Therefore, in the case where Zr is added, it is
preferable that the Zr content be 0.02% or less, more preferably 0.004% to 0.018%.
REM: 0.003% or more and 0.02% or less
[0037] REM is a chemical element which is effective for improving toughness as a result
of the dispersion of oxides. It is preferable that the REM content be at least 0.003%
or more in order to realize this effect, but the effect becomes saturated in the case
where the REM content is more than 0.02%. Therefore, in the case where REM is added,
it is preferable that the REM content be 0.02% or less, more preferably 0.004% to
0.018%.
O: 0.0030% or less
[0038] O is contained as an inevitable impurity and decreases cleanliness as a result of
being present in the form of oxides in steel. Therefore, it is preferable that the
O content be as small as possible in the present invention. In the case where the
O content is more than 0.0030%, since there is an increase in the size of CaO containing
inclusions, there is a negative effect on toughness. Furthermore, in order to crystallize
Ca in the form of CaS in the present invention, since O has strong affinity for Ca,
it is preferable that the O content in molten steel be decreased to 0.0030% or less
by performing intensive degassing or by adding a deoxidation agent before Ca is added.

[0039] Here, ACR = (Ca - (0.18 + 130×Ca)×O)/1.25/S, where Ca, O and S respectively represent
the contents (mass%) of Ca, O and S.
[0040] In order to finely disperse the nuclei of ferrite transformation which are not dissolved
even at a high temperature when high-heat input welding is performed and in order
to realize an increase in toughness by forming a fine (ferrite + pearlite) structure
in a welded heat affected zone, it is necessary that the contents of Ca and S satisfy
the relationship 0.3 ≤ ACR ≤ 0.8.
[0041] By controlling ACR value to be 0.3 or more and 0.8 or less, since MnS, which is effective
as a nucleus of ferrite formation, is precipitated on CaS and finely dispersed, it
is possible to realize an increase in toughness by forming a fine (ferrite + pearlite)
structure in a welded heat affected zone when high-heat input welding is performed.
[0042] In the case where ACR value is less than 0.3, since CaS is not crystallized, S is
precipitated only in the form of MnS. Since MnS is elongated by performing rolling
when a steel plate is manufactured, a decrease in the toughness of a base metal is
caused. In addition, since MnS is dissolved in a welded heat affected zone, which
is the most important zone in the present invention, fine dispersion cannot be realized.
[0043] On the other hand, in the case where ACR value is more than 0.8, since most of S
is fixed by Ca, MnS, which is effective as a nucleus of ferrite formation, is not
precipitated on CaS, which results in sufficient effect not being realized.
[Manufacturing condition]
[0044] In the present invention, since an appropriate amount of solid solution B can be
stably achieved by a chemical composition being controlled as described above, it
is possible to decrease the scatter of strength caused by changes in plate thickness
and rolling conditions. Therefore, while variation of strength of a steel plate is
inevitable as a plate thickness changes from the thicker portion to the thinner portion
in the case where accelerated cooling is performed in order to increase the strength
of a conventional tapered plate, according to the present invention, it is possible
to obtain a high strength tapered plate having a small difference in strength between
a thicker portion and a thinner portion in the case where accelerated cooling is performed.
[0045] A steel slab which is used as a raw material of the tapered plate according to the
present invention may be manufactured by smelting steel having the chemical composition
described above using an ordinary refining process such as a steel converter, an electric
furnace or a vacuum melting furnace and then by casting the smelted steel using an
ordinary method such as a continuous casting method or an ingot casting-slabbing rolling
method, and there is no particular limitations on what methods are used.
[0046] In the present invention, a slab heating temperature, hot rolling conditions and
cooling conditions are specified as described hereafter.
Slab heating temperature: 1000°C or higher and 1200°C or lower
[0047] In the case where the slab heating temperature is lower than 1000°C, added components
do not sufficiently form solid solutions. On the other hand, in the case where the
slab heating temperature is higher than 1200°C, there is an increase in austenite
grain size and the grain size is not decreased even by subsequently performing rolling,
which results in a decrease in toughness. Therefore, the slab heating temperature
is set to the range of 1000°C or higher and 1200°C or lower, preferably to the range
of 1030°C to 1180°C.
Hot rolling conditions
[0048] After a steel slab has been heated, hot rolling is performed. In hot rolling, a taper
in which a plate thickness changes in the longitudinal direction is provided. Change
in plate thickness in the longitudinal direction of a tapered plate is achieved by
changing a roll gap while hot rolling in a predetermined pass after starting rolling
of the steel plate.
