Technical Field
[0001] The present invention relates to a method for manufacturing a high-purity or high-cleanliness
steel cast piece with which the cleanliness of molten steel is increased by promoting
the flotation separation of oxide-based non-metal inclusions such as deoxidation products
in a tundish, and, moreover, to a continuous casting tundish with which the cleanliness
of molten steel is increased by promoting the flotation separation of oxide-based
non-metal inclusions such as deoxidation products in the tundish.
Background Art
[0002] In a continuous casting process for steel, a cast piece is manufactured by charging
molten steel from a ladle into a tundish once and by then discharging the molten steel
into a mold from the tundish while a specified amount of molten steel is retained
in the tundish. The tundish has a function of supplying molten steel when a ladle
is replaced during continuous casting is continued using plural ladles one after another
and has a function of distributing molten steel into plural molds. In addition, by
retaining a specified molten steel in the tundish, the tundish has a function of precisely
controlling the amount of molten steel discharged into a mold from the tundish, and,
moreover, of promoting the flotation separation of oxide-based non-metal inclusions
(hereinafter, simply referred to as "inclusions") such as deoxidation products which
are suspended in molten steel. In particular, since there is a demand for high-quality
steel materials nowadays, techniques with which inclusions are efficiently removed
in a tundish using a flotation separation method are widely used.
[0003] Among methods for removing inclusions using a flotation separation method in a tundish,
a method in which a molten steel flow is controlled using weirs which are placed in
a tundish is generally used. For example, Patent Literature 1 discloses a tundish
in which the inside of the tundish is separated into a steel receiving zone and virtually
calm steel zones by placing weirs having a penetration hole in the bottom portions
of the weirs and extending from the bottom of the tundish up over the upper surface
of molten steel in the tundish at two positions in the tundish so as to face each
other across a zone into which molten steel is charged from a ladle in order to remove
inclusions using a flotation separation method in the virtually calm steel zone.
[0004] Patent Literature 2 discloses a tundish in which the inside of the tundish is separated
into a steel receiving side and a steel discharge side with a weir having two penetration
holes that are in contact with the bottom of the tundish, in which a dam-like weir
(referred to as "lower weir") is placed downstream of the weir, in which the ratio
L/W of the length L of a long side of the tundish to the length W of the short side
of the tundish is set to be 2 to 7 and in which the volume ratio of the steel receiving
side to the whole tundish is set to be 10% to 40%.
[0005] Patent Literature 3 discloses a method in which the inside of a tundish is separated
with a weir in which a molten steel flow channel is formed so that the flow direction
is changed to a downward direction in the middle of the flow channel and in which
inclusions are removed in the tundish by blowing a gas into the molten steel flow
channel.
[0006] Patent Literature 4 discloses a tundish collision pad made of a heat-resistant material
consisting of a base provided with a collision surface and an endless outer side wall
extending upward from the base so as to completely surround an internal space having
an upper opening through which a molten metal flow is received, in which the outer
side wall includes a circular inside surface having at least a first part extending
in the direction of the opening, inward and upward.
[0007] There are techniques proposed in order to improve the technique according to Patent
Literature 4, and, for example, Patent Literature 5 discloses a flow control pad which
is placed at a position where a molten metal flow charged from a ladle collides with
the bottom of the tundish in order to control the flow of the molten metal in the
tundish, which has a wall part surrounding the collision position of the molten metal
flow and extending upward from the bottom of the tundish and an eave-shaped part extending
from the top edge of the wall part toward the center of the space surrounded by the
wall part and which has notches in the walls facing the surface on the long sides
of the tundish.
[0008] In addition, while the collision pad according to Patent Literature 4 is an integral
structure of a refractory, Patent Literature 6 discloses, instead of a collision pad,
a flow control weir consisting of a wall part extending upward from the bottom of
the tundish in a direction opposite to the molten metal flow from the ladle into the
tundish and an eave-shaped part extending from the top edge of the wall part toward
the molten metal flow, in which the height h of the wall part and the width d of the
eave-shaped part satisfy the relational expression 0.1 ≤ d/h ≤ 1.0.
[0009] Moreover, Patent Literature 7 discloses a method for manufacturing a high-cleanliness
steel cast piece using a continuous casting method using a tundish in which a flow
control pad consisting of a wall part surrounding a position where a molten steel
flow from a ladle into the tundish collides with the bottom of the tundish and extending
upward from the bottom of the tundish and an eave-shaped part extending from the top
edge of the wall part toward the center of the space surrounded by the wall part is
placed at the collision position of the molten steel flow and in which a molten metal
charging rate q (m
3/min), the area A1 (m
2) of the upper surface of the flow control pad other than the eave-shaped part and
the area A2 (m
2) of the bottom of the flow control pad satisfy the relational expression 0.5 < (q/A2)×(A1/A2)
< 5.0.
Citation List
Patent Literature
[0010]
PTL 1: Japanese Unexamined Patent Application Publication No. 53-6231
PTL 2: Japanese Unexamined Patent Application Publication No. 10-216909
PTL 3: Japanese Unexamined Patent Application Publication No. 2005-957
PTL 4: Japanese Unexamined Patent Application Publication (Translation of PCT Application)
No. 9-505242
PTL 5: Japanese Unexamined Patent Application Publication No. 2004-1077
PTL 6: Japanese Unexamined Patent Application Publication No. 2004-98066
PTL 7: Japanese Unexamined Patent Application Publication No. 2004-154803
Summary of Invention
Technical Problem
[0011] Since there has been a significant improvement in the flotation separation of inclusions
in a tundish due to Patent Literatures 1 through 7, there has been a significant increase
in cleanliness of molten steel in comparison to the cases where a weir is not used.
In particular, in Patent Literatures 4 through 7, since a molten steel flow charged
from a ladle into the tundish is stirred by "a circular inside surface extending in
the direction toward the opening, inward and upward" or "an eave-shaped part extending
from the top edge of a wall part toward the center of the space surrounded by the
wall part" so that the flow goes back to a molten steel charging position, a short-circuit
flow and a rapid flow in the tundish are eliminated due to a decrease in the velocity
of the charged molten steel flow, which results in contribution to an improvement
in the flotation separation of inclusions. It is known that the short-circuit flow
and the rapid flow described above obstruct the flotation separation of inclusions
in a tundish.
[0012] However, even in the cases of Patent Literatures 4 through 7, there is still room
for improvement. That is, for example, in the case of Patent Literature 6, if the
height of the weir, the area of the upper opening of the weir, the distances between
the eave part of the weir and the surfaces on the short side and long side of the
tundish and so forth are not appropriately determined in accordance with the height
of the upper surface of molten steel in the tundish and the flow rate of the charged
molten steel from the ladle into the tundish, since it is impossible to uniformly
decrease the velocity of the molten steel flow charged from the ladle, that is, since
the effect of the weir cannot be sufficiently realized, it is impossible to expect
that the flotation separation of inclusions in a tundish is promoted.
