FIELD OF THE INVENTION
[0001] The present invention relates to the field of processes for producing optical effect
layers (OELs) comprising magnetically oriented platelet-shaped magnetic or magnetizable
pigment particles. In particular, the present invention provides processes for magnetically
orienting platelet-shaped magnetic or magnetizable pigment particles in more than
one coating layers so as to produce OELs and the use of said OELs as anti-counterfeit
means on security documents or security articles as well as decorative purposes.
BACKGROUND OF THE INVENTION
[0002] It is known in the art to use inks, compositions, coatings or layers containing oriented
magnetic or magnetizable pigment particles, particularly also optically variable magnetic
or magnetizable pigment particles, for the production of security elements, e.g. in
the field of security documents. Coatings or layers comprising oriented magnetic or
magnetizable pigment particles are disclosed for example in
US 2,570,856;
US 3,676,273;
US 3,791,864;
US 5,630,877; and
US 5,364,689. Coatings or layers comprising oriented magnetic color-shifting pigment particles,
resulting in particularly appealing optical effects, useful for the protection of
security documents, have been disclosed in
WO 2002/090002 A2 and
WO 2005/002866 A1.
[0003] Security features, e.g. for security documents, can generally be classified into
"covert" security features on the one hand, and "overt" security features on the other
hand. The protection provided by covert security features relies on the principle
that such features are difficult to detect, typically requiring specialized equipment
and knowledge for detection, whereas "overt" security features rely on the concept
of being easily detectable with the unaided human senses, e.g. such features may be
visible and/or detectable via the tactile sense while still being difficult to produce
and/or to copy. However, the effectiveness of overt security features depends to a
great extent on their easy recognition as a security feature.
[0004] Overt features in the forms of foils or patches comprising holograms, lenticular
structures and arrays of micro-lenses and micromirrors have been widely used in security
documents, in particular banknotes. These security features are produced separately
and integrated into the security document during its production. Foils and patches
are produced on reels of substrate by several techniques selected from the group of
printing, coating, vapor deposition, etching, varnishing and/or combination thereof,
which are finally sliced into foils and patches to be inserted into the security document
substrates during their production and are applied by gluing or by hot-stamping onto
the security document substrates. These structures can be integrated in windowed security
threads, security foils, security patches, or applied, e.g. by hot-stamping, as such
to the security document substrate for e.g. on a transparent window of a security
document.
[0005] Said security features are said to be highly eye-catching features due to their high
brightness having often a metallic aspect. Said security features are particularly
suitable to be applied on foils and windows of value documents, in particular banknotes.
Due to the highly demanding application of protecting value documents, in particular
banknotes, said security features exhibit poor chemical and physical resistance during
their exposure to the environment and conditions such as those met during circulation
of valued documents carrying those security features, thus leading to their premature
deterioration.
[0006] With the aim of optimizing and increasing the counterfeiting resistance of security
documents, in particular banknotes, striking and sophisticated magnetically induced
images and optical effects layers (OELs) have been developed. Magnetic or magnetizable
pigment particles in printing inks or coatings allow for the production of magnetically
induced images, designs and/or patterns (also referred in the art as "Optical Effect
Layers (OELs)") through the application of a correspondingly structured magnetic field,
inducing a local orientation of the magnetic or magnetizable pigment particles in
the not yet hardened (i.e. wet) coating, followed by the hardening of the coating.
The result is a fixed and stable magnetically induced image, design or pattern. Materials
and technologies for the orientation of magnetic or magnetizable pigment particles
in coating compositions are known. The magnetically induced images in question can
only be produced by having access to both, the magnetic or magnetizable pigment particles
or the corresponding ink, and the particular technology employed to print said ink
and to orient said pigment in the printed ink. Said OELs are obtained by using specific
magnetic assemblies and advantageously exhibit a dynamic appearance upon tilting.
Examples of such dynamic OELs include reflection zone bars moving as the OEL is tilted,
loop-shaped bodies moving as the OEL is tilted, loop-shaped bodies having a varying
shape as the OEL is tilted, bright areas and dark areas moving as the OEL is tilted.
WO 2012/104098 A1 discloses OELs comprising more than one magnetically induced images.
WO 2012/104098 A1 discloses an OEL comprising two areas, each one exhibiting a reflection zone bar
moving as the OEL is tilted, one of said bar moving away the observer upon tilting
of the OEL and the other said bar moving towards the observer upon tilting of the
OEL.
[0007] A need remains for improved processes for producing eye-catching and highly bright
overt security features for security printers at industrial speed, wherein said so-produced
security features are easily authenticated by the man in the street, are resistant
to chemical and physical stress conditions borne by a security document or article
comprising said features while said processes are highly difficult to be implemented
on a mass-scale production by counterfeiters and the illicit market.
SUMMARY OF THE INVENTION
[0008] Accordingly, it is an object of the present invention to overcome the deficiencies
of the prior art as discussed above. This is achieved by the provision of a process
for producing an optical effect layer (OEL) on a substrate (x10), said optical effect
layer (OEL) comprising a first motif comprising magnetically oriented platelet-shaped
magnetic or magnetizable pigment particles oriented according to a first magnetic
pattern and a second motif comprising magnetically oriented platelet-shaped magnetic
or magnetizable pigment particles oriented according to a second magnetic pattern,
said process comprising:
a first set of steps consisting of
a') applying onto the substrate (x10) a first radiation curable coating composition,
preferably a first UV-Vis-curable curable coating composition, comprising the platelet-shaped
magnetic or magnetizable pigment particles so as to form a first coating layer (x20')
on said the substrate (x10), said coating composition being in a first state;
b') exposing the first radiation curable coating composition of step a') to a magnetic
field of a magnetic assembly (x30') so as to magnetically orient at least a part of
the platelet-shaped magnetic or magnetizable pigment particles;
c') at least partially curing the first radiation curable coating composition of step
b') to a second state so as to fix the platelet-shaped magnetic or magnetizable pigment
particles in their adopted positions and
orientations and so as to produce the first motif; and
a second set of steps consisting of
a") applying in register a second radiation curable coating composition, preferably
a second UV-Vis-curable curable coating composition, comprising platelet-shaped magnetic
or magnetizable pigment particles so as to form a second coating layer (x20"), said
coating composition being in a first state, and at least a part of the second coating
layer (x20") being adjacent to at least a part of the first coating layer (x20');
b") exposing the second radiation curable coating composition of step a") to a magnetic
field of a magnetic assembly (x30") so as to bi-axially orient at least a part of
the platelet-shaped magnetic or magnetizable pigment particles to i) have both their
X-axis and Y-axis substantially parallel to the substrate (x10) surface, or ii) have
their X-Y plane parallel to an imaginary spheroid surface;
c") at least partially curing the second radiation curable coating composition of
step b") to a second state so as to fix the platelet-shaped magnetic or magnetizable
pigment particles in their adopted positions and orientations and so as to produce
the second motif.
[0009] Also described herein are processes for producing OELs comprising the first motif
comprising the platelet-shaped magnetic or magnetizable pigment particles oriented
according to the first magnetic pattern described herein, the second motif comprising
the platelet-shaped magnetic or magnetizable pigment particles oriented according
to the second magnetic pattern described herein, and a third motif comprising the
platelet-shaped magnetic or magnetizable pigment particles oriented according to a
third magnetic pattern, wherein the first and second motifs are different from each
other and wherein the third and second patterns may be the same or different from
each other, wherein the third motif is adjacent to and in proper register with at
least a part of the first motif and/or adjacent to and in proper register with at
least a part of the second motif (i.e. the third motif is at least partially adjacent
to and in proper register with the first motif and/or at least partially adjacent
to and in proper register with the second motif), and wherein said processes comprise
the first set of steps (S1) a'), b') and c') described herein, the second set of steps
(S2) a"), b") and c") described herein and a third set of steps (S3) a‴), b‴) and
c‴), said third step a‴) being carried out subsequently to and continuously with step
c").
[0010] The OELs described herein comprises at least the first and second motifs described
herein, i.e. the OELs described herein may comprise a third motif, a fourth motif,
etc., provided that at least one motif outmost facing the environment comprises magnetically
oriented platelet-shaped magnetic or magnetizable pigment particles oriented according
to a magnetic pattern, wherein said particles have i) have both their X-axis and Y-axis
substantially parallel to the substrate (x10) surface, or ii) have their X-Y plane
parallel to an imaginary spheroid surface.
[0011] Also described herein are optical effect layers (OELs) produced by the process described
herein and security documents as well as decorative elements and objects comprising
one or more optical OELs described herein.
[0012] Also described herein are methods of manufacturing a security document or a decorative
element or object, comprising a) providing a security document or a decorative element
or object, and b) providing an optical effect layer (OEL) obtained by the process
described herein, so that it is comprised by the security document or decorative element
or object.
[0013] The present invention provides processes advantageously allowing the manufacture
of eye-catching highly bright optical effect layers (OELs) which are easily authenticated
by the man in the street. The so-produced optical effect layers (OELs) made from security
inks comprising magnetically oriented pigment particles according to specific magnetic
patterns are highly bright, reflective, metallic shiny and dynamic when observed from
the side of the substrate carrying at least the second coating layer and are thus
particularly attractive for the protection of security documents, in particular banknotes,
due to the combined eye-catching optical effect, their resistance against physical
and chemical attacks from the environment and the high design flexibility to produce
them.
BRIEF DESCRIPTION OF DRAWINGS
[0014]
Figs 1-13 provided therein schematically illustrates the present invention and are
not true to scale. The optical effect layers (OELs) described herein and their production
are now described in more detail with reference to the drawings and to particular
embodiments, wherein
Figs 1A-B schematically illustrates the combination of a first motif comprising platelet-shaped
magnetic or magnetizable pigment particles oriented according to a first magnetic
pattern and a second motif comprising platelet-shaped magnetic or magnetizable pigment
particles oriented according to a second magnetic pattern, wherein the first and second
motifs are either on the same side of the substrate (Fig. 1A) or on opposite sides
(Fig. 1B), wherein said OEL is highly bright, in particular highly bright and dynamic,
when observed from the side carrying the second motif (120") (see eye in Figs. 1A-B).
Fig. 1C schematically illustrates the combination of a first motif comprising platelet-shaped
magnetic or magnetizable pigment particles oriented according to a first magnetic
pattern, a second motif comprising platelet-shaped magnetic or magnetizable pigment
particles oriented according to a second magnetic pattern and a third motif comprising
platelet-shaped magnetic or magnetizable pigment particles oriented according to a
third magnetic pattern, wherein the first and second motifs are on the same side of
the substrate (110) and the third motif is on the opposite side of the substrate (110),
wherein said OEL is highly bright, in particular highly bright and dynamic, when observed
from the side carrying the second motif (120") and/or from the side carrying the third
motif (120‴) (see eyes in 1C).
Fig. 2 schematically illustrates a platelet-shaped pigment particle.
Fig. 3A schematically illustrates a first set of steps (S1) described herein, wherein the
orientation step b') is a one-step orientation step and wherein a substrate (310)
carrying a first coating layer (320') obtained by screen printing (340') (step a'))
is exposed to the magnetic field of a magnetic assembly (330') and wherein the first
coating layer (320') is, partially simultaneously with step b'), at least partially
cured with a first curing unit (350') (step c')).
Figs 3B and 3C illustrate an industrial one-step orientation step steps b') shown in Fig. 3, wherein
the first coating layer (320') is exposed to the magnetic field of a magnetic assembly
(330') being either mounted on a rotating magnetic cylinder with the first coating
layer (320') facing the environment (Fig. 3B) or placed outside a rotating cylinder
with the first coating layer (320') facing said magnetic assembly (330') (Fig. 3C)
and wherein the first coating layer (320') is, partially simultaneously with step
b'), at least partially cured with a curing unit (350') (step c')).
Fig. 4A illustrates a first set of steps (S1) described herein, wherein the orientation step
b') is a one-step orientation step wherein the first coating layer (420') is exposed
to the resultant magnetic field of a first magnetic assembly (430'-a) and of a second
magnetic assembly (430'-b), and wherein the first coating layer (420') is, partially
simultaneously with step b'), at least partially cured with a first curing unit (450')
(step c')).
Fig. 4B illustrates an industrial one-step orientation step b') shown in Fig. 4A, wherein
the first coating layer (420') is exposed to the resultant magnetic field of a first
magnetic assembly (430'-a) and of a second magnetic assembly (430'-b), wherein said
first magnetic assembly (430'-a) is mounted on a rotating magnetic cylinder and the
second magnetic assembly (430'-b) is placed outside the rotating magnetic cylinder
and wherein the first coating layer (420') is, partially simultaneously with step
b'), at least partially cured with a curing unit (450') (step c')).
Fig. 5A schematically illustrates a first set of steps (S1) described herein, wherein the
orientation step b') is a two-steps orientation step and wherein a substrate (510)
carrying a first coating layer (520') obtained by screen printing (540') (step a'))
is first exposed to a first magnetic field of a magnetic assembly (530'-a) (step b'-1))
and then subsequently exposed to a second magnetic field of a magnetic assembly (530'-b)
(step b'-2)) so as to re-orient the pigment particles (step b')) and wherein the first
coating layer (520') is, partially simultaneously with step b') at least partially
cured with a first curing unit (550') (step c')).
Fig. 5B illustrates an industrial two-steps orientation step b') shown in Fig. 5A, wherein
the first coating layer (520') is first exposed to the magnetic field of a first magnetic
assembly (530'-a) and subsequently to the magnetic field of a second magnetic assembly
(530'-b), wherein said first magnetic assembly (530'-a) is placed outside and before
a rotating magnetic cylinder and said second magnetic assembly (530'-b) is mounted
on said rotating magnetic cylinder and wherein the first coating layer (520') is,
partially simultaneously with step b'), at least partially cured with a curing unit
(550') (step c')).
Fig. 6A schematically illustrates a first set of steps (S1) described herein, wherein the
orientation step b') is a two-steps orientation step and wherein a substrate (610)
carrying a first coating layer (620') obtained by screen printing (640') (step a'))
is first exposed to a first magnetic field of a magnetic assembly (630'-a) (step b'-1))
and then subsequently exposed to the resultant magnetic field of a second magnetic
assembly (630'-a) and of a third magnetic assembly (630'-c) (step b'-2)) and wherein
the coating layer (620') is, partially simultaneously with step b') at least partially
cured with a first curing unit (650') (step c')).
Fig. 6B illustrates an industrial two-steps orientation step b') shown in Fig. 6A, wherein
the coating layer (620') is first exposed to the magnetic field of a first magnetic
assembly (630'-a) and subsequently to the resultant magnetic field of a second magnetic
assembly (630'-b) and of a third magnetic assembly (630'-c), wherein said first magnetic
assembly (630'-a) is placed outside a rotating magnetic cylinder, said second magnetic
assembly (630'-b) is mounted on said rotating magnetic cylinder and said third magnetic
assembly (630'-c) is placed outside said rotating magnetic cylinder and wherein the
first coating layer (620') is, partially simultaneously with step b') at least partially
cured with a curing unit (650') (step c')).
Fig 7A schematically illustrates a second set of steps (S2) described herein, wherein the
orientation step b") is a one-step orientation step and wherein a substrate (710)
carrying a first coating layer (720') and a second coating layer (720") obtained by
screen printing (740") (step a")) on the same side as the first coating layer (720')
is exposed to the magnetic field of a magnetic assembly (730") so as to bi-axially
orient the pigment particles and wherein the second coating layer (720") is, partially
simultaneously with step b"), at least partially cured with a second curing unit (750")
(step c")).
Fig. 7B schematically illustrates a second set of steps (S2) described herein, wherein the
orientation step b") is a one-step orientation step and wherein a substrate (710)
carrying a first coating layer (720') and a second coating layer (720") obtained by
screen printing (740") (step a")) on the side of the substrate (710) lacking the first
coating layer (720') is exposed to a magnetic field of a magnetic assembly (730")
so as to bi-axially orient the pigment particles and wherein the second coating layer
(720") is, partially simultaneously with step b"), at least partially cured with a
second curing unit (750") (step c")).
Fig. 7C illustrates a one-step industrial orientation step b") shown in Fig. 7A, wherein
the second coating layer (720") is exposed to the magnetic field of a magnetic assembly
(730"), wherein said magnetic assembly (730") is placed outside a rotating cylinder
(two alternative positions are shown in Fig. 7C) and wherein the second coating layer
(720") is at least partially cured with a curing unit (750') (step c")).
Fig. 8A schematically illustrates a second set of steps (S2) described herein, wherein the
orientation step b") is a one-step orientation step and wherein a substrate (810)
carrying a first coating layer (820') and a second coating layer (820") obtained by
screen printing (840") (step a")) on the same side as the first coating layer (820')
is exposed to a magnetic field of a spinning magnetic assembly (830") so as to bi-axially
orient the pigment particles (step b") and wherein the second coating layer (820")
is, partially simultaneously with step b"), at least partially cured with a second
curing unit (850") (step c")).
Fig. 8B schematically illustrates a second set of steps (S2) described herein, wherein the
orientation step b") is a one-step orientation step and wherein a substrate (810)
carrying a first coating layer (820') and a second coating layer (820") obtained by
screen printing (840") (step a")) on the side of the substrate (810) lacking the first
coating layer (820') is exposed to a magnetic field of a spinning magnetic assembly
(830") so as to bi-axially orient the pigment particles (step b") and wherein the
second coating layer (820") is, partially simultaneously with step b"), at least partially
cured with a second curing unit (850") (step c")).
Fig. 8C illustrates a one-step industrial orientation step b") shown in Fig. 8A, wherein
the second coating layer (820") is exposed to the magnetic field of a spinning magnetic
assembly (830"), wherein said magnetic assembly (830") is mounted on a rotating magnetic
cylinder and wherein the second coating layer (820") is, partially simultaneously
with step b"), at least partially cured with a curing unit (850") (step c")).
Fig. 9 schematically illustrates a third set of steps (S3) described herein occurring after
the second set of steps (S2), wherein the orientation step b‴) is a one-step orientation
step and wherein a substrate (910) carrying a first and second coating layers (920'
and 920") and a third coating layer (920‴) obtained by screen printing (940‴) (step
a‴)) on the opposite side as the first and second coating layers (920' and 920") is
exposed to a magnetic field of a spinning magnetic assembly (930‴) so as to bi-axially
orient the pigment particles (step b‴) and wherein the third coating layer (920‴)
is, partially simultaneously with step b‴), at least partially cured with a third
curing unit (950‴) (step c‴)).
Fig. 10 schematically illustrates a magnetic assembly (1030) for bi-axially orienting the
pigment particles used in step b') of the Examples E1-E5 and in step b") of the Example
E1 provided therein.
Fig. 11 schematically illustrates a magnetic assembly (1130) used in step b') of the Example
E1-E5 provided therein and being suitable for producing a motif exhibiting a dynamic
movement of a reflective bar moving when the motif is tilted.
Fig. 12 schematically illustrates a magnetic assembly (1230) for bi-axially orienting the
pigment particles and used in step b") of the Examples E2 and E4 and in step b‴) of
the Example E4 provided therein.
Fig. 13 schematically illustrates a magnetic assembly (1330) for bi-axially orienting the
pigment particles used in step b") of the Examples E3 and E5 and in step b‴) of the
Example E5 provided therein.
[0015] The distances provided in the Figures are only illustrative and not true to scale.
DETAILED DESCRIPTION
Definitions
[0016] The following definitions are to be used to interpret the meaning of the terms discussed
in the description and recited in the claims.
[0017] As used herein, the indefinite article "a" indicates one as well as more than one
and does not necessarily limit its referent noun to the singular.
[0018] As used herein, the term "at least" is meant to define one or more than one, for
example one or two or three.
[0019] As used herein, the term "about" means that the amount or value in question may be
the specific value designated or some other value in its neighborhood. Generally,
the term "about" denoting a certain value is intended to denote a range within ± 5%
of the value. As one example, the phrase "about 100" denotes a range of 100 ± 5, i.e.
the range from 95 to 105. Generally, when the term "about" is used, it can be expected
that similar results or effects according to the invention can be obtained within
a range of ±5% of the indicated value.
[0020] As used herein, the term "and/or" means that either all or only one of the elements
of said group may be present. For example, "A and/or B" shall mean "only A, or only
B, or both A and B". In the case of "only A", the term also covers the possibility
that B is absent, i.e. "only A, but not B".
[0021] The term "comprising" as used herein is intended to be non-exclusive and open-ended.
Thus, for instance a coating composition comprising a compound A may include other
compounds besides A. However, the term "comprising" also covers, as a particular embodiment
thereof, the more restrictive meanings of "consisting essentially of" and "consisting
of', so that for instance "a fountain solution comprising A, B and optionally C" may
also (essentially) consist of A and B, or (essentially) consist of A, B and C.
[0022] The term "optical effect layer (OEL)" as used herein denotes a coating or layer that
comprises oriented platelet-shaped magnetic or magnetizable pigment particles and
a binder, wherein said platelet-shaped magnetic or magnetizable pigment particles
are oriented by a magnetic field and wherein the oriented platelet-shaped magnetic
or magnetizable pigment particles are fixed/frozen in their orientation and position
(i.e. after hardening/curing) so as to form a magnetically induced image.
[0023] The term "coating composition" refers to any composition which is capable of forming
an optical effect layer (EOL) on a solid substrate and which can be applied preferably
but not exclusively by a printing method. The coating composition comprises the platelet-shaped
magnetic or magnetizable pigment particles described herein and the binder described
herein.
[0024] As used herein, the term "wet" refers to a coating layer which is not yet cured,
for example a coating in which the platelet-shaped magnetic or magnetizable pigment
particles are still able to change their positions and orientations under the influence
of external forces acting upon them.
[0025] As used herein, the term "indicia" shall mean discontinuous layers such as patterns,
including without limitation symbols, alphanumeric symbols, motifs, letters, words,
numbers, logos and drawings.
[0026] The term "curing" is used to denote a process wherein the viscosity of a coating
composition in a first physical state which is not yet hardened (i.e. wet) is increased
so as to convert it into a second physical state, i.e. a hardened or solid state,
where the platelet-shaped magnetic or magnetizable pigment particles are fixed/frozen
in their current positions and orientations and can no longer move nor rotate.
[0027] The term "security document" refers to a document which is usually protected against
counterfeit or fraud by at least one security feature. Examples of security documents
include without limitation value documents and value commercial goods.
[0028] The term "security feature" is used to denote an image, pattern or graphic element
that can be used for authentication purposes.