[0049] In the present invention, there is no particular limitation regarding rolling reduction
(also called draft) in each pass. The finishing rolling temperature of hot rolling
is set to be 900°C or lower and equal to or higher than the Ar
3 point in terms of the surface temperature of a steel plate. In the case where the
finishing rolling temperature is lower than the Ar
3 point, it is impossible to achieve the specified strength, and in the case where
the finishing rolling temperature is higher than 900°C, there is a decrease in toughness.
Therefore, the finishing rolling temperature is set to be 900°C or lower and equal
to or higher than the Ar
3 point, preferably to the range of (Ar
3 point + 10°C) to 880°C.
Cooling conditions
[0050] After hot rolling has been finished, accelerated cooling is performed. In the case
where a cooling stop temperature is higher than 500°C, since it is impossible to obtain
a steel plate having a tensile strength of 570 MPa or more, accelerated cooling is
performed until the surface temperature of a steel plate decreases to a temperature
of 500°C or lower, preferably to the range of 490°C or lower.
[0051] Incidentally, the surface temperature of a steel plate, which is used to specify
the hot rolling conditions and cooling conditions, can be determined using, for example,
a radiation thermometer.
[0052] In the present invention, under conditions regarding combination of the chemical
composition and the manufacturing conditions described above, since an appropriate
amount of solid solute B can be stably achieved so as to realize effects of improving
the hardenability and the toughness of a welded heat affected zone formed as a result
of performing high-heat input welding, a tapered plate having a tensile strength of
570 MPa or more and excellent toughness of a welded heat-affected zone formed as a
result of performing high-heat input welding despite that a difference in thickness
(taper amount) between a thicker portion and a thinner portion of the tapered plate
is 10 mm or more in the steel plate.
[EXAMPLE 1]
[0053] By performing hot rolling on the steel slabs having the chemical compositions given
in Table 1 under the conditions given in Table 2, tapered plates having a thickness
of the thicker portion of 60 mm, a thickness of the thinner portion of 50 mm and a
taper amount (difference in thickness between the thicker portion and the thinner
portion) of 10 mm, were manufactured.
[0054] Specimens described below were respectively cut out from a depth of 1/4 of the plate
thickness of a thicker portion and a thinner portion of the tapered plate. Round bar
type tensile specimens having a parallel part of 14φ × 85 mm and a gauge length of
70 mm were cut out in a direction perpendicular to the rolling direction, and 2 mm
V notched Charpy specimens were cut out in a direction parallel to the rolling direction.
The absorbed energy at-40°C and strength of a base metal were evaluated. The absorbed
energy at -40°C was defined by an average value for three specimens.
[0055] Moreover, 2 mm V notched Charpy test was performed in order to evaluate the toughness
of a welded heat affected zone (hereinafter also referred to as HAZ), specifically,
the toughness of a simulated HAZ. Prepared were test pieces having a width of 80 mm,
a length of 80 mm and a thickness of 15 mm that were cut out from these steel plates
and then subjected to a weld thermal cycle. This weld thermal cycle includes a cooling
step that decreases the temperature of the test pieces, which have been heated to
1450°C, from 800°C to 500°C in 270 seconds (This cycle corresponds to a thermal cycle
in which a welded heat affected zone undergoes when a steel plate having a plate thickness
of 55 mm is subjected to electrogas arc welding with a heat input of 400 kJ/cm).
[0056] The mechanical properties and toughness after a weld thermal cycle had been performed
of the thicker portion and thinner portion of the tapered plates are given in Table
2. In the case of all of the examples of the present invention No. 1 through No. 8,
the conditions that YS: 460 MPa or more, TS: 570 MPa or more and absorbed energy at
-40°C: 300 J or more (an average value for 3 specimens) were satisfied. Regarding
a difference in strength between a thicker portion and a thinner portion, a difference
in TS was less than 20 MPa and a difference in YS was less than 30 MPa, which means
the both differences were small. Moreover, vTrs was -40°C or lower, which means these
examples had excellent toughness of a simulated HAZ.
[0057] On the other hand, in the case of No. 11 and No. 14 where N - Ti/3.42 was more than
0.0025, a difference in strength between a thicker portion and a thinner portion was
large. In addition, in the case where a condition regarding appropriate chemical composition
or manufacturing conditions was not satisfied, one or more of the conditions that
YS: 460 MPa or more, TS: 570 MPa or more, absorbed energy: 300 J or more and vTrs
for the toughness of a simulated HAZ: -40°C or lower were unsatisfied.
