(19)
(11) EP 3 722 467 A1

(12) EUROPEAN PATENT APPLICATION
published in accordance with Art. 153(4) EPC

(43) Date of publication:
14.10.2020 Bulletin 2020/42

(21) Application number: 19734225.6

(22) Date of filing: 01.04.2019
(51) International Patent Classification (IPC): 
D02G 3/44(2006.01)
D02G 3/38(2006.01)
D04B 1/18(2006.01)
D02G 3/04(2006.01)
D04B 1/14(2006.01)
(86) International application number:
PCT/CN2019/080735
(87) International publication number:
WO 2020/168616 (27.08.2020 Gazette 2020/35)
(84) Designated Contracting States:
AL AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HR HU IE IS IT LI LT LU LV MC MK MT NL NO PL PT RO RS SE SI SK SM TR
Designated Extension States:
BA ME
Designated Validation States:
KH MA MD TN

(30) Priority: 20.02.2019 CN 201910125947

(71) Applicant: Honghan Nantong Protection of Science & Technology Co., Ltd.
Nantong City, Jiangsu 226400 (CN)

(72) Inventor:
  • LIN, Xin
    Nantong City, Jiangsu 226400 (CN)

(74) Representative: ZHAOffice SPRL 
Rue de Bedauwe 13
5030 Gembloux
5030 Gembloux (BE)


(56) References cited: : 
   
       


    (54) METHOD FOR PREPARING TUNGSTEN WIRE TWIST-WRAPPED ANTI-CUT YARN AND METHOD FOR MAKING TEXTILE USING SAME


    (57) Disclosed is a method of preparing tungsten-based twisted and wrapped cut-resistant yarn, which comprises two steps: preparation of tungsten-based twisted yarn and preparation of tungsten-based twisted and wrapped cut-resistant yarn. Also disclosed is a method of producing a textile from the tungsten-based twisted and wrapped cut-resistant yarn, wherein by a knitting process with double yarn feeders U2, a textile is produced from spandex stretch yarn and the tungsten-based twisted and wrapped cut-resistant yarn. The present invention is advantageous in that: because China is a major producer of tungsten filaments and the reserves account for 75% of the world's total reserves, the present invention, using the tungsten filament as the raw material, has a broad variety of raw material sources and low costs. Moreover, the produced textiles are light, thin, and soft; and have high cut resistance, chemical stability, bending resistance, and deformation resistance during washing, and excellent electrical conductivity.




    Description

    Technical Field



    [0001] The present invention relates to the field of yarns, and in particular, to a method of preparing tungsten-based twisted and wrapped cut-resistant yarn, and a method of producing a textile using same.

    Background



    [0002] Cut-resistant gloves are functional gloves. To achieve cut resistance, the thickness of current cut-resistant gloves is usually increased. The increase in thickness enhances the cut resistance of the gloves, but brings an uncomfortable feeling to a user. The gloves are stiff, thick and heavy, and do not bend easily, increasing the burden on an operator.

    Summary of the Invention



    [0003] To solve the foregoing technical problem, the present invention provides a method of preparing tungsten-based twisted and wrapped cut-resistant yarn, and a method of producing a textile using same.

    [0004] The present invention adopts the following technical solution:
    A method of preparing tungsten-based twisted and wrapped cut-resistant yarn includes the following operation steps:
    1. a. preparation of tungsten-based twisted yarn: twisting together and intertwining auxiliary yarn I and a tungsten filament at the twisting degree of 400 to 700 twists/meter, to prepare the tungsten-based twisted yarn; and
    2. b. preparation of tungsten-based twisted and wrapped cut-resistant yarn: wrapping a high-molecular-weight polyethylene fiber around the tungsten-based twisted yarn obtained in step a, at the twisting degree of 120 to 280 twists/meter, to prepare the tungsten-based twisted and wrapped cut-resistant yarn.


    [0005] Further, in the tungsten-based twisted yarn in step a, the tungsten filament accounts for 35% to 75%, and the auxiliary yarn I accounts for 25% to 65%.