[0029] Where the present description refers to "preferred" embodiments/features, combinations
of these "preferred" embodiments/features shall also be deemed as disclosed as long
as this combination of "preferred" embodiments/features is technically meaningful.
[0030] The present invention provides processes for producing optical effect layers (OELs)
being suitable as security features against counterfeit or fraud and comprising magnetically
oriented platelet-shaped magnetic or magnetizable pigment particles on substrates.
As shown in Figs 1A-B, said OELs comprise a first motif (in the form of a cured first
coating layer 120') comprising platelet-shaped magnetic or magnetizable pigment particles
oriented according to a first magnetic pattern and a second motif (in the form of
a cured second coating layer 120") comprising platelet-shaped magnetic or magnetizable
pigment particles oriented according to a second magnetic pattern, wherein said first
and second motifs are at least partially adjacent to each other (i.e. the second motif
is adjacent to at least a part of the first motif) and in proper register.
[0031] As shown in Fig. 1C, said OELs comprise a first motif (in the form of a cured first
coating layer 120') comprising platelet-shaped magnetic or magnetizable pigment particles
oriented according to a first magnetic pattern, a second motif (in the form of a cured
second coating layer 120") comprising platelet-shaped magnetic or magnetizable pigment
particles oriented according to a second magnetic pattern, and a third motif (in the
form of a cured third coating layer 120‴) comprising platelet-shaped magnetic or magnetizable
pigment particles oriented according to a third magnetic pattern wherein at least
a part of the third motif is adjacent to at least a part of the first motif and in
proper register and/or adjacent to at least a part of the second motif and in proper
register (i.e. the third motif is at least partially adjacent to and in proper register
with the first motif and/or at least partially adjacent to and in proper register
with the second motif), preferably adjacent to and in proper register with at least
a part of the first motif and adjacent to and in proper register with at least a part
of the second motif (i.e. at least partially adjacent to and in proper register with
the first motif and at least partially adjacent to and in proper register with the
second motif).
[0032] The first and second motifs (in the form of a cured first coating layer (x20')' and
second coating layer (20")) may independently consist of single sub-motifs or may,
as shown in Figs 1, consist of more than one sub-motifs, said more than one sub-motifs
independently forming the first and second motifs, respectively. Should the first
and/or second motifs described herein independently consist of sub-first-motifs and
sub-second-motifs (as shown for example in Figs 1), the OEL results from the combination
of a plurality or of all sub-motifs.
[0033] As described herein, the first magnetic pattern of the first motif and the second
magnetic pattern of the second motif are obtained by independently exposing the first
radiation curable coating composition of step a') and the second radiation curable
coating composition of step a") to the magnetic field of a magnetic assembly (x30')
during step b') so as to magnetically orient at least a part of the platelet-shaped
magnetic or magnetizable pigment particles and to the magnetic field of a magnetic
assembly (x30") during step b") so as to bi-axially orient at least a part of the
platelet-shaped magnetic or magnetizable pigment particles.
[0034] The process described herein comprises at least two sets of steps, i.e. a first set
(S1) comprising steps a'), b') and c') and a second set (S2) comprising steps a"),
b") and c") (optionally a third set of steps (S3) comprising a‴), b‴) and c‴), optionally
a fourth set of steps (S4) comprising aʺʺ), bʺʺ) and c‴), etc.), wherein the last
set of steps consists of bi-axially orienting at least a part of the platelet-shaped
magnetic or magnetizable pigment particles so that they i) have both their X-axis
and Y-axis substantially parallel to the substrate (x10) surface, or ii) have their
X-Y plane parallel to an imaginary spheroid surface. For embodiments comprising three
set of steps, preferably the step b') of the first set (S1) consists of orienting
the at least a part of the pigment particles so that the first motif exhibit a dynamic
effect, the step b") of the second set (S2) and the step b‴) of the last set (S3)
consist of bi-axially orienting at least a part of the pigment particles so that they
i) have both their X-axis and Y-axis substantially parallel to the substrate (x10)
surface, or ii) have their X-Y plane parallel to an imaginary spheroid surface, alternatively
for embodiments comprising three set of steps, preferably the step b') of the first
set (S1) consists of orienting the at least a part of the pigment particles so that
the first motif exhibits a dynamic effect, the step b") of the first set (S2) consists
of orienting the at least a part of the pigment particles so that second motif exhibits
a dynamic effect and the step b‴) of the last set (S3) consists of bi-axially orienting
at least a part of the pigment particles so that they i) have both their X-axis and
Y-axis substantially parallel to the substrate (x10) surface, or ii) have their X-Y
plane parallel to an imaginary spheroid surface; for embodiments comprising n set
of steps, preferably, the step b(
n-1)') of the (n-1) set (S(n-1)) and the step b
n') of the last set (Sn) consists of bi-axially orient at least a part of the pigment
particles so that they i) have both their X-axis and Y-axis substantially parallel
to the substrate (x10) surface, or ii) have their X-Y plane parallel to an imaginary
spheroid surface. The process described herein is thus a continuous process meaning
that the second set of steps (S2) is carried out directly after the first set (S1)
(in other words, the step a") of the second set is carried out subsequently and directly
after step c') of the first set), for embodiments comprising n set of steps, the step
a
n') of the n set (S(n)) is carried out subsequently and directly after step c(
n-1') of the (n-1)
th set. In other words, the multi-sets of steps process described herein is a continuous
process using a single machine, said machine allowing the application, preferably
printing, of coating compositions, the exposure of said compositions to magnetic fields
and the at least partial curing of said compositions, said process allowing the preparation
of OELs comprising the first motif and the second motif described herein being at
least partially adjacent to each other (i.e. the second motif is adjacent to at least
a part of the first motif) and in proper register, wherein an observer sees a highly
bright effect, preferably highly bright and dynamic effect wherein said first motif
and second motif are at least partially adjacent to each other (i.e. the second motif
is adjacent to at least a part of the first motif) and in proper register.
[0035] As shown in Figs 1A-B, the OEL described herein comprises the first and second motifs
(i.e. the first and second cured coating layers 120' and 120") on the same side of
the substrate (110) (see Fig. 1 A) or on the opposite side of the substrate (110)
(i.e. the side of the substrate lacking the first motif) (see Fig. 1 B), wherein said
substrate (110) is preferably transparent, and wherein said first and second motifs
are at least partially adjacent to each other (i.e. the second motif is adjacent to
at least a part of the first motif) and in proper register so that an observer sees
the OEL as highly bright (when observed from the side of the substate (110) carrying
the first and second coating layers (120' and 120") in Fig. 1A or when observed from
the side of the substrate (110) carrying the second layer (120") in Fig. 1B , see
the eye in Figs 1A-B) and sees said OEL as a bright continuous feature in a see-through
observation mode, in a reflection observation mode or in a transparency observation
mode.
[0036] As shown in Fig. 1C, the OEL described herein comprises the first, second and third
motifs (i.e. the first, second and third cured coating layers 120', 120" and 120‴),
wherein the first and second motifs (120' and 120") are on the same sides of the substrate
(110) and the third motif (120‴) is on the side of the substrate (110) lacking the
first motif (120') and lacking the second motif (120"), wherein said substrate (110)
is preferably transparent, and wherein said first and second motifs are at least partially
adjacent to each other (i.e. the second motif is adjacent to at least a part of the
first motif) and in proper register and the third motif is at least partially adjacent
to and in proper register with the first motif and/or at least partially adjacent
to and in proper register with the second motif (i.e. the third motif at least partially
adjacent to and in proper register with the first motif and at least partially adjacent
and in proper register with the second motif in Fig. 1C) so that an observer sees
the OEL as highly bright (when observed from the side of the substate (110) carrying
the first and second coating layers (120' and 120") and/or when observed from the
side of the substrate (110) carrying the third layer (120‴) in Fig. 1C , see the eye
in Figs 1C) and sees said OEL as a continuous feature in a see-through observation
mode, in a reflection observation mode or in a transparency observation mode.
[0037] By "adjacent", it means that the first and second motifs are superimposed, encompassing
that the second coating layer (x20") is in direct contact with the first coating layer
(x20') (see Figs 1A and 1C) as well as that the second coating layer (x20") is in
direct contact with the first coating layer (x20') through the substrate (i.e. the
substrate is present therebetween and they are in indirect contact) (see Fig. 1B.
In other words, the second motif is present on top of and in direct contact with the
first motif or the second motif faces the first motif through the substrate.
[0038] The process described herein comprises at least two independent steps a') and a")
consisting of applying the first radiation curable coating composition so as to form
the first coating layer (x20') (step a') and consisting of applying in register the
second radiation curable coating composition so as to form the second coating layer
(x20") (step a"), wherein said first and second radiation curable coating compositions
are in a first physical state which allows their application as layers and which are
in a not yet hardened (i.e. wet) state wherein the platelet-shaped magnetic or magnetizable
pigment particles can move and rotate within the binder material.
[0039] By applying in register in step a"), it is meant that the radiation curable coating
composition is applied without or with a very limited (smaller than 1 mm, preferably
smaller than 0.5 mm, more preferably smaller than or equal to 0.2 mm) misalignment
and misplacement between the second coating layer (x20") and the first coating layer
(x20') so that the obtained OEL appears to the naked eye as a continuous layer (i.e.
no breakup image). Said application in register is allowed by the claimed continuous
process using a single machine. According to one embodiment, the first and second
coating layers (x20' and x20") are applied within a register of ± 1 mm, preferably
± 0.5 mm and more preferably ± 0.2 mm. Said application in register is allowed by
the claimed continuous process using a single machine.
[0040] Preferably, said steps a') and a") are independently carried out by a printing process,
preferably independently selected from the group consisting of screen printing, rotogravure
printing, flexography printing and intaglio printing (also referred in the art as
engraved copper plate printing and engraved steel die printing), more preferably selected
from the group consisting of screen printing, rotogravure printing and flexography
printing and still more preferably by screen printing.
[0041] Screen printing (also referred in the art as silkscreen printing) is a stencil process
wherein an ink is transferred to a surface through a stencil supported by a fine fabric
mesh of silk, mono- or multifilaments made of synthetic fibers such as for example
polyamides or polyesters or metal threads stretched tightly on a frame made for example
of wood or a metal (e.g. aluminum or stainless steel). Alternatively, the screen-printing
mesh may be a chemically etched, a laser-etched, or a galvanically formed porous metal
foil, e.g. a stainless steel foil. The pores of the mesh are blocked in the non-image
areas and left open in the image area, the image carrier being called the screen.
Screen printing might be of the flat-bed or rotary type. Screen printing is further
described for example in
The Printing ink manual, R.H. Leach and R.J. Pierce, Springer Edition, 5th Edition,
pages 58-62 and in
Printing Technology, J.M. Adams and P.A. Dolin, Delmar Thomson Learning, 5th Edition,
pages 293-328.
[0042] Rotogravure (also referred in the art as gravure) is a printing process wherein the
image elements are engraved into the surface of a cylinder. The non-image areas are
at a constant original level. Prior to printing, the entire printing plate (non-printing
and printing elements) is inked and flooded with ink. Ink is removed from the non-image
by a wiper or a blade before printing, so that ink remains only in the cells. The
image is transferred from the cells to the substrate by a pressure typically in the
range of 2 to 4 bars and by the adhesive forces between the substrate and the ink.
The term rotogravure does not encompass intaglio printing processes (also referred
in the art as engraved steel die or copper plate printing processes) which rely for
example on a different type of ink. More details are provided in "
Handbook of print media", Helmut Kipphan, Springer Edition, page 48 and in
The Printing ink manual, R.H. Leach and R.J. Pierce, Springer Edition, 5th Edition,
pages 42-51.
[0043] Flexography preferably uses a unit with a doctor blade, preferably a chambered doctor
blade, an anilox roller and plate cylinder. The anilox roller advantageously has small
cells whose volume and/or density determines the ink application rate. The doctor
blade lies against the anilox roller, and scraps off surplus ink at the same time.
The anilox roller transfers the ink to the plate cylinder which finally transfers
the ink to the substrate. Specific design might be achieved using a designed photopolymer
plate. Plate cylinders can be made from polymeric or elastomeric materials. Polymers
are mainly used as photopolymer in plates and sometimes as a seamless coating on a
sleeve. Photopolymer plates are made from light-sensitive polymers that are hardened
by ultraviolet (UV) light. Photopolymer plates are cut to the required size and placed
in an UV light exposure unit. One side of the plate is completely exposed to UV light
to harden or cure the base of the plate. The plate is then turned over, a negative
of the job is mounted over the uncured side and the plate is further exposed to UV
light. This hardens the plate in the image areas. The plate is then processed to remove
the unhardened photopolymer from the nonimage areas, which lowers the plate surface
in these nonimage areas. After processing, the plate is dried and given a post-exposure
dose of UV light to cure the whole plate. Preparation of plate cylinders for flexography
is described in
Printing Technology, J. M. Adams and P.A. Dolin, Delmar Thomson Learning, 5th Edition,
pages 359-360 and in
The Printing ink manual, R.H. Leach and R.J. Pierce, Springer Edition, 5th Edition,
pages 33-42.
[0044] The first and second radiation curable coating compositions are independently applied
during steps a') and a") thus forming the first coating layer (x20') and the second
coating layer (x20"), respectively. The first and second radiation curable coating
compositions independently comprise a binder and the platelet-shaped magnetic or magnetizable
pigment particles described herein. The first radiation curable coating composition
is applied during step a') on the substrate (x10) thus forming the first coating layer
(x20') and the second radiation curable coating composition may be applied either
on the same side (see Figs 7A and 8A) as the first coating layer (x20') or on the
opposite side, i.e. the side of the substrate (x10) lacking the first coating layer
(x20') (see Figs 7B and 8B) in register during step a") thus forming the second coating
layer (x20").
[0045] According to one embodiment, the first radiation curable coating composition exhibits
a color and the second radiation curable coating composition exhibits the same color
with the naked eyes. According to one embodiment, the first and second radiation curable
coating compositions have different binders but comprise the same platelet-shaped
magnetic or magnetizable pigment particles so that they exhibit the same color with
the naked eyes. According to another embodiment, the first and second radiation curable
coating compositions are the same, i.e. they comprise the same binder and comprise
the same platelet-shaped magnetic or magnetizable pigment particles. According to
one embodiment wherein the OEL comprises a third motif, the first radiation curable
coating composition exhibits a color, the second radiation curable coating composition
exhibits the same color with the naked eyes and the third radiation curable coating
composition exhibits the same color with the naked eyes as the first and the second
compositions with the naked eyes.
[0046] According to one embodiment, the first radiation curable coating composition exhibits
a first color and the second radiation curable coating composition exhibits a second
color, said second color being different from the first color as observed with the
naked eyes. According to one embodiment, the first and second radiation curable coating
compositions have a same binder but comprise different platelet-shaped magnetic or
magnetizable pigment particles so that they exhibit a different color with the naked
eyes. According to said embodiment, the so-obtained OEL not only exhibit an eye catching
effect due to its dynamic and highly bright effect but also a high level of counterfeit
resistance due to the sophisticated adjacent motifs of different colors.
[0047] According to one embodiment, the first and second radiation curable coating compositions
comprise the same platelet-shaped magnetic or magnetizable pigment particles but comprise
a different binder, the binder of the first composition comprising a dye and/or a
colorant so that the compositions exhibit a different color with the naked eyes. According
to one embodiment, the first and second radiation curable coating compositions comprise
the same platelet-shaped magnetic or magnetizable pigment particles but comprise a
different binder, the binder of the second composition comprising a dye and/or a colorant
so that the compositions exhibit a different color with the naked eyes. According
to one embodiment, the first and second radiation curable coating compositions comprise
the same platelet-shaped magnetic or magnetizable pigment particles but comprise a
different binder, the binder of the first composition comprising a dye and/or colorant
and the binder of the second composition comprising a dye and/or a colorant having
a different color so that the compositions exhibit a different color with the naked
eyes. For optically variable platelet-shaped magnetic or magnetizable pigment particles,
i.e. pigments exhibiting a different color upon tilting (i.e. exhibiting a face color
and a different angle color), "different colors" refer to different face colors or
different angle colors or different face and angle colors. According to one embodiment,
the first radiation curable coating composition comprises optically variable platelet-shaped
magnetic or magnetizable pigment particles having a first face color and a first angle
color and the second radiation curable coating composition comprises optically variable
platelet-shaped magnetic or magnetizable pigment particles having a second face color
and a second angle color, wherein the first face color is different from the second
face color and the first angle color is different from the second angle color. According
to one embodiment, the first radiation curable coating composition comprises optically
variable platelet-shaped magnetic or magnetizable pigment particles having a first
face color and a first angle color and the second radiation curable coating composition
comprises optically variable platelet-shaped magnetic or magnetizable pigment particles
having a second face color and a second angle color, wherein the first face color
is the same as the second face color and the first angle color is different from the
second angle color. According to one embodiment, the first radiation curable coating
composition comprises optically variable platelet-shaped magnetic or magnetizable
pigment particles having a first face color and a first angle color and the second
radiation curable coating composition comprises optically variable platelet-shaped
magnetic or magnetizable pigment particles having a second face color and a second
angle color, wherein the first face color is different from the second face color
and the first angle color is the same as the second angle color.
[0048] According to one embodiment wherein the OEL comprises a third motif, the first radiation
curable coating composition exhibits a color, the second radiation curable coating
composition exhibits the same color with the naked eyes and the third radiation curable
coating composition exhibits a different color with the naked eyes; or the first radiation
curable coating composition exhibits a color, the third radiation curable coating
composition exhibits the same color with the naked eyes and the second radiation curable
coating composition exhibits a different color with the naked eyes; or the second
radiation curable coating composition exhibits a color, the third radiation curable
coating composition exhibits the same color with the naked eyes and the first radiation
curable coating composition exhibits a different color with the naked eyes. According
to one embodiment wherein the OEL comprises a third motif, the first radiation curable
coating composition exhibits a color, the second radiation curable coating composition
exhibits a different color with the naked eyes and the third radiation curable coating
composition exhibits a different color with the naked eyes (or in other words the
first, second and third compositions have different colors).
[0049] The first and second coating compositions described herein as well as the first coating
layer (x20') and the second coating layer (x20") described herein comprise the platelet-shaped
magnetic or magnetizable pigment particles described herein. In contrast to needle-shaped
pigment particles which can be considered as quasi one-dimensional particles, platelet-shaped
pigment particles are quasi two-dimensional particles due to the large aspect ratio
of their dimensions. As shown in Fig. 2, platelet-shaped pigment particle can be considered
as a two-dimensional structure wherein the dimensions X and Y are substantially larger
than the dimension Z. Platelet-shaped pigment particles are also referred in the art
as oblate particles or flakes. Such pigment particles may be described with a main
axis X corresponding to their longest dimension crossing the pigment particle and
a second axis Y perpendicular to X and corresponding to the second longest dimension
crossing the pigment particle. In other words, the XY plane roughly defines the plane
formed by the first and second longest dimensions of the pigment particle, the Z dimension
being ignored.
[0050] The platelet-shaped magnetic or magnetizable pigment particles described herein have,
due to their non-spherical shape, non-isotropic reflectivity with respect to incident
electromagnetic radiation for which the hardened/cured binder material is at least
partially transparent. As used herein, the term "non-isotropic reflectivity" denotes
that the proportion of incident radiation from a first angle that is reflected by
a particle into a certain (viewing) direction (a second angle) is a function of the
orientation of the particles, i.e. that a change of the orientation of the particle
with respect to the first angle can lead to a different magnitude of the reflection
to the viewing direction.
[0051] In the first and second motifs of the OELs described herein, the platelet-shaped
magnetic or magnetizable pigment particles described herein are dispersed in the first
and second coating layers (x20' and x20"), respectively, said layers independently
comprising a hardened binder material that fixes the orientation of the platelet-shaped
magnetic or magnetizable pigment particles. The binder material is at least in its
hardened or solid state (also referred to as second state herein), at least partially
transparent to electromagnetic radiation of a range of wavelengths comprised between
200 nm and 2500 nm, i.e. within the wavelength range which is typically referred to
as the "optical spectrum" and which comprises infrared, visible and UV portions of
the electromagnetic spectrum. Accordingly, the particles contained in the binder material
in its hardened or solid state and their orientation-dependent reflectivity can be
perceived through the binder material at some wavelengths within this range. Preferably,
the hardened binder material is at least partially transparent to electromagnetic
radiation of a range of wavelengths comprised between 200 nm and 800 nm, more preferably
comprised between 400 nm and 700 nm. Herein, the term "transparent" denotes that the
transmission of electromagnetic radiation through a layer of 20 µm of the hardened
binder material as present in the OEL (not including the platelet-shaped magnetic
or magnetizable pigment particles, but all other optional components of the OEL in
case such components are present) is at least 50%, more preferably at least 60 %,
even more preferably at least 70%, at the wavelength(s) concerned. This can be determined
for example by measuring the transmittance of a test piece of the hardened binder
material (not including the platelet-shaped magnetic or magnetizable pigment particles)
in accordance with well-established test methods, e.g. DIN 5036-3 (1979-11).
[0052] The platelet-shaped magnetic or magnetizable pigment particles described herein are
defined as having, due to their non-spherical shape, non-isotropic reflectivity with
respect to an incident electromagnetic radiation for which the cured binder material
is at least partially transparent. As used herein, the term "non-isotropic reflectivity"
denotes that the proportion of incident radiation from a first angle that is reflected
by a particle into a certain (viewing) direction (a second angle) is a function of
the orientation of the particles, i.e. that a change of the orientation of the particle
with respect to the first angle can lead to a different magnitude of the reflection
to the viewing direction. Preferably, the platelet-shaped magnetic or magnetizable
pigment particles described herein have a non-isotropic reflectivity with respect
to incident electromagnetic radiation in some parts or in the complete wavelength
range of from about 200 to about 2500 nm, more preferably from about 400 to about
700 nm, such that a change of the particle's orientation results in a change of reflection
by that particle into a certain direction. As known by the man skilled in the art,
the magnetic or magnetizable pigment particles described herein are different from
conventional pigments, in that said conventional pigment particles exhibit the same
color and reflectivity, independent of the particle orientation, whereas the magnetic
or magnetizable pigment particles described herein exhibit either a reflection or
a color, or both, that depend on the particle orientation.
[0053] The first and second radiation curable coating compositions described herein as well
as the first and second coating layers (x20', x20") described herein independently
comprise the platelet-shaped magnetic or magnetizable pigment particles described
herein preferably in an amount from about 1 wt.% and about 40 wt.%, preferably between
about 3 wt.% and about 35 wt.%, more preferably between about 5 wt.% and about 30
wt.%, the weight percentages being based on the total weight of the radiation curable
coating composition or the coating layer.