[0013] The present invention has been completed in view of the situation described above,
and an object of the present invention is to provide a method for manufacturing a
high-cleanliness steel cast piece using a continuous casting method with which, when
continuous casting is performed using a tundish in which a weir consisting of a wall
part extending upward from the bottom of a tundish and an eave-shaped part horizontally
extending from the top edge of the wall part toward a molten steel charging position
is placed at a position between the molten steel charging position and a molten steel
discharge port of the tundish, the flotation separation of inclusions can be performed
with increased certainty and efficiency in the tundish in comparison to conventional
methods, which results in a significant decrease in the number of product defects
caused by inclusions.
[0014] Also, an object is to provide a continuous casting tundish with which, when continuous
casting is performed using a tundish in which a weir consisting of the wall part and
the eave-shaped part is placed, the flotation of inclusions is promoted in order to
increase the cleanliness of molten steel in comparison to conventional cases, and
to provide a method for manufacturing a high-cleanliness steel cast piece using a
continuous casting method with which the flotation separation of inclusions can be
performed with increased certainty and efficiency in the tundish in comparison to
conventional methods, which results in a significant decrease in the number of product
defects caused by inclusions.
Solution to Problem
[0015] The subject matter of the present invention in order to solve the problems described
above is as follows.
[0016] [1] A method for manufacturing a high-cleanliness steel cast piece using a continuous
casting method, the method including charging deoxidized molten steel from a ladle
into a tundish once and then discharging the molten steel from the tundish into a
mold in order to continuously cast a steel cast piece using a continuous casting tundish
in which a weir consisting of a wall part extending upward from the bottom of the
tundish so as to surround a molten steel charging position where a molten steel flow
charged from the ladle collides with the bottom of the tundish from four directions
and an eave-shaped part horizontally extending from the top edge of the wall part
toward the molten steel charging position is placed at a position between the molten
steel charging position and a molten steel discharge port where the molten steel is
discharged into the mold from the tundish, in which the wall part and the eave-shaped
part have one or more notches penetrating through the wall part and the eave-shaped
part and in which the height of the weir, the area of the upper opening of the weir,
the distance between the front edge on the molten steel charging position side of
the eave-shaped part and the surface on the short side of the tundish, the distance
between the front edge on the molten steel charging position side of the eave-shaped
part and the surface on the long side of the tundish, the height of the upper surface
of the molten steel in the tundish and the flow rate of the molten steel charged from
the ladle into the tundish satisfy expression (1) below.
[0017] [Math. 1]

[0018] Here, in expression (1), H represents the height (m) of the upper surface of the
molten steel in the tundish, h represents the height (m) of the weir, S represents
the area (m
2) of the upper opening of the weir having an eave-shaped part, ρ represents the density
(ton/m
3) of the molten steel, Q represents the flow rate (ton/min) of the molten steel charged
from the ladle into the tundish, L represents the distance (m) between the front edge
on the molten steel charging position side of the eave-shaped part and the surface
on the short side of the tundish, W represents the distance (m) between the front
edge on the molten steel charging position side of the eave-shaped part and the surface
on the long side of the tundish.
[0019] [2] The method for manufacturing a high-cleanliness steel cast piece using a continuous
casting method according to item [1] above, in which the wall part surrounds an internal
space having a shape of a rectangular solid, and in which the ratio (L'/ W') of the
length (L' in units of m) of the rectangular solid in the direction of the long side
of the tundish to the length (W' in units of m) of the rectangular solid in the direction
of the short side of the tundish is 0.3 or more and 4.0 or less.
[0020] [3] The method for manufacturing a high-cleanliness steel cast piece using a continuous
casting method according to item [1] or [2] above, in which a maximum surface flow
velocity (Ve) of the molten steel in the tundish is 0.10 m/s or more and 0.50 m/s
or less.
[0021] [4] The method for manufacturing a high-cleanliness steel cast piece using a continuous
casting method according to any one of items [1] to [3] above, in which an inert gas
is blown into the molten steel in the tundish at a gas flow rate satisfying expression
(2) below through a gas blowing port which is fitted to the top of the eave-shaped
part in order to blow the inert gas and through a gas introduction pipe which is installed
in the wall part in order to introduce the inert gas to the gas blowing port.
[0022] [Math. 2]

[0023] Here, in expression (2), R represents the inert gas flow rate (NL/(s×m
2)) per unit area of the gas blowing port of the gas which is blown through the gas
blowing port.
[0024] [5] A continuous casting tundish, the tundish having a weir consisting of a wall
part extending upward from the bottom of the tundish so as to surround a molten steel
charging position where a molten steel flow charged from the ladle collides with the
bottom of the tundish from four directions and an eave-shaped part horizontally extending
from the top edge of the wall part toward the molten steel charging position, in which
the weir is placed at a position between the molten steel charging position and a
molten steel discharge port where the molten steel is discharged into the mold from
the tundish, in which the wall part and the eave-shaped part have one or more notches
penetrating through the wall part and the eave-shaped part, and in which a gas blowing
port is fitted to the top of the eave-shaped part in order to blow the inert gas and
a gas introduction pipe is installed in the wall part in order to introduce the inert
gas to the gas blowing port.
[0025] [6] A method for manufacturing a high-cleanliness steel cast piece using a continuous
casting method, the method including charging deoxidized molten steel from a ladle
into a tundish and then discharging the molten steel from the tundish into a mold
in order to continuously cast a steel cast piece using the continuous casting tundish
according to item [5] above while blowing an inert gas through a gas blowing port
into the molten steel in the tundish at a gas flow rate satisfying expression (2)
below.
[0026] [Math. 3]

[0027] Here, in expression (2), R represents the inert gas flow rate (NL/(s×m
2)) per unit area of the gas blowing port of the gas which is blown through the gas
blowing port.
[0028] [7] The method for manufacturing a high-cleanliness steel cast piece using a continuous
casting method according to item [6] above, in which an inert gas is blown through
all the positions of the eave-shaped parts on the four sides surrounding the molten
steel charging position.
Advantageous Effects of Invention
[0029] According to the present invention described in item [1] above, since the shape and
placement position of a weir having an eave-shaped part is optimized in accordance
with casting conditions, and since the height of the upper surface of molten steel
in a tundish and the flow rate of molten steel charged from a ladle into the tundish
are controlled to be within the specified ranges in accordance with the shape and
position of the weir, the flotation separation of inclusions in the tundish is promoted,
which results in an increase in the cleanliness of molten steel to be discharged into
a mold. As a result, since there is an increase in the cleanliness of a steel cast
piece which is continuously cast, there is a significant decrease in the number of
product defects caused by inclusions.
[0030] In addition, according to item [5] above, since an inert gas is blown from the top
of the eave-shaped part, it is possible to promote the flotation of fine inclusions
which are difficult to separate from molten steel with the upward flow alone of molten
steel from the weir. Therefore, since the flotation separation of inclusions in a
tundish is promoted in comparison to conventional cases, there is an increase in the
cleanliness of a steel cast piece which is cast using a continuous casting method
as a result of an increase in the cleanliness of molten steel which is charged into
a mold, which results in a significant decrease in the number of product defects caused
by inclusions.
Brief Description of Drawings
[0031]
[Fig. 1] Fig. 1 is a schematic elevation cross-sectional view illustrating a tundish
and a mold placed below the tundish in one example of a continuous casting apparatus
used in the present invention.
