Technical Field
[0001] The present invention relates to a pile fabric with high softness that prevents pile
fibers from falling off, and a method for producing the same.
Background Art
[0002] Pile fabrics have been known as fabrics that are made to look like furs, and called
imitation furs, fake furs, boas, etc. The pile fabrics are constituted by pile knitting
or pile weave. Knitted piles are generally formed using seal-fraise knitting machines
or sliver knitting machines (circular knitting machines), and in either cases pile
fibers are cut. In the case of using double Russell machines (warp knitting machines),
knitted piles are formed by making a double ground structure while tangling the double
ground structure with binder yarns, and cutting the middle of the binder yarns. In
weaving, velvet looms or moquette looms are used to tangle a pair of upper and lower
ground structures and between the ground structures with binder yarns, and cut the
middle of the upper and lower base fabrics with a knife to obtain two woven fabrics
simultaneously. However, such woven and knitted fabrics, particularly knitted fabrics
such as high pile fabrics, have a problem of a large amount of falling-off of fibers.
[0003] In order to prevent the falling-off of fibers of pile fabrics, there have been a
proposal of mixing low-melting fibers into pile fibers (Patent Document 1), and a
proposal of mixing low-melting fibers into ground yarns constituting a ground structure
(Patent Documents 2-3). However, in these proposals, since the whole fabric is heated
at a temperature equal to or higher than the melting point of the low-melting fibers,
the entire ground structure or pile fibers are also fused, resulting in a coarse texture.
[0004] To cope with the above problem, Patent Document 4 proposes a pile fabric made from
specific fibers, which can prevent pile fibers from falling off without impairing
the texture of the piloerection surface by fusing only specific parts of the pile
fibers on the back surface side of the pile fabric.
Prior Art Documents
Patent Documents
Disclosure of Invention
Problem to be Solved by the Invention
[0006] However, in the pile fabric of Patent Document 4, the fusion of the pile fibers on
the back surface side of the pile fabric sometimes hardens the back surface of the
pile fabric, which accordingly hardens the pile fabric.
[0007] In order to solve the above problem, the present invention provides a pile fabric
having improved softness while preventing pile fibers from falling off in a pile fabric
in which at least parts of pile fibers located on the back surface side of the pile
fabric are fused, and a method for producing the same.
Means for Solving Problem
[0008] The present invention relates to a pile fabric that includes: a ground structure;
and pile fibers that are tangled with ground yarns constituting the ground structure
and that stand on a front surface side of the ground structure. The pile fibers include
at least one selected from the group consisting of acrylic fibers and modacrylic fibers
and have a lower softening point than fibers constituting the ground structure. Among
the pile fibers tangled with the ground yarns constituting the ground structure, the
pile fibers standing on the front surface side of the ground structure are not fused,
whereas at least parts of the pile fibers located on a back surface side of the ground
structure outside of the ground yarns constituting the ground structure are fused.
0.4 parts by weight or more of an organically-modified silicone-based softener is
adhered with respect to 100 parts by weight of the pile fibers located on a back surface
side of the pile fabric. The organically-modified silicone-based softener is at least
one selected from the group consisting of amino-modified silicone-based softeners,
epoxy-modified silicone-based softeners, and carboxyl-modified silicone-based softeners.
[0009] The present invention further relates to a method for producing the pile fabric described
above. The pile fabric includes: a ground structure; and pile fibers that are tangled
with ground yarns constituting the ground structure and that stand on a front surface
side of the ground structure. The pile fibers include at least one selected from the
group consisting of acrylic fibers and modacrylic fibers and have a lower softening
point than fibers constituting the ground structure. 0.4 parts by weight or more of
an organically-modified silicone-based softener is adhered with respect to 100 parts
by weight of the pile fibers located on a back surface side of the pile fabric. The
organically-modified silicone-based softener is at least one selected from the group
consisting of amino-modified silicone-based softeners, epoxy-modified silicone-based
softeners, and carboxyl-modified silicone-based softeners. The back surface side of
the pile fabric is subjected to heat sensitive sealing at a temperature equal to or
higher than the softening point of the pile fibers and lower than the softening point
of the fibers constituting the ground structure, so that among the pile fibers tangled
with the ground yarns constituting the ground structure, the pile fibers standing
on the front surface side of the ground structure are not fused, whereas at least
parts of the pile fibers located on a back surface side of the ground structure outside
of the ground yarns constituting the ground structure are fused.
[0010] The organically-modified silicone-based softener is preferably an amino-modified
silicone-based softener. The pile fibers are preferably modacrylic fibers. The ground
yarns are preferably polyester fiber yarns. It is preferred that 0.4 to 2.5 parts
by weight of the organically-modified silicone-based softener is adhered with respect
to 100 parts by weight of the pile fibers located on the back surface side of the
pile fabric.
Effect of the Invention
[0011] The present invention can provide a pile fabric having improved softness while preventing
the falling-off of pile fibers (pile fiber loss). Moreover, the production method
of the pile fabric of the present invention enables easy production of pile fabrics
having improved softness while preventing the pile fiber loss.
Brief Description of Drawings
[0012]
[FIG. 1] FIG. 1 is a schematic view for explaining a positional relationship between
ground yarns and pile fibers tangled with the ground yarns in high pile fabrics in
one embodiment of the pile fabric of the present invention.
[FIG. 2] FIG. 2 illustrates a production process showing an exemplary method for producing
the pile fabric of the present invention.
[FIG. 3] FIG. 3 is a schematic view for explaining a method for measuring the amount
of the fiber loss of pile fabrics in embodiments of the present invention.
[FIG. 4] FIG. 4 is a schematic cross-sectional view for explaining a method for evaluating
the softness of pile fabrics in embodiments of the present invention.
Description of the Invention
[0013] The present inventors repeatedly examined ways to improve the softness of pile fabrics
while preventing the pile fiber loss in pile fabrics that include as pile fibers at
least one selected from the group consisting of acrylic fibers and modacrylic fibers,
wherein at least parts of the pile fibers among the pile fibers located on the back
surface side of the pile fabric outside of the ground yarns are fused. As a result,
the inventors found that it is possible to improve the softness of pile fabrics while
preventing the pile fiber loss by adhering 0.4 parts by weight or more of an organically-modified
silicone-based softener with respect to 100 parts by weight of the pile fibers on
the back surface side of the pile fabric, the organically-modified silicone-based
softener being at least one selected from the group consisting of amino-modified silicone-based
softeners, epoxy-modified silicone-based softeners, and carboxyl-modified silicone-based
softeners. Thus, the present invention is achieved. Softeners (also called soft finishing
agents) generally impart softness and smoothness of fiber surfaces. In the present
application, it was surprisingly found that it is possible to improve the softness
of pile fabrics while preventing the pile fiber loss by adhering a given amount of
a specific softener to the pile fibers located on the back surface side of the pile
fabrics.