    [0006] Further, the auxiliary yarn I in step a is made from one of nylon, polyester, cotton, bamboo fiber, and tencel; and has a linear density of 40D to 140D.

    [0007] Further, the linear density of the nylon is preferably 40D, 50D, 70D, 100D or 140D.

    [0008] Further, one or more of tungsten filaments with diameters of 0.01 mm, 0.015 mm, 0.02 mm, 0.025 mm, and 0.03 mm are selected as the tungsten filament in step a.

    [0009] Further, in the tungsten-based twisted and wrapped cut-resistant yarn in step b, the tungsten-based twisted yarn accounts for 35% to 65%, and the polyethylene fiber accounts for 35% to 65%.

    [0010] Further, the polyethylene fiber in step b has a molecular weight of 10W to 500W and a linear density of 50D to 400D.

    [0011] Further, the linear density of the polyethylene fiber is preferably 50D, 100D, 150D, 200D, 300D, or 400D.

    [0012] A method of producing a textile from tungsten-based twisted and wrapped cut-resistant yarn includes: by a knitting process with double yarn feeders U2, producing a textile from spandex stretch yarn and the tungsten-based twisted and wrapped cut-resistant yarn, wherein the tungsten-based twisted and wrapped cut-resistant yarn accounts for 60% to 80%, and the spandex stretch yarn accounts for 20% to 40%.

    [0013] Further, the spandex stretch yarn is made from nylon-wrapped spandex, polyester-wrapped spandex, or polyethylene-fiber-wrapped spandex; and is made by twisting together a spandex filament with the specification of 20D to 100D and auxiliary yarn II with the specification of 50D to 200D at the twisting degree of 180 to 580 twists/meter, wherein the auxiliary yarn II is made from nylon, polyester or polyethylene; and the tension ratio of the spandex stretch yarn ranges from 1.5 to 2.4.

    [0014] The present invention achieves the following advantageous effects: 1. A tungsten filament with rigidity of 9, ranking only second to diamond, is used as the raw material. Therefore, textiles produced with this material are highly rigid, thin and light. Moreover, China is a major producer of tungsten filaments, and the reserves account for 75% of the world's total reserves. Therefore, the present invention has advantages of a broad variety of raw material sources and low costs. 2. The produced textiles are light, thin, and soft; and have high cut resistance, chemical stability, bending resistance, and deformation resistance during washing, and excellent electrical conductivity. Further, the textiles can reach a cut resistance grade of A6 or higher in the ASTM standard; an ISO grade of F or higher in the European standard; and a wear resistance grade of 4, cut resistance grade of 5, tear resistance grade of 4, and puncture resistance grade of 4 in the European Union (EN) 388 standard.

    Brief Description of the Drawings



    [0015] 

    FIG. 1 is a schematic structural diagram of tungsten-based twisted yarn in the present invention (using one strand of auxiliary yarn I and one tungsten filament);

    FIG. 2 is a schematic structural diagram of tungsten-based twisted yarn in the present invention (using one strand of auxiliary yarn I and two or more tungsten filaments);

    FIG. 3 is a schematic structural diagram of tungsten-based twisted and wrapped cut-resistant yarn in the present invention (using one strand of auxiliary yarn I, one tungsten filament, and one strand of polyethylene fiber);

    FIG. 4 is a schematic structural diagram of tungsten-based twisted and wrapped cut-resistant yarn in the present invention (using one strand of auxiliary yarn I, two or more tungsten filaments, and one strand of polyethylene fiber); and

    FIG. 5 is a schematic structural diagram of spandex stretch yarn in the present invention.


    Meanings of numerals in the drawings:



    [0016] 1. Auxiliary yarn I, 2. Tungsten filament, 3. Polyethylene fiber, 4. Spandex filament, and 5. Auxiliary yarn II

    Detailed Description



    [0017] In order to further understand the present invention, the present invention is further described in detail below with reference to examples and the accompanying drawings. The examples are only intended to explain the present invention, and not to limit the protection scope of the present invention.

