Technical Field
[0001] The present invention relates to a nonwoven fabric which exhibits excellent absorption
together with high holding of liquid such as water and chemical solution as well as
excellent bulkiness, softness, and texture, and therefore, which is particularly suitable
for use as a nonwoven fabric for skin in cosmetic or cleansing purpose. More specifically,
the present invention relates to a nonwoven fabric well adapted for use as a wiper
which, when used for cosmetic purpose, will exhibit high holding of the cosmetic liquid
with releasability of the liquid as needed, and when used for cleansing purpose, which
exhibits high wiping performance without damaging the skin with the wiped smudges
retained within the nonwoven fabric without re-deposition.
Background Art
[0002] Various nonwoven fabrics have been proposed as a nonwoven fabric for human cleansing
applications used in wet condition. An exemplary such nonwoven fabric is the one containing
40 to 77% by weight of a polyester fiber and a polyolefin fiber in the entire fabric,
and this highly soft fabric does not experience loss of bulkiness when wet (see Patent
Document 1). Despite the good texture realized by the use of the polyolefin fiber,
the nonwoven fabric of this proposal, however, suffered from the problems of poor
liquid retention due to the lack of rigidity and insufficient bulkiness as well as
insufficient cleansing ability.
[0003] A nonwoven fabric for wiper application having good bulkiness, wiping ability, and
actual usability prepared by using a fiber having an irregular cross-section and a
fibrillated fiber has also been proposed (see Patent Document 2). However, the situation
is not such that every fiber having an irregular cross-section has improved liquid
holding and cleansing ability irrespective of its cross-sectional shape, and fibrillated
fibers which often have pointed fiber cross-section had the problem of the risk of
damaging the skin when they are used for human cleansing purpose.
[0004] Also proposed is a nonwoven fabric containing a fiber having an irregular cross-section
with hollow cross-section, and this nonwoven fabric is said to exhibit liquid holding
and cleansing ability (see Patent Document 3). The nonwoven fabric of this proposal
exhibited improved liquid holding due to its shape of cross-section. However, it suffered
from collapse of the hollow section, and hence, insufficient shape retention, and
this resulted in the insufficient liquid holding performance.
[0005] A sheet material for water-absorbing article having improved tensile strength and
anti-transparency is also proposed (see Patent Document 4). The main fiber constituting
this sheet is characterized by the single fiber cross-sectional shape having a degree
of oblateness of up to 2.0 and at least 2 openings each having an opening angle of
less than 120 degrees. The nonwoven fabric of this proposal, however, suffered from
the problem of insufficient softness as a nonwoven fabric due to the low degree of
oblateness despite its good anti-transparency by the diffuse reflection.
Prior Art Document
Patent Document
Summary of the Invention
Problems to Be Solved by the Invention
[0007] Accordingly, an object of the present invention is to provide a nonwoven fabric which
exhibits high absorption, retention, and release of liquids that could not be realized
by the prior art as described above or sole use of the natural fiber or the cellulose
fiber, suitable bulkiness and softness, and reduced irritation to the skin due to
the texture together with improved wiping ability, and which is well adapted for use
in human cleansing and cosmetic wiper applications.
Means for Solving the Problems
[0008] The present invention is an attempt to solve the problems as described above, and
in the course of such attempt, the inventors found that combined use of the polyester
fiber having an oblate multilobal cross-section with the cellulose fiber enables improvement
of wiping ability with no damage to the skin, and when used by impregnating the nonwoven
fabric with a liquid, such combination also enables improvement of liquid retention
and liquid holding without sacrificing releasability of the liquid upon use. The present
invention has been completed in view of such finding.
[0009] Accordingly, the nonwoven fabric of the present invention is a nonwoven fabric comprising
20 to 80% by weight of a polyester fiber having an oblate multilobal cross-section
and 20 to 80% by weight of a cellulose fiber wherein
the polyester fiber having an oblate multilobal cross-section has an oblate cross-section
with at least 6 lobes on its periphery, and
when the cross-section of the polyester fiber having a multilobal oblate cross-section
has maximum length A, maximum width B, length C of line connecting adjacent lobe apexes
in the section with largest lobes, and length D of perpendicular between the line
C connecting the adjacent lobe apexes and the bottom of recess between the adjacent
lobes,
degree of oblateness (A/B) and degree of irregularity (C/D) simultaneously satisfy
the following relations (1) and (2) :

and

[0010] According to a preferable embodiment of the present invention, when maximum length
A of the polyester fiber having an oblate multilobal cross-section is regarded as
axis of symmetry, and line segments are depicted between opposing lobe apexes on opposite
sides of the maximum length A, and second longest line segment next to the maximum
width B of the line segments has length E, lobe ratio (E/B) satisfies the following
relation (3):

[0011] According to a preferable embodiment of the present invention, the polyester fiber
having a multilobal oblate cross-section has a single-fiber fineness of up to 2.0
dtex.