[0014] A pile fabric of the present invention is a pile fabric including: a ground structure;
and pile fibers that are tangled with ground yarns constituting the ground structure
and that stand on the front surface side of the ground structure. There is no particular
limitation on the pile fabric, and examples thereof include high pile fabrics, boa
fabrics, and tufted carpets. The pile fabric of the present invention is particularly
suitable for high pile fabrics, which often cause the pile fiber loss. The high pile
fabrics are not particularly limited, but they are preferably, e.g., fabrics with
a pile fiber length of 15 to 100 mm at piloerection portion.
[0015] The high pile fabrics are pile knitted fabrics, and the ground structure is stockinette.
Specifically, the high pile fabrics include: a stockinette ground structure; and pile
fibers that are tangled with ground yarns constituting the ground structure while
standing on a front surface side of the ground structure. Since the ground structure
of the high pile fabrics is stockinette, the structure can have excellent stretchability.
Stockinette is generally a fabric formed by making a loop with one or more yarns,
hooking the loop to make a next new loop, and continuously making loops in a planar
shape. The weft stockinette stitch, in which knitting proceeds in the weft direction,
forms a planar fabric by making loops with yarns reciprocatingly from side to side,
or forms a tubular fabric by making loops spirally. The warp stockinette stitch forms
a fabric by making loops with a plurality of orderly arranged warp yarns while intermeshing
the yarns with adjacent left and right warp yarns via loops. Examples of the weft
stockinette stitch include plain stitch, rib stitch, and purl stitch. Examples of
the warp stockinette stitch include Denbigh stitch, cord stitch, atlas stitch, and
chain stitch. The stitch of the ground structure of the high pile fabrics is preferably
weft stockinette stitch from the viewpoint of marketability and productivity.
[0016] In the present invention, the arrangement of the pile fibers with respect to the
stockinette ground structure may be, e.g., an arrangement in which the pile fibers
are tangled with all of the loops of the ground yarns constituting the stockinette
ground structure, or an arrangement in which the pile fibers are not tangled with
some of the loops of the ground yarns constituting the stockinette ground structure
in the wale direction and/or course direction.
[0017] Any fibers having a higher softening point than the pile fibers can be used as the
fibers constituting the ground structure, i.e., the fibers constituting the ground
yarns. Examples of the fibers constituting the ground structure include polyester
fibers and cellulose-based fibers. The polyester fibers may be, e.g., synthetic fibers
obtained by spinning a resin composition containing a polyester resin such as polyethylene
terephthalate. The cellulose-based fibers may be, e.g., cotton. The ground yarns are
preferably polyester fiber yarns from the viewpoint of preventing the pile fiber loss
while improving the softness of pile fabrics more effectively.
[0018] The pile fibers have a lower softening point than the fibers constituting the ground
structure. Among the pile fibers tangled with the ground yarns, part or all of the
pile fibers located on the back surface side of the ground structure outside of the
ground yarns are fused, whereas the pile fibers standing on the front surface side
of the ground structure are not fused. Thought there is no particular limitation on
the means for fusing the pile fibers, it is preferable to subject the pile fabric
to heat sensitive sealing from the back surface side of the pile fabric at a temperature
equal to or higher than the softening point of the pile fibers and lower than the
softening point of the fibers constituting the ground structure.
[0019] The pile fibers include acrylic fibers and/or modacrylic fibers, and thus a pile
fabric with an excellent texture can be obtained. If the pile fibers are thermoplastic
fibers, and a polishing process is performed at a temperature equal to or higher than
the melting point or softening point of the thermoplastic fibers, generally, the pile
fibers on the front surface side of the pile fabric burn or melt, and a pile fabric
with a favorable appearance and texture cannot be obtained. If the polishing process
is performed at a temperature equal to or lower than the glass transition point of
the thermoplastic fibers, crimps of the pile fibers on the front surface side of the
pile fabric are not straightened, and a pile fabric with a favorable appearance and
texture cannot be obtained. On the other hand, crimps of acrylic fibers and modacrylic
fibers can be straightened at temperatures lower than the melting point. The acrylic
fibers and modacrylic fibers have a glass transition point of about 100°C and a softening
point of about 150 to 230°C. If the pile fibers are acrylic fibers and/or modacrylic
fibers, the polishing process can be performed at temperatures equal to or higher
than the glass transition point and equal to or lower than the softening points, e.g.,
at temperatures of 100 to 150°C. Moreover, there is a tendency that crimps of the
acrylic fibers and modacrylic fibers are straightened more easily than crimps of fibers
of other materials, and thus a pile fabric with a favorable appearance and texture
can be obtained.
[0020] The pile fibers may contain synthetic fibers that are produced by spinning a resin
composition containing a polyester resin (e.g., polyethylene terephthalate, polytrimethylene
terephthalate), or other fibers, as long as the effects of the present invention are
not impaired.
[0021] The pile fibers are not particularly limited as long as the softening point is lower
than the softening point of the fibers constituting the ground yarns. A difference
between the softening point of the fibers constituting the ground yarns and the softening
point of the pile fibers is preferably 10°C or more, more preferably 20°C or more,
and particularly preferably 30°C or more. By setting the difference to be 10°C or
more, it becomes easier to subject only part or all of the pile fibers located on
the back surface side of the pile fabric outside of the ground yarns to heat sensitive
sealing for fusion, and not to subject the pile fibers standing on the front surface
side of the ground structure to heat sensitive sealing.
[0022] The pile fibers may be fibers that are all softened at a predetermined temperature,
or mixed fibers including fibers softened at different temperatures. When the pile
fibers are mixed fibers including fibers softened at different temperatures, it is
preferable to mix fibers softened at a relatively low temperature in an amount of
20% by weight (wt%) or more, more preferably 50 wt% or more, and to subject the fibers
softened at a relatively low temperature to heat sensitive sealing.