    [0018] A method of preparing tungsten-based twisted and wrapped cut-resistant yarn includes the following operation steps:
    1. a. Preparation of tungsten-based twisted yarn: As shown in FIG. 1 and FIG. 2, auxiliary yarn I 1 and a tungsten filament 2 are twisted together and intertwined at the twisting degree of 400 to 700 twists/meter, to prepare the tungsten-based twisted yarn. The tungsten filament accounts for 35% to 75%, and the auxiliary yarn I 1 accounts for 25% to 65%. The auxiliary yarn I 1 is made from one of nylon, polyester, cotton, bamboo fiber, and tencel; and has a linear density of 40D to 140D. The tungsten filament 2 is selected to be one tungsten filament having a diameter of 0.01 mm, 0.015 mm, 0.02 mm, 0.025 mm, or 0.03 mm.
    2. b. Preparation of tungsten-based twisted and wrapped cut-resistant yarn: As shown in FIG. 3 and FIG. 4, a high-molecular-weight polyethylene fiber 3 is wrapped around the tungsten-based twisted yarn obtained in step a, at the twisting degree of 120 to 280 twists/meter, to prepare the tungsten-based twisted and wrapped cut-resistant yarn. In the tungsten-based twisted and wrapped cut-resistant yarn, the tungsten-based twisted yarn accounts for 35% to 65%, and the polyethylene fiber 3 accounts for 35% to 65%. The polyethylene fiber has a molecular weight of 10W to 500W and a linear density of 50D to 400D. The linear density of the polyethylene fiber is preferably 50D, 100D, 150D, 200D, 300D, or 400D.


    [0019] Afterwards, a method of producing a textile using the tungsten-based twisted and wrapped cut-resistant yarn as described above is as follows: By a knitting process with double yarn feeders U2, a textile is produced from spandex stretch yarn and the tungsten-based twisted and wrapped cut-resistant yarn. The tungsten-based twisted and wrapped cut-resistant yarn accounts for 60% to 80%, and the spandex stretch yarn accounts for 20% to 40%. The spandex stretch yarn is made from nylon-wrapped spandex, polyester-wrapped spandex, or polyethylene-fiber-wrapped spandex. As shown in FIG. 5, the spandex stretch yarn is made by twisting together a spandex filament 4 with the specification of 20D to 100D and auxiliary yarn II 5 with the specification of 50D to 200D at the twisting degree of 180 to 580 twists/meter. The auxiliary yarn II is made from nylon, polyester or polyethylene; and the tension ratio of the spandex stretch yarn ranges from 1.5 to 2.4.

    [0020] Data and detection results, regarding textiles produced by the method of preparing tungsten-based twisted and wrapped cut-resistant yarn and by the method of producing a textile using the yarn, in five comparative examples and eleven examples are shown below:
    Sample No. Diameter of the tungsten filament (mm) Fineness of the auxiliary yarn I (D) Fineness of the polyethylene fiber (D) Fineness of the spandex filament (D) Fineness of the auxiliary yarn II (D) Weight (g/piece) Cut resistance (ASTM)
    comparative example 1 0.006 70 50 20 100 13.5 A4
    comparative example 2 0.01 30 100 30 200 14.5 A4
    comparative example 3 0.015 70 100 140 100 15 A4
    comparative example 4 0.015 100 150 40 250 15.5 A5
    comparative example 5 0.015 100 200 70 250 16 A5
    Example 1 0.02 50 100 20 70 16.8 A6
    Example 2 0.02 70 150 40 100 17 A6
    Example 3 0.02 100 200 30 70 17.8 A7
    Example 4 0.02 70 200 20 140 18.8 A7
    Example 5 0.025 70 150 30 100 18 A6
    Example 6 0.025 100 200 40 70 19 A6
    Example 7 0.025 140 200 70 100 19 A7
    Example 8 0.03 140 200 40 140 19 A6
    Example 9 0.03 70 200 40 70 19.2 A6
    Example 10 0.03 100 300 70 140 20 A7
    Example 11 0.03 100 300 100 100 20 A8
    Note: The auxiliary yarn I in the comparative examples 1 to 3 and the examples 1 to 4 is made from nylon; the auxiliary yarn I in the comparative examples 4 and 5 and the examples 5 to 8 is made from polyester; the auxiliary yarn I in the examples 9 to 11 is made from cotton; the auxiliary yarn II in the comparative examples 1 to 3 and the examples 1 to 4 is made from nylon; the auxiliary yarn II in the comparative examples 4 and 5 and the examples 5 to 8 is made from polyester; and the auxiliary yarn II in the examples 9 to 11 is made from polyethylene.