[EXAMPLE 2]
[0058] By performing hot rolling on the steel slabs having the chemical compositions given
in Table 3 under the conditions given in Table 4, tapered plates having a thickness
of the thicker portion of 60 mm, a thickness of the thinner portion of 50 mm and a
taper amount (difference in thickness between the thicker portion and the thinner
portion) of 10 mm, were manufactured.
[0059] Specimens described below were respectively cut out from a depth of 1/4 of the plate
thickness of a thicker portion and a thinner portion of the tapered plate. Round bar
type tensile specimens having a parallel part of 14φ × 85 mm and a gauge length of
70 mm were cut out in a direction perpendicular to the rolling direction, and 2 mm
V notched Charpy specimens were cut out in a direction parallel to the rolling direction.
The absorbed energy at-40°C and strength of a base metal were evaluated. The absorbed
energy at -40°C was defined by an average value of three specimens.
[0060] Moreover, 2 mm V notched Charpy test was performed in order to evaluate the toughness
of a welded heat affected zone (hereinafter also referred to as HAZ), specifically,
the toughness of a simulated HAZ. Prepared were test pieces having a width of 80 mm,
a length of 80 mm and a thickness of 15 mm that were cut out from these steel plates
and then subjected to a weld thermal cycle. This weld thermal cycle includes a cooling
step that decreases the temperature of the test pieces, which have been heated to
1450°C, from 800°C to 500°C in 270 seconds (This cycle corresponds to a thermal cycle
in which a welded heat affected zone undergoes when a steel plate having a plate thickness
of 55 mm is subjected to electrogas arc welding with a heat input of 400 kJ/cm).
[0061] The mechanical properties and toughness after a weld thermal cycle had been performed
of a thicker portion and a thinner portion of the tapered plates are given in Table
4. In the case of both of No. 21 and No. 22 where the specification of ACR was satisfied,
the conditions that YS: 460 MPa or more, TS: 570 MPa or more and absorbed energy at
-40°C: 300 J or more (an average value for 3 specimens) were satisfied. Regarding
a difference in strength between a thicker portion and a thinner portion, a difference
in TS was less than 20 MPa and a difference in YS was less than 30 MPa, which means
the both differences were small. Moreover, vTrs was -65°C or lower, which means these
examples had excellent toughness of a simulated HAZ.
[Table 1-1]
| Table 1-1 |
(mass%) |
| Steel No. |
C |
Si |
Mn |
P |
S |
Al |
Cu |
Ni |
Cr |
Mo |
v |
Nb |
Ti |
Ca |
Classification |
| 1 |
0.055 |
0.06 |
2.05 |
0.005 |
0.0022 |
0.048 |
- |
- |
- |
- |
- |
0.013 |
0.017 |
0.0022 |
Example |
| 2 |
0.100 |
0.25 |
1.53 |
0.011 |
0.0019 |
0.032 |
- |
- |
- |
- |
- |
0.012 |
0.013 |
0.0025 |
Example |
| 3 |
0.058 |
0.07 |
1.55 |
0.006 |
0.0018 |
0.053 |
0.33 |
0.77 |
- |
- |
- |
0.014 |
0.014 |
0.0018 |
Example |
| 4 |
0.051 |
0.17 |
1.82 |
0.004 |
0.0019 |
0.036 |
- |
- |
0.12 |
- |
- |
0.010 |
0.013 |
0.0018 |
Example |
| 5 |
0.049 |
0.10 |
1.98 |
0.005 |
0.0021 |
0.055 |
- |
- |
0.20 |
- |
- |
0.011 |
0.011 |
0.0017 |
Example |
| 6 |
0.045 |
0.07 |
1.85 |
0.008 |
0.0010 |
0.042 |
- |
- |
- |
0.2 |
- |
0.012 |
0.014 |
0.0031 |
Example |
| 7 |
0.042 |
0.12 |
1.52 |
0.006 |
0.0021 |
0.036 |
0.45 |
0.78 |
- |
- |
0.04 |
0.007 |
0.011 |
0.0016 |
Example |
| 8 |
0.072 |
0.08 |
1.56 |
0.007 |
0.0035 |
0.055 |
0.38 |
0.87 |
- |
- |
- |
0.008 |
0.008 |
0.0021 |
Example |
| 9 |
0.170 |
0.07 |
1.82 |
0.006 |
0.0023 |
0.042 |
- |
- |
- |
- |
- |
0.012 |
0.013 |
0.0015 |
Comparative Example |
| 10 |
0.045 |
0.09 |
2.52 |
0.004 |
0.0019 |
0.032 |
- |
- |
- |
- |
- |
0.012 |
0.011 |
0.0020 |
Comparative Example |
| 11 |
0.052 |
0.06 |
1.57 |
0.008 |
0.0024 |
0.052 |
0.65 |
0.66 |
- |
- |
- |
0.010 |
0.009 |
0.0015 |
Comparative Example |
| 12 |
0.075 |
0.11 |
1.86 |
0.014 |
0.0022 |
0.044 |
- |
- |
- |
- |
- |
0.008 |
0.012 |
0.0019 |
Comparative Example |
| 13 |
0.052 |
0.07 |
1.78 |
0.006 |
0.0014 |
0.037 |
- |
- |
- |
0.3 |
- |
0.011 |
0.008 |
0.0018 |
Comparative Example |
| 14 |
0.056 |
0.10 |
2.08 |
0.005 |
0.0022 |
0.048 |
- |
- |
- |
- |
- |
0.010 |
0.013 |
0.0017 |
Comparative Example |
| 15 |
0.049 |
0.08 |
1.96 |
0.005 |
0.0022 |
0.051 |
- |
- |
- |
- |
- |
0.012 |
0.012 |
0.0001 |
Comparative Example |
| 16 |
0.055 |
0.08 |
1.57 |
0.007 |
0.0021 |
0.047 |
0.35 |
0.75 |
- |
- |
- |
0.018 |
0.011 |
0.0018 |
Comparative Example |
Note 1 Underlined value is out of the range according to the present invention.