[0024] In embodiments of the present invention, the acrylic fibers are fibers made up of
a polymer obtained by polymerizing a composition containing acrylonitrile in an amount
of 85 wt% or more and other copolymerizable monomers in an amount of 15 wt% or less.
The modacrylic fibers are fibers made up of a polymer obtained by polymerizing a composition
containing acrylonitrile in an amount of 35 wt% or more and less than 85 wt% and other
copolymerizable monomers in an amount of more than 15 wt% and 65 wt% or less.
[0025] In embodiments of the present invention, there is no particular limitation on the
copolymerizable monomers as long as they can be copolymerized with acrylonitrile.
Examples of the copolymerizable monomers include: vinyl halides represented by vinyl
chloride and vinyl bromide; vinylidene halides represented by vinylidene chloride
and vinylidene bromide; sulfonic acid-containing monomers represented by allylsulfonic
acid, methallylsulfonic acid, styrenesulfonic acid, isoprenesulfonic acid, 2-acrylamido-2-methylpropanesulfonic
acid, and their metal salts and amine salts; lower alkyl esters of acrylic acid and
methacrylic acid, N-alkyl substituted aminoalkyl esters, N,N-alkyl substituted aminoalkyl
esters and glycidyl esters ; acrylamide, methacrylamide, and their N-alkyl substituted
products and N,N-alkyl substituted products; anionic vinyl monomers such as carboxyl
group-containing vinyl monomers represented by acrylic acid, methacrylic acid and
itaconic acid and their sodium, potassium or ammonium salts; cationic vinyl monomers
represented by quaternary aminoalkyl esters of acrylic acid and quaternary aminoalkyl
esters of methacrylic acid; vinyl group-containing lower alkyl ethers; vinyl group-containing
lower carboxylic acid esters represented by vinyl acetate; and styrene. These monomers
may be used alone or in a combination of two or more kinds.
[0026] As the copolymerizable monomers, it is preferable to use one or more kinds of monomers
selected from the group consisting of vinyl halides, vinylidene halides, and metal
salts of sulfonic acid-containing monomers, and it is more preferable to use one or
more kinds of monomers selected from the group consisting of vinyl chloride, vinylidene
chloride, and sodium styrenesulfonate.
[0027] The pile fibers are preferably modacrylic fibers, more preferably modacrylic fibers
obtained by polymerizing a composition containing acrylonitrile in an amount of 35
wt% or more and less than 85 wt%, and vinyl chloride and/or vinylidene chloride and
other copolymerizable monomers in a total amount of more than 15 wt% and 65 wt% or
less.
[0028] In embodiments of the present invention, there is no particular limitation on the
combination of the fibers constituting the ground yarns and the pile fibers, as long
as the above conditions are satisfied. The following describes specific examples of
the combination.
[0029] When the fibers constituting the ground yarns are fibers of, e.g., polyethylene terephthalate
(PET, softening point: about 258°C), the pile fibers are preferably modacrylic fibers
or mixed fibers of modacrylic fibers and acrylic fibers. The following are favorably
used as the modacrylic fibers.
- (1) Vinyl chloride-aciylonitrile fiber (e.g., trade name " Kanekalon" manufactured
by Kaneka Corporation, softening point: 150 to 220°C, literature value)
- (2) Vinylidene chloride-acrylonitrile fiber (softening point: 150 to 220°C, literature
value)
[0030] When the fibers constituting the ground yarns are fibers of, e.g., cotton (tree cotton,
no softening point), the pile fibers are preferably acrylic fibers. An example of
the acrylic fibers is "Exlan K691" (trade name) manufactured by Exlan Co., Ltd., (softening
point: 190 to 232°C, literature value).
[0031] An organically-modified silicone-based softener that is at least one selected from
the group consisting of amino-modified silicone-based softeners, epoxy-modified silicone-based
softeners, and carboxyl-modified silicone-based softeners, is adhered to at least
the pile fibers located on the back surface side of the pile fabric. The organically-modified
silicone-based softener such as an amino-modified silicone-based softener may or may
not be adhered to the pile fibers on the front surface side of the pile fabric. The
adhesion amount of the organically-modified silicone-based softener such as an amino-modified
silicone-based softener to the pile fibers located on the back surface side of the
pile fabric is preferably larger than the adhesion amount of the organically-modified
silicone-based softener such as an amino-modified silicone-based softener to the pile
fibers located on the front surface side of the pile fabric, from the viewpoint of
preventing the fiber loss while improving the softness of the pile fabric more effectively.
Hereinafter, the "organically-modified silicone-based softener" refers to at least
one selected from the group consisting of amino-modified silicone-based softeners,
epoxy-modified silicone-based softeners, and carboxyl-modified silicone-based softeners
unless otherwise specified. There is no particular limitation on the amino-modified
silicone-based softeners as long as they are softeners containing as a main component
a polysiloxane containing an amino functional group. There is no particular limitation
on the epoxy-modified silicone-based softeners as long as they are softeners containing
as a main component a polysiloxane containing an epoxy functional group. There is
no particular limitation on the carboxyl-modified silicone-based softeners as long
as they are softeners containing as a main component a polysiloxane containing an
epoxy functional group. Here, the "main component" refers to a component contained
in an amount of preferably 40 wt% or more, more preferably 50 wt% or more, further
preferably 60 wt% or more, and still further preferably 70 wt% or more, with respect
to the total weight of the solid content in the softener. Softeners other than the
organically-modified silicone-based softener may be adhered to the pile fibers on
the back surface side and/or the front surface side of the pile fabric, as long as
the effects of the present invention are not impaired.
[0032] The organically-modified silicone-based softener is preferably an ammo-modified silicone-based
softener from the viewpoint of preventing the pile fiber loss while improving the
softness of the pile fabric more effectively. The amino-modified silicone-based softener
is not particularly limited, and may be a solution in which an amino-modified polysiloxane,
which is commonly used as a soft finishing agent for fibers, is dispersed by a method
such as emulsification. In the ammo-modified polysiloxane to be used herein, amino
functional groups may be attached to one or both terminals of the polysiloxane (main
chain), or attached to the side chains, or attached to the terminals and the side
chains. Though there is no particular limitation on the structure of the amino functional
groups, the examples include a monoamine type, a diamine type, a triamine type, and
a polyamine type. Though there is no particular limitation on the amino-modified silicone-based
softener, it is possible to use marketed softeners such as "Matsumoto Silicone Softener
N-20" manufactured by Matsumoto Yushi-Seiyaku Co., Ltd., "POLON-MF-14" manufactured
by Shin-Etsu Chemical Co., Ltd., and "TSF4702" manufactured by Momentive Performance
Materials Inc.