[0012] The nonwoven fabric of the present invention is particularly adapted for use as a
nonwoven fabric for a wiper.
Advantageous Effect of the Invention
[0013] The present invention is capable of producing a nonwoven fabric which exhibits high
absorption, retention, and release of liquids such as water and chemical solution,
suitable bulkiness and softness, and reduced irritation to the skin together with
improved wiping ability, and which is well adapted for use in human cleansing and
cosmetic applications.
Brief Description of the Drawings
[0014] [FIG. 1] FIG. 1 is a cross-sectional view for illustrating the cross-section of the
polyester fiber having an oblate multilobal cross-section with a plurality of lobes
(8 lobes) on its periphery used in the nonwoven fabric of the present invention.
Description of Preferred Embodiments
[0015] Next, the nonwoven fabric of the present invention is described in detail.
[0016] The cellulose fiber used in the present invention is at least one cellulose fiber
selected from natural fibers such as linen, silk, and cotton, regenerated fibers such
as viscose rayon, cuprammonium rayon, and solvent spun cellulose, and semi-synthetic
fibers such as acetate. Of these, the preferred is use of viscose rayon and solvent
spun cellulose in view of handling convenience and versatility.
[0017] The cellulose fiber used in the present invention may have any cross-section, while
the cross-section is preferably oblate shape having lobes and recesses on its periphery.
Larger number of the lobes and recesses on the periphery corresponds to higher liquid
absorption, and in addition, reduced water spot due to uniform liquid dispersion to
the entire nonwoven fabric by the capillary action.
[0018] The number of lobes on the periphery is preferably at least 5, and more preferably
at least 8. Preferably, the shape of the lobe and the recess is curbed in view of
the texture.
[0019] The cellulose fiber may preferably have a single fiber fineness of 1.0 to 5 dtex.
The single fiber fineness is more preferably 1.2 to 2.2 dtex. When the single fiber
fineness is less than 1.0 dtex, the fiber is easily wound around the card cylinder,
and this may invite drastic loss of processability. As a result, the nonwoven fabric
is likely to suffer from texture unevenness. On the other hand, when the single fiber
fineness is in excess of 5 dtex, the nonwoven fabric will have a hard feel and this
tends to be particularly unfavorable for use with human. Increased size of the single
fiber also results in the excessive increase in the size of the gap between the fibers,
and this tends to result in the drastic loss of the liquid holding.
[0020] The cellulose fiber preferably has a fiber length of 30 to 80 mm in view of efficiently
producing a nonwoven fabric exhibiting a high interlace with other constituent fibers
such as polyester fiber, high liquid absorption, sufficient liquid holding and release,
and uniform texture. The fiber length is more preferably 35 to 64 mm. Exemplary commercially
available cellulose fibers include rayon manufactured by Daiwabo Rayon Co., Ltd. of
Japan.
[0021] In the nonwoven fabric of the present invention, content of the cellulose fiber is
20 to 80% by weight. When the blend ratio (content) of the cellulose fiber is less
than 20% by weight, water absorption for the liquid impregnation will be reduced,
and function of holding the water in the nonwoven fabric will be insufficient and
the liquid will unnecessarily flow out of the nonwoven fabric during its use. The
flexibility inherent to the cellulose fiber will also be lost from the nonwoven fabric
of the present invention, and the texture in its use will be unfavorable. On the other
hand, the blend ratio of the cellulose fiber in excess of 80% by weight will invite
holding of the impregnated liquid in the fiber, and the fiber will not be able to
release a sufficient amount of liquid when needed. The nonwoven fabric will also lose
its bulkiness, and this will invite reduced liquid retention as well as bulky touch.
Accordingly, preferable content of the cellulose fiber is 40 to 60% by weight.
[0022] The polyester constituting the polyester fiber used in the present invention is,
for example, high molecular weight polymer produced by condensation between terephthalic
acid and ethylene glycol or butylene glycol, condensation product of sebacic acid,
adipic acid, trimellitic acid, isophthalic acid, paraoxybenzoic acid or the like with
ethylene glycol or butylene glycol, or a polyester polymer containing other polyesters.