[0054] Suitable examples of platelet-shaped magnetic or magnetizable pigment particles described
herein include without limitation pigment particles comprising a magnetic metal selected
from the group consisting of cobalt (Co), iron (Fe), and nickel (Ni); a magnetic alloy
of iron, manganese, cobalt, nickel or a mixture of two or more thereof; a magnetic
oxide of chromium, manganese, cobalt, iron, nickel or a mixture of two or more thereof;
or a mixture of two or more thereof. The term "magnetic" in reference to the metals,
alloys and oxides is directed to ferromagnetic or ferrimagnetic metals, alloys and
oxides. Magnetic oxides of chromium, manganese, cobalt, iron, nickel or a mixture
of two or more thereof may be pure or mixed oxides. Examples of magnetic oxides include
without limitation iron oxides such as hematite (Fe
2O
3), magnetite (Fe
3O
4), chromium dioxide (CrO
2), magnetic ferrites (MFe
2O
4), magnetic spinels (MR
2O
4), magnetic hexaferrites (MFe
12O
19), magnetic orthoferrites (RFeOs), magnetic garnets M
3R
2(AO
4)
3, wherein M stands for two-valent metal, R stands for three-valent metal, and A stands
for four-valent metal.
[0055] Examples of platelet-shaped magnetic or magnetizable pigment particles described
herein include without limitation pigment particles comprising a magnetic layer M
made from one or more of a magnetic metal such as cobalt (Co), iron (Fe), or nickel
(Ni); and a magnetic alloy of iron, cobalt or nickel, wherein said magnetic or magnetizable
pigment particles may be multilayered structures comprising one or more additional
layers. Preferably, the one or more additional layers are layers A independently made
from one or more selected from the group consisting of metal fluorides such as magnesium
fluoride (MgF
2), silicon oxide (SiO), silicon dioxide (SiO
2), titanium oxide (TiO
2), and aluminum oxide (Al
2O
3), more preferably silicon dioxide (SiO
2); or layers B independently made from one or more selected from the group consisting
of metals and metal alloys, preferably selected from the group consisting of reflective
metals and reflective metal alloys, and more preferably selected from the group consisting
of silver (Ag), aluminum (Al), chromium (Cr), and nickel (Ni), and still more preferably
aluminum (Al); or a combination of one or more layers A such as those described hereabove
and one or more layers B such as those described hereabove. Typical examples of the
platelet-shaped magnetic or magnetizable pigment particles being multilayered structures
described hereabove include without limitation A/M multilayer structures, A/M/A multilayer
structures, A/M/B multilayer structures, A/B/M/A multilayer structures, A/B/M/B multilayer
structures, A/B/M/B/A/multilayer structures, B/M multilayer structures, B/M/B multilayer
structures, M/A/M multilayer structures, B/A/M/A multilayer structures, B/A/M/B multilayer
structures, B/A/M/B/A multilayer structures, B/A/M/A/B multilayer structures, B/A/B/A/M/A/B/A/B
multilayer structures, A/B/A/B/A/M/A/B/A/B/A multilayer structures, wherein the layers
A, the magnetic layers M and the layers B are chosen from those described hereabove.
[0056] The UV-Vis radiation curable coating composition described herein may comprise platelet-shaped
optically variable magnetic or magnetizable pigment particles, and/or platelet-shaped
magnetic or magnetizable pigment particles having no optically variable properties.
Preferably, at least a part of the platelet-shaped magnetic or magnetizable pigment
particles described herein is constituted by platelet-shaped optically variable magnetic
or magnetizable pigment particles. In addition to the overt security provided by the
colorshifting property of the optically variable magnetic or magnetizable pigment
particles, which allows easily detecting, recognizing and/or discriminating an article
or security document carrying an ink, coating composition, or coating layer comprising
the optically variable magnetic or magnetizable pigment particles described herein
from their possible counterfeits using the unaided human senses, the optical properties
of the optically variable magnetic or magnetizable pigment particles may also be used
as a machine readable tool for the recognition of the OEL. Thus, the optical properties
of the optically variable magnetic or magnetizable pigment particles may simultaneously
be used as a covert or semi-covert security feature in an authentication process wherein
the optical (e.g. spectral) properties of the pigment particles are analyzed and thus
increase the counterfeiting resistance.
[0057] The use of platelet-shaped optically variable magnetic or magnetizable pigment particles
in coating layers for producing an OEL enhances the significance of the OEL as a security
feature in security document applications, because such materials are reserved to
the security document printing industry and are not commercially available to the
public.
[0058] As mentioned above, preferably at least a part of the platelet-shaped magnetic or
magnetizable pigment particles is constituted by platelet-shaped optically variable
magnetic or magnetizable pigment particles. These are more preferably selected from
the group consisting of platelet-shaped magnetic thin-film interference pigment particles,
platelet-shaped interference coated pigment particles.
[0059] Magnetic thin film interference pigment particles are known to those skilled in the
art and are disclosed e.g. in
US 4,838,648;
WO 2002/073250 A2;
EP 0 686 675 B1;
WO 2003/000801 A2;
US 6,838,166;
WO 2007/131833 A1;
EP 2 402 401 B1;
WO 2019/103937 A1;
EP 3 587 500 A1,
EP 3 587 501 A1,
EP 3 587 502 A1,
EP 3 587503 A1,
WO 2020/006286 A1,
WO 2020/131700 A1,
US 2021/0101402,
US 2021/038812,
US 2022/0282094, and in the documents cited therein. Preferably, the magnetic thin film interference
pigment particles comprise pigment particles having a five-layer Fabry-Perot multilayer
structure and/or pigment particles having a six-layer Fabry-Perot multilayer structure
and/or pigment particles having a seven-layer Fabry-Perot multilayer structure and/or
pigment particles having a nine-layer Fabry-Perot multilayer structure and/or pigment
particles having an eleven-layer Fabry-Perot multilayer structure and/or pigment particles
having a multilayer structure combining one or more multilayer Fabry-Perot structures.
[0060] Preferred five-layer Fabry-Perot multilayer structures consist of absorber/dielectric/reflector/dielectric/absorber
multilayer structures wherein the reflector and/or the absorber is also a magnetic
layer, preferably the reflector and/or the absorber is a magnetic layer comprising
nickel, iron and/or cobalt, and/or a magnetic alloy comprising nickel, iron and/or
cobalt and/or a magnetic oxide comprising nickel (Ni), iron (Fe) and/or cobalt (Co).
[0061] Further preferred five-layer Fabry-Perot multilayer structures consist of dielectric/reflector/magnetic/reflector/dielectric
multilayer structures.
[0062] Preferred six-layer Fabry-Perot multilayer structures consist of absorber/dielectric/reflector/magnetic/dielectric/absorber
multilayer structures.
[0063] Preferred seven-layer Fabry Perot multilayer structures consist of absorber/dielectric/reflector/magnetic/reflector/dielectric/absorber
multilayer structures such as disclosed in
US 4,838,648.
[0064] Preferred nine-layer Fabry-Perot multilayer structures consist of dielectric/absorber/dielectric/reflector/magnetic/dielectric/absorber/dielectric
multilayer structures.
[0065] Preferred eleven-layer Fabry-Perot multilayer structures consist of absorber/dielectric/absorber/dielectric/reflector/magnetic/reflector/dielectric/absorber/dielectric/absorber
multilayer structures.
[0066] Preferably, the reflector layers described herein are independently made from one
or more selected from the group consisting of metals and metal alloys, preferably
selected from the group consisting of reflective metals and reflective metal alloys,
more preferably selected from the group consisting of aluminum (Al), silver (Ag),
copper (Cu), gold (Au), platinum (Pt), tin (Sn), titanium (Ti), palladium (Pd), rhodium
(Rh), niobium (Nb), chromium (Cr), nickel (Ni), and alloys thereof, even more preferably
selected from the group consisting of aluminum (Al), chromium (Cr), nickel (Ni) and
alloys thereof, and still more preferably aluminum (Al). Preferably, the dielectric
layers are independently made from one or more selected from the group consisting
of metal fluorides such as magnesium fluoride (MgF
2), aluminum fluoride (AlF
3), cerium fluoride (CeF
3), lanthanum fluoride (LaF
3), sodium aluminum fluorides (e.g. Na
3AlF
6), neodymium fluoride (NdF
3), samarium fluoride (SmF
3), barium fluoride (BaF
2), calcium fluoride (CaF
2), lithium fluoride (LiF), and metal oxides such as silicon oxide (SiO), silicium
dioxide (SiO
2), titanium oxide (TiO
2), aluminum oxide (Al
2O
3), more preferably selected from the group consisting of magnesium fluoride (MgF
2) and silicon dioxide (SiO
2) and still more preferably magnesium fluoride (MgF
2). Preferably, the absorber layers are independently made from one or more selected
from the group consisting of aluminum (Al), silver (Ag), copper (Cu), palladium (Pd),
platinum (Pt), titanium (Ti), vanadium (V), iron (Fe) tin (Sn), tungsten (W), molybdenum
(Mo), rhodium (Rh), Niobium (Nb), chromium (Cr), nickel (Ni), metal oxides thereof,
metal sulfides thereof, metal carbides thereof, and metal alloys thereof, more preferably
selected from the group consisting of chromium (Cr), nickel (Ni), metal oxides thereof,
and metal alloys thereof, and still more preferably selected from the group consisting
of chromium (Cr), nickel (Ni), and metal alloys thereof. Preferably, the magnetic
layer comprises nickel (Ni), iron (Fe) and/or cobalt (Co); and/or a magnetic alloy
comprising nickel (Ni), iron (Fe) and/or cobalt (Co); and/or a magnetic oxide comprising
nickel (Ni), iron (Fe) and/or cobalt (Co). When magnetic thin film interference pigment
particles comprising a seven-layer Fabry-Perot structure are preferred, it is particularly
preferred that the magnetic thin film interference pigment particles comprise a seven-layer
Fabry-Perot absorber/dielectric/reflector/magnetic/reflector/dielectric/absorber multilayer
structure consisting of a Cr/MgF
2/Al/M/Al/MgF
2/Cr multilayer structure wherein M is Ni, Fe or Co.
[0067] The magnetic thin film interference pigment particles described herein may be multilayer
pigment particles being considered as safe for human health and the environment and
being based for example on five-layer Fabry-Perot multilayer structures, six-layer
Fabry-Perot multilayer structures, seven-layer Fabry-Perot multilayer structures,
nine-layer Fabry-Perot multilayer structures, eleven-layer Fabry-Perot multilayer
structures and pigment particles having a multilayer structure combining one or more,
or two or more, multilayer Fabry-Perot structures, wherein said pigment particles
include one or more magnetic layers comprising a magnetic alloy having a substantially
nickel-free composition including about 40 wt.% to about 90 wt.% iron, about 10 wt.%
to about 50 wt.% chromium and about 0 wt.% to about 30 wt.% aluminum. Typical examples
of multilayer pigment particles being considered as safe for human health and the
environment can be found in
EP 2 402 401 B1 whose content is hereby incorporated by reference in its entirety.
[0068] Suitable interference coated pigment particles comprising one or more magnetic materials
include without limitation structures consisting of a substrate selected from the
group consisting of a core coated with one or more layers, wherein at least one of
the core or the one or more layers have magnetic properties. For example, suitable
interference coated pigment particles comprise a core made of a magnetic material
such as those described hereabove, said core being coated with one or more layers
made of one or more metal oxides, or they have a structure consisting of a core made
of synthetic or natural micas, layered silicates (e.g. talc, kaolin and sericite),
glasses (e.g. borosilicates), silicon dioxides (SiO
2), aluminum oxides (Al
2O
3), titanium oxides (TiO
2), graphites and mixtures of two or more thereof, said core being coated with one
or more magnetic materials. Furthermore, one or more additional layers such as coloring
layers may be present.
[0069] The platelet-shaped magnetic or magnetizable pigment particles of the first and second
described herein preferably have a size d50 between about 2 µm and about 50 µm (as
measured by direct optical granulometry).
[0070] The platelet-shaped magnetic or magnetizable pigment particles described herein may
be surface treated so as to protect them against any deterioration that may occur
in the coating composition and coating layer and/or to facilitate their incorporation
in said coating composition and coating layer; typically corrosion inhibitor materials
and/or wetting agents may be used.
[0071] Further, subsequently to the independent applications of the first and second radiation
curable coating compositions described herein so as to form the first coating layer
(x20') and the second coating layer (x20") (step a') and step a")) described herein,
said first and second radiation curable coating compositions of step a') and step
a") are independently exposed to the magnetic field of a magnetic assembly (x30',
x30", respectively) so as to independently magnetically orient at least a part of
the platelet-shaped magnetic or magnetizable pigment particles (step b') and step
b"), respectively).
[0072] The process described herein comprises at least two independent steps b') and b")
consisting of exposing the first and second radiation curable coating compositions
described herein to the magnetic field of magnetic assemblies so as to magnetically
orient at least a part of the platelet-shaped magnetic or magnetizable pigment particles,
wherein the step b") is carried out by exposing the second radiation curable coating
composition of step a") to the magnetic field of a magnetic assembly (x30") so as
to bi-axially orient said pigment particles.
[0073] During the orientation step b') and step b") described herein, the substrate (x10)
may be independently disposed on a non-magnetic supporting plate (x70) which is made
of one or more non-magnetic materials.
[0074] As described hereafter, "x30'" and "x30"" independently either refer to single magnets
or refer to assemblies (x30) comprising two or more magnets or refer to assemblies
comprising one or more magnets and an engraved magnetic plate, or refer to assemblies
comprising one or more magnets and a soft magnetic plate or refers to an assembly
comprising a magnet and one or more pole pieces or comprising two or more magnets
and one or more pole pieces, said magnetic assemblies (x30' and x30") being selected
according to the design of the orientation patterns of the first and second motifs
of the OELs to be produced. Should the magnetic assemblies (x30' and x30") comprise
more than one components, the platelet-shaped magnetic or magnetizable pigment particles
are exposed to the resultant magnetic field of said more than one components.
[0075] The process described herein comprises the orientation step b') described herein.
[0076] According to one embodiment shown for example in Fig. 3A, the orientation step b')
of the first set of steps (S1) is a one-step orientation step, wherein the substrate
(310) carrying the first coating layer (320') obtained by screen printing (340') (step
a')) is exposed to the magnetic field of a magnetic assembly (330') and wherein the
first coating layer (320') is, partially simultaneously with step b'), at least partially
cured with a first curing unit (350') (step c')).
[0077] According to one embodiment shown for example in Fig. 4A, the orientation step b')
of the first set of steps (S1) is a one-step orientation step, wherein an assembly
comprising the substrate (410) carrying the first coating layer (420') described herein
is placed on a first magnetic assembly (430'-a) and said assembly is concomitantly
moved in the vicinity of a static second magnetic assembly (430'-b).
[0078] According to one embodiment shown for example 4B, the process described herein allows
the preparation of OELs, wherein step b') consists of placing the substrate (410)
carrying the first coating layer (420') on a first magnetic assembly (430'-a) providing
a first magnetic field vector component, said first magnetic assembly being mounted
on a rotating magnetic cylinder thereby subjecting the platelet-shaped magnetic or
magnetizable pigment particles to said first magnetic field vector component and concomitantly
moving said substrate (410) carrying the first coating layer (420') and said first
magnetic assembly (430'-a) in the vicinity of a static second magnetic assembly (430'-b),
said second magnetic assembly (430'-b), providing a second magnetic field vector component,
thereby subjecting the platelet-shaped magnetic or magnetizable pigment particles
to a time-dependent resultant magnetic field formed by the first and second magnetic
field vector components so as to bi-axially orient at least a part of the platelet-shaped
magnetic or magnetizable pigment particle. According to one embodiment, the ratio
of the magnetic flux density of the first magnetic assembly (430'-a) and the magnetic
flux density of the static second first magnetic assembly (430'-b) is less than about
4.0, preferably less than about 1.9 and more preferably between about 1.5 and about
0.5. The first magnetic assembly (430'-a) onto which the substrate (410) carrying
the first coating layer (420') is preferably selected from the magnetic assemblies
described hereabove for orienting pigment particles and the soft magnetic plates described
hereabove. The second magnetic assembly (430'-b) is preferably selected from the magnetic
assemblies described hereabove for bi-axially orienting pigment particles. Such processes
are disclosed in
WO 2019/14142 A1 and
WO 2019/141453 A1.
[0079] According to one embodiment shown for example in Fig. 5A, the orientation step b')
of the first set of steps (S1) is a two-steps orientation step, said two-steps orientation
step consisting of the two following ones: a first orienting step (b'-1) to bi-axially
orient the platelet-shaped magnetic or magnetizable pigment particles such as described
herein followed by a second orienting step to re-orient (b'-2) the platelet-shaped
magnetic or magnetizable pigment particles such as described herein, wherein the substrate
(510) carrying the first coating layer (520') is exposed to the magnetic field of
a magnetic assembly (530'-a) and subsequently to the magnetic field of a magnetic
assembly (530'-b), said both magnetic assemblies (530'-a and 530'-b) being positioned
on the second side of the substrate (i.e. the side lacking the first coating layer
(520')). Fig. 5B (not true to scale) illustrates a process wherein the orientation
step b') consists of a two-steps orientation step, wherein the first radiation curable
coating composition described herein is first exposed to the magnetic field of a first
magnetic assembly (530'-a) and subsequently exposed to the magnetic field of a second
magnetic assembly (530'-b), wherein said second magnetic assembly (530'-b) is mounted
on a rotating magnetic cylinder.
[0080] According to one embodiment shown for example in Fig. 6A-B, the orientation step
b') of the first set of steps (S1) is a two-steps orientation step, said step two-steps
consisting of the two following ones: a first orienting step (b'-1) to bi-axially
orient the platelet-shaped magnetic or magnetizable pigment particles such as described
herein followed by a second orienting step to re-orient (b'-2) the platelet-shaped
magnetic or magnetizable pigment particles such as described herein, wherein the substrate
(610) carrying the first coating layer (620') is exposed to the magnetic field of
the magnetic assembly (630'-a) and subsequently to the resultant magnetic field of
second magnetic assembly (630'-b) and of a third magnetic assembly (630'-c), said
magnetic assemblies (630'-a, 630'-b, 630'-c) being positioned on the side lacking
the first coating layer (620').
[0081] Fig. 6B (not true to scale) illustrates a process wherein the orientation step b')
of the first set of steps (S1) is a two-steps orientation step, said step two-steps
consisting of the two following ones: a first orienting step (b'-1) to bi-axially
orient the platelet-shaped magnetic or magnetizable pigment particles such as described
herein followed by a second orienting step to re-orient (b'-2) the platelet-shaped
magnetic or magnetizable pigment particles such as described herein, wherein the substrate
(610) carrying the first coating layer (620') is exposed to the magnetic field of
the magnetic assembly (630'-a) and subsequently to the resultant magnetic field of
a second magnetic assembly (630'-b) and of a third magnetic assembly (630'-c), said
magnetic assemblies 630'-a and 630'-b being positioned on the side lacking the first
coating layer (620') and said magnetic assembly 630'-c being positioned on the side
comprising the first coating layer (620'), wherein the magnetic assembly 630'-b is
mounted on a rotating magnetic cylinder and the magnetic assembly 630'-c is placed
outside the rotating magnetic cylinder. Suitable processes wherein the orientation
steps b') consist of a two-steps orientation step are disclosed in
WO 2015/086257 A1.
[0082] According to one embodiment, the process described herein allows the preparation
of OELs wherein the first motif exhibits one or more indicia, wherein step b') consists
of exposing the radiation curable coating composition to an engraved magnetic plate
(x30), wherein said engraved magnetic plate (x30) comprises one or more engravings
(I) having the shape of the one or more indicia. The engraved magnetic plate (x30)
described herein is preferably made from a permanent magnetic powder material and
a polymer. The engraved magnetic plate (x30) described herein may typically be produced
by an injection molding process or by metal or laser engraving. Preferred permanent
magnetic powder materials include cobalt, iron and their alloys, chromium dioxide,
generic magnetic oxide spinels, generic magnetic garnets, generic magnetic ferrites
including the hexaferrites such as calcium-, strontium-, and barium-hexaferrite (CaFe12019,
SrFe12019, BaFe12019, respectively), generic alnico alloys, generic samarium-cobalt
(SmCo) alloys, and generic rare-earth-iron-boron alloys (such as NdFeB), as well as
the permanent-magnetic chemical derivatives thereof (such as indicated by the term
generic) and mixtures thereof. Plates made of a composite material comprising a polymer
and a permanent magnetic powder are obtainable from many different sources, such as
from Bomatec, Höri, CH, ARNOLD
® Magnetic Technologies (Plastiform
®) or from Materiali Magnetici, Albairate, Milano, IT (Plastoferrite).
[0083] According to one embodiment, the process described herein allows the preparation
of OELs wherein a first motif exhibits a dynamic movement upon tilting said OEL and
one or more indicia, wherein said step b') consists of exposing the radiation curable
coating composition to a magnetic assembly (x30) comprising a bar dipole magnet and
an engraved magnetic plate, wherein said engraved magnetic plate comprises one or
more engravings having the shape of the one or more indicia, wherein the engraved
magnetic plate is placed above the bar dipole magnet.
[0084] According to one embodiment, the process described herein comprises the step b')
consisting of exposing the first radiation curable coating composition to a magnetic
assembly such as those disclosed in
US 8,025,952 and
EP 1 819 525 B1 and
WO 2022/049024 A1, wherein this effect is so-called Venetian-blind" effect. Fig. 5A-B of
US 7,047,883 discloses a magnetic assembly comprising two spaced apart magnets 84 placed on a
magnetic base 62 with their North poles facing the substrate. Fig. 9B of
US 7,047,883 discloses a magnetic assembly comprising a magnet 140 and the substrate comprising
the coating layer being placed with an offset position relatively the magnet axes.