[Fig. 2] Fig. 2 is a plan view of the tundish illustrated in Fig. 1.
[Fig. 3] Fig. 3 is a side view of the tundish illustrated in Fig. 1.
[Fig. 4] Fig. 4 is a schematic elevation cross-sectional view illustrating a tundish
and a mold placed below the tundish in another example of a continuous casting apparatus
used in the present invention.
[Fig. 5] Fig. 5 is a plan view of the tundish illustrated in Fig. 4.
[Fig. 6] Fig. 6 is a side view of the tundish illustrated in Fig. 4.
[Fig. 7] Fig. 7 is a plan view illustrating an example of a tundish having repositioned
gas blowing ports in eave-shaped parts.
[Fig. 8] Fig. 8 is a plan view illustrating another example of a tundish having repositioned
gas blowing ports in eave-shaped parts.
[Fig. 9] Fig. 9 is a diagram illustrating the results of the investigation regarding
the influence of a value calculated by expression (3) on the occurrence number density
of defects caused by inclusions in a steel sheet.
[Fig. 10] Fig. 10 is a diagram illustrating the results of the investigation regarding
the influence of the ratio (L'/W') between the side lengths of the internal space
of a weir having a shape of a rectangular solid on the occurrence number density of
defects caused by inclusions in a steel sheet.
[Fig. 11] Fig. 11 is a diagram illustrating the results of the investigation regarding
the influence of the maximum surface flow velocity of molten steel in a tundish on
the occurrence number density of defects caused by inclusions in a steel sheet.
[Fig. 12] Fig. 12 is a diagram illustrating the results of the investigation regarding
the relationship between the flow rate of argon gas blown into molten steel in a tundish
and the number density of inclusions in a cast slab.
[Fig. 13] Fig. 13 is a diagram illustrating the results of the investigation regarding
the relationship between the blowing position of argon gas blown and the number density
of inclusions in a cast slab.
[Fig. 14] Fig. 14 is a diagram illustrating the results of the investigation regarding
the number of inclusions in a cast piece in EXAMPLE 1 for comparison among the examples
of the present invention, comparative examples and a conventional example.
[Fig. 15] Fig. 15 is a diagram illustrating the results of the investigation regarding
the number of inclusions in a cast piece in EXAMPLE 2 for comparison among the examples
of the present invention, comparative examples and a conventional example.
Description of Embodiments
[0032] The present invention will be specifically described with reference to the drawings
hereafter.
[0033] Fig. 1 is a schematic elevation cross-sectional view illustrating a tundish and a
mold placed below the tundish in one example of a continuous casting apparatus used
in the present invention, Fig. 2 is a plan view of the tundish illustrated in Fig.
1 and Fig. 3 is a side view of the tundish illustrated in Fig. 1.
[0034] In Figs. 1 through 3, symbol 1 denotes a tundish, 2 denotes a mold, 3 denotes a long
nozzle fitted to the bottom of a ladle (not illustrated) and 4 denotes a submerged
nozzle fitted to the bottom of the tundish 1. While molten steel 13 which has been
deoxidized using a deoxidation agent such as aluminum, silicon, titanium and manganese
and contained in a ladle is being charged into the tundish 1 through the long nozzle
3, the molten steel 13 in the tundish is discharged into the mold 2 through the submerged
nozzle 4 so that a specified amount of the molten steel 13 is retained in the tundish.
The molten steel 13 which has been discharged into the mold is cooled by the mold
2 in order to manufacture a steel cast piece 14. These drawings illustrate a case
where two lines (two strands) of slab pieces are continuously cast using two molds
2.
[0035] In the tundish 1, as illustrated in Figs. 1 through 3, a weir 7 is placed between
a molten steel charging position 5 where a molten steel flow charged from a ladle
(not illustrated) into the tundish 1 through the long nozzle 3 collides with the bottom
of the tundish 1 and a molten steel discharge port 6 for discharging the molten steel
from the tudigh 1 into the mold 2. The weir 7 has a wall part 8 vertically extending
upward from the bottom of the tundish 1 and an eave-shaped part 9 horizontally extending
from the top edge of the wall part 8 toward the molten steel charging position. The
outer and inner shapes of the wall part 8 projected onto a horizontal plane are rectangular.
Although the connection part of the surface on the molten steel charging position
side of the wall part 8 and the lower surface of the eave-shaped part 9 of the weir
7 has a smooth shape of a circular arc as illustrated in Fig. 1, the surface on the
molten steel charging position side of the wall part 8 and the lower surface of the
eave-shaped part 9 may bisect each other at right angles.
[0036] The weir 7 is also placed on the side of the surface on the long side of the tundish
1 so that the weir 7 surrounds the molten charging position 5 from four directions.
That is, the molten steel charging position 5 is surrounded from four directions by
the weir 7 whose outer and inner shapes projected onto a horizontal plane are square
or rectangular. However, the weir 7 has at least one notch 12 penetrating through
the wall part 8 and the eave-shaped part 9. That is, the weir 7 is configured so that
the molten steel 13 in the internal space surrounded by the weir 7 is discharged through
the notch 12 toward the molten steel discharge port 6 when casting is finished.
[0037] Although, in the case of the tundish 1 illustrated in Figs. 1 through 3, the notches
12 are formed at two positions, the notches 12 may be formed at one position or three
or more positions. In addition, although the notches 12 are formed on the sides of
the long side surfaces of the tundish 1 in Fig. 2, it is not necessary that the notches
12 be formed on the sides of the long side surfaces of the tundish 1, and the notches
12 may be formed on the sides of the short side surfaces of the tundish 1. However,
in the case where the notches 12 are formed on the sides of the short side surfaces
of the tundish 1, since there is concern that a short-cut flow toward the molten steel
discharge port 6 may be formed by the molten steel 13 which has passed through the
notches 12, which results in the flotation of inclusions being obstructed, it is preferable
that the notches 12 be formed on the side of the long side surfaces of the tundish
1. Here, "short-cut flow" refers to a narrow flux of the molten steel 13, which has
been charged into the molten steel charging position 5, flows from the molten steel
charging portions 5 toward the molten steel discharge port 6 without spreading, that
is, without diffusing in the tundish.
[0038] Fig. 4 is a schematic elevation cross-sectional view illustrating a tundish and a
mold placed below the tundish in another example of a continuous casting apparatus
used in the present invention, Fig. 5 is a plan view of the tundish illustrated in
Fig. 4, and Fig. 6 is a side view of the tundish illustrated in Fig. 4.
[0039] The tundish 1 illustrated in Fig. 4 is similar to the tundish 1 illustrated in Fig.
1 described above with the exception of the fact that a gas blowing port 10 is placed
on the top of the eave-shaped part 9 in the case of the tundish 1 illustrated in Fig.
4. Others are the same as the tundish 1 illustrated in Fig. 1.
[0040] That is, in the case of the tundish 1 illustrated in Fig. 4, a gas introducing pipe
11 is installed in the inside of the wall part 8 and the eave-shaped part 9, and the
top edge of the gas introduction pipe 11 is connected to a gas blowing port 10 which
is placed on the top of the eave-shaped part 9 and which is made of, for example,
porous brick. That is, the tundish 1 is configured so that an inert gas such as argon
gas which is introduced through the gas introduction pipe 11 from the outside of the
tundish 1 is blown into the internal space of the tundish 1 through the gas blowing
port 10.