[0023] The polyester fiber having an oblate multilobal cross-section used in the present
invention is an oblate fiber wherein the cross-section has at least 6 lobes on the
periphery.
[0024] The polyester fiber having an oblate multilobal cross-section used in the present
invention is a polyester fiber having an oblate cross section having at least 6 lobes.
When the number of lobes on the periphery is less than 6, the gap formed by the adjacent
fibers will be insufficient and the water absorption and water retention will be insufficient.
The oblate cross section realizes gaps between the fibers, and this gap formed between
the fibers results in the excellent bulkiness. In addition, use of such polyester
fiber results in the higher likeliness of bending or flattening of the single fibers
constituting the nonwoven fabric, and hence, in soft feel.
[0025] FIG. 1 shows an embodiment of the cross-sectional shape of the single fiber of the
polyester fiber having an oblate multilobal cross-section used in the present invention.
FIG. 1 illustrates the cross-sectional shape of the polyester fiber having an oblate
multilobal cross-section according to the nonwoven fabric of the present invention
having a plurality of lobes (8 lobes) on its periphery.
[0026] In the present invention, the polyester fiber used has an oblate cross-section with
at least 6, preferably at least 8, and more preferably at least 10 lobes. Upper limit
for the number of lobes is preferably 12, and the lobes preferably have a curved shape
in view of the texture.
[0027] The polyester fiber having an oblate multilobal cross-section used in the present
invention has an oblate multilobal cross-section of the single fiber which simultaneously
has the degree of oblateness (A/B) and the degree of irregularity (C/D) satisfying
the following relations (1) and (2):

and

[0028] In the relations as described above, "A" is length of the longest line segment of
the oblate multilobal cross-section; "B" is length of the line segment which is the
maximum width between the lobe apexes perpendicular to the line segment length A.
"C" is length of the line segment connecting adjacent lobe apexes which are the largest
lobes of the oblate multilobal cross-section. "D" is length of the perpendicular between
the line C connecting the adjacent lobe apexes and the bottom of recess between the
adjacent lobes.
[0029] In other words, according to preferred embodiment of the nonwoven fabric of the present
invention, the polyester fiber having an oblate multilobal cross-section which is
used by blending with another fiber has the degree of oblateness and the degree of
irregularity simultaneously satisfying the relations (1) and (2) when the cross-section
of the polyester fiber having a multilobal oblate cross-section has maximum length
A, maximum width B, length C of line connecting adjacent lobe apexes in the section
with largest lobes, and length D of perpendicular between the line C connecting the
adjacent lobe apexes and the bottom of recess between the adjacent lobes.
[0030] When the degree of oblateness (A/B) is less than 2.0 in the present invention, fiber
flattening will be difficult, and soft feel will not be realized. On the other hand,
the degree of oblateness (A/B) in excess of 3.0 will result in the insufficient tension
and loss of resilience, and also, loss of spinnablity and poor degree of irregularity.
The degree of oblateness (A/B) is preferably 2.0 to 2.7, and more preferably 2.0 to
2.5.
[0031] The degree of irregularity (C/D) shows size of the recess between adjacent lobes
in the oblate multilobal cross-section, and the larger degree of irregularity means
the smaller recess while the smaller degree of irregularity means the larger recess.
Since larger degree of irregularity (C/D) results in the shallow recess, namely, in
the smaller space between the fibers, and this results in the lower water absorption
and retention, and also, in the lower wiping ability of the smudges. Accordingly,
the degree of irregularity (C/D) is up to 5.0. In the meanwhile, an excessively small
degree of irregularity (C/D) invites easy bending of the cross section at the recess,
and retention the oblate shape tends to be difficult. In addition, the fiber is easily
damaged by abrasion, and this results in the risk of skin damage upon frictional contact
with the skin. In view of the situation as described above, the degree of irregularity
(C/D) is at least 1.0. Accordingly, the degree of irregularity (C/D) is in the range
of 1.0 to 5.0, and in view of absorption and retention of the liquid as well as wiping
ability, the degree of irregularity (C/D) is 2.0 to 4.0 in the more preferable embodiment.