[0033] In the pile fabric in which at least parts of the pile fibers located on the back
surface side of the pile fabric outside of the ground yarns are fused, generally,
the softness of the back surface of the pile fabric is enhanced by adhering a backing
resin such as an acrylic ester-based resin used for back coating of pile fabrics,
to the back surface of the pile fabric. Meanwhile, in the present invention, the softness
of the pile fabric is enhanced by adhering the organically-modified silicone-based
softener such as an amino-modified silicone-based softener to the pile fibers located
on the back surface side of the pile fabric without adhering a backing resin to the
back surface of the pile fabric. Moreover, the touch (softness, low factional properties)
of the back surface of the pile fabric improves by adhering the organically-modified
silicone-based softener to the pile fibers located on the back surface side of the
pile fabric without adhering a backing resin to the back surface of the pile fabric.
[0034] There is no particular limitation on the adhesion amount of the organically-modified
silicone-based softener as long as 0.4 parts by weight or more of the organically-modified
silicone-based softener is adhered with respect to 100 parts by weight of the pile
fibers on the back surface side of the pile fabric. However, the adhesion amount of
the organically-modified silicone-based softener is preferably 0.4 to 2.5 parts by
weight, more preferably 0.4 to 2.0 parts by weight, and further preferably 0.4 to
1.5 parts by weight, with respect to 100 parts by weight of the pile fibers located
on the back surface side of the pile fabric. Within the above range of the adhesion
amount of the organically-modified silicone-based softener, it is possible to prevent
the pile fiber loss while improving the softness of the pile fabric more effectively.
The adhesion amount of the organically-modified silicone-based softener such as an
amino-modified silicone-based softener in the pile fibers can be determined by, e.g.,
X-ray fluorescence analysis. For example, the adhesion amount of the amino-modified
silicone-based softener can be determined by quantifying the Si element in accordance
with X-ray fluorescence analysis using a wavelength dispersion type X-ray fluorescence
analyzer, and creating the calibration curve. Specifically, with use of an X-ray fluorescence
spectrometer RIX 3100 (manufactured by Rigaku Corporation), the Si element is analyzed
under the following conditions: Rh tube (tube current: 50 mA- tube voltage: 50 kV),
measurement diameter: 30 mmφ, analyzing crystal: pentaerythritol (PET), and 2θ angle:
106 to 112°, and first, a calibration curve is created using a sample whose amino-modified
silicone-based softener content is known. Next, the Si element of a measurement sample
(thickness: 3 mm, diameter: 30 mm) is analyzed which is obtained by molding fibers
to be measured (e.g., fibers on the back surface side of the pile fabric other than
the ground yarns (i.e., pile files)) with pressure using a press (tablet molding machine).
The adhesion amount of the amino-modified silicone-based softener can be calculated
by substituting the obtained Si detection count into a calibration curve equation.
[0035] It is possible to use a backing resin as long as the effects of the present invention
are not impaired. Any backing resin that is commonly used for back coating of pile
fabrics can be used as the backing resin. Examples of the backing resin include acrylic
ester-based resins and polyurethane-based resins. In the case of using the backing
resin, it is preferable to impregnate the back surface of the pile fabric with the
backing resin prior to a heat sensitive sealing step in the production method of the
pile fabric to be described later. The impregnation of the backing resin can be performed
using, e.g., latexes, emulsions, and dispersions of acrylic ester-based resins and
polyurethane-based resins. The backing resin may be used alone or in a combination
of two or more kinds.
[0036] Hereinafter, the pile fabric of the present invention will be described with reference
to the drawings. FIG. 1 is a schematic view for explaining a positional relationship
between ground yarns and pile fibers tangled with the ground yarns in a high pile
fabric in one embodiment of the pile fabric of the present invention. As illustrated
in FIG. 1, a high pile fabric 5 includes: ground yarns 1 constituting stockinette
loops 6; and pile fibers 2 that are tangled with the loops 6 of the ground yarns 1
and that are opened on a front surface side 7 of a ground structure (high pile fabric
5), thereby forming raised piles 3. Further, at least parts of the pile fibers 2 located
on the back surface side 8 of the ground structure (high pile fabric 5) outside of
the ground yarns 1 are bonded to the ground yarns 1 by heat sensitive sealing, thereby
forming a heat sensitive sealing part 4. An organically-modified silicone-based softener
that is adhered to the back surface of the pile fabric is not illustrated. FIG. 1
substantially illustrates a schematic positional relationship in which the pile fibers
2 are placed under the ground yarns 1. The "outside of the ground yarns 1" in this
drawing is substantially the portion under the ground yarns 1.
[0037] Hereinafter, a method for producing the pile fabric of the present invention will
be described.
[0038] First, pile fibers including at least one selected from the group consisting of acrylic
fibers and modacrylic fibers and ground yarns having a higher softening point than
the pile fibers are used to produce, in an ordinary method, a pile fabric that includes:
a ground structure; and pile fibers that are tangled with ground yarns constituting
the ground structure and that stand on a front surface side of the ground structure.
The pile fibers are preferably composed of acrylic fibers and/or modacrylic fibers.
In this step, if pile fibers to which an organically-modified silicone-based softener
is adhered are used as the pile fibers, it is possible to omit a step of adhering
the organically-modified silicone-based softener such as an amino-modified silicone-based
softener to the back surface of the pile fabric (described later), or it is possible
to further apply an organically-modified silicone-based softener. A method for adhering
the organically-modified silicone-based softener such as an amino-modified silicone-based
softener to the pile fibers is not particularly limited, and any known method can
be adopted appropriately. For example, the pile fibers may be impregnated with or
sprayed with the organically-modified silicone-based softener. For simplifying the
step, the adhesion of the organically-modified silicone-based softener to the pile
fibers can be performed simultaneously with dyeing. Of course, the adhesion can be
performed as a separate step from dyeing. In this case, it is preferable to perform
the dyeing step first and then adhere the organically-modified silicone-based softener
to the pile fibers, from the viewpoint of improving the softness of the pile fabric.