[0041] In this case, although the gas introduction pipe 11 may be formed using a metal pipe
or a refractory pipe, the wall part 8 and the eave-shaped part 9 which are made of
refractory may only be penetrated by, for example, a thin cutting hole or a penetration
hole. In addition, it is not necessary that the gas blowing port 10 be made of porous
brick, and brick having a large number of thin penetration holes may be used. In addition,
in Figs. 4 through 6, although the gas blowing port 10 is placed on some portion of
the top of the eave-shaped part 9, the gas blowing port 10 may be placed on the entire
of the top of the eave-shaped part 9. The gas introduction pipe 11 is configured so
as to introduce an inert gas in a manner, for example, such that the gas introduction
pipe 11 is connected to a gas feeding pipe (not illustrated) penetrating the steel
shell (not illustrated) of the bottom of the tundish 1.
[0042] In addition, in Figs. 4 through 6, although the gas blowing port 10 is placed at
all the positions of the eave-shaped part 9 so as to surround the molten steel charging
position 5 from four directions, it is not necessary that the gas blowing port 10
be placed at all the positions of the eave-shaped part 9 so as to surround the molten
steel charging position 5 in order to blow an inert gas. An inert gas may be blown
only from the surfaces of the eave-shaped part 9 which are placed at a right angle
to the surface on the long side of the tundish 1 as illustrated in Fig. 7, and an
inert gas may be blown only from the surfaces of the eave-shaped part 9 which are
placed in parallel with the surface on the long side of the tundish 1 as illustrated
in Fig. 8. In the present invention, a method in which an inert gas is blown from
all the position of the eave-shaped part 9 surrounding the molten steel charging position
5 as illustrated in Figs. 4 through 6 is referred to as "blowing in four directions",
a method in which an inert gas is blown from the surfaces which are placed at a right
angle to the surface on the long side of the tundish 1 as illustrated in Fig. 7 is
referred to as "blowing at right angle to long side surface" and a method in which
an inert gas is blown from the surfaces which are placed in parallel with the surface
on the long side of the tundish 1 as illustrated in Fig. 8 is referred to as "blowing
in parallel with the long side surface".
[0043] In the case where the tundish 1 illustrated in Fig. 4 is used, the steel cast piece
14 is continuously cast by charging the molten steel 13 from the ladle into the tundish
1 through the long nozzle 3 while an inert gas such as argon gas or helium gas (=
rare gasses) is blown into the molten steel through the gas blowing port 10 and by
subsequently discharging the molten steel 13 from the tundish into the mold 2.
[0044] In the case where continuous casting is performed using the tundish 1 illustrated
in Fig. 1 or Fig. 4, the molten steel 13 which is charged into the molten steel charging
positon 5 through the long nozzle 3 flows in four directions along the bottom surface
of the tundish 1 due to the falling energy of the molten steel flow after the molten
steel 13 has collided with the molten steel charging positon 5. The direction of this
flow is changed to an upward direction as a result of collision with the wall part
8 of the weir 7, and, further, changed to the direction toward the molten steel charging
position 5 by the eave-shaped part 9 which is placed on the top edge of the weir 7.
Since these flows coming from four directions toward the molten steel charging position
5 collide with each other, there is a decrease in flow velocity due to the consumption
of kinetic energy. That is, using the weir 7, while the velocity of the molten steel
flow which is charged at a high velocity through the long nozzle 3 is significantly
decreased, the molten steel flow in the tundish is homogenized. Therefore, since a
shot-circuit flow and a rapid flow in the tundish are eliminated, there is a decrease
in the amount of inclusions which are carried into the mold 2 through the molten steel
discharge port 6 by these flows. That is, the flotation separation of inclusions in
the tundish 1 is promoted.
[0045] However, in order to realize the functions and effects of the weir 7, it is necessary
that, while the shape of the weir 7 is optimized, appropriate height of the upper
surface of the molten steel in the tundish be maintained in accordance with the shape
of the weir 7 and the molten steel 13 be charged into the tundish 1 at an appropriate
flow rate in accordance with the shape of the weir 7.
[0046] The present inventors conducted investigations, in the case of the tundish 1 having
the weir 7, regarding the influence of 6 factors, that is, the height of the weir
7, the area of the upper opening of the weir 7, the distance between the front edge
on the molten steel charging position side of the eave-shaped part 9 and the surface
on the short side of the tundish, the distance between the front edge on the molten
steel charging position side of the eave-shaped part 9 and the surface on the long
side of the tundish, the height of the upper surface of the molten steel in the tundish
and the flow rate of the molten steel 13 which is charged from the ladle into the
tundish 1, on the cleanliness of the steel cast piece 14, and, as a result, found
the following facts.
[0047] That is, firstly, it is necessary that the shape and position of the weir 7 be determined
in accordance with the height of the upper surface of the molten steel in the tundish
and the flow rate of the molten steel 13 which is charged from the ladle into the
tundish 1, and, subsequently, it is necessary that, after the weir 7 having the specified
shape has been placed at the specified position, the molten steel 13 be charged into
the tundish 1 while the height of the upper surface of the molten steel in the tundish
is maintained in accordance with the casting conditions which has been used to determine
the shape and the position of the weir 7.
[0048] The results of the investigations will be described hereafter, where the height of
the upper surface of the molten steel in the tundish is represented by H (m), the
flow rate of the molten steel 13 which is charged from the ladle into the tundish
1 is represented by Q (ton/min), the height of the weir 7 is represented by h (m),
the area of the upper opening of the weir 7 is represented by S (m
2), the distance between the front edge on the molten steel charging position side
of the eave-shaped part 9 and the surface on the short side of the tundish is represented
by L (m), the distance between the front edge on the molten steel charging position
side of the eave-shaped part and the surface on the long side of the tundish is represented
by W (m) and the density of the molten steel is represented by ρ (ton/m
3).
[0049] Here, the height H of the upper surface of the molten steel in the tundish is the
height of the upper surface of the molten steel in the region which is surrounded
by the weir 7 as illustrated in Fig. 3, the height h of the weir is the distance between
the bottom of the tundish 1 and the upper surface of the eave-shaped part 9 as illustrated
in Fig. 1, and the area S of the upper opening of the weir 7 is the area of the region
which is surrounded by the eave-shaped part 9 from four directions as illustrated
in Fig. 2. In addition, the distance L between the front edge on the molten steel
charging position side of the eave-shaped part 9 and the surface on the short side
of the tundish and the distance W between the front edge on the molten steel charging
position side of the eave-shaped part 9 and the surface on the long side of the tundish
are the distances at the height of the upper surface of the molten steel in the tundish
as illustrated in Fig. 1 and Fig. 3. Since the flow distance of inclusions under the
upper surface of the molten steel is important, the distance L and the distance W
are defined by the distances at the height of the upper surface of the molten steel.