[0032] In the present invention, content of the polyester fiber having an oblate multilobal
cross-section in the nonwoven fabric is 20 to 80% by weight. When the blend ratio
(content) of the polyester fiber having an oblate multilobal cross-section is less
than 20% by weight, the nonwoven fabric will lose its bulkiness and this results in
the poor liquid holding. The feel of the nonwoven fabric will also be hard detracting
from the texture. On the other hand, when the blend ratio (content) of the polyester
fiber having an oblate multilobal cross-section is in excess of 80% by weight, the
space between the fibers will be excessive and there will be a problem that the liquid
will flow out of the nonwoven fabric during its use despite the good bulkiness of
the nonwoven fabric. The content of the polyester fiber having an oblate multilobal
cross-section in the nonwoven fabric is preferably 40 to 60% by weight.
[0033] The polyester fiber having an oblate multilobal cross-section used in the present
invention comprises the polyester fibers satisfying the lobe ratio as defined by the
following relation (3) when maximum length A of the polyester fiber having an oblate
multilobal cross-section is regarded as axis of symmetry, and line segments are depicted
between opposing lobe apexes on opposite sides of the maximum length A, and second
longest line segment next to the maximum width B of the line segments has length E.

[0034] The lobe ratio (E/B) has the meaning of an index for evaluating the degree of deformation
of the substantially oblong shape depicted by connecting the lobe apexes at opposite
ends of the maximum width B, the E, and the maximum length A. When the lobe ratio
is too small, the depth of the recess will be insufficient and the cross-section will
resemble an oblate cross shape to the extremity. As a consequence, the space ratio
between the fibers will be reduced, and this results in reduced water absorption and
retention. In addition, when the nonwoven fabric is brought in contact with the skin,
the number of lobes that becomes in contact with the skin will be reduced due to the
resemblance of the cross-section with the oblate cross shape, and this results in
the poor texture and softness. Accordingly, the lobe ratio is preferably at least
0.6.
[0035] On the other hand, when the lobe ratio is excessively high, more recesses will be
completely blocked when the lobes and recesses of the fiber are brought to fit with
each other, and the space ratio will be reduced with reduced water absorption and
retention. In addition, when the nonwoven fabric is brought in contact with the skin,
the number of lobes that become in contact with the skin will be reduced due to the
resemblance with the cross-section to oblate hexagonal shape, and this results in
the poor texture and softness. In view of the situation as described above, the lobe
ratio (E/B) is preferably up to 0.9. Accordingly, the lobe ratio (E/B) is more preferably
0.6 to 0.9, and in view of the balance, the lobe ratio (E/B) is preferably 0.6 to
0.8, and more preferably 0.7 to 0.8.
[0036] The polyester fiber having an oblate multilobal cross-section used in the present
invention preferably has a single fiber fineness of up to 2.0 dtex. The single fiber
fineness is more preferably 1.0 to 2.0 dtex, and still more preferably 1.2 to 1.8
dtex. When the single fiber fineness is in excess of 2 dtex, rigidity inherent to
the polyester fiber will be high, and the texture will be poor with higher irritation
to the skin, and the soft feel will be impaired. In addition, the gap between the
fibers will be excessive, and liquid holding will be poor despite the high liquid
retention, and liquid tends to flow out of the nonwoven fabric in the use of the nonwoven
fabric. On the other hand, the single fiber fineness of less than 1.0 dtex is likely
invite insufficient processability in the carding step as well as reduced productivity.
[0037] The polyester fiber having an oblate multilobal cross-section preferably has a fiber
length of 30 to 64 mm in view of preventing the fiber falling off the nonwoven fabric.
The fiber length is more preferably 35 to 51 mm.
[0038] The nonwoven fabric of the present invention may additionally include a heat fusion
fiber. Inclusion of a heat fusion fiber in the nonwoven fabric enables improvement
of the morphological stability which is an important function for use in wiping operation
by the heat fusion of the heat fusion fiber. While the heat fusion fiber may be a
single component-heat fusion fiber, preferable embodiment is use of a composite-type
heat fusion fiber such as side-by-side or core-sheath type heat fusion fiber comprising
two or more resin components and including the parts not fused by the heat treatment
since the fiber strength is retained by the parts not fused by the heat treatment.
[0039] Exemplary components constituting the heat fusion fiber include combinations such
as 6-nylon and a polyethylene, a polypropylene and a polyethylene, a polypropylene
and an ethylene-vinyl acetate copolymer, a polyester and a polypropylene, a polyester
and a polyethylene, 6-nylon and 66-nylon, and a high density polyester and a low density
polyester. Preferable blend ratio of the heat fusion fiber is 5 to 20% by weight in
relation to the weight of the nonwoven fabric.
[0040] Next, the production method of the nonwoven fabric of the present invention is described.