The organically-modified silicone-based softener may be used alone or in a combination
of two or more kinds. As a material of the pile fabric, marketed fibers to which an
organically-modified silicone-based softener (e.g., amino-modified silicone-based
softener) is adhered may be used. In the case of using such marketed fibers to which
an organically-modified silicone-based softener is adhered as the pile fibers, an
organically-modified silicone-based softener may be adhered further to the fibers
before production of the pile fabric.
[0039] Next, the above organically-modified silicone-based softener such as an amino-modified
silicone-based softener is adhered to the back surface of the pile fabric. Thereby,
the organically-modified silicone-based softener is adhered to the pile fibers on
the back surface side of the pile fabric. A method for adhering the organically-modified
silicone-based softener such as an amino-modified silicone-based softener to the back
surface of the pile fabric is not particularly limited, and any known method can be
adopted appropriately. For example, the back surface of the pile fabric may be impregnated
with or sprayed with the organically-modified silicone-based softener. The organically-modified
silicone-based softener may be used alone or in a combination of two or more kinds.
[0040] Softeners generally impart softness and smoothness to fiber surfaces. In the present
application, surprisingly, in the pile fabric that include as pile fibers at least
one selected from the group consisting of acrylic fibers and modacrylic fibers, wherein
at least parts of the pile fibers among the pile fibers located on the back surface
side of the pile fabric outside of the ground yarns are fused, it is possible to improve
the softness of the pile fabric while preventing the pile fiber loss by adhering 0.4
parts by weight or more of the above organically-modified silicone-based softener
with respect to 100 parts by weight of the pile fibers on the back surface side of
the pile fabric. The reason for this is uncertain, but the following are considered.
By adhering the organically-modified silicone-based softener to the pile fibers on
the back surface side of the pile fabric and subjecting the back surface side of the
pile fabric to heat sensitive sealing at a temperature equal to or higher than the
softening point of the pile fibers and lower than the softening point of the fibers
constituting the ground structure (described later), functional groups such as terminal
amino groups in the organically-modified silicone-based softener, which is adhered
to the pile fibers on the back surface side of the pile fabric, are cross-linked.
After production of the pile fabric using pile fibers to which an organically-modified
silicone-based softener is not adhered or pile fibers to which an organically-modified
silicone-based softener is adhered, preferably an organically-modified silicone-based
softener is adhered to the back surface side of the pile fabric from the viewpoint
of preventing the pile fiber loss while improving the softness of the pile fabric
more effectively.
[0041] Next, the back surface side of the pile fabric is subjected to heat sensitive sealing
at a temperature equal to or higher than the softening point of the pile fibers and
lower than the softening point of the fibers constituting the ground structure. Thereby,
the pile fibers standing on the front surface side of the ground structure are not
fused, whereas part or all of the pile fibers located on the back surface side of
the ground structure outside of the ground yarns constituting the ground structure
are fused. The heat sensitive sealing can be performed, e.g., by arranging the back
surface side of the pile fabric so as to come into contact with a heating roller or
hot plate and applying pressure by a rubber roller. By using the heating roller or
hot plate, the heat sensitive sealing can be performed in a short time, and at least
parts of the pile fibers located on the back surface side of the ground structure
outside of the ground yarns can be bonded by heat sensitive sealing. Further, since
the pile fabric is not heated to the extent that the pile fibers on the front surface
side of the pile fabric melt, the pile fibers standing on the front surface side of
the ground structure do not melt.
[0042] During and/or after heat sensitive sealing from the back surface side of the pile
fabric, preferably, a side of the pile fabric on which the pile fibers stand is cooled.
Moreover, after heat sensitive sealing from the back surface side of the pile fabric,
preferably, the back surface side of the pile fabric is cooled. As the cooling means,
preferably, the front surface and/or the back surface of the pile fabric are cooled
with a cooling roller in which water of 50°C or lower flows. The temperature of the
water flowing inside the cooling roller is preferably 10 to 40°C, more preferably
10 to 35°C, and further preferably 15 to 30°C, from the viewpoint of the cooling efficiency
and productivity. Such cooling can maintain the dimensional stability of the pile
fabric and reduce heat damage to the pile fibers.
[0043] The heat sensitive sealing in one example of the production method of the pile fabric
of the present invention will be described more specifically with reference to the
drawing.
[0044] FIG. 2 illustrates a production process schematically showing a heat sensitive sealing
step of a pile fabric performed at a predetermined temperature from the back surface
side of the pile fabric. The heat sensitive sealing, specifically, a processing device
10 to be used in the heat sensitive sealing, includes a heating roller 11 that is
coated with a fluorocarbon resin such as polytetrafluoroethylene, a cooling rubber
roller 12 in which cooling water of 30°C flows and that applies pressure to the heating
roller 11, a metal cooling roller 13 in which cooling water of 30°C flows and that
applies pressure to the cooling rubber roller 12, a metal cooling roller 14 in which
cooling water of 30°C flows, and a guide roller 15. A raw pile fabric (a high pile
fabric to which an organically-modified silicone-based softener is adhered) 18 is
led out from a container 16 and supplied so that a back surface 18b of the fabric
18 comes into contact with the heating roller 11 and a front surface (piloerection
side) 18a thereof comes into contact with the cooling rubber roller 12. After the
heat sensitive sealing, the back surface 18b is cooled with the metal cooling roller
14. A pile fabric 19 after this processing is contained in a container 17. Note that
the device for the heat sensitive sealing is not limited to the processing device
shown in FIG. 2, and may be a device partially modified from the processing device
shown in FIG. 2, a hot plate, or other devices. For example, a rubber roller not for
cooling may be used instead of the cooling rubber roller 12. The metal cooling roller
13 may be omitted. In the heat sensitive sealing, the heating temperature is not particularly
limited as long as it is equal to or higher than the softening point of the pile fibers
and lower than the softening point of the fibers constituting the ground yarns. It
is preferred that the pressure force is 0.01 to 100 Kgf/cm
2 (0.98 kPa to 9.8 MPa) in linear pressure, the supply rate of the raw pile fabric
is 0.1 to 20 m/minute, and the contact time with heater (e.g., heating roller) is
1 to 60 seconds. It is more preferred that the pressure force is 2.0 to 50 Kgf/cm
2 (0.20 to 4.9 MPa) in linear pressure, and the contact time with the heater is 1 to
10 seconds, from the viewpoint of reducing damages on the front surface of the pile
fabric.
[0045] In the case of the high pile fabric, the high pile fabric shrinks in a wale direction
during the heat sensitive sealing. Therefore, the high pile fabric may be drawn in
the wale direction after the heat sensitive sealing.