In the present invention, the height H of the upper surface of the molten steel in
the tundish is 0.4 to 1.3 m, the flow rate Q of the molten steel 13 is 4 to 18 ton/min,
the height h of the weir is 0.1 to 0.6 m, the area S of the upper opening of the weir
7 is 0.1 to 0.8 m
2, the distance L is 4 to 5 m and the distance W is 0.1 to 0.5 m. It is appropriate
that the density ρ of the molten steel be about 7.0 ton/m
3.
[0050] Fig. 9 illustrates the results of the investigation regarding the influence of a
value (Z) calculated by expression (3) on the occurrence number density of defects
caused by inclusions in a steel sheet, where the value calculated by expression (3)
below is measured along the horizontal axis and the occurrence number density of defects
caused by inclusions in a steel sheet is measured along the vertical axis.
[0051] [Math. 4]

[0052] Here, the term [(H-h)×(S×ρ/Q)
1.37]
-0.6 in expression (3) indicates the degree of the upward motion from the weir of the
molten steel 13 which has been charged into the weir and the degree of the flotation
separation of inclusions in the top of the weir. The term [(7L/6)×(S×ρ/Q)
1.37] in the expression (3) indicates the degree of the flotation separation when the
inclusions which has flown up to near the upper surface of the molten steel from the
weir 7 flows in the direction of the long side of the tundish. The term [(7W/6)×(S×ρ/Q)
1.37] in the expression (3) indicates the degree of the flotation separation when the
inclusions which has flown up to near the upper surface of the molten steel from the
weir 7 flows in the direction of the short side of the tundish. In addition, Fig.
9 illustrates the results under conditions such that the width of each of the two
notches 12 was 30 mm.
[0053] As indicated in Fig. 9, it is clarified that there is a decrease in the occurrence
number of defects caused by inclusions in the steel sheet in the case where the height
H of the upper surface of the molten steel in the tundish, the flow rate Q of the
molten steel 13, the height h of the weir, the area S of the upper opening of the
weir 7, the distance L and the distance W satisfy expression (1) below.
[0054] [Math. 5]

[0055] It is not preferable that the value calculated by expression (3) be less than 3.50,
because there is a decrease in the degree of the upward motion of inclusions from
the upper opening of the weir, and, in addition to that, because there is a decrease
in a flotation effect when the inclusions which has flown up to near the upper surface
of the molten steel flows in the direction of the long side or short side of the tundish.
On the other hand, it is not preferable that the value calculated by expression (3)
be more than 9.50, because there is a decrease in an effect of aggregating inclusions
realized by the dispersion of kinetic energy of molten steel in the weir due to an
excessive large area of the opening of the weir 7, which results in a decrease in
the flotation performance of inclusions. Therefore, it is necessary that the height
H of the upper surface of the molten steel in the tundish, the flow rate Q of the
molten steel 13, the height h of the weir, the area S of the upper opening of the
weir 7, the distance L and the distance W satisfy expression (1) above.
[0056] In addition, Fig. 10 is a diagram illustrating the results of the investigation regarding
the influence of the ratio (L'/W') between the side lengths of the internal space
surrounded by the wall part 8 of the weir 7 having a shape of a rectangular solid
on the cleanliness of the molten steel, where the length of the side in the direction
of the long side of the tundish of the inner space surrounded by the wall part 8 having
a shape of a rectangular solid is represented by L' (m) and the length of the side
in the direction of the short side of the tundish of the inner space surrounded by
the wall part 8 having a shape of a rectangular solid is represented by W' (m). In
this case, the ratio (L'/W') is a factor indicating the degree of the dissipation
of the kinetic energy of the molten steel 13 which has been charged into the inside
of the weir. The length (L') of the side in the direction of the long side of the
tundish of the inner space having a shape of a rectangular solid is illustrated in
Fig. 1, and the length (W') of the side in the direction of the short side of the
tundish of the inner space having a shape of a rectangular solid is illustrated in
Fig. 3.
[0057] As illustrated in Fig. 10, it is clarified that there is a decrease in the occurrence
number of defects caused by inclusions, in the case where the ratio (L'/W') of the
length (L') of the side in the direction of the long side of the tundish of inner
space having a shape of a rectangular solid and the length (W') of the side in the
direction of the short side of the tundish of inner space having a shape of a rectangular
solid is 0.3 or more and 4.0 or less. In the case where the ratio (L'/W') is 0.3 or
more and 4.0 or less, since there is an increase in the amount of the kinetic energy
dissipated of the molten steel 13 which has been charged into the weir, the aggregation
of inclusions is promoted in the weir, which results in promotion of the flotation
separation of inclusions.
[0058] Moreover, Fig. 11 illustrates the results of the investigation regarding the influence
of the maximum surface flow velocity of molten steel in a tundish on the cleanliness
of a steel sheet. Here, in the case where the weir 7 having the eave-shaped part 9
is placed in the tundish, since the surface flow velocity of molten steel has a maximum
value in the vicinity (of the circumference) of the long nozzle 3, the maximum surface
flow velocity of molten steel was determined in the vicinity of the circumference
of the long nozzle 3. The maximum surface flow velocity (Ve) of the molten steel in
the tundish increases in proportion to the upward flow of the molten steel from the
weir 7.
[0059] As illustrated in Fig. 11, it is clarified that there is a decrease in the occurrence
number of defects caused by inclusions in the case where the maximum surface flow
velocity (Ve) is 0.10 m/s or more and 0.50 m/s or less. In the case where the maximum
surface flow velocity (Ve) is 0.10 m/s or more, since sufficient upward flow velocity
from the weir 7 is achieved, there is an increase in the effect of flotation separation
of the inclusions, and, on the other hand, in the case where the maximum surface flow
velocity (Ve) is 0.50 m/s or less, since the maximum surface flow velocity (Ve) is
not excessively large, the entrainment of tundish slag is prevented from occurring,
which results in the contamination of the molten steel being prevented from occurring.
[0060] Here, it is assumed that the molten steel 13 be present over the weir 7, therefore,
it is only necessary that the height h of the weir be less than the depth of the molten
steel in the tundish at the position where the weir 7 is placed. In addition, it is
preferable that the height h of the weir be equal to or less than 1/2 of the height
H of the upper surface of the molten steel in the tundish at the position where the
weir 7 is placed. On the other hand, in the case where the height h of the weir is
excessively low, since the effect of the weir 7 cannot be realized, it is preferable
that the height h of the weir be 100 mm or more. That is, it is preferable that, under
conditions such that the height h of the weir is 100 mm or more and equal to or less
than 1/2 of the height H of the upper surface of the molten steel in the tundish,
the other factors such as the area S of the upper opening of the weir 7, the distance
L and the distance W be controlled so as to satisfy expression (1).
[0061] In accordance with a planned values of the height H of the upper surface of the molten
steel and the flow rate Q of the molten steel 13, the shape and position of the weir
7 are determined so that the height h of the weir 7, the area S of the upper opening
of the weir 7, the distance L between the front edge on the molten steel charging
position side of the eave-shaped part 9 and the surface on the short side of the tundish
and the distance W between the front edge on the molten steel charging positon side
of the eave-shaped part 9 and the surface on the long side of the tundish satisfy
expression (1) above. Then, the weir 7 having the determined shape is placed at the
specified position in the tundish 1.