Fig. 9C of
US 7,047,883 discloses a magnetic assembly comprising two magnets 142 and one magnet 142' having
a diamond-shaped cross section, wherein the two magnets 142 have their North pole
facing the substrate while the intervening magnet 142' has its South pole facing the
substrate. Fig. 9D of
US 7,047,883 discloses a magnetic assembly comprising two magnets 144, and one magnet 144' having
roof-shaped, hexagonal, rounded, trapezoidal, or other cross-sections, wherein the
two magnets 144 have their North pole facing the substrate while the intervening magnet
144' has its South pole facing the substrate. Fig. 9E of
US 7,047,883 discloses a magnetic assembly comprising five magnets, the first magnet 142 being
a diamond-shaped magnet with its North pole facing the substrate, the second magnet
146 being a rectangular magnet with its South pole facing the substrate, the third
magnet 148 being a magnet with rounded top having its North pole facing the substrate,
the fourth magnet 150 being a roof-shaped and having its South pole facing the substrate
and the fifth magnet 152 being also a roof-shaped magnet and having its North pole
facing the substrate. Fig. 4A1 of
WO 2022/049024 A1 discloses a magnetic assembly comprising a bar dipole magnet and the particles are
exposed to the magnetic field (magnetic field lines shown as lines with arrows pointing
from the North Pole to the South Pole) of the magnetic assembly in one or more areas
(shown as a dotted rectangle A) wherein the magnetic field is substantially homogeneous
and wherein the magnetic field lines are substantially parallel to each other in said
one or more areas. Fig. 4A2 of
WO 2022/0490241 A discloses a magnetic assembly comprising two bar dipole magnets (M1, M2) having a
same magnetic direction and an iron yoke (Y) and the particles are exposed to the
magnetic field (magnetic field lines shown as lines with arrows pointing from the
North Pole to the South Pole) of the magnetic assembly in one or more areas (shown
as a dotted rectangle A) wherein the magnetic field is substantially homogeneous and
wherein the magnetic field lines are substantially parallel to each other in said
one or more areas. Fig. 6A-B of
WO 2022/049024 A1 discloses a magnetic assembly comprising a rectangular assembly comprising two bar
dipole magnets (M1, M2) and two pole pieces (P1, P2) and the particles are exposed
to the magnetic field (magnetic field lines shown as lines with arrows pointing from
the North Pole to the South Pole) of the magnetic assembly in one or more areas (shown
as a dotted rectangle A) wherein the magnetic field is substantially homogeneous and
wherein the magnetic field lines are substantially parallel to each other in said
area.
[0085] According to one embodiment shown for example in Fig. 11 (examples E1-E5, magnetic
assembly (1130) used during step b'), the process described herein allows the preparation
of OELs wherein the first motif exhibits a dynamic motion upon tilting said OEL, said
dynamic movement being a bright reflective horizontal bar moving in a vertical direction
(up/down) when the OEL is tilted around a horizontal axis; wherein said step b') consists
of exposing the first radiation curable coating composition to a bar dipole magnet
having a magnetic axis oriented to be substantially parallel to a substrate and substantially
parallel to the machine feed direction. This effect is the so-called "rolling bar"
effect, as disclosed in
US 2005/0106367. A "rolling bar" effect is based on pigment particles orientation imitating a curved
surface across the coating. The observer sees a specular reflection zone/bar which
moves away or towards the observer as the OEL is tilted.
[0086] According to another embodiment, the process described herein allows the preparation
of OELs wherein the first motif exhibits a dynamic motion upon tilting said OEL, said
dynamic movement of the OEL being a bright reflective vertical bar moving in a horizontal
(left/right) direction when the OEL is tilted around a vertical axis; wherein said
step b') consists of exposing the first radiation curable coating composition to a
bar dipole magnet having a magnetic axis oriented to be substantially parallel to
the substrate and substantially perpendicular to the machine feed direction. This
effect is the so-called "rolling bar" effect, as disclosed in
US 2005/0106367.
[0087] According to another embodiment, the process described herein allows the preparation
of OELs wherein the first motif exhibits a dynamic motion upon tilting said OEL, said
dynamic movement of the OEL being a bright reflective vertical bar moving in a horizontal
(left/right) direction when the OEL is tilted around a horizontal axis; wherein said
step b') consists of exposing the first radiation curable coating composition to a
magnetic assembly such as those disclosed in
WO 2020/160993 A1. Figs 2-5 of
WO 2020/160993 A1 discloses magnetic assemblies comprising a) at least one dipole magnet (x40) being
a square-shaped or rectangle-shaped dipole magnet having its magnetic axis oriented
to be substantially parallel to a substrate and b) a combination of n sets of spaced
apart bar dipole magnets (x30-a1, x30-a2) with n being an integer equal to or bigger
than 1, wherein each of said bar dipole magnets (x30-a1, x30-a2) has its North-South
magnetic axis substantially parallel to the substrate surface, wherein, for each set
of said n sets, the bar dipole magnets (x30-a1, x30-a2) have their North pole pointing
in a same direction and are substantially parallel to each other; wherein the vector
sum H1 of the magnetic axes of the bar dipole magnets (x30-a1 , x30-a2) and the vector
sum H2 of the at least one dipole magnet (x40) form an angle α in the range from about
5° to about 175° or in the range from about 185° to about 355°; wherein the combination
of n sets of spaced apart bar dipole magnets (x30-a1, x30-a2) is placed below or above
the at least one dipole magnet (x40), and wherein the at least one dipole magnet (x40)
and the combination of n sets of spaced apart bar dipole magnets (x30-b1 , x30-b2)
are essentially centered with respect to one another (see for example Figs 2-5 of
WO 2020/160993 A1).
[0088] According to another embodiment, the process described herein allows the preparation
of OELs wherein the first motif exhibits a dynamic motion upon tilting said OEL, said
dynamic movement of the OEL a bright reflective horizontal bar moving in a vertical
direction (up/down) when the OEL is tilted around a horizontal axis; wherein said
step b') consists of exposing the first radiation curable coating composition to a
magnetic assembly such as those disclosed in
WO 2014/198905 A2. Figs 5-9 of
WO 2014/198905 A2 disclose magnetic assemblies comprising:
- a) a bar dipole magnet (M1) and a pair of bar dipole magnets (M2) and (M3), said bar
dipole magnets (M1), (M2) and (M3) having their North-South axis substantially parallel
to the substrate and the same magnetic North-South direction, wherein a1) said bar
dipole magnet (M1) is disposed below the substrate and said pair of bar dipole magnets
(M2) and (M3) are disposed below the bar dipole magnet (M1) apart from each other;
or a2) said pair of bar dipole magnets (M2) and (M3) are disposed below the substrate
and apart from each other, and said bar dipole magnet (M1) is disposed below said
pair of bar dipole magnets (M2) and (M3); or
- b) a pair of bar dipole magnets (M4) and (M5) and a pole piece (Y), said pair of bar
dipole magnets (M4) and (M5) having their North-South axis substantially parallel
to the substrate and the same magnetic North-South direction, said pole piece (Y)
being disposed between said bar dipole magnet (M4) and said bar dipole magnet (M5);
or
- c) a pair of bar dipole magnets (M4) and (M5), a pole piece (Y) and a magnetic plate
(M6), said pair of bar dipole magnets (M4) and (M5) having their North-South axis
substantially parallel to the substrate and the same magnetic North-South direction,
said magnetic plate (M6) having its North-South axis substantially perpendicular to
the substrate, said pole piece (Y) being disposed between said bar dipole magnet (M4)
and said bar dipole magnet (M5). Particularly suitable magnetic assemblies are those
shown in Figs 5c, 6c and 7d of WO 2014/198905 A2.
[0089] According to one embodiment, the process described herein allows the preparation
of OELs wherein at least one of the first motif and second motif exhibits a dynamic
motion upon tilting said OEL, said dynamic movement being a pattern of bright areas
and dark areas moving when the OEL is tilted; wherein said steps b') consists of exposing
the radiation curable coating composition to a magnetic assembly such as those disclosed
in
WO 2013/167425 A1 and
WO 2021/083809 A1. Disclosed magnetic assemblies of
WO 2021/083809 A1 comprise at least one dipole magnet (x41) having a magnetic axis oriented to be substantially
parallel to the substrate and a combination comprising at least four additional dipole
magnets (x31) having their North poles pointing in a same direction and having their
magnetic axes oriented to be substantially parallel to the substrate, wherein each
of the additional dipole magnets (x31) is arranged on an intersection of at least
two substantially parallel straight lines α
i (i = 1, 2, ...) and at least two substantially parallel straight lines β
j(j = 1, 2, ...), the straight lines α
i and β
j forming a grid, wherein at least two additional dipole magnets (x31) are disposed
on one of the straight lines α
i and at least two other additional dipole magnets (x31) are disposed on another one
of the straight lines α
i, wherein the magnetic axes of the additional dipole magnets are oriented substantially
parallel to the substantially parallel straight lines α
i, wherein the at least one dipole magnet (x40) is disposed below the combination comprising
at least four dipole magnets (x31). According to one embodiment, each straight line
α
i and a vector H of the magnetic axis of the at least one dipole magnet (x41) is substantially
parallel or substantially perpendicular with respect to each other and the OEL exhibits
a dynamic movement being a pattern of bright areas and dark areas moving when the
substrate carrying said OEL is tilted, said pattern of bright areas and dark areas
moving in the same direction as the tilting direction. According to another embodiment,
each straight line α
i and a vector H of the magnetic axis of the at least one dipole magnet (x41) is substantially
non-parallel and substantially non-perpendicular with respect to each other OEL, preferably
wherein each straight line α
i and the vector sum H of the magnetic axis of the at least one dipole magnet (x41)
form an angle γ in the range from about 20° to about 70° or in the range from about
110° to about 160° or in the range from about 200° to about 250°, or in the range
from about 290° to about 340°; and the OEL exhibits a dynamic movement being a pattern
of bright areas and dark areas moving not only in a diagonal direction when the substrate
carrying said OEL is tilted around a vertical axis but also moving in a diagonal direction
when the substrate carrying said OEL is tilted around a horizontal axis (in other
words, the optical effect layer OEL described herein provides the optical impression
of a plurality of dark and a plurality of bright spots that are moving when the substrate
carrying said OEL is tilted around two perpendicular axes, i.e. horizontal axis and
vertical axis. Suitable magnetic assemblies are those shown in Figs 6-8 of
WO 2021/083809 A1.
[0090] According to one embodiment, the process described herein allows the preparation
of OELs wherein at least one of the first motif and second motif exhibits a dynamic
motion upon tilting said OEL, said dynamic movement being a pattern of bright areas
and dark areas moving when the OEL is tilted; wherein said steps b') consists of exposing
the radiation curable coating composition to a magnetic assembly such as those disclosed
in
WO 2021/083808 A1. Disclosed magnetic assemblies of
WO 2021/083808 A1 comprise at least one dipole magnet (x41) having a magnetic axis oriented to be substantially
parallel to the substrate and a combination comprising at least four additional dipole
magnets (x31) having their North poles pointing in a same direction and having their
magnetic axes oriented to be substantially parallel to the substrate, wherein each
of the additional dipole magnets (x31) is arranged on an intersection of at least
two substantially parallel straight lines α
i (i = 1, 2, ...) and at least two substantially parallel straight lines β
j(j = 1, 2, ...), the straight lines α
i and β
j forming a grid, wherein at least two additional dipole magnets (x31) are disposed
on one of the straight lines α
i and at least two other additional dipole magnets (x31) are disposed on another one
of the straight lines α
i, wherein the magnetic axes of the additional dipole magnets (x31) are oriented substantially
parallel to the substrate, straight lines α
i, wherein the at least one dipole magnet (x41) is disposed below the combination comprising
at least four first dipole magnets (x31), wherein, on each straight line α
i, and on each straight line β
j, neighboring additional dipole magnets (x31) have their North pole pointing in an
opposite direction, wherein each straight line α
i and a vector H of the magnetic axis of the at least one dipole magnet (x41) is substantially
non-parallel and substantially non-perpendicular with respect to each other OEL, preferably
wherein each straight line α
i and the vector sum H of the magnetic axis of the at least one dipole magnet (x41)
form an angle γ in the range from about 20° to about 70° or in the range from about
110° to about 160° or in the range from about 200° to about 250°, or in the range
from about 290° to about 340°; and the OEL exhibits a dynamic movement being a pattern
of bright areas and dark areas moving not only in a diagonal direction when the substrate
carrying said OEL is tilted about a vertical axis but also moving in a diagonal direction
when the substrate carrying said OEL is tilted about a horizontal axis (in other words,
the optical effect layer OEL described herein provides the optical impression of a
plurality of dark and a plurality of bright spots that are moving when the substrate
carrying said OEL is tilted about two perpendicular axes, i.e. horizontal axis and
vertical axis). Suitable magnetic assemblies are those shown in Figs 5-7 of
WO 2021/083808 A1.
[0091] According to one embodiment, the process described herein allows the preparation
of OELs wherein the first motif exhibits a dynamic motion upon tilting said OEL, said
dynamic movement being a loop-shaped body moving when the OEL is tilted; wherein said
step b') consists of exposing the first radiation curable coating composition to a
magnetic assembly such as those disclosed in
WO 2014/108404 A2. The disclosed magnetic assemblies of
WO 2014/108404 A2 comprise either a) at least one dipole magnet having a magnetic axis oriented to
be substantially perpendicular to the substrate and one or more pole pieces, said
one or more pole pieces being disposed below the at least one dipole magnet and in
contact with the dipole magnet and/or being spaced apart from and laterally surrounding
the at least one dipole magnet (see for example Figs 3-5 of
WO 2014/108404 A2); b) the at least one dipole magnet being a loop-shaped magnet having a radial magnetization
(i.e. having its magnetic North-South axis radially extending from the center of the
loop-shaped magnet to the periphery) (see for example Fig. 6 of
WO 2014/108404 A2); or c) the at least one dipole magnet being three or more dipole magnets disposed
in a loop-shaped arrangement having a radial magnetization (i.e. each of said three
or more dipole magnets has its magnetic axis oriented to be substantially parallel
to the substrate and has its magnetic axis aligned such as to be substantially radially
extending from the center of symmetry of the loop-shaped arrangement, wherein the
North-South directions of said three or more dipole magnets point either all towards
or all away from the center of symmetry (see for example Fig. 7 of
WO 2014/108404 A2).
WO 2014/108404 A2 also disclose spinneable magnetic assemblies comprising a) at least two bar dipole
magnets having their magnetic axis substantially parallel to the substrate and having
either the same magnetic direction (Fig. 9) or an opposite magnetic direction (see
Fig. 11 of
WO 2014/108404 A2) or comprising b) at least two bar dipole magnets having their magnetic axis substantially
perpendicular to the substrate and having an opposite magnetic direction (see Fig.
10 of
WO 2014/108404 A2).
[0092] According to one embodiment, the process described herein allows the preparation
of OELs wherein the first motif exhibits a dynamic motion upon tilting said OEL, said
dynamic movement being a multi-loop-shaped body moving when the OEL is tilted; wherein
said step b') consists of exposing the first radiation curable coating composition
to a magnetic assembly such as those disclosed in
WO 2014/108303 A2. Disclosed magnetic assemblies of
WO 2014/108303 A2 comprise one of the following:
- a) at least one dipole magnet being a loop-shaped magnet defining a loop and having
a magnetic axis oriented to be substantially perpendicular to the substrate and a
pole piece (x60) being disposed below the at least one dipole magnet and within the
loop of said at least one dipole magnet and having one or more protrusions disposed
within the loop of the at least one dipole magnet (see for example Figs 3-5 of WO 2014/108303 A2); or
- b) at least one dipole magnet having a magnetic axis oriented to be substantially
perpendicular to the substrate, an additional dipole magnet having a magnetic axis
oriented to be substantially perpendicular to the substrate and two or more pole pieces,
wherein said at least one dipole magnet and additional magnet have the same magnetic
direction and are provided in different distances from substrate, wherein said two
or more pole pieces are arranged in the space between the magnets and in contact therewith
and wherein at least one of the two or more pole pieces form one or more loop-shaped
projections surrounding a central area in which the at least one dipole magnet is
arranged (see for example Fig. 6 WO of 2014/108303 A2); or
- c) at least one dipole magnet having a magnetic axis oriented to be substantially
perpendicular to the substrate, a plate-like-shaped pole piece being disposed below
and in contact with the at least one dipole magnet, and one or more loop-shaped pole
pieces being disposed on top the at least one dipole magnet, wherein a central pole
piece of said one or more loop-shaped pole pieces is in contact with the at least
one dipole magnet, and wherein said plate-like-shaped pole piece may comprise one
or more protrusions laterally and spaced apart surrounding the at least one dipole
magnet (see for example Fig. 7 of WO 2014/108303 A2). WO 2014/108303 A2 also disclose spinneable magnetic assemblies comprising a) at least two bar dipole
magnets having their magnetic axis substantially perpendicular to the substrate (see
Figs 8-10 and 13-14 of WO 2014/108303 A2) or comprising b) at least four bar dipole magnets having their magnetic axis substantially
parallel to the substrate (see Figs 11, 12 and 15 of WO 2014/108303 A2).
[0093] According to one embodiment, the process described herein allows the preparation
of OELs wherein the first motif exhibits a dynamic motion upon tilting said OEL, said
dynamic movement being a loop-shaped body having a size that varies when the OEL is
tilted; wherein said step b') consists of exposing the first radiation curable coating
composition to a magnetic assembly such as those disclosed in
WO 2017/064052 A1,
WO 2017/080698 A1 and
WO 2017/148789 A1. Disclosed magnetic assemblies of
WO 2017/064052 A1,
WO 2017/080698 A1 and
WO 2017/148789 A1 comprise one of the following:
- a) at least one dipole magnet (x40) being either a single bar dipole magnet having
a North-South magnetic axis substantially parallel to a substrate or a combination
of two or more bar dipole magnets having a resulting North-South magnetic axis substantially
parallel to the substrate and b) a loop-shaped magnetic-field generating device (x30)
being either a single loop-shaped dipole magnet having a North-South magnetic axis
substantially perpendicular to the substrate or a combination of two or more dipole
magnets disposed in a loop-shaped arrangement and having a resulting North-South magnetic
axis substantially perpendicular to the substrate (see for example Figs 1-4 of WO 2017/064052 A1), or
- a) at least one dipole magnet (x40) being either a single dipole magnet having a magnetic
axis substantially parallel to the substrate or a combination of two or more bar dipole
magnets, each of the two or more bar dipole magnets having a magnetic axis substantially
parallel to the substrate and having a same magnetic field direction, b) a loop-shaped
magnetic-field generating device (x31) being either a single loop-shaped dipole magnet
having a magnetic axis substantially perpendicular to the substrate or a combination
of two or more dipole magnets disposed in a loop-shaped arrangement, each of the two
or more dipole magnets having a magnetic axis substantially perpendicular to the substrate
and having a same magnetic field direction, and c) a single dipole magnet (x32) having
a magnetic axis substantially perpendicular to the substrate or two or more dipole
magnets, each of the two or more dipole magnets having a magnetic axis substantially
perpendicular to the substrate and having a same magnetic field direction and/or one
or more pole pieces (see for example Figs 1-12 of WO 2017/080698 A1), or
- a) at least one dipole magnet (x40) being either a single bar dipole magnet having
a magnetic axis substantially parallel to the substrate or a combination of two or
more bar dipole magnets, each of the two or more bar dipole magnets having a magnetic
axis substantially parallel to the substrate and having a same magnetic field direction,
b) a loop-shaped magnetic-field generating device (x31) being either a single loop-shaped
magnet or a combination of two or more dipole magnets (x31), disposed in a loop-shaped
arrangement, the loop-shaped magnetic-field generating device having a radial magnetization,
and c) a single dipole magnet (x32) having a magnetic axis substantially perpendicular
to the substrate or a single dipole magnet having a magnetic axis substantially parallel
to the substrate (x32), or two or more dipole magnets (x32), each of said two or more
dipole magnets (x32) having a magnetic axis substantially perpendicular to the substrate,
wherein the North pole of said single dipole magnet (x32) or the North pole of at
least one of said two or more dipole magnets (x32) is pointing towards the substrate
when the North pole of the single loop-shaped magnet (x31) or of the two or more dipole
magnets (x31) forming the loop-shaped magnetic-field generating device is pointing
towards the periphery of said loop-shaped magnetic-field generating device, or wherein
the South pole of said single dipole magnet (x32) or the South pole of at least one
of said two or more dipole magnets (x32) is pointing towards the substrate when the
South pole of the single loop-shaped magnet (x31) or of the two or more dipole magnets
(x31) forming the loop-shaped magnetic-field generating device is pointing towards
the periphery of said loop-shaped magnetic-field generating device (x31) (see for
example Figs 1-14 of WO 2017/148789 A1).
[0094] According to one embodiment, the process described herein allows the preparation
of OELs wherein the first motif exhibits a dynamic motion upon tilting said OEL, said
dynamic movement being a loop-shaped body having a shape that varies when the OEL
is tilted; wherein said step b') consists of exposing the first radiation curable
coating composition to a magnetic assembly such as those disclosed in
WO 2018/054819 A1. In particular, the disclosed magnetic assembly of
WO 2018/054819 A1 comprises a loop-shaped magnetic-field generating device (x31) being either a single
loop-shaped magnet (x31) or a combination of two or more dipole magnets (x31) disposed
in a loop-shaped arrangement, the loop-shaped magnetic-field generating device (x31)
having a radial magnetization; and a single dipole magnet (x32) having a magnetic
axis substantially perpendicular to the substrate (x20) surface or two or more dipole
magnets (x32), each of said two or more dipole magnets (x32) having a magnetic axis
substantially perpendicular to the substrate surface, wherein the single dipole magnet
(x32) or the two or more dipole magnets (x32) are located partially within, within
or above the loop defined by the single loop-shaped magnet (x31) or partially within,
within or above the loop defined by the two or more dipole magnets (x31) disposed
in the loop-shaped arrangement, and wherein the South pole of said single dipole magnet
(x32) or the South pole of each of said two or more dipole magnets (x32) is pointing
towards the substrate surface when the North pole of the single loop-shaped magnet
(x31) or of the two or more dipole magnets (x31) forming the loop-shaped magnetic-field
generating device (x31) is pointing towards the periphery of said loop-shaped magnetic-field
generating device (x31) or the North pole of said single dipole magnet (x32) or the
North pole of each said two or more dipole magnets (x32) is pointing towards the substrate
surface when the South pole of the single loop-shaped magnet (x31) or of the two or
more dipole magnets (x31) forming the loop-shaped magnetic-field generating device
(x31) is pointing towards the periphery of said loop-shaped magnetic-field generating
device (x31).