[0041] The polyester fiber having an oblate multilobal cross-section and the cellulose fiber
are carded to form a fiber web. As described above, mixing ratio (weight ratio) of
the polyester fiber having an oblate multilobal cross-section to the cellulose fiber
is such that the polyester fiber having an oblate multilobal cross-section/cellulose
fiber is 20/80 to 80/20, and preferably 30/70 to 70/30.
[0042] Next, the fiber web formed by the carding is sent to the spunlacing step by a feed
lattice, where the web is processed into a sheet by interlacing using a high pressure
water jet. The nonwoven fabric after the spunlacing is sent to drying step by a conveyer.
When the nonwoven fabric includes the heat treatment fiber as described above, the
nonwoven fabric may also be subjected to a heat treatment simultaneously with the
drying at a temperature solely allowing the melting of the heat fusion fiber.
[0043] The thus produced nonwoven fabric exhibits excellent water absorption and water retention
as well as soft texture, and therefore, the sheet is well adapted for use as a nonwoven
fabric for human wiping and cosmetic use intended in the present invention.
[0044] More specifically, the sheet obtained from the nonwoven fabric produced as described
above exhibits excellent water absorption together with high holding of liquid such
as water and chemical solution as well as excellent bulkiness, softness, and texture,
and therefore, such sheet is particularly suitable for use as a nonwoven fabric used
for skin in cosmetic or cleansing purpose. When used for cosmetic purpose, the sheet
will exhibit high holding of the cosmetic liquid with releasability of the liquid
as needed. When used for cleansing purpose, it exhibits high wiping performance without
damaging the skin, and the wiped smudges are retained in the recesses on the fiber
surface, namely, within the nonwoven fabric. A sheet with high cleansing performance
without re-deposition is thereby realized.
[0045] Examples of the final application include baby wipes, wet tissues, cleansing sheets,
and facial sheets.
Examples
[0046] Next, the present invention is described in further detail by referring to the following
Examples which by no means limit the scope of the invention. The physical property
values in the Examples are the values measured by the following procedures, and the
values are average of 3 measurements.
[Evaluation method of the thickness of the nonwoven fabric]
[0047] 5 nonwoven fabrics each having a unit weight of 50 g/m
2 were laminated and the thickness of the laminate was measured with a vernier calliper.
[Evaluation method of liquid retention]
[0048] The evaluation was conducted according to water absorbency defined in JIS L 1907
7.2 (2010). A square test piece of 10 cm x 10 cm was cut out of the nonwoven fabric
having a unit weight of 50 g/m
2, and its mass (A) was measured. The test piece was immersed in ion exchanged water
for 30 seconds. The test piece was collected from the water by pinching a corner of
the test piece with forceps, and weight (B) after 1 minute was measured.
[0049] The liquid retention (C) is calculated by the following equation:

[Evaluation method of remaining liquid (liquid holding)]
[0050] The evaluation was conducted according to water absorbency defined in JIS L 1907
7.2 (2010). A square test piece of 10 cm x 10 cm was cut out of the nonwoven fabric
having a unit weight of 50 g/m
2, and its mass (A) was measured. The test piece was immersed in ion exchanged water
for 30 seconds. The test piece was collected from the water by pinching a corner of
the test piece with forceps, and weight (D) after 5 minutes was measured. The liquid
holding (E) is calculated by the following equation:

[Wiping ability]
[0051] A square test piece of 10 cm x 10 cm was cut out of the nonwoven fabric having a
unit weight of 50 g/m
2, and the test piece was folded into quarters before the use. The test piece was impregnated
with 3 times its weight of water. The wiping ability was evaluated by 5 test participants
according to the following criteria by wiping the lipstick applied to their arm with
the test piece. "A" was evaluated pass.
- A: successfully wiped off
- B: slight remaining of the lipstick
- C: the lipstick barely wiped off
[Texture]
[0052] A square test piece of 10 cm x 10 cm was cut out of the nonwoven fabric having a
unit weight of 50 g/m
2, and the test piece was folded into quarters before the use. The test piece was impregnated
with 3 times its weight of water. The texture was evaluated by 5 test participants
according to the following criteria by wiping their arm with the test piece. "A" was
evaluated pass.
- A: good texture
- B: slight discomfort after the wiping
- C: irritation after the wiping
[Touch (feel)]
[0053] A square test piece of 10 cm x 10 cm was cut out of the nonwoven fabric having a
unit weight of 50 g/m
2, and the test piece was folded into quarters before the use. The test piece was impregnated
with 3 times its weight of water. The touch was evaluated by 5 test participants according
to the following criteria by gripping the test piece. "A" was evaluated pass.