[0062] Subsequently, using this tundish 1, and by performing continuous casting while the
height H of the upper surface of the molten steel and the flow rate Q of the molten
steel 13 which is charged into the tundish 1 are controlled so that the height H of
the upper surface of the molten steel in the tundish and the flow rate Q of the molten
steel 13 which is charged into the tundish 1 satisfy relational expression (1), since
inclusions in the molten steel which is charged through the long nozzle 3 is forced
to flow upward by the weir 7, the inclusions flow up to the upper surface of the molten
steel in the tundish and are separated. That is, since the flotation separation of
the inclusions in the molten steel is promoted by the weir 7, it is possible to manufacture
clean steel cast piece 14.
[0063] That is, according to the present invention, by optimizing the shape and position
of the weir 7 having an eave-shaped part 9 in accordance with casting conditions,
and, further by controlling the height H of the upper surface of the molten steel
in the tundish and the flow rate Q of the molten steel which is charged from the ladle
into the tundish 1 to be within the specified ranges in accordance with the shape
and position of the weir 7, the flotation separation of inclusions in the tundish
1 is promoted to a much higher degree in comparison to the conventional cases. As
a result, since there is an increase in the cleanliness of the molten steel 13 which
is discharged into the mold 2, there is an increase in the cleanliness of the steel
cast piece 14 which is continuously cast, which results in a significant decrease
in the number of product defects caused by inclusions.
[0064] In addition, in the case where the tundish 1 illustrated in Fig. 4 is used, by blowing
an inert gas into molten steel through the gas blowing port 10 when continuous casting
is performed, fine inclusions which are difficult to remove from the molten steel
13 using a flotation separation method due to its low flowing-up velocity are trapped
by the bubbles of the inert gas so as to flow up to the upper surface of the molten
steel in the tundish with the bubbles of the inert gas.
[0065] That is, it is possible to deliver the molten steel 13 having only a small amount
of inclusions into the mold 2 with combination of the effect of the weir 7 and the
effect of the inert gas blown through the gas blowing port 10. In addition, in the
case where the weir 7 having a shape satisfying expression (1) is placed, where casting
is performed under casting conditions satisfying the relation of expression (1), and
where an inert gas is blown through the gas blowing port 10 into the molten steel,
there is a further decrease in the number of inclusions in the molten steel.
[0066] However, in order to realize the effect of blowing an inert gas from the top of the
eave-shaped part 9, it is necessary to optimize the blowing flow rate through the
gas blowing port 10.
[0067] Fig. 12 is a diagram illustrating the results of the investigation regarding the
relationship between the flow rate of argon gas and the number density of inclusions
in a cast slab when the argon gas was blown from all the positions of the eave-shaped
part 9 surrounding the molten steel charging position 5, that is, when the argon gas
was blown using a method of "blowing in four directions", under condition such that
the flow rate per unit area of the gas blowing port 10 of the argon gas which was
blown from the top of the eave-shaped part 9 was controlled in a range of 10 to 330
NL/(s×m
2). Here, "the area of the gas blowing port 10" refers to the total area of the gas
blowing part 10 in a plan view as illustrated in Fig. 5, and the area of the region
indicated by two diagonal lines crossing each other in Fig. 5, Fig. 7 and Fig. 8.
[0068] A tundish 1 having a capacity of 80 tons in terms of molten steel was used in the
investigations, and a weir 7 having a length of a side in the direction of the long
side of the tundish 1 (this side is referred to as a "weir long side") of 1200 mm,
a length of a side in the direction of the short side of the tundish 1 (this side
is referred to as a "weir short side") of 600 mm and a height of the weir of 230 mm
was placed in the tundish 1. This weir 7 has one notch 12 having a width of 10 mm
on each of the sides on the long side of the tundish 1. Moreover, the weir has two
gas blowing ports 10 having a length of 0.3 m and a width of 0.01 m across the notch
12 on the top of the eave-shaped part 9 on each of the weir long sides and one gas
blowing port 10 having a length of 0.3 m and a width of 0.01 m on the top of the eave-shaped
part 9 on each of the weir short sides. The total area of the gas blowing ports 10
is 0.018 m
2 (= 6 ports×0.3 m×0.01 m).
[0069] In addition, Fig. 12 illustrates the results of the investigation regarding the influence
of the position of an argon gas blowing port on the number density of inclusions in
a cast slab, by adding the results of an argon gas blowing test in which, using a
tundish having a weir 7 having the same shape as described above, argon gas was blown
from the bottom of the tundish outside the weir 7. In the case of the test where argon
gas was blown from the bottom of the tundish, one gas blowing port having an area
of 0.009 m
2 was placed between the weir 7 and the molten steel discharge port 6 on each of both
sides of the weir 7 (the total area of the gas blowing ports = 0.018 m
2) so that the total area of the gas blowing ports was equal to that in the case where
the gas blowing ports 10 were placed on the eave-shaped part 9.
[0070] As illustrated in Fig. 12, it is clarified that there is a high effect of decreasing
the number of inclusions in the case where the flow rate of argon gas which was blown
through the gas blowing port 10 placed on the eave-shaped part 9 was within the range
of expression (2) below.

[0071] Here, in expression (2), R represents the inert gas flow rate (NL/(s×m
2)) per unit area of the gas blowing port of the gas which is blown through the gas
blowing port 10 placed on the top of the eave-shaped part 9.
[0072] In the case where the inert gas flow rate (R) is less than 20 NL/(s×m
2), since the gas flow rate is excessively small, there is a decrease in the effect
of trapping inclusions using gas bubbles. On the other hand, in the case where the
inert gas flow rate (R) is more than 300 NL/(s×m
2), since there is an increase in the surface flow velocity of the molten steel in
the tundish due to an excessive increase in the strength of the upward flow of the
molten steel 13, the entrainment and cutting-in of tundish slag which is present on
the molten steel in the tundish occur, which results in a decrease in the cleanliness
of molten steel on the contrary.
[0073] In addition, as illustrated in Fig. 12, it is clarified that, in comparison to the
case where a gas is blown from the bottom of the tundish 1, there is a higher effect
of decreasing the number of inclusions in the case where a gas is blown from the top
of the eave-shaped part 9. This is because, by blowing the gas from the top of the
eave-shaped part 9, the spreading of the distribution of the gas bubbles can be prevented
and the separation of the trapped inclusions from the gas bubbles can be prevented,
which results in inclusions being efficiently trapped.
[0074] In addition, using three methods of blowing a gas from the eave-shaped part 9 described
above, that is, "blowing in four directions", "blowing at right angle to long side
surface" and "blowing in parallel with long side surface", the influence of these
three blowing methods on the inclusion number density in a steel cast piece was investigated.
The investigation results are illustrated in Fig. 13.