[0095] According to one embodiment, the process described herein allows the preparation
of OELs wherein the first motif exhibits a dynamic motion upon tilting said OEL, said
dynamic movement being a moon crescent moving and rotating when the OEL is tilted;
wherein said step b') consists of exposing the first radiation curable coating composition
to a magnetic assembly such as those disclosed in
WO 2019/215148 A1. Disclosed magnetic assemblies of
WO 2019/215148 A1 comprise a) a first magnetic-field generating device (x30) having its North-South
magnetic axis substantially perpendicular to the substrate surface and having length
L1, b) a second magnetic-field generating device (x40) having its North-South magnetic
axis substantially perpendicular to the substrate and having a length L3, and c) a
flat pole piece (x50) lacking any protrusions or projections extending outside the
surface of said pole piece and having a length L5, wherein the first magnetic-field
generating device and the second magnetic-field generating device have a same magnetic
field direction, wherein the first magnetic-field generating device faces the substrate
and is disposed above the flat pole piece), wherein the second magnetic-field generating
device faces the environment and is disposed below the flat pole piece, wherein the
length L1 of the first magnetic-field generating device is smaller than the length
L3 of the second magnetic-field generating device, wherein the length L1 of the first
magnetic-field generating device is smaller than the length L5 of the flat pole piece,
and wherein the length L3 of the second magnetic-field generating device is smaller
than the length L5 of the pole piece (see for example Figs 1-12 of
WO 2017/148789 A1).
[0096] According to one embodiment, the process described herein allows the preparation
of OELs wherein the first motif exhibits a dynamic motion upon tilting said OEL, said
dynamic movement being a loop-shaped body surrounded by a substantially loop-shaped
body having their shape and/or their brightness varying when the OEL is tilted; wherein
said step b') consists of exposing the first radiation curable coating composition
to a magnetic assembly such as those disclosed in
WO 2020/193009 A1. Disclosed magnetic assemblies of
WO 2020/193009 A1 comprise a) a combination of three or more first dipole magnets (x31-ai), each of
said first dipole magnets having its center disposed on a loop in a plane parallel
to the substrate, wherein said first dipole magnets (x31-ai) have their magnetic axes
oriented to be substantially parallel to the substrate and b) at least one second
dipole magnet (x41) having its magnetic axis oriented to be substantially perpendicular
to the substrate and being arranged to have a projection of its center on the substrate
be located at a projection point within the loop, wherein the at least one second
dipole magnet (x41) is disposed above the combination of three or more first dipole
magnets (x31-ai), wherein angles α
i are formed between each of the vectors
Cx41Cx31-a2,
Cx41Cx31-a3) and the vector
![](https://data.epo.org/publication-server/image?imagePath=2024/12/DOC/EPNWA2/EP23218609NWA2/imgb0002)
of the magnetic axis of the respective first dipole magnet magnets (x31-ai), wherein
all of the angles α
i, when measured in a counterclockwise direction, are in a range from about 20° to
about 160° or in a range from about 200° to about 340°, and wherein each of the first
dipole magnets (x31-ai) is disposed at a first distance (Y
i), said first distance (Y
i) being on the substrate between the projection point and the center of the first
dipole magnet (x31-ai) (see for example Figs 2-9 of in
WO 2020/193009 A1).
[0097] According to one embodiment, the process described herein allows the preparation
of OELs wherein the first motif exhibits a dynamic motion upon tilting said OEL, said
dynamic movement being a change from dark to light of two areas when the OEL is tilted
(effect so-called flip-flop); wherein said step b') consists of exposing the first
radiation curable coating composition to a magnetic assembly such as those disclosed
in Figs 1, 3 and 6 of
US 2005/0106367.
[0098] According to one embodiment, the process described herein allows the preparation
of OELs wherein the first motif exhibits a dynamic motion upon tilting said OEL, said
dynamic movement being a comet-shaped spot rotating around said center of rotation
upon tilting said OEL, wherein said step b') consists of exposing the first radiation
curable coating composition to a magnetic assembly such as those disclosed in
WO 2019/038371 A1,
WO 2019/ 038370 A1 and
WO 2019/038369 A1. Disclosed magnetic assemblies of
WO 2019/038371 A1,
WO 2019/ 038370 A1 and
WO 2019/038369 A1 comprise at least one of the following:
- a) first magnetic-field generating device (x30) and b) a second magnetic-field generating
device (x40), wherein said first magnetic-field generating device (x30) and said second
magnetic-field generating device (x40) have mutually skew magnetic axes, wherein said
first magnetic-field generating device (x30) has its magnetic axis substantially perpendicular
to the axis of spinning and said second magnetic-field generating device (x40) has
its magnetic axis substantially perpendicular to the axis of spinning and wherein
the projection of the magnetic axis of the first magnetic-field generating device
(x30) and the projection of the magnetic axis of the second magnetic-field generating
device (x40) along the axis of spinning onto a plane perpendicular to the axis of
spinning form an angle (Ω) either in the range from about 5° to about 175° or in the
range from about -5° to about -175°, and wherein the first magnetic-field generating
device (x30) comprises a bar dipole magnet having its North-South magnetic axis substantially
perpendicular to the axis of spinning, or two or more bar dipole magnets, each of
said two or more bar dipole magnets having its North-South magnetic axis substantially
perpendicular to the axis of spinning and all of said two or more bar dipole magnets
having a same magnetic field direction, or a loop-shaped dipole magnet having its
North-South magnetic axis substantially perpendicular to the axis of spinning, or
a disc-shaped dipole magnet being nested inside a loop-shaped dipole magnet, each
of the disc-shaped dipole magnet and the loop-shaped dipole magnets having their North-South
magnetic axis substantially perpendicular to the axis of spinning and having a same
magnetic field direction, or two or more nested loop-shaped dipole magnets, each of
said two or more nested loop-shaped dipole magnets, having its North-South magnetic
axis substantially perpendicular to the axis of spinning and all of said two or more
nested ring-shaped magnets having a same magnetic field direction; and wherein the
second magnetic-field generating device (x40) comprises a disc-shaped dipole magnet
having its North-South magnetic axis substantially perpendicular to the axis of spinning,
or a loop-shaped dipole magnet having its North-South magnetic axis substantially
perpendicular to the axis of spinning, or a bar dipole magnet having its North-South
magnetic axis substantially perpendicular to the axis of spinning;
- a first magnetic-field generating device (x30) and b) a second magnetic-field generating
device (x40), wherein the first magnetic-field generating device (x30) comprises at
least one pair of two bar dipole magnets (x31) at least partially or fully embedded
in a supporting matrix (x32), each of said bar dipole magnets (x31) having its North-South
magnetic axis substantially parallel to the axis of spinning, said two bar dipole
magnets (x31) of the at least one pair having opposite magnetic field directions and
being arranged in a symmetric configuration around the axis of spinning along a line
(α), and
the second magnetic-field generating device (x40) comprises b1) a disc-shaped dipole
magnet (x41) having its North-South magnetic axis substantially perpendicular to the
axis of spinning, b2) a loop-shaped dipole magnet (x41) having its North-South magnetic
axis substantially perpendicular to the axis of spinning, b3) a bar dipole magnet
(x41) having its North-South magnetic axis substantially perpendicular to the axis
of spinning and arranged on the axis of spinning, and/or b4) at least one pair of
two bar dipole magnets (x41), each of said bar dipole magnets (x41) having its North-South
magnetic axis substantially parallel to the axis of spinning, said two bar dipole
magnets (x41) of the at least one pair having opposite magnetic field directions and
being arranged in a symmetric configuration around the axis of spinning along a line
(β), wherein the projection of the line (α) where the bar dipole magnets (x31) of
the at least one pair of the first magnetic-field generating device (x30) are arranged
and the projection of the magnetic axis of the second magnetic-field generating device
(x40) form along the axis of spinning onto a plane perpendicular to the axis of spinning
an angle (Ω) either in the range from about 5° to about 175° or in the range from
about -5° to about -175°; or
- a magnetic-field generating device (x30) comprising a disc-shaped dipole magnet (x31)
having its North-South magnetic axis substantially perpendicular to the axis of spinning,
or a loop-shaped, preferably a ring-shaped, dipole magnet (x31) having its North-South
magnetic axis substantially perpendicular to the axis of spinning, or a bar dipole
magnet (x31) having its North-South magnetic axis substantially perpendicular to the
axis of spinning and arranged on the axis of spinning, wherein the disc-shaped dipole
magnet (x31), the loop-shaped, preferably the ring-shaped, dipole magnet (x31) or
the bar dipole magnet (x31) of the magnetic-field generating device (x30) comprises
at least one pair of indentations (I) and/or at least one pair of voids (V) and/or
at least one pair of protrusions (P), wherein the indentations (I) of the at least
one pair, the voids (V) of the at least one pair and/or the protrusions (P) of the
at least one pair are located: symmetrically about the axis of spinning, and asymmetrically
with respect to a mirror plane which is perpendicular to the North-South magnetic
axis of the disc-shaped dipole magnet (x31), the loop-shaped, preferably the ring-shaped,
dipole magnet (x31) or the bar dipole magnet (x31) of the magnetic-field generating
device (x30) and which contains the axis of spinning.
[0099] According to one embodiment, the process described herein allows the preparation
of OELs, wherein step b') consists of independently exposing the first radiation curable
coating composition to the resultant magnetic field of a combination of a magnetic
assembly described hereafter for bi-axially orienting pigment particles and a soft
magnetic plate comprising one or more indentations (I) and/or one or more voids (V)
and/or one or more protrusions (P). The soft magnetic plate described herein comprises
one or more soft magnetic materials, i.e. materials having a low coercivity and a
high permeability µ. Their coercivity is lower than 1000 Am
-1 as measured according to IEC 60404-1 :2000, to allow for a fast magnetization and
demagnetization. Suitable soft magnetic materials have a maximum relative permeability
µR max of at least 5, where the relative permeability
µR is the permeability of the material µ relative to the permeability of the free space
µ
0 (
µR = µ / µ
0) (
Magnetic Materials, Fundamentals and Applications, 2nd Ed., Nicola A. Spaldin, p.
16-17, Cambridge University Press, 2011). Soft magnetic materials are described, for example, in the following handbooks:
(1)
Handbook of Condensed Matter and Materials Data, Chap. 4.3.2, Soft Magnetic Materials,
p. 758-793, and
Chap. 4.3. 4, Magnetic Oxides, p. 811-813, Springer 2005; (2)
Ferromagnetic Materials, Vol. 1, Iron, Cobalt and Nickel, p. 1-70, Elsevier 1999; (3)
Ferromagnetic Materials, Vol. 2, Chap. 2, Soft Magnetic Metallic Materials, p. 55-188, and
Chap. 3, Ferrites for non-microwave Applications, p. 189-241, Elsevier 1999; (4)
Electric and Magnetic Properties of Metals, C. Moosbrugger, Chap. 8, Magnetically
Soft Materials, p. 196-209, ASM International, 2000; (5)
Handbook of modern Ferromagnetic Materials, Chap. 9, High-permeability High-frequency
Metal Strip, p. 155-182, Kluwer Academic Publishers, 2002; and (6)
Smithells Metals Reference Book, Chap. 20.3, Magnetically Soft Materials, p. 20-9
- 20-16, Butterworth-Heinemann Ltd, 1992. The soft magnetic plate described herein may either be a plate made of one or more
metals, alloys or compounds of high magnetic permeability (hereafter referred as "soft
magnetic metal plate") or a plate made of a composite comprising soft magnetic particles
dispersed in a non-magnetic material (hereafter referred as "soft magnetic composite
plate"). According to one embodiment, the soft magnetic metal plate described herein
is made of one or more soft magnetic metals or alloys easily workable as sheets or
threads. Preferably, the soft magnetic metal plate described herein is made from one
or more materials selected from the group consisting of iron, cobalt, nickel, nickel-molybdenum
alloys, nickel-iron alloys (permalloy or supermalloy-type materials), cobalt-iron
alloys, cobalt-nickels alloys iron-nickel-cobalt alloys (Fernico-type materials),
Heusler-type alloys (such as Cu
2MnSn or Ni
2MnAl), low silicon steels, low carbon steels, silicon irons (electrical steels), iron-aluminum
alloys, iron-aluminum-silicon alloys, amorphous metal alloys (e.g. alloys like Metglas
®, iron-boron alloys), nanocrystalline soft magnetic materials (e.g. Vitroperm
®) and combinations thereof, more preferably selected from the group consisting of
iron, cobalt, nickel, low carbon steels, silicon irons, nickel-iron alloys and cobalt-iron
alloys and combinations thereof.
[0100] According to one embodiment, the process described herein comprises the bi-axial
orientation step b") consisting of a one-step orientation step.
[0101] Contrary to a mono-axial orientation wherein platelet-shaped magnetic or magnetizable
pigment particles are orientated in such a way that only their main axis is constrained
by the magnetic field, carrying out a bi-axial orientation means that the platelet-shaped
magnetic or magnetizable pigment particles are made to orientate in such a way that
their two main axes are constrained. In contrast to needle-shaped pigment particles
which can be considered as one-dimensional particles, platelet-shaped pigment particles
have an X-axis and a Y-axis defining a plane of predominant extension of the particles.
In other words, platelet-shaped pigment particles may be considered to be two-dimensional
particles due to the large aspect ratio of their dimensions as can be seen in Fig.
2. As shown in Fig. 2, a platelet-shaped pigment particle can be considered as a two-dimensional
structure wherein the dimensions X and Y are substantially larger than dimension Z.
Platelet-shaped pigment particles are also referred in the art as oblate particles
or flakes. Such pigment particles may be described with a main axis X corresponding
to the longest dimension crossing the pigment particle and a second axis Y perpendicular
to X which also lies within said pigment particles. Carrying out a bi-axial orientation
leads to platelet-shaped magnetic or magnetizable pigment particles having two main
axes constrained, i.e. bi-axially oriented neighboring platelet-shaped magnetic pigment
particles are close to each other in space and are essentially parallel to each other.
Put another way, bi-axial orientation aligns the planes of the platelet-shaped magnetic
or magnetizable pigment particles so that the planes of said pigment particles are
oriented to be essentially parallel relative to the planes of neighboring (in all
directions) platelet-shaped magnetic or magnetizable pigment particles.
[0102] Bi-axially oriented platelet-shaped magnetic or magnetizable pigment particles described
herein consist of platelet-shaped magnetic or magnetizable pigment particles forming
a sheet-like structure with their X and Y axes preferably substantially parallel to
the substrate (x10) surface and are planarized in said two dimensions.
[0103] According to another embodiment, the magnetic assembly described hereafter allow
to biaxially orient the platelet-shaped magnetic or magnetizable pigment particles
described herein such that the platelet-shaped magnetic or magnetizable pigment particles
have both their X-axis and Y-axis substantially parallel to the substrate (x10) surface.
[0104] According to another embodiment, the magnetic assembly described hereafter allow
to biaxially orient the platelet-shaped magnetic or magnetizable pigment particles
described herein such that the platelet-shaped magnetic or magnetizable pigment particles
have their X-Y plane substantially parallel to an imaginary spheroid surface.
[0105] According to another embodiment, the magnetic assembly described hereafter allow
to biaxially orient the platelet-shaped magnetic or magnetizable pigment particles
described herein such that the platelet-shaped magnetic or magnetizable pigment particles
have a first axis within the X-Y plane substantially parallel to the substrate (x10)
surface and a second axis being perpendicular to said first axis at a substantially
non-zero elevation angle to the substrate (x10) surface, or iii) have their X-Y plane
parallel to an imaginary spheroid surface.
[0106] According to one embodiment, the process described herein comprises the orientation
step b") consisting of a one-step orientation step to bi-axially orient the magnetic
or magnetizable pigment particles described herein so that i) they have both their
X-axis and Y-axis substantially parallel to the substrate (x10) surface, or ii) have
their X-Y plane parallel to an imaginary spheroid surface.
[0107] According to one embodiment shown for example in Fig. 7A, the orientation step b")
of the second set of steps (S2) is a one-step orientation step, wherein the substrate
(710) carrying the first coating layer (720') and the second coating layer (720")
on its same side is exposed to the magnetic field of a magnetic assembly (730") being
positioned on the side of the substrate (710) lacking the first and second coating
layers (720' and 720"). Fig. 7C (not true to scale) illustrates a process wherein
the orientation step b") consists of a one-step orientation step, wherein the substrate
(710) carrying the first and second coating layers (720' and 720") on its same side
is exposed to the magnetic field of a static magnetic assembly (730"), wherein said
magnetic assembly (730") is arranged in the vicinity of a rotating cylinder (2 positions
are shown in Fig. 7C), wherein the second coating layer (720") is exposed either to
one and/or the other of said magnetic assemblies (730").
[0108] According to one embodiment shown for example in Fig. 7B, the orientation step b")
of the second set of steps (S2) is a one-step orientation step, wherein the substrate
(710) carrying the first coating layer (720') on a first side and the second coating
layer (720") on a second side of the substrate (710) (i.e. the side of the substrate
(710) lacking the first coating layer (720')) is exposed to the magnetic field of
a magnetic assembly (730") being positioned on the side comprising the cured first
coating layer (720').
[0109] According to one embodiment shown for example in Fig. 8A, the orientation step b")
of the second set of steps (S2) is a one-step orientation step, wherein the substrate
(810) carrying the first coating layer (820') and the second coating layer (820")
on its same side is exposed to the magnetic field of a spinning magnetic assembly
(830") being positioned on the side of the substrate (810) lacking the first and second
coating layers (820' and 820"). Fig. 8C (not true to scale) illustrates a process
wherein the orientation step b") consists of a one-step orientation step, wherein
the substrate (810) carrying the first and second coating layers (820' and 820") described
herein is exposed to the magnetic field of a spinning magnetic assembly (830"), wherein
said magnetic assembly (830") is mounted on a rotating cylinder.
[0110] According to one embodiment shown for example in Fig. 8B, the orientation step b")
of the second set of steps (S2) is a one-step orientation step, wherein the substrate
(810) carrying the first coating layer (820') on a first side and the second coating
layer (820") on a second side of the substrate (810) (i.e. the side of the substrate
(810) lacking the first coating layer (820')) is exposed to the magnetic field of
a spinning magnetic assembly (830") being positioned on the side comprising the cured
first coating layer (820').
[0111] According to one embodiment shown in Fig. 9, the process described herein comprises
a third set of steps (S3), said third set of steps (S3) occurring after the second
set (S2), said a third set of steps (S3) comprising an orientation step b‴) consisting
of a one-step orientation step, wherein the substrate (910) carrying the first coating
layer (920') and the second coating layer (920") on a first and same side and carrying
a third coating layer (920") on a second side of the substrate (910) (i.e. the side
of the substrate lacking the first and second coating layers (920' and 920") is exposed
to the magnetic field of a spinning magnetic assembly (930‴) being positioned on the
side of the substrate (910) comprising the first and second cured coating layers (920'
and 920").
[0112] Suitable magnetic assemblies for bi-axially orienting the platelet-shaped magnetic
or magnetizable pigment particles described herein are provided hereafter as non-limiting
examples.
[0113] According to one embodiment shown for example in Fig. 10 (Example E1-E5, magnetic
assembly (1030) used during steps b') and Example E1 during step b")), bi-axially
orientation is carried out by exposing the radiation curable coating composition to
a magnetic assembly such as those disclosed in
WO 2021/239607 A1. The disclosed magnetic assemblies of
WO 2021/239607 A1 comprise:
- a) at least a first set (S1) and a second set (S2), each of the first and second sets
(S1, S2) comprising: i) one first bar dipole magnet (x31) having a first thickness
(L1), a first length (L4) and a first width (L5), and having its magnetic axis oriented
to be substantially parallel to the substrate, and ii) two second bar dipole magnets
(x32a and x32b) having a second thickness (L2), a second length (L6) and a second width (L7), the
two second bar dipole magnets (x32a, x32b) having their uppermost surfaces flush with each other, and having their magnetic
axes oriented to be substantially perpendicular to the substrate, wherein the first
bar dipole magnet (x31) of the first set (S1) has a magnetic direction opposite to
the magnetic direction of the first bar dipole magnet (x31) of the second set (S2),
the first bar dipole magnets (x31) of the first and second sets (S1, S2) is spaced
apart by a first distance (d1), the first bar dipole magnet (x31) of the first set
(S1) has substantially the same first length (L4) and first width (L5) as the first
bar dipole magnet (x31) of the second set (S2), and the two second bar dipole magnets
(x32a and x32b) of the first set (S1) has substantially the same second lengths (L6) and second
widths (L7) as the two second bar dipole magnets (x32a and x32b) of the second set (S2), wherein the first bar dipole magnet (x31) and the second
bar dipole magnets (x32a and x32b) of each of the first and second sets (S1, S2) are aligned to form a column, in that
the first bar dipole magnet (x31) of the first and second sets (S1, S2) is respectively
placed between and spaced apart from the second bar dipole magnets (x32a and x32b) by a second distance (d2), the first width (L5) and the second length (L6) being
substantially the same, the North pole of one second bar dipole magnet (x32a and x32b) of each of the first and second sets (S1, S2) pointing towards the first plane as
the North Pole of the first bar dipole magnet (x31) pointing towards said one, and
the South pole of the other of the second bar dipole magnet (x32a and x32b) of each of the first and second sets (S1, S2) pointing towards the first plane and
the South Pole of the first bar dipole magnet (x31) pointing towards said other; and
- b) a first pair (P1) of third bar dipole magnets (x33a and x33b) having a third thickness (L3), a third length (L8) and a third width (L9) and having
their magnetic axes oriented to be substantially parallel to the substrate, the second
width (L7) of the two second bar dipole magnets (x32a and x32b) of the first and second sets (S1, S2) having substantially the same value as the
third width (L9) of the third bar dipole magnets (x33a and x33b), each of the third bar dipole magnets (x33a and x33b) being aligned with one second bar dipole magnet (x32a and x32b) of the first set (S1) and one second bar dipole magnet (x32a and x32b) of the second set (S2) so as to form two lines, the third bar dipole magnets (x33a and x33b) being placed between and spaced apart from the respective second bar dipole magnets
(x32a and x32b) by a third distance (d3), the North poles of the third bar dipole magnets (x33a
and x33b) respectively pointing towards one of the second bar dipole magnets (x32a and x32b) when the North Poles of said ones of the second bar dipole magnets (x32a and x32b) point towards the substrate or the South poles of the third bar dipole magnets (x33a and x33b) respectively pointing towards one of the second bar dipole magnets (x32a and x32b) when the South Poles of said ones of the second bar dipole magnets (x32a and x32b) pointing towards the substrate.