[0046] As the drawing, the high pile fabric is drawn in the wale direction by holding both
ends (selvages) of the high pile fabric in the wale direction so that the draw ratio
in the wale direction (length) will be preferably about 5 to 20%, more preferably
about 7 to 15%, and further preferably about 8 to 12%. The draw ratio in the wale
direction (length) is expressed by the formula below.

[0047] When heat is applied during the drawing, the temperature of the drawing is preferably
90 to 150°C, more preferably 100 to 130°C, and further preferably 105 to 120°C.
[0048] Such drawing can be performed using known devices such as a tenter. The tenter, generally
used for heat setting, heats fabrics at a predetermined temperature while holding
both selvages of the fabrics to widen the fabrics to a predetermined width. However,
the above heating is not essential in the present invention. Exemplary methods for
holding the selvages of fabrics in the tentor include a clip tentor method and a pin
tentor method, and both of them can be used. The pin tentor method is preferred from
the viewpoint of step stability and/or productivity.
[0049] In the case of performing the drawing while heating the high pile fabric, it is preferable
to set a minimum temperature and a minimum volume of air necessary for the drawing
to prevent the surfaces of the high pile fabric from being damaged.
[0050] The pile fabric of the present invention can prevent the fiber loss. The average
amount of the fiber loss measured in accordance with the method below is preferably
4.0 g/m
2 or less, more preferably 3.0 g/m
2 or less, and further preferably 2.0 g/m
2 or less. The maximum amount of the fiber loss measured in accordance with the method
below is preferably 5.0 g/m
2 or less, more preferably 4.0 g/m
2 or less, and further preferably 3.0 g/m
2 or less.
[0051] A distance at 90° of the pile fabric of the present invention measured in accordance
with the method below is preferably 50 mm or less, more preferably 45 mm or less,
from the viewpoint of excellent softness.
Examples
[0052] Hereinafter, the present invention will be described more specifically by way of
examples. Note that the present invention is not limited to the examples below.
<Measurement method>
1. Amount of fiber loss
[0053] As illustrated in FIG. 3, a pile fabric 21 (length: 280 mm, width: 210 mm) was placed
on an inclined surface of a metal plate 22 so that the pile direction of the fabric
would be oriented toward the upper side of the inclined surface. The metal plate 22
arranged obliquely had an inclination angle a of 30°. An adhesive tape 23 (Scotch
No. 850 manufactured by 3M company, width: 25 mm) cut in a length of 100 mm was stuck
on the surface of the pile fabric 21, to which a load of 1.5 g/cm
2 was applied for one minute from the top of the adhesive tape 23 (not illustrated).
Then, the adhesive tape 23 was continuously peeled off from the pile fabric 21 from
an end of the tape 23 located at the upper part of the inclined surface. The weight
(g) of the fibers attached to the adhesive tape was measured, and the weight of the
fibers per area of the adhesive tape (g/m
2) was calculated to determine the amount of the fiber loss. The amounts of the fiber
loss at any of three sections in the pile fabric were measured and calculated as described
above to determine the average amount of the fiber loss and the maximum amount of
the fiber loss.
2. Evaluation of fiber loss
[0054] The fiber loss of the pile fabric was ranked into the following four grades based
on the amount of the fiber loss. The evaluations of S, A, and B mean pass, and the
evaluation of C means fail.
S: The average amount of the fiber loss is 2.0 g/m2 or less, and the maximum amount of the fiber loss is 3.0 g/m2 or less.
A: The average amount of the fiber loss is more than 2.0 g/m2 and 3.0 g/m2 or less, and the maximum amount of the fiber loss is more than 3.0 g/m2 and 4.0 g/m2 or less.
B: The average amount of the fiber loss is more than 3.0 g/m2 and 4.0 g/m2 or less, and the maximum amount of the fiber loss is more than 4.0 g/m2 and 5.0 g/m2 or less.
C: The average amount of the fiber loss is more than 4.0 g/m2, and the maximum amount of the fiber loss is more than 5.0 g/m2 (failure level)
(Softness of pile fabric)
[0055]
- (1) The pile fabric was cut in the warp direction into a width of 20 mm to obtain
a cloth piece having a length of 200 mm and a width of 20 mm.
- (2) As illustrate in FIG. 4A, the cloth piece 31 of the pile fabric was arranged on
a horizontal board 32 (width: 600 mm, length: 600 mm) made from melamine resin. Next,
the cloth piece 31 of the pile fabric was gradually slid out of the horizontal board
32 along the pile direction of the pile fabric.
- (3) As illustrated in FIG. 4B, the cloth piece 31 of the pile fabric was slid until
a tangent 41 and the horizontal board 32 formed an angle a of 90°. The tangent 41
was drawn to the tip of the cloth piece 31 of the pile fabric extending out of the
horizontal board 32.
- (4) A distance L (distance at 90°) of the cloth piece 31 of the pile fabric sliding
out from the horizontal board 32 was measured to evaluate the softness of the pile
fabric in accordance with the following criteria.
- A: The distance at 90° is less than 50 mm (the pile fabric is very soft).
- B: The distance at 90° is 50 mm or more and 55 mm or less (the pile fabric is soft).
- C: The distance at 90° exceeds 55 mm (the pile fabric is hard).
<Fibers>
1. Pile fibers
[0056]
- (1) Trade name "Kanekalon (registered trademark) ELP" (manufactured by Kaneka Corporation):
modacrylic fiber (vinyl chloride-acrylonitrile fiber), softening point: 180 to 190°C,
fineness: 27 dtex, cut length: 102 mm (hereinafter, referred to as ELP simply), with
no adhesion of an amino-modified silicone-based softener
- (2) Trade name "Kanekalon (registered trademark) AH" (manufactured by Kaneka Corporation):
modacrylic fiber (vinyl chloride-acrylonitrile fiber), softening point: 180 to 190°C,
fineness: 7.8 dtex, cut length: 76 mm (hereinafter, referred to as AH7.8 simply),
with adhesion of 0.3 parts by weight of an amino-modified silicone-based softener
to 100 parts by weight of fibers (analysis value calculated from X-ray fluorescence
analysis)
- (3) Trade name "Kanekalon (registered trademark) AH" (manufactured by Kaneka Corporation):
modacrylic fiber (vinyl chloride-acrylonitrile fiber), softening point: 180 to 190°C,
fineness: 5.6 dtex, cut length: 51 mm (hereinafter, referred to as AH5.6 simply),
with adhesion of 0.3 parts by weight of an amino-modified silicone-based softener
to 100 parts by weight of fibers (analysis value calculated from X-ray fluorescence
analysis)
- (4) Trade name "Kanekalon (registered trademark) MCS" (manufactured by Kaneka Corporation):
modacrylic fiber (vinyl chloride-acrylonitrile fiber), softening point: 180 to 190°C,
fineness: 4.4 dtex, cut length: 32 mm (hereinafter, referred to as MCS simply), with
no adhesion of an amino-modified silicone-based softener
[0057] In the above, the adhesion amount of the amino-modified silicone-based softener in
the modacrylic fibers was determined by quantifying the Si element in accordance with
X-ray fluorescence analysis using a wavelength dispersion type X-ray fluorescence
analyzer, and creating the calibration curve. Specifically, with use of an X-ray fluorescence
spectrometer RIX 3100 (manufactured by Rigaku Corporation), the Si element was analyzed
under the following conditions: Rh tube (tube current: 50 mA - tube voltage: 50 kV),
measurement diameter: 30 mmφ, analyzing crystal: pentaerythritol (PET), and 2θ angle:
106 to 112°, and first, a calibration curve was created using a sample whose amino-modified
silicone-based softener content was known. Next, the Si element of a measurement sample
(thickness: 3 mm, diameter: 30 mm) was analyzed which was obtained by molding fibers
to be measured with pressure using a press (tablet molding machine). The adhesion
amount of the amino-modified silicone-based softener was calculated by substituting
the obtained Si detection count into a calibration curve equation.
2. Ground structure constituent fibers (ground yarns)
[0058] A multifilament with a total fineness of 334 dtex (a fiber yarn composed of two filaments,
each filament having a fineness of 167 dtex and composed of 50 polyester single fibers)
was used. The softening point was 258°C.
[0059] The softening point of the fibers is a temperature determined in the following manner.
1g of fibers is opened, placed on a hot plate heated to a predetermined temperature,
and pressurized with a pressure roller at 0.07 Kgf/cm
2 (nip pressure) for 3 seconds. The temperature at which the surfaces of single fibers
in contact with the hot plate are soften and bonded to each other into a plate shape
is defined as the softening point of the fibers.
(Example 1)
[0060] With use of a sliver knitting machine (circular knitting machine) for production
of fake furs and the above polyester fiber yarns as the ground yarns, a high pile
fabric of Example 1 was knitted by supplying a pile fiber sliver (10 to 14 g) composed
of ELP, AH7.8 andAH5.6 mixed uniformly in a ratio of ELP/AH7.8/AH5.6 = 15/35/50 (wt%).
The number of loops in the wale of the ground structure was 16 to 17/inch, and the
number of loops in the course of the ground structure was 22 to 33/inch. Next, the
pile fibers on the piloerection surface side of the high pile fabric were aligned
by polishing and shearing. Specifically, first, the pile fibers were polished twice
at 120°C, and then sheared twice.
[0061] An aqueous solution of an amino-modified silicone-based softener (trade name "Matsumoto
Silicone Softener N-20" manufactured by Matsumoto Yushi-Seiyaku Co., Ltd., solid content:
20 wt%) was sprayed on the back surface of the obtained high pile fabric so that 0.2
parts by weight of the amino-modified silicone-based softener (solid content) would
be adhered to 100 parts by weight of the pile fibers on the back surface side. Thereafter,
the high pile fabric was dried for 3 minutes using a pin tentor drier at an inner
drier temperature of 125°C while drawing the width to 160 cm, followed by cooling
to 80°C or lower with the width being held at 160 cm.
[0062] The heat sensitive sealing was performed with respect to the back surface of the
high pile fabric (width: 160 cm) with a heat sensitive sealing device shown in FIG.
2 under the following conditions: the temperature of the heating roller: 215°C, the
contact time between the heating roller and the high pile fabric: 3 seconds, the nip
pressure of the heating roller and the cooling rubber roller: 50 Kgf/cm
2 (4.9 MPa). At this time, the width of the high pile fabric shrank to 135 cm. Thereafter,
the high pile fabric was dried for 3 minutes using a pin tentor drier at an inner
drier temperature of 125°C while drawing the width to 160 cm, followed by cooling
to 80°C or lower with the width being held at 160 cm.
[0063] In the high pile fabric obtained, the pile fibers on the front surface side of the
pile fabric were aligned by polishing, brushing, and shearing. Specifically, first,
the pile fibers were brushed twice, polished once at each of 155°C, 150°C, 145°C,
130°C and 120°C, then sheared twice, and lastly polished twice at 100°C. Consequently,
a high pile fabric with a weight per unit area of 700 g/m
2 and a pile fiber length at piloerection portion of 20 mm was obtained.
(Example 2)
[0064] A high pile fabric of Example 2 was produced in the same manner as in Example 1 except
that the aqueous solution of the ammo-modified silicone-based softener was sprayed
on the back surface of the high pile fabric so that 1 part by weight of the amino-modified
silicone-based softener (solid content) would be adhered to 100 parts by weight of
the pile fibers on the back surface side of the pile fabric.
(Comparative Example 1)
[0065] A high pile fabric of Comparative Example 1 was produced in the same manner as in
Example 1 except that an unmodified silicone-based softener (trade name "Dimethyl
Silicone K" manufactured by Matsumoto Yushi-Seiyaku Co., Ltd., the solid content:
20 wt%) was used in place of the amino-modified silicone-based softener.
(Comparative Example 2)
[0066] A high pile fabric of Comparative Example 2 was produced in the same manner as in
Example 2 except that an unmodified silicone-based softener (trade name "Dimethyl
Silicone K" manufactured by Matsumoto Yushi-Seiyaku Co., Ltd., the solid content:
20 wt%) was used in place of the amino-modified silicone-based softener.
(Comparative Example 3)
[0067] A high pile fabric of Comparative Example 3 was produced in the same manner as in
Example 1 except that a fatty acid-based softener ("PK-608" manufactured by Yancheng
Jiaye Textile Materials Co., Ltd., the solid content: 20 wt%) was used in place of
the amino-modified silicone-based softener.
(Comparative Example 4)
[0068] A high pile fabric of Comparative Example 4 was produced in the same manner as in
Example 2 except that a fatty acid-based softener ("PK-608" manufactured by Yancheng
Jiaye Textile Materials Co., Ltd., the solid content: 20 wt%) was used in place of
the ammo-modified silicone-based softener.