[0075] In this case, a tundish 1 having a total area of gas blowing ports 10 of 0.018 m
2 was used for "blowing in four directions". This tundish 1 is the same as the tundish
1 used to investigate the data illustrated in Fig. 12. Although the tundish 1 which
was used for "blowing in four directions" was used for "blowing at right angle to
long side surface", a gas was not blown through the gas blowing ports 10 placed on
the top of the eave-shaped part 9 on the weir long side, and an argon gas was blown
only through the gas blowing ports 10 placed on the top of the eave-shaped part 9
on the weir short side. In this case, the total area of the gas blowing ports 10 is
0.006 m
2 (= 2 ports×0.3 m×0.01 m). In addition, although the tundish 1 which was used for
"blowing in four directions" was used for "blowing in parallel with long side surface",
a gas was not blown through the gas blowing ports 10 placed on the top of the eave-shaped
part 9 on the weir short side, and an argon gas was blown only through the gas blowing
ports 10 placed on the top of the eave-shaped part 9 on the weir long side. In this
case, the total area of the gas blowing ports 10 is 0.012 m
2 (= 4 ports×0.3 m×0.01 m).
[0076] As illustrated in Fig. 13, it is clarified that, in the case where a gas is blown
from all positions of the eave-shaped part 9 surrounding the molten steel charging
position 5, that is, in the case of "blowing from four directions", there is a maximum
effect of flotation separation of inclusions. However, even in the case of "blowing
at right angle to long side surface" and "blowing in parallel with long side surface",
an inclusion number density was less than 0.30 number/m
2. In reference to Fig. 12, since the inclusion number density was 0.30 number/m
2 or more in the case where an inert gas was blown from the bottom of the tundish 1,
in comparison to this case, it is clarified that there was a large effect of decreasing
the number of inclusions.
[0077] That is, according to the present invention, by blowing an inert gas from the top
of the eave-shaped part 9, it is possible to promote the flotation of fine inclusions
which are difficult to separate from the molten steel 13, the flotation separation
of inclusions in the tundish 1 is promoted in comparison to conventional cases.
[0078] In addition, in the case where the shape of the weir 7 is optimized in accordance
with expression (1) and further, an inert gas is blown from the top of the eave-shaped
part 9, since the flotation separation of inclusions in the tundish 1 is promoted
to a higher degree, it is possible to manufacture a steel cast piece 14 having a significantly
high cleanliness.
[0079] Incidentally, in the case where the opening width of the notch 12 is less than 0.5
mm, since the flow rate of molten steel which passes through the notch 12 is excessively
small, there is a case where some of the molten steel 13 is left in the space surrounded
by the weir 7. Therefore, it is preferable to ensure that the opening width of the
notch 12 be 0.5 mm or more.
[0080] In addition, since the molten steel charging position 5 is not a "point" and actually
has an area to some extent, in order to surround such molten steel charging position
from four directions while ensuring that the weir 7 surround a sufficient absolute
amount of a space, the length of the upper opening of the weir 7 in the direction
of the long side of the tundish is set to be at least equivalent to the inner diameter
of the bottom edge of the long nozzle 3, preferably more than the inner diameter.
Here, in Fig. 1 and Fig. 4, the center of the molten steel charging position which
has an area is used to indicate the molten steel charging position 5.
EXAMPLE 1
[0081] In a continuous casting test, about 250 tons of aluminum killed ultralow-carbon steel
which had been smelted by performing carburization refining using a converter furnace
and by then performing vacuum degassing refining using an RH vacuum degassing refining
system was cast into a steel cast slab using a slab continuous casting apparatus having
a tundish of a 2 strand type which had a capacity of 80 tons and which was configured
as illustrated in Fig. 1.
[0082] At that time, by changing the height H of the upper surface of the molten steel in
the tundish, the flow rate Q of the molten steel charged from the ladle into the tundish,
the height h of the weir, the area S of the upper opening of the weir, the distance
L between the front edge on the molten steel charging position side of the eave-shaped
part and the surface on the short side of the tundish, and the distance W between
the front edge on the molten steel charging position side of the eave-shaped part
and the surface on the long side of the tundish, tests (the examples of the present
invention 1 through 14) in which the ranges according to the present invention were
satisfied and tests (comparative examples 1 through 3) in which the ranges according
to the present invention were not satisfied were carried out.
[0083] In addition, at that time, the ratio (L'/W') between the length (L') of the side
in the direction of the long side of the tundish of the inner space of the weir having
a shape of rectangular solid and the length (W') of the side in the direction of the
short side of the tundish of the inner space were changed within a range of 0.25 to
4.5. For all the tundishes, the opening width of each of the two notches was 20 mm,
the extension length of the eave-shaped part (the extension length from the inner
wall surface of the wall part) was 0.12 m, and the radius of the circular arc connecting
the wall part and the eave-shaped part was 0.06 m. The maximum surface flow velocity
(Ve) was within a range of 0.08 to 0.52 m/s in accordance with the shape of the weir.
[0084] In addition, for comparison, a test (conventional example 1) was carried out using
a tundish which was the same as that used in the tests described above with exception
of the fact this tundish did not have a weir.
[0085] The height of the upper surface of the molten steel in the tundish, the flow rate
of the molten steel charged from the ladle into the tundish, the shape of the weir
of the used tundish are given in Table 1. In addition, the value of expression (3)
which was determined from the height of the upper surface of the molten steel in the
tundish, the flow rate of the molten steel charged from the ladle into the tundish
and the shape of the weir are also given in Table 1. Moreover, the ratio (L'/W') and
the maximum surface flow velocity (Ve) of the molten steel in the tundish which was
determined by the tilting angle of a bar which was dipped in the molten steel in the
tundish are given in Table 1.