[0114] According to one embodiment, the process described herein comprises i) steps b")
or ii) both steps b") and b') or iii) both steps b") and b‴) independently consisting
of exposing the radiation curable coating composition to a magnetic assembly such
as those described in
EP 2 157 141 A1. The disclosed magnetic assemblies of
EP 2 157 141 A1 provide a magnetic field that changes its direction while the platelet-shaped magnetic
or magnetizable pigment particles move through said assemblies, forcing the platelet-shaped
magnetic or magnetizable pigment particles to rapidly oscillate until both main axes
become parallel to the substrate, i.e. the platelet-shaped magnetic or magnetizable
pigment particles oscillate until they come to a stable sheet-like formation with
their X and Y axes parallel to the substrate to the substrate and are planarized in
said two dimensions. As shown in Fig. 5 of
EP 2 157 141, the magnetic assembly comprises a linear arrangement of at least three magnets that
are positioned in a staggered fashion or in zigzag formation, said at least three
magnets being on opposite sides of a feedpath where magnets at the same side of the
feedpath have the same polarity, which is opposed to the polarity of the magnet(s)
on the opposing side of the feedpath in a staggered fashion. The arrangement of the
at least three magnets provides a predetermined change of the field direction as platelet-shaped
magnetic or magnetizable pigment particles in a coating composition move past the
magnets (direction of movement: arrow). According to one embodiment, the magnetic
assembly comprises a) a first magnet and a third magnet on a first side of a feedpath
and b) a second magnet between the first and third magnets on a second opposite side
of the feedpath, wherein the first and third magnets have a same polarity and wherein
the second magnet has a complementary polarity to the first and third magnets. According
to another embodiment, the magnetic assembly further comprises a fourth magnets on
the same side of the feedpath as the second magnet, having the polarity of the second
magnet and complementary to the polarity of the third magnet.
[0116] According to one embodiment, bi-axially orientation is carried out by exposing the
radiation curable coating composition to spinning magnetic assemblies at an appropriate
speed. Examples of spinning magnetic assemblies are assemblies comprising one or more
disc-shaped spinning magnets or magnetic assemblies that are essentially magnetized
along their diameter. magnetic assemblies consisting of spinning magnets or magnetic-field
generating devices are described in
US 2007/0172261 A1, said spinning magnets or magnetic-field generating devices generating radially symmetrical
time-variable magnetic fields, allowing the bi-axial orientation of pigment particles.
These magnetic assemblies are driven by a shaft (or spindle) connected to an external
motor.
CN 102529326 B discloses examples of magnetic assemblies comprising spinning magnets that might
be suitable for bi-axially orienting pigment particles. In a preferred embodiment,
suitable magnetic assemblies are shaft-free disc-shaped spinning magnetic assemblies
constrained in a housing made of non-magnetic, preferably non-conducting, materials
and are driven by one or more magnet-wire coils wound around the housing. Examples
of such shaft-free disc-shaped spinning magnetic assemblies are disclosed in
WO 2015/082344 A1 and
WO 2016/026896 A1.
[0117] According to one embodiment shown for example in Figs. 12-13, the bi-axially orientation
step is carried out by exposing the radiation curable coating composition to the spinning
magnetic assemblies disclosed in
WO2018/141547 A1 at an appropriate speed. The disclosed magnetic assemblies (x30) of
WO2018/141547 A1 comprise
- a) a first block (A) comprising a1) a holder (1a) having mounted thereto a stator
comprising n magnet-wire coils (1b) disposed in n annular slots arranged in a circle
around the axis of a magnetic-field-guiding stator core (1c); and
- b) a second block (B) comprising:
b1) a casing (4)
b2) a rotor comprising m permanent magnet poles (3a) of alternating polarity arranged
around a circle in or on one side of a rotor disc (3b), wherein said m permanent magnet
poles (3a) face the rotor protection plate (2);
b3) a rotor protection plate (2), preferably a titanium rotor protection plate (2),
wherein said rotor protection plate (2) covers the rotor (3a + 3b); and
b4) a permanent magnet assembly (PMA) (5) driven by the rotor (3a + 3b), wherein said
permanent magnet assembly (PMA) (5) is disposed on the opposite side of the rotor
disc (3b),
wherein the stator (1b + 1c) and the rotor (3a + 3b) act together as a brushless DC
(BLDC) motor, wherein n is a multiple of 3 and m is a multiple of 2, provided that
n/m is 3/2, 3/4, 6/4, 6/8, 9/8, 9/10, 12/10 or 12/14, and
wherein the first block (A) is configured to be removeably fixed to a base of a rotating
magnetic orienting cylinder (RMC) or a flatbed (FB) magnetic orienting printing unit,
and
wherein the second block (B) is removeably fixed to the first block (A).
[0118] According to one embodiment, the orientation step b") of the second set of steps
(S2) is a two-steps orientation step, with a first step so as to bi-axially orient
at least a part of the platelet-shaped magnetic or magnetizable pigment particles
such as those described herein and a second step so as to bi-axially orient at least
a part of the platelet-shaped magnetic or magnetizable pigment particles such as those
described herein, wherein the magnetic assemblies (x30") used in both steps may be
the same or may be different.
[0119] According to one embodiment, the process described herein comprises a third set of
steps (S3), wherein the orientation step b‴) consists of exposing a third radiation
curable coating composition of step a‴) to a magnetic field of a magnetic assembly
(x30‴) so as to bi-axially orient at least a part of the platelet-shaped magnetic
or magnetizable pigment particles to i) have both their X-axis and Y-axis substantially
parallel to the substrate (x10) surface, or ii) have their X-Y plane parallel to an
imaginary spheroid surface, and form a third coating layer (x20‴) and a third magnetic
pattern, said third coating layer (x20‴) being adjacent to and in proper register
with at least a part of the first motif and/or adjacent to and in proper register
with at least a part of the second motif (i.e. the third motif is at least partially
adjacent to and in proper register with the first coating layer (x20') and/or adjacent
to and in proper register with at least a part of the second coating layer (x20"),
wherein said third magnetic pattern may be the same as the second magnetic pattern
or may be different from the second magnetic pattern.
[0120] According to one embodiment, the orientation step b‴) of the third set of steps (S3)
is a one-step orientation step or a two-steps orientation step such as those described
for step b') or for step b"). Preferably, the orientation step b‴) of the third set
of steps (S3) is a one-step orientation step such as those described for step b")
of the second set of steps (S2), wherein the so-obtained third magnetic pattern is
the same as the second magnetic pattern or different from the second magnetic pattern.
[0121] Also described herein are the following combinations of sets of steps:
- the first set of steps (S1) comprising the step b') and the second set (S2) comprising
the step b"), both independently consisting of one-step orientation steps as described
herein;
- the first set of steps (S1) comprising the step b') consisting of a two-steps orientation
step as described herein, preferably a two-steps orientation step independently comprising
a first orienting step to bi-axially orient the platelet-shaped magnetic or magnetizable
pigment particles followed by a second orienting step to re-orient the platelet-shaped
magnetic or magnetizable pigment particles described herein and the second set of
steps (S2) comprising the step b") consisting of a one-step orientation step as described
herein to bi-axially orient the platelet-shaped magnetic or magnetizable pigment particles;
and
- the first set of steps (S1) comprising the step b') and the second set of steps (S2)
comprising the step b"), both independently consisting of two-steps orientation steps,
the steps of b') consisting of first orienting step to bi-axially orient the platelet-shaped
magnetic or magnetizable pigment particles followed by the second orienting step to
re-orient the platelet-shaped magnetic or magnetizable pigment particles described
herein and the steps b") consisting of first orienting step to bi-axially orient the
platelet-shaped magnetic or magnetizable pigment particles followed by the second
orienting step to bi-axially orient the platelet-shaped magnetic or magnetizable pigment
particles described herein,
- the first set of steps (S1) comprising the step b'), the second set (S2) comprising
the step b") and the third set of steps (S3) comprising the step b‴), the three independently
consisting of one-step orientation steps as described herein;
- the first set of steps (S1) comprising the step b') consisting of the two-steps orientation
steps as described herein, preferably the two-steps orientation steps independently
comprising the first orienting step to bi-axially orient the platelet-shaped magnetic
or magnetizable pigment particles followed by the second orienting step to re-orient
the platelet-shaped magnetic or magnetizable pigment particles described herein; the
second set of steps (S2) comprising the step b") consisting of a one-step orientation
step as described herein; and the third set of steps (S3) comprising the step b‴)
consisting of a one-step orientation step as described herein;
- the first set of steps (S1) comprising the step b') and the second set of steps (S2)
comprising the step b"), both independently consisting of two-steps orientation steps,
the steps of b') consisting of first orienting step to bi-axially orient the platelet-shaped
magnetic or magnetizable pigment particles followed by the second orienting step to
re-orient the platelet-shaped magnetic or magnetizable pigment particles described
herein and the steps b") consisting of first orienting step to bi-axially orient the
platelet-shaped magnetic or magnetizable pigment particles followed by the second
orienting step to bi-axially orient the platelet-shaped magnetic or magnetizable pigment
particles described herein and the third set of steps (S3) comprising the step b‴)
consisting of a one-step orientation step as described herein; and
- the first set of steps (S1) comprising the step b'), the second set of steps (S2)
comprising the step b") and the third set of steps (S3) comprising the step b‴), the
three steps independently consisting of two-steps orientation steps, the steps of
b') consisting of first orienting step to bi-axially orient the platelet-shaped magnetic
or magnetizable pigment particles followed by the second orienting step to re-orient
the platelet-shaped magnetic or magnetizable pigment particles described herein, the
step b") consisting of first orienting step to bi-axially orient the platelet-shaped
magnetic or magnetizable pigment particles followed by the second orienting step to
bi-axially orient the platelet-shaped magnetic or magnetizable pigment particles described
herein and the third set of steps (S3) comprising the step b‴) consisting of first
orienting step to bi-axially orient the platelet-shaped magnetic or magnetizable pigment
particles followed by the second orienting step to bi-axially orient the platelet-shaped
magnetic or magnetizable pigment particles described herein.
[0122] Subsequently to or partially simultaneously with, preferably partially simultaneously
with, the steps of orienting the platelet-shaped magnetic or magnetizable pigment
particles described herein (step b') and step b") and optional step b‴)), the orientation
of the platelet-shaped magnetic or magnetizable pigment particles is independently
fixed or frozen (step c'), step c") and optional step c‴)) by curing. The first and
second coating compositions, optionally the third coating composition, must thus noteworthy
have a first state, i.e. a liquid or pasty state, wherein the compositions are not
yet hardened and wet or soft enough, so that the platelet-shaped magnetic or magnetizable
pigment particles dispersed in the compositions are freely movable, rotatable and
orientable upon exposure to a magnetic field, and a second hardened (e.g. solid or
solid-like) state, wherein the platelet-shaped magnetic or magnetizable pigment particles
are fixed or frozen in their respective positions and orientations.
[0123] Such a first and second state is preferably provided by using a certain type of coating
compositions. For example, the components of the first and second radiation curable
coating composition other than the platelet-shaped magnetic or magnetizable pigment
particles may take the form of an ink or coating composition such as those which are
used in security applications, e.g. for banknote printing. The aforementioned first
and second states can be provided by using a material that shows an increase in viscosity
in reaction to a stimulus such as for example a temperature change or an exposure
to an electromagnetic radiation. That is, when the fluid binder material is hardened
or solidified, said binder material converts into the second state, i.e. a hardened
or solid state, where the platelet-shaped magnetic or magnetizable pigment particles
are fixed in their current positions and orientations and can no longer move nor rotate
within the binder material. As known to those skilled in the art, ingredients comprised
in an ink or coating composition to be applied directly or indirectly onto a substrate
and the physical properties of said ink or coating composition must fulfil the requirements
of the process used to transfer said ink or coating composition. Consequently, the
binder material comprised in the coating compositions described herein is typically
chosen among those known in the art and depends on the coating or printing process
used to apply the ink or coating composition and the chosen hardening process.
[0124] The curing steps described herein (step c'), step c") and optional step c‴)) independently
involve a chemical reaction, for instance curing, which is not reversed by a simple
temperature increase (e.g. up to 80°C) that may occur during a typical use of a security
document. The term "curing" or "curable" refers to processes including the chemical
reaction, crosslinking or polymerization of at least one component in the applied
coating composition in such a manner that it turns into a polymeric material having
a greater molecular weight than the starting substances. Preferably, the curing causes
the formation of a stable three-dimensional polymeric network. Such a curing is generally
induced by applying an external stimulus to the compositions (i) after its application
(step a'), step a") and optional step a‴)) and (ii) subsequently to or partially simultaneously
with the orientation (step b'), step b") and optional step b‴)) of at least part of
the platelet-shaped magnetic or magnetizable pigment particles (step c'), step c")
and optional step c‴)). Advantageously the curing steps (step c'), step c") and optional
step c‴) of the first and second coating layers (x20' and x20") and optional third
coating layer (x20‴) described herein is independently carried out partially simultaneously
with the orientation (step b'), step b") and optional step b‴)) of at least a part
of the platelet-shaped magnetic or magnetizable pigment particles (step c'), step
c") and optional step c‴). Radiation curing, in particular UV-Vis curing, advantageously
leads to an instantaneous increase in viscosity of the first and second radiation
curable coating compositions after exposure to the irradiation, thus preventing any
further movement of the pigment particles and in consequence any loss of information
after the magnetic orientation steps. Preferably, the curing steps (step c'), step
c") and optional step c‴)) are independently carried out by irradiation with UV-visible
light (i.e. UV-Vis light radiation curing) or by E-beam (i.e. E-beam radiation curing),
more preferably by irradiation with UV-Vis light since UV-Vis curing advantageously
allows very fast curing processes and hence drastically decreases the preparation
time of the OEL described herein, documents and articles and documents comprising
said OEL.
[0125] Preferably, the first or the second or the optional third radiation curable coating
compositions, preferably the first and the second and the third UV-Vis-curable curable
coating compositions, independently comprise one or more compounds selected from the
group consisting of radically curable compounds and cationically curable compounds.
The compositions described herein may be hybrid systems and comprise a mixture of
one or more cationically curable compounds and one or more radically curable compounds.
Cationically curable compounds are cured by cationic mechanisms typically including
the activation by radiation of one or more photoinitiators which liberate cationic
species, such as acids, which in turn initiate the curing so as to react and/or cross-link
the monomers and/or oligomers to thereby harden the coating composition. Radically
curable compounds are cured by free radical mechanisms typically including the activation
by radiation of one or more photoinitiators, thereby generating radicals which in
turn initiate the polymerization so as to harden the coating composition. Depending
on the monomers, oligomers or prepolymers used to prepare the binder comprised in
the first and second radiation curable coating compositions described herein, different
photoinitiators might be used. Suitable examples of free radical photoinitiators are
known to those skilled in the art and include without limitation acetophenones, benzophenones,
benzyldimethyl ketals, alpha-aminoketones, alpha-hydroxyketones, phosphine oxides
and phosphine oxide derivatives, as well as mixtures of two or more thereof. Suitable
examples of cationic photoinitiators are known to those skilled in the art and include
without limitation onium salts such as organic iodonium salts (e.g. diaryl iodoinium
salts), oxonium (e.g. triaryloxonium salts) and sulfonium salts (e.g. triarylsulphonium
salts), as well as mixtures of two or more thereof. Other examples of useful photoinitiators
can be found in standard textbooks. It may also be advantageous to include a sensitizer
in conjunction with the one or more photoinitiators in order to achieve efficient
curing. Typical examples of suitable photosensitizers include without limitation isopropyl-thioxanthone
(ITX), 1-chloro-2-propoxy-thioxanthone (CPTX), 2-chloro-thioxanthone (CTX) and 2,4-diethyl-thioxanthone
(DETX) and mixtures of two or more thereof. The one or more photoinitiators comprised
in the UV-Vis-curable coating compositions are preferably present in a total amount
from about 0.1 wt-% to about 20 wt-%, more preferably about 1 wt-% to about 15 wt-%,
the weight percents being based on the total weight of the first and second radiation
curable coating compositions, respectively.
[0126] The first, the second and the third radiation curable coating compositions described
herein may further independently comprise one or more additives including without
limitation compounds and materials which are used for adjusting physical, rheological
and chemical parameters of the composition such as the viscosity (e.g. solvents and
surfactants), the consistency (e.g. anti-settling agents, fillers and plasticizers),
the foaming properties (e.g. antifoaming agents), the lubricating properties (waxes),
UV reactivity and stability (photosensitizers and photostabilizers) and adhesion properties,
etc. Additives described herein may be present in the coating compositions described
herein in amounts and in forms known in the art, including in the form of so-called
nano-materials where at least one of the dimensions of the particles is in the range
of 1 to 1000 nm.
[0127] The first and second radiation curable coating compositions described herein may
be independently prepared by dispersing or mixing the platelet-shaped magnetic or
magnetizable pigment particles described herein and the one or more additives when
present in the presence of the binder material described herein, thus forming liquid
compositions. When present, the one or more photoinitiators may be added to the composition
either during the dispersing or mixing step of all other ingredients or may be added
at a later stage, i.e. after the formation of the liquid coating composition.
[0128] The process for producing the OEL described herein comprises partially simultaneously
with step b) (step b') and/or b") and/or optional step b‴)) or subsequently to step
b) (step b') and/or b") and/or optional step b‴)), preferably partially simultaneously,
a curing step c) (step c') and/or c") and/or optional step c‴)) of the radiation curable
coating compositions. The step of curing the coating compositions allows the platelet-shaped
magnetic or magnetizable pigment particles to be fixed in their adopted positions
and orientations in a desired pattern to form the OEL, thereby transforming the radiation
curable coating composition to a second state. However, the time from the end of orientation
step b) (step b') and/or b") and/or optional step b‴)) to the beginning of the curing
step c) (step c') and/or c") and/or optional step c‴)) is preferably relatively short
in order to avoid any de-orientation and loss of information. Typically, the time
between the end of step b) (step b') and/or b") and/or optional step b‴)) and the
beginning of step c) (step c') and/or c") and/or optional step c‴)) is less than 1
minute, preferably less than 20 seconds, further preferably less than 5 seconds. It
is particularly preferable that there is essentially no time gap between the end of
the orientation step b) (step b') and/or b")) and the beginning of the curing step
c) (step c') and/or c") and/or optional step c‴)), i.e. that step c) follows immediately
after step b) or already starts while step b) is still in progress (partially simultaneously).
By "partially simultaneously", it is meant that both steps are partly performed simultaneously,
i.e. the times of performing each of the steps partially overlap. In the context described
herein, when curing is performed partially simultaneously with the step c), it must
be understood that curing becomes effective after the orientation so that the platelet-shaped
magnetic or magnetizable pigment particles orient before the complete or partial curing
of the OEL. As mentioned herein, the curing step c)) (step c') and/or c") and/or optional
step c‴)) may be performed by using different means or processes depending on the
binder material comprised in the coating composition that also comprises the platelet-shaped
magnetic or magnetizable pigment particles.
[0129] The curing steps generally may be any step that increases the viscosity of the radiation
curable coating composition such that a substantially solid material adhering to the
substrate is formed. The curing steps may involve a physical process based on the
evaporation of a volatile component, such as a solvent, and/or water evaporation (i.e.
physical drying). Herein, hot air, infrared or a combination of hot air and infrared
may be used. Alternatively, the curing steps may include a chemical reaction, such
as a curing, polymerizing or cross-linking of the binder and optional initiator compounds
and/or optional cross-linking compounds comprised in the radiation curable coating
composition. Such a chemical reaction may be initiated by heat or IR irradiation as
outlined above for the physical hardening processes, but may preferably include the
initiation of a chemical reaction by a radiation mechanism including without limitation
Ultraviolet-Visible light radiation curing (hereafter referred as UV-Vis curing) and
electronic beam radiation curing (E-beam curing); oxypolymerization (oxidative reticulation,
typically induced by a joint action of oxygen and one or more catalysts preferably
selected from the group consisting of cobalt-containing catalysts, vanadium-containing
catalysts, zirconium-containing catalysts, bismuth-containing catalysts and manganese-containing
catalysts); cross-linking reactions or any combination thereof.
[0130] Radiation curing is particularly preferred, and UV-Vis light radiation curing is
even more preferred, since these technologies advantageously lead to very fast curing
processes and hence drastically decrease the preparation time of any article comprising
the OEL described herein. Moreover, radiation curing has the advantage of producing
an almost instantaneous increase in viscosity of the coating composition after exposure
to the curing radiation, thus minimizing any further movement of the particles. In
consequence, any loss of orientation after the magnetic orientation step can essentially
be avoided. Particularly preferred is radiation-curing by photo-polymerization, under
the influence of actinic light having a wavelength component in the UV or blue part
of the electromagnetic spectrum (typically 200 nm to 650 nm; more preferably 200 nm
to 420 nm). Suitable curing units (x50', x50" and optional x50‴) for the curing steps
(step c') and step c") and/or optional step c‴)) may comprise a high-power light-emitting-diode
(LED) lamp, or an arc discharge lamp, such as a medium-pressure mercury arc (MPMA)
or a metal-vapor arc lamp, as the source of the actinic radiation. On the contrary
to medium-pressure mercury lamps that have emission bands in the UV-A, UV-B and UV-C
regions of the electromagnetic spectrum, UV-LED lamps emit radiation in the UV-A region
and/or visible (Vis) region, e.g. in the range from about 350 nm to about 470 nm.
Moreover, current UV-LED and Vis-LED lamps emit quasi monochromatic radiation, i.e.
only emit at one wavelength, such as 365 nm, 385 nm, 395 nm, 405 nm or 450 nm. Preferably,
at least one of the steps c') and c") and optional c‴), more preferably steps c')
and c") and optional step c‴), described herein are carried out by exposing the first
coating layer (x20') and the second coating layer (x20") and the optional third coating
layer (x20‴), respectively, to UV light with the LED curing unit (x50', x50", x50‴),
preferably to one or more wavelengths between about 355 nm and about 415 nm, more
preferably by exposure to UV light at 365 nm and/or 385 nm and/or 395 nm, emitted
from the LED curing unit (x50', x50", x50‴)
[0131] The process described herein may further comprise a step of customization during
the first set of steps so as produce OELs comprising a first motif further exhibiting
one or more indicia, wherein said step of customization occurs after step b') and
prior to step c'). The customization steps are preferably carried out by independently
applying a liquid coating composition on top of the coating layer which is still is
a wet state (a wet-on-wet process), said application being carried out contactless
fluid microdispensing process such as disclosed in
WO 2021/259527 A1.