- A: soft feel
- B: slightly hard feel
- C: hard feel
[Example 1]
[0054] 20% by weight of a polyester fiber having oblate multilobal cross-section with 8
lobes (single-fiber fineness, 1.7 dtex; fiber length, 51mm) with degree of oblateness
of 2.1, degree of irregularity of 2.7, and lobe ratio of 0.8 and 80% by weight of
a rayon fiber (single-fiber fineness, 1.7 dtex; fiber length, 51 mm) were uniformly
mixed, and a carded fiber web having a unit weight of 60 g/cm
2 was produced by a method commonly used in the art. A sheet was then prepared by duplex
treatment with water jet (water pressure, 50 kg/cm
2; speed, 1 m/min; nozzle diameter, 0.1 mm; pitch, 0.6 mm; 834 holes; effective width,
500 mm), and the sheet was dried at a temperature of 120°C to obtain a nonwoven fabric
having a unit weight of 50 g/m
2. Fiber constitution of the nonwoven fabric is shown in Table 1, and the results of
the evaluation are shown in Table 2.
[Example 2]
[0055] 50% by weight of a polyester fiber having oblate multilobal cross-section with 8
lobes (single-fiber fineness, 1.7 dtex; fiber length, 51mm) with degree of oblateness
of 2.1, degree of irregularity of 2.7, and lobe ratio of 0.8 and 50% by weight of
a rayon fiber (single-fiber fineness, 1.7 dtex; fiber length, 51 mm) were uniformly
mixed, and a carded fiber web having a unit weight of 60 g/cm
2 was produced by a method commonly used in the art. A sheet was then prepared by duplex
treatment with water jet (water pressure, 50 kg/cm
2; speed, 1 m/min; nozzle diameter, 0.1 mm; pitch, 0.6 mm; 834 holes; effective width,
500 mm), and the sheet was dried at a temperature of 120°C to obtain a nonwoven fabric
having a unit weight of 50 g/m
2. Fiber constitution of the nonwoven fabric is shown in Table 1, and the results of
the evaluation are shown in Table 2.
[Example 3]
[0056] 80% by weight of a polyester fiber having oblate multilobal cross-section with 8
lobes (single-fiber fineness, 1.7 dtex; fiber length, 51mm) with degree of oblateness
of 2.1, degree of irregularity of 2.7, and lobe ratio of 0.8 and 20% by weight of
a rayon fiber (single-fiber fineness, 1.7 dtex; fiber length, 51 mm) were uniformly
mixed, and a carded fiber web having a unit weight of 60 g/cm
2 was produced by a method commonly used in the art. A sheet was then prepared by duplex
treatment with water jet (water pressure, 50 kg/cm
2; speed, 1 m/min; nozzle diameter, 0.1 mm; pitch, 0.6 mm; 834 holes; effective width,
500 mm), and the sheet was dried at a temperature of 120°C to obtain a nonwoven fabric
having a unit weight of 50 g/m
2. Fiber constitution of the nonwoven fabric is shown in Table 1, and the results of
the evaluation are shown in Table 2.
[Table 1]
| |
Example 1 |
Example 2 |
Example 3 |
| Polyester with oblate octalobal cross-section |
20 |
50 |
80 |
| Polyester with hexalobal cross-section (degree of oblateness, 1) |
|
|
|
| Polyester with trilobal (Y-shaped) cross-section |
|
|
|
| Polyester with substantially C-shaped cross-section |
|
|
|
| Polyester with circular cross-section |
|
|
|
| Rayon |
80 |
50 |
20 |
[Table 2]
| |
Example 1 |
Example 2 |
Example 3 |
| Thickness (mm) |
3.0 |
3.3 |
3.5 |
| Liquid retention (%) |
850 |
930 |
1110 |
| Liquid holding (%) |
44 |
32 |
25 |
| Wiping ability |
A |
A |
A |
| Texture |
A |
A |
A |
| Touch (feel) |
A |
A |
A |
[Comparative Example 1]
[0057] 15% by weight of a polyester fiber having oblate multilobal cross-section with 8
lobes (single-fiber fineness, 1.7 dtex; fiber length, 51mm) with degree of oblateness
of 2.1, degree of irregularity of 2.7, and lobe ratio of 0.8 and 85% by weight of
a rayon fiber (single-fiber fineness, 1.7 dtex; fiber length, 51 mm) were uniformly
mixed, and a carded fiber web having a unit weight of 60 g/cm
2 was produced by a method commonly used in the art. A sheet was then prepared by duplex
treatment with water jet (water pressure, 50 kg/cm
2; speed, 1 m/min; nozzle diameter, 0.1 mm; pitch, 0.6 mm; 834 holes; effective width,
500 mm), and the sheet was dried at a temperature of 120°C to obtain a nonwoven fabric
having a unit weight of 50 g/m
2. Fiber constitution of the nonwoven fabric is shown in Table 3, and the results of
the evaluation are shown in Table 4.