Note 2 Ceq(IIW)=C+Mn/6+(Cr+Mo+v)/5+(Cu+Ni)/15 (%), where an atomic symbol represents
the content (mass%) of a chemical element represented by the symbol.
Note 3 Ar3(°C)=910-273C-74Mn-57Ni-16Cr-9Mo-5Cu, where an atomic symbol represents the content
(mass%) of a chemical element represented by the symbol.
Note 4 Expression (1): 0≤N-Ti/3.42≤0.0025, where N and Ti respectively represent the
contents (mass%) of N and Ti. |
[0062] [Table 1-2]
Table 1-2
| Steel No. |
Mg |
Zr |
REM |
B |
N |
Ceq(IIW) |
Expression (1) |
Ar3 |
Classification |
| 1 |
- |
- |
- |
0.0008 |
0.0052 |
0.397 |
0.0002 |
743 |
Example |
| 2 |
- |
- |
- |
0.0011 |
0.0042 |
0.355 |
0.0004 |
769 |
Example |
| 3 |
- |
- |
- |
0.0012 |
0.0046 |
0.390 |
0.0005 |
734 |
Example |
| 4 |
- |
- |
- |
0.0014 |
0.0052 |
0.378 |
0.0014 |
759 |
Example |
| 5 |
0.0011 |
- |
- |
0.0017 |
0.0035 |
0.419 |
0.0003 |
747 |
Example |
| 6 |
- |
- |
- |
0.0021 |
0.0063 |
0.393 |
0.0022 |
759 |
Example |
| 7 |
- |
0.0090 |
- |
0.0012 |
0.0045 |
0.385 |
0.0013 |
739 |
Example |
| 8 |
- |
- |
0.0070 |
0.0011 |
0.0042 |
0.415 |
0.0019 |
723 |
Example |
| 9 |
- |
- |
- |
0.0013 |
0.0048 |
0.473 |
0.0010 |
729 |
Comparative Example |
| 10 |
- |
- |
- |
0.0015 |
0.0042 |
0.465 |
0.0010 |
711 |
Comparative Example |
| 11 |
- |
- |
- |
0.0011 |
0.0057 |
0.401 |
0.0031 |
739 |
Comparative Example |
| 12 |
- |
- |
- |
0.0000 |
0.0052 |
0.385 |
0.0017 |
752 |
Comparative Example |
| 13 |
- |
- |
0.0080 |
0.0014 |
0.0022 |
0.409 |
-0.0001 |
761 |
Comparative Example |
| 14 |
0.0012 |
- |
- |
0.0012 |
0.0075 |
0.403 |
0.0037 |
741 |
Comparative Example |
| 15 |
- |
- |
- |
0.0013 |
0.0050 |
0.376 |
0.0015 |
752 |
Comparative Example |
| 16 |
- |
- |
- |
0.0011 |
0.0045 |
0.390 |
0.0013 |
734 |
Comparative Example |
Note 1 Underlined value is out of the range according to the present invention.
Note 2 Ceq(IIW)=C+Mn/6+(Cr+Mo+V)/5+(Cu+Ni)/15 (%), where an atomic symbol represents
the content (mass%) of a chemical element represented by the symbol.
Note 3 Ar3(°C)=910-273C-74Mn-57Ni-16Cr-9Mo-5Cu, where an atomic symbol represents the content
(mass%) of a chemical element represented by the symbol.