[Table 1]
|
H (m) |
Q (ton/min) |
h (m) |
S (m2) |
L (m) |
W (m) |
L' (m) |
W' (m) |
Value of Relational Expression (3) |
L'/W |
Ve (m/s) |
Conventional Example 1 |
1.0 |
3.0 |
- |
- |
- |
- |
- |
- |
- |
- |
0.45 |
Example 1 |
1.0 |
4.0 |
0.20 |
0.40 |
3.80 |
0.46 |
1.20 |
0.61 |
4.60 |
1.97 |
0.30 |
Example 2 |
1.1 |
5.0 |
0.20 |
0.50 |
3.95 |
0.46 |
0.90 |
0.61 |
4.61 |
1.48 |
0.48 |
Example 3 |
1.0 |
4.0 |
0.20 |
0.10 |
3.95 |
0.46 |
0.90 |
0.61 |
5.24 |
1.48 |
0.45 |
Example 4 |
1.3 |
5.0 |
0.20 |
0.27 |
4.20 |
0.46 |
0.90 |
0.61 |
3.54 |
1.48 |
0.30 |
Example 5 |
1.0 |
5.0 |
0.20 |
0.42 |
4.10 |
0.53 |
0.90 |
0.61 |
4.39 |
1.48 |
0.15 |
Example 6 |
0.8 |
5.0 |
0.40 |
0.10 |
4.03 |
0.59 |
0.88 |
0.61 |
9.04 |
1.44 |
0.44 |
Example 7 |
0.7 |
3.4 |
0.20 |
0.15 |
4.13 |
0.53 |
0.88 |
0.61 |
5.05 |
1.44 |
0.40 |
Example 8 |
1.0 |
6.0 |
0.30 |
0.25 |
4.04 |
0.54 |
0.88 |
0.61 |
4.39 |
1.44 |
0.32 |
Example 9 |
1.0 |
5.0 |
0.20 |
0.80 |
3.60 |
0.62 |
0.86 |
0.52 |
6.84 |
1.65 |
0.08 |
Example 10 |
1.0 |
6.5 |
0.15 |
0.07 |
3.62 |
0.64 |
0.86 |
0.52 |
9.32 |
1.65 |
0.52 |
Example 11 |
1.0 |
4.6 |
0.34 |
0.10 |
3.95 |
0.92 |
0.90 |
0.20 |
6.43 |
4.50 |
0.45 |
Example 11 |
1.0 |
4.0 |
0.20 |
0.10 |
4.20 |
0.35 |
0.20 |
0.80 |
5.25 |
0.25 |
0.45 |
Example 13 |
1.1 |
6.5 |
0.34 |
0.08 |
4.15 |
1.12 |
0.90 |
0.20 |
9.01 |
4.50 |
0.52 |
Example 14 |
1.05 |
5.2 |
0.20 |
0.55 |
3.90 |
0.30 |
0.20 |
0.80 |
4.68 |
0.25 |
0.09 |
Comparative Example 1 |
1.15 |
6.5 |
0.08 |
0.33 |
3.10 |
0.40 |
1.50 |
0.25 |
3.23 |
6.00 |
0.55 |
Comparative Example 2 |
1.3 |
6.5 |
0.05 |
0.50 |
3.00 |
0.40 |
1.40 |
0.25 |
3.16 |
5.60 |
0.09 |
Comparative Example 3 |
1.5 |
6.0 |
0.05 |
0.50 |
3.05 |
0.58 |
1.42 |
0.27 |
3.28 |
5.26 |
0.09 |
[0086] After casting had been performed, the number of inclusions in the cast piece was
investigated by performing ultrasonic flaw inspection. Fig. 14 illustrates the results
of the investigation on the number of inclusions. Here, in Fig. 14, the results are
illustrated in the form of an index which was determined using the number of inclusions
determined in conventional example 1 in which a tundish having no weir was used as
a standard (= 1.0).
[0087] As illustrated in Fig. 14, it is clarified that, using the present invention, there
was a significant decrease in the number of inclusions in a steel cast slab. That
is, it is clarified that, using the present invention, it is possible to significantly
promote the flotation effect of inclusions in the tundish.
EXAMPLE 2
[0088] In a continuous casting test, about 250 tons of aluminum killed ultralow-carbon steel
which had been smelted by performing carburization refining using a converter furnace
and by then performing vacuum degassing refining using an RH vacuum degassing refining
system was cast into a steel cast slab using a slab continuous casting apparatus having
a tundish of a 2 strand type which was configured as illustrated in Fig. 4.
[0089] The used tundish had a capacity of 80 tons in terms of molten steel, and a weir having
an eave-shaped part and having a length of weir long side of 1200 mm, a length of
the weir short side of 600 mm and a height of the weir of 230 mm was placed in the
tundish. Two gas blowing ports having a length of 0.3 m and a width of 0.01 m were
placed across a notch on the top of the eave-shaped part on the each of the weir long
sides. In addition, one gas blowing port having a length of 0.3 m and a width of 0.01
m was placed on the top of the eave-shaped part on the each of the weir short sides.
The total area of the gas blowing ports was 0.018 m
2 (= 6 ports×0.3 m×0.01 m). This weir had one notch having a width of 10 mm on each
of the weir long sides.
[0090] Using this tundish, in "blowing in four directions", argon gas was blown through
all the gas blowing ports (total area = 0.018 m
2) as an inert gas. In "blowing at right angle to long side surface", an inert gas
was not blown through the gas blowing ports placed on the top of the eave-shaped part
on the weir long sides, and argon gas was blown only through the gas blowing ports
placed on the top of the eave-shaped part on the weir short sides (total area = 0.006
m
2). In addition, in "blowing in parallel with long side surface", an inert gas was
not blown through the gas blowing ports placed on the top of the eave-shaped part
on the weir short sides, and argon gas was blown only through the gas blowing ports
placed on the top of the eave-shaped part on the weir long sides (total area = 0.012
m
2).
[0091] The gas blowing ports were made of porous brick, and the gas blowing ports were formed
by embedding the porous brick in the eave-shaped part.
[0092] In the test, by changing the flow rate of argon gas which was blown through the gas
blowing ports on the eave-shaped part, tests (the examples of the present invention
21 through 28) in which the ranges according to the present invention were satisfied
and tests (comparative examples 22 through 26) in which the ranges according to the
present invention were not satisfied were carried out. In addition, a test (comparative
example 21) in which argon gas was blown from the positions on the bottom of the tundish
which were placed away from the eave-shaped part toward the molten steel discharge
ports. In comparative example 21, the total area of the gas blowing ports were 0.018
m
2. Moreover, for comparison, a test (conventional example 21) was carried out using
a tundish which was the same as that used in the tests described above with exception
of the fact this tundish did not have a weir. The flow rate and blowing position of
the argon gas blown into the molten steel in the tundish are given in Table 2.
[Table 2]
|
Argon Gas Flow Rate (NL/(s×m2)) |
Gas Blowing Position |
Conventional Example 21 |
- |
- |
Example 21 |
50 |
Eave-shaped Part: Blowing in Four Directions |
Example 22 |
100 |
Eave-shaped Part: Blowing in Four Directions |
Example 23 |
150 |
Eave-shaped Part: Blowing in Four Directions |
Example 24 |
300 |
Eave-shaped Part: Blowing in Four Directions |
Example 25 |
50 |
Eave-shaped Part: Blowing at Right Angle to Long Side Surface |
Example 26 |
150 |
Eave-shaped Part: Blowing at Right Angle to Long Side Surface |
Example 27 |
50 |
Eave-shaped Part: Blowing in Parallel with Long Side Surface |
Example 28 |
150 |
Eave-shaped Part: Blowing in Parallel with Long Side Surface |
Comparative Example 21 |
150 |
Bottom of Tundish |
Comparative Example 22 |
350 |
Eave-shaped Part: Blowing at Right Angle to Long Side Surface |
Comparative Example 23 |
350 |
Eave-shaped Part: Blowing in Four Directions |
Comparative Example 24 |
330 |
Eave-shaped Part: Blowing in Four Directions |
Comparative Example 25 |
350 |
Eave-shaped Part: Blowing in Four Directions |
Comparative Example 26 |
0 |
- |
[0093] After casting had been performed, the number of inclusions in the cast piece was
investigated by performing ultrasonic flaw inspection. Fig. 15 illustrates the results
of the investigation on the number of inclusions.
[0094] As illustrated in Fig. 15, it is clarified that, using the present invention, there
was a significant decrease in the number of inclusions in a steel cast slab. That
is, it is clarified that, using the present invention, it is possible to significantly
promote flotation effect of inclusions in the tundish.
Reference Signs List
[0095]
- 1
- tundish
- 2
- mold
- 3
- long nozzle
- 4
- submerged nozzle
- 5
- molten steel charging position
- 6
- molten steel discharge port
- 7
- weir
- 8
- wall part
- 9
- eave-shaped part
- 10
- gas blowing port
- 11
- gas introduction pipe
- 12
- notch
- 13
- molten steel
- 14
- steel cast piece