[0132] The present invention provides the processes to produce the OELs described herein
on the substrate (x10) described herein. The substrate described herein is preferably
selected from the group consisting of papers or other fibrous materials (including
woven and non-woven fibrous materials), such as cellulose, paper-containing materials,
glasses, metals, ceramics, plastics and polymers, metalized plastics or polymers,
at least partially opacified plastics or polymers, composite materials and mixtures
or combinations of two or more thereof. Typical paper, paper-like or other fibrous
materials are made from a variety of fibers including without limitation abaca, cotton,
linen, wood pulp, and blends thereof. As is well known to those skilled in the art,
cotton and cotton/linen blends are preferred for banknotes, while wood pulp is commonly
used in non-banknote security documents. Typical examples of plastics and polymers
include polyolefins such as polyethylene (PE) and polypropylene (PP) including biaxially
oriented polypropylene (BOPP), polyamides, polyesters such as polyethylene terephthalate)
(PET), poly(1,4-butylene terephthalate) (PBT), polyethylene 2,6-naphthoate) (PEN)
and polyvinylchlorides (PVC). Spunbond olefin fibers such as those sold under the
trademark Tyvek
® may also be used as substrate. Typical examples of metalized plastics or polymers
include the plastic or polymer materials described hereabove having a metal disposed
continuously or discontinuously on their surface. Typical examples of metals include
without limitation aluminum (Al), chromium (Cr), copper (Cu), gold (Au), silver (Ag),
alloys thereof and combinations of two or more of the aforementioned metals. The metallization
of the plastic or polymer materials described hereabove may be done by an electrodeposition
process, a high-vacuum coating process or by a sputtering process. Opacified polymers
have been developed with the aim of mimicking the appearance and some properties of
conventional paper-based substrates for security document and consist of polymeric
transparent substrates which are surface treated typically on one or on both of their
sides with opacifying layers so as to form opacified polymer based substrates. Typical
examples of composite materials include without limitation multilayer structures or
laminates of paper and at least one plastic or polymer material such as those described
hereabove as well as plastic and/or polymer fibers incorporated in a paper-like or
fibrous material such as those described hereabove. Of course, the substrate can comprise
further additives that are known to the skilled person, such as fillers, sizing agents,
whiteners, processing aids, reinforcing or wet strengthening agents, etc. When the
OELs produced according to the present invention are used for decorative or cosmetic
purposes including for example fingernail lacquers, said OEL may be produced on other
type of substrates including nails, artificial nails or other parts of an animal or
human being.
[0133] According to one embodiment, the substrate (x10) described herein is a transparent
substrate preferably selected from the group consisting of transparent polyolefins
(such as polyethylene (PE) and polypropylene (PP) including biaxially oriented polypropylene
(BOPP)), transparent polyamides, transparent polyesters (such as polyethylene terephthalate)
(PET), poly(1,4-butylene terephthalate) (PBT), polyethylene 2,6-naphthoate) (PEN)
and transparent polyvinylchlorides (PVC), more preferably biaxially oriented polypropylene;
or a partially opacified substrate, in particular an at least partially opacified
transparent polymer, preferably selected from the group consisting of transparent
polyolefins (such as polyethylene (PE) and polypropylene (PP) including biaxially
oriented polypropylene (BOPP)), transparent polyamides, transparent polyesters (such
as polyethylene terephthalate) (PET), poly(1,4-butylene terephthalate) (PBT), polyethylene
2,6-naphthoate) (PEN) and transparent polyvinylchlorides (PVC), more preferably biaxially
oriented polypropylene. According to one embodiment, the OELs described herein are
present on a banknote and are present on a transparent substrate such as those described
herein and preferably in the form of a window or a foil or on an at least partially
opacified substrate such as those described herein, preferalby in the non-opacified
areas, preferably in the form of a non-opacified area in the form of a window or a
foil.
[0134] The substrates (x10) described herein may be in the form of webs, sheets, thread
reels, film reels, labels of the roll or label stocks, preferably sheets.
[0135] Should the OEL produced according to the present invention be on a security document,
and with the aim of further increasing the security level and the resistance against
counterfeiting and illegal reproduction of said security document, the substrate may
comprise printed, coated, or laser-marked or laser-perforated indicia, watermarks,
security threads, fibers, planchettes, luminescent compounds, windows, foils, decals
and combinations of two or more thereof. With the same aim of further increasing the
security level and the resistance against counterfeiting and illegal reproduction
of security documents, the substrate may comprise one or more marker substances or
taggants and/or machine readable substances. According to one embodiment, the substrate
(x10) comprises a printed pattern, preferably an offset printed pattern, wherein at
least one of the radiation curable coating compositions of steps a') and a") and optional
a‴) is applied at least partially on top of said printed pattern and the process described
herein comprises a step of printing an ink on the substrate (x10) described herein,
wherein said step occurs prior to step a') and step a") and optional step a‴) described
herein, as the case may be.
[0136] If desired, a primer layer may be applied to the substrate (x10) prior to the step
a') or prior to step a") or prior to the optional step a‴). This may enhance the quality
of the OEL described herein or promote adhesion. Examples of such primer layers may
be found in
WO 2010/058026 A2.
[0137] With the aim of increasing the durability through soiling or chemical resistance
and cleanliness and thus the circulation lifetime of an article, a security document
or a decorative element or object comprising the OEL obtained by the process described
herein, or with the aim of modifying their aesthetical appearance (e.g. optical gloss),
one or more protective layers may be applied on top of the OEL. When present, the
one or more protective layers are typically made of protective varnishes. These may
be transparent or slightly colored or tinted and may be more or less glossy. Protective
varnishes may be radiation curable compositions, thermal drying compositions or any
combination thereof. Preferably, the one or more protective layers are radiation curable
compositions, more preferable UV-Vis curable compositions. The protective layers are
typically applied after the formation of the OEL.
[0138] The process described herein may further comprise a step of embossing the OEL described
herein using for example an embossing dye or an intaglio printing plate as disclosed
in
WO 2012/025206 A2 and
WO 2019/233624 A1,
[0140] The present invention further provides optical effect layers (OELs) produced by the
process according to the present invention.
[0141] According to one embodiment shown in the Examples E4-E5, the OEL comprises the first
motif comprising platelet-shaped magnetic or magnetizable pigment particles oriented
according to the first magnetic pattern described herein, the second motif comprising
the platelet-shaped magnetic or magnetizable pigment particles oriented according
to the second magnetic pattern described herein, and a third motif comprising the
platelet-shaped magnetic or magnetizable pigment particles oriented according to the
third magnetic pattern described herein, wherein the first and second patterns are
different from each other, the third and second patterns are the same or different
from each other, wherein the second motif is at least partially adjacent to and in
proper register with the first motif and wherein the third motif is at least partially
adjacent to and in proper register with the first motif and/or at least partially
adjacent to and in proper register with the second motif. Also described herein are
processes for producing OELs with the three motifs described herein, wherein said
processes comprise the first set of steps (S1) a'), b') and c') described herein,
the second set of steps (S2) a"), b") and c") described herein and a third set of
steps (S3) a‴), b‴) and c‴) described herein, said third set of steps (S3), in particular
said step a‴) being carried out subsequently to and continuously with step c").
[0142] According to one embodiment shown in Fig. 1C, the process described herein comprises
the two set of steps (S1 and S2) described herein and further comprises a third set
of steps (S3) so as to produce an optical effect layer (OEL) comprising the first
motif comprising magnetically oriented platelet-shaped magnetic or magnetizable pigment
particles oriented according to the first magnetic pattern described herein, the second
motif comprising magnetically oriented platelet-shaped magnetic or magnetizable pigment
particles oriented according to the second magnetic pattern described herein and a
third motif comprising magnetically oriented platelet-shaped magnetic or magnetizable
pigment particles oriented according to a third magnetic pattern, wherein the substrate
(x10) comprises the first coating layer (x20') and the second coating layer (x20")
being present on the same side of the substrate (x10), said third set of steps (S3)
comprising:
a‴) applying onto the side of the substrate (x10) lacking the first coating layer
(x20') and lacking the second coating layer (x20") in register a third radiation curable
coating composition, preferably a third UV-Vis-curable curable coating composition,
comprising platelet-shaped magnetic or magnetizable pigment particles so as to form
a third coating layer (x20‴), said coating composition being in a first state, and
at least a part of the third coating layer (x20‴) being adjacent to at least a part
of the first coating layer (x20') and/or adjacent to at least a part of the second
coating layer (x20") (see for example Fig. 1C and Fig. 9);
b‴) exposing the third radiation curable coating composition of step a‴) to a magnetic
field of a magnetic assembly (x30‴) so as to bi-axially orient at least a part of
the platelet-shaped magnetic or magnetizable pigment particles; and
c‴) at least partially curing the second radiation curable coating composition of
step b‴) to a second state so as to fix the platelet-shaped magnetic or magnetizable
pigment particles in their adopted positions and orientations and so as to produce
the third motif.
[0143] According to one embodiment, the process described herein comprises the two sets
of steps (S1 and S2) described herein and further comprises a third set of steps (S3)
so as to produce an optical effect layer (OEL) comprising the first motif comprising
magnetically oriented platelet-shaped magnetic or magnetizable pigment particles oriented
according to the first magnetic pattern described herein, the second motif comprising
magnetically oriented platelet-shaped magnetic or magnetizable pigment particles oriented
according to the second magnetic pattern described herein and a third motif comprising
magnetically oriented platelet-shaped magnetic or magnetizable pigment particles oriented
according to a third magnetic pattern, wherein the first coating layer (x20') is present
on a first side of the substrate (x10) and the second coating layer (x20") is present
on a second side (i.e. the opposite side) of the substrate (x10), said third set of
steps (S3) comprising:
a‴) applying onto the side of the substrate (x10) comprising the first coating layer
(x20') in a cured state and lacking the second coating layer (x20") in register a
third radiation curable coating composition, preferably a third UV-Vis-curable curable
coating composition, comprising platelet-shaped magnetic or magnetizable pigment particles
so as to form a third coating layer (x20‴), said coating composition being in a first
state, and at least a part of the third coating layer (x20‴) being adjacent to at
least a part of the first coating layer (x20') and/or adjacent to at least a part
of the second coating layer (x20");
b‴) exposing the third radiation curable coating composition of step a‴) to a magnetic
field of a magnetic assembly (x30‴) so as to bi-axially orient at least a part of
the platelet-shaped magnetic or magnetizable pigment particles; and
c‴) at least partially curing the third radiation curable coating composition of step
b‴) to a second state so as to fix the platelet-shaped magnetic or magnetizable pigment
particles in their adopted positions and orientations as described herein and so as
to produce the third motif.
[0144] According to one embodiment, the process described herein comprises the two sets
of steps (S1 and S2) described herein and further comprises a third set of steps (S3)
so as to produce an optical effect layer (OEL) comprising the first motif comprising
magnetically oriented platelet-shaped magnetic or magnetizable pigment particles oriented
according to the first magnetic pattern described herein, the second motif comprising
magnetically oriented platelet-shaped magnetic or magnetizable pigment particles oriented
according to the second magnetic pattern described herein and a third motif comprising
magnetically oriented platelet-shaped magnetic or magnetizable pigment particles oriented
according to a third magnetic pattern, wherein the first coating layer (x20') is present
on a first side of the substrate (x10) and the second coating layer (x20") is present
on a second side (i.e. the opposite side), of the substrate (x10), said third set
of steps (S3) comprising:
a‴) applying onto the side of the substrate (x10) comprising the second coating layer
(x20") in a cured state and lacking the first coating layer (x20') in register a third
radiation curable coating composition, preferably a third UV-Vis-curable curable coating
composition, comprising platelet-shaped magnetic or magnetizable pigment particles
so as to form a third coating layer (x20‴), said coating composition being in a first
state, and at least a part of the third coating layer (x20‴) being adjacent to at
least a part of the first coating layer (x20') and/or adjacent to at least a part
of the second coating layer (x20");
b‴) exposing the third radiation curable coating composition of step a‴) to a magnetic
field of a magnetic assembly (x30‴) so as to bi-axially orient at least a part of
the platelet-shaped magnetic or magnetizable pigment particles; and
c‴) at least partially curing the third radiation curable coating composition of step
b‴) to a second state so as to fix the platelet-shaped magnetic or magnetizable pigment
particles in their adopted positions and orientations as described herein and so as
to produce the third motif.
[0145] According to one embodiment, the process described herein comprises the two sets
of steps (S1 and S2) described herein and further comprises a third set of steps (S3)
so as to produce an optical effect layer (OEL) comprising the first motif comprising
magnetically oriented platelet-shaped magnetic or magnetizable pigment particles oriented
according to the first magnetic pattern described herein, the second motif comprising
magnetically oriented platelet-shaped magnetic or magnetizable pigment particles oriented
according to the second magnetic pattern described herein and a third motif comprising
magnetically oriented platelet-shaped magnetic or magnetizable pigment particles oriented
according to a third magnetic pattern, wherein the substrate (x10) comprises the first
coating layer (x20') and the second coating layer (x20") being present on the same
side of the substrate (x10), said third set of steps (S3) comprising:
a‴) applying onto the side of the substrate (x10) comprising the first coating layer
(x20') and the second coating layer (x20") in a cured state in register a third radiation
curable coating composition, preferably a third UV-Vis-curable curable coating composition,
comprising platelet-shaped magnetic or magnetizable pigment particles so as to form
a third coating layer (x20‴), said coating composition being in a first state, and
at least a part of the third coating layer (x20‴) being adjacent to at least a part
of the first coating layer (x20') and/or adjacent to at least a part of the second
coating layer (x20");
b‴) exposing the third radiation curable coating composition of step a‴) to a magnetic
field of a magnetic assembly (x30‴) so as to bi-axially orient at least a part of
the platelet-shaped magnetic or magnetizable pigment particles; and
c‴) at least partially curing the third radiation curable coating composition of step
b‴) to a second state so as to fix the platelet-shaped magnetic or magnetizable pigment
particles in their adopted positions and orientations as described herein and so as
to produce the third motif.
[0146] The OEL described herein may be provided directly on a substrate (x10) on which it
shall remain permanently (such as for banknote applications). Alternatively, an OEL
may also be provided on a temporary substrate for production purposes, from which
the OEL is subsequently removed. This may for example facilitate the production of
the OEL, particularly while the binder material is still in its fluid state. Thereafter,
after curing the radiation curable compositions for the production of the OEL, the
temporary substrate may be removed from said OEL.
[0147] Alternatively, in another embodiment an adhesive layer may be present. Therefore,
an adhesive layer may be applied after the curing step of the last set of steps described
herein has been completed. Such an article may be attached to all kinds of documents
or other articles or items without printing or other processes involving machinery
and rather high effort. Alternatively, the substrate described herein comprising the
OEL described herein may be in the form of a transfer foil, which can be applied to
a document or to an article in a separate transfer step. For this purpose, the substrate
is provided with a release coating, on which the OEL is produced as described herein.
[0148] Also described herein are substrates (x10) comprising more than one, i.e. two, three,
four, etc. OELs obtained by the process described herein, each of said OELs independently
comprising the first and second motifs described herein in the form of the first and
second coating layers (x20', x20"). The process for producing more than one OELs on
the substrate (x10) described herein may comprises a first set of steps (S1) a'),
b') and c') to produce the first motif of a first OEL, a second set of steps (S2)
a"), b") and c") to produce the second motif of the first OEL, a third set of steps
(S3) a‴), b‴) and c‴) to produce the first motif of the second OEL and a fourth set
of steps (S4) a''''), b‴
') and c'''') to produce the second motif of the second OEL. Alternatively, the process
for producing more than one OELs on the substrate (x10) described herein may comprise
a first set of steps (S1) a'), b') and c') to produce the first motif of a first OEL,
a second set of steps(S2) a"), b") and c") to produce the first motif of the second
OEL, a third set of steps (S3) a‴), b‴) and c‴) to produce the second motif of the
first OEL and a fourth set of steps (S4) aʺʺ), bʺʺ) and cʺʺ) to produce the second
motif of the second OEL.
[0149] Also described herein are articles, in particular security documents, decorative
elements or objects, comprising the OEL produced according to the present invention.
The articles, in particular security documents, decorative elements or objects, may
comprise more than ones (for example two, three, etc.) OELs produced according to
the present invention.
[0150] As mentioned hereabove, the OEL produced according to the present invention may be
used for decorative purposes as well as for protecting and authenticating a security
document.
[0151] Typical examples of decorative elements or objects include without limitation luxury
goods, cosmetic packaging, automotive parts, electronic/electrical appliances, furniture
and fingernail articles.
[0152] Security documents include without limitation value documents and value commercial
goods. Typical examples of value documents include without limitation banknotes, deeds,
tickets, checks, vouchers, fiscal stamps and tax labels, agreements and the like,
identity documents such as passports, identity cards, visas, driving licenses, bank
cards, credit cards, transactions cards, access documents or cards, entrance tickets,
public transportation tickets or titles and the like, preferably banknotes, identity
documents, right-conferring documents, driving licenses and credit cards. The term
"value commercial good" refers to packaging materials, in particular for cosmetic
articles, nutraceutical articles, pharmaceutical articles, alcohols, tobacco articles,
beverages or foodstuffs, electrical/electronic articles, fabrics or jewelry, i.e.
articles that shall be protected against counterfeiting and/or illegal reproduction
in order to warrant the content of the packaging like for instance genuine drugs.
Examples of these packaging materials include without limitation labels, such as authentication
brand labels, tamper evidence labels and seals. It is pointed out that the disclosed
substrates, value documents and value commercial goods are given exclusively for exemplifying
purposes, without restricting the scope of the invention.
[0153] Alternatively, the OEL may be produced onto an auxiliary substrate such as for example
a security thread, security stripe, a foil, a decal, a window or a label and consequently
transferred to a security document in a separate step.
[0154] The skilled person can envisage several modifications to the specific embodiments
described above without departing from the spirit of the present invention. Such modifications
are encompassed by the present invention.
[0155] Further, all documents referred to throughout this specification are hereby incorporated
by reference in their entirety as set forth in full herein.
EXAMPLES
[0156] The present invention is now described in more details with reference to non-limiting
examples. The Examples below provide more details for the processes according to the
present invention and suitable magnetic assemblies for the production of optical effects
layers (OELs).
[0157] The OELs obtained by the process of Examples E1-E5 were prepared on a laboratory
equipment according to processes comprising two sets of steps (E1-E3) or three sets
of steps (E4-E5), wherein
the first orientation step b') of the first set is shown in Fig. 5A to mimic an industrial
process comprising a two-steps orientation step shown in Fig. 5B (E1-E5);
wherein the orientation step b") of the second set is shown in Fig. 7A to mimic an
industrial process comprising a one-step orientation step shown in Fig. 7C (for example
E1) or shown in Fig. 8A to mimic an industrial process comprising a one-step orientation
step shown in Fig. 8C (for examples E2-E5); and
wherein the orientation step b‴) of the third set is shown in Fig. 9 to mimic an industrial
process comprising a one-step orientation step similar to step b") shown in Fig. 8C
(for examples E4-E5).
[0158] The exact register of the first motif, the second motif and the third motif, when
present, (i.e. of the first, second and third cured coating layers (x20', x20", x20‴)
was ensured by using screens comprising, in addition to the motifs to be printed,
guiding marks.
[0159] Examples E1-E3 were independently prepared by using the UV-curable screen printing
inks of Table 1, wherein the first UV-curable screen printing ink I1 was applied in
steps a') on a first side of a transparent substrate (x10) (polymeric BOPP substrate,
Guardian
™ from CCL) so as to form the first coating layer (x20') and the second UV-curable
screen printing ink I1 was applied (step a")) on the same side of the substrate (x10)
and partially on top and in directed contact with the first coating layer (x20') (see
Figs 1A and 7).
[0160] Examples E4-E5 were independently prepared by using the UV-curable screen printing
inks of Table 1, wherein the first UV-curable screen printing ink I1 was applied in
steps a') on a first side of the transparent substrate (x10) so as to form the first
coating layer (x20'); the second UV-curable screen printing ink I1 was applied (step
a")) in register with the first coating layer (x20') on the same side of the substrate
(x10) and partially on top of and in directed contact with the first coating layer
(x20'); and the third UV-curable screen printing ink I2 was applied (step a‴)) in
register with the first and second coating layers (x20', x20") on the opposite side
of the substrate (x10) (i.e. the side of the substrate (x10) lacking the first and
second coating layers (x20' and x20") and on top of and in indirect contact (through
the substrate (x10) with the first coating layer (x20') and the second coating layer
(x20") (see Figs 1C and 9).
[0161] The first UV-curable screen printing ink was applied (step a')) by hand screen printing
using a first T90 screen (x40') so as to form the first coating layer (x20') having
a thickness of about 20 µm and having a shape as shown in Tables 2.
[0162] The second UV-curable screen printing ink was applied (step a")) on the first side
of the substrate (x10) in exact register with the first coating layer (x20") applied
in step a'), said application being carried out by hand screen printing using a second
T90 screen (x40") so as to form the second coating layer (x20") having a thickness
of about 20 µm and having a shape shown in Tables 2.
[0163] The third UV-curable screen printing ink was applied (step a‴)) on the second side
of the substrate (x10) (i.e. the side of the substrate (x10) lacking the first and
second coating layers (x20' and x20") in exact register with the first coating layer
(x20') applied in step a") and in exact register with the second coating layer (x20"),
said application being carried out by hand screen printing using a third T90 screen
(x40") so as to form the third coating layer (x20‴) having a thickness of about 20
µm and having a shape shown in Tables 2.
Two-steps orientation for the first coating layer/first motif (Fig. 5A, steps b')-c')
of Examples E1-E5)
[0164] The substrate (510) carrying the first coating layer (520') was moved (see grey arrow
in Fig. 5A) above a static magnetic assembly (530'-a) (step b'-1)) and was subsequently
placed on a second magnetic assembly (530'-b), said second magnetic assembly (530'-b)
being the magnetic assembly 1130 of Fig. 11. The so-obtained magnetic orientation
pattern of the platelet-shaped magnetic pigment particles was then, partially simultaneously
with the orientation step b'-2), (i.e. while the substrate (510) carrying the first
coating layer (520') was still in the magnetic field of the magnetic assembly (530'-b),
fixed by exposing for about 1.5 seconds to UV-curing the layer comprising the pigment
particles using a first UV-LED-lamp (550') from Phoseon (Type FireFlex 50 x 75 mm,
395 nm, 8 W/cm
2) (step c').