Note 4 Expression (1): 0≤N-Ti/3.42≤0.0025, where N and Ti respectively represent the contents
(mass%) of N and Ti. |
[0063] [Table 2]
Table 2
| No. |
Steel No. |
Heating Temperature |
Finishing Temperature |
Cooling Stop Temperature |
Thicker Portion (60 mm) |
Thinner Portion (50 mm) |
Difference in Strength between Thicker and Thinner Portions |
Toughness of Simulated HAZ vTrs(°C) |
Classification |
| (°C) |
(°C) |
(°C) |
YS (MPa) |
TS (MPa) |
El (%) |
vE-40 (J) |
YS (MPa) |
TS (MPa) |
El (%) |
vE-40 (J) |
YS (MPa) |
TS (MPa) |
| 1 |
1 |
1130 |
775 |
395 |
497 |
624 |
24 |
345 |
517 |
638 |
22 |
354 |
20 |
14 |
-55 |
Example |
| 2 |
2 |
1130 |
837 |
376 |
464 |
584 |
23 |
311 |
468 |
591 |
23 |
308 |
4 |
7 |
-50 |
Example |
| 3 |
3 |
1130 |
762 |
338 |
493 |
620 |
24 |
352 |
512 |
636 |
22 |
366 |
19 |
16 |
-60 |
Example |
| 4 |
4 |
1150 |
785 |
378 |
478 |
605 |
24 |
345 |
507 |
624 |
23 |
337 |
29 |
19 |
-50 |
Example |
| 5 |
5 |
1100 |
823 |
318 |
511 |
645 |
21 |
315 |
534 |
655 |
21 |
324 |
23 |
10 |
-50 |
Example |
| 6 |
6 |
1050 |
792 |
341 |
488 |
615 |
24 |
347 |
514 |
634 |
23 |
352 |
26 |
19 |
-55 |
Example |
| 7 |
7 |
1170 |
766 |
327 |
488 |
605 |
25 |
335 |
507 |
622 |
24 |
357 |
19 |
17 |
-50 |
Example |
| 8 |
8 |
1050 |
754 |
386 |
507 |
644 |
21 |
343 |
535 |
657 |
22 |
347 |
28 |
13 |
-50 |
Example |
| 9 |
9 |
1100 |
787 |
355 |
564 |
654 |
16 |
168 |
584 |
678 |
16 |
178 |
20 |
24 |
-10 |
Comparative Example |
| 10 |
10 |
1100 |
765 |
387 |
557 |
662 |
18 |
175 |
576 |
694 |
15 |
154 |
19 |
32 |
0 |
Comparative Example |
| 11 |
11 |
1130 |
778 |
367 |
434 |
569 |
25 |
339 |
508 |
627 |
23 |
364 |
74 |
58 |
-65 |
Comparative Example |
| 12 |
12 |
1130 |
810 |
395 |
417 |
555 |
25 |
258 |
421 |
562 |
25 |
278 |
4 |
7 |
-10 |
Comparative Example |
| 13 |
13 |
1170 |
792 |
345 |
498 |
632 |
21 |
335 |
521 |
648 |
22 |
328 |
23 |
16 |
0 |
Comparative Example |
| 14 |
14 |
1170 |
780 |
375 |
418 |
552 |
26 |
245 |
478 |
605 |
23 |
353 |
60 |
53 |
-65 |
Comparative Example |
| 15 |
15 |
1000 |
803 |
346 |
475 |
594 |
25 |
357 |
501 |
617 |
24 |
347 |
26 |
23 |
-20 |
Comparative Example |
| 16 |
16 |
1130 |
758 |
352 |
512 |
635 |
23 |
321 |
525 |
649 |
21 |
327 |
13 |
14 |
0 |
Comparative Example |
| 17 |
3 |
1230 |
785 |
395 |
517 |
634 |
20 |
179 |
524 |
651 |
21 |
205 |
7 |
17 |
- |
Comparative Example |
| 18 |
3 |
1130 |
915 |
357 |
547 |
652 |
21 |
147 |
551 |
667 |
20 |
155 |
4 |
15 |
- |
Comparative Example |
| 19 |
3 |
1130 |
702 |
345 |
423 |
568 |
25 |
338 |
425 |
568 |
25 |
345 |
2 |
0 |
- |
Comparative Example |
| 20 |
3 |
1130 |
760 |
524 |
403 |
545 |
26 |
253 |
418 |
556 |
26 |
254 |
15 |
11 |
- |
Comparative Example |
| Note 1 Underlined value is out of the range according to the present invention. |