[Comparative Example 2]
[0058] 85% by weight of a polyester fiber having oblate multilobal cross-section with 8
lobes (single-fiber fineness, 1.7 dtex; fiber length, 51mm) with degree of oblateness
of 2.1, degree of irregularity of 2.7, and lobe ratio of 0.8 and 15% by weight of
a rayon fiber (single-fiber fineness, 1.7 dtex; fiber length, 51 mm) were uniformly
mixed, and a carded fiber web having a unit weight of 60 g/cm
2 was produced by a method commonly used in the art. A sheet was then prepared by duplex
treatment with water jet (water pressure, 50 kg/cm
2; speed, 1 m/min; nozzle diameter, 0.1 mm; pitch, 0.6 mm; 834 holes; effective width,
500 mm), and the sheet was dried at a temperature of 120°C to obtain a nonwoven fabric
having a unit weight of 50 g/m
2. Fiber constitution of the nonwoven fabric is shown in Table 3, and the results of
the evaluation are shown in Table 4.
[Comparative Example 3]
[0059] A carded fiber web having a unit weight of 60 g/cm
2 was produced from 100% by weight of a rayon fiber (single-fiber fineness, 1.7 dtex;
fiber length, 51 mm) by a method commonly used in the art. A sheet was then prepared
by duplex treatment with water jet (water pressure, 50 kg/cm
2; speed, 1 m/min; nozzle diameter, 0.1 mm; pitch, 0.6 mm; 834 holes; effective width,
500 mm), and the sheet was dried at a temperature of 120°C to obtain a nonwoven fabric
having a unit weight of 50 g/m
2. Fiber constitution of the nonwoven fabric is shown in Table 3, and the results of
the evaluation are shown in Table 4.
[Comparative Example 4]
[0060] 80% by weight of a polyester fiber having irregular cross-section with 6 lobes on
its periphery (single-fiber fineness, 1.7 dtex; fiber length, 51mm) with degree of
oblateness of 1.0 and 20% by weight of a rayon fiber (single-fiber fineness, 1.7 dtex;
fiber length, 51 mm) were uniformly mixed, and a carded fiber web having a unit weight
of 60 g/cm
2 was produced by a method commonly used in the art. A sheet was then prepared by duplex
treatment with water jet (water pressure, 50 kg/cm
2; speed, 1 m/min; nozzle diameter, 0.1 mm; pitch, 0.6 mm; 834 holes; effective width,
500 mm), and the sheet was dried at a temperature of 120°C to obtain a nonwoven fabric
having a unit weight of 50 g/m
2. Fiber constitution of the nonwoven fabric is shown in Table 3, and the results of
the evaluation are shown in Table 4.
[Comparative Example 5]
[0061] 80% by weight of a polyester fiber having irregular (Y-shaped) cross-section with
3 lobes on its periphery (single-fiber fineness, 1.7 dtex; fiber length, 51mm) and
20% by weight of a rayon fiber (single-fiber fineness, 1.7 dtex; fiber length, 51
mm) were uniformly mixed, and a carded fiber web having a unit weight of 60 g/cm
2 was produced by a method commonly used in the art. A sheet was then prepared by duplex
treatment with water jet (water pressure, 50 kg/cm
2; speed, 1 m/min; nozzle diameter, 0.1 mm; pitch, 0.6 mm; 834 holes; effective width,
500 mm), and the sheet was dried at a temperature of 120°C to obtain a nonwoven fabric
having a unit weight of 50 g/m
2. Fiber constitution of the nonwoven fabric is shown in Table 3, and the results of
the evaluation are shown in Table 4.