One-step orientation for the second coating layer/second motif applied on the side
of the substrate carrying the first coating layer/first motif (Fig. 7A, steps a")-c")
of Example E1)
[0165] The second UV-curable screen printing ink was applied (step a")) onto the same side
of substrate (710) carrying the first coating layer (720') so as to form the second
coating layer (720") in exact register with said first coating layer (720'). The substrate
(710) carrying the first and second coating layers (720' and 720") was placed above
a static magnetic assembly (730") being the magnetic assembly 1030 of Fig. 10 (step
b")) and moved back and forth ten times at a linear speed of about 1 m/s in the magnetic
field generated by said assembly (step b'-1)) with the side of the substrate (710)
lacking the first and second coating layers (720' and 720") facing the static magnetic
assembly (730"). The so-obtained magnetic orientation pattern of the platelet-shaped
magnetic pigment particles was then, partially simultaneously with the orientation
step b"), (i.e. while the substrate (710) carrying the first and second coating layers
(720' and 720") was still in the magnetic field of the magnetic assembly (730"), fixed
by exposing for about 1.5 seconds to UV-curing the layer comprising the pigment particles
using a second UV-LED-lamp (750") from Phoseon (Type FireFlex 50 x 75 mm, 395 nm,
8 W/cm
2) (step c")).
One-step orientation for the second coating layer/second motif applied on the side
of the substrate carrying the first coating layer/first motif (Fig. 8A, steps a")-c")
of Examples E2-E5)
[0166] The second UV-curable screen printing ink was applied (step a")) onto the same side
of the substrate (810) carrying the first coating layer (820') so as to form the second
coating layer (820") in exact register with said first coating layer (820'). The substrate
(810) carrying the first and second coating layers (820' and 820") was placed above
a spinning magnetic assembly (830") (step b")) with the side of the substrate (810)
lacking the first and second coating layers (820' and 820") facing the spinning magnetic
assembly (830"). The so-obtained magnetic orientation pattern of the platelet-shaped
magnetic pigment particles was then, partially simultaneously with the orientation
step b"), (i.e. while the substrate (810) carrying the first and second coating layers
(820' and 820") was still in the magnetic field of the magnetic assembly (830"), fixed
by exposing for about 1.5 seconds to UV-curing the layer comprising the pigment particles
using a second UV-LED-lamp (850") from Phoseon (Type FireFlex 50 x 75 mm, 395 nm,
8 W/cm
2) (step c")).
One-step orientation for the third coating layer/third motif applied on the side of
the substrate lacking the first and second coating layers (Fig. 9, steps a‴)-c‴) of
Examples E4-E5)
[0167] The substrate carrying the first coating layer (920') and the second coating layer
(920") on the same side was flipped/rotated and the third UV-curable screen printing
ink was applied (step a‴)) on the side of the substrate lacking the first and second
coating layers (920', 920") so as to form the third coating layer (920‴) in exact
register with said first coating layer (920') and in exact register with said second
coating layer (920"). The substrate (910) carrying the first, second and third coating
layers (920', 920", 920‴) was placed above a spinning magnetic assembly (930") with
the side of the substrate (910) comprising the first and second coating layers (920'
and 920") in a cured state facing the spinning magnetic assembly (930‴). The so-obtained
magnetic orientation pattern of the platelet-shaped magnetic pigment particles was
then, partially simultaneously with the orientation step b‴), (i.e. while the substrate
(910) carrying the first, second and third coating layers (920', 920", 920‴) was still
in the magnetic field of the spinning magnetic assembly (930‴), fixed by exposing
for about 1.5 seconds to UV-curing the layer comprising the pigment particles using
a second UV-LED-lamp (950‴) from Phoseon (Type FireFlex 50 x 75 mm, 395 nm, 8 W/cm
2) (step c‴)).
Table 1
|
I1 |
I2 |
Epoxyacrylate oligomer |
28.5% |
28.5% |
Trimethylolpropane triacrylate monomer |
20.6% |
20.6% |
Tripropyleneglycol diacrylate monomer |
20.6% |
20.6% |
Genorad 16 (Rahn) |
1% |
1% |
Aerosil 200 (Evonik) |
1.6% |
1.6% |
Speedcure TPO-L (Lambson) |
2.8% |
2.8% |
Omnirad 184 (IGM) |
2% |
2% |
Genocure® DETX (Rahn) |
0.5% |
0.5% |
Genocure® EPD (Rahn) |
2% |
2% |
BYK® 371 (BYK) |
2% |
2% |
Tego Foamex N (Evonik) |
1.9% |
1.9% |
7-layer colorshifting magnetic pigment particles (*) (Viavi Solutions) |
16.5% |
-- |
7-layer colorshifting magnetic pigment particles (**) / (Viavi Solutions) |
-- |
16.5% |
(*) gold-to-green colorshifting magnetic pigment particles having a flake shape (platelet-shaped
pigment particles) of diameter d50 of about 11 µm and thickness about 1 µm.
(**) green-to-blue colorshifting magnetic pigment particles having a flake shape (platelet-shaped
pigment particles) of diameter d50 of about 11 µm and thickness about 1 µm. |
Magnetic assembly of Fig. 10
[0168] The magnetic assembly (1030) used to bi-axially orient the pigment particles according
to the process of the present invention is disclosed in Fig. 3A of
WO 2021/239607 A1. The magnetic assembly (1030) consists of (530'-a) when used in the first step b'-1
of Fig. 5A or (730") when used in the step of Fig. 7A.
[0169] The magnetic assembly (1030) comprised a) a first set (S1) comprising a first bar
dipole magnet (1531-a) and two second bar dipole magnets (1032-a and 1032-d), a second
set (S2) comprising a first bar dipole magnet (1031-b) and two second bar dipole magnets
(1032-b and 1032-e), a third set (S3) comprising a first bar dipole magnet (1031-c)
and two second bar dipole magnets (1032-c and 1032-f),and b) a first pair (P1) of
third bar dipole magnets (1033-a and 1033-b) and a second pair (P2) of third bar dipole
magnets (1033-c and 1033-f).
[0170] The uppermost surface of the first bar dipole magnet (1031-a, 1031-b and 1031-c)
of the first, second and third sets (S1, S2, S3), of the second bar dipole magnets
(1032-a to 1032-f) of the first, second and third sets (S1, S2, S3) and of the third
bar dipole magnets (1033-a to 1033-d) of the first and second pairs (P1 and P2) were
flush with each other.
[0171] The third bar dipole magnet (1033-a) of the first pair (P1) was aligned with the
second bar dipole magnet (1032-a) of the first set (S1), with the second bar dipole
magnet (1032-b) of the second set (S2), with the third bar dipole magnet (1033-c)
of the second pair (P2) and with the second bar dipole magnet (1032-c) of the third
set (S3) so as to form a line. The third bar dipole magnet (1033-b) was aligned with
the second bar dipole magnet (1032-d) of the first set (S1), with the second bar dipole
magnet (1032-e) of the second set (S2), with the third bar dipole magnet (1033-d)
of the second pair (P2) and with the second bar dipole magnet (1032-f) of the third
set (S3) so as form a line. For each line described herein, the third bar dipole magnets
(1033-a, 1033-b, 1033-c and 1033-d) and the second bar dipole magnets (1032-a to 1032-f)
were spaced apart by a third distance (d2) of 2 mm. The first bar dipole magnet (1031-a)
of the first set (S1) and the first bar dipole magnet (1031-b) of the second set (S2),
and the first bar dipole magnet (1031-c) of the third set (S3) were spaced apart by
a distance (d3) of 24 mm.
[0172] The first bar dipole magnets (1031-a, 1031-b and 1031-c) of the first, second and
third sets (S1, S2, S3) had the following dimensions: first length (L1) of 60 mm,
first width (L2) of 40 mm and first thickness (L3) of 5 mm. Each of the second bar
dipole magnets (1032-a to 1032-f) of the first, second and third set (S1, S2, S3)
had the following dimensions: second length (L4) of 40 mm, second width (L5) of 10
mm and second thickness (L6) of 10 mm. Each of the third bar dipole magnets (1033-a
to 1033-d) of the first and second pairs (P1, P2) had the following dimensions: third
length (L7) of 20 mm, third width (L8) of 10 mm and third thickness (L9) of 10 mm.
[0173] The first bar dipole magnet (1031-a) of the first set (S1) and the second bar dipole
magnets (1032-a and 1032-d) of the first set (S1) were aligned to form a column; and
the first bar dipole magnet (1031-b) of the second set (S2) and the second bar dipole
magnets (1032-b and 1032-e) of the second set (S2) were aligned to form a column;
and the first bar dipole magnet (1031-c) of the third set (S3) and the second bar
dipole magnets (1032-c and 1032-f) of the third set (S3) were aligned to form a column.
For each set (S1, S2, S3) and each column described herein, the first bar dipole magnets
(1031-a, 1031-b and 1031-c) and the two second bar dipole magnets (1032-a and 1032-d;
1032-b and 1032-e; and 1032-c and 1032-f, respectively) were spaced apart by a second
distance (d1) of 2 mm.
[0174] The first bar dipole magnets (1031-a, 1031-b and 1031-c) of the first, second and
third sets (S1, S2, S3) had their magnetic axis oriented to be substantially parallel
to the substrate (1010) and substantially parallel to the substrate (1010), wherein
the first bar dipole magnet (1031-a) of the first set (S1) had its magnetic direction
opposite to the magnetic direction of the first bar dipole magnet (1031-b) of the
second set (S2), and the first bar dipole magnet (1031-b) of the second set (S2) had
its magnetic direction opposite to the magnetic direction of the first bar dipole
magnet (1031-c) of the third set (S3). The first bar dipole magnet (1031-a) of the
first set (S1) and first bar dipole magnet (1031-b) of the second set (S2), as well
as the first bar dipole magnet (1031-b) of the second set (S2) and the first bar dipole
magnet (1031-c) of the third set (S3), were spaced apart by a first distance (d3)
of 24 mm (corresponding to the sum of the third length (L7) and the two third distances
(d2)).
[0175] The two second bar dipole magnets (1032-a to 1032-f) of the first, second and third
set (S1, S2, S3) had their magnetic axis oriented to be substantially perpendicular
to the substrate (1010) surface. The South pole of the second bar dipole magnet (1032-a)
of the first set (S1), the South pole of the second bar dipole magnet (1032-e) of
the second set (S2) and the South pole of the second bar dipole magnet (1032-c) of
the third set (S3) pointed towards the substrate (1010). The North pole of the second
bar dipole magnet (1032-d) of the first set (S1), the North pole of the second bar
dipole magnet (1032-b) of the second set (S2) and the North pole of the second bar
dipole magnet (1032-f) of the third set (S3) pointed towards the substrate (1010).
The North pole of the first bar dipole magnet (1031-a) of the first set (S1) pointed
towards the second bar dipole magnet (1032-d) of the first set (S1), the North pole
of the second bar dipole magnet (1031-b) of the second set (S2) pointed towards the
first bar dipole magnet (1032-b) of the second set (S2) and the North pole of the
first bar dipole magnet (1031-c) of the third set (S3) pointed towards the second
bar dipole magnet (1032-f) of the third set (S3). The South pole of the third bar
dipole magnet (1033-a) of the first pair (P1) pointed towards the second bar dipole
magnet (1032-a) of the first set (S1), said second bar dipole magnet (1032-a) having
its South pole pointing towards the substrate (1010); the South pole of the third
bar dipole magnet (1033-d) of the second pair (P1) pointed towards the second bar
dipole magnet (1032-e) of the second set (S2), said second bar dipole magnet (1032-e)
having its South pole pointing towards the substrate (1010); the North pole of the
third bar dipole magnet (1033-b) of the first pair (P1) pointed towards the second
bar dipole magnet (1032-d) of the first set (S1), said second bar dipole magnet (1032-d)
having its North pole pointing towards the substrate (1010); and the North pole of
the third bar dipole magnet (1033-c) of the second pair (P2) pointed towards the second
bar dipole magnet (1032-b) of the second set (S2), said second bar dipole magnet (1032-b)
having its North pole pointing towards the substrate (1010).
[0176] The first bar dipole magnets (1031-a, 1031-b and 1031-c) of the first, second and
third sets (S1, S2, S3) and the second bar dipole magnets (1032-a to 1032-f) of the
first, second and third sets (S1, S2, S3) were made of NdFeB N42; the third bar dipole
magnets (1033-a, 1033-b, 1033-c and 1033-d) of the first and second pairs (P1, P2)
were made of NdFeB N48. All the magnets (1031-a to 1031-c, 1032-a to 1032-f and 1033-a
to 1033-d) were embedded in a non-magnetic supporting matrix (not shown) made of POM
having the following dimensions: 200 mm x 120 mm x 12 mm.
Magnetic assembly of Fig. 11
[0177] The magnetic assembly (1130) used to re-orient the pigment particles according to
the process of the present invention is shown in Fig. 11. The magnetic assembly (1130)
consists of (530'-b) when used in the second step b'-2) of Fig. 5A. The magnetic assembly
(1130) comprised a bar dipole magnet (1130-1) and a holding case (1170). The bar dipole
magnet (1130-1) had a length and a width of about 30 mm and a thickness of about 8.5
mm. The North-South magnetic axis of the bar dipole magnet (1130-1) was parallel to
the substrate (1110) surface, parallel to its length (L1) and parallel to the machine
feed direction (shown by the arrow in Fig. 11). The bar dipole magnet (1130-b1) was
made of NdFeB BMnPi 80/48.
[0178] The holding case (1170) was made of a hollow top part with a curved surface and a
bottom lid. The hollow top part had a length of about 40 mm, a width of about 40 mm,
a thickness of about 15.1 mm and was made of PPS. The bottom lid had a length of about
35 mm, a width of about 35 mm, a thickness of about 3 mm and was made of POM. The
curved surface was suitable to match the surface of a rotating magnetic cylinder of
an industrial printing press. The hollow top part was suitable for receiving the bar
dipole magnet (1130-1).
[0179] The distance (h) between the top surface of the bar dipole magnet (1130-1) and the
surface of the bottom substrate (1110) was about 3.35 mm.
Magnetic assembly of Fig. 12
[0180] The magnetic assembly (1230) was a spinning magnet similar to the assembly disclosed
in Fig. 1 of
WO 2018/151547 A1. The magnetic assembly (1230) consists of (830") when used in the step b") of Fig.
8A and consists of (930‴) when used in the step b‴) of Fig. 9. The magnetic assembly
(1230) comprised:
- i) a holder (1a) (external dimensions: 60 mm x 40 mm x 25 mm) made of aluminum, comprising
a rectangular recess (40 mm x 40 mm x 12.5 mm) to receive a "H"-shaped casing (4)
and a lid (8), and comprising a square cavity (36.5 mm x 36.5 mm x 6 mm) to receive
a magnetic-field-guiding stator core (1c);
- ii) a magnetic-field-guiding stator core (1c) (36 mm x 36 mm x 5 mm; see details in
Fig. 3A-B of WO 2018/151547 A1) was milled out of pure iron (Armco) and insulated with a layer of urethane lacquer
dried at 80°C for two hours. The magnetic-field-guiding stator core (1c) comprised
n (n = 6) annular winding slots (external diameter = 10 mm, internal diameter = 5
mm, depth = 4 mm) disposed in a circle (diameter = 25 mm) and a central hole for mounting
purposes. N (n = 6) 120 turns magnet-wire coils (1b) of enameled 0.20 mm self-bonding
copper wire (POLYSOL 155 1 x 02 MM HG from Distrelec AG) were wound and fixed to a
self-standing condition by a hot air treatment for about two minutes at 250°C and
inserted into the n (n = 6) winding slots. The magnet-wire coils (1b) were wired together
such as to form a 3-phase Y-scheme stator winding (u, v, w, u', v, w'), wherein each
two opposite magnet-wire coils (u, u'), (v, v') (w, w') were electrically connected
together such as to produce the same magnetic polarity at diametrically opposed locations.
The stator winding was connected via 4 wires (U,V,W,GND) to a motor driver described
hereabove;
- iii) a sensorless BLDC motor driver running at 12V DC power (DRV11873EVM, from Texas
Instruments);
- iv) a winding protection plate (7) (36 mm x 36 mm x 0.5 mm) made of titanium, comprising
a central mounting hole (10 mm diameter) and disposed on top of the magnetic-field-guiding
stator core (1c), protecting the magnet-wire coils (1b) and the magnetic-field-guiding
stator core (1c);
- v) a single-piece "H"-shaped casing (4) (see Fig. 4A-B of WO 2018/151547 A1) (30 mm x 30 mm x 12.5 mm) made of titanium and having four corners pillars (height
= 12.5 mm, width = 10 mm). The "H"-shaped casing (4) comprised a first and a second
cavity delimited by a horizontal middle-plate having a thickness of 2 mm and being
located at 7 mm from the top surface and 3.5 mm from the bottom surface of the "H"-shaped
casing (4). The "H"-shaped casing (4) comprised a central circular hole (diameter
= 10 mm) for receiving a ceramic ball bearing (3c) (external diameter = 10 mm, internal
diameter = 5 mm, height = 3 mm) which was fixed with epoxy glue in this hole;
- vi) a rotor protection plate (2) (30 mm x 30 mm x 0.5 mm) made of titanium, for closing
the first cavity of the "H"-shaped casing (4);
- vii) a rotor disc (3b) (see Fig. 2A-B of WO 2018/151547 A1) (diameter = 30 mm, thickness 2 mm) made of iron (Armco) and comprising a central
hub or protrusion with a M3-threaded hole (as illustrated in Fig 2A of WO 2018/151547 A1) on its upper surface; the rotor disc (3b) comprised on its lower surface, m (m =
8) cavities (diameter = 7 mm, depth = 1.2 mm), wherein m (m = 8) permanent magnet
poles (NdFeB N45 disc-shaped axially magnetized dipole magnets (3a) (diameter = 6
mm, thickness = 1 mm)) were glued with alternating North and South poles, yielding
an octupolar NSNSNSNS circular lower face of the rotor disc (3b). The rotor disc (3b)
was inserted into the first cavity of the H"-shaped casing (4), with the hub or protrusion
protruding through the ceramic ball bearing (3c);
- viii) a disc-shaped magnet support (6) support with a 3 mm mounting hole (diameter
= 30 mm, thickness = 2 mm) made of aluminum and fixed with an M3 screw to the hub
or protrusion of the rotor disc (3b);
- ix) a permanent magnet assembly (5) being a diametrically magnetized NdFeB N40 disc-shaped
dipole magnet (diameter = 25 mm, thickness = 2 mm) and glued onto the disc-shaped
magnet support (6); and
- x) a lid (8) (40 mm x 40 mm x 15 mm) made of PPS (polyphenylene sulfide), fitted into
the rectangular recess of the holder (A) and comprising a recess (30 mm x 30 mm x
13 mm) to accommodate the "H"-shaped casing (4).
[0181] The magnetic gap (G) given by the distance between the topmost surface of the stator
(1b + 1c), i.e. the top surface of the magnetic-field-guiding stator core (1c), and
the lowest surface of the rotor, was about 2.0 mm, comprising noteworthy the combined
thicknesses of the winding protection plate (7) and the titanium protection plate
(2) (2 x 0.5 mm) and a about 1 mm free air gap between the lower surface of the rotor
and the upper surface rotor protection plate (2).
[0182] The permanent magnet assembly (5) was used at a spinning rate of about 200 rpm for
about 2 seconds during the orientation step.
[0183] The distance between the top surface of the permanent magnet assembly (5) and the
bottom surface of the substrate (1210) was about 3 mm.
Magnetic assembly of Fig. 13
[0184] The magnetic assembly (1330) was a spinning magnet similar to the assembly disclosed
in Fig. 1 of
WO 2018/151547 A1. The magnetic assembly (1330) consists of (830") when used in the step b") of Fig.
8A and consists of (930‴) when used in the step b‴) of Fig. 9. The magnetic assembly
(1330) was the same as the magnetic assembly (1230) shown in Fig. 12 except that the
permanent magnet assembly (5) comprised a diametrically magnetized ring-shaped dipole
magnet (5-1) made of NdFeB N40 and having an external diameter of about 25 mm, an
internal diameter of about 14 mm and a thickness of about 2 mm and a diametrically
magnetized disc-shaped dipole magnet (5-2) made of NdFeB N40 and having a diameter
of about 25 mm and a thickness of about 2 mm. The ring-shaped dipole magnet (5-1)
was disposed directly on top of the disc-shaped dipole magnet (5-2) and was centrally
aligned with the disc-shaped dipole magnet (5-1). The assembly (1330) was used at
a spinning rate of about 200 rpm for about 2 seconds during the orientation step.
[0186] The OEL, i.e. the combination of the first motif, second motif and third motif, when
present, shown in Tables 2 had the following dimensions: length of about 25 mm and
height of about 20 mm.
[0187] The OEL of example E1 provided, when observed from the side of the substrate carrying
the first and second coating layers, a highly reflective image of a turtle with a
dynamic effect in the form of a rolling bar, said dynamic effect being particularly
visible within the head and legs areas of the turtle, which was moving in a vertical
direction when the substrate was tilted around a horizontal axis.
[0188] The OELs of examples E2-E3, when observed from the side of the substrate carrying
the first and second coating layers, provided a highly reflective image of a turtle
with a dynamic effect in the form of a rolling bar, said dynamic effect being particularly
visible within the head and legs areas of said turtle, and a particularly highly reflective
shell area of said turtle with a shimmering spot dynamic effect. The dynamic and bright
effect was moving in a vertical direction when the substrate was tilted around a horizontal
axis, while the shimmering spot dynamic effect was moving across the shell of said
turtle when the substrate was tilted around the same horizontal axis.
[0189] The OELs of example E1-E3 were identical when observed from both the recto and the
verso sides of the substrate although less reflective and bright when observed from
the verso side.
[0190] The OELs of examples E4-E5, when observed from the side of the substrate carrying
the first and second coating layers as well as from the side of the substrate carrying
the third coating layer, provided a highly reflective image of a turtle with a dynamic
effect in the form of a rolling bar, said dynamic effect being particularly visible
within the head and legs areas of said turtle, and a particularly highly reflective
shell of said turtle area with a shimmering spot dynamic effect. The dynamic and bright
effect was moving in a vertical direction when the substrate was tilted around a horizontal
axis, while the shimmering spot dynamic effect was moving across the shell of said
turtle when the substrate was tilted around the same horizontal axis. The OELs of
examples E4-E5 displayed a gold-to-green color travel effect when observed at face
viewing angle and at side viewing angle from the recto side of the substrate; when
observed from the verso side, the OELs of examples E4-E5 displayed a gold-to-green
color travel effect within the head and legs areas of said turtle, and mainly a green-to-blue
color travel effect within the shell areas of said turtle, when observed at face viewing
angle and at side viewing angle.