(Comparative Example 5)
[0069] A high pile fabric of Comparative Example 5 was produced in the same manner as in
Example 1 except that the heat sensitive sealing was performed without adhering a
softener to the pile fibers on the back surface side of the pile fabric.
(Comparative Example 6)
[0070] A high pile fabric of Comparative Example 6 was produced in the same manner as in
Example 1 except that a sliver (10 to 14 g) composed of 100 wt% ofAH7.8 was used as
the pile fiber sliver.
(Comparative Example 7)
[0071] A high pile fabric of Comparative Example 7 was produced in the same manner as in
Example 1 except that a sliver (10 to 14 g) composed of ELP and MCS mixed uniformly
in a ratio of ELP/MCS = 20/80 (wt%) was used as the pile fiber sliver.
[0072] The fiber loss and the softness of the high pile fabrics obtained in Examples 1 to
2 and Comparative Examples 1 to 7 were measured and evaluated by the methods described
above. Table 1 below shows the results. In Table 1, Adhesion amount of softener is
a weight ratio of the softener with respect to 100 parts by weight of the pile fibers
on the back surface side of the pile fabric. Specifically, in Example 1, the adhesion
amount of the softener is the sum of the amount of the softener adhered to the fibers
used as the material of the pile fibers and the amount of the softener of the same
kind additionally adhered to the pile fibers on the back surface side of the pile
fabric in the production step of the pile fabric, and calculated in the following
manner. In Example 2 and Comparative Examples 1 to 7, the adhesion amounts of the
respective softeners were calculated in the same manner as in Example 1. Example 1:
The amount of the amino-modified silicone-based softener adhered with respect to 100
parts by weight of the fibers used as the material of the pile fibers = AH7.8 and
AH5.6 derivatives = 3 (parts by weight) × 85 (wt%) = 0.255 parts by weight The amount
of the amino-modified silicone-based softener additionally adhered with respect to
100 parts by weight of the pile fibers on the back surface side of the pile fabric
in the production step of the pile fabric = 0.2 parts by weight The adhesion amount
of the amino-modified silicone-based softener to 100 parts by weight of the pile fibers
on the back surface side of the pile fabric = 0.255 + 0.2 (parts by weight) = 0.455
parts by weight
[Table 1]
| |
Adhesion amount of softener (parts by weight) |
Fiber loss |
Softness |
| Amino-modified silicone-based softener |
Unmodified silicone-based softener |
Fatty acid-based softener |
Amount of fiber loss |
Evaluation |
Distance at 90° (mm) |
Evaluation |
| Average (g/m2) |
Maximum (g/m2) |
| Ex. 1 |
0.455 |
/ |
/ |
1.49 |
1.81 |
S |
44 |
A |
| Ex. 2 |
1.255 |
/ |
/ |
2.28 |
2.92 |
A |
40 |
A |
| Comp. Ex. 1 |
0.255 |
0.2 |
/ |
4.24 |
5.74 |
C |
39 |
A |
| Comp. Ex. 2 |
0.255 |
1 |
/ |
4.72 |
5.36 |
C |
37 |
A |
| Comp. Ex. 3 |
0.255 |
/ |
0.2 |
4.33 |
5.55 |
C |
41 |
A |
| Comp. Ex. 4 |
0.255 |
/ |
1 |
4.85 |
5.61 |
C |
41 |
A |
| Comp. Ex. 5 |
0.255 |
/ |
/ |
2.29 |
2.55 |
A |
56 |
C |
| Comp. Ex. 6 |
0.3 |
/ |
/ |
3.12 |
3.35 |
B |
63 |
C |
| Comp. Ex. 7 |
/ |
/ |
/ |
2.37 |
2.89 |
A |
61 |
C |
| *Example: Ex. Comparative Example: Comp. Ex. |
[0073] As can be seen from the results of Table 1 above, the pile fabrics of Examples 1
and 2, in which 0.4 parts by weight or more of the amino-modified silicone-based softener
was adhered with respect to 100 parts by weight of the pile fibers on the back surface
side of the pile fabric, resulted in high softness and reduced pile fiber loss.
[0074] Meanwhile, the pile fabrics of Comparative Examples 1 and 2, in which the total adhesion
amount of the amino-modified silicone-based softener and the unmodified silicone-based
softener to the pile fibers on the back surface side of the pile fabrics was 0.4 parts
by weight or more with respect to 100 parts by weight of the pile fibers on the back
surface side but the adhesion amount of the amino-modified silicone-based softener
with respect to 100 parts by weight of the pile fibers on the back surface side was
less than 0.4 parts by weight, resulted in favorable softness but a large amount of
pile fiber loss. Moreover, the pile fabrics of Comparative Examples 3 and 4, in which
the total adhesion amount of the amino-modified silicone-based softener and the fatty
acid-based softener to the pile fibers on the back surface side of the pile fabrics
was 0.4 parts by weight or more with respect to 100 parts by weight of the pile fibers
on the back surface side but the adhesion amount of the amino-modified silicone-based
softener with respect to 100 parts by weight of the pile fibers on the back surface
side was less than 0.4 parts by weight, resulted in favorable softness but a large
amount of pile fiber loss. Moreover, the pile fabrics of Comparative Examples 5 and
6, in which the adhesion amount of the amino-modified silicone-based softener to the
pile fibers on the back surface side of the pile fabrics was less than 0.4 parts by
weight with respect to 100 parts by weight of the pile fibers on the back surface
side, and the pile fabric of Comparative Example 7, in which the amino-modified silicone-based
softener was not adhered to the pile fibers on the back surface side of the pile fabric,
resulted in reduced pile fiber loss but hard texture.
Description of Reference Numerals
[0075]
1 ground yarn
2 pile fiber
3 raised pile
4 heat sensitive sealing part
5 high pile fabric
6 loop
7 front surface side
8 back surface side
10 processing device
11 heating roller
12 cooling rubber roller
13,14 metal cooling roller
15 guide roller
16,17 container
18 raw pile fabric
18a front surface side of raw pile fabric
18b back surface side of raw pile fabric
19, 21 pile fabric
22 metal plate
23 adhesive tape
31 cloth piece of pile fabric
32 horizontal board
41 tangent drawn to the tip of the cloth piece of pile fabric