[Comparative Example 6]
[0062] 80% by weight of a polyester fiber having irregular C-shaped cross-section (single-fiber
fineness, 1.7 dtex; fiber length, 51mm) and 20% by weight of a rayon fiber (single-fiber
fineness, 1.7 dtex; fiber length, 51 mm) were uniformly mixed, and a carded fiber
web having a unit weight of 60 g/cm
2 was produced by a method commonly used in the art. A sheet was then prepared by duplex
treatment with water jet (water pressure, 50 kg/cm
2; speed, 1 m/min; nozzle diameter, 0.1 mm; pitch, 0.6 mm; 834 holes; effective width,
500 mm), and the sheet was dried at a temperature of 120°C to obtain a nonwoven fabric
having a unit weight of 50 g/m
2. Fiber constitution of the nonwoven fabric is shown in Table 3, and the results of
the evaluation are shown in Table 4.
[Comparative Example 7]
[0063] 80% by weight of a polyester fiber with circular cross-section (single-fiber fineness,
1.7 dtex; fiber length, 51mm) and 20% by weight of a rayon fiber (single-fiber fineness,
1.7 dtex; fiber length, 51 mm) were uniformly mixed, and a carded fiber web having
a unit weight of 60 g/cm
2 was produced by a method commonly used in the art. A sheet was then prepared by duplex
treatment with water jet (water pressure, 50 kg/cm
2; speed, 1 m/min; nozzle diameter, 0.1 mm; pitch, 0.6 mm; 834 holes; effective width,
500 mm), and the sheet was dried at a temperature of 120°C to obtain a nonwoven fabric
having a unit weight of 50 g/m
2. Fiber constitution of the nonwoven fabric is shown in Table 3, and the results of
the evaluation are shown in Table 4.
[Table 3]
| |
Comparative Example 1 |
Comparative Example 2 |
Comparative Example 3 |
Comparative Example 4 |
Comparative Example 5 |
Comparative Example 6 |
Comparative Example 7 |
| Polyester with oblate octalobal cross-section |
15 |
85 |
|
|
|
|
|
| Polyester with hexalobal cross-section (degree of oblateness, 1) |
|
|
|
80 |
|
|
|
| Polyester with trilobal (Y-shaped) cross-section |
|
|
|
|
80 |
|
|
| Polyester with substantially C-shaped cross-section |
|
|
|
|
|
80 |
|
| Polyester with circular cross-section |
|
|
|
|
|
|
80 |
| Rayon |
85 |
15 |
100 |
20 |
20 |
20 |
20 |
[Table 4]
| |
Comparative Example 1 |
Comparative Example 2 |
Comparative Example 3 |
Comparative Example 4 |
Comparative Example 5 |
Comparative Example 6 |
Comparative Example 7 |
| Thickness (mm) |
2.7 |
3.8 |
1.8 |
4.0 |
4.2 |
2.8 |
2.4 |
| Liquid retention (%) |
790 |
1140 |
700 |
1160 |
1200 |
810 |
780 |
| Liquid holding (%) |
48 |
22 |
55 |
21 |
19 |
27 |
29 |
| Wiping ability |
B |
A |
B |
A |
B |
B |
C |
| Texture |
A |
B |
A |
C |
C |
B |
B |
| Touch (feel) |
B |
A |
B |
C |
C |
B |
B |
[0064] As shown in Examples 1 to 3, the nonwoven fabric prepared from 20 to 80% by weight
of a polyester fiber having an oblate multilobal cross-section with 8 lobes on its
periphery and 20 to 80% by weight of rayon was confirmed to exhibit a high liquid
retention, namely, high capability of retaining liquid such as water and chemical
solution as well as low liquid holding, namely, capability of releasing the retained
liquid to enable efficient use of the liquid. High wiping ability as well as good
touch (feel) and texture were also confirmed.
[0065] On the other hand, as shown in Comparative Example 1, content of the cellulose fiber
in excess of 80% by weight results in the loss of bulkiness of the nonwoven fabric
despite the good texture, and this results in the reduced liquid retention. The liquid
holding is also high due to the retention of the chemical solution in the cellulose
fiber, and this may become the cause of poor release of the chemical solution.
[0066] In addition, as shown in Comparative Example 2, content of the polyester fiber having
an oblate multilobal cross-section in excess of 80% by weight invites loss of flexibility
realized by the cellulose fiber, and this results in the poor texture.
[0067] In contrast, as shown in Comparative Examples 3 to 7, use of other polyester fiber
having a non-flat irregular cross-section results in the drastically reduced liquid
holding despite increase in the liquid retention, and this will be the cause for liquid
flow during use of the nonwoven fabric due to the insufficient liquid holding in the
nonwoven fabric. In addition, non-oblate cross-section results in the hard feeling
and poor texture.