    [0021] It can be seen from the above examples and comparative examples that, the textiles produced within the data ranges of the present invention can all reach a cut resistance grade of A6 or higher in the ASTM standard.


    Claims

    1. A method of preparing tungsten-based twisted and wrapped cut-resistant yarn, comprising the following operation steps:

    a. preparation of tungsten-based twisted yarn: twisting together and intertwining auxiliary yarn I and a tungsten filament at the twisting degree of 400 to 700 twists/meter, to prepare the tungsten-based twisted yarn; and

    b. preparation of tungsten-based twisted and wrapped cut-resistant yarn: wrapping a high-molecular-weight polyethylene fiber around the tungsten-based twisted yarn obtained in step a, at the twisting degree of 120 to 280 twists/meter, to prepare the tungsten-based twisted and wrapped cut-resistant yarn.


     
    2. The method of preparing tungsten-based twisted and wrapped cut-resistant yarn according to claim 1, wherein in the tungsten-based twisted yarn in step a, the tungsten filament accounts for 35% to 75%, and the auxiliary yarn I accounts for 25% to 65%.
     
    3. The method of preparing tungsten-based twisted and wrapped cut-resistant yarn according to claim 1, wherein the auxiliary yarn I in step a is made from one of nylon, polyester, cotton, bamboo fiber, and tencel; and has a linear density of 40D to 140D.
     
    4. The method of preparing tungsten-based twisted and wrapped cut-resistant yarn according to claim 3, wherein the linear density of the nylon is preferably 40D, 50D, 70D, 100D, or 140D.
     
    5. The method of preparing tungsten-based twisted and wrapped cut-resistant yarn according to claim 1, wherein one or more of tungsten filaments with diameters of 0.01 mm, 0.015 mm, 0.02 mm, 0.025 mm, and 0.03 mm are selected as the tungsten filament in step a.
     
    6. The method of preparing tungsten-based twisted and wrapped cut-resistant yarn according to claim 1, wherein in the tungsten-based twisted and wrapped cut-resistant yarn in step b, the tungsten-based twisted yarn accounts for 35% to 65%, and the polyethylene fiber accounts for 35% to 65%.
     
    7. The method of preparing tungsten-based twisted and wrapped cut-resistant yarn according to claim 1, wherein the polyethylene fiber in step b has a molecular weight of 10W to 500W and a linear density of 50D to 400D.
     
    8. The method of preparing tungsten-based twisted and wrapped cut-resistant yarn according to claim 7, wherein the linear density of the polyethylene fiber is preferably 50D, 100D, 150D, 200D, 300D, or 400D.
     
    9. A method of producing a textile from tungsten-based twisted and wrapped cut-resistant yarn, comprising: by a knitting process with double yarn feeders U2, producing a textile from spandex stretch yarn and the tungsten-based twisted and wrapped cut-resistant yarn, wherein the tungsten-based twisted and wrapped cut-resistant yarn accounts for 60% to 80%, and the spandex stretch yarn accounts for 20% to 40%.
     
    10. The method of producing a textile from tungsten-based twisted and wrapped cut-resistant yarn according to claim 9, wherein the spandex stretch yarn is made from nylon-wrapped spandex, polyester-wrapped spandex, or polyethylene-fiber-wrapped spandex; and is made by twisting together a spandex filament with the specification of 20D to 100D and auxiliary yarn II with the specification of 50D to 200D at the twisting degree of 180 to 580 twists/meter, the auxiliary yarn II being made from nylon, polyester or polyethylene, and the tension ratio of the spandex stretch yarn ranging from 1.5 to 2.4.